US3093146A - Process for permanent setting of living hair by surface active compounds - Google Patents
Process for permanent setting of living hair by surface active compounds Download PDFInfo
- Publication number
- US3093146A US3093146A US798805A US79880559A US3093146A US 3093146 A US3093146 A US 3093146A US 798805 A US798805 A US 798805A US 79880559 A US79880559 A US 79880559A US 3093146 A US3093146 A US 3093146A
- Authority
- US
- United States
- Prior art keywords
- hair
- setting
- surface active
- active compounds
- permanent waving
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
Definitions
- the hairdressers final purpose is in effect to realize by a hair disposition a style of hair-dressing adapted to the up to date taste and to the treated hair; such disposition is socalled a setting in the art.
- the hairdresser arranges Wet hair, previously curled by the permanent waving, in locks which he rolls at his will and dries when the whole of the operation is completed.
- the present invention aims to simplify and facilitate the hairdressers work for such hair setting which constitutes the essential part of his art, owing to the fact that it makes unnecessary the previous permanent waving proper of the hair and that it makes it possible to accomplish the hair setting in a single opera-tion while giving to the hair a better lasting which extends the duration of the hair-dressing in a noticeable manner.
- This invention has for a primary object a hair setting process eliminating any previous permanent waving, charaoterized by the fact that the hair is impregnated with an aqueous solution of a compound having a reducing effect analogous to that of mercaptans, so as to impart to the hair the desired plasticity, and having moreover the characteristics of a cation-active detergent which cleans the hair and comprises a fatty chain susceptible of adhering to the cleaned hair while giving the same a brightness and a suppleness which facilitate the hair setting, that such hair setting is performed after rinsing of the hair and that the hair is air dried so as to permit an oxidation which gives again to the set hair its natural elasticity.
- the present invention has for another object to provide a cation aotive addition salt of an amine, comprising a thiol group reducing the keratin disulphide bridges to put into practice the aforementioned hair setting process, said salt being characterized by the fact that it belongs to the general formula:
- R is a hydrogen atom or a lower alkyl radical comprising not more than 6 carbon atoms
- R" is a lower alkyl radical, any either of substituents 'R, R' being selected from hydrogen and a lower alkyl radical and the other being a water repelling fatty radical having from 8 to 24 carbon atoms and X being an acid anion harmless to the live hair and to the scalp.
- the compound according to this invention may be used advantageously in the state of an addition salt obtained by reacting this compound with an inorganic or organic acid.
- one object of the present invention is to provide a process for making a cation-active compound of the aforementioned Formula (I), characterized by the fact that it consists in bringing into reaction equimolecular amount of a mercaptan having the general formula:
- the reduced bridges SS- in a relatively low number by the application of these reducing surfaceactive products, may be rebuilt by the sole action of the oxygen of air during the conventional operations of drying in a draught, under a helmet, without using an oxidizing solution as in the case of a permanent waving.
- foaming cationic detergent properties allow them to be applied as a shampoo as it is applied in a conventional manner previously to the purely manual operation of hair-setting; so as to avoid, in particular, when first applied, any excessive dilution by water, after which the hair is rinsed and the hair-setting and drying operations are elfected according to the usual practice.
- the efiiciency of the amide formation may be increased by reacting under the same conditions as those mentioned above new amounts of ethyl thioglycolate, once or twice, taking into consideration the amount of non reacted amine.
- the product may be purified by using its insoluble cadmium salt (by reacting cadmium acetate) which can be separated and decomposed later by hydrogen sulphide.
- the practically pure product is thus obtained in the form of an aqueous solution.
- This product having an 85% purity was directly treated with lactic acid. There was obtained a gel, which was dissolved in water at a 30% to 35% concentration. This solution is used as a shampoo.
- An improved process for setting living hair without submitting the hair to a previous permanent waving which comprises, impregnating the hair with an aqueous solution of an addition salt of a member of the group consisting of the organic and inorganic acid salts of a compound having a general formula wherein R is a member of the group consisting of a hydrogen atom and a lower alkyl radical having not more than 6 carbon atoms, R" is a lower alkyl radical, and one of the substituents R and R is selected from the group consisting of a hydrogen atom and a lower alkyl radical, the other being a water repelling fatty acid radical having from 8 to 24 carbon atoms, the organic and inorganic acids being harmless to the live hair and to the scalp, said addition salt having a reducing action analogous to that of mercaptans, so as to impart to the hair the desired plasticity and having moreover the characteristics of a cation-active detergent which cleans the hair and com prises a fatty chain susceptible to adhere to the cleaned hair
- An improved process for setting live hair without submitting the hair to previous permanent waving which comprises, impregnating the hair with an aqueous solution of an addition salt of lactic acid, with a compound having a general formula wherein R is a member of the group consisting of a hydrogen atom and a lower alkyl radical having not more than 6 carbon atoms, R is a lower alkyl radical, and one of the substituents R and R, is selected from the group consisting of a hydrogen atom and a lower alkyl radical, the other being a water repelling fatty acid radical having from 8 to 24 carbon atoms, rinsing the hair so impregnated, separating the hair into individual locks, setting the hair in the form desired and allowing the hair to dry so as to permit oxidation to impart to the hair in a set condition its natural elasticity.
- An improved process for setting hair without submitting the hair to previous permanent waving which comprises impregnating the hair with an aqueous solution containing an addition salt of lactic acid with mercapto- N-lauryl-N-(Z-diethylaminoethyl) acetamide, rinsing the so impregnated hair, separating the hair into individual locks, setting the hair in the form desired and air drying the same to permit oxidation to impart to the hair in a set condition its natural elasticity.
- An improved process for setting hair without submitting the hair to previous permanent waving which comprises, impregnating the hair with an aqueous solution containing an addition salt of lactic acid with mercapto N (2 methyl,2 lauryl,aminoethyl) acetamide, rinsing the so impregnated hair, separating the hair into individual locks, setting the hair in the form desired and allowing the hair to dry so as to permit oxidation to impart to the hair in a set condition its natural elasticity.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR760586 | 1958-03-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3093146A true US3093146A (en) | 1963-06-11 |
Family
ID=8705985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US798805A Expired - Lifetime US3093146A (en) | 1958-03-14 | 1959-03-12 | Process for permanent setting of living hair by surface active compounds |
Country Status (7)
Country | Link |
---|---|
US (1) | US3093146A (fr) |
BE (1) | BE576566A (fr) |
CH (2) | CH401083A (fr) |
DE (1) | DE1150491B (fr) |
FR (1) | FR1193289A (fr) |
GB (1) | GB891600A (fr) |
NL (1) | NL111194C (fr) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4098811A (en) * | 1976-12-02 | 1978-07-04 | Ciba-Geigy Corporation | Perfluoroalkylthioamido amine and ammonium compounds |
US4567198A (en) * | 1983-02-07 | 1986-01-28 | Roussel Uclaf | Ethanethioates and mercaptoamides and use thereof as analgesic and enkephalinase inhibitory compounds |
FR2636841A1 (fr) * | 1988-09-29 | 1990-03-30 | Seiwa Kasei Co Ltd | Composition pour l'ondulation permanente des cheveux |
US4973475A (en) * | 1988-10-07 | 1990-11-27 | Revlon, Inc. | Hair treatment and conditioning agents |
US5091573A (en) * | 1990-08-11 | 1992-02-25 | Rohm And Haas Company | Thiol-terminated hydroxyamides |
US5247125A (en) * | 1990-08-11 | 1993-09-21 | Rohm And Haas Company | Thiol-terminated hydroxyamides |
FR2692481A1 (fr) * | 1992-06-23 | 1993-12-24 | Oreal | Composition cosmétique réductrice pour la déformation permanente des cheveux à base d'un mercaptoalkylamino-amide et procédé de déformation permanente des cheveux. |
EP0712633A1 (fr) * | 1994-11-18 | 1996-05-22 | Izhak Blank | Compositions pharmaceutiques pour l'application topique |
US20070225611A1 (en) * | 2006-02-06 | 2007-09-27 | Kumar Uday N | Non-invasive cardiac monitor and methods of using continuously recorded cardiac data |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2654617B1 (fr) * | 1989-11-20 | 1993-10-08 | Oreal | Composition cosmetique reductrice pour permanente contenant, en tant qu'agent reducteur, de l'aletheine ou l'un de ses sels, et son utilisation dans un procede de deformation permanente des cheveux. |
DE19732079C1 (de) * | 1997-07-25 | 1999-02-04 | Wella Ag | Gesättigte, alkylsubstituierte N-Mercaptoacetyl-Heterocyclen, Mittel und Verfahren zur dauerhaften Haarverformung auf deren Basis |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2577710A (en) * | 1941-06-16 | 1951-12-04 | Procter & Gamble | Permanent waving compositions and methods |
US2714119A (en) * | 1953-08-07 | 1955-07-26 | Sterling Drug Inc | Process for preparing amides of alphamercapto lower fatty acids |
US2792307A (en) * | 1953-07-20 | 1957-05-14 | Universal Oil Prod Co | Stabilization of organic compounds |
US2817342A (en) * | 1953-12-17 | 1957-12-24 | Colgate Palmolive Co | Method of permanently reshaping a keratin-containing substance |
US2869559A (en) * | 1957-10-07 | 1959-01-20 | Procter & Gamble | Non-volatile mercaptan and hydroxyamine impregnated end wrap and method of use |
-
1958
- 1958-03-14 FR FR1193289D patent/FR1193289A/fr not_active Expired
-
1959
- 1959-03-09 GB GB8134/59A patent/GB891600A/en not_active Expired
- 1959-03-11 NL NL236977A patent/NL111194C/xx active
- 1959-03-11 BE BE576566A patent/BE576566A/fr unknown
- 1959-03-12 US US798805A patent/US3093146A/en not_active Expired - Lifetime
- 1959-03-13 CH CH1671664A patent/CH401083A/fr unknown
- 1959-03-13 CH CH7075359A patent/CH387229A/fr unknown
- 1959-03-13 DE DES62136A patent/DE1150491B/de active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2577710A (en) * | 1941-06-16 | 1951-12-04 | Procter & Gamble | Permanent waving compositions and methods |
US2792307A (en) * | 1953-07-20 | 1957-05-14 | Universal Oil Prod Co | Stabilization of organic compounds |
US2714119A (en) * | 1953-08-07 | 1955-07-26 | Sterling Drug Inc | Process for preparing amides of alphamercapto lower fatty acids |
US2817342A (en) * | 1953-12-17 | 1957-12-24 | Colgate Palmolive Co | Method of permanently reshaping a keratin-containing substance |
US2869559A (en) * | 1957-10-07 | 1959-01-20 | Procter & Gamble | Non-volatile mercaptan and hydroxyamine impregnated end wrap and method of use |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4098811A (en) * | 1976-12-02 | 1978-07-04 | Ciba-Geigy Corporation | Perfluoroalkylthioamido amine and ammonium compounds |
US4567198A (en) * | 1983-02-07 | 1986-01-28 | Roussel Uclaf | Ethanethioates and mercaptoamides and use thereof as analgesic and enkephalinase inhibitory compounds |
FR2636841A1 (fr) * | 1988-09-29 | 1990-03-30 | Seiwa Kasei Co Ltd | Composition pour l'ondulation permanente des cheveux |
EP0361391A2 (fr) * | 1988-09-29 | 1990-04-04 | Seiwa Kasei Co., Ltd. | Composition pour onduler les cheveux |
US5116608A (en) * | 1988-09-29 | 1992-05-26 | Seiwa Kasei Co., Ltd. | Permanent waving composition |
EP0361391A3 (fr) * | 1988-09-29 | 1990-12-27 | Seiwa Kasei Co., Ltd. | Composition pour onduler les cheveux |
US5071441A (en) * | 1988-10-07 | 1991-12-10 | Revlon, Inc. | Hair treatment and conditioning agents |
US4973475A (en) * | 1988-10-07 | 1990-11-27 | Revlon, Inc. | Hair treatment and conditioning agents |
US5091573A (en) * | 1990-08-11 | 1992-02-25 | Rohm And Haas Company | Thiol-terminated hydroxyamides |
US5247125A (en) * | 1990-08-11 | 1993-09-21 | Rohm And Haas Company | Thiol-terminated hydroxyamides |
FR2692481A1 (fr) * | 1992-06-23 | 1993-12-24 | Oreal | Composition cosmétique réductrice pour la déformation permanente des cheveux à base d'un mercaptoalkylamino-amide et procédé de déformation permanente des cheveux. |
EP0577473A1 (fr) * | 1992-06-23 | 1994-01-05 | L'oreal | Composition cosmétique réductrice pour la déformation permanente des cheveux à base d'un mercaptoalkylamino-amide et procédé de déformation permanente des cheveux |
EP0712633A1 (fr) * | 1994-11-18 | 1996-05-22 | Izhak Blank | Compositions pharmaceutiques pour l'application topique |
US20070225611A1 (en) * | 2006-02-06 | 2007-09-27 | Kumar Uday N | Non-invasive cardiac monitor and methods of using continuously recorded cardiac data |
Also Published As
Publication number | Publication date |
---|---|
NL111194C (fr) | 1965-05-17 |
CH401083A (fr) | 1965-10-31 |
FR1193289A (fr) | 1959-11-02 |
BE576566A (fr) | 1959-09-11 |
GB891600A (en) | 1962-03-14 |
DE1150491B (de) | 1963-06-20 |
CH387229A (fr) | 1965-01-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69002739T2 (de) | Reduzierende Zusammensetzung zur dauerhaften Haarverformung, die als reduzierendes Agens ein Aminomercaptoalkylamid oder eines seiner Salze enthält sowie ihre Verwendung in einem Verfahren zur dauerhaften Haarverformung. | |
DE68903212T2 (de) | 4-mercapto-butyramide-n-mono- oder n,n-disubstituiert durch ein mono- oder polyhydroxyalkyl-radikal und ihre verwendung als reduktionsmittel zur dauernden verformung von haaren. | |
US4192863A (en) | Completely one-step permanent wave solution and a method for using the same | |
US3093146A (en) | Process for permanent setting of living hair by surface active compounds | |
US4832948A (en) | Permanent wave solution | |
DE2223306B2 (de) | Kosmetische Zubereitung gegen fettiges Aussehen von Haar und Haut und gegen Schuppenbildung | |
DE1617918C3 (de) | Verfahren zur Herstellung von dauerhaften Formveränderungen der menschlichen Haare | |
EP0261387A1 (fr) | Composition et procédé d'ondulation permanente des cheveux | |
US3678157A (en) | Hair treatment compositions containing polycondensable compounds | |
DE2245903A1 (de) | Neue mittel auf der grundlage von s-substituierten glutathionderivaten und verfahren zur bekaempfung des fettigen und unaesthetischen aussehens des haares und zur verbesserung des aussehens der haut mit hilfe der gemaess dem erfindungsgemaessen verfahren hergestellten mittel | |
EP1198219A2 (fr) | Agent et procede pour le permanentage durable des cheveux a base d'amides de l'acide 2-mercaptopropionique et procede pour leur production | |
EP0895470A1 (fr) | Procede et agent pour permanentes a base de mercaptoacetamides substitues par alkyle a chaine n-ramifiee et procede permettant de preparer ledit agent | |
EP0840592A1 (fr) | Agent et procede pour l'ondulation permanente des cheveux a base de mercaptoacetamides, et procede pour sa fabrication | |
US4331656A (en) | Composition and process for reducing the oily appearance of the hair and skin | |
US3157578A (en) | Permanent deformation of hair | |
EP0302265A1 (fr) | Agent pour onduler ou épiler les cheveux | |
US3257449A (en) | Surface active amine salts | |
DE1917433A1 (de) | Kosmetische Zubereitung und Verfahren zur dauerhaften Verformung der Haare sowie Enthaarungsverfahren | |
US3167478A (en) | Color stabilized hair dye composition of ammonia and trihydroxybenzene | |
DE1617706A1 (de) | Verfahren zur kosmetischen Behandlung des menschlichen Haares,insbesondere zu deren Geeignetmachung fuer die Legung von Wasserwellen,Herstellung dieser und Mittel zur Durchfuehrung dieser Arbeitsweisen | |
EP0653201A1 (fr) | Agent pour la mise en plis permanente des cheveux ainsi que des nouveaux esters de la cystéine et la glycérine réducteurs de la kératine des cheveux | |
DE1186581B (de) | Verfahren zur Herstellung eines stabilen Trockenpraeparates zur Wellung von menschlichem Haar | |
US3694141A (en) | Method of hair conditioning | |
EP0624572B1 (fr) | Compositions pour la déformation permanente des cheveux ainsi que des nouveaux esters 2-hydroxy-3-mercaptopropionique réductrices de la kératine des cheveux | |
DE905193C (de) | Verfahren zur Kraeuselung oder Entkraeuselung von menschlichen oder tierischen Haaren od. dgl. |