US3382574A - Method of making an electrical resistor - Google Patents

Method of making an electrical resistor Download PDF

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Publication number
US3382574A
US3382574A US410091A US41009164A US3382574A US 3382574 A US3382574 A US 3382574A US 410091 A US410091 A US 410091A US 41009164 A US41009164 A US 41009164A US 3382574 A US3382574 A US 3382574A
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United States
Prior art keywords
resistors
resistor
temperature
cure
silicone
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Expired - Lifetime
Application number
US410091A
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English (en)
Inventor
George F Chadwick
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Airco Inc
Original Assignee
Air Reduction Co Inc
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Filing date
Publication date
Application filed by Air Reduction Co Inc filed Critical Air Reduction Co Inc
Priority to US410091A priority Critical patent/US3382574A/en
Priority to FR25276A priority patent/FR1440529A/fr
Priority to LU49129A priority patent/LU49129A1/xx
Priority to BE667242D priority patent/BE667242A/xx
Priority to GB37330/65A priority patent/GB1068699A/en
Priority to ES0317407A priority patent/ES317407A1/es
Priority to SE13333/65A priority patent/SE314428B/xx
Priority to DK535165AA priority patent/DK116008B/da
Priority to NL6513572A priority patent/NL6513572A/xx
Priority to DE19651465230 priority patent/DE1465230A1/de
Priority to AT999465A priority patent/AT270806B/de
Application granted granted Critical
Publication of US3382574A publication Critical patent/US3382574A/en
Priority to US00061045A priority patent/US3742423A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/14—Conductive material dispersed in non-conductive inorganic material
    • H01B1/18—Conductive material dispersed in non-conductive inorganic material the conductive material comprising carbon-silicon compounds, carbon or silicon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01C—RESISTORS
    • H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01C—RESISTORS
    • H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
    • H01C17/06—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01C—RESISTORS
    • H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
    • H01C17/06—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base
    • H01C17/065—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thick film techniques, e.g. serigraphy
    • H01C17/06506—Precursor compositions therefor, e.g. pastes, inks, glass frits
    • H01C17/06573—Precursor compositions therefor, e.g. pastes, inks, glass frits characterised by the permanent binder
    • H01C17/06586—Precursor compositions therefor, e.g. pastes, inks, glass frits characterised by the permanent binder composed of organic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01C—RESISTORS
    • H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
    • H01C17/30—Apparatus or processes specially adapted for manufacturing resistors adapted for baking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01C—RESISTORS
    • H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
    • H01C7/001—Mass resistors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49082—Resistor making
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49082—Resistor making
    • Y10T29/49087—Resistor making with envelope or housing

Definitions

  • This invention relates to the manu-facture of electrical resistors of the type used in such electrical apparatus as radio and television receivers and electrical control equipment. More particularly, the invention relates to the type of electrical resistors known in the trade as composition resistors. The invention is useful also in making related resistors of other configurations such as those printed on ceramic or composition substrates.
  • a silicone polyorgano-siloxane
  • the improved results may be obtained by the use of a silicone resin which has the ability to cure, at least partially, by condensation, but which can lbe further cured under special treatment to produce an exceptionally stable resistor component.
  • any reactive silicone can be utilized, the preferred embodiment of the invention uses a condensable type rather than an unsaturated type.
  • Resistors made according to this invention may be of any convenient shape, such as rods, cubes, etc., and any desired termination such as pressed metallic ends or molded in wire leads.
  • the binder maybe advanced without loss of the improved stability of the completed resistor.
  • the resistor is iirst molded or shaped by either a hot molding process or a cold molding process and then Igiven a fast heat cure.
  • a prebaking or procuring can be carried out concurrently with or immediately after the molding or shaping to irnpart ladditional strength to the resistor during further handling and prior to a fast and high-temperature heat cure.
  • the shortterm, ⁇ high-temperature cure of this invention produces exceptional properties in the resistor.
  • This invention utilizes two procedures for curing the silicone resins to produce optimum stability and electrical properties. These procedures, which are substantially equivalents, are high-temperature thermal cure and infrared irradiation.
  • Another object of the invention is to provide improved ⁇ apparatus for curing resistors in accordance with the method of this invention.
  • FIGURE 1 is 'a flow diagram combined with a diagrammatic illustration of apparatus for making resistors with the short-period, high-temperature cure of this invention
  • FIGURE 2 is an isometric view of a leadless resistor made in accordance with this invention.
  • FIGURE 3 is an isometric view of another resistor, having leads at both ends, and made in accordance with this invention.
  • FIGURE 4 is a sectional view taken through the longitudinal axis of the resistor shown in FIGURE 3;
  • FIGURE 5 is a graph comparing resistance change of prior art resistors with that of resistors made in accordance with the present invention when subjected to electrical load for extended periods;
  • FIGURE v6 is a graph comparing resistance change of prior art resistors with that of resistors made in accordance with the present invention when subjected to moisture for extended periods.
  • the mixture used for making resistors includes a silicone resin binder and a .ller, which may be considered the basic mix.
  • a silicone resin binder and a .ller, which may be considered the basic mix.
  • To this basic mix is yadded a quantity of electrically-conductive material, the amount of which depends upon the desired resistance of the resistor.
  • the basic mix includes the following ranges of proportions (all percentages stated herein being by weight):
  • Percent Silicone resin (solids) 15-50 Filler such as pulverized silica, mica, wollastonite, asbestos fibers, chopped fiber glass, or a mixture of these and other materials 50-85
  • calcined carbon black or (graphite las the electricallyconductive material Carbon or graphite in amounts greater than 10% may be added to the mix to decrease the resistance of the resulting resistor if desired.
  • the carbon or graphite can be included in the original mixing of the ingredients of the basic mix to produce what may be considered as homogeneous mix; or the carbon or graphite can be added later to the already-mixed basic mix to produce what may be considered a heterogeneous mixture. Better results are obtained by using carbon black calcined at 1,000 C. or even higher temperatures.
  • a pulverized silica sand (silica our which would pass a B25-mesh screen), with suflicient toluene to prepare a wet paste, was mixed with the silicone resin in a sigma mixer, the mixer lbeing preheated to about C.
  • rIlhe granules were dumped out onto a clean paper or into pans for cooling. After cooling, the coarse mix was ground, using a corn mill or hammer mill. The mix was then screened (through 40-mesh) and was used both for the shell and for the core of heterogeneous type resistors. For use as core, the 4Q-mesh ⁇ granules were placed in a clean, dry ball mill and the desired carbon black added. The ball mill was then filled to about one-third capacity with clean balls and the mix was tumbled for thirty minutes.
  • the silicone resin is preferably a heat-condensable resin and excellent results have been obtained with both alkyl, aryl and alkyl silicones in the resistor or with either silicone in the resistor. Among those giving especially good results are the silicones sold by the General Electric Company under the trade designations 81888 and SR211. Other suitable resins include General Electric SR220 and Dow Corning 5061 and 2105A. The preferred percentage of resin is between 18 and 22% of the basic mix when silica flour is the principal filler. All percentages are by weight. 21% has been used with very good results.
  • lt is desirable to include of asbestos fines in the filler, this percentage being taken as a portion of the basic mix; or 10% of glass fibers of mixtures of asbestos fines and glass bers are especially desirable. 1,732 glass fibers have been used with good results. The glass fibers and asbestos result in a materially stronger resistor without harm to the thermal stability and moisture resistance. It was found that by including 10% asbestos fines in place of some of the silica powder, an almost two-fold increase in the fiber strength of the mix resulted.
  • a catalyst and mild pressure have been used to advantage to give the original green-molded resistor somewhat greater strength.
  • the amount of catalyst used has been up to 1% of the mix, but the catalyst is not essential.
  • the General Electric Company supplies a proprietary quaternary ammonium compound to promote silicone polymerization.
  • a number of other catalysts were also used for this invention but did not produce any better results than the General Electric catalyst. Neither the catalyst type nor its concentration was found to affect the final resistor properties obtained. The catalyst was found to improve the precured strength, however, which permitted more severe final cures. Examples of other catalysts which were used include: hexamethylenetetramine; hexamethylenetetramine ethiodide; boron tritiuoride; dicyandiaminc; cobalt and manganese driers; and arsenic pentoxide.
  • Resistors were prepared from this mix by compression molding in regular production presses in multicavity dies. The resistors were cured for five minutes at 425 C. No impregnation lwas necessary to produce the desired 'resistor properties. The cure can be accomplished by baking in an oven, by infrared radiation, by microwave, or other means for supplying the energy required.
  • the catalyst used was a quaternary amine supplied by the General Electric Company under the designation 81784.
  • the silicone in this mix can be varied between l() and 25% with good results but better results are obtained within a range of 1824%; and with proportionate reduction in the asbestos and silica but higher initial strength for handling is obtained if there is little or no reduction in the asbestos.
  • the granular mix was ground to the desired size (40, 60 mesh). Grinding was done successfully on different lots using a corn mill, a hammer mill and a Stokes Tornado mill. All three mills were satisfactory, though size distribution differed somewhat with the grinder used. Carbon black was added by the usual ball mill technique minutes).
  • the molding pressure is preferably of the order of 20,000 pounds per square inch.
  • the application of substantial pressure increased the density of the resistor and adds correspondingly to its strength. Much better results are obtained if an internal lubricant is included in the mixture to facilitate ejection from the mold.
  • Zinc stcarate and Carnauba wax are suitable as lubricants.
  • This invention can be used to make leadless-type resistors having metal ends, and it can be used for making conventional style resistors with wire leads embedded in the conductive core and with a jacket of electrically-insulating material convering the core.
  • the molded (green) resistors may lack sufficient strength to be supported by their leads during a high-temperature cure. It was found, however, that the use of a short, lower-temperature precuIe, advanced the silicones sufficiently to sustain further handling and more severe heat treatment, as previously explained. When a precure is used, 15 to 30 minutes at about 150 to 185 C. was found to yield improved strength without having any apparent effect on the electrical properties. Optional low temperature precure is not to be confused with the short high temperature final cure essential to the present invention.
  • the load test Two standard tests used in evaluating these resistors and resistors of the prior art were the load test and the 170 C. oven stability test.
  • an appropriate electrical load (2 watts and not over 500 volts for a 2 watt resistor for example) is applied at C. for 1,000 hours.
  • the load is applied in cyclesminutes load and 30 minutes no load.
  • the Stability of the resistor is judged by comparing the resistance before and after the test.
  • the military specification on this test requires an average change in resistance not exceeding 6% and a maximum deviation for any one piece not to exceed plus or minus 10%.
  • the oven stability test subjects the components of known resistance value to an ambient temperature of C. (at no load) for an arbitrary period of 500 or 1,000 hours, after which the resistance values of the test pieces are again determined.
  • the short-period, high-temperature heat cure may be for a period of about 3 to l5 minutes.
  • the preferred time is between aboutS and 6 minutes.
  • the temperature should be about between 400 to 525 C. and preferably between about 425 to 475 C. This time does not seem to be affected by whether or not the resistor was subjected to a prebaking or low-temperature cure for increasing the strength of the green-mold resistor prior to further handling.
  • resistors made according to the present invention are characterized by their superior stability and useful life under conditions of varying temperature, moisture and load. This superiority over the prior art carbon composition resistors has been demonstrated by comparing resistors made according to the present invention with such prior art resistors in standard tests.
  • FIGURE 5 illustrates the change in resistance with time under standard load conditions for (1) resistors made in accordance with the present invention, (2) silicone bonded resistors with the conventional low temperature cure, and 3) conventional phenolic bonded resistors. It is quite apparent from reference to FIGURE 5 that the novel resistor of the present invention completely outclasses prior art silicone bonded resistors after less than 500 hours under load and is similarly superior to the conventional phenolic bonded resistors after less than 5,000 hours.
  • this invention produces resistors of outstanding load-life stability.
  • resistors cured in a nitrogen atmosphere as opposed to being cured in air.
  • resistors cured for-about five minutes at 525 C. are scarcely changed in resistance, the change averaging about plus 1.5%.
  • FIGURE 6 of the drawings shows typical resistor behavior during extended moisture exposure for commercial phenolic bonded resistors and for silicone bonded resistors made according to the present invention. While both types fall well within the 10% resistance increase tolerance of the military specification after 75 hours of accelerated testing at 65 C., 95-100% relative humidity, the resistors of the present invention exhibit mu-ch less change. However, after 1,000 hours or more the novel resistors are obviously vastly superior. Experience indicates that moisture changes of 3% or less can be expected in accordance with the present invention.
  • Resistors can be cured by subjection to infrared radiation. Intense infrared radiation rapidly heats the silicone resistors, probably because of their strong infrared absorption around 9 microns. Further, the soldercoated lead wires reflect most of the radiation and thus are less severely degraded than during equivalent thermal cure.
  • a continuous-belt conveyor assembly was used to provide for simultaneous radiation on both sides of the resistors. The degree of heating of the resistor material with infrared heating is substantially the same as with ordinary thermal heating.
  • the drawing illustrates the steps of mixing the ingredients; molding or shaping the resistor; and prebaking, if such a step is to be used for increasing the strength of the green-molded resistor for further handling.
  • the attachment of terminals is not illustrated since it is conventional, well understood in the art, and its inclusion in this application is not necessary for a complete understanding of the invention.
  • the resistors are then subjected to a short-time, hightemperature cure.
  • This short, high-temperature cure is at elevated temperatures which were previously considered undesirable.
  • the short-period, high-temperature cure produces exceptionally good results which are better than those obtained with conventional curing.
  • the curing apparatus shown in the drawing includes a base 10 with blocks 12 in which there are bearings for shafts 14 and 16. There is a wheel 16 on the shaft 14 between the blocks 12, and a pulley 20 on the shaft 14 beyond the blocks 12.
  • Power is transmitted to the shaft 14 from a motor 22 which drives a speed reducer 24 having a belt 26 that drives the pulley 20.
  • the speed reducer 24 has an adjustment 32 for changing the speed of rotation of the pulley 20.
  • the pulley 20 and wheel 18 are secured to the shaft 14 so that rotation imparted to the pulley 20 causes rotation of the wheel 18 in the same direction.
  • the conveyor belt 40 passes around a wheel 44 supported by a shaft 46 in bearings in blocks 48 extending upwardly from the base 10.
  • Some tension is imparted to the conveyor belt 40, to hold it in firm contact with the wheels 18, 36, and 44, by an idler roller 52 carried by an arm 54.
  • This arm 54 may be loaded by a spring 56, the tension of which is adjustable by a lead screw 58.
  • the conveyor belt 40 is preferably made of an endless metal strip having openings 60 at evenly-spaced locations along its length. These openings 60 are of a size to receive resistors 62 and the drawing shows resistors 62 located in the openings 60' beyond a region 64 which may be considered the loading station for the conveyor. These resistors 62 can be placed in the openings 60, which constitute holders for the resistors either manually or by automatic feeding means.
  • heaters 64 and 66 are carried on a support 70 which maintains them in parallel relation to one another and to the path of travel of the conveyor belt 40 between the heaters 64 and 66.
  • the speed reducer 24 is adjusted, in proportion to the length of run of the conveyor belt 40, between the heaters r64 and 66 so as to maintain each resistor 62 between the heaters for the length of time required for the hightemperature cure.
  • the heaters 64 and 66 are preferably infrared radiant heaters and the space between them is not substantially greater than the height of the resistors 62. This results in a rapid and intense heating of the'resistors 62 with the lower portions of the resistors exposed to radiant heat from the lower heater 66 as a result of the openings 60 in the conveyor.
  • the wheel 44 is located some distance beyond the heaters 64 and 66 so that there will be a substantial cooling of the resistors before the conveyor belt 40 reaches the Wheel 44. As the belt 40 curves around the circumference of the wheel 44, the resistors 62 are pushed out of the openings 60 by the surface of the wheel 44; and the displaced resistors drop into a tote box 75.
  • FIGURE 2 shows a leadless-type resistor 82 having an electrically-conductive core 84 and metal ends S6 which are preferably made of metal powder.
  • FIGURE 3 shows one of the resistors 62 with wire leads 88 extending from both ends of a conductive core 90 (FIGURE 4).
  • Each of the resistor leads SS preferably has its end portion, which extends into the core 90, coated with a lead dope consisting of approximately 37.5% silicone resin and 62.5% graphite mixed with enough toluene to give proper flow.
  • the resistors 62 preferably have an outside jacket 92 of electrically-insulating material.
  • the method described in claim 1 characterized by the resistor being molded at substantially room temperature and then being subjected to a low-temperature precure immediately after the molding and before further handling, the low-temperature precure being for a period of about to 30 minutes at a temperature of about 150 to 185 C. to improve the physical strength of the resistor, and thereafter heating the resistor to a temperature between about 400 and 525 C. for a period of about 3 to 15 minutes to cure the resin.
  • an electric resistor element from a mixture of from l5 to 50% solids of a silicone resin binder, from to 85% ller, and up to 10% of electrically-conductive material, the improvement which comprises molding the mixture at relatively low temperature and after molding to the desired shape, subjecting the mixture at a temperature of about 400 to 525 C. for long enough to cure the resin binder.
  • the method described in claim 8 characterized by the silicone being in an amount between about 18 to 22% and the filler including about 10% asbestos fines, and strengthening the resistor prior to curing by including in the a catalyst for the silicone.
  • composition resistors having a silicone resin binder
  • the process comprising: admixing pulverized silica, silicone resin and finely-divided carbon; cold-molding the mix to form a dense, green, composition body; and heating the body at a temperature in excess of 400 C. and for approximately 3 to l5 minutes duration to cause condensation of the resin of said body to form a permanent, dense mechanically strong, conductive composition resistor.

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Apparatuses And Processes For Manufacturing Resistors (AREA)
  • Details Of Resistors (AREA)
US410091A 1964-11-10 1964-11-10 Method of making an electrical resistor Expired - Lifetime US3382574A (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
US410091A US3382574A (en) 1964-11-10 1964-11-10 Method of making an electrical resistor
FR25276A FR1440529A (fr) 1964-11-10 1965-07-20 Fabrication de résistances électriques agglomérées
LU49129A LU49129A1 (es) 1964-11-10 1965-07-21
BE667242D BE667242A (es) 1964-11-10 1965-07-22
GB37330/65A GB1068699A (en) 1964-11-10 1965-09-01 Electrical resistor
ES0317407A ES317407A1 (es) 1964-11-10 1965-09-13 Metodo de produccion de un resistor electrico.
SE13333/65A SE314428B (es) 1964-11-10 1965-10-14
DK535165AA DK116008B (da) 1964-11-10 1965-10-19 Elektrisk modstand og fremgangsmåde til fremstilling af denne.
NL6513572A NL6513572A (es) 1964-11-10 1965-10-20
DE19651465230 DE1465230A1 (de) 1964-11-10 1965-11-02 Elektrischer Widerstand und Verfahren zu seiner Herstellung
AT999465A AT270806B (de) 1964-11-10 1965-11-04 Verfahren zur Herstellung elektrischer Vollmassewiderstände mit einem Paar leitender Enden
US00061045A US3742423A (en) 1964-11-10 1970-07-13 Electrical resistor

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Application Number Priority Date Filing Date Title
US410091A US3382574A (en) 1964-11-10 1964-11-10 Method of making an electrical resistor

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US3382574A true US3382574A (en) 1968-05-14

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US410091A Expired - Lifetime US3382574A (en) 1964-11-10 1964-11-10 Method of making an electrical resistor

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US (1) US3382574A (es)
AT (1) AT270806B (es)
BE (1) BE667242A (es)
DE (1) DE1465230A1 (es)
DK (1) DK116008B (es)
ES (1) ES317407A1 (es)
FR (1) FR1440529A (es)
GB (1) GB1068699A (es)
LU (1) LU49129A1 (es)
NL (1) NL6513572A (es)
SE (1) SE314428B (es)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3445554A (en) * 1966-03-11 1969-05-20 Dow Corning Manufacture of silicon carbide ribbons
US3676925A (en) * 1970-07-28 1972-07-18 Matsushita Electric Ind Co Ltd Method for making molded carbon composition resistors
US3680027A (en) * 1971-04-19 1972-07-25 Avnet Inc Ignition cable
US3689618A (en) * 1970-08-05 1972-09-05 Air Reduction Use of an unadvanced silicone resin binder in resistor manufacture
US3808678A (en) * 1972-08-16 1974-05-07 Matsushita Electric Ind Co Ltd Method of making pressure-sensitive resistor element
US4101862A (en) * 1976-11-19 1978-07-18 K.K. Tokai Rika Denki Seisakusho Current limiting element for preventing electrical overcurrent
US4243624A (en) * 1979-05-21 1981-01-06 Exxon Research & Engineering Co. Method of making cathodes derived from ammonium-metal-chalcogen compounds
US4433092A (en) * 1981-03-09 1984-02-21 Champion Spark Plug Company Green ceramic of lead-free glass, conductive carbon, silicone resin and AlPO4, useful, after firing, as an electrical resistor
US4511524A (en) * 1981-02-23 1985-04-16 Champion Spark Plug Company Carbon resistor and method for producing same
US4606117A (en) * 1983-05-13 1986-08-19 Tdk Corporation Apparatus for automatically mounting chip type circuit elements on printed circuit boards
WO1992016305A1 (de) * 1991-03-19 1992-10-01 Georg Sillner Melf-lackiermaschine
US20070249757A1 (en) * 2004-09-17 2007-10-25 Rabe James A Siloxane Composition, Agglomerate, and Method of Preparing

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2526059A (en) * 1947-02-13 1950-10-17 Allen Bradley Co Fixed electrical resistor
US2529830A (en) * 1948-05-13 1950-11-14 Boston Woven Hose & Rubber Co Vulcanizing method and apparatus
US2795680A (en) * 1952-05-16 1957-06-11 Sprague Electric Co Printed resistors and inks
US3003975A (en) * 1958-11-26 1961-10-10 Myron A Coler Conductive plastic composition and method of making the same
US3022213A (en) * 1958-02-13 1962-02-20 Michigan Res Lab Inc Conductive web and method of making same
US3037266A (en) * 1957-01-30 1962-06-05 Allen Bradley Co Method for making sealed resistors

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2526059A (en) * 1947-02-13 1950-10-17 Allen Bradley Co Fixed electrical resistor
US2529830A (en) * 1948-05-13 1950-11-14 Boston Woven Hose & Rubber Co Vulcanizing method and apparatus
US2795680A (en) * 1952-05-16 1957-06-11 Sprague Electric Co Printed resistors and inks
US3037266A (en) * 1957-01-30 1962-06-05 Allen Bradley Co Method for making sealed resistors
US3022213A (en) * 1958-02-13 1962-02-20 Michigan Res Lab Inc Conductive web and method of making same
US3003975A (en) * 1958-11-26 1961-10-10 Myron A Coler Conductive plastic composition and method of making the same

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3445554A (en) * 1966-03-11 1969-05-20 Dow Corning Manufacture of silicon carbide ribbons
US3676925A (en) * 1970-07-28 1972-07-18 Matsushita Electric Ind Co Ltd Method for making molded carbon composition resistors
US3689618A (en) * 1970-08-05 1972-09-05 Air Reduction Use of an unadvanced silicone resin binder in resistor manufacture
US3680027A (en) * 1971-04-19 1972-07-25 Avnet Inc Ignition cable
US3808678A (en) * 1972-08-16 1974-05-07 Matsushita Electric Ind Co Ltd Method of making pressure-sensitive resistor element
US4101862A (en) * 1976-11-19 1978-07-18 K.K. Tokai Rika Denki Seisakusho Current limiting element for preventing electrical overcurrent
US4243624A (en) * 1979-05-21 1981-01-06 Exxon Research & Engineering Co. Method of making cathodes derived from ammonium-metal-chalcogen compounds
US4511524A (en) * 1981-02-23 1985-04-16 Champion Spark Plug Company Carbon resistor and method for producing same
US4433092A (en) * 1981-03-09 1984-02-21 Champion Spark Plug Company Green ceramic of lead-free glass, conductive carbon, silicone resin and AlPO4, useful, after firing, as an electrical resistor
US4606117A (en) * 1983-05-13 1986-08-19 Tdk Corporation Apparatus for automatically mounting chip type circuit elements on printed circuit boards
WO1992016305A1 (de) * 1991-03-19 1992-10-01 Georg Sillner Melf-lackiermaschine
US20070249757A1 (en) * 2004-09-17 2007-10-25 Rabe James A Siloxane Composition, Agglomerate, and Method of Preparing
US7737082B2 (en) * 2004-09-17 2010-06-15 James Alan Rabe Siloxane composition, agglomerate, and method of preparing

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LU49129A1 (es) 1965-09-21
GB1068699A (en) 1967-05-10
DK116008B (da) 1969-12-01
FR1440529A (fr) 1966-05-27
BE667242A (es) 1965-08-13
NL6513572A (es) 1966-05-11
DE1465230A1 (de) 1969-04-03
AT270806B (de) 1969-05-12
SE314428B (es) 1969-09-08
ES317407A1 (es) 1966-05-16

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