US3144209A - Rotatable spray apparatus - Google Patents

Rotatable spray apparatus Download PDF

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Publication number
US3144209A
US3144209A US146527A US14652761A US3144209A US 3144209 A US3144209 A US 3144209A US 146527 A US146527 A US 146527A US 14652761 A US14652761 A US 14652761A US 3144209 A US3144209 A US 3144209A
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United States
Prior art keywords
spray head
annular
series
discharge holes
feed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US146527A
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English (en)
Inventor
Edward H Griffiths
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CBS Corp
Original Assignee
Westinghouse Electric Corp
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Filing date
Publication date
Application filed by Westinghouse Electric Corp filed Critical Westinghouse Electric Corp
Priority to US146527A priority Critical patent/US3144209A/en
Priority to DEW29048U priority patent/DE1927123U/de
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Publication of US3144209A publication Critical patent/US3144209A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B3/00—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements
    • B05B3/02—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements
    • B05B3/10—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements discharging over substantially the whole periphery of the rotating member, i.e. the spraying being effected by centrifugal forces
    • B05B3/1057—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements discharging over substantially the whole periphery of the rotating member, i.e. the spraying being effected by centrifugal forces with at least two outlets, other than gas and cleaning fluid outlets, for discharging, selectively or not, different or identical liquids or other fluent materials on the rotating element
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/025—Discharge apparatus, e.g. electrostatic spray guns
    • B05B5/04—Discharge apparatus, e.g. electrostatic spray guns characterised by having rotary outlet or deflecting elements, i.e. spraying being also effected by centrifugal forces
    • B05B5/0403—Discharge apparatus, e.g. electrostatic spray guns characterised by having rotary outlet or deflecting elements, i.e. spraying being also effected by centrifugal forces characterised by the rotating member
    • B05B5/0411—Discharge apparatus, e.g. electrostatic spray guns characterised by having rotary outlet or deflecting elements, i.e. spraying being also effected by centrifugal forces characterised by the rotating member with individual passages at its periphery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00—Concentrating evaporators
    • Y10S159/09—Two liquids dried simultaneously
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00—Concentrating evaporators
    • Y10S159/17—Two liquids

Definitions

  • This invention relates in general to a rotatable spray head, a spray apparatus and method of spraying liquid coating materials therewith. More particularly, it relates to a rotatable foraminous spray head and associated apparatus adapted for the simultaneous centrifugal spraying and electrostatic deposition of a plurality of liquid coating materials.
  • this invention accomplishes the foregoing objects with a rotatable spray head having a series of discharge holes located on a plurality of concentric circles.
  • a plurality of radially located circular flanges extend rearwardly from the discharge holes so that they provide a feed surface for each series of holes. Feeding of the dissimilar coating materials is accomplished by providing separate feed means for each flange feed surface. Speckled or multi-colored finishes are applied by appropriately selecting the size, number, location and angle of the discharge holes and the speed of rotation to provide a spray that preserves the individual characteristics of each ma terial without the homogenization and loss of identity inherent in complete atomization.
  • the efiiciency of deposition is increased by electrically charging the spray head with a high voltage and grounding the article to be coated.
  • FIGURE 1 is a view in elevation, partly in section, of a spray apparatus
  • FIG. 2 is an end view of the rotatable spray head illustrated in FIG. 1,
  • FIG. 3 is a view in elevation, partly in section illustrating a portion of the apparatus of FIG. 1 with another type of rotatable spray head,
  • FIG. 4 is an end view of the spray head illustrated in FIG. 3,
  • FIG. 5 is a view in elevation, partly in section, illustrating a portion of the apparatus of FIG. 1, with another type of rotatable spray head, and,
  • FIG. 6 is an end view of the spray head illustrated in FIG. 5.
  • FIG. 1 there is illustrated the electrostatic spray apparatus 10, embodying the rotatable spray head 30 of this invention, adapted for centrifugally and simultaneously spraying a plurality of coating materials and adapted to apply an electrical charge to the sprayed particles.
  • An accurately regulated driving means 11 which may, for example, be an air motor, is connected. to a rotatable shaft 12, formed of two sections, an electrical insulating section 13 and an electrical conducting section 14.
  • the spray head 3t is rigidly fixed to the conducting section 14 and held in place by the cap nut 15.
  • the electrical insulating section 13 may be a solid shaft member prepared from convolutely wound sheets of kraft paper impregnated and bonded together with a cured thermoset phenolic resin. Such insulating materials are available commercially under the proprietary name Micarta.
  • a stationary sleeve or tube 16 prepared from electrical insulating material, encloses at least a major portion of the shaft 12 so that the apparatus may be handled and held without danger of electrical shock.
  • the tube 16 may be prepared from the phenolic impregnated kraft paper described heretofore for making the shaft section 13.
  • the rotatable shaft 12 is supported within the tube 16 by bearings 17 and 18.
  • One side of a high voltage source 19 is electrically connected to the terminal 20 when employed for electro static spraying applications.
  • the terminal 20 is electrically connected to hearing 17 and to the spray head 30 through the conductive shaft section 14.
  • the spray head 39 is made from an electrically conductive material such as steel, aluminum, brass, copper or the like so that the discharged sprayed coating particles are negatively charged.
  • the other side of the high voltage source 19 is connected to ground.
  • the high voltage source When energized the high voltage source establishes an electric field between the rotatable spray head 30 and the surface of an article (not shown) to be coated.
  • Appropriate electrical controls (not shown) permit application of the high-voltage from a remote position by an operator at ground potential.
  • the articles, the surfaces of which are to be coated are preferably maintained at ground potential, and can be passed into and through a zone where the coating material is applied thereto by well known conveyor means.
  • FIGS. 1 and 2 there is illustrated two series of discharge holes or apertures 31, 32 located on concentric circles 33, 34 and extending directly through the forward plate or disc 36 from the rearward surface or side 4-3 of the rotatable spray head 30 to the exterior side or external forward surface or side 44.
  • a plurality of circular flanges 37, 38 extend rearwardly from the forward plate and are flared inwardly toward the axis of rotation of the shaft and spray head. Radially, the flanges are located so that they each enclose a series of discharge holes.
  • Each flange 37, 38 provides an annular feed surface 39, 40.
  • the annular feed surfaces 39, 40 are sloped inwardly toward the axis of rotation at an angle of from about 15 to about 45 to the axis of rotation to provide a uniform flow of liquid coating material to the discharge holes 31, 32 and to prevent the possible undesirable discharge of liquid coatings from the back side of the spray head.
  • the discharge holes are located as close as possible to the inner flange feed surface. It is preferred, therefore to locate the discharge holes so that the outermost edge of the hole coincides with the feed surface. If the holes are circular, for example, it is preferred that they be tangent to the feed surface. For descriptive purposes, it may be said that the annular surface is junctured or connected to the forward plate.
  • discharge holes may then be described as bordered by the annular surface or it may be said that the juncture of the annular surface to the forward plate and the discharge holes are juxtaposed.
  • the center line of the discharge holes be parallel to the feed surface. It will be understood, of course, that the spray head is operable with the holes located a short distance from the feed surface and with the center line of the holes not parallel to the inner feed surface.
  • the individual series of holes need not be exactly located in a circular pattern, although such an arrangement is preferred.
  • the liquid coating materials to be sprayed are supplied to the annular feed surfaces 39, 40 of the circular flanges 38, 39 at a controlled rate by means of feed tubes 41 and 42, respectively.
  • the tubes 41, 42 are preferably rigid and may be constructed, for example, from steel tubing.
  • the coating materials can be supplied through the feed tubes by an convenient means such as a pump, pressure pot or merely by gravity. It is preferred to position the feed tubes to point in the direction of rotation of the head to minimize splashing or loss of coating material. Dissimilar materials may be supplied to different feed tubes.
  • the structure of the head provides separate annular compartments or channels for each material and prevents mixing of the individual coating materials.
  • Example I A spray head with a forward plate about six inches in diameter is constructed from aluminum.
  • the exterior circular flange has an axial dimension of two inches
  • the interior circular flange has an axial dimension of one inch.
  • a series of 16 equally spaced inch holes is drilled through the forward plate so that the center lines of the holes are parallel to the annular feed surface of the outer circular flange and so that the annular feed surface is tangent to the holes.
  • a series of 8 equally spaced inch holes in drilled adjacent to the interior circular flange.
  • Distance between the flanges is approximately 2 inches. Both flanges flare inwardly toward the axis at an angle of about 30.
  • the feed tubes are located adjacent the inner feed surfaces of the flanges, as illustrated in FIG. 1.
  • two contrasting colored paints are individually supplied through the feed tubes at a rate of /2 to 4 ozs. of paint per minute, depending on conveyor speed, to the rotating head.
  • the paint viscosity is from 25 to 35 seconds in a Zahn No. 2 cup.
  • the spray head is rotated at a speed of about 300 to about 600 rpm. Speeds greater than 600 rpm. will atomize the paints to such a degree that the speckled multi-color effect is not visible to the naked eye.
  • the article to be coated is located 10 to 14 inches from the spray head.
  • the voltage impressed on the spray head is in the order of 60,000 to 90,000 volts.
  • the article is grounded. A discontinuous multi-colored speckled finish is satisfactorily attained.
  • FIGS. 3 and 4 Another version of the spray head is illustrated in FIGS. 3 and 4. With the three circular flanges 51, 52 and 53, the three concentric series of discharge holes 54, 55 and 56 and the three feed tubes 57, 58 and 59, three dissimilar coating materials may be applied simultaneously.
  • FIGS. and 6 Another mode of constructing a spray head according to this invention is illustrated in FIGS. and 6.
  • a spray head 60 with a relatively thick forward plate 61 The outer circular flange 62 is similar to the flanges illustrated heretofore.
  • the inner circular flange 63 may, however, be easily formed by machining or cutting away a portion of the forward plate 51.
  • the feed holes 64 65 are similar to those previously described.
  • a spray head with any practical number of flanges, annular feed surfaces, discharge holes and feed tubes may be constructed according to this invention.
  • Incompatible or immiscible coating materials such as lacquer and enamel may be simultaneously sprayed and deposited. While the spray head is especially adapted for the application of a plurality of different materials, it will also be understood that a single coating ma terial may be sprayed from each head flange and deposited according to this invention.
  • a rotatable spray head adapted for rotation about an axis comprising a plate having a rearward surface and an external forward surface and at least one series of discharge holes extending through the plate from said rearward to said forward surface, at least one circular flange having an annular feed surface, the annular surface joining said rearward surface to form a juncture therewith, the annular surface flaring inwardly from said juncture at an angle of from about 15 to about 45 to the axis of rotation, a series of the discharge holes being disposed radially inwardly from said juncture.
  • a rotatable spray head adapted for rotation about an axis comprising a forward plate having a rearward surface and an external forward surface and a plural series of discharge holes extending through the plate from said rearward to said forward surface, a plurality of circular flanges extending from said rearward surface, each flange having an annular surface joined to said plate to form a juncture therewith, the annular surfaces flaring inwardly from said junctures at an angle of from about 15 to about 45 to the axis of rotation, each series of said discharge holes located so that said holes are disposed radially inwardly from said juncture.
  • a rotatable spray head adapted for rotation about an axis comprising a forward plate having a first and second series of discharge holes projecting therethrough from one side to an exterior side of the plate, first and second circular flanges extending from said plate, each flange having an annular feed surface joined to said plate to form first and second junctures therewith, the annular surfaces flaring inwardly from said junctures at an angle of about 15 to 45 to the axis of rotation, the discharge holes being so located that the first series and said first juncture are juxtaposed and so that the second series and said second juncture are juxtaposed.
  • a rotatable spray head adapted for rotation about an axis comprising a forward plate having a rearward surface and an external forward surface and at least one series of discharge holes extending through the plate from said rearward to said forward surface, at least one circular flange having an annular feed surface, the annular surface joining said rearward surface to form a juncture therewith, the annular surface flaring inwardly from said juncture at an angle of from about 15 to about 45 to the axis of rotation, the series of discharge holes being located so thatsaid holes and said juncture are juxtaposed, means for supplying liquid coating material to said annular surface, means for rotating the head to cause the liquid to form a film on said annular surface and to flow to and through said discharge holes and means including a high voltage source electrically connected to said head to electrically charge the discharged liquid.
  • a rotatable spray head adapted for rotation about an axis comprising a forward plate having a plural series of discharge holes extending therethrough from one side to an exterior side of the plate, a plurality of circular flanges extending from said plate, each flange having an annular surface joined to said plate to form a juncture therewith, the annular surfaces flaring inwardly from said junctures at an angle of from about 15 to about 45 to the axis of rotation, each series of said discharge holes located so that said holes and said junctures are juxtaposed, means for supplying a liquid coating material to each of said annular surfaces, means for rotating the head to cause the materials to form a film on said annular surfaces and to flow to and through said discharge holes and means including a high voltage source electrically connected to said head to electrically charge the discharged liquids.
  • a rotatable spray head adapted for rotation about an axis comprising a forward plate having a first and a second series of discharge holes projecting therethrough from one side to an exterior side, first and second circular flanges extending from said plate, each flange having an annular feed surface joined to said plate to form first and second junctures therewith, the annular surfaces flaring inwardly from said junctures at an angle of about 15 to 45 to the axis of rotation, the discharge holes being so located that the first series and said first juncture are juxtaposed and so that the second series and said second juncture are juxtaposed, means for simultaneously supplying liquid coating materials to each of said annular surfaces, means for rotating the head to cause the materials to form a film on each of said annular surfaces and to flow to and through said discharge holes and means including a high voltage source electrically connected to said head to electrically charge the discharged liquids.
  • a rotatable spray head for simultaneously spraying a plurality of liquids comprising, in combination, a disc having an internal rearward surface and an external for ward surface, means cooperating with said rearward surface to define a plurality of annular feed surfaces, discharge apertures extending directly through said disc and adapted to provide liquid communication between each annular feed surface and the external forward face of said disc and means for simultaneously supplying a liquid to each annular feed surface.
  • a rotatable spray head adapted for rotation about an axis comprising a disc having an internal rearward surface and an external forward surface, a plural series of apertures extending directly through said disc from the rearward to the forward surface, means providing an annular feed surface for each series of apertures, the annular feed surfaces being flared inwardly toward the axis and adapted to supply liquid to each of said series of apertures and means for simultaneously supplying liquid to each annular feed surface.
  • a rotatable spray head adapted for rotation about an axis comprising a disc having an internal rearward surface and an external forward surface, plural series of apertures extending directly through said disc from the rearward. to the forward surface, means providing an annular feed surface for each series of apertures, the annular feed surfaces being flared inwardly toward the axis and adapted to supply liquid to each of said series of apertures, means for simultaneously supplying liquid to each annular feed surface, means for rotating the head to cause the liquid to form a film on said annular surface and to flow to and through said apertures and means including a high voltage source electrically connected to said head to electrically charge the discharged liquid.

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  • Electrostatic Spraying Apparatus (AREA)
US146527A 1961-10-20 1961-10-20 Rotatable spray apparatus Expired - Lifetime US3144209A (en)

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US146527A US3144209A (en) 1961-10-20 1961-10-20 Rotatable spray apparatus
DEW29048U DE1927123U (de) 1961-10-20 1962-09-19 Elektrostatische spruehvorrichtung.

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3224680A (en) * 1964-06-11 1965-12-21 Ford Motor Co Atomizing apparatus having a liquid accumulation cavity
US3313489A (en) * 1965-03-05 1967-04-11 Amchem Prod Rotating lawn sprayer nozzle having depending cylindrical deflecting surfaces
US3327948A (en) * 1964-07-07 1967-06-27 Cosmic Inc Method of electrostatic coating including velocity reduction
US3342415A (en) * 1963-02-19 1967-09-19 Sames Sa De Machines Electrost Electrostatic coating system
US3342418A (en) * 1962-11-15 1967-09-19 Wallis Neil Rudolph Coating apparatus
US3343981A (en) * 1963-11-29 1967-09-26 Northern Electric Co Colour coding apparatus
US3411715A (en) * 1964-03-31 1968-11-19 Wallis Neil Rudolph Centrifugal electrostatic spraying head
US3481546A (en) * 1966-12-02 1969-12-02 Niro Atomizer As Atomizer wheel for simultaneously atomizing two components
US3504851A (en) * 1967-06-15 1970-04-07 Villamos Automatika Intezet Electrostatic spray gun
US3667676A (en) * 1969-03-26 1972-06-06 Nippon Kogei Kogyo Co Apparatus for electrostatically coating powders on a workpiece
US3900164A (en) * 1973-03-08 1975-08-19 Norsk Hydro As Means for feeding fluid materials to a prilling bucket
DE3000002A1 (de) * 1980-01-02 1981-07-09 Ernst Mueller Gmbh & Co, 7057 Winnenden Elektrostatische farbspritzpistole mit rotationszertaeuber
US4511084A (en) * 1983-05-12 1985-04-16 Won Vann Y Top feeding liquid atomizer
US4785995A (en) * 1986-03-18 1988-11-22 Mazda Motor Corporation Methods and apparatus for conducting electrostatic spray coating
DE4024805C1 (de) * 1990-08-04 1992-02-06 Metallgesellschaft Ag, 6000 Frankfurt, De
US5133499A (en) * 1987-03-23 1992-07-28 Behr Industrieanlagen Gmbh & Co. Rotary atomizer with turbine motor
US5156336A (en) * 1989-12-27 1992-10-20 Xerox Corporation Multiple fluid injection nozzle array for rotary atomizer
US20110056431A1 (en) * 2004-09-13 2011-03-10 Basf Aktiengesellschaft Method for the production of composite elements based on isocyanate-based foams
FR3055106A1 (fr) * 2016-08-20 2018-02-23 Sprai Dispositif d'injection du liquide pour atomiseur a disque rotatitf

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1853682A (en) * 1927-05-18 1932-04-12 Chemical Construction Corp Atomizing apparatus
AT170850B (de) * 1948-07-10 1952-03-25 Hauser & Cie Ag Neumuehle Toes Vorrichtung zum Zerstäuben von Flüssigkeiten
US2809902A (en) * 1951-08-09 1957-10-15 Ransburg Electro Coating Corp Method and apparatus for electrostatically coating articles
FR1184756A (fr) * 1957-10-10 1959-07-24 Dispositif pour le contrôle de l'allumage des moteurs à explosion
US2975756A (en) * 1958-02-26 1961-03-21 Gen Motors Corp Electrostatic paint spray
US3063642A (en) * 1959-03-31 1962-11-13 Sames Mach Electrostat Rotating heads for electrostatic atomizing and spraying apparatus

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1853682A (en) * 1927-05-18 1932-04-12 Chemical Construction Corp Atomizing apparatus
AT170850B (de) * 1948-07-10 1952-03-25 Hauser & Cie Ag Neumuehle Toes Vorrichtung zum Zerstäuben von Flüssigkeiten
US2809902A (en) * 1951-08-09 1957-10-15 Ransburg Electro Coating Corp Method and apparatus for electrostatically coating articles
FR1184756A (fr) * 1957-10-10 1959-07-24 Dispositif pour le contrôle de l'allumage des moteurs à explosion
US2975756A (en) * 1958-02-26 1961-03-21 Gen Motors Corp Electrostatic paint spray
US3063642A (en) * 1959-03-31 1962-11-13 Sames Mach Electrostat Rotating heads for electrostatic atomizing and spraying apparatus

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3342418A (en) * 1962-11-15 1967-09-19 Wallis Neil Rudolph Coating apparatus
US3342415A (en) * 1963-02-19 1967-09-19 Sames Sa De Machines Electrost Electrostatic coating system
US3343981A (en) * 1963-11-29 1967-09-26 Northern Electric Co Colour coding apparatus
US3411715A (en) * 1964-03-31 1968-11-19 Wallis Neil Rudolph Centrifugal electrostatic spraying head
US3224680A (en) * 1964-06-11 1965-12-21 Ford Motor Co Atomizing apparatus having a liquid accumulation cavity
US3327948A (en) * 1964-07-07 1967-06-27 Cosmic Inc Method of electrostatic coating including velocity reduction
US3313489A (en) * 1965-03-05 1967-04-11 Amchem Prod Rotating lawn sprayer nozzle having depending cylindrical deflecting surfaces
US3481546A (en) * 1966-12-02 1969-12-02 Niro Atomizer As Atomizer wheel for simultaneously atomizing two components
US3504851A (en) * 1967-06-15 1970-04-07 Villamos Automatika Intezet Electrostatic spray gun
US3667676A (en) * 1969-03-26 1972-06-06 Nippon Kogei Kogyo Co Apparatus for electrostatically coating powders on a workpiece
US3900164A (en) * 1973-03-08 1975-08-19 Norsk Hydro As Means for feeding fluid materials to a prilling bucket
DE3000002A1 (de) * 1980-01-02 1981-07-09 Ernst Mueller Gmbh & Co, 7057 Winnenden Elektrostatische farbspritzpistole mit rotationszertaeuber
US4511084A (en) * 1983-05-12 1985-04-16 Won Vann Y Top feeding liquid atomizer
US4785995A (en) * 1986-03-18 1988-11-22 Mazda Motor Corporation Methods and apparatus for conducting electrostatic spray coating
US5133499A (en) * 1987-03-23 1992-07-28 Behr Industrieanlagen Gmbh & Co. Rotary atomizer with turbine motor
US5156336A (en) * 1989-12-27 1992-10-20 Xerox Corporation Multiple fluid injection nozzle array for rotary atomizer
DE4024805C1 (de) * 1990-08-04 1992-02-06 Metallgesellschaft Ag, 6000 Frankfurt, De
US20110056431A1 (en) * 2004-09-13 2011-03-10 Basf Aktiengesellschaft Method for the production of composite elements based on isocyanate-based foams
US8578876B2 (en) * 2004-09-13 2013-11-12 Basf Aktiengesellschaft Method for the production of composite elements based on isocyanate-based foams
FR3055106A1 (fr) * 2016-08-20 2018-02-23 Sprai Dispositif d'injection du liquide pour atomiseur a disque rotatitf

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Publication number Publication date
DE1927123U (de) 1965-11-11

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