US3429707A - Photographic sensitive materials containing morpholino alkylalkenoylamide polymers - Google Patents
Photographic sensitive materials containing morpholino alkylalkenoylamide polymers Download PDFInfo
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- US3429707A US3429707A US492667A US3429707DA US3429707A US 3429707 A US3429707 A US 3429707A US 492667 A US492667 A US 492667A US 3429707D A US3429707D A US 3429707DA US 3429707 A US3429707 A US 3429707A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
- C07D295/125—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/13—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
- G03C1/053—Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Definitions
- the present invention relates to a gelatino silver halide photographic sensitive material containing a morpholino alkylalkenoylamide polymer and/or a copolymer containing a morpholino alkylalkenoylamide.
- an object of this invention is to provide a photographic silver halide emulsion having improved sensitivity, maximum density, and contrast.
- the inventors have found that by incorporating a polymer of morpholino alkylalkenoylamide and/ or a copolymer containing morpholino alkylalkenoylamide in a photographic gelatino silver halide emulsion that has been sensitized into the most suitable sensitivity with a usual chemical sensitizer, such as, unstable sulfur com pounds, reducing agents, and gold compounds, the sensitivity of the emulsion is further increased. Moreover, as shown in curve (C) in the accompanying drawing it has been confirmed that in this case, not only the covering power, contrast, and maximum density but also the sensitivity at the lower end portion of the characteristic curve is largely increased, and hence this is a very profitable sensitizing process in practice.
- a usual chemical sensitizer such as, unstable sulfur com pounds, reducing agents, and gold compounds
- the morpholino alkylalkenoylamide copolymer is shown by the following general formula I H C ⁇ /CH2 wherein R represents H or CH X represents a positive integer; and n is 1, 2, or 3, and the copolymer containing 3,429,101 Patented Feb. 25, 1969 morpholino alkylalkenoylamide is shown by the following general formula wherein R and R each represents H or CH x and y are positive integres, n is l, 2, or 3, and Z represents I ZHNHz, 600C113 GOOCH:
- poly-Nlmorpholino methylacrylamide may be produced by polymerizing N-morpholino methylacrylamide obtained by the reaction of acrylamide, Formalin, and morpholi-ne.
- the copolymer of morpholino methylacrylamide may be obtained by polymerizing a mixture of N-morpholino methylacrylamide and vinyl acetate, methyl acrylate, acrylamide, vinyl pyrrolidone, or acryloylmorpholine. In this case, however, it is de sirable that more than 30 mole percent of N-morpholino methylacrylamide is present in the copolymer.
- the intrinsic viscosity of the polymer or the copolymer in N,N-dimethylformamide is [1 152.0 (35 C.).
- the amount of the polymer or the copolymer to be incorporated in an emulsion in this invention may be selected desirably but the most suitable amount of it for increasing the sensitivity, gamma, and maximum density is influenced by the type of photographic silver halide emulsion and purposes. In general, it is suitable that the amount of the polymer of morpholino alkylalkenoylamide and/or the copolymer containing morpholino alkylalker oylamide is 340% by weight, in particular, 620% by weight of the whole mediums in the photographic gelatino silved halide emulsion.
- the polymer of morpholino alkylalkenoylamide and/or the copolymer of morpholino alkylalkenoylamide may be incorporated in a layer adjacent the photographic silver halide emulsion layer in an amount of 10-40% by weight.
- the polymer or the copolymer may be added in any step in the emulsion but it is suitable to add after the secondary ripening and before applying the emulsion on a support.
- the polymer or the copolymer may be added as powders but it profitably added as a 1020% aqueous solution of it. At that, since a hydrolysis is liable to occur if the pH of the aqueous solution is higher than 7, it is preferable to adjust the pH to 4 6.
- the present invention can be applied to any types of silver halide emulsions, e.g., to a silver-iodide-bromide emulsion and to a silver-chloride-bromide emulsion.
- the photographic silver halide emulsion used in this invention may be one that has been subjected to a sulfur sensitization and/or a gold sensitization and may contain a light sensitizer, a polyalkyleneoxide sensitizer, various stabilizers, a hardening agent, coating aids, and couplers.
- a support or base for the photographic material of this invention usual supports for photographic emulsions may be used, such as, a glass plate, a triacetylcellulose film base, a polyethylene terephthalate film base, polycarbonate film base, polystyrene film base, polypropylene film base, a baryta paper, and the like.
- Synthesis 2 Into 400 m1. of a 20% aqueous isopropyl alcohol solution was dissolved 100 g. of the N-morpholino methylacrylamide in Synthesis 1, and the solution was added with 0.5 g. L-ascorbic acid and 0.6 ml. of a 30% aqueous hydrogen peroxide solution and maintained for hours at 40 C. in a nitrogen stream. The product was dialyzed for 1 day using a cellophane diaphragm and dried by freezing to give 80 g. of a water-soluble polymer of N- rnorpholino methylacrylamide having the intrinsic viscosity of 0.2
- Synthesis 4 Into 76 ml. of dimethyl formamide was dissolved 24 g. of the N-morpholino ethylacrylamide in Synthesis 3, the solution was then added with 0.05 g. of azobisiobutyronitrile and stirred for 4 hours at 70 C. in a nitrogen stream. Dimethylformamide was concentrated and the product was dissolved in water, dialyzed, and dried by freezing to give 11 g. of poly-N-morpholino ethylacrylamide.
- Synthesis 6 A solution of 30 g. of morpholino propylacrylamide in 100 ml. of dimethylformamide was added with 0.03 g. of azobisisobutyronitrile and the system was polymerized for 8 hours at 70 C. in a nitrogen stream. After the polymerization, the greater part of dimethylformamide was removed by a reduced-pressure distillation and then the product was dissolved into water and dialized using a cellophane diaphragm. By drying thus obtained product by freezing, 20 g. of polymorpholino propylacrylamide was obtained. The intrinsic viscosity of the product in dimethylformamide at 35 C. was 0.125.
- Synthesis 7 A solution of g. of methylacrylamide in 200 ml. of Water was added with 1 g. of hydroquinone and 120 ml. of 30% Formalin. Into the solution was added dropwise 87 g. of morpholine with stirring while increasing the temperature of the system to 5060 C. Thereafter, the system was stirred for another 3 hours at 70 C. to finish the reaction. The product was filtered and, after distilling off water under reduced pressure, was subjected to a vacuum distillation to give N-morpholino methylmethacrylamide (B.P. l34138 C./0.5 mm. Hg). After recrystallizing from benzene, the melting point of the product was 8284 C.
- Synthesis 8 Into 70 ml. of water was dissolved 30 g. of the N- morpholino methylmethacrylamide obtained in Example 7, and the solution was stirred for 4 hours in a nitrogen stream at 70 C. with the addition of 0.09 g. of potassium peroxide. The product was dialized and dried by freezing to give 11 g. of a water-solution polymer having the intrinsic viscosity of 0.47.
- Synthesis 9 Into 300 ml. of 30% isopropyl alcohol were dissolved 71 g. of N-morpholino methylacrylamide and 29 g. of acrylamide and the system was stirred for 4 hours at 40 C, in a nitrogen stream while adding 0.5 g. of L- ascorbic acid and 6 ml. of an aqueous 30% hydrogen peroxide solution. The solution was dialized for 1 day using a cellophane diaphragm and dried by freezing to give 65 g. of water-soluble polymer having the intrinsic viscosity of 0.2.
- Synthesis 1O Into 300 ml. of an aqueous 30% isopropyl alcohol solution were dissolved 90 g. of N-morpholino methylacrylamide and 10 g. of acrylamide and the solution was stirred for 4 hours at 40 C. in a nitrogen stream while adding 0.5 g. of L-ascorbic acid and 6 ml. of an aqueous 30% hydrogen peroxide solution. The solution was dialized for 1 day using a cellophane diaphragm and dried by freezing to give 76 g. of a water-soluble polymer having the intrinsic viscosity of 0.26.
- Synthesis 11 Into 300 ml. of an aqueous 30% isopropyl alcohol solution were dissolved 51 g. of N-morpholino methylacrylamide and 49 g. of acrylamide and the solution was stirred for 4 hours at 40 C. in a nitrogen stream while adding 0.5 g. of L-ascorbic acid and 6 ml. of an aqueous 30% hydrogen peroxide solution. The solution was dialized for 1 day using a cellophane diaphragm and dried by freezing to give 57 g. of a water-soluble polymer having the intrinsic viscosity of 0.5.
- Synthesis 12 Into 300 m1. of water were dissolved 85 g. of N- Inorpholino methylacrylamide and 56 g. of vinylpyrrolidone and the solution was stirred for 4 hours at 40 C. in a nitrogen stream while adding 0.75 g. of L-ascorbic acid and 3 ml. of an aqueous 30% hydrogen peroxide solution. The solution was then dialized for 1 day using a cellophane diaphragm and dried by freezing to give 118 g. of a water-soluble polymer having the intrinsic viscosity of 0.65.
- Synthesis 13 Into 300 ml. of an aqueous 25% isopropyl alcohol solution were dissolved 54 g. of N-morpholino methylacrylamide and 54 g. of acryloylmorpholine and the solution was stirred for 6 hours at 40 C. in a nitrogen stream while adding 1.5 g. of L-ascorbic acid and 5.3 ml. of an aqueous 30% hydrogen peroxide solution. Thus obtained product was dialized for 1 day using a cellophane diaphragm and dried by freezing to give 60 g. of watersoluble polymer having the intrinsic viscosity of 0.1.
- EXAMPLE 1 A photographic gelatino silver halide emulsion for highsensitive negative photographic materials containing 1.8 mol of silver halides consisting of 5.0 mol of silver iodide and 95.0 mol of silver bromide 250 g. of gelatin, that has been ripened with a sulfur sensitizer and a gold sensitizer into the most suitable sensitivity was divided into three equal parts, and each part of them was added with g. of each of the following materials.
- each emulsion was added with a sensitizing dye, a stabilizer, a coating aid, and a hardening agent in equal proportion and then coated on a triacetylcellulose film base in a same film thickness, followed by drying.
- the coated film was exposed at 1/20 of second in a sensitometer of 5400 K. in intensity scale and developed for 150 minutes at C. in a developing solution of the composition:
- the gamma and the sensitivity of the photographic emulsion were increased by the addition of poly-N-morpholino methylacrylamide. Furthermore, while the addition of polyvinylpyrrolidone does not increase the intensity at the lower end portion of the characteristic curve, the sensitivity of that portion can be increased by the addition of poly-N-morpholino methylacrylamide.
- EXAMPLE 2 A photographic gelatino silver halide emulsion for high-sensitive negative photographic materials containing 3.0 mol of silver halides consisting of 5 .0 mol percent of silver iodide and 95.0 mol percent of silver bromide and 1050 g. of gelatin and had been ripened into the most suitable sensitivity with a sulfur sensitizer and a gold sen sitizer was divided into 10 equal parts. Each part of them was added with 50 ml. of an aqueous 10% solution of each of the following materials:
- Each emulsion was endowed with panchromatic property by adding a sensitizing dye and then added with 20 ml. of an aqueous 1% solution of 4-hydroxy-6-methyl- 1,3,3a,7-tetra-azaindene as a stabilizer, 1.5 m1. of an aqueous 10% solution of chrome alum as a hardening agent, and 1.5 ml. of an aqueous 4% solution of saponin as a coating aid.
- the emulsion was coated on a triacetylcellulose film base in a same thickness and dried.
- Thus obtained photographic sensitive film was exposed at 1/20 of second in a sensitometer of 5400 K. in intensity scale and developed for 7 minutes at 20 C. in the solution of the following composition:
- the emulsion was coated upon a subbed polyethylene terephthalate film base in a same thickness each and then dried.
- EXAMPLE 4 A solution of 26 g. of potassium chloride, 7 g. of potassium bromide, and 8 g. of gelatin in 230 ml. of water was maintained at 55 C. Into the above solution was added an aqueous solution of 50 g. of silver nitrate in 920 ml. of water with stirring at 55 C. Then, after adding 100 g. of gelatin, the system was further stirred for minutes, solidified by cooling with ice, divided into fine parts, and rinsed with water until the conductivity of the emulsion became 1,500 micro mho/cm.
- the emulsion was dissolved again while heating, and, after adding 24 g. of sensitizing gelatin and 80 g. of inactive gelatin, heated to 55 C. for 100 minutes.
- Into thus obtained emulsion was dissolved g. of poly-N- morpholino methyl acrylamide, and the solution was added with 40 ml. of a 0.05% methyl alcohol solution of 3 aryl 3' ethyl 5 (2 (1 ethyl 4 quinolinidene) ethylidene) 5', 6' dimethyl 4 oxothiazolinooxycyanine iodide and 300 ml.
- the cyan coupling color photographic emulsion layer showed a high coupling density by a same exposure as compared with an emulsion layer prepared by using the same materials and by the same procedures but using an equivalent amount of inactive gelatin instead of the poly-N-morpholino methylacrylamide.
- EXAMPLE 5 The photographic emulsion in Example 1 was coated in a thickness of about 10 microns upon a triacetylcellulose film base and the film was divided into two parts. One of them was further coated with an aqueous soluti-on (I) of 13 g. of gelatin and 8 g. of poly-N-morpholino methylacrylamide in 1 liter of water in a thickness of about 2 microns and another film was coated with an aqueous solution -(II) of g. of gelatin in 1 liter of water in a thickness of about 2 microns, and they were dried.
- I aqueous soluti-on
- a photographic sensitive material comprising a support and a silver halide photographic emulsion layer, said emulsion layer containing at least one additive sewherein R represents a member selected from the group consisting of H and CH x is a positive integer; and n is '1, 2, or 3 and a copolymer shown by the general formula r r ⁇ / B2 -CHzC 0112- wherein R and R each represents a member selected from the group consisting of H and CH x and y are positive integers; n is l, 2, or 3; and Z represents a member selected from the group consisting of I I l OONHZ, 000cm, 0000113, H20
- the photographic sensitive material according to claim 1 whertin said polymer is selected from poly-N- morpholino methylacrylamide and poly-N-morpholino methylmethacrylamide.
- copolymer is selected from N-morpholino methylacrylamide-acrylamide copolymer, N-morpholino methylacrylamide-vinyl acetate copolymer, N- morpholino methylacrylamide-methylacrylate copolymer, N- morpholino methylacrylamidevinylpyrrolidone copolymer, and' 'N-morpholino methylacrylamide-acryloyl morpholinecopolymer.
- said emulsion layer contains said additive in an amount of 33-40% by weight, based on the whole mediums in said emulsion.
- n 1, 2, or 3 and a copolymer shown by the general formula wherein R and R each represents a member selected from the group consisting of H and CH x and y are 10 positive integers; n is 1, 2, or 3; and Z represents a member selected from the group consisting of I I I CONHZ, OCOCHZ, COOCH;
- copolymer is selected from N-morpholino methylacrylamide-acrylamide copolymer, N-morpholino methylacrylamide-vinyl acetate copolymer, N- morpholino methylacrylamide-methylacrylate copolymer, N-morpholino methylacrylamide-vinylpyrrolidone copolymer, and N-morpholino methylacrylamide-acryloyl morpholine copolymer.
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Description
1969 YOSUKE NAKAJIMA ETAL 9,
PHOTOGHAPHIC SENSITIVE MATERIALS CONTAINING MORPHOLINO I ALKYLALKENOYLAMIDE POLYMERS Filed Oct. 4. 1965 Z 2 E O! i ll-l U 5 U i 2 E O Log(EXPOSURE) INVENTORS YOSUKE NAKAJIMA DAIJIRO NISHIO BY SYU WATARAI THEIR A RNEYS United States Patent 39/ 56,599 U.S. Cl. 9685 Claims Int. Cl. G03c 1/86, 1/04 The present invention relates to a gelatino silver halide photographic sensitive material containing a morpholino alkylalkenoylamide polymer and/or a copolymer containing a morpholino alkylalkenoylamide.
It has hitherto been known that in the production of light-sensitive silver halide photographic emulsions, by adding into the photographic emulsion a natural or synthetic high molecular compound other than gelatin, such as, poly-Nwinyl lactams, dextrin, laminarin, manan, hydroxy ethylated celluloses, and the like, the covering power of said emulsion, that is, a value of the optical density divided by the gram number of developed silver per one square decimeter is increased and hence the contrast and the maximum density can be increased. (Cf.: U.S. Patent 3,058,826; French Patent 1,261,846; Belgian Patent 611,622; Belgian Patent 611,623; and U.S. Patent 3,003,878.)
However, as clear from the curves shown in the accompanying drawing, the sensitivity near the lower end of curve (B) showing the characteristic curve of a photographic emulsion containing the above-mentioned high molecular compound is substantially same as that of curve (A) showing the characteristic curve of a photographic emulsion containing no such a high molecular compound.
Therefore, an object of this invention is to provide a photographic silver halide emulsion having improved sensitivity, maximum density, and contrast.
The inventors have found that by incorporating a polymer of morpholino alkylalkenoylamide and/ or a copolymer containing morpholino alkylalkenoylamide in a photographic gelatino silver halide emulsion that has been sensitized into the most suitable sensitivity with a usual chemical sensitizer, such as, unstable sulfur com pounds, reducing agents, and gold compounds, the sensitivity of the emulsion is further increased. Moreover, as shown in curve (C) in the accompanying drawing it has been confirmed that in this case, not only the covering power, contrast, and maximum density but also the sensitivity at the lower end portion of the characteristic curve is largely increased, and hence this is a very profitable sensitizing process in practice.
The morpholino alkylalkenoylamide copolymer is shown by the following general formula I H C\ /CH2 wherein R represents H or CH X represents a positive integer; and n is 1, 2, or 3, and the copolymer containing 3,429,101 Patented Feb. 25, 1969 morpholino alkylalkenoylamide is shown by the following general formula wherein R and R each represents H or CH x and y are positive integres, n is l, 2, or 3, and Z represents I ZHNHz, 600C113 GOOCH:
For producing such polymers or copolymers, for example, poly-Nlmorpholino methylacrylamide may be produced by polymerizing N-morpholino methylacrylamide obtained by the reaction of acrylamide, Formalin, and morpholi-ne. Further, the copolymer of morpholino methylacrylamide may be obtained by polymerizing a mixture of N-morpholino methylacrylamide and vinyl acetate, methyl acrylate, acrylamide, vinyl pyrrolidone, or acryloylmorpholine. In this case, however, it is de sirable that more than 30 mole percent of N-morpholino methylacrylamide is present in the copolymer. Since the compatibility of the polymer or copolymer with gelatin is lowered if the polymerization degree is too high, it is desirable that the intrinsic viscosity of the polymer or the copolymer in N,N-dimethylformamide [is [1 152.0 (35 C.).
The amount of the polymer or the copolymer to be incorporated in an emulsion in this invention may be selected desirably but the most suitable amount of it for increasing the sensitivity, gamma, and maximum density is influenced by the type of photographic silver halide emulsion and purposes. In general, it is suitable that the amount of the polymer of morpholino alkylalkenoylamide and/or the copolymer containing morpholino alkylalker oylamide is 340% by weight, in particular, 620% by weight of the whole mediums in the photographic gelatino silved halide emulsion. Furthermore, in the present invention, instead of adding directly into the photographic gelatino silver halide emulsion layer, the polymer of morpholino alkylalkenoylamide and/or the copolymer of morpholino alkylalkenoylamide may be incorporated in a layer adjacent the photographic silver halide emulsion layer in an amount of 10-40% by weight.
The polymer or the copolymer may be added in any step in the emulsion but it is suitable to add after the secondary ripening and before applying the emulsion on a support. The polymer or the copolymer may be added as powders but it profitably added as a 1020% aqueous solution of it. At that, since a hydrolysis is liable to occur if the pH of the aqueous solution is higher than 7, it is preferable to adjust the pH to 4 6.
The present invention can be applied to any types of silver halide emulsions, e.g., to a silver-iodide-bromide emulsion and to a silver-chloride-bromide emulsion. The photographic silver halide emulsion used in this invention may be one that has been subjected to a sulfur sensitization and/or a gold sensitization and may contain a light sensitizer, a polyalkyleneoxide sensitizer, various stabilizers, a hardening agent, coating aids, and couplers.
As a support or base for the photographic material of this invention, usual supports for photographic emulsions may be used, such as, a glass plate, a triacetylcellulose film base, a polyethylene terephthalate film base, polycarbonate film base, polystyrene film base, polypropylene film base, a baryta paper, and the like.
The invention will be explained more in detail referring to the following examples for synthesizing the polymer or the copolymer of morpholino alkylalkenoylamide and preferred examples of this invention but it should be understood that the invention is not limited to them.
Synthesis '1 An aqueous solution of 71 g. of acrylamide in 200 ml. of water was added with 1 g. of hydroquinone and then 120 m1. of 30% Formalin. While stirring the solution, -87 g. of morpholine was slowly added dropwise into the solution and after finishing the addition and then increasing the temperature of the system to 70 C., stirring was further continued for 3 hours to finish the reaction. The product was filtered and, after distilling off water from the product under a reduced pressure, distilled in vacuo to give N-morpholino methylacrylamide (B.P. l36138 C./0.6 mm. Hg). The melting point of the product after recrystallizing from benzene was 92-93 C.
Elementary analysis as C H O N Calculated: C, 56.45%; H, 8.29%; and N, 16.46%. Found: C, 56.57%; H, 8.04%; and N, 16.62%.
Synthesis 2 Into 400 m1. of a 20% aqueous isopropyl alcohol solution was dissolved 100 g. of the N-morpholino methylacrylamide in Synthesis 1, and the solution was added with 0.5 g. L-ascorbic acid and 0.6 ml. of a 30% aqueous hydrogen peroxide solution and maintained for hours at 40 C. in a nitrogen stream. The product was dialyzed for 1 day using a cellophane diaphragm and dried by freezing to give 80 g. of a water-soluble polymer of N- rnorpholino methylacrylamide having the intrinsic viscosity of 0.2
Synthesis 3 In 600 ml. of absolute ethyl alcohol were mixed 129 g. of ethyleneimine, 500 g. of morpholine, and 3 g. of concentrated sulfuric acid and the mixture was refluxed for 12 hours. After distilling off ethyl alcohol and excess morpholine under reduced pressure, the system was subjected to a vacuum distillation to give 200 g. of morpholino ethylamine at a boiling point of 6973 C./5 mm. Hg.
Into 500 ml. of toluene was added 90.5 g. of acryloylchloride and a mixture of 130 g. of the morpholino ethylarnine obtained in the above procedure and 1011 g. of triethylamine was added dropwise into thus prepared solution while stirring under ice-cooling. After filtering oif thus precipitated triethylamine hydrochloride, the product was added with a small amount of hydroquinone to distil off the toluene and then subjected to a vacuum distillation to give the crystal of N-morpholino ethylacrylamide having the melting point of 160 C. at a boiling point of 13l140 C./0.06 mm. Hg.
Elementary analysis as C H N O Calculated: N, 15.22%. Found: N, 15.25%.
Synthesis 4 Into 76 ml. of dimethyl formamide was dissolved 24 g. of the N-morpholino ethylacrylamide in Synthesis 3, the solution was then added with 0.05 g. of azobisiobutyronitrile and stirred for 4 hours at 70 C. in a nitrogen stream. Dimethylformamide was concentrated and the product was dissolved in water, dialyzed, and dried by freezing to give 11 g. of poly-N-morpholino ethylacrylamide.
Synthesis 5 While stirring under cooling by a cooling medium, a mixture of 91 g. (1 mol) of acryloyl chloride and 300 ml. of toluene was added dropwise a mixture of 144 g. (1 mol) of N-aminopropylmorpholine and 101 g. (1 mol) of triethylamine at temperatures lower than 10 C. After stirring the system for 3 hours at room temperature, thus formed triethylamine hydrochloride was filtered, and the product was dried by granular sodium hydroxide and, after distilling oli the toluene, subjected to a vacuum distillation in a nitrogen stream with the addition of a small amount of hydroquinone to give 73 g. of N-morpholino propylacrylamide (B.P. 149152 C./0.05 mm. Hg) (yield 37% Elementary analysis as C H N O Calculated: N, 14.13%. Found N, 14.08%.
Synthesis 6 A solution of 30 g. of morpholino propylacrylamide in 100 ml. of dimethylformamide was added with 0.03 g. of azobisisobutyronitrile and the system was polymerized for 8 hours at 70 C. in a nitrogen stream. After the polymerization, the greater part of dimethylformamide was removed by a reduced-pressure distillation and then the product was dissolved into water and dialized using a cellophane diaphragm. By drying thus obtained product by freezing, 20 g. of polymorpholino propylacrylamide was obtained. The intrinsic viscosity of the product in dimethylformamide at 35 C. was 0.125.
Synthesis 7 A solution of g. of methylacrylamide in 200 ml. of Water was added with 1 g. of hydroquinone and 120 ml. of 30% Formalin. Into the solution was added dropwise 87 g. of morpholine with stirring while increasing the temperature of the system to 5060 C. Thereafter, the system was stirred for another 3 hours at 70 C. to finish the reaction. The product was filtered and, after distilling off water under reduced pressure, was subjected to a vacuum distillation to give N-morpholino methylmethacrylamide (B.P. l34138 C./0.5 mm. Hg). After recrystallizing from benzene, the melting point of the product was 8284 C.
Elementary analysis as C H O N Calculated: C, 58.67%; H, 8.75%; N,15.21%. Found: C, 59.35%; H, 8.72%; N, 15.19%.
Synthesis 8 Into 70 ml. of water was dissolved 30 g. of the N- morpholino methylmethacrylamide obtained in Example 7, and the solution was stirred for 4 hours in a nitrogen stream at 70 C. with the addition of 0.09 g. of potassium peroxide. The product was dialized and dried by freezing to give 11 g. of a water-solution polymer having the intrinsic viscosity of 0.47.
Synthesis 9 Into 300 ml. of 30% isopropyl alcohol were dissolved 71 g. of N-morpholino methylacrylamide and 29 g. of acrylamide and the system was stirred for 4 hours at 40 C, in a nitrogen stream while adding 0.5 g. of L- ascorbic acid and 6 ml. of an aqueous 30% hydrogen peroxide solution. The solution was dialized for 1 day using a cellophane diaphragm and dried by freezing to give 65 g. of water-soluble polymer having the intrinsic viscosity of 0.2.
Synthesis 1O Into 300 ml. of an aqueous 30% isopropyl alcohol solution were dissolved 90 g. of N-morpholino methylacrylamide and 10 g. of acrylamide and the solution was stirred for 4 hours at 40 C. in a nitrogen stream while adding 0.5 g. of L-ascorbic acid and 6 ml. of an aqueous 30% hydrogen peroxide solution. The solution was dialized for 1 day using a cellophane diaphragm and dried by freezing to give 76 g. of a water-soluble polymer having the intrinsic viscosity of 0.26.
Synthesis 11 Into 300 ml. of an aqueous 30% isopropyl alcohol solution were dissolved 51 g. of N-morpholino methylacrylamide and 49 g. of acrylamide and the solution was stirred for 4 hours at 40 C. in a nitrogen stream while adding 0.5 g. of L-ascorbic acid and 6 ml. of an aqueous 30% hydrogen peroxide solution. The solution was dialized for 1 day using a cellophane diaphragm and dried by freezing to give 57 g. of a water-soluble polymer having the intrinsic viscosity of 0.5.
Synthesis 12 Into 300 m1. of water were dissolved 85 g. of N- Inorpholino methylacrylamide and 56 g. of vinylpyrrolidone and the solution was stirred for 4 hours at 40 C. in a nitrogen stream while adding 0.75 g. of L-ascorbic acid and 3 ml. of an aqueous 30% hydrogen peroxide solution. The solution was then dialized for 1 day using a cellophane diaphragm and dried by freezing to give 118 g. of a water-soluble polymer having the intrinsic viscosity of 0.65.
Synthesis 13 Into 300 ml. of an aqueous 25% isopropyl alcohol solution were dissolved 54 g. of N-morpholino methylacrylamide and 54 g. of acryloylmorpholine and the solution was stirred for 6 hours at 40 C. in a nitrogen stream while adding 1.5 g. of L-ascorbic acid and 5.3 ml. of an aqueous 30% hydrogen peroxide solution. Thus obtained product was dialized for 1 day using a cellophane diaphragm and dried by freezing to give 60 g. of watersoluble polymer having the intrinsic viscosity of 0.1.
EXAMPLE 1 A photographic gelatino silver halide emulsion for highsensitive negative photographic materials containing 1.8 mol of silver halides consisting of 5.0 mol of silver iodide and 95.0 mol of silver bromide 250 g. of gelatin, that has been ripened with a sulfur sensitizer and a gold sensitizer into the most suitable sensitivity was divided into three equal parts, and each part of them was added with g. of each of the following materials.
(a) inactive gelatin, (b) polyvinylpyrrolidone, molecular weight 40,000 and (c) poly-N-morpholino methylacrylamide [1 ]=0.25.
Then each emulsion was added with a sensitizing dye, a stabilizer, a coating aid, and a hardening agent in equal proportion and then coated on a triacetylcellulose film base in a same film thickness, followed by drying. The coated film was exposed at 1/20 of second in a sensitometer of 5400 K. in intensity scale and developed for 150 minutes at C. in a developing solution of the composition:
Grams l-phenyl-3-pyrazolidone 0.2 Sodium sulfite (anhydrous) 100 Hydroquinone 7 Borax l0 Boric acid 3 Potassium bromide 1 Water to 1 liter.
The photographic densities of thus developed photographic films were measured, the results of which are shown in the following table.
TABLE 1 Relative sensi- Relative sensitivity giving tivity giving Gamma Fog density 0! 0.1 density of 0.5
on fog on log (a) 100 100 1. 17 0. 10 (b) 97 105 1. 26 0.10 (c) 131 151 1. 34 0. 10
As shown in the above table, the gamma and the sensitivity of the photographic emulsion were increased by the addition of poly-N-morpholino methylacrylamide. Furthermore, while the addition of polyvinylpyrrolidone does not increase the intensity at the lower end portion of the characteristic curve, the sensitivity of that portion can be increased by the addition of poly-N-morpholino methylacrylamide.
EXAMPLE 2 A photographic gelatino silver halide emulsion for high-sensitive negative photographic materials containing 3.0 mol of silver halides consisting of 5 .0 mol percent of silver iodide and 95.0 mol percent of silver bromide and 1050 g. of gelatin and had been ripened into the most suitable sensitivity with a sulfur sensitizer and a gold sen sitizer was divided into 10 equal parts. Each part of them was added with 50 ml. of an aqueous 10% solution of each of the following materials:
Each emulsion was endowed with panchromatic property by adding a sensitizing dye and then added with 20 ml. of an aqueous 1% solution of 4-hydroxy-6-methyl- 1,3,3a,7-tetra-azaindene as a stabilizer, 1.5 m1. of an aqueous 10% solution of chrome alum as a hardening agent, and 1.5 ml. of an aqueous 4% solution of saponin as a coating aid. The emulsion was coated on a triacetylcellulose film base in a same thickness and dried. Thus obtained photographic sensitive film was exposed at 1/20 of second in a sensitometer of 5400 K. in intensity scale and developed for 7 minutes at 20 C. in the solution of the following composition:
Water to 1 liter.
The results of measuring the photographic densities of these developed films are shown in the following table.
TABLE 2 Relative sensi- Relative sensitivity giving tivity giving Gamma Fog density of 0.1 density of 0.5 on log on log 7 EXAMPLE 3 A gelatino silver-iodide-bromide emulsion for high sensitive X-ray films that had been chemically ripened into the most suitable sensitivity was added with each of the following compounds in an amount of g. per 0.6 mol of the silver halide in the emulsion;
(n) inactive gelatin (0) poly-N-morpholino ethylacrylamide (p) poly-N-morpholino propylacrylamide.
After adding a stabilizer, hardening agent and coating aid, the emulsion was coated upon a subbed polyethylene terephthalate film base in a same thickness each and then dried.
Thus obtained photographic sensitive film was exposed at A of second in a sensitometer of intensity scale having a blue filter and developed in a metolhydroquinone developing solution of a high pH. As the results of measuring the photographic densities, it was confirmed that the sensitivity of the photographic sensitive film added with polymer o) or polymer (p) was higher than that of the sensitive film added with additive =(n).
EXAMPLE 4 A solution of 26 g. of potassium chloride, 7 g. of potassium bromide, and 8 g. of gelatin in 230 ml. of water was maintained at 55 C. Into the above solution was added an aqueous solution of 50 g. of silver nitrate in 920 ml. of water with stirring at 55 C. Then, after adding 100 g. of gelatin, the system was further stirred for minutes, solidified by cooling with ice, divided into fine parts, and rinsed with water until the conductivity of the emulsion became 1,500 micro mho/cm.
The emulsion was dissolved again while heating, and, after adding 24 g. of sensitizing gelatin and 80 g. of inactive gelatin, heated to 55 C. for 100 minutes. Into thus obtained emulsion was dissolved g. of poly-N- morpholino methyl acrylamide, and the solution was added with 40 ml. of a 0.05% methyl alcohol solution of 3 aryl 3' ethyl 5 (2 (1 ethyl 4 quinolinidene) ethylidene) 5', 6' dimethyl 4 oxothiazolinooxycyanine iodide and 300 ml. of a 5% aqueous alkaline solution of N-n-octadecyl-l-hydroxy-4-sulfo=2-naphthamide. The mixture was coated on a subbed triacetylcellulose film base in a thickness of about 5 microns.
As the results of measuring by means of a sensitometer, the cyan coupling color photographic emulsion layer showed a high coupling density by a same exposure as compared with an emulsion layer prepared by using the same materials and by the same procedures but using an equivalent amount of inactive gelatin instead of the poly-N-morpholino methylacrylamide.
EXAMPLE 5 The photographic emulsion in Example 1 was coated in a thickness of about 10 microns upon a triacetylcellulose film base and the film was divided into two parts. One of them was further coated with an aqueous soluti-on (I) of 13 g. of gelatin and 8 g. of poly-N-morpholino methylacrylamide in 1 liter of water in a thickness of about 2 microns and another film was coated with an aqueous solution -(II) of g. of gelatin in 1 liter of water in a thickness of about 2 microns, and they were dried. As the results of conducting the exposure and development as in Example 1, the case of coating solu' tion (I) showed the higher maximum density than the case of coating solution (II).
What we claim is:
1. A photographic sensitive material comprising a support and a silver halide photographic emulsion layer, said emulsion layer containing at least one additive sewherein R represents a member selected from the group consisting of H and CH x is a positive integer; and n is '1, 2, or 3 and a copolymer shown by the general formula r r\/ B2 -CHzC 0112- wherein R and R each represents a member selected from the group consisting of H and CH x and y are positive integers; n is l, 2, or 3; and Z represents a member selected from the group consisting of I I l OONHZ, 000cm, 0000113, H20
and
H20 om H 41 CH O 2. The photographic sensitive material according to claim 1 whertin said polymer is selected from poly-N- morpholino methylacrylamide and poly-N-morpholino methylmethacrylamide.
3. The photographic sensitive material according to claim 1 wherein said copolymer is selected from N-morpholino methylacrylamide-acrylamide copolymer, N-morpholino methylacrylamide-vinyl acetate copolymer, N- morpholino methylacrylamide-methylacrylate copolymer, N- morpholino methylacrylamidevinylpyrrolidone copolymer, and' 'N-morpholino methylacrylamide-acryloyl morpholinecopolymer.
4. The photographic sensitive material according to claim 1 wherein said emulsion layer contains said additive in an amount of 33-40% by weight, based on the whole mediums in said emulsion.
5. The photographic sensitive material according to claim 1 wherein said additive is incorporated in said emulsion layer by adding it after the secondary ripening and before coating on the support.
6. The photographic sensitive material according to claim 5 wherein said additive is added as a 10-20% aqueous solution having a pH of 4 to 6.
general formula 11111 HDn 111 1128 CH2 15 H C F 3H wherein R represents a member selected from the group 20 consisting of H and CH x is a positive integer; and
n is 1, 2, or 3 and a copolymer shown by the general formula wherein R and R each represents a member selected from the group consisting of H and CH x and y are 10 positive integers; n is 1, 2, or 3; and Z represents a member selected from the group consisting of I I I CONHZ, OCOCHZ, COOCH;
8. The photographic sensitive material according to claim 7 wherein said polymer is selected from poly-N- morpholino methylacrylamide and poly-N-morpholino methylmethacrylamide.
9. The photographic sensitive material according to claim 7 wherein said copolymer is selected from N-morpholino methylacrylamide-acrylamide copolymer, N-morpholino methylacrylamide-vinyl acetate copolymer, N- morpholino methylacrylamide-methylacrylate copolymer, N-morpholino methylacrylamide-vinylpyrrolidone copolymer, and N-morpholino methylacrylamide-acryloyl morpholine copolymer.
10. The photographic sensitive material according to claim 4 wherein said emulsion layer contains said additive an an amount of 6-20% by weight based on the Whole mediums in said emulsion.
References Cited UNITED STATES PATENTS 3,178,269 4/1965 Minsk et a1 961 14 3,271,158 9/ 1966 Allentoff et al. 96-1 14 3,341,332 9/1967 Nakajima et al. 96-407 J. TRAVIS BROWN, Primary Examiner.
RONA'LD H. SMITH, Assistant Examiner.
US. Cl. X.R. 9687, 114
Claims (1)
1. A PHOTOGRAPHIC SENSITIVE MATERIAL COMPRISING A SUPPORT AND A SILVER HALIDE PHOTOGRAPHIC EMULSION LAYER, SAID EMULSION LAYER CONTAINING AT LEAST ONE ADDITIVE SELECTED FROM THE GROUP CONSISTING OF A POLYMER SHOWN BY THE GENERAL FORMULA
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP5659964 | 1964-10-05 |
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US3429707A true US3429707A (en) | 1969-02-25 |
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Application Number | Title | Priority Date | Filing Date |
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US492667A Expired - Lifetime US3429707A (en) | 1964-10-05 | 1965-10-04 | Photographic sensitive materials containing morpholino alkylalkenoylamide polymers |
Country Status (3)
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US (1) | US3429707A (en) |
DE (1) | DE1547817A1 (en) |
GB (1) | GB1076378A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3957492A (en) * | 1973-01-08 | 1976-05-18 | Fuji Photo Film Co., Ltd. | Photographic silver halide emulsion comprising an amphoteric copolymer |
US4075023A (en) * | 1971-12-20 | 1978-02-21 | Agfa-Gevaert N.V. | Polymerizable unsaturated oxazolidines and tetrahydro-1,3-oxazines and polymers thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DE4119505A1 (en) * | 1991-06-13 | 1992-12-17 | Du Pont Deutschland | METHOD FOR PRODUCING A RADIOGRAPHIC RECORDING MATERIAL WITH LOW LIGHT SENSITIVITY |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3178269A (en) * | 1964-07-10 | 1965-04-13 | William E Mcconnaughey | Carbon dioxide absorption manifold |
US3271158A (en) * | 1963-08-09 | 1966-09-06 | Eastman Kodak Co | Photographic silver halide emulsions having high wet density retention |
US3341332A (en) * | 1963-07-24 | 1967-09-12 | Fuji Photo Film Co Ltd | Light-sensitive photographic material containing polyalkenoylmorpholine |
-
1965
- 1965-10-02 DE DE19651547817 patent/DE1547817A1/en active Pending
- 1965-10-04 US US492667A patent/US3429707A/en not_active Expired - Lifetime
- 1965-10-05 GB GB42296/65A patent/GB1076378A/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3341332A (en) * | 1963-07-24 | 1967-09-12 | Fuji Photo Film Co Ltd | Light-sensitive photographic material containing polyalkenoylmorpholine |
US3271158A (en) * | 1963-08-09 | 1966-09-06 | Eastman Kodak Co | Photographic silver halide emulsions having high wet density retention |
US3178269A (en) * | 1964-07-10 | 1965-04-13 | William E Mcconnaughey | Carbon dioxide absorption manifold |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4075023A (en) * | 1971-12-20 | 1978-02-21 | Agfa-Gevaert N.V. | Polymerizable unsaturated oxazolidines and tetrahydro-1,3-oxazines and polymers thereof |
US3957492A (en) * | 1973-01-08 | 1976-05-18 | Fuji Photo Film Co., Ltd. | Photographic silver halide emulsion comprising an amphoteric copolymer |
Also Published As
Publication number | Publication date |
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GB1076378A (en) | 1967-07-19 |
DE1547817A1 (en) | 1969-11-20 |
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