US3097830A - Mining methods and systems including caving to relieve pressure - Google Patents

Mining methods and systems including caving to relieve pressure Download PDF

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US3097830A
US3097830A US60054A US6005460A US3097830A US 3097830 A US3097830 A US 3097830A US 60054 A US60054 A US 60054A US 6005460 A US6005460 A US 6005460A US 3097830 A US3097830 A US 3097830A
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mining
trona
area
rooms
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Robert F Love
Thomas S Bernatis
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FMC Corp
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21CMINING OR QUARRYING
    • E21C41/00Methods of underground or surface mining; Layouts therefor
    • E21C41/16Methods of underground mining; Layouts therefor
    • E21C41/24Methods of underground mining; Layouts therefor for oil-bearing deposits

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  • the trona deposits in Sweetwater County and adjacent counties in Wyoming consist of a main trona bed having a varying thickness up to about 16 feet, averaging more nearly 7 to 13 feet, located at a depth of about 1500 to 1800 feet underground and of several thinner beds. Only the main trona bed is mined. Because of its great depth below the surface and its relative hardness, the main Wyoming trona bed is difficult to ⁇ mine and this difficulty is increased by the fact that the main ltrona bed is stronger th-an the formation above yand below it.
  • the main trona bed lies substantially horizontal.
  • the overlying strata are also horizontal in attitude and are chiefly composed of unconsolidated shales and fine grained sandstones.
  • the 400 feet of strata immediately above the main trona bed are mainly weak, laminated grey shales and oil shale, and fan approximately 8 -foot bed of somewhat plastic oil shale lies immedi-ately below the main trona bed.
  • the comparative strength of the main trona bed and of the overlying and underlying shale layers in average values is substantially as follows:
  • vtrona mining essentially comprises xemoving the only strong layer in the formation and leaving an essentially -weak roof that is incapable of supporting itself over large spans, while the plastic shale immediately below the trona bed is pushed upward into the mine cavity when the overlying wei-ght, effecting vertical compression of the plastic shale, is relieved by the removal of la portion of the trona bed in the mining operation.
  • the trona is mined from secondary entries by the roomand-pillar method commonly used in mining coal. Normally in mining the pillars, rooms fifteen feet wide are first driven at right angles to the secondary development. Several rooms are started at the extreme end of the development entries with the room closest to the unmined trona bed being completed slightly before the others.
  • the rooms are spaced about 50 -to 60 feet apart and 'the resulting pillar between them is extracted.
  • the extraction is normally done by driving lifts twenty feet wide through the pillars starting from the ends of the rooms farthest from the development entry.
  • the lifts are usually driven at right angles to the rooms, and hence parallel to the secondary development entries, and are separated from the mined out area by a narrow fender of-trona, fixe feet or less in thickness.
  • the next parallel lift is started, also leaving a five foot fender between it ⁇ and the previously caved section until it is completed, and this process is repeated until the entire pillar has been drawn and the roof thereover caved.
  • the rooms are driven in a direction at right angles away from the entries and the pillars are extracted by lifts at right angles to the rooms or parallel to the entries moving back toward the entires, or on the retreat.
  • the roofs of all entries rooms and lifts are supported by roof bolts, preferably on four foot centers, which are removed as much 4as possible before caving. Timbering is used whenever necessary.
  • One of the objects of this invention is to provide a method of still fur-ther reducing overburden pressures introna mining pillar extraction areas which will reduce the mining hazards land provide safer mining conditions.
  • Another object of the invention is to provide va methodof protecting the pillar extraction areas from premature or unplanned caving which will reduce the previous cost of timbering .and permit complete pillar extraction before necessity for abandoning :a give area.
  • FIG. 2 is a section view on an enlarged scale along'V the line A-A of FIG. 1; and' 4 FIG. 3 is a section view through a larger area of the formation also substantially on the line A--A of FIG. 1.
  • FIG. l a four entry secondary development panel 1 consisting of entries 1a, 1b, 1c and 1d has been driven into the trona mining area 2 and communicates at the left side of the drawing with the main development entries (not shown), through which the men, machines and supplies, etc. are brought into the mine and the mined trona removed.
  • a belt conveyor 3 is shown in entry 1c on which mined trona brought from the active mining areas 2 is deposited for conveyance out of the mine.
  • the previously caved panel area is shown at 4 and the freshly caved areas adjacent the active mining operation is shown at 5.
  • rooms 6 and ⁇ 6a are iirst driven at right angles to the secondary development entry 1d, through the bed of trona, to the old caved panel 4, and rooms 7 and 7a are immediately driven parallel to and between the rst rooms 6 and 6a and the caved ground 5 from the freshly completed pillar extraction operation.
  • the rooms 6 and 7 and 6a and 7a are usually left separated by approximately ten foot pillars 1S and a.
  • the pillar 8 between the room 7 and the previous mining operation is shown in the process of being mined. Mining of the pillar 8a is started when room 7a is completed to caved area 4. As the pillars 8, 8a, etc. are being mined by retreat on the entries 1, 1a, 1b and 1c, the supporting pillars 9 left between the entries are also extracted to remove the trona therein and cave the secondary development panel area 1a, 1b, 1c, etc., as well as the room-and-pillar area 8, 8a, etc. The mining of the room pillars 8, 8a, etc. is conducted slightly in advance of the mining of the entry pillars 9.
  • Ventilation of the Working areas is carried out through entries 1a, 1b, 1c and 1d, and when it is desired to ventilate the caved area 5, as required by some mining laws, it is best to leave one row of pillars in place so that air may be conducted through entry 1a and the cross entries therefrom into the caved area 5. In this manner, fresh air is kept circulating through the cave areas.
  • the rooms 6, 6a, etc. are left untimbered. These rooms then cave Within a few days after they are driven, with the caving extending sufficiently far up into the overburden 10, as indicated at 11, to break the weight of the overburden on the unmined trona layers 12 so that the pressure on the alternate rooms 7 and 7a and theV pillars 8 and 8a is reduced suiciently to permit mining of the pillars 8 and 8a without undue hazards and costs.
  • the majority of the roof failures and iloor heaving takes place in the first rooms 6 and 6a and the second rooms 7 and 7a remain relatively good and pillar extraction between the rooms 7 or 7a and the previously mined area may proceed under much more safe and workable conditions. Any roof bolts installed in rooms 6 and 6a are recovered if this can be done safely.
  • FIG. 2 shows a partial cross section through the mine area and indicates, by the arrows 11, how a portion of the overburden has been caved into the rooms ⁇ 6 and 6a to partially break the superincumbent effect of the overburden over the unmined portions 12 of the trona bed.
  • the trona layer is approximately 1500 to 1800 feet below the earths surface.
  • This figure illustrates the theory of the invention.
  • the shale beam roofs of the rooms are weak and will not support much overburden weight before cracking and beginning to cave. Part of the superincumbent weight of the overburden of the roofs must be supported by the pillars 8 and 8a on the abutments formed by the vertical walls of these pillars, and the amount of superincumbent overburden weight that the pillars 8 and 8a must support is a function of the percentage of extraction of the pillars.
  • the method of mining trona by the room-and-pillar system and of relieving overburden pressure on the pillar extraction area which comprises ⁇ driving two substantially parallel rooms spaced approximately l0 feet apart between the active pillar extraction area and the unmined trona area, caving the room nearest the unmined trona area, extracting the pillar in the pillar extraction area from the parallel room nearest the pillar extraction area and when the pillars have been extracted caving the roof over the pillar extraction area and 4advancing the mine in the ⁇ direction of the unmined trona area by driving two further parallel rooms spaced approximately l0 feet apart between the pillar area to be extracted and the unmined trona area, caving the room nearest the unmined trona area and extracting the pillar in the pillar extraction area from the uncaved room between the caved room and the pillar extraction area and continuing this process in advancing the mine in the direction of the unmined trona area.
  • the method of mining trona and relieving overburden pressure in the mining operation which comprises driving two adjacent rooms into the trona bed between the active mining area and the unmined trona area, the said rooms being close enough so that upon caving the room adjacent the unmined trona area the overburden pressure will be reduced to avoid unplanned, premature caving in the active mining area, caving the room adjacent the unmined trona area and, mining the pillars in the active mining area from the uncaved room.
  • the method of mining trona and relieving overburden pressure in the mining operation which comprises driving two adjacent rooms into the trona bed between the active mining area and the unmined trona area, the said rooms being close enough so that upon caving the room adjacent the unmined trona area the overburden pressure will be reduced to avoid unplanned, premature caving in the active mining area, caving the room adjacent the unmined trona area, mining the pillars in the active mining area from the uncaved room and caving the roof over the pillars in the active mining area as the pillars are mined.

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  • Engineering & Computer Science (AREA)
  • Mining & Mineral Resources (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Remote Sensing (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Excavating Of Shafts Or Tunnels (AREA)

Description

July 16, 1963 R. F. LOVE ETAL MINING METHODS AND SYSTEMS INCLUDING GAMING ID RELIEVE PRESSURE 2 Sheets-Sheet l Filed 001.. 3. 1960 July' 16, 1963 R. F. LovE ETAL MINING METHODS AND SYSTEMS INCLUDING CAVING TO RELIEVE PRESSURE 2 Sheets-Sheet 2 Filed OCT.. I5. 1960 NEEN Wu United States Patent O 3,097,830 MINING METHODS AND SYSTEMS INCLUDING CAVING TO RELIEVE PRESSURE Robert F. Love, Rowayton, Conn., and Thomas S. Bernatis, Rock Springs, Wyo., assignors to FMC Corporation, New York, N.Y., a corporation of Delaware Filed Oct. 3, 1960, Ser. No. 60,054 4 Claims. (Cl. 262-1) This invent-ion relates to the mining of trona as found in Sweetwater County and adjacent counties in southwestern Wyoming and in similar {tron-a deposits found elsewhere.
The trona deposits in Sweetwater County and adjacent counties in Wyoming consist of a main trona bed having a varying thickness up to about 16 feet, averaging more nearly 7 to 13 feet, located at a depth of about 1500 to 1800 feet underground and of several thinner beds. Only the main trona bed is mined. Because of its great depth below the surface and its relative hardness, the main Wyoming trona bed is difficult to` mine and this difficulty is increased by the fact that the main ltrona bed is stronger th-an the formation above yand below it.
The main trona bed lies substantially horizontal. The overlying strata are also horizontal in attitude and are chiefly composed of unconsolidated shales and fine grained sandstones. The 400 feet of strata immediately above the main trona bed are mainly weak, laminated grey shales and oil shale, and fan approximately 8 -foot bed of somewhat plastic oil shale lies immedi-ately below the main trona bed.
The comparative strength of the main trona bed and of the overlying and underlying shale layers in average values is substantially as follows:
Where the trona supporting layer is completely removed as in a mining tunnel or by drawing a pil-lar, neither the roof shale nor the floor shale have suicient strength to sustain the addi-tional burden placed thereon. The roof shale therefore caves and the floor shale heaves into the mining cavities.
These conditions make conventional mining operations very difricult because unlike coal and similar mining operations under a slate, compacted sandstone or other firmly compacted roof, vtrona mining essentially comprises xemoving the only strong layer in the formation and leaving an essentially -weak roof that is incapable of supporting itself over large spans, while the plastic shale immediately below the trona bed is pushed upward into the mine cavity when the overlying wei-ght, effecting vertical compression of the plastic shale, is relieved by the removal of la portion of the trona bed in the mining operation.
In past Wyoming trona mining operations, it has been the practice to mine essentially rectangular tunnels in the trona formation according to the conventional roomand-pillar mining system by shear ycutting and drilling the trona mining face and blasting out the trona.
The trona is mined from secondary entries by the roomand-pillar method commonly used in mining coal. Normally in mining the pillars, rooms fifteen feet wide are first driven at right angles to the secondary development. Several rooms are started at the extreme end of the development entries with the room closest to the unmined trona bed being completed slightly before the others.
ICC
The rooms are spaced about 50 -to 60 feet apart and 'the resulting pillar between them is extracted. The extraction is normally done by driving lifts twenty feet wide through the pillars starting from the ends of the rooms farthest from the development entry. The lifts are usually driven at right angles to the rooms, and hence parallel to the secondary development entries, and are separated from the mined out area by a narrow fender of-trona, fixe feet or less in thickness. When Ea lift is completed, [the fender is removed by blasting and the unsupported roof, adjacent the previously mined out and caved tarea, will cave. Thus the mined out areas are caved to relieve the roof Iand floor pressure adjacent the mined out areas soon 'after the extraction of each section of a pillar is finished.
When one lift has been driven and the blasted, the next parallel lift is started, also leaving a five foot fender between it `and the previously caved section until it is completed, and this process is repeated until the entire pillar has been drawn and the roof thereover caved. The rooms are driven in a direction at right angles away from the entries and the pillars are extracted by lifts at right angles to the rooms or parallel to the entries moving back toward the entires, or on the retreat. Prior to caving, .the roofs of all entries, rooms and lifts are supported by roof bolts, preferably on four foot centers, which are removed as much 4as possible before caving. Timbering is used whenever necessary.
Due to the great depth of the trona beds and the overburden weight, the unplanned roof failures and floor heaving in the pillar extraction areas have become so excess-ive as to make the mining opera-tion very hazardous fand costly, requiring elaborate timbering in some instances and in other instances requiring the abandonment of mining in specific areas before all the pillars have been drawn.
One of the objects of this invention is to provide a method of still fur-ther reducing overburden pressures introna mining pillar extraction areas which will reduce the mining hazards land provide safer mining conditions.
Another object of the invention is to provide va methodof protecting the pillar extraction areas from premature or unplanned caving which will reduce the previous cost of timbering .and permit complete pillar extraction before necessity for abandoning :a give area. 1
Other objects and advantages of the invention will appear as this description proceeds. p
We have found that part of the pressure on the pillar extraction areas is due to the superincumbent overburden weight `and that the pillars act as abutments in the working area or room. This excess overburden pressure can be reduced or dispatched to other more remote areas by driving a room between the room used for mining the active pillar extraction area and the still unmined trona area and permitting this first room to cave so that the caving extends a substantial distance up into the overburden. After caving of a room between the activemining area and the unmined trona area or pillar, the pillar can be extracted by driving another room very close to the Vcaved room, and lifts can then be driven to the cave line and the pillar removed. In this manner,v pressure on the active pillar extraction area is reduced and mining conditions rendered less hazardous and mining less costly.
FIG. 2 is a section view on an enlarged scale along'V the line A-A of FIG. 1; and' 4 FIG. 3 is a section view through a larger area of the formation also substantially on the line A--A of FIG. 1.
Patented July 16, 1963 fenderV As illustrated in FIG. l, a four entry secondary development panel 1 consisting of entries 1a, 1b, 1c and 1d has been driven into the trona mining area 2 and communicates at the left side of the drawing with the main development entries (not shown), through which the men, machines and supplies, etc. are brought into the mine and the mined trona removed. A belt conveyor 3 is shown in entry 1c on which mined trona brought from the active mining areas 2 is deposited for conveyance out of the mine. The previously caved panel area is shown at 4 and the freshly caved areas adjacent the active mining operation is shown at 5.
In applying the principles of our invention rooms 6 and `6a are iirst driven at right angles to the secondary development entry 1d, through the bed of trona, to the old caved panel 4, and rooms 7 and 7a are immediately driven parallel to and between the rst rooms 6 and 6a and the caved ground 5 from the freshly completed pillar extraction operation. The rooms 6 and 7 and 6a and 7aare usually left separated by approximately ten foot pillars 1S and a. While two rooms 6 and 6a and two alternate rooms 7 and 7a (one not completed) have been shown to better illustrate the application of our invention, it will be understood that the mining operation may be moved backward in the direction of mining indicated by the arrow 12, one pillar at a time, in which case only one room 6 will be driven and one alternate room 7, and after the pillar 8 between the room 7 and the previous mining area 5 has been completely extracted and the area caved, a second room 6a and a second alternate room 7a is driven and the new pillar 8a is mined.
The pillar 8 between the room 7 and the previous mining operation is shown in the process of being mined. Mining of the pillar 8a is started when room 7a is completed to caved area 4. As the pillars 8, 8a, etc. are being mined by retreat on the entries 1, 1a, 1b and 1c, the supporting pillars 9 left between the entries are also extracted to remove the trona therein and cave the secondary development panel area 1a, 1b, 1c, etc., as well as the room-and- pillar area 8, 8a, etc. The mining of the room pillars 8, 8a, etc. is conducted slightly in advance of the mining of the entry pillars 9.
Ventilation of the Working areas is carried out through entries 1a, 1b, 1c and 1d, and when it is desired to ventilate the caved area 5, as required by some mining laws, it is best to leave one row of pillars in place so that air may be conducted through entry 1a and the cross entries therefrom into the caved area 5. In this manner, fresh air is kept circulating through the cave areas.
The rooms 6, 6a, etc. are left untimbered. These rooms then cave Within a few days after they are driven, with the caving extending sufficiently far up into the overburden 10, as indicated at 11, to break the weight of the overburden on the unmined trona layers 12 so that the pressure on the alternate rooms 7 and 7a and theV pillars 8 and 8a is reduced suiciently to permit mining of the pillars 8 and 8a without undue hazards and costs. The majority of the roof failures and iloor heaving takes place in the first rooms 6 and 6a and the second rooms 7 and 7a remain relatively good and pillar extraction between the rooms 7 or 7a and the previously mined area may proceed under much more safe and workable conditions. Any roof bolts installed in rooms 6 and 6a are recovered if this can be done safely.
FIG. 2 shows a partial cross section through the mine area and indicates, by the arrows 11, how a portion of the overburden has been caved into the rooms `6 and 6a to partially break the superincumbent effect of the overburden over the unmined portions 12 of the trona bed.
As indicated in FIG. 3, which is a diagrammatic crosssection through the formation, the trona layer is approximately 1500 to 1800 feet below the earths surface. This figure illustrates the theory of the invention. The shale beam roofs of the rooms are weak and will not support much overburden weight before cracking and beginning to cave. Part of the superincumbent weight of the overburden of the roofs must be supported by the pillars 8 and 8a on the abutments formed by the vertical walls of these pillars, and the amount of superincumbent overburden weight that the pillars 8 and 8a must support is a function of the percentage of extraction of the pillars.
When the first rooms 6 and 6a cave as shown by arrows 13a, it is believed that horizontal pressures and deformations towards the caved rooms cause the extra superincumbent fweight that the pillars 8 and 8a must bear to move back to more solid and confined ground in the direction of arrow 13. This effects an apparent pressure relief in the vicinity of the deliberately caved rooms 6 or 6a as the horizontal confining stress, which normally opposes Poissons ratio applied to the vertical weight, can not develop in this region. In this manner, any vertical Weight is transmitted away from the mining area due to the deformation of the soft shale beds towards the caved areas.
While we have shown a preferred embodiment of our invention yand set forth certain theories as to why we believe the caving of rooms 6 and 6a relieves the pressure on the :active mining areas, we have in any event found this to be the fact regardless of whether the theories advanced herein are correct or not. It will be understood that the invention can be practiced in other ways than according to the preferred embodiment herein illustrated and that various modifications and changes can be made in active mining operations within the spirit of our invention and the scope of the following claims.
We claim:
1. The method of mining trona by the room-and-pillar system and of relieving overburden pressure on the pillar extraction area, which comprises `driving two substantially parallel rooms spaced approximately l0 feet apart between the active pillar extraction area and the unmined trona area, caving the room nearest the unmined trona area, extracting the pillar in the pillar extraction area from the parallel room nearest the pillar extraction area and when the pillars have been extracted caving the roof over the pillar extraction area and 4advancing the mine in the `direction of the unmined trona area by driving two further parallel rooms spaced approximately l0 feet apart between the pillar area to be extracted and the unmined trona area, caving the room nearest the unmined trona area and extracting the pillar in the pillar extraction area from the uncaved room between the caved room and the pillar extraction area and continuing this process in advancing the mine in the direction of the unmined trona area.
2. The method of mining trona and relieving overburden pressure in the mining operation which comprises driving two adjacent rooms into the trona bed between the active mining area and the unmined trona area, the said rooms being close enough so that upon caving the room adjacent the unmined trona area the overburden pressure will be reduced to avoid unplanned, premature caving in the active mining area, caving the room adjacent the unmined trona area and, mining the pillars in the active mining area from the uncaved room.
3. The method of mining trona and relieving overburden pressure in the mining operation which comprises driving two adjacent rooms into the trona bed between the active mining area and the unmined trona area, the said rooms being close enough so that upon caving the room adjacent the unmined trona area the overburden pressure will be reduced to avoid unplanned, premature caving in the active mining area, caving the room adjacent the unmined trona area, mining the pillars in the active mining area from the uncaved room and caving the roof over the pillars in the active mining area as the pillars are mined.
4. 'I'he method of mining trona by the room and pillar system and of relieving overburden pressure on the pillar the pillars in the pillar extraction area from the room yadjacent to the active mining area.
References Cited in the le of this patent UNITED STATES PATENTS Gr-ifth Sept. 26, 1911 Bucky Aug. 5, 1958

Claims (1)

  1. 2. THE METHOD OF MINING TRONA AND RELIEVING OVERBURDEN PRESSURE IN THE MINING OPERATION WHICH COMPRISES DRIVING TWO ADJACENT ROOMS INTO THE TRONA BED BETWEEN THE ACTIVE MINING AREA AND THE UNMINED TRONA AREA, THE SAID ROOMS BEING CLOSE ENOUGH SO THAT UPON CAVING THE ROOM ADJACENT THE UNMINED TRONA AREA THE OVERBURDEN PRESSURE WILL BE REDUCED TO AVOID UNPLANNED, PREMATURE CAVING IN THE ACTIVE MINING AREA, CAVING THE ROOM ADJACENT THE UNMINED TRONA AREA AND, MINING THE PILLARS IN THE ACTIVE MINING AREA FROM THE UNCAVED ROOM.
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3934935A (en) * 1974-08-26 1976-01-27 Bechtel International Corporation Hydraulic mining of oil bearing formation
US4084384A (en) * 1976-09-13 1978-04-18 Shosei Serata Advanced slot stress control method of underground excavation
US4265570A (en) * 1979-06-01 1981-05-05 Conoco, Inc. Mine roof control
US4307978A (en) * 1978-11-30 1981-12-29 Mitsui Sekitan Kogyo Kabushiki Kaisha Method of relieving earth pressure in a working area
US4465401A (en) * 1981-06-15 1984-08-14 In Situ Technology, Inc. Minimizing subsidence effects during production of coal in situ
US5766270A (en) * 1996-05-21 1998-06-16 Tg Soda Ash, Inc. Solution mining of carbonate/bicarbonate deposits to produce soda ash
US5955043A (en) * 1996-08-29 1999-09-21 Tg Soda Ash, Inc. Production of sodium carbonate from solution mine brine
US6322767B1 (en) 1996-05-21 2001-11-27 Fmc Corporation Process for making sodium carbonate decahydrate from sodium carbonate/bicarbonate liquors
CN102322262A (en) * 2011-09-12 2012-01-18 山东科技大学 Colliery isolated island coal column crossheading bump control method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1004418A (en) * 1911-03-06 1911-09-26 William Griffith Method of mining.
US2846205A (en) * 1952-04-19 1958-08-05 Philip B Bucky Mining method for supporting geological structures

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1004418A (en) * 1911-03-06 1911-09-26 William Griffith Method of mining.
US2846205A (en) * 1952-04-19 1958-08-05 Philip B Bucky Mining method for supporting geological structures

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3934935A (en) * 1974-08-26 1976-01-27 Bechtel International Corporation Hydraulic mining of oil bearing formation
US4084384A (en) * 1976-09-13 1978-04-18 Shosei Serata Advanced slot stress control method of underground excavation
US4307978A (en) * 1978-11-30 1981-12-29 Mitsui Sekitan Kogyo Kabushiki Kaisha Method of relieving earth pressure in a working area
US4265570A (en) * 1979-06-01 1981-05-05 Conoco, Inc. Mine roof control
US4465401A (en) * 1981-06-15 1984-08-14 In Situ Technology, Inc. Minimizing subsidence effects during production of coal in situ
US5766270A (en) * 1996-05-21 1998-06-16 Tg Soda Ash, Inc. Solution mining of carbonate/bicarbonate deposits to produce soda ash
US6251346B1 (en) 1996-05-21 2001-06-26 Tg Soda Ash, Inc. Solution mining of carbonate/bicarbonate deposits to produce soda ash
US6322767B1 (en) 1996-05-21 2001-11-27 Fmc Corporation Process for making sodium carbonate decahydrate from sodium carbonate/bicarbonate liquors
US5955043A (en) * 1996-08-29 1999-09-21 Tg Soda Ash, Inc. Production of sodium carbonate from solution mine brine
CN102322262A (en) * 2011-09-12 2012-01-18 山东科技大学 Colliery isolated island coal column crossheading bump control method

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