US3211551A - Diffusion transfer process - Google Patents
Diffusion transfer process Download PDFInfo
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- US3211551A US3211551A US7841A US784160A US3211551A US 3211551 A US3211551 A US 3211551A US 7841 A US7841 A US 7841A US 784160 A US784160 A US 784160A US 3211551 A US3211551 A US 3211551A
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- layer
- silver halide
- positive
- water
- transfer layer
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- 238000000034 method Methods 0.000 title claims description 23
- 230000008569 process Effects 0.000 title claims description 19
- 238000009792 diffusion process Methods 0.000 title claims description 10
- -1 SILVER HALIDE Chemical class 0.000 claims description 30
- 229910052709 silver Inorganic materials 0.000 claims description 27
- 239000004332 silver Substances 0.000 claims description 27
- 239000000839 emulsion Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 15
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 11
- 239000003638 chemical reducing agent Substances 0.000 claims description 8
- 230000004913 activation Effects 0.000 claims description 7
- 230000009467 reduction Effects 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 11
- 239000001632 sodium acetate Substances 0.000 description 11
- 235000017281 sodium acetate Nutrition 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- 239000004133 Sodium thiosulphate Substances 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 6
- 235000019345 sodium thiosulphate Nutrition 0.000 description 6
- 239000001828 Gelatine Substances 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 229920000159 gelatin Polymers 0.000 description 5
- 235000019322 gelatine Nutrition 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 235000011083 sodium citrates Nutrition 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- VSTZVCJQGSLNLL-UHFFFAOYSA-N 2-aminophenyl hydrogen sulfate Chemical compound NC1=CC=CC=C1OS(O)(=O)=O VSTZVCJQGSLNLL-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 1
- 239000004297 potassium metabisulphite Substances 0.000 description 1
- 235000010263 potassium metabisulphite Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/40—Development by heat ; Photo-thermographic processes
- G03C8/4006—Development by heat ; Photo-thermographic processes using materials covered by the groups G03C8/04 - G03C8/06
Definitions
- the invention is applicable to the production of positive images from all kinds of exposed photographic, silverhalide containing emulsion layers comprising additional developing substances.
- a latent image is first produced by exposure of a photographic layer, whereupon this image is developed in contact with a gelatine layer containing reduction nuclei, preferably colloidal silver, by dissolving the unexposed silver-halide in the photographic layer.
- a gelatine layer containing reduction nuclei preferably colloidal silver
- a further object of the invention resides in the provision of a process for producing correctly sided positive images from exposed photographic layers.
- correctly sided positive images are formed by pressing against the exposed film layer a positive or transfer layer comprising polyvinyl alcohol and a hydrate, such as sodium acetate, capable of yielding water of crystallization.
- a positive or transfer layer comprising polyvinyl alcohol and a hydrate, such as sodium acetate, capable of yielding water of crystallization.
- Polyvinyl alcohol upon heatingin contrast to gelatine-is not reversible upon absorption of water.
- the polyvinyl alcohol layer comprises, in addition to the 3,211,551 Patented Oct. 12,1965
- water-releasing substances also bifunctional or trifunctional alcohols which assure a high residual moisture and at the same time act as reducing agents.
- the positive layer is not formed by re-v versible gelatine, but that polyvinyl alcohol isused, and that this transfer layer does not contain colloidal silver.
- Polyvinyl alcohol if used as a layer-forming substance will liberate the bound water of crystallization much better than the known layer substances, e.g., gelatine.
- sodium acetate is added to the polyvinyl layer as a deliquescent thermally activable hydrate.
- the amount of sodium acetate is chosen in such a manner that, during use and upon heating, an amount of water is liberated which is required to enable the activation of the developing agents in the negative layer and the diffusion of the silver salt from its unexposed areas into the positive layer.
- sodium citrate and sodium sulphate can be used.
- glycerol is added as a reducing agent. In a positive layer formed in this way the presence of colloidal silver is superfluous.
- the negative layer from which the image is to be transferred, may comprise any desired silver-halide emulsion, for example, silver-chloride and silver-bromide emulsion in varying mixtures, having a high or low sensitivity with any desired gradations and with a normal, increased or decreased content of silver.
- the commonly known photographic developing substances are added to the negative emulsion layer.
- developing substances can be used: methyl p aminophenol-sulphate, paraphenylenediamine and its derivatives and hydroquinone.
- alkali substances may be used: sodium carbonate and caustic soda.
- heating presses electrically heated high-gloss presses, drum dryers, or the like may 'be used for the developing and the simultaneous transmission of the image to the positive layer.
- the temperature is chosen so that it remains below the hardening point of the positive layer.
- a working temperature of -80 C. is advantageous, but this of course is dependent on the positive-layer composition, hence I wish not to limit myself to this temperature range.
- the invention includes a temperature range from 70 to 120 for operation.
- the press has a pressure of 0.5-1.0 kg./m.
- the positive layer is applied onto a carrier sheet or strip such as paper, plastic or the like. It is of course within the scope of this invention to coat the carrier material with positive layers on both sides. In this case and during developing by heat the carrier coated on both sides will be placed between two negative layers so that a copy on each side is obtained in a single step.
- substances may be added to the positive layer which will further and enhance the development of the negative layer.
- additives may include, for example, alkali-metal salts such as sodium carbonate and substances which facilitate the conversion of the unexposed silver halide into a soluble complex compound, such as sodium thiosulphate.
- the deliquescent hydrates are added, with reference to the polyvinyl alcohol, in amounts of about -200%.
- conventional hardening agents as well as additives for preventing yellowing and achieving improved blackening and contrast may be added to the positive layer.
- Example 1 10 g. of polyvinyl alcohol are stirred with 20 ml. of glycerol in a porcelain dish until a homogeneous paste is formed. A solution of 2 g. of sodium carbonate in 50 ml. of water is added to this paste under constant stirring. The mass thus otbtained is then heated to SO -100 C. and 15 g. of sodium acetate in solid form is added. After the sodium acetate is completely dissolved, the mass is coated onto a carrier such as paper, whereupon the layer is dried.
- a carrier such as paper
- Example 2 A positive layer is prepared as in Example 1, with the further addition of 1 g. of sodium thiosulphate to induce the unexposed silver halide of the negative layer to form soluble complex salts.
- Example 3 A positive layer is prepared as in Example 2 with the further addition of 0.2 g. of benztriazole for increasing the blackening effect of the reduced silver in the positive layer.
- Example 4 A positive layer is prepared as in Example 2 with the further addition of 0.2 g. of potassium metabisulphite to increase the dissolving action of the sodium thiosulphate.
- Example 5 A positive layer is prepared as in Example 4 with the further addition of 0.2 g. of sodium bicarbonate to minimize yellowing.
- a sheet of paper or plastic material is used as the carrier.
- the carrier material should advantageously be water-repelling.
- Example 6 A coated carrier sheet obtained according to any one of Examples 1-5 is placed against an exposed photographic emulsion layer, e.g., an exposed film, containing common developing substances. Pressure and heat are applied. The temperature should be about 70-80 C. The image appears on the positive layer after a short time.
- an exposed photographic emulsion layer e.g., an exposed film, containing common developing substances. Pressure and heat are applied. The temperature should be about 70-80 C. The image appears on the positive layer after a short time.
- the temperature depends on the hardening degree of the negative layer and may thus vary in accordance with the composition of this layer.
- the duration of the heating depends on the nature and amount of the water-liberating substance used in the layer.
- a process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing a hydrate thermally activable to release bound water, said transfer layer further containing a water-retaining reducing agent and a solvent for silver halide; and heating said layers to a temperature not exceeding 100 C.
- a process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing a hydrate thermally activable to release bound water, said transfer layer further containing a water-retaining reducing agent, an alkalimetal salt and a solvent for silver halide; and heating said layers to a temperature not exceeding 100 C.
- a process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing a hydrate thermally activable to release bound water, said transfer layer further containing a water-retaining reducing agent selected from the group which consists of difunctional and trifunctional alcohols and a solvent for silver halide; and heating said layers to a temperature not exceeding 100 C.
- a process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing a hydrate thermally activable to release bound water, said transfer layer further containing a water-retaining reducing agent selected from the group which consists of difunctional and trifunctional alcohols, an alkali-metal salt and a solvent for silver halide; and heating said layers to a temperature not exceeding 100 C.
- a process as defined in claim 4 wherein said hydrate is selected from the group which consists of sodium acetate, sodium citrate and sodium sulphate.
- a process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing sodium acetate, glycerol, sodium thiosulphate and sodium carbonate, and heating said layers to a temperature ranging substantially between 70 and C. to liberate water from said sodium acetate with resulting activation of said developer, diffusion of silver halide from unexposed portions of said emulsion layer into said transfer layer and reduction of the diifused silver halide whereby a positive image is produced in said transfer layer.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Description
United States Patent f 3,211,551 DIFFUSION TRANSFER PROCESS Rudolf Wendt, Hamburg, Germany, assignor to Lumoprint Zindler KG., Hamburg, Germany No Drawing. Filed Feb. 10, 1960, Ser. No. 7,841 11 Claims. (Cl. 96--29) This invention relates to photographic developing and copying processes and is more particularly concerned with a novel contact-copying material and a method for its manufacture for producing correctly sided positive images from exposed photographic emulsion layers. The invention, moreover, provides for a new process for producing such positive images by employing the novel contact-copying material.
The invention is applicable to the production of positive images from all kinds of exposed photographic, silverhalide containing emulsion layers comprising additional developing substances.
In known photographic diffusion processes, generally, a latent image is first produced by exposure of a photographic layer, whereupon this image is developed in contact with a gelatine layer containing reduction nuclei, preferably colloidal silver, by dissolving the unexposed silver-halide in the photographic layer.
It is also known to cause and initiate such a diffusion by the action of heat, in which case substances are added to the. corresponding layers which, upon heating above their melting point, split off water of crystallization. Such a water-yielding substance (i.e. a hydrate) is, for example, crystallized sodium sulphate. The water of crystallization liberated during the heating referred to dissolves the developing substances and fixing agents, so that the development and fixing are caused merely by heating. In prior methods of this kind gelatine was used which is reversible so as to absorb part of the liberated water of crystallization by its own swelling.
Furthermore a method for producing embossed pictures by heating is known in which the heat acts upon the developers having tanning characteristics. This method also uses gelatine for both the negative and positive layers.
It is a primary object of this invention to overcome the drawbacks of known processes of the kind referred to, and to provide a novel contact material which, merely upon being pressed while heated against an exposed photographic layer, will result in the formation of a correctly sided positive image on the material corresponding to the latent image on the exposed photographic layer.
A further object of the invention resides in the provision of a process for producing correctly sided positive images from exposed photographic layers.
It is also an object of this invention generally to improve on photographic contact-copying processes and photographic contact-copying material and methods for their manufacture as presently practiced and used.
Briefly, in accordance with this invention, correctly sided positive images are formed by pressing against the exposed film layer a positive or transfer layer comprising polyvinyl alcohol and a hydrate, such as sodium acetate, capable of yielding water of crystallization. Polyvinyl alcohol upon heatingin contrast to gelatine-is not reversible upon absorption of water.
According to a preferred embodiment of the invention,
the polyvinyl alcohol layer comprises, in addition to the 3,211,551 Patented Oct. 12,1965
ice
water-releasing substances, also bifunctional or trifunctional alcohols which assure a high residual moisture and at the same time act as reducing agents.
It is essential for the successful operation according to the invention that the positive layer is not formed by re-v versible gelatine, but that polyvinyl alcohol isused, and that this transfer layer does not contain colloidal silver.
Polyvinyl alcohol if used as a layer-forming substance will liberate the bound water of crystallization much better than the known layer substances, e.g., gelatine. Advantageously, sodium acetate is added to the polyvinyl layer as a deliquescent thermally activable hydrate. The amount of sodium acetate is chosen in such a manner that, during use and upon heating, an amount of water is liberated which is required to enable the activation of the developing agents in the negative layer and the diffusion of the silver salt from its unexposed areas into the positive layer. Besides sodium acetate, sodium citrate and sodium sulphate can be used. Preferably, glycerol is added as a reducing agent. In a positive layer formed in this way the presence of colloidal silver is superfluous.
The negative layer, from which the image is to be transferred, may comprise any desired silver-halide emulsion, for example, silver-chloride and silver-bromide emulsion in varying mixtures, having a high or low sensitivity with any desired gradations and with a normal, increased or decreased content of silver. The commonly known photographic developing substances are added to the negative emulsion layer. As developing substances can be used: methyl p aminophenol-sulphate, paraphenylenediamine and its derivatives and hydroquinone. The following alkali substances may be used: sodium carbonate and caustic soda.
Advantageously, heating presses, electrically heated high-gloss presses, drum dryers, or the like may 'be used for the developing and the simultaneous transmission of the image to the positive layer. The temperature is chosen so that it remains below the hardening point of the positive layer. Generally, a working temperature of -80 C. is advantageous, but this of course is dependent on the positive-layer composition, hence I wish not to limit myself to this temperature range. Advantageously, the invention includes a temperature range from 70 to 120 for operation. Advantageously, the press has a pressure of 0.5-1.0 kg./m.
The positive layer is applied onto a carrier sheet or strip such as paper, plastic or the like. It is of course within the scope of this invention to coat the carrier material with positive layers on both sides. In this case and during developing by heat the carrier coated on both sides will be placed between two negative layers so that a copy on each side is obtained in a single step. According to a preferred embodiment, substances may be added to the positive layer which will further and enhance the development of the negative layer. Such additives may include, for example, alkali-metal salts such as sodium carbonate and substances which facilitate the conversion of the unexposed silver halide into a soluble complex compound, such as sodium thiosulphate. Preferably, the deliquescent hydrates are added, with reference to the polyvinyl alcohol, in amounts of about -200%. Furthermore, conventional hardening agents as well as additives for preventing yellowing and achieving improved blackening and contrast may be added to the positive layer.
The invention will now be described with reference to the following examples, it being understood, however, that these examples are given by way of illustration and not of limitation and that many alterations may be made in, e.g., quantities, choice of material and operating conditions in general Without departing from the scope and spirit of this invention as described in the appended claims.
Example 1 10 g. of polyvinyl alcohol are stirred with 20 ml. of glycerol in a porcelain dish until a homogeneous paste is formed. A solution of 2 g. of sodium carbonate in 50 ml. of water is added to this paste under constant stirring. The mass thus otbtained is then heated to SO -100 C. and 15 g. of sodium acetate in solid form is added. After the sodium acetate is completely dissolved, the mass is coated onto a carrier such as paper, whereupon the layer is dried.
Example 2 A positive layer is prepared as in Example 1, with the further addition of 1 g. of sodium thiosulphate to induce the unexposed silver halide of the negative layer to form soluble complex salts.
Example 3 A positive layer is prepared as in Example 2 with the further addition of 0.2 g. of benztriazole for increasing the blackening effect of the reduced silver in the positive layer.
Example 4 A positive layer is prepared as in Example 2 with the further addition of 0.2 g. of potassium metabisulphite to increase the dissolving action of the sodium thiosulphate.
Example 5 A positive layer is prepared as in Example 4 with the further addition of 0.2 g. of sodium bicarbonate to minimize yellowing.
In all examples, a sheet of paper or plastic material is used as the carrier. The carrier material should advantageously be water-repelling.
Example 6 A coated carrier sheet obtained according to any one of Examples 1-5 is placed against an exposed photographic emulsion layer, e.g., an exposed film, containing common developing substances. Pressure and heat are applied. The temperature should be about 70-80 C. The image appears on the positive layer after a short time.
However, it is pointed out that the temperature depends on the hardening degree of the negative layer and may thus vary in accordance with the composition of this layer. The duration of the heating depends on the nature and amount of the water-liberating substance used in the layer.
The concept of using polyvinyl alcohol as layer-forming material in positive contact-copying material is entirely novel and the beneficial result obtained thereby is certainly surprising and unexpected.
I claim:
1. A process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor, comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing a hydrate thermally activable to release bound water, said transfer layer further containing a water-retaining reducing agent and a solvent for silver halide; and heating said layers to a temperature not exceeding 100 C. but sufficient to liberate water from said hydrate with resulting activation of said developer, difiusion of a solution of undeveloped silver halide from unexposed portions of said emulsion layer into said transfer layer and reduction of the diffused silver halide whereby a positive image is produced in said transfer layer.
2. A process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor, comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing a hydrate thermally activable to release bound water, said transfer layer further containing a water-retaining reducing agent, an alkalimetal salt and a solvent for silver halide; and heating said layers to a temperature not exceeding 100 C. but sutficient to liberate water from said hydrate with resulting activation of said developer, diffusion of a solution of undeveloped silver halide from unexposed portions of said emulsion layer into said transfer layer and reduction of the diffused silver halide whereby a positive image is produced in said transfer layer.
3. A process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor, comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing a hydrate thermally activable to release bound water, said transfer layer further containing a water-retaining reducing agent selected from the group which consists of difunctional and trifunctional alcohols and a solvent for silver halide; and heating said layers to a temperature not exceeding 100 C. but sufficient to liberate Water from said hydrate with resulting activation of said developer, diffusion of silver halide from unexposed portions of said emulsion layer into said transfer layer and reduction of the diffused silver halide whereby a positive image is produced in said transfer layer.
4. A process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor, comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing a hydrate thermally activable to release bound water, said transfer layer further containing a water-retaining reducing agent selected from the group which consists of difunctional and trifunctional alcohols, an alkali-metal salt and a solvent for silver halide; and heating said layers to a temperature not exceeding 100 C. but sutficient to liberate water from said hydrate with resulting activation of said developer, diffusion of a solution of undeveloped silver halide from unexposed portions of said emulsion layer into said transfer layer and reduction of the diffused silver halide whereby a positive image is produced in said transfer layer.
5. A process as defined in claim 4 wherein said hydrate is selected from the group which consists of sodium acetate, sodium citrate and sodium sulphate.
6. A process as defined in claim 4 wherein said reducing agent is glycerol.
7. A process as defined in claim 4 wherein said solvent is sodium thiosulphate.
8. A process as defined in claim 4 wherein said alkalimetal salt is sodium carbonate.
9. A process for producing positive contact copies from an exposed negative provided with a photographic emulsion layer containing a silver halide and a developer therefor, comprising the steps of placing said emulsion layer in contact with a transfer layer of polyvinyl alcohol devoid of colloidal silver and containing sodium acetate, glycerol, sodium thiosulphate and sodium carbonate, and heating said layers to a temperature ranging substantially between 70 and C. to liberate water from said sodium acetate with resulting activation of said developer, diffusion of silver halide from unexposed portions of said emulsion layer into said transfer layer and reduction of the diifused silver halide whereby a positive image is produced in said transfer layer.
10. A process as defined in claim 9 wherein the proportion of sodium acetate ranges substantially between 100% and 200%, by weight, of the polyvinyl alcohol.
11. A process as defined in claim 10 wherein the sodium carbonate and the sodium thiosulphate are present in quantities of the order of one-tenth the weight of the sodium acetate.
References Cited by the Examiner UNITED STATES PATENTS 2,352,014 6/44 Rott 96-29 2,412,200 12/46 Blum 26029.6 2,747,999 5/ 56 Yutzy et a1. 96-29 2,878,121 3/59 Gray 96-29 2,971,840 2/61 Haydn et a1. 9629 6 FOREIGN PATENTS 555,103 8/57 Belgium. 1,003,578 2/57 Germany.
614,155 10/48 Great Britain. 5 790,811 2/ 58 Great Britain. 801,053 9/58 Great Britain.
OTHER REFERENCES Glafkides, Photographic Chemistry, Fountain Press, 10 London, 1958, pages 150-154.
NORMAN G. TORCIHN, Primary Examiner.
MILTON STERMAN, PHILIP E. MANGAN, l5 Examiners.
Claims (1)
1. A PROCESS FOR PRODUCING POSITIVE CONTACT COPIES FROM AN EXPOSED NEGATVE PROVIDED WITH A PHOTOGRAPHIC EMULSION LAYER CONTAINING A SILVER HALIDE AND A DEVELOPER THEREFOR, COMPRISING THE STEPS OF PLACING SAID EMULSION LAYER IN CONTACT WITH A TRANSFER LAYER OF POLYVINYL ALCOHOL DEVOID OF COLLOIDAL SILVER AND CONTAINING A HYDRATE THERMALLY ACTIVABLE TO RELEASE BOUND WATER, SAID TRANSFER LAYER FURTHER CONTAINING A WATER-RETAINING REDUCING AGENT AND A SOLVENT FOR SILVER HALIDE; AND HEATING SAID LAYERS TO A TEMPERATURE NOT EXCEEDING 100*C. BUT SUFFICIENT TO LIBERATE WATER FROM SAID HYDRATE WITH RESULTING ACTIVATION OF SAID DEVELOPER, DIFFUSION OF A SOLUTION OF UNDEVELOPED SILVER HALIDE FROM UNEXPOSED PORTIONS OF SAID EMULSION LAYER INTO SAID TRANSFER LAYER AND REDUCTION OF THE DIFFUSED SILVER HALIDE WHEREBY A POSITIVE IMAGE IS PRODUCED IN SAID TRANSFER LAYER.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEL29247A DE1080854B (en) | 1957-12-10 | 1957-12-10 | Process for the production of correct-sided positive images under the influence of heat and positive material for the implementation of this process |
Publications (1)
Publication Number | Publication Date |
---|---|
US3211551A true US3211551A (en) | 1965-10-12 |
Family
ID=10427061
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US7841A Expired - Lifetime US3211551A (en) | 1957-12-10 | 1960-02-10 | Diffusion transfer process |
Country Status (4)
Country | Link |
---|---|
US (1) | US3211551A (en) |
DE (1) | DE1080854B (en) |
FR (1) | FR1245422A (en) |
GB (1) | GB921370A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1175988B (en) * | 1958-04-19 | 1964-08-13 | Zindler Lumoprint Kg | Process for developing and at the same time stabilizing exposed photographic halogen silver emulsion layers, material for carrying out this process and process for producing this material |
US3248219A (en) * | 1960-09-06 | 1966-04-26 | Cons Electrodynamics Corp | Photographic element for dry processing |
DE1298415B (en) * | 1962-10-29 | 1969-06-26 | Eastman Kodak Co | Method for the transmission of images |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE555103A (en) * | 1956-02-18 | |||
US2352014A (en) * | 1941-07-21 | 1944-06-20 | Rott Andre | Photomechanical printing process and printing material for carrying out the same |
US2412200A (en) * | 1941-09-12 | 1946-12-10 | Jr Robert D Blum | Hectograph mass |
GB614155A (en) * | 1939-11-02 | 1948-12-10 | Gevaert Photo Prod Nv | Improvements in and relating to photographic processes |
US2747999A (en) * | 1953-03-16 | 1956-05-29 | Eastman Kodak Co | Photographic reproduction process |
DE1003578B (en) * | 1952-09-04 | 1957-02-28 | Zindler Lumoprint Kg | Process for producing photographic images and means for carrying out the same |
GB790811A (en) * | 1955-02-11 | 1958-02-19 | Agfa Ag Fur Photofabrikation | Process for the production of laterally non-reversed positive copies by heat development |
GB801053A (en) * | 1955-02-07 | 1958-09-03 | Agfa Ag | Process for the production of laterally non-reversed positive copies by heat development |
US2878121A (en) * | 1954-11-15 | 1959-03-17 | Du Pont | Photographic elements and processes |
-
1957
- 1957-12-10 DE DEL29247A patent/DE1080854B/en active Pending
-
1959
- 1959-12-18 GB GB43040/59A patent/GB921370A/en not_active Expired
-
1960
- 1960-01-19 FR FR816022A patent/FR1245422A/en not_active Expired
- 1960-02-10 US US7841A patent/US3211551A/en not_active Expired - Lifetime
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB614155A (en) * | 1939-11-02 | 1948-12-10 | Gevaert Photo Prod Nv | Improvements in and relating to photographic processes |
US2352014A (en) * | 1941-07-21 | 1944-06-20 | Rott Andre | Photomechanical printing process and printing material for carrying out the same |
US2412200A (en) * | 1941-09-12 | 1946-12-10 | Jr Robert D Blum | Hectograph mass |
DE1003578B (en) * | 1952-09-04 | 1957-02-28 | Zindler Lumoprint Kg | Process for producing photographic images and means for carrying out the same |
US2747999A (en) * | 1953-03-16 | 1956-05-29 | Eastman Kodak Co | Photographic reproduction process |
US2878121A (en) * | 1954-11-15 | 1959-03-17 | Du Pont | Photographic elements and processes |
GB801053A (en) * | 1955-02-07 | 1958-09-03 | Agfa Ag | Process for the production of laterally non-reversed positive copies by heat development |
US2971840A (en) * | 1955-02-07 | 1961-02-14 | Agfa Ag | Process for the production of nonlaterally reversed positive copies by heat development |
GB790811A (en) * | 1955-02-11 | 1958-02-19 | Agfa Ag Fur Photofabrikation | Process for the production of laterally non-reversed positive copies by heat development |
BE555103A (en) * | 1956-02-18 |
Also Published As
Publication number | Publication date |
---|---|
FR1245422A (en) | 1960-11-04 |
GB921370A (en) | 1963-03-20 |
DE1080854B (en) | 1960-04-28 |
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