US3445650A - Double focussing mass spectrometer including a wedge-shaped magnetic sector field - Google Patents
Double focussing mass spectrometer including a wedge-shaped magnetic sector field Download PDFInfo
- Publication number
- US3445650A US3445650A US494378A US3445650DA US3445650A US 3445650 A US3445650 A US 3445650A US 494378 A US494378 A US 494378A US 3445650D A US3445650D A US 3445650DA US 3445650 A US3445650 A US 3445650A
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- field
- wedge
- plane
- ions
- lens
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/26—Mass spectrometers or separator tubes
- H01J49/28—Static spectrometers
- H01J49/30—Static spectrometers using magnetic analysers, e.g. Dempster spectrometer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
- H01J29/46—Arrangements of electrodes and associated parts for generating or controlling the ray or beam, e.g. electron-optical arrangement
- H01J29/58—Arrangements for focusing or reflecting ray or beam
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement, ion-optical arrangement
- H01J37/05—Electron or ion-optical arrangements for separating electrons or ions according to their energy or mass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/252—Tubes for spot-analysing by electron or ion beams; Microanalysers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/252—Tubes for spot-analysing by electron or ion beams; Microanalysers
- H01J37/256—Tubes for spot-analysing by electron or ion beams; Microanalysers using scanning beams
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/02—Details
- H01J49/022—Circuit arrangements, e.g. for generating deviation currents or voltages ; Components associated with high voltage supply
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/02—Details
- H01J49/10—Ion sources; Ion guns
- H01J49/14—Ion sources; Ion guns using particle bombardment, e.g. ionisation chambers
- H01J49/142—Ion sources; Ion guns using particle bombardment, e.g. ionisation chambers using a solid target which is not previously vapourised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/02—Details
- H01J49/20—Magnetic deflection
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/26—Mass spectrometers or separator tubes
- H01J49/28—Static spectrometers
- H01J49/284—Static spectrometers using electrostatic and magnetic sectors with simple focusing, e.g. with parallel fields such as Aston spectrometer
- H01J49/286—Static spectrometers using electrostatic and magnetic sectors with simple focusing, e.g. with parallel fields such as Aston spectrometer with energy analysis, e.g. Castaing filter
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/26—Mass spectrometers or separator tubes
- H01J49/28—Static spectrometers
- H01J49/32—Static spectrometers using double focusing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/26—Mass spectrometers or separator tubes
- H01J49/28—Static spectrometers
- H01J49/32—Static spectrometers using double focusing
- H01J49/322—Static spectrometers using double focusing with a magnetic sector of 90 degrees, e.g. Mattauch-Herzog type
Definitions
- a mass spectrometer including a wedge-shaped, 90, magnetic sector lens in tandem with a 45, spherical, electrical condenser lens.
- This invention relates to a novel mass spectrometer of the double focussing type, and, more particularly, to a novel mass spectrometer including magnetic and electric focussing elements that complement each other to produce a stigmatic image of a particulate source.
- Mass spectrometers are widely used for chemical analysis and isotope separation. They frequently consist of two focussing elements, or lenses, an electric lens and a mag netic lens, in tandem.
- the electric lens disperses particles in accordance with their respective energies, and concentrates particles having energies within a given range, or band into a predetermined region.
- the magnetic lens disperses the particles in accordance with their momenta, which under the usual conditions correspond to their masses.
- either lens may be first traversed by the charged particles under analysis.
- the principal object of the present invention is to improve the art of mass spectrometry by providing a novel mass spectrometer having good resolution, and stigmatic imaging characteristics, together with a relatively large acceptance angle, large aperture and relatively high transmission factor, and therefore capable of a greater sensitivity than heretofore achievable with comparable resolving power.
- FIGURE 1 is a schematic plan view of the magnetic sector field lens of the mass spectrometer of the invention
- FIGURE 2 is a cross-sectional view, taken along the line 22 of FIGURE 1;
- FIGURE 3 is a view generally similar to the view of FIGURE 1, but showing the effect of momentum dispersion
- FIGURE 4 is a partly schematic, thin horizontal sectional view of a spectrometer according to a presently preferred embodiment of the invention.
- FIGURE 5 is a rear elevational view of the spectrometer shown in FIGURE 4.
- FIGURE 6 is an end elevational view of the spectrometer shown in FIGURES 4 and 5.
- the invention contemplates the combination of a wedge-shaped magnetic field having an arcuate main Patented May 20, 1969 ICC axis extending through about in combination with a spherically curved electric condenser lens, the main axis of which extends through about 45. It has been found that this combination is particularly advantageous, not only in its performance characteristics, but also in that it is relatively simple and inexpensive to manufacture.
- the spectrometer of the present invention includes a magnetic sector field of wedge shape, of the general type described by I. S. OConnell in the Review of Scientific Instruments, volume 32 (1961),
- the present field arrangement is novel, however, in that its dimensions are so chosen that it has a stigmatic focal point and no second order angular image aberration.
- the field is defined by the faces 10 and 12, respectively, of a pair of pole pieces 14 and 16, which may be energized by any desired means (not shown) preferably by an electromagnet, so that its strength may be easily varied.
- the pole faces 10 and 12 may be thought of as rectangular in shape, and as being inclined relative to each other with their upper and lower edges parallel and lying in common respective planes normal to the plane of symmetry of the wedge.
- the principal coordinate axis of the system is defined as the line 20 of intersection of the planes in which the pole faces 10 and 12, respectively, lie. In a practical instrument, the angle between the pole faces 10 and 12 would be about 10 to 20 depending upon the amount of power available for energizing the field.
- the field lines, indicated at 22 are in the form of circularly curved arcs centered on thecoordinate axis 20. Because of this configuration, the field focusses ions passing through it not only in the radial direction, i.e., in the plane of FIG- URE 1, but also in the axial direction, i.e., in the plane of FIGURE 2.
- the field strength decreases proportionately to the distance from the coordinate axis 20, and may be expressed:
- An important feature of the invention pertains to the relative dimensions of the field, which may be most simply described with reference to FIGS. 1 and 2, and with reference to ions of a selected momentum that enter the field through its narrow edge 29 along paths within a solid angle, 0, centered about a selected normal 23 to the lower edge 29 and about equal in magnitude to the wedge angle of the field.
- the ions are assumed to come from a point source 24 located on the selected normal 23.
- the pole faces 10 and 12 need not be rectangular, but are preferably curved to conform generally to the curvature of the ion paths in order to minimize the mass of the pole pieces and the power required for producing the magnetic field. They extend radially slightly beyond the limits of the ion paths in order to avoid the effects of fringe fields.
- the magnetic sector lens acts as a momentum dispersing element, and is combined in tandem with an electric lens, which acts as an energy dispersing element.
- an electric lens acts as an energy dispersing element.
- a momentum dispersion factor may be calculated for it which is applicable for ions of any selected mass.
- the calculation shows that to match this dispersion factor, the sector angle of the spherical condenser should be 44.
- the sector angle of the spherical condenser may be 45, and exact energy focussing obtained by adjusting the mean potential of the spherical condenser field.
- FIGURES 4, 5 and 6 illustrate the basic geometry of the mass spectrometer of the invention including the 90 magnetic sector field 40, and the 45 electric spherical condenser 42.
- the sequence of fields may be passed by the ion beam in either direction.
- the ions are moving from right to left, as viewed in FIGURES 4 and 5, from a source 41 defined by an apertured entrance diaphragm 43, passing through the electric lens 42 first and then through the magnetic lens 40 to an image point 44 defined by an apertured exit diaphragm 46.
- a narrow bundle of ions from the source 41 is selected by the apertured collimating diaphragm 48 for admission into the spherical condenser 42.
- the spherical condenser 42 disperses the ions in accordance with their energies. Ions having energies within a selected limited range pass through the selector diaphragm 50, which is placed between the electric and magnetic fields 42 and 40, respectively.
- the magnetic sector lens 40 then disperses the ions in accordance with their momenta, or masses, and those ions having the selected momentum are stigmatically focussed at the image point 44.
- momentum dispersion is carried out first, and the selector diaphragm 50 acts as a momentum selector rather than an energy selector.
- the spectrometer of the invention produces a stigmatic image subject only to relatively small image aberrations, it may be designed with a larger angular aperture than previous mass spectrometers of the same resolving power. This provides improved sensitivity, because a greater proportion may be used of the ions coming from the source than in instruments heretofore available.
- Manufacture of the spectrometer is also relatively simple and inexpensive. No complicated surfaces need be produced.
- the surfaces for forming the magnetic field are planes, and those for forming the electric field are spherical. It is not only easy to make elements of these simple shapes, it is also much easier to assemble them and adjust their positions relative to each other than to assemble and adjust elements of more complicated or irregular shapes such as have heretofore been proposed.
- a further advantage of the spectrometer of the invention is that both the source and the image are located well away from the dispersing fields, thus avoiding shielding problems such as might otherwise be encountered when using a field sensitive device at the image or at the source, for example, an electron multiplier at the image point.
- Mass resolving power Adjustable from to 10,000. Mass range Up to mass 1,000 at 1.5 kv. ion energy.
- the entrance aperture 48, the selector aperture 50, and the exit aperture 46 are preferably all adjustable in size to permit adjustment to the optimum operating condiitons for ions of various diiferent energies and momenta, and of various different concentrations at the source 41.
- the apertures will be adjusted together to maximize the mass resolving power to the limit set by the sensitivity desired.
- the mass spectrometer of the invention is included in a microanalyzer described and claimed in my copending patent application filed concurrently herewith, Ser. No. 494,388, entitled Ion Microprobe, wherein it is shown in combination with an embodiment of an invention described and claimed in another copending application field concurrently herewith, Ser. No. 494,490, entitled, Lens System for Particulate Radiation.
- a magnetic sector lens for deflecting moving charged particles comprising means for producing a wedge-shaped magnetic field characterized by curved field lines that pass normally through the plane of symmetry of the wedge, said field having planar entrance and exit boundaries, one of said boundaries being parallel to the planes of curvature of the field lines, the other one of said boundaries lying along the narrow edge of the wedge and being normal to said one boundary and to the plane f symmetry, means for directing ions into a field produced by said producing means through one of said boundaries generally normally thereto, and means for utilizing ions emerging from the field through the other one of said boundaries generally normally thereto, said field being arranged to deflect ions having a selected momentum from said directing means along trochoidal paths between said boundaries, said paths being grouped about a median path that passes normally through both of said boundaries.
- a magnetic sector lens for deflecting electrically charged particles comprising means for producing a wedge-shaped magnetic field characterized by curved field lines that pass normally through the plane of symmetry of the wedge, the line of intersection of the planes of the major faces of the wedge being defined as the coordinate axis of the lens, said field having a first boundary plane normal to said coordinate axis, and a second boundary plane lying along the narrow edge of the wedge and normal both to said first boundary plane and to the plane of symmetry, said field being substantially uniform throughout a predetermined area of said second boundary plane centered at a distance from said first boundary plane equal to about 1.347 times the distance between said second boundary plane and said coordinate axis, the strength of said field varying substantially uniformly ininverse proportion to distance from said coordinate axis throughout a predetermined area of said first boundary plane cencentered at a distance from said second boundary plane equal to about 1.10 times the direction between said second boundary plane and said coordinate axis, means for directing ions into a fiield produced by said producing means through one of said predetermined areas of
- a magnetic sector lens for deflecting electrically charged particles comprising a pair of pole pieces each having a planar face, means mounting said pole pieces with said planar faces confronting each other and defining a wedge-shaped space symmetrical about a plane midway between them, said planar faces having straight edges in each of two planes that are normal to each other and normal to said plane of symmetry, one of said planes of said straight edges lying along the narrow edge of the wedge-shaped space, means defining a median particle path in said plane of symmetry extending normally through said one plane of said straight edges and spaced from the other plane of said straight edges a distance equal to about 1.347 times the distance between said one plane and the line of intersecton of the planes of said planar faces, said pole faces extending in said other plane of said straight edges on both sides of a point space from said one plane 1.1 times the distance from said one plane to said line of intersection, whereby when said pole pieces are energized to establish a magnetic field between them, charged particles directed into the field with a predetermined momentum along said median
- a magnetic sector lens for deflecting charged particles comprising a pair of pole pieces having a planar face, means mounting said pole pieces with said planar faces confronting each other and defining a wedge-shaped space symmetrical about a plane midway between them, said planar faces having straight edges in each of two planes that are normal to each other and normal to said plane of symmetry, one of said planes of said straight edges lying along the narrow edge of the wedge-shaped space, means defining an aperture confronting the trapezoidal face of said wedge-shaped space bounded by two of said straight edges, said aperture being centered a distance from said one plane of said straight edges equal to about 1.10 times the distance from said one plane to the line of intersection of the planes of said planar faces, said straight edges in said one plane extending on both sides of a point spaced from the plane of said trapezoidal face a distance equal to about 1.347 times the distance from said one plane to said line of intersection, whereby when said pole pieces are energized to produce a magnetic field between them and ions are injected through
- a mass spectrometer comprising means for producing a wedge-shaped magnetic field characterized by curved field lines that pass normally through the plane of symmetry of the wedge, said field having a planar entrance and exit boundaries, one of said boundaries being parallel to the planes of curvature of the field lines, the other one of said boundaries lying along the narrow edge of the wedge and being normal to said one boundary and to the plane of symmetry, said field being arranged to deflect ions having a selected momentum along trochoidal paths between said boundaries, said paths being grouped about a median path that passes normally through both of said boundaries, and a spherically curved, toroidal condenser having a planar boundary confronting and aligned with the boundary of said magnetic field that is parallel to the planes of the magnetic field lines, said condenser having a sector angle of about 45, means for directing ions into one of said magnetic lens and said condenser for passage through and deflection by both of them in sequence and means for detecting ions after passage through said magnetic lens and said conden
- a mass spectrometer comprising means for producing a wedge-shaped magnetic field characterized by curved field lines that pass normally through the plane of symmetry of the wedge, said field having planar entrance and exit boundaries, one or said boundaries being parallel to the planes of curvature of the field lines, the other one of said boundaries lying along the narrow edge of the wedge and being normal to said one boundary and to the plane of symmetry, said field being arranged to deflect ions having a selected momentum along trochoidal paths between said boundaries, said paths being grouped about a median path that passes normally through both of said boundaries, and a spherically curved, toroidal condenser having a planar boundary confronting and parallel to the boundary of said magnetic field that is parallel to the planes of the magnetic field lines, said condenser having a sector angle of 45, and means defining an aperture between said magnetic field means and said condenser for restricting the passage of ions between said field and said condenser, means for directing ions into one of said magnetic lens and said condenser
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- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Electron Tubes For Measurement (AREA)
- Analysing Materials By The Use Of Radiation (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
Description
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US49449065A | 1965-10-11 | 1965-10-11 | |
US49438865A | 1965-10-11 | 1965-10-11 | |
US49437865A | 1965-10-11 | 1965-10-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3445650A true US3445650A (en) | 1969-05-20 |
Family
ID=27413976
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US494378A Expired - Lifetime US3445650A (en) | 1965-10-11 | 1965-10-11 | Double focussing mass spectrometer including a wedge-shaped magnetic sector field |
US494388A Expired - Lifetime US3517191A (en) | 1965-10-11 | 1965-10-11 | Scanning ion microscope with magnetic sector lens to purify the primary ion beam |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US494388A Expired - Lifetime US3517191A (en) | 1965-10-11 | 1965-10-11 | Scanning ion microscope with magnetic sector lens to purify the primary ion beam |
Country Status (4)
Country | Link |
---|---|
US (2) | US3445650A (en) |
DE (3) | DE1798021B2 (en) |
FR (1) | FR1508152A (en) |
GB (1) | GB1145107A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3610921A (en) * | 1968-05-01 | 1971-10-05 | Perkin Elmer Corp | Metastable mass analysis |
US3761707A (en) * | 1970-06-26 | 1973-09-25 | Max Planck Gesellschaft | Stigmatically imaging double focusing mass spectrometer |
US3842269A (en) * | 1971-10-05 | 1974-10-15 | Max Planck Gesellschaft | Mass spectrometer of high detection efficiency |
US4843239A (en) * | 1987-05-18 | 1989-06-27 | Max-Planck-Gesellschaft Zur Foerderung Der Wisserschaften E.V. | Compact double focussing mass spectrometer |
US4847504A (en) * | 1983-08-15 | 1989-07-11 | Applied Materials, Inc. | Apparatus and methods for ion implantation |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4833903B1 (en) * | 1969-04-08 | 1973-10-17 | ||
JPS5034439B1 (en) * | 1969-05-16 | 1975-11-08 | ||
JPS5036397B1 (en) * | 1969-07-11 | 1975-11-25 | ||
DE1937482C3 (en) * | 1969-07-23 | 1974-10-10 | Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften E.V., 3400 Goettingen | Microbeam probe |
BE758925A (en) * | 1969-11-14 | 1971-04-16 | Bayer Ag | METHOD FOR THE ANALYSIS OF SOLID BODY SURFACES BY MASS SPECTROMETRY |
FR2087652A5 (en) * | 1970-05-27 | 1971-12-31 | Onera (Off Nat Aerospatiale) | |
US3659236A (en) * | 1970-08-05 | 1972-04-25 | Us Air Force | Inhomogeneity variable magnetic field magnet |
US3930155A (en) * | 1973-01-19 | 1975-12-30 | Hitachi Ltd | Ion microprobe analyser |
US4100409A (en) * | 1973-02-02 | 1978-07-11 | U.S. Phillips Corporation | Device for analyzing a surface layer by means of ion scattering |
JPS5015594A (en) * | 1973-06-08 | 1975-02-19 | ||
US3878392A (en) * | 1973-12-17 | 1975-04-15 | Etec Corp | Specimen analysis with ion and electrom beams |
US3916191A (en) * | 1974-03-01 | 1975-10-28 | Minnesota Mining & Mfg | Imaging apparatus and method for use with ion scattering spectrometer |
US4107527A (en) * | 1977-07-13 | 1978-08-15 | Valentin Tikhonovich Cherepin | Ion-emission microanalyzer microscope |
AT353519B (en) * | 1978-03-07 | 1979-11-26 | Oesterr Studien Atomenergie | DEVICE FOR CONCENTRATING THE PRIMAERION BEAM |
JPS5917500B2 (en) * | 1981-03-18 | 1984-04-21 | 株式会社東芝 | Neutral particle detection device |
DE3403254A1 (en) * | 1984-01-31 | 1985-08-01 | Siemens AG, 1000 Berlin und 8000 München | METHOD AND DEVICE FOR COMPENSATING CHARGES IN SECONDARY ISSUE MASS SPECTROMETRY (SIMS) ELECTRICALLY BAD CONDUCTING SAMPLES |
FR2575597B1 (en) * | 1984-12-28 | 1987-03-20 | Onera (Off Nat Aerospatiale) | APPARATUS FOR VERY HIGH RESOLUTION ION MICROANALYSIS OF A SOLID SAMPLE |
GB8703012D0 (en) * | 1987-02-10 | 1987-03-18 | Vg Instr Group | Secondary ion mass spectrometer |
NL8701871A (en) * | 1987-08-10 | 1989-03-01 | Philips Nv | LOADED PARTICLE DEVICE WITH BUNDLE MIXER. |
FR2624610B1 (en) * | 1987-12-11 | 1990-03-30 | Cameca | TIME-OF-FLIGHT, CONTINUOUSLY SCAN ANALYSIS METHOD AND ANALYSIS DEVICE FOR CARRYING OUT SAID METHOD |
US4800273A (en) * | 1988-01-07 | 1989-01-24 | Phillips Bradway F | Secondary ion mass spectrometer |
GB8812940D0 (en) * | 1988-06-01 | 1988-07-06 | Vg Instr Group | Mass spectrometer |
US5220167A (en) * | 1991-09-27 | 1993-06-15 | Carnegie Institution Of Washington | Multiple ion multiplier detector for use in a mass spectrometer |
GB2269934B (en) * | 1992-08-19 | 1996-03-27 | Toshiba Cambridge Res Center | Spectrometer |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2947868A (en) * | 1959-07-27 | 1960-08-02 | Geophysics Corp Of America | Mass spectrometer |
US3061720A (en) * | 1960-02-29 | 1962-10-30 | Ewald Heinz | Spectrograph |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3103584A (en) * | 1963-09-10 | Electron microanalyzer system | ||
US2772363A (en) * | 1952-03-21 | 1956-11-27 | Cons Electrodynamics Corp | Method and apparatus for ionization of solids |
FR1352167A (en) * | 1962-11-28 | 1964-02-14 | Ct Nat De La Rech Scient Et Cs | New device for microanalysis by secondary ionic emission |
-
1965
- 1965-10-11 US US494378A patent/US3445650A/en not_active Expired - Lifetime
- 1965-10-11 US US494388A patent/US3517191A/en not_active Expired - Lifetime
-
1966
- 1966-10-04 GB GB44183/66A patent/GB1145107A/en not_active Expired
- 1966-10-11 FR FR79474A patent/FR1508152A/en not_active Expired
- 1966-10-11 DE DE19661798021 patent/DE1798021B2/en active Pending
- 1966-10-11 DE DE1539660A patent/DE1539660C3/en not_active Expired
- 1966-10-11 DE DE1966A0053727 patent/DE1539659B2/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2947868A (en) * | 1959-07-27 | 1960-08-02 | Geophysics Corp Of America | Mass spectrometer |
US3061720A (en) * | 1960-02-29 | 1962-10-30 | Ewald Heinz | Spectrograph |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3610921A (en) * | 1968-05-01 | 1971-10-05 | Perkin Elmer Corp | Metastable mass analysis |
US3761707A (en) * | 1970-06-26 | 1973-09-25 | Max Planck Gesellschaft | Stigmatically imaging double focusing mass spectrometer |
US3842269A (en) * | 1971-10-05 | 1974-10-15 | Max Planck Gesellschaft | Mass spectrometer of high detection efficiency |
US4847504A (en) * | 1983-08-15 | 1989-07-11 | Applied Materials, Inc. | Apparatus and methods for ion implantation |
US4843239A (en) * | 1987-05-18 | 1989-06-27 | Max-Planck-Gesellschaft Zur Foerderung Der Wisserschaften E.V. | Compact double focussing mass spectrometer |
Also Published As
Publication number | Publication date |
---|---|
DE1539660C3 (en) | 1978-06-01 |
US3517191A (en) | 1970-06-23 |
DE1798021B2 (en) | 1977-10-20 |
DE1539659A1 (en) | 1969-12-18 |
DE1539660B2 (en) | 1977-09-22 |
DE1539659B2 (en) | 1977-07-07 |
GB1145107A (en) | 1969-03-12 |
DE1798021A1 (en) | 1971-08-26 |
FR1508152A (en) | 1968-01-05 |
DE1539660A1 (en) | 1970-04-09 |
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