US3403690A - Filters for tobacco smoke - Google Patents
Filters for tobacco smoke Download PDFInfo
- Publication number
- US3403690A US3403690A US621130A US62113067A US3403690A US 3403690 A US3403690 A US 3403690A US 621130 A US621130 A US 621130A US 62113067 A US62113067 A US 62113067A US 3403690 A US3403690 A US 3403690A
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- US
- United States
- Prior art keywords
- zinc
- filters
- smoke
- filter
- tobacco
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
Definitions
- the zinc salt may preferably be zinc acetate, zinc acetylacetonate, zinc isobutyrate, or Zinc trimethylacetate.
- This invention concerns improvements relating to filters for tobacco smoke, particularly cigarette filters.
- Filters for tobacco smoke are already known which remove the particulate phase of tobacco smoke by me chanical means, but may also adversely affect the taste of the filtered smoke.
- These filters formed from filamentary or sheet material, have differing capacities for the removal of specific constituents which it may be desired to remove. In any case, a large proportion of the constituents which it may be desired to remove occurs, partially at least, in the form of vapours which cannot be removed by mechanical filtration, but only by absorption or adsorption on a suitable surface, or by chemical reaction.
- the more volatile acidic compounds especially hydrogen sulphide, may be those which it is particularly desired to remove.
- An object of the present invention is to provide simple but effective means whereby these acidic compounds can be removed to a substantially increased extent from the smoke of burning tobacco.
- fibrous, filamentary or sheet tobacco-smoke filtering material is treated with an aliphatic organo-zinc salt compound, preferably, a neutral or basic zinc salt or complex, such as, for instance, zinc acetate, zinc acetylacetonate, zinc isobutyrate or zinc trimethylacetate.
- an aliphatic organo-zinc salt compound preferably, a neutral or basic zinc salt or complex, such as, for instance, zinc acetate, zinc acetylacetonate, zinc isobutyrate or zinc trimethylacetate.
- the zinc compound may be applied to the supporting, smoke filtering material, which constitutes the bulk of the filter, as a solid in powder form by dusting, or as a liquid in solution form by dipping or spraying. This may be done before or during the formation of the filter.
- the amount of zinc compound added will not generally exceed 50% by weight of the original weight of the supporting material. Preferably, however, the addition will not exceed Examples of ways of carrying out the invention will now be described:
- EXAMPLE I 2.5 gm. of zinc acetate dihydrate were dissolved in 100 ml. water and 4 ml. were sprayed onto a strip of openmesh creped wadding (such for example as that known as Myria paper) 90 mm. wide and weighing approximately 0.8 gm., so as to give a final concentration of 10% zinc acetate, calculated as the percentage of anhydrous zinc acetate by weight of the original weight of the paper.
- openmesh creped wadding such for example as that known as Myria paper
- the treated paper was allowed to dry overnight at room temperature (2025 C.) and was then rolled by hand to form a rod which was 90 mm. long and of cigarette diameter.
- EXAMPLE II Paper filters were prepared as in Example I except that the final concentration of the Zinc acetate was 5% by weight. The filters were attached to cigarettes and smoked as in Example 1. Analysis of the smoke obtained from these cigarettes and from those of Example I gave the following results:
- EXAMPLE VI 2.5 gm. zinc isobutyrate were mixed with ml. water and 4 ml. were sprayed onto creped wadding as in Example I to give, after drying, a final concentration of 10% zinc isobutyrate by weight. Filter cigarettes were prepared and smoked as previously described. Analysis of the smoke obtained showed that 61% of the hydrogen sulphide and 47% of the hydrogen cyanide had been removed.
- EXAMPLE VIII A 6% aqueous solution of potassium zincate was sprayed onto paper filter material to give, after removal of the solvent by drying, an increase in weight of 29% of the original weight of the said material. On smoking a cigarette through a filter made from the treated material, 70-80% of the hydrogen sulphide, more than 90% of the hydrogen cyanide, and 5060% of the other acids in the smoke which are volatile in steam were found to have been removed.
- a filter for a burnable tobacco charge comprising tobacco-smoke filtering material having added thereto in an amount less than 50% by weight of said material, an aliphatic organo-zinc salt compound, said burnable tobacco charge being substantially free of said salt.
- a filter as claimed in claim 1, wherein the zinc compound is zinc acetylacetonate.
- a filter as claimed in claim 1, wherein the zinc compound is Zinc isobutyrate.
- a filter as claimed in claim 1, wherein the zinc compound is zinc trimethylacetate.
Description
United States Patent 015cc 3,403,690 Patented Oct. 1, 1968 ABSTRACT OF THE DISCLOSURE A tobacco smoke filter having an aliphatic organozinc salt added to a tobacco-smoke filtering material. The zinc salt may preferably be zinc acetate, zinc acetylacetonate, zinc isobutyrate, or Zinc trimethylacetate.
This invention concerns improvements relating to filters for tobacco smoke, particularly cigarette filters.
Filters for tobacco smoke are already known which remove the particulate phase of tobacco smoke by me chanical means, but may also adversely affect the taste of the filtered smoke. These filters, formed from filamentary or sheet material, have differing capacities for the removal of specific constituents which it may be desired to remove. In any case, a large proportion of the constituents which it may be desired to remove occurs, partially at least, in the form of vapours which cannot be removed by mechanical filtration, but only by absorption or adsorption on a suitable surface, or by chemical reaction.
Of these constituents, the more volatile acidic compounds, especially hydrogen sulphide, may be those which it is particularly desired to remove. An object of the present invention is to provide simple but effective means whereby these acidic compounds can be removed to a substantially increased extent from the smoke of burning tobacco.
According to the invention, fibrous, filamentary or sheet tobacco-smoke filtering material is treated with an aliphatic organo-zinc salt compound, preferably, a neutral or basic zinc salt or complex, such as, for instance, zinc acetate, zinc acetylacetonate, zinc isobutyrate or zinc trimethylacetate.
The zinc compound, or more than one such compound, may be applied to the supporting, smoke filtering material, which constitutes the bulk of the filter, as a solid in powder form by dusting, or as a liquid in solution form by dipping or spraying. This may be done before or during the formation of the filter. For practical purposes, the amount of zinc compound added will not generally exceed 50% by weight of the original weight of the supporting material. Preferably, however, the addition will not exceed Examples of ways of carrying out the invention will now be described:
EXAMPLE I 2.5 gm. of zinc acetate dihydrate were dissolved in 100 ml. water and 4 ml. were sprayed onto a strip of openmesh creped wadding (such for example as that known as Myria paper) 90 mm. wide and weighing approximately 0.8 gm., so as to give a final concentration of 10% zinc acetate, calculated as the percentage of anhydrous zinc acetate by weight of the original weight of the paper.
The treated paper was allowed to dry overnight at room temperature (2025 C.) and was then rolled by hand to form a rod which was 90 mm. long and of cigarette diameter.
mm. lengths of the rod were attached as filters to cigarettes and the cigarettes were smoked by machine at 1 puff per minute, each puff being of 2 seconds duration and a volume of 35 ml. The smoke obtained was then analysed in comparison with that from control cigarettes to which untreated filters had been attached. The untreated filters, in this and the following examples, were prepared exactly as the treated filters, except that water was applied to the paper instead of the zinc compound.
EXAMPLE II Paper filters were prepared as in Example I except that the final concentration of the Zinc acetate was 5% by weight. The filters were attached to cigarettes and smoked as in Example 1. Analysis of the smoke obtained from these cigarettes and from those of Example I gave the following results:
Concentration of zinc Filtration efficiency (percent) foracetate (calculated as anhydrous) on the Hydrogen sulphide Hydrogen cyanide paper EXAMPLE III EXAMPLE IV Further lengths of cellulose acetate fibrous filter rods of filament denier 5 and total denier 72,000 were prepared as in Example III except that the final concentration of zinc acetate was 5% by weight. The filter lengths were attached to cigarettes and smoked as in Example I.
The result of the analysis of the smoke obtained from the cigarettes of Examples IH and IV is given below:
Concentration of zinc Filtration efficiency (percent) foracetate (calculated as anhydrous) on the Hydrogen sulphide Hydrogen cyanide Cellulose acetate EXAMPLE V 2.5 gm. of zinc acetylacetonate were mixed with 100 ml. of water and 4 ml. of the mixture were sprayed onto a strip of open mesh creped wadding of the kind indicated in Example I to give a final concentration, after drying overnight at room-temperature, of 10% of zinc acetylacetonate. The treated paper strips were formed into filter rods mm. long and of cigarette-diameter. 15 mm. lengths cut from these rods were attached to cigarettes and smoked as in Example I. Analysis of the smoke obtained showed that 61% of the hydrogen sulphide and 77% of the hydrogen cyanide had been removed.
EXAMPLE VI 2.5 gm. zinc isobutyrate were mixed with ml. water and 4 ml. were sprayed onto creped wadding as in Example I to give, after drying, a final concentration of 10% zinc isobutyrate by weight. Filter cigarettes were prepared and smoked as previously described. Analysis of the smoke obtained showed that 61% of the hydrogen sulphide and 47% of the hydrogen cyanide had been removed.
3 EXAMPLE v11 2.5 gm. of zinc trimethylacetate were mixed with 100 ml. of water and 4 ml. were sprayed onto creped wadding to give, after drying, a final concentration of 10% of zinc trimethylacetate by weight. Filter cigarettes were prepared and smoked as before. Analysis of the smoke obtained showed that 64% of the hydrogen sulphide and 53% of the hydrogen cyanide had been removed.
EXAMPLE VIII A 6% aqueous solution of potassium zincate was sprayed onto paper filter material to give, after removal of the solvent by drying, an increase in weight of 29% of the original weight of the said material. On smoking a cigarette through a filter made from the treated material, 70-80% of the hydrogen sulphide, more than 90% of the hydrogen cyanide, and 5060% of the other acids in the smoke which are volatile in steam were found to have been removed.
Little or no adverse efiect on the taste of the smoke filtered by filters prepared in accordance with any of the above examples was observed.
We claim:
1. A filter for a burnable tobacco charge comprising tobacco-smoke filtering material having added thereto in an amount less than 50% by weight of said material, an aliphatic organo-zinc salt compound, said burnable tobacco charge being substantially free of said salt.
2. A filter as claimed in claim 1, wherein the zinc compound is zinc acetate.
3. A filter as claimed in claim 1, wherein the zinc compound is zinc acetylacetonate.
4. A filter as claimed in claim 1, wherein the zinc compound is Zinc isobutyrate.
5. A filter as claimed in claim 1, wherein the zinc compound is zinc trimethylacetate.
6. A filter as claimed in claim 1, wherein the concentration of zinc compound is not more than 10% of the original weight of the said filtering material.
References Cited UNITED STATES PATENTS 2,429,567 10/1947 Cranford 13117 X 3,251,365 5/1966 Keith et al 13110.7
FOREIGN PATENTS 640,193 12/1936 Germany.
28,470 1902 Great Britain.
OTHER REFERENCES Shmuk, A. A., The Chemistry and Technology of Tobacco, Vol. III, Moscow, Pishchepromizdat, 1953.
SAMUEL KOREN, Primary Examiner.
D. J. DONOHUE, Assistant Examiner.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US621130A US3403690A (en) | 1967-03-07 | 1967-03-07 | Filters for tobacco smoke |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US621130A US3403690A (en) | 1967-03-07 | 1967-03-07 | Filters for tobacco smoke |
Publications (1)
Publication Number | Publication Date |
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US3403690A true US3403690A (en) | 1968-10-01 |
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US621130A Expired - Lifetime US3403690A (en) | 1967-03-07 | 1967-03-07 | Filters for tobacco smoke |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4763674A (en) * | 1986-04-16 | 1988-08-16 | Hercules Incorporated | Method and device for controlling hydrogen cyanide and nitric oxide concentrations in cigarette smoke |
US4811745A (en) * | 1988-02-04 | 1989-03-14 | Hercules Incorporated | Method and device for control of by-products from cigarette smoke |
US4896683A (en) * | 1988-10-17 | 1990-01-30 | Hercules Incorporated | Selective delivery and retention of nicotine by-product from cigarette smoke |
US5009239A (en) * | 1988-12-20 | 1991-04-23 | Hoechst Celanese Corporation | Selective delivery and retention of aldehyde and nicotine by-product from cigarette smoke |
US5038803A (en) * | 1988-02-04 | 1991-08-13 | Hercules Incorporated | Method and device for control of by-products from cigarette smoke |
WO2014099468A1 (en) * | 2012-12-20 | 2014-06-26 | Eastman Chemical Company | Surface attachment of particles to cellulose ester fibers |
CN109475177A (en) * | 2016-08-17 | 2019-03-15 | 菲利普莫里斯生产公司 | Aerosol with improved packaging material generates product |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US242967A (en) * | 1881-06-14 | Barrel-roller | ||
GB190228470A (en) * | 1902-12-24 | 1903-02-12 | Pierre Mercier | New or Improved Means for Preventing or Minimizing the Deleterious Effects of Tobacco Smoke |
DE640193C (en) * | 1933-03-24 | 1936-12-24 | Karl Klein Dr Ing | Process for reducing the nicotine content in tobacco smoke |
US3251365A (en) * | 1963-03-04 | 1966-05-17 | Ii Charles H Keith | Tobacco smoke filter |
-
1967
- 1967-03-07 US US621130A patent/US3403690A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US242967A (en) * | 1881-06-14 | Barrel-roller | ||
GB190228470A (en) * | 1902-12-24 | 1903-02-12 | Pierre Mercier | New or Improved Means for Preventing or Minimizing the Deleterious Effects of Tobacco Smoke |
DE640193C (en) * | 1933-03-24 | 1936-12-24 | Karl Klein Dr Ing | Process for reducing the nicotine content in tobacco smoke |
US3251365A (en) * | 1963-03-04 | 1966-05-17 | Ii Charles H Keith | Tobacco smoke filter |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4763674A (en) * | 1986-04-16 | 1988-08-16 | Hercules Incorporated | Method and device for controlling hydrogen cyanide and nitric oxide concentrations in cigarette smoke |
US4811745A (en) * | 1988-02-04 | 1989-03-14 | Hercules Incorporated | Method and device for control of by-products from cigarette smoke |
US5038803A (en) * | 1988-02-04 | 1991-08-13 | Hercules Incorporated | Method and device for control of by-products from cigarette smoke |
US4896683A (en) * | 1988-10-17 | 1990-01-30 | Hercules Incorporated | Selective delivery and retention of nicotine by-product from cigarette smoke |
US5009239A (en) * | 1988-12-20 | 1991-04-23 | Hoechst Celanese Corporation | Selective delivery and retention of aldehyde and nicotine by-product from cigarette smoke |
WO2014099468A1 (en) * | 2012-12-20 | 2014-06-26 | Eastman Chemical Company | Surface attachment of particles to cellulose ester fibers |
CN104869852A (en) * | 2012-12-20 | 2015-08-26 | 伊士曼化工公司 | Surface attachment of particles to cellulose ester fibers |
CN109475177A (en) * | 2016-08-17 | 2019-03-15 | 菲利普莫里斯生产公司 | Aerosol with improved packaging material generates product |
KR20190035725A (en) * | 2016-08-17 | 2019-04-03 | 필립모리스 프로덕츠 에스.에이. | An aerosol-generating article having an improved wrapper |
US11178906B2 (en) | 2016-08-17 | 2021-11-23 | Philip Morris Products S.A. | Aerosol-generating article having improved wrapper |
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