US3160646A - Production of monoglycerides - Google Patents
Production of monoglycerides Download PDFInfo
- Publication number
- US3160646A US3160646A US142783A US14278361A US3160646A US 3160646 A US3160646 A US 3160646A US 142783 A US142783 A US 142783A US 14278361 A US14278361 A US 14278361A US 3160646 A US3160646 A US 3160646A
- Authority
- US
- United States
- Prior art keywords
- glycerol
- weight
- reaction
- monoglycerides
- glycerides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/02—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with glycerol
- C11C3/025—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with glycerol with a stoechiometric excess of glycerol
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
- C11C3/06—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with glycerol
Definitions
- This invention relates to new and useful improvements in the production of glycerldes.
- the invention more particularly relates to a novel process for the production of glyceride mixtures having a high content of monoglycerides.
- Monoglycerides constitute valuable commercial materials constituting excellent emulsifiers and are widely used for techrical purposes and in the food industry.
- Glycerides may be produced by the esterification of free fatty acids or the alcoholysis of fatty acid esters with glycerol.
- the glycerides so produced are in the form of a mixture which contains, in addition to the monoglycerides, a relatively large content of diand tri-glycerides.
- an equilibrium exists between glycerol, mono-, diand tri-glycerides which can only be shifted in favor of the valuable monoglycerides by'the presence of a large excess of glycerol.
- the shifting or the equilibrium in this manner is impeded by the relative irnmiscibility of glycerol and triglycerols and/ or glycerol and fatty acids.
- One object of this invention is a novel process for the production of glyceride mixtures having a high content of monoglycerides without the above-mentioned disadvantagcs.
- glyceride mixtures with an extraordinarily high content of monoglycerides may be obtained in 'a simple commercially feasible manner without the use of solvents or catalysts if the glycerol and fatty acids and/ or esters to be reacted are added at a carefully controlled rate with a controlled amount of glycerol to a reaction medium containing specific amounts of monoand di-glycerides under carefully controlled conditions of temperature.
- the reactants consist of glycerol and the conventional fatty acids and/ or fatty acid esters used in the production of glycerides.
- the glycerol must be present in a quantity with respect to the acids and/or esters so that there is at least two, as for example 2-6 mols of glycerol radicals present per mol of fatty acid radicals.
- the quantity should be such that there is about 3-5 mols of glycerol radicals per mol of fatty acid radicals.
- the glycerol and the fatty acids and/ or fatty acid esters are introduced into a reaction medium containing glycerol and monoglycerides at a rate of not more than 0.5 part by weight per hour per part by weight of the initial reaction medium.
- the glycerol and the fatty acids and/ or fatty acid esters could be introduced into the glycerol-glyceride reaction medium at a rate between about 0.15 and 0.5 and preferably 0.15-0.4 part by weight per hour per part of the initial reaction medium.
- the reaction medium into which the glycerol and fatty acid and/ or fatty acid esters is introduced at the controlled rate should contain at least 50 mol percent of glycerol, 10-35 mol percent of monoglycerides and not more than 15 mol percent as for example 5-15 of the higher glycerides, ie the diand triglycerides.
- the reaction should be effected at a temperature in excess of 260 degrees C., as for example between about 260- 300 degrees C.
- the reaction media into which the glycerol and acid or ester is introduced at the controlled rate should have a glyceride content of 30-20 mol percent and 21 glycerol content of 60-75 percent. If the content of diand tri-glycerides is high within the permissible maximum of 15 mol percent, it is desirable that the content of the glycerol be correspondingly greater.
- the fatty acids from which the glycerides used in the reaction medium are produced may be of a random origin. Particularly applicable are saturated or unsaturated C -C fatty acids of natural origin, such as, for example, occur in the fats of plants, land, and marine animals. Also suitable, however, are hydrogenation products of natural fatty acids as well as synthetic straight-or-branched chain fatty acids.
- the fatty acids which are added with glycerol constitute the same group of acids.
- esters of these acids with glycerol or other mono-or-polyvalent alcohols may be used.
- the alcohol component of these esters should be alcohols having a boiling point below the boiling point of glycerol as for example C alcohols as for example methyl alcohol, ethyl alcohol, ethyleneglycol, propylene glycol, etc.
- the monoglyceride used may be obtained from any source. Later the monoglycerides obtained according to the process itself may be used wherein also a part of the crude reaction product obtained in accordance with the invention may be recirculated so far as it has the necessary composition.
- the required mol ratio of fatty acid radicals to the glycerol radicals in the added glycerol and acid and/ or esters is independent of the form in which these are charged and preferably lies between 1:3 and 1:5. So far as, for example, the fatty acid is charged in the form of dior tri-glycerides, the glycerol introduced in this form must be also calculated since indeed it participates, like free glycerol, in the reaction.
- the reaction is carried out at temperatures of at least 260 degrees C. and preferably of at least 270 degrees C.
- glycerol distills off from the reaction mixture at the reaction temperature, it may be recirculated or supplemented through added fresh glycerol, so that the quantity of glycerol in the reaction mixture does not fall below the permissible minimum quantity.
- the maximum rate of introduction of the glycerol and acid and/ or ester varies somewhat with the working temperature. It amounts at high temperatures of, for example 280 degrees C., at most about 0.40.5 weight part per hour preferably 0.3 weight part per hour but decreases at lower temperatures, for example at 260 degrees C. to about 0.2-0.15 weight part per hour.
- the process may be carried out continuously or semi-continuously. In semi-continuous operation, a quantity of reaction medium is used which only fills a part of the reaction vessel.
- the quantity of the reaction medium increases and the rate of introduction may be correspondingly increased. It is advisable to provide for as rapid and vigorous a mixing as possible, as for example, through the use of effective stirrers.
- reaction chamber may be subdivided into several individual reaction vessels, through which the reacting mixture flows. Therein the first vessel may take on the function of a mixer. However, it is also possible to mount in a single reaction vessel installations of the most varied type, through which the reacting mixture is positively guided. Finally, narrow long reaction vessels may be used, such as for example, pipe-lines, pipe coils, etc.
- the formation of the monoglycerides may be accelerated through the use of conventional catalysts.
- the known acid, basic, or metallic esterification or alcoholysis catalysts are applicable.
- 1t is a particular advantage of the process in accordance with the invention that the esterification and/ or alcoholysis also takes place without catalysts with technically nteresting velocities.
- a separation of the catalysts is unnecessary and a soap-free monoglyceride is directly obtained, which is particularly well suited for use in the food industry. If, however, operation is effected with catalysts, it is advisable to cool the still hot reaction prod- 65 uct as rapidly as possible, or to inactivate the catalyst before the cooling.
- the crude alcoholysis mixture separates after the coolmg into two layers: the lower layer consists essentially of glycerol, which may be recirculated, the upper layer contains besides the high-percentage monoglyceride which may be 80 percent by weight and more based on the glycerides, up to 30 percent and preferably -25 percent free glycerol. This may be separated. in customary manner, for example through distillation, wherein, however,
- glycerol may also be removed by washing with salt solutions or by washing with water. The washing with water has been described more in detail in the German prepublication of Patent DAS 1,066,573.
- Example 2 The drawn off reaction product, after cooling, separated into a monoglyceride-containing upper phase and a lower phase essentially consisting of glycerol, which was recirculated into the process. After separation of the glycerol dissolved in the monoglyceridecontaining phase, the monoglyceride content amounted to 79 weight percent; the Acid Number of the product was Example 2
- the mixture was heated to 270 degrees C. and 10 weight parts fatty acid and 21 weight parts glycerol were added per hour.
- the product isolated from the raw product had a monoglyceride
- Example 3 A mixture of 37 weight percent monolaurin, 7 weight parts dilaurin, 1 weight part trilaurin and weight parts glycerol (18.2 molpercent monolaurin, 79.8 mol percent glycerol) was used as the starting material. The mixture was heated to a temperature of 270 degrees C. and 12 parts by weight lauric acid and 28 weight parts glycerol were added per hour. The product obtained after processing had a monolaurin content of 86 weight percent; the Acid Number was 0.7
- Example 4 A mixture of 57 weight parts mono-olein, 17 weight parts di-olein, 1 weight part triolein and 25 weight parts glycerol (34.1 mol percent mono-olein, 57.9 mol percent glycerol) was heated to- 280 degrem C. and olive oil and glycerol were added at an hourly rate of 14 and 16 parts by weight respectively. The product obtained after the processing of the crude reaction product had a mono glyceride content of 78 weight percent.
- Example 5 To the mixture of lauric acid glycerides mentioned in Example 3, 13 weight parts lauric-acid-methyl-ester and 27 weight parts glycerol per hour were added at a temperature of 270 degrees C. The methanol liberated in the re-esterification distilled oii through the air cooler and was condensed in the descending water cooler. I The technical monoglyceride obtained after the processing had a monolaurin content of 87 weight percent.
- the improvement for the production of a glyceride mixture with a high content of monoglycerides which comprises maintaining a reaction medium containing at least 50-mol percent of glycerol, 35 mol percent of monoglycerides, and not more than mol percent of higher glycerides at a temperature between about 260300 C.
- reaction medium contains about 20-30 mol percent of monoglycerides and -75 mol percent of glycerol.
- said ester is selected from the group consisting of methyl and glycerol esters of fatty acids.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEH40631A DE1206881B (de) | 1960-10-11 | 1960-10-11 | Verfahren zur Herstellung von Fettsaeureglycerid-gemischen mit hohem Monoglyceridgehalt |
Publications (1)
Publication Number | Publication Date |
---|---|
US3160646A true US3160646A (en) | 1964-12-08 |
Family
ID=7154316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US142783A Expired - Lifetime US3160646A (en) | 1960-10-11 | 1961-10-04 | Production of monoglycerides |
Country Status (7)
Country | Link |
---|---|
US (1) | US3160646A (de) |
BE (1) | BE609023A (de) |
DE (1) | DE1206881B (de) |
DK (1) | DK118714B (de) |
FR (1) | FR1316499A (de) |
GB (1) | GB950667A (de) |
NL (1) | NL270102A (de) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6127561A (en) * | 1997-08-19 | 2000-10-03 | Global Palm Products Sdn. Bhd. | Process for the production of monoglyceride based on the glycerolysis of methyl ester |
US20050048187A1 (en) * | 2003-06-04 | 2005-03-03 | Jim Doucet | Shortening system |
US20090017181A1 (en) * | 2003-08-21 | 2009-01-15 | Jim Doucet | Shortening system |
US20100148117A1 (en) * | 2008-12-11 | 2010-06-17 | Logan Roger L | Method of making glycerol monoesters |
KR102043442B1 (ko) * | 2019-02-01 | 2019-11-11 | 주식회사 천강 | 지방산 및 유리지방산을 다량 함유한 유지를 촉매를 사용하지 않고 바이오디젤 원료용 저산가 글리세라이드를 제조하는 방법 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU66093A1 (de) * | 1972-09-15 | 1974-03-25 | ||
AU2002347198B2 (en) * | 2001-12-13 | 2008-04-17 | Jott Australia Pty Ltd | Process for production of fatty acid esters |
WO2017085737A1 (en) * | 2015-11-19 | 2017-05-26 | Fine Research & Development Centre Pvt Ltd | A natural based monoglyceride with improved odor and flavor |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2383581A (en) * | 1943-05-06 | 1945-08-28 | Colgate Palmolive Peet Co | Process for preparing fatty materials |
US2478354A (en) * | 1946-04-26 | 1949-08-09 | Colgate Paimolive Peet Company | Preparation of partial esters |
US2634278A (en) * | 1949-07-16 | 1953-04-07 | Eastman Kodak Co | Process for substantially complete conversion of fatty material to partial ester |
US2732387A (en) * | 1956-01-24 | Method of making monoglycerides | ||
US2744124A (en) * | 1952-11-28 | 1956-05-01 | Colgate Palmolive Co | Process for preparing fatty acid partial esters of polyhydric alcohols |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2022494A (en) * | 1935-02-14 | 1935-11-26 | Armour & Co | Process of preparing mono and di-glycerides |
US2759954A (en) * | 1949-02-02 | 1956-08-21 | Chemical Foundation Inc | Refining crude fatty acid monoglyceride |
FR980205A (fr) * | 1949-02-07 | 1951-05-09 | Paix & Cie | Procédé de préparation de produits mouillants, moussants, détergents et m?lsion nants |
US2634279A (en) * | 1949-07-16 | 1953-04-07 | Eastman Kodak Co | Preparation of monoglycerides |
US2727913A (en) * | 1952-10-11 | 1955-12-20 | Eastman Kodak Co | Method of obtaining concentrated monoglycerides |
US2789119A (en) * | 1954-02-09 | 1957-04-16 | Boake Roberts & Co Ltd | Production of fatty acid monoglycerides |
-
1960
- 1960-10-11 DE DEH40631A patent/DE1206881B/de active Pending
-
1961
- 1961-09-19 GB GB33446/61A patent/GB950667A/en not_active Expired
- 1961-09-27 FR FR874325A patent/FR1316499A/fr not_active Expired
- 1961-10-04 US US142783A patent/US3160646A/en not_active Expired - Lifetime
- 1961-10-10 DK DK401761AA patent/DK118714B/da unknown
- 1961-10-10 NL NL270102A patent/NL270102A/xx unknown
- 1961-10-11 BE BE609023A patent/BE609023A/fr unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2732387A (en) * | 1956-01-24 | Method of making monoglycerides | ||
US2383581A (en) * | 1943-05-06 | 1945-08-28 | Colgate Palmolive Peet Co | Process for preparing fatty materials |
US2478354A (en) * | 1946-04-26 | 1949-08-09 | Colgate Paimolive Peet Company | Preparation of partial esters |
US2634278A (en) * | 1949-07-16 | 1953-04-07 | Eastman Kodak Co | Process for substantially complete conversion of fatty material to partial ester |
US2744124A (en) * | 1952-11-28 | 1956-05-01 | Colgate Palmolive Co | Process for preparing fatty acid partial esters of polyhydric alcohols |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6127561A (en) * | 1997-08-19 | 2000-10-03 | Global Palm Products Sdn. Bhd. | Process for the production of monoglyceride based on the glycerolysis of methyl ester |
US20050048187A1 (en) * | 2003-06-04 | 2005-03-03 | Jim Doucet | Shortening system |
US20090017181A1 (en) * | 2003-08-21 | 2009-01-15 | Jim Doucet | Shortening system |
US20100148117A1 (en) * | 2008-12-11 | 2010-06-17 | Logan Roger L | Method of making glycerol monoesters |
KR102043442B1 (ko) * | 2019-02-01 | 2019-11-11 | 주식회사 천강 | 지방산 및 유리지방산을 다량 함유한 유지를 촉매를 사용하지 않고 바이오디젤 원료용 저산가 글리세라이드를 제조하는 방법 |
Also Published As
Publication number | Publication date |
---|---|
DE1206881B (de) | 1965-12-16 |
NL270102A (de) | |
FR1316499A (fr) | 1963-02-01 |
GB950667A (en) | 1964-02-26 |
DK118714B (da) | 1970-09-28 |
BE609023A (fr) | 1962-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS611640A (ja) | 短鎖アルコールの脂肪酸エステルの製法 | |
ITMI971837A1 (it) | Processo di fabbricazione di esteri a partire da oli vegetali o animali e da alcoli | |
US4004041A (en) | Production of liquid edible oil from palm oil or similar oils | |
US3160646A (en) | Production of monoglycerides | |
US2206168A (en) | Process for manufacturing fatty esters | |
JP2013139433A (ja) | 脂肪酸モノグリセライド含有混合物の製造方法。 | |
US2750429A (en) | Continuous hydrogenation of fatty material | |
DE69313068T2 (de) | Verfahren zur Herstellung von Methylmethacrylat | |
US3634473A (en) | Process for manufacture of symmetrical glycerides | |
JPH0114901B2 (de) | ||
US2744124A (en) | Process for preparing fatty acid partial esters of polyhydric alcohols | |
US5254722A (en) | Process for the production of triglycerides | |
IE47316B1 (en) | Process for the manufacture of fatty acid nitriles and glycerol from glycerides,especially from natural fats and oils | |
US2874175A (en) | Process for making fatty acid diglyceride, diesters of dibasic acids | |
US3907884A (en) | Formic acid synthesis by lower alkyl formate hydrolysis | |
US3878231A (en) | Acylation of symmetrical diglycerides with fatty acid anhydride | |
US1944887A (en) | Esters and method of preparing same | |
US2378007A (en) | Process of modifying the molecular structure of oils and fats | |
US2794043A (en) | Preparation of aliphatic nitriles | |
US2759954A (en) | Refining crude fatty acid monoglyceride | |
US2931797A (en) | Mixed methyl glucoside-glycerol fatty acid ester emulsifiers | |
US3755385A (en) | Preparation of fatty acid ester mixtures enriched in unsaturates | |
US3040075A (en) | Method of making fatty alkanol amides | |
US3068206A (en) | Polyester synthetic resin reaction system | |
US3512994A (en) | Method for the preparation of confectioners' fats |