US3203788A - Free machining steels of improved transverse mechanical properties and method of making same - Google Patents

Free machining steels of improved transverse mechanical properties and method of making same Download PDF

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Publication number
US3203788A
US3203788A US141002A US14100261A US3203788A US 3203788 A US3203788 A US 3203788A US 141002 A US141002 A US 141002A US 14100261 A US14100261 A US 14100261A US 3203788 A US3203788 A US 3203788A
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United States
Prior art keywords
steels
mechanical properties
free machining
making same
steel
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Expired - Lifetime
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US141002A
Inventor
Gustad P Contractor
David E C King
Robert J Mcclure
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Priority to US141002A priority Critical patent/US3203788A/en
Priority to GB33905/62A priority patent/GB975337A/en
Priority to ES280761A priority patent/ES280761A1/en
Priority to LU42387D priority patent/LU42387A1/xx
Application granted granted Critical
Publication of US3203788A publication Critical patent/US3203788A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00

Definitions

  • This invention relates to tree machining steels and method of making same.
  • resulphurized steels There are many types and grades of steels which fall within the classification of free machining steels and which possess the quality of machinability as the result of the addition of sulphur thereto and which are, therefore, frequently referred to as resulphurized steels.
  • resulphurized steels are the 1100 series of carbon steels, the 416 and 430E types in martensitic and ferritic stainless steels, the 303 type in austenitic stainless steels, and resulphurized high speed steels.
  • Another object of the invention is to provide a method of producing a resulphurized steel of desirable free machining quality and which possesses substantially unimpaired corrosion resistant and transverse mechanical properties.
  • Another object is to provide a resulphurized free machining steel which possesses higher quality surface characteristics and which does not sutier from decreased ductility whereby production operations, such as cold-heading, would be impaired.
  • uranium is added to the steel melt with the sulphur in the production of resulphurized steels in sufiicient quantity to react with the sulphur present to form uranium sulphides.
  • uranium sulphides are formed as small round or cubic particles which are present in the steel as small and widely dispersed, substantially evenly distributed inclusions, minimizing any directionality which would adversely affect transverse properties.
  • a method of producing a free machining resulphurized steel which comprises adding uranium with sulphur to the steel melt in a percentage thereof approximately 1 to 9 times that of sulphur present to react with substantially all of the sulphur present and form uranium sulphides.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Heat Treatment Of Steel (AREA)

Description

FREE MACHINEJG STEELS E IMPROVED TRANS- VERSE MECHANHCAL PRGPERTKES AND METH- UD (BE MAKTNG SAME Gustad P. IIontractor and David E. C. King, Ottawa, Ontario, and Robert .ll. McClure, Bells Corners, Ontario, Canada, assignors, by direct and mesne assignments, to Her Majesty The Queen in right of Canada as represented by the Minister of Mines and Technical Surveys No Drawing. Filed Sept. 27, 1961, Ser. No. 141,002
3 (Ilaiins. (Cl. 75-129) This invention relates to tree machining steels and method of making same.
There are many types and grades of steels which fall within the classification of free machining steels and which possess the quality of machinability as the result of the addition of sulphur thereto and which are, therefore, frequently referred to as resulphurized steels. Examples of such resulphurized steels are the 1100 series of carbon steels, the 416 and 430E types in martensitic and ferritic stainless steels, the 303 type in austenitic stainless steels, and resulphurized high speed steels.
The presence of the long stringers of iron manganese sulphides is a well known characteristic of these resulphurized steels, such stringers occurring as a result of the formation of these sulphides due to the addition of sulphur. It has long been recognized that the presence of these sulphide stringers in the steel results in inferior corrosion resistance, ductility and loss of surface quality, as well as poor transverse mechanical properties as a result of elongation of the sulphide stringers due to rolling and in the direction of such rolling, but these disadvantages have been universally accepted in compromise for greatly improved machinability.
It is an object of this invention to provide a resulphurized steel which is free from iron manganese sulphide stringers and which, as a result, possesses improved transverse mechanical properties.
Another object of the invention is to provide a method of producing a resulphurized steel of desirable free machining quality and which possesses substantially unimpaired corrosion resistant and transverse mechanical properties.
Another object is to provide a resulphurized free machining steel which possesses higher quality surface characteristics and which does not sutier from decreased ductility whereby production operations, such as cold-heading, would be impaired.
In accordance with the invention, uranium is added to the steel melt with the sulphur in the production of resulphurized steels in sufiicient quantity to react with the sulphur present to form uranium sulphides. These uranium sulphides are formed as small round or cubic particles which are present in the steel as small and widely dispersed, substantially evenly distributed inclusions, minimizing any directionality which would adversely affect transverse properties.
Since uranium possesses an afiinity for the sulphur present, the formation of stringers of iron manganese sulphides is substantially completely avoided.
33%,788 Patented Aug. 31, 1965 is not impaired.
The following table gives the results of elongation tests carried out in respect of Type 416 steels containing carbon about .10%, chromium about 12%, sulphur about 25% and uranium as indicated:
Ratio of Transverse to Longitudinal Elongation,
Percent Percent U added It will be observed that the addition of uranium to steels results in a transverse elongation approaching the longitudinal elongation and that, in the case of steel (4), the most favourable condition has been achieved in that the ratio is unity.
We claim:
1. A method of producing a free machining resulphurized steel which comprises adding uranium with sulphur to the steel melt in a percentage thereof approximately 1 to 9 times that of sulphur present to react with substantially all of the sulphur present and form uranium sulphides.
2. A method of producing a free machining resulphurized steel as defined in claim 1, wherein said uranium is added in a percentage approximately 2 to 5 times the percentage of sulphur present.
3. A method of producing a free machining resulphu'rized steel as defined in claim I wherein said uranium is added in a percentage approximately 7.5 times the percentage of sulphur present.
References Cited by the Examiner FOREIGN PATENTS 720,008 7/31 France.
OTHER REFERENCES Titanium in Iron and Steel, p. 41, edited by Comstock, pub. 1955 by John Wiley and Sons, Inc., New York.
DAVID L. RECK, Primary Examiner.
RAY K. WINDHAM, Examiner.

Claims (1)

1. A METHOD OF PRODUCING A FREE MACHINING RESULPHURIZED STEEL WHICH COMPRISES ADDING URANIUM WITH SULPHUR TO THE STEEL MELT IN A PERCENTAGE THEREOF APPROXIMATELY 1 TO 9 TIMES THAT OF SULPHUR PRESENT TO REACT WITH SUBSTANTIALLY ALL OF THE SULPHUR PRESENT AND FORM URANIUM SULPHIDES.
US141002A 1961-09-27 1961-09-27 Free machining steels of improved transverse mechanical properties and method of making same Expired - Lifetime US3203788A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US141002A US3203788A (en) 1961-09-27 1961-09-27 Free machining steels of improved transverse mechanical properties and method of making same
GB33905/62A GB975337A (en) 1961-09-27 1962-09-04 Free machining steels of improved transverse mechanical properties and method of making same
ES280761A ES280761A1 (en) 1961-09-27 1962-09-13 A procedure to produce a resulfilled steel of easy mechanization (Machine-translation by Google Translate, not legally binding)
LU42387D LU42387A1 (en) 1961-09-27 1962-09-19

Applications Claiming Priority (1)

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US141002A US3203788A (en) 1961-09-27 1961-09-27 Free machining steels of improved transverse mechanical properties and method of making same

Publications (1)

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US3203788A true US3203788A (en) 1965-08-31

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US141002A Expired - Lifetime US3203788A (en) 1961-09-27 1961-09-27 Free machining steels of improved transverse mechanical properties and method of making same

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US (1) US3203788A (en)
ES (1) ES280761A1 (en)
GB (1) GB975337A (en)
LU (1) LU42387A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3313620A (en) * 1963-02-18 1967-04-11 E I Te R S P A Elettochimica I Steel with lead and rare earth metals
US3948649A (en) * 1971-08-04 1976-04-06 Daido Seiko Kabushiki Kaisha Free cutting steel
US4383853A (en) * 1981-02-18 1983-05-17 William J. McCollough Corrosion-resistant Fe-Cr-uranium238 pellet and method for making the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR720008A (en) * 1930-07-22 1932-02-15 Krupp Ag Chemically neutral chrome-steel-nickel alloys

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR720008A (en) * 1930-07-22 1932-02-15 Krupp Ag Chemically neutral chrome-steel-nickel alloys

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3313620A (en) * 1963-02-18 1967-04-11 E I Te R S P A Elettochimica I Steel with lead and rare earth metals
US3948649A (en) * 1971-08-04 1976-04-06 Daido Seiko Kabushiki Kaisha Free cutting steel
US4383853A (en) * 1981-02-18 1983-05-17 William J. McCollough Corrosion-resistant Fe-Cr-uranium238 pellet and method for making the same

Also Published As

Publication number Publication date
LU42387A1 (en) 1962-11-19
GB975337A (en) 1964-11-18
ES280761A1 (en) 1963-03-01

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