US3456156A - Apparatus for applying an electrostatic charge to fibrous material - Google Patents

Apparatus for applying an electrostatic charge to fibrous material Download PDF

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US3456156A
US3456156A US628868A US3456156DA US3456156A US 3456156 A US3456156 A US 3456156A US 628868 A US628868 A US 628868A US 3456156D A US3456156D A US 3456156DA US 3456156 A US3456156 A US 3456156A
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electrode
target
ion gun
deflector
web
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Claude William Kilby
James Gerald Smith
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T19/00Devices providing for corona discharge
    • H01T19/04Devices providing for corona discharge having pointed electrodes

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  • 317-4 14 Claims ABSTRACT OF THE DICLOSURE An apparatus for applying an electrostatic charge to fibrous material moving in a planar path.
  • An annular disc target electrode is located on one side of the path and a multi-needle ion gun is positioned on the opposite side of the path.
  • the needles of the ion gun are aimed at a portion of the target electrode to provide a corona discharge zone.
  • the target electrode is rotatable so that that portion of its surface outside the corona discharge zone can be cleaned during operation.
  • This invention concerns an apparatus for applying an electrostatic charge to fibrous material moving in a planar path. It is more particularly concerned with an apparatus for applying a charge to a fibrous web, thereby preventing the web from collapsing and providing an electrostatic force to promote controlled deposit of the web on an oppositely charged moving belt or roll.
  • a second electrode termed an ion gun, which is a corona charging electrode, is used to deposit an electrostatic charge on the open network as it passes along the surface of the target plate.
  • the charged network is then deposited on an oppositely charged belt or roll.
  • residues of polymer, fibrils or other substances have tended to collect on the target plate surface principally by electrostatic precipitation.
  • the residues cause a reduction in the charging efliciency with a resulting deterioration in the collected sheet.
  • interruption of the process is required while the target is cleaned or replaced. This, of course, is a disadvantage resulting in costly loss of production time.
  • an apparatus for applying an electrostatic charge to fibrous material moving in a planar path comprises an ion gun and an annular flat disc target electrode.
  • the ion gun is located in proximity to the path and has a multiplicity of needles, each connected to a source of high voltage, disposed across the width of the path and pointed toward the path, the points of the needles being located in a plane generally parallel to the path.
  • the target electrode is positioned so that its face is aligned in a plane generally parallel to the plane of the needle points and extends across the width of the path.
  • the needles of the ion gun are aimed at a portion of the electrode so as to provide a corona discharge zone between that portion of the electrode and the needles.
  • the apparatus further comprises a bearing for supporting the electrode for rotation in a plane generally parallel to the path.
  • the electrode is rotatable so that a clean portion can be rotated into the corona discharge zone during operation.
  • FIGURE 1 is a cross-sectional side view of the apparatus of the invention.
  • FIGURE 2 is a front view, partly in cross-section, of the apparatus of the invention.
  • FIGURE 3 is a front view of a U-shaped, multi-needle ion gun suitable for use in the apparatus of this invention.
  • FIGURE 4 is a side view of a scraper for continuously cleaning a rotating target electrode.
  • FIGURE 5 is a front view of the scraper of FIG- URE 4.
  • the target electrode is continuously rotatable and continuously cleaned during operation.
  • the preferred cleaning means is a scraper assembly comprising a scraper blade and means for urging the blade against the face of the electrode as it rotates.
  • the scraper assembly is surrounded by a housing connected to a vacuum line for collecting and removing debris cleaned from the electrode.
  • the needles of the ion gun are preferably disposed along the arc of a circle which is concentric with the target electrode.
  • the diameter of the circle must, of course, be greater than the inside diameter but less than the outside diameter of the target electrode.
  • the needles will be disposed over approximately a semicircle and will be aimed at the lower portion of the target electrode.
  • the scraper, or other means of cleaning the electrode will then be located at the upper portion of the electrode.
  • the apparatus of the invention is especially designed for use in combination with a circular rotatable baffle and means for rotating the baffle.
  • the baflle diameter is slightly less than the inside diameter of the target electrode.
  • the baflle is positioned so that it is concentric with the target electrode and so that the surface of the baflle at its periphery is aligned in the same plane as the surface of the target electrode.
  • the surface of the bailie is contoured to receive a fibrous strand moving in a generally horizontal direction on to deflect the strand into a generally vertical plane downward toward a collecting surface.
  • the baffle spreads the strand into a flattened web and causes the web to oscillate in a generally vertical plane.
  • the web As the web is deflected downward, it passes through the corona discharge zone between the ion gun and the target electrode.
  • the annular target electrode and with the ion gun needles arranged on the arc of a circle the area of the discharge zone through which the web must pass is equal at all points of oscillation.
  • FIGURE 1 shows a preferred embodiment of the apparatus of the invention comprising a rotatable strand deflector 1, an annular, flat-surfaced target electrode 2, and a multi-needle ion gun 3.
  • Deflector 1 and target plate 2 are also shown in the front view of the apparatus, FIGURE 2.
  • Location of the needles 4 of ion gun 3 are also indicated in FIGURE 2.
  • Ion gun 3 is shown in FIG. 3.
  • FIGURE 1 there is also shown a spinneret nozzle 5 terminating in exit orifice 6.
  • Axis 7 of orifice 6 is parallel to axis 8 of deflector 1. Both axes are horizontal.
  • a polymer solution under high temperature and pressure is extruded through orifice 6.
  • the solvent evaporates and the polymer solidifies, forming what has come to be known as a plexifilamentary strand 9.
  • This strand impinges upon the fillet portion 10 between hub portion 11 and disc portion 12 of deflector 1.
  • the strand 9 approaches the deflector 1 in a direction substantially parallel to the axis 8.
  • Deflector 1 diverts the strand downward through the area 13 between the needles 4 of ion gun 3 and target electrode 2. Expansion of the vaporized solvent against the hub of the rotating deflector causes the strand to be spread into a planar web 14 which increases in width as it passes through area 13, as indicated in FIGURE 2. It is in the area 13 that an electrostatic charge is applied to the fibrous web by corona discharge between needles 4 and target electrode 2. This electrostatic charge prevents the web 14 from collapsing and also aids in collecting and pinning the web on a surface, e.g. an oppositely charged moving belt, located below the spinning unit.
  • a surface e.g. an oppositely charged moving belt
  • Spinneret nozzle 5 is preferably the horizontal arm of a spinneret pack comprising an L-shaped solution supply tube.
  • the pack is adapted for mounting in the ceiling of a closed spinning cell above an oppositely charged surface.
  • the spinneret pack is further described and claimed in US. application of James G. Smith Ser. No. 628,888, filed simultaneously herewith. For further details on the spinneret pack, reference should be made to the Smith application, the entire disclosure of which is hereby incorporated.
  • the preferred deflector 1 is a one piece structure having a hub portion 11 and a flat disc portion 12, the disc portion having a circular trailing edge 15. Hub portion 11 and disc portion 12 are integrally connected by means of a fillet 10* having lobes 16. There should be one or more (preferably 2-4) lobes 16 in the fillet portion 10, the embodiment shown in FIGURES 1 and 2 having three. The presence of lobes 16 in fillet portion 10 cause the Web to oscillate from side to side (as viewed in FIGURE 2) as deflector 1 rotates. By proper design of the deflector web oscillation amplitudes as high as about :55 degrees can be obtained. The preferred deflector design is further described and claimed in US. application of 'Pollock and Smith, Ser. No. 628,871, filed simultaneously herewith. The entire disclosure of said application is hereby incorporated by reference.
  • the network 14 leaves the circular trailing edge of the rotating strand deflector 1 it passes directly to the flat surface of the annular electrode 2.
  • This surface should be in substantially the same plane as the top surface of disc portion 12 of deflector 1 or set back slightly therefrom. This permits the fibrous web to cross the circular trailing edge 15 of deflector 1 and over the circular leading edge 17 of target electrode 2 without gathering into clumps.
  • the circles defining the edges (17 and 18) of target electrode 2 are concentric with the circle defining the trailing edge 15 of deflector 1.
  • the web then passes across the surface of the flat target electrode 2. As it approaches the circular trailing edge 18 of target electrode 2 it passes through the corona discharge zone 13 between needles 4 of ion gun 3 and target electrode 2 where an electrostatic charge is placed on the web.
  • the charged web leaves the trailing edge 18 of electrode 2 and is deposited in overlapping, multidirectional layers on a moving, oppositely charged, belt (not shown).
  • a moving, oppositely charged, belt not shown.
  • the fibers are carried approximately the same distance across the surface regardless of orientation of the deflector at any particular moment.
  • the fiber at the end of the oscillation stroke had farther to travel than at the center of stroke and tended 'to lose momentum and to clump on the surface of the target electrode.
  • a rim 1-9 of epoxy resin or other insulating material is provided on the circular trailing edge 18 of target electrode 2.
  • the purpose of this rim is to avoid secondary ionization at -'the edge 18.
  • an inlaid ring 20 of epoxy material may be provided to reduce the amount of conducting material surface, thereby -reducing the amount of surface to be cleaned and providing a more uniformly concentrated field.
  • the ring 20 is inset to provide a smooth transition of the fiber from the deflector 1 to the; conducting portion 21 of the surface of target electrode 2.
  • deflector 1 is mounted on an extension 22 of shaft 23 of motor 24 to provide for rotation thereof.
  • Motor 24 is mounted on flange 25 which is in turn mounted on plate 26.
  • Plate 26 is welded to housing 27.
  • An 0 ring seal 28 is provided between flange 25 and plate 26 and seal members 28' are provided around shaft extension 22 to prevent entry of fluids to motor 24 or to the interior of housing 27.
  • the support means for annular target electrode 2 includes means for rotating the electrode during spinning so that a fresh surface may be presented as needed to the corona charging area 13. Electrode 2 rotates independently of and much slower than deflector 1. Thus when residues form on the target electrode 2 or when deposited there by electrostatic attraction, a fresh surface may be provided by rotation of the target electrode. The residues are thereby carried out of the charging area 13 and may be removed from the surface of electrode 2 by means which will be discussed hereinafter.
  • the target plate 2 is rotatably mounted on a tubular shaft 29 which is carried in ball bearings 30 which, in turn, are mounted inside the stationary ring 31.
  • the ring 31 extends outwardly from the housing 27 and is being secured to the plate 26.
  • a small slow-speed motor 32 which is secured to the plate 26; the motor body and the shaft are sealed in respect to the housing 27 in the same manner as themotor 24; the motor 32 carries a small pinion 33 which meshes with a gear 34 on stationary jackshaft 35.
  • a small pinion 36 Secured to the gear 34 is a small pinion 36 which meshes with a large gear 37 secured to the rearward end of the tubular shaft 29.
  • the motor 32 will drive the target plate 2 at a very low rate, for example at 2 revolutions per minute.
  • a carbon brush 38- is urged against the back of the plate 2 by a spring 39 and both are mounted in a hole in the stationary ring 31.
  • a sheet metal guard 40 covers the gear train.
  • Target plate 2 is threadedly engaged in the tubular shaft 29 and consequently may be removed without the necessity for disassembling any other members.
  • Multi-needle ion gun 3 is situated in proximity to the spinneret orifice 6 and the target plate 2. As shown in FIGURE 3 the ion gun is U-shaped and carries a number of needles 4 provided with a high voltage power supply to promote corona discharge between the needles 4 and the annular target plate 2.
  • the ion gun comprises a tubular conductive sheath 41 with numerous ports 42 along its length. At each end of the tubular material is a cylindrical sheathed resistor housing 43 made of electroconductive material. The entire structure is supported by support arms 44 which are composed of insulating material and are cemented to the sheath 41.
  • the lower portion of the U-shaped sheath 41 is fabricated from aluminum having an oval cross-section as shown in FIGURE 1.
  • each insulative insert Extending through the center of each insulative insert is acorona generating needle 4 which is connected to a separate insulated wire conductor. Each wire conductor is connected to a separate resistor located in resistor housing 43.
  • the needles 4 are adjusted, so that their sharp, conical ends are equidistant from the surface of the target plate 2 being spaced therefrom by about 0.62 inch (1.6 cm.).
  • the ion gun is oriented so that the points are aimed at an imaginary curve (a semi-circle) situated about 1.3 cm. from the edge 18 of the target plate.
  • the entire interior of the sheath 41 is filled with epoxy resin (Armstrong EC-OOl, R. Hardener) to retain the inserts and for other purposes described further below.
  • Each wire conductor is insulated along its length from the corona generating point to the resistor.
  • the wires pass upwardly through the legs of the tube 41 into the confines of one of the aluminum resistor housings 43 where each wire is joined to one terminal of its respective resistor, the resistance of these being substantially equal and being in the range of to 1000 megohrn.
  • the resistor housing 43 as shown in FIGURE 1, is provided with a threaded hole 51 to receive a jack for supplying high voltage direct current to the gun.
  • the conductive sheath is electrically connected to the power source and in addition each needle is connected through a resistor to this source.
  • the ion gun is supported and electrically insulated from the remaining parts of the apparatus by insulative support arms 44, Whlch are in turn attached to the ion gun by an epoxy cement.
  • Nonconductive bolts 46 are used to attach insulated support arms 44, to insulated rigid supports 45 as shown in FIGURE 1, the support 45 being shown partially cut away.
  • Supports 45 are in turn attached at the opposite ends through insulator 49 to housing 27 by means of bolts 48 shown at the right side of FIGURE 1 and also in FIGURE 2.
  • the annular target plate is grounded and the distance between the points and the target together with the voltage are adjusted to promote corona discharge, this being readily apparent from a glow in the dark.
  • the voltage betwen the power source at jack hole 51 and the grounded target electrodes is usually between 50 and 150 kilovolts.
  • the protective tubular shield on the ion gun has a beneficial eflect in extending the life of the ion gun.
  • the voltage drop from the bus bar in the resistor housing to the corona generation points is typically only 3 to 5 k110- volts.
  • the voltage drop between the tubular shield and the wires leading to the corona generating points is likewise only 3 to 5 kilovolts.
  • the ion gun 3 should have a small frontal area in a plane perpendicular to the axes of the needles 4.
  • the flat surface of the target electrode 2 should be aligned with the flat surface of the deflector 1 at its trailing edge 15".
  • the deflector 1 may, in an alternate embodiment, have a flat conical surface near its trailing edge 15 provided that the angle between the hub 11 and the disc 12 is between and degrees.
  • the surface of the target plate 2 should preferably be planar to provide the best alignment with the deflector.
  • the target electrode 2 should have a flattened conical shape.
  • the target electrode 2 may be oflset slightly, being slightly below the level of the strand deflector 1. This permits flow of the web over the deflector 1 onto the target electrode 2 without entanglement or pile up. Generally this offset is between 0.12 and 0.38 mm.
  • the trailing edge 18 0f the annular target electrode should be very thin, i.e., less than 5 mm. in thickness, and should permit streamlined fiow of gases within the spinning cell over the back side of the trailing edge as well as over the front side.
  • the target electrod has a faired edge (smoothly curved) which permits smooth flow of aspirated vapors along the motor casing to the backside of the annular electrode. Eddy currents at the trailing edge are thereby minimized.
  • the bearings for the annular electrode 2 are protected from the corrosive atmosphere by means of O-ring seals which may be made, for example, of neoprene.
  • the annular target plate 2 is continually cleaned at a point outside of the area of electrostatic influence.
  • a scraper as shown in FIGURES 4 and 5 may be used.
  • the target plate scraper comprises a sharp edge blade 52, of tungsten carbide, which is secured to a holder 53 which is pivotally mounted on a shoulder bolt 54; the latter engages an L-shaped member 55 having a rearward projecting lug which is suspended by a shoulder bolt 56 from an adjusting screw 57.
  • the screw 57 is supported by a cantilever arm 58 which is secured to plate 26 of the housing 27.
  • a fixed bracket 59 At the end of the cantilever arm 58 is a fixed bracket 59 the lower end of which carries a small spring 60 which urges the blade 52 edge against the face of the target plate 2 by pivoting the L-shaped member 55 about the axis of the shoulder bolt 56; consequently the blade edge always rests in contiguity with the face of the target plate 2.
  • the entire scraper assembly is surrounded by a housing 61, the interior of which collects debris; the housing 61 may be removed periodically for cleaning by removal of thumb screws 62.
  • the scraper embodiment shown in FIGURES 4 and 5 may be conveniently modified by connection of a vacuum tube or hose to a port in the collection box 61 so that the collected debris may be removed.
  • a vent may be provided to allow air to sweep through the box into the vacuum line.
  • tension for the scraper of FIG- URE 4 may be provided by means of pneumatic pressure supplied through a tube to a piston and cylinder which replace tension spring 60.
  • Tension on the scraper may be 7 adjusted remotely in this embodiment of the invention without opening the spinning chamber. This is accomplished simply by increasing or decreasing the pneumatic pressure.
  • a solution of about 14% linear polyethylene in trichlorofluoromethane is typically spun from a spinneret at the rate of approximately 16 kg./hour. It is intercepted immediately by a rotating contoured deflector preferably of trilobal design. The rotating deflector turns at the rate of 500 to 2000 revolutions per minute (25 to 100 strand oscillation cycles per second). The deflected stand passes then over the annular target plate. The annular target plate is rotated through the cleaning area with scraper at the rate of about 1 to 10 revolutions per minute. It is important to avoid excessive speed of the target electrode or of the rotating strand deflector since this may create an aerodynamic disturbance, which will upset the theadline.
  • the multiple needles of the ion gun should be aimed at a line upstream of the trailing edge of the target electrode so that the edge of the corona field is upstream of the trailing edge and secondary ionization from the edge is minimized.
  • the needles of the ion gun must be arranged in a semi-circle having a radius smaller than that of the trailing edge of the target plate.
  • the points should be in series with elements of high resistance, for example, in the range of 200 to 600 megohms.
  • a corona current at each needle from about to about 30 microamps is adequate; between and 20 microamps per needle is preferred for charging a plexifilamentary web.
  • the ion gun described herein provides a high impedance circuit to each point so that normal fluctuations in the effective dynamic resistance of corona discharge have little effect on emitted current. This is done by using a resistance of sufficient magnitude in series with each point to provide a voltage drop at least about 3,000 volts.
  • the effective dynamic resistance of corona discharge is about 60 megohms, whereas the resistance placed in series with each point to provide a corona current at each point of at least 5 microamps is typically 600 megohms and for 12 to 20 microamps is typically 270 megohms.
  • Use of the resistors makes the needle-to-needle current variations much less sensitive to such factors as point/target spacing.
  • corona generating points 4 The position of corona generating points 4 with reference to target plate 2 is important for efficient operation. It will be apparent that the clearance between the needle points 4 and plate 2 should be as small as efficient operation will permit. Generally a clearance of from about 1 cm. to about 2.5 cm. is satisfactory although this will vary with the design and capacity of the particular equipment.
  • the points 4 and the target electrode 2 should be reduced as the distance between the needle points 4 and the target electrode 2 is reduced, the total applied voltage across the resistor and the gap should be reduced to keep the current per point in the 5-30 microampere range.
  • the needle point-to-electrode distance is decreased, it is desirable to increase the number of points per inch in order to deposit a uniform charge on all parts of the web.
  • the voltage should be increased and/ or the number of points per cm. decreased. For optimum operation, the points should be equally spaced along the tubular shield.
  • FIGURES 1 and 2 The arrangement of the ion gun 3 opposite the annular target plate 2 is shown in FIGURES 1 and 2.
  • the rotary deflector 1 is shown at the center. Smooth operation of the equipment with uniform laydown generally occurs when the outside diameter of the target plate is 19 cm.
  • the diameter of the semi-circular ring of needles 4 in the ion gun is 16.5 cm.
  • Making the circle diameter for the needles smaller can cause pinning or clinging of the Web to the target plate. This results in bunching for an instant, an uneven discharge across the web width, and a falling free of the bunched web which contributes to sheet non-uniformity.
  • use of a small diameter circle as the locus of the needles 4 results in a very abrupt web charge curve, making the process more dificult to control.
  • the ion gun is aimed too near the outer edge of the target plate, secondary ionization will develop at the edge of the target plate generating ion of opposite polarity which will tend to discharge the web.
  • ion gun and target plate are shown in connection with flash spinning, the combination obviously is useful for a wide variety of purposes, such as for applying a charge to fibers in melt spinning, dry spinning, or in control of fluff or short staple fibers.
  • continuous spinning operations may be maintained in a closed cell with a much reduced frequency of shut-down. Because of t e continuous cleaning or the continuous provisions for new target electrode surface afforded by the present invention, atmospheric conditions within the cell may be controlled more effectively so as to promote more uniform charging.
  • the invention also has an important advantage in that no replaceable fibers, sheets, or discardable materials are used. The use of such materials, although very effective under certain circumstances, still requires interruption of the process from time to time. Changes in the quality of such materials greatly affect the charging efficiency. These problems are largely eliminated by the apparatus of this invention.
  • the ion gun 3, deflector 1, and target electrode 2 assembly are suspended through upper flat plate '50 welded to housing 27.
  • This assembly may be supported independently of spinneret 5.
  • spinneret 5 is part of a spinneret pack comprising an L-shaped solution supply tube and the gun-deflector-electrode assembly is supported through structure secured to the vertical arm of the spinneret pack.
  • This arrangement provides a modular unit which facilitates placement in and removal from the ceiling structure of a closedcell spinning chamber.
  • the g'un-defiector-electrode assembly may be rigidly mounted in a fixed position, or it may be mounted through intermediate structure providing for longitudinal, vertical, and/or transverse motion rela tive to the horizontal axis 7 of spinneret 5. An arrangement of the latter type is described and claimed in US. application of James G. Smith, Ser. No. 628,872, filed simultaneously herewith, the disclosure of which is hereby incorporated.
  • the deflected, charged web, as it leaves the target electrode 2 is deposited, along with similar webs from the other spinneret positions, in overlapping .multi-directional layers on an oppositely charged moving belt.
  • a suitable charged frame and belt laydown machine is described in US. application of J. E. Owens and S. P. Scheinberg, Ser. No. 628,870, filed simultaneously herewith. The entire disclosure of the Owens and Scheinberg application is also incorporated herein.
  • An apparatus for applying an electrostatic charge to fibrous material moving in a planar path comprising:
  • an ion gun located in proximity to the path and having a multiplicity of needles disposed across the width of the path and pointed toward the path, the points of the needles being located in a plane generally parallel to the planar path;
  • annular flat disc target electrode located on the pposite side of the path, extending across the width of the path, aligned in a plane parallel to the plane of the needle points, and positioned so that the needles of the ion gun are aimed at a portion of the electrode, whereby there is provided a corona discharge zone between that portion of the electrode and the needles when a direct current source of high voltage is applied to the needles;
  • a bearing for supporting the electrode for rotation in a plane generally parallel to the path whereby a clean portion of the electrode can be rotated into the corona discharge Zone.
  • An apparatus as defined in claim 1 which comprises, in addition, means located outside the corona discharge zone for cleaning the face of the electrode.
  • An apparatus as defined in claim 2 which comprises, in addition, means for collecting and removing debris cleaned from the electrode.
  • An apparatus as defined in claim 2 including means for continuously rotating the electrode.
  • the means for rotating the target electrode comprises a ring gear concentric with the target electrode and connected to and extending from the rear side of the target electrode, a pinion positioned to mesh with the ring gear and mounted on a shaft, and means for rotating the shaft.
  • An apparatus as defined in claim 11 wherein the means for cleaning the electrode is a scraper assembly comprising a scraper blade and means for urging the blade against the face of the electrode as it rotates.
  • An apparatus as defined in claim 10 which in cludes a separate circular, rotatable baflie and means for rotating the bafile, the bafile ha ing a diameter slightly less than the inside diameter of the target electrode, the baffle being concentric with the target electrode, the surface of the baffle at its periphery being aligned in the same plane as the surface of the target electrode, and the surface of the bathe being contoured to receive a fibrous strand moving in a generally horizontal direction and deflect it into a generally vertical plane downward toward a collecting surface, while simultaneously causing it to oscillate in the generally vertical plane.

Description

July 15, 1969 c. w. KILBY ET AL 3,456,156
APPARATUS FOR APPLYING AN ELECTROSTATIC CHARGE TO FIBROUS MATERIAL Filed April 6, 1967 4 Sheets-Sheet 1 July 15, 1969 c w, ET AL 3,456,156
APPARATUS FOR APPLYING AN ELECTROSTATlC CHARGE TO FIBROUS MATERIAL Filed April 6, 1967 4 Sheets-Sheet f3 July 15, 1969 K|LBY ET AL APPARATUS FOR APPLY [NG AN ELECTROSTATIC CHARGF TO FIBROUS MATERIAL Filed April 1967 4 Sheets-Sheet L- July 15, 1969 c. w. KILBY ET AL APPARATUS FOR APPLYING AN ELECTROSTATIC CHARGE TO FIBROUS MATERIAL Filed April 1967 4 Sheets-Sheet 4 United States Patent 3,456,156 APPARATUS FOR APPLYING AN ELECTROSTATIC CHARGE T0 FROUS MATERIAL Claude William Kilby, Chester, Va, and James Gerald Smith, Newark, DeL, assiguors to E. I. du Pont de Nemours and Company, Wilmington, Del, a corporation of Delaware Filed Apr. 6, 1967, Ser. No. 628,868 Int. 61. HllSf 3/06, 1 00 US. (ll. 317-4 14 Claims ABSTRACT OF THE DICLOSURE An apparatus for applying an electrostatic charge to fibrous material moving in a planar path. An annular disc target electrode is located on one side of the path and a multi-needle ion gun is positioned on the opposite side of the path. The needles of the ion gun are aimed at a portion of the target electrode to provide a corona discharge zone. The target electrode is rotatable so that that portion of its surface outside the corona discharge zone can be cleaned during operation.
Background of the invention This invention concerns an apparatus for applying an electrostatic charge to fibrous material moving in a planar path. It is more particularly concerned with an apparatus for applying a charge to a fibrous web, thereby preventing the web from collapsing and providing an electrostatic force to promote controlled deposit of the web on an oppositely charged moving belt or roll.
In U.S. Patent 3,081,519 to Blades and White a flashextrusion method is described for preparing fibrillated strands. These strands are composed of three-dimensional networks of extremely fine film-fibrils. The network struc ture is particularly useful in preparation of nonwoven fibrous sheets, these having been described in Steuber US. Patent 3,169,899. In further development of this technology an apparatus has been developed wherein the network passes from a curved baffle opposite the spinneret hole to the center of a rectangular flat target plate electrode. The network then is carried along the flat surface and leaves the electrode by passage over a straight trailing edge. The target plate is ,electrically grounded. A second electrode, termed an ion gun, which is a corona charging electrode, is used to deposit an electrostatic charge on the open network as it passes along the surface of the target plate. The charged network is then deposited on an oppositely charged belt or roll. In this process it has been found that residues of polymer, fibrils or other substances have tended to collect on the target plate surface principally by electrostatic precipitation. The residues cause a reduction in the charging efliciency with a resulting deterioration in the collected sheet. As a consequence, interruption of the process is required while the target is cleaned or replaced. This, of course, is a disadvantage resulting in costly loss of production time.
In U.S. application of Pollock and Smith Ser. No. 628,871, filed simultaneously herewith, there is described a new type of rotating web deflector which spreads a plexifilamentary strand into a web and causes the web to oscillate as it leaves the deflector by means of surface contours. This deflector is capable of oscillating the web through large angles. Consequently the straight-edge target plate is not completely satisfactory. In particular, the use of a straight-edge target plate requires that the strand traverse a much larger portion of the target plate when it is at its maximum point of oscillation.
Summary of the invention In accordance with this invention there is provided an apparatus for applying an electrostatic charge to fibrous material moving in a planar path. The apparatus comprises an ion gun and an annular flat disc target electrode. The ion gun is located in proximity to the path and has a multiplicity of needles, each connected to a source of high voltage, disposed across the width of the path and pointed toward the path, the points of the needles being located in a plane generally parallel to the path. On the opposite side of the path from the ion gun the target electrode is positioned so that its face is aligned in a plane generally parallel to the plane of the needle points and extends across the width of the path. The needles of the ion gun are aimed at a portion of the electrode so as to provide a corona discharge zone between that portion of the electrode and the needles. The apparatus further comprises a bearing for supporting the electrode for rotation in a plane generally parallel to the path. The electrode is rotatable so that a clean portion can be rotated into the corona discharge zone during operation.
Brief description of the drawings FIGURE 1 is a cross-sectional side view of the apparatus of the invention.
'FIGURE 2 is a front view, partly in cross-section, of the apparatus of the invention.
FIGURE 3 is a front view of a U-shaped, multi-needle ion gun suitable for use in the apparatus of this invention.
FIGURE 4 is a side view of a scraper for continuously cleaning a rotating target electrode.
FIGURE 5 is a front view of the scraper of FIG- URE 4.
Preferred embodiments In the preferred embodiment the target electrode is continuously rotatable and continuously cleaned during operation. The preferred cleaning means is a scraper assembly comprising a scraper blade and means for urging the blade against the face of the electrode as it rotates. The scraper assembly is surrounded by a housing connected to a vacuum line for collecting and removing debris cleaned from the electrode.
The needles of the ion gun are preferably disposed along the arc of a circle which is concentric with the target electrode. The diameter of the circle must, of course, be greater than the inside diameter but less than the outside diameter of the target electrode. Generally the needles will be disposed over approximately a semicircle and will be aimed at the lower portion of the target electrode. The scraper, or other means of cleaning the electrode, will then be located at the upper portion of the electrode.
The apparatus of the invention is especially designed for use in combination with a circular rotatable baffle and means for rotating the baffle. The baflle diameter is slightly less than the inside diameter of the target electrode. The baflle is positioned so that it is concentric with the target electrode and so that the surface of the baflle at its periphery is aligned in the same plane as the surface of the target electrode. The surface of the bailie is contoured to receive a fibrous strand moving in a generally horizontal direction on to deflect the strand into a generally vertical plane downward toward a collecting surface. At the same time the baffle spreads the strand into a flattened web and causes the web to oscillate in a generally vertical plane. As the web is deflected downward, it passes through the corona discharge zone between the ion gun and the target electrode. With the annular target electrode and with the ion gun needles arranged on the arc of a circle, the area of the discharge zone through which the web must pass is equal at all points of oscillation.
FIGURE 1 shows a preferred embodiment of the apparatus of the invention comprising a rotatable strand deflector 1, an annular, flat-surfaced target electrode 2, and a multi-needle ion gun 3. Deflector 1 and target plate 2 are also shown in the front view of the apparatus, FIGURE 2. Location of the needles 4 of ion gun 3 are also indicated in FIGURE 2. Ion gun 3 is shown in FIG. 3.
In FIGURE 1 there is also shown a spinneret nozzle 5 terminating in exit orifice 6. Axis 7 of orifice 6 is parallel to axis 8 of deflector 1. Both axes are horizontal. In operation of this embodiment, a polymer solution under high temperature and pressure is extruded through orifice 6. Immediately upon extrusion, the solvent evaporates and the polymer solidifies, forming what has come to be known as a plexifilamentary strand 9. This strand impinges upon the fillet portion 10 between hub portion 11 and disc portion 12 of deflector 1. The strand 9 approaches the deflector 1 in a direction substantially parallel to the axis 8. Deflector 1 diverts the strand downward through the area 13 between the needles 4 of ion gun 3 and target electrode 2. Expansion of the vaporized solvent against the hub of the rotating deflector causes the strand to be spread into a planar web 14 which increases in width as it passes through area 13, as indicated in FIGURE 2. It is in the area 13 that an electrostatic charge is applied to the fibrous web by corona discharge between needles 4 and target electrode 2. This electrostatic charge prevents the web 14 from collapsing and also aids in collecting and pinning the web on a surface, e.g. an oppositely charged moving belt, located below the spinning unit.
Spinneret nozzle 5 is preferably the horizontal arm of a spinneret pack comprising an L-shaped solution supply tube. The pack is adapted for mounting in the ceiling of a closed spinning cell above an oppositely charged surface. The spinneret pack is further described and claimed in US. application of James G. Smith Ser. No. 628,888, filed simultaneously herewith. For further details on the spinneret pack, reference should be made to the Smith application, the entire disclosure of which is hereby incorporated.
Considering FIGURE 2, the preferred deflector 1 is a one piece structure having a hub portion 11 and a flat disc portion 12, the disc portion having a circular trailing edge 15. Hub portion 11 and disc portion 12 are integrally connected by means of a fillet 10* having lobes 16. There should be one or more (preferably 2-4) lobes 16 in the fillet portion 10, the embodiment shown in FIGURES 1 and 2 having three. The presence of lobes 16 in fillet portion 10 cause the Web to oscillate from side to side (as viewed in FIGURE 2) as deflector 1 rotates. By proper design of the deflector web oscillation amplitudes as high as about :55 degrees can be obtained. The preferred deflector design is further described and claimed in US. application of 'Pollock and Smith, Ser. No. 628,871, filed simultaneously herewith. The entire disclosure of said application is hereby incorporated by reference.
As the network 14 leaves the circular trailing edge of the rotating strand deflector 1 it passes directly to the flat surface of the annular electrode 2. This surface should be in substantially the same plane as the top surface of disc portion 12 of deflector 1 or set back slightly therefrom. This permits the fibrous web to cross the circular trailing edge 15 of deflector 1 and over the circular leading edge 17 of target electrode 2 without gathering into clumps. The circles defining the edges (17 and 18) of target electrode 2 are concentric with the circle defining the trailing edge 15 of deflector 1. The web then passes across the surface of the flat target electrode 2. As it approaches the circular trailing edge 18 of target electrode 2 it passes through the corona discharge zone 13 between needles 4 of ion gun 3 and target electrode 2 where an electrostatic charge is placed on the web. The charged web leaves the trailing edge 18 of electrode 2 and is deposited in overlapping, multidirectional layers on a moving, oppositely charged, belt (not shown). It should be noted that in this circular type of target electrode the fibers are carried approximately the same distance across the surface regardless of orientation of the deflector at any particular moment. In older fiber target electrodes, particularly those having a straight trailing edge, the fiber at the end of the oscillation stroke had farther to travel than at the center of stroke and tended 'to lose momentum and to clump on the surface of the target electrode.
In the embodiment of FIGURES 1 and 2, a rim 1-9 of epoxy resin or other insulating material is provided on the circular trailing edge 18 of target electrode 2. The purpose of this rim is to avoid secondary ionization at -'the edge 18. In addition an inlaid ring 20 of epoxy material may be provided to reduce the amount of conducting material surface, thereby -reducing the amount of surface to be cleaned and providing a more uniformly concentrated field. The ring 20 is inset to provide a smooth transition of the fiber from the deflector 1 to the; conducting portion 21 of the surface of target electrode 2.
As shown in FIGURE 1, deflector 1 is mounted on an extension 22 of shaft 23 of motor 24 to provide for rotation thereof. Motor 24 is mounted on flange 25 which is in turn mounted on plate 26. Plate 26 is welded to housing 27. An 0 ring seal 28 is provided between flange 25 and plate 26 and seal members 28' are provided around shaft extension 22 to prevent entry of fluids to motor 24 or to the interior of housing 27.
The support means for annular target electrode 2 includes means for rotating the electrode during spinning so that a fresh surface may be presented as needed to the corona charging area 13. Electrode 2 rotates independently of and much slower than deflector 1. Thus when residues form on the target electrode 2 or when deposited there by electrostatic attraction, a fresh surface may be provided by rotation of the target electrode. The residues are thereby carried out of the charging area 13 and may be removed from the surface of electrode 2 by means which will be discussed hereinafter.
Referring to FIGURE 1, the target plate 2 is rotatably mounted on a tubular shaft 29 which is carried in ball bearings 30 which, in turn, are mounted inside the stationary ring 31. The ring 31 extends outwardly from the housing 27 and is being secured to the plate 26. Inside the housing 27 is a small slow-speed motor 32 which is secured to the plate 26; the motor body and the shaft are sealed in respect to the housing 27 in the same manner as themotor 24; the motor 32 carries a small pinion 33 which meshes with a gear 34 on stationary jackshaft 35. Secured to the gear 34 is a small pinion 36 which meshes with a large gear 37 secured to the rearward end of the tubular shaft 29. From this it will be seen that the motor 32 will drive the target plate 2 at a very low rate, for example at 2 revolutions per minute. To assure electrical grounding of the target plate 2, a carbon brush 38-is urged against the back of the plate 2 by a spring 39 and both are mounted in a hole in the stationary ring 31..A sheet metal guard 40 covers the gear train. Target plate 2 is threadedly engaged in the tubular shaft 29 and consequently may be removed without the necessity for disassembling any other members.
Multi-needle ion gun 3 is situated in proximity to the spinneret orifice 6 and the target plate 2. As shown in FIGURE 3 the ion gun is U-shaped and carries a number of needles 4 provided with a high voltage power supply to promote corona discharge between the needles 4 and the annular target plate 2. The ion gun comprises a tubular conductive sheath 41 with numerous ports 42 along its length. At each end of the tubular material is a cylindrical sheathed resistor housing 43 made of electroconductive material. The entire structure is supported by support arms 44 which are composed of insulating material and are cemented to the sheath 41.
The lower portion of the U-shaped sheath 41 is fabricated from aluminum having an oval cross-section as shown in FIGURE 1.
In the lower portion of the sheath 41, shown in FIG- URE 3, spaced from each other with a chordal distance of about 0.965 cm. (or 710 angular spacing), are holes 42 each occupied by an insulative tubular insert. Extending through the center of each insulative insert is acorona generating needle 4 which is connected to a separate insulated wire conductor. Each wire conductor is connected to a separate resistor located in resistor housing 43. The needles 4 are adjusted, so that their sharp, conical ends are equidistant from the surface of the target plate 2 being spaced therefrom by about 0.62 inch (1.6 cm.). The ion gun is oriented so that the points are aimed at an imaginary curve (a semi-circle) situated about 1.3 cm. from the edge 18 of the target plate. The entire interior of the sheath 41 is filled with epoxy resin (Armstrong EC-OOl, R. Hardener) to retain the inserts and for other purposes described further below.
Each wire conductor is insulated along its length from the corona generating point to the resistor. The wires pass upwardly through the legs of the tube 41 into the confines of one of the aluminum resistor housings 43 where each wire is joined to one terminal of its respective resistor, the resistance of these being substantially equal and being in the range of to 1000 megohrn. The resistor housing 43, as shown in FIGURE 1, is provided with a threaded hole 51 to receive a jack for supplying high voltage direct current to the gun. The conductive sheath is electrically connected to the power source and in addition each needle is connected through a resistor to this source.
Considering FIGURE 3, the ion gun is supported and electrically insulated from the remaining parts of the apparatus by insulative support arms 44, Whlch are in turn attached to the ion gun by an epoxy cement. Nonconductive bolts 46 are used to attach insulated support arms 44, to insulated rigid supports 45 as shown in FIGURE 1, the support 45 being shown partially cut away. Supports 45 are in turn attached at the opposite ends through insulator 49 to housing 27 by means of bolts 48 shown at the right side of FIGURE 1 and also in FIGURE 2.
In operation the annular target plate is grounded and the distance between the points and the target together with the voltage are adjusted to promote corona discharge, this being readily apparent from a glow in the dark. The voltage betwen the power source at jack hole 51 and the grounded target electrodes is usually between 50 and 150 kilovolts.
The protective tubular shield on the ion gun has a beneficial eflect in extending the life of the ion gun. The voltage drop from the bus bar in the resistor housing to the corona generation points is typically only 3 to 5 k110- volts. The voltage drop between the tubular shield and the wires leading to the corona generating points is likewise only 3 to 5 kilovolts.
The flow of solvent gases tends to aspirate additional gases over the tubular portion of the ion gun 3 on the side nearest the spinneret 5. It is to be noted that the inner surface of the ion gun 3 is conical and generally concentric with the conical surface of the spinneret housing Thus there is smooth flow of the atmospheric gases over the U-shaped ion gun 3 into the flow line provided by the solvent escaping from the orifice 6. In a similar manner, gas is aspirated along the bottom surface of the target assembly, and is carried toward and past the back surface of the thin outer epoxy-covered edge 19 of the annular target plate 2. Because of the aerodynamic design, turbulence is minimized and the formation of the low pressure area along the face of the target plate is maximized. This permits the web to ride close to the target electrode surface in a zone of high voltage gradient and maximum charging efliciency.
In general, to minimize resistance to gas flow, the ion gun 3 should have a small frontal area in a plane perpendicular to the axes of the needles 4.
In fabricating the apparatus of this invention the flat surface of the target electrode 2 should be aligned with the flat surface of the deflector 1 at its trailing edge 15". However, the deflector 1 may, in an alternate embodiment, have a flat conical surface near its trailing edge 15 provided that the angle between the hub 11 and the disc 12 is between and degrees. When this angle is 90 the surface of the target plate 2 should preferably be planar to provide the best alignment with the deflector. When the angle between the hub 11 and the trailing edge 15 of the deflector 1 is other than 90, the target electrode 2 should have a flattened conical shape.
It should also be noted at this point that the target electrode 2 may be oflset slightly, being slightly below the level of the strand deflector 1. This permits flow of the web over the deflector 1 onto the target electrode 2 without entanglement or pile up. Generally this offset is between 0.12 and 0.38 mm.
In construction of the annular target plate 2 certain aerodynamic principles should be observed. In particular, the trailing edge 18 0f the annular target electrode should be very thin, i.e., less than 5 mm. in thickness, and should permit streamlined fiow of gases within the spinning cell over the back side of the trailing edge as well as over the front side. In FIGURE 1 it will be noted that the target electrod has a faired edge (smoothly curved) which permits smooth flow of aspirated vapors along the motor casing to the backside of the annular electrode. Eddy currents at the trailing edge are thereby minimized.
The preferred ion gun for use in the apparatus of this invention is more fully described and claimed in the US. application of Rapp Wallace Crook III, Ser. No. 628,983, filed simultaneously herewith.
The bearings for the annular electrode 2 are protected from the corrosive atmosphere by means of O-ring seals which may be made, for example, of neoprene.
In a preferred form of the invention, the annular target plate 2 is continually cleaned at a point outside of the area of electrostatic influence. For example, a scraper as shown in FIGURES 4 and 5 may be used.
Referring to FIGURES 4 and 5, the target plate scraper comprises a sharp edge blade 52, of tungsten carbide, which is secured to a holder 53 which is pivotally mounted on a shoulder bolt 54; the latter engages an L-shaped member 55 having a rearward projecting lug which is suspended by a shoulder bolt 56 from an adjusting screw 57. The screw 57 is supported by a cantilever arm 58 which is secured to plate 26 of the housing 27. At the end of the cantilever arm 58 is a fixed bracket 59 the lower end of which carries a small spring 60 which urges the blade 52 edge against the face of the target plate 2 by pivoting the L-shaped member 55 about the axis of the shoulder bolt 56; consequently the blade edge always rests in contiguity with the face of the target plate 2. The entire scraper assembly is surrounded by a housing 61, the interior of which collects debris; the housing 61 may be removed periodically for cleaning by removal of thumb screws 62.
The scraper embodiment shown in FIGURES 4 and 5 may be conveniently modified by connection of a vacuum tube or hose to a port in the collection box 61 so that the collected debris may be removed. A vent may be provided to allow air to sweep through the box into the vacuum line.
In another variation tension for the scraper of FIG- URE 4 may be provided by means of pneumatic pressure supplied through a tube to a piston and cylinder which replace tension spring 60. Tension on the scraper may be 7 adjusted remotely in this embodiment of the invention without opening the spinning chamber. This is accomplished simply by increasing or decreasing the pneumatic pressure.
While the invention has been illustrated by using separate bafile and target electrode pieces, it is possible that a single piece may serve the same purpose. However, in developing a high-speed laydown process the requirements for oscillation of the baffie and for renewal of the target electrode are different, and it is preferred then to have two separately moving pieces. In a single piece bathe/target the ion gun should be aimed near the edge of the piece which, of course, should be well grounded.
In operation of the invention a solution of about 14% linear polyethylene in trichlorofluoromethane is typically spun from a spinneret at the rate of approximately 16 kg./hour. It is intercepted immediately by a rotating contoured deflector preferably of trilobal design. The rotating deflector turns at the rate of 500 to 2000 revolutions per minute (25 to 100 strand oscillation cycles per second). The deflected stand passes then over the annular target plate. The annular target plate is rotated through the cleaning area with scraper at the rate of about 1 to 10 revolutions per minute. It is important to avoid excessive speed of the target electrode or of the rotating strand deflector since this may create an aerodynamic disturbance, which will upset the theadline. The multiple needles of the ion gun should be aimed at a line upstream of the trailing edge of the target electrode so that the edge of the corona field is upstream of the trailing edge and secondary ionization from the edge is minimized. Obviously, the needles of the ion gun must be arranged in a semi-circle having a radius smaller than that of the trailing edge of the target plate. In order to promote uniform corona discharge from each of the multiple parallel points, the points should be in series with elements of high resistance, for example, in the range of 200 to 600 megohms.
In operation of the charging apparatus, a corona current at each needle from about to about 30 microamps is adequate; between and 20 microamps per needle is preferred for charging a plexifilamentary web. At these low currents of 5 to 30 microamperes per needle and in the absence of the resistors the effect of fluctuations in dynamic resistance between electrodes would be magnified. The ion gun described herein, however, provides a high impedance circuit to each point so that normal fluctuations in the effective dynamic resistance of corona discharge have little effect on emitted current. This is done by using a resistance of sufficient magnitude in series with each point to provide a voltage drop at least about 3,000 volts. In a typical ion gun target configuration the effective dynamic resistance of corona discharge is about 60 megohms, whereas the resistance placed in series with each point to provide a corona current at each point of at least 5 microamps is typically 600 megohms and for 12 to 20 microamps is typically 270 megohms. Use of the resistors makes the needle-to-needle current variations much less sensitive to such factors as point/target spacing.
The position of corona generating points 4 with reference to target plate 2 is important for efficient operation. It will be apparent that the clearance between the needle points 4 and plate 2 should be as small as efficient operation will permit. Generally a clearance of from about 1 cm. to about 2.5 cm. is satisfactory although this will vary with the design and capacity of the particular equipment.
It should be noted that as the distance between the needle points 4 and the target electrode 2 is reduced, the total applied voltage across the resistor and the gap should be reduced to keep the current per point in the 5-30 microampere range. In addition, as the needle point-to-electrode distance is decreased, it is desirable to increase the number of points per inch in order to deposit a uniform charge on all parts of the web. On the other hand, when increasing the distance between the needle points and the target electrode the voltage should be increased and/ or the number of points per cm. decreased. For optimum operation, the points should be equally spaced along the tubular shield. It has been found convenient in developing dimensions for the ion gun and target plate to create a carbon black deposit on target plate 2 by spraying powdered carbon black into the operating area between the plate and the gun. An oval pattern is outlined by carbon deposits opposite each needle indicating the area of electrostatic influence of each needle under the particular conditions employed. The patterns laid down by single points are centered approximately the same distance apart as the needles. The shape and size of the oval varies depending on needle-to-target spacing. The arrangement of the ion gun 3 opposite the annular target plate 2 is shown in FIGURES 1 and 2. The rotary deflector 1 is shown at the center. Smooth operation of the equipment with uniform laydown generally occurs when the outside diameter of the target plate is 19 cm. and the diameter of the semi-circular ring of needles 4 in the ion gun is 16.5 cm. Making the circle diameter for the needles smaller can cause pinning or clinging of the Web to the target plate. This results in bunching for an instant, an uneven discharge across the web width, and a falling free of the bunched web which contributes to sheet non-uniformity. In addition, use of a small diameter circle as the locus of the needles 4 results in a very abrupt web charge curve, making the process more dificult to control. On the other hand, if the ion gun is aimed too near the outer edge of the target plate, secondary ionization will develop at the edge of the target plate generating ion of opposite polarity which will tend to discharge the web.
While the ion gun and target plate are shown in connection with flash spinning, the combination obviously is useful for a wide variety of purposes, such as for applying a charge to fibers in melt spinning, dry spinning, or in control of fluff or short staple fibers.
-By use of the apparatus of the invention continuous spinning operations may be maintained in a closed cell with a much reduced frequency of shut-down. Because of t e continuous cleaning or the continuous provisions for new target electrode surface afforded by the present invention, atmospheric conditions within the cell may be controlled more effectively so as to promote more uniform charging. The invention also has an important advantage in that no replaceable fibers, sheets, or discardable materials are used. The use of such materials, although very effective under certain circumstances, still requires interruption of the process from time to time. Changes in the quality of such materials greatly affect the charging efficiency. These problems are largely eliminated by the apparatus of this invention.
The ion gun 3, deflector 1, and target electrode 2 assembly are suspended through upper flat plate '50 welded to housing 27. This assembly may be supported independently of spinneret 5. In the preferred embodiment however spinneret 5 is part of a spinneret pack comprising an L-shaped solution supply tube and the gun-deflector-electrode assembly is supported through structure secured to the vertical arm of the spinneret pack. This arrangement provides a modular unit which facilitates placement in and removal from the ceiling structure of a closedcell spinning chamber. The g'un-defiector-electrode assembly may be rigidly mounted in a fixed position, or it may be mounted through intermediate structure providing for longitudinal, vertical, and/or transverse motion rela tive to the horizontal axis 7 of spinneret 5. An arrangement of the latter type is described and claimed in US. application of James G. Smith, Ser. No. 628,872, filed simultaneously herewith, the disclosure of which is hereby incorporated.
As stated above, the deflected, charged web, as it leaves the target electrode 2 is deposited, along with similar webs from the other spinneret positions, in overlapping .multi-directional layers on an oppositely charged moving belt. A suitable charged frame and belt laydown machine is described in US. application of J. E. Owens and S. P. Scheinberg, Ser. No. 628,870, filed simultaneously herewith. The entire disclosure of the Owens and Scheinberg application is also incorporated herein.
We claim:
1. An apparatus for applying an electrostatic charge to fibrous material moving in a planar path, said apparatus comprising:
an ion gun located in proximity to the path and having a multiplicity of needles disposed across the width of the path and pointed toward the path, the points of the needles being located in a plane generally parallel to the planar path;
an annular flat disc target electrode located on the pposite side of the path, extending across the width of the path, aligned in a plane parallel to the plane of the needle points, and positioned so that the needles of the ion gun are aimed at a portion of the electrode, whereby there is provided a corona discharge zone between that portion of the electrode and the needles when a direct current source of high voltage is applied to the needles;
a bearing for supporting the electrode for rotation in a plane generally parallel to the path whereby a clean portion of the electrode can be rotated into the corona discharge Zone.
2. An apparatus as defined in claim 1 which comprises, in addition, means located outside the corona discharge zone for cleaning the face of the electrode.
3. An apparatus as defined in claim 2 which comprises, in addition, means for collecting and removing debris cleaned from the electrode.
4. An apparatus as defined in claim 2 including means for continuously rotating the electrode.
5. An apparatus as defined in claim 2 wherein the means for cleaning the electrode is a scraper assembly comprising ascraper blade and means for urging the blade against the face of the electrode as it rotates.
6. An apparatus as defined in claim wherein a remotely operated pneumatic system urges the blade against the face of the electrode.
7. An apparatus as defined in claim 3 wherein the means for collecting and removing the debris comprises a housing around the scraper assembly and a vacuum line connected to the housing.
8. An apparatus as defined in claim 4 wherein the means for rotating the target electrode comprises a ring gear concentric with the target electrode and connected to and extending from the rear side of the target electrode, a pinion positioned to mesh with the ring gear and mounted on a shaft, and means for rotating the shaft.
9. An apparatus as defined in claim 8 wherein the target electrode threadedly engages a concentric tubular shaft extending from the rear side of the target electrode, the tubular shaft being integral with the ring gear.
10. An apparatus as defined in claim 1 wherein the needles of the ion gun are disposed along an arc of a circle, the circle being concentric with the target electrode and having a diameter greater than the inside diameter and less than the outside diameter of the target electrode.
11. An apparatus as defined in claim 10 wherein the arc is an approximate semi-circle, the needles are aimed at the lower portion of the target electrode, and the means for cleaning the electrode is located at the upper portion or the electrode.
12. An apparatus as defined in claim 11 wherein the means for cleaning the electrode is a scraper assembly comprising a scraper blade and means for urging the blade against the face of the electrode as it rotates.
13. An apparatus as defined in claim 10 which in cludes a separate circular, rotatable baflie and means for rotating the bafile, the bafile ha ing a diameter slightly less than the inside diameter of the target electrode, the baffle being concentric with the target electrode, the surface of the baffle at its periphery being aligned in the same plane as the surface of the target electrode, and the surface of the bathe being contoured to receive a fibrous strand moving in a generally horizontal direction and deflect it into a generally vertical plane downward toward a collecting surface, while simultaneously causing it to oscillate in the generally vertical plane.
14. An apparatus as defined in claim 1 wherein a rim of insulating material is provided on the outer edge of the annular disc electrode.
References Cited UNITED STATES PATENTS 3,387,326 6/1968 Hollberg l88 JOHN F. COUCH, Primary Examiner D. HARNISH, Assistant Examiner US. Cl. X.R.
US628868A 1967-04-06 1967-04-06 Apparatus for applying an electrostatic charge to fibrous material Expired - Lifetime US3456156A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3578739A (en) * 1969-05-13 1971-05-18 Du Pont Apparatus for applying electrostatic charge to fibrous structure
US3860369A (en) * 1972-11-02 1975-01-14 Du Pont Apparatus for making non-woven fibrous sheet
US4215682A (en) * 1978-02-06 1980-08-05 Minnesota Mining And Manufacturing Company Melt-blown fibrous electrets
US5200620A (en) * 1991-11-05 1993-04-06 The United States Of America As Represented By The Secretary Of The Navy Electrostatic fiber spreader including a corona discharge device
US5601853A (en) * 1994-07-29 1997-02-11 E. I. Du Pont De Nemours And Company Electrically conductive ceramics and their use in fiber charging apparatus
US5643524A (en) * 1994-12-30 1997-07-01 E. I. Du Pont De Nemours And Company Corona charging of flash spun plexifilamentary film-fibril webs in poor charging environments
US6049956A (en) * 1999-06-18 2000-04-18 Adherent Technologies, Inc. Method and apparatus for spreading fiber bundles
US20050087287A1 (en) * 2003-10-27 2005-04-28 Lennon Eric E. Method and apparatus for the production of nonwoven web materials
US20070101564A1 (en) * 2005-11-04 2007-05-10 Karl Mayer Malimo Textilmaschinenfabrik Gmbh Device and method for spreading a carbon fiber hank

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3387326A (en) * 1964-06-04 1968-06-11 Du Pont Apparatus for charging and spreading a web

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3387326A (en) * 1964-06-04 1968-06-11 Du Pont Apparatus for charging and spreading a web

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3578739A (en) * 1969-05-13 1971-05-18 Du Pont Apparatus for applying electrostatic charge to fibrous structure
US3860369A (en) * 1972-11-02 1975-01-14 Du Pont Apparatus for making non-woven fibrous sheet
US4215682A (en) * 1978-02-06 1980-08-05 Minnesota Mining And Manufacturing Company Melt-blown fibrous electrets
US5200620A (en) * 1991-11-05 1993-04-06 The United States Of America As Represented By The Secretary Of The Navy Electrostatic fiber spreader including a corona discharge device
US5601853A (en) * 1994-07-29 1997-02-11 E. I. Du Pont De Nemours And Company Electrically conductive ceramics and their use in fiber charging apparatus
US5656203A (en) * 1994-07-29 1997-08-12 E. I. Du Pont De Nemours And Company Electrically conductive ceramics with oxides of Al, Cr, and Mg
US5643524A (en) * 1994-12-30 1997-07-01 E. I. Du Pont De Nemours And Company Corona charging of flash spun plexifilamentary film-fibril webs in poor charging environments
US6049956A (en) * 1999-06-18 2000-04-18 Adherent Technologies, Inc. Method and apparatus for spreading fiber bundles
US20050087287A1 (en) * 2003-10-27 2005-04-28 Lennon Eric E. Method and apparatus for the production of nonwoven web materials
US8333918B2 (en) 2003-10-27 2012-12-18 Kimberly-Clark Worldwide, Inc. Method for the production of nonwoven web materials
US20070101564A1 (en) * 2005-11-04 2007-05-10 Karl Mayer Malimo Textilmaschinenfabrik Gmbh Device and method for spreading a carbon fiber hank
US7536761B2 (en) * 2005-11-04 2009-05-26 Karl Mayer Malimo Textilmaschinenfabrik Gmbh Device and method for spreading a carbon fiber hank

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