US2988416A - Process of creaseproofing linen fabric by applying resin, mercerizing and reapplyingresin and product produced thereby - Google Patents
Process of creaseproofing linen fabric by applying resin, mercerizing and reapplyingresin and product produced thereby Download PDFInfo
- Publication number
- US2988416A US2988416A US65376057A US2988416A US 2988416 A US2988416 A US 2988416A US 65376057 A US65376057 A US 65376057A US 2988416 A US2988416 A US 2988416A
- Authority
- US
- United States
- Prior art keywords
- fabric
- resin
- urea
- formaldehyde
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title claims description 127
- 229920005989 resin Polymers 0.000 title claims description 55
- 239000011347 resin Substances 0.000 title claims description 55
- 238000000034 method Methods 0.000 title claims description 28
- 238000004855 creaseproofing Methods 0.000 title description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 92
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 35
- 239000004202 carbamide Substances 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 12
- 239000004753 textile Substances 0.000 claims description 11
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 36
- 235000013877 carbamide Nutrition 0.000 description 32
- 230000008961 swelling Effects 0.000 description 26
- 238000005470 impregnation Methods 0.000 description 19
- 229910021529 ammonia Inorganic materials 0.000 description 18
- 239000000203 mixture Substances 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000007859 condensation product Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 241000208202 Linaceae Species 0.000 description 7
- 235000004431 Linum usitatissimum Nutrition 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 230000005484 gravity Effects 0.000 description 5
- 229920003002 synthetic resin Polymers 0.000 description 5
- 239000000057 synthetic resin Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- GKQWDAXSOVPFCM-UHFFFAOYSA-N C(O)NC1=NC(=NC(=N1)NCCCCCCCCCCCCCCCCCC)NCO Chemical compound C(O)NC1=NC(=NC(=N1)NCCCCCCCCCCCCCCCCCC)NCO GKQWDAXSOVPFCM-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical class NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000005517 mercerization Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2369—Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
- Y10T442/2393—Coating or impregnation provides crease-resistance or wash and wear characteristics
Definitions
- This invention relates to improvements in the treatment with synthetic resins of linen textile fabrics manufactured wholly or partly from flax.
- the condensation of formaldehyde with urea to produce a resin-forming condensation product is customarily carried out in the presence of a quantity of a solution in water of ammonia having a specific gravity of 0.88, equivalent to 8.8% by weightcalculated on the weight of urea, as condensing agent.
- a quantity of ammonia is used in preparing the resin-forming condensation product from formaldehyle and urea in the molecular proportion of 1.6:1
- one tenth of the quantity of formaldehyde combines with the ammonia and is prevented from combining with the urea, and the equivalent proportions will be different if larger or smaller quantities of ammonia or no condensing agent, or a condensing agent other than ammonia, is used.
- a molecular proportion of formaldehyde to urea of 1:6;1 in the presence of a quantity of a solution in water of ammonia havinga specific gravity of 0.88, equivalent to 8.8% by weight calculated on the weight of urea is equivalent to a molecular proportion of 1.6 9/10:l, i.e. 1.44:1 where no condensing agent, or a condensing agent other than ammonia, is used.
- the proportion of formaldehyde which is prevented from combining with the urea compared with the total quantity of formaldehyde present is less than one tenth in simple proportion.
- a process for the production of a linen textile fabric having thermosetting synthetic resin within and substantially not beween the fibers in which the fabric is, in a first stage, impregnated with a low-viscosity resin-forming condensa tion product, which penetrates Within the fibers of the fabric, formed from urea and formaldehyde in the molecular proportion of formaldehyde to urea between the limits of 1.4:1 and 2.521 inclusive and containing an acidic or potentially acidic catalyst, the fabric then being heated to form such resin and thereafter being subjected to a swelling, or swelling and shrinking, process as set forth in our U.S. Patent :No.
- the fabric in a second stage, is further impregnated with a low-viscosity resin-forming condensation product, which penetrates within the fibers of the fabric, formed from urea and formaldehyde in the molecular proportion of formaldehyde to urea between the limits 1.4:1 and 2.521 inclusive and containing an acidic or potentially acidic catalyst, the fabric again being heated to form such resin without thereafter being subjected to a swelling, or swelling and shrinking, process, the amount of resin formed in the fabric as a result of the first stage impregnation and remaining in the fabric after the swelling, or swelling and shrinking, process being between the limits of 1% and 13% inclusive, the amount of resin formed in the fabric as a result of the second stage impregnation being between the limits 1% to 9% inclusive, and the total amount of resin in the fabric being between the limits of 4% and 18% inclusive, the percentage resin contents being calculated on the weight of the dry fabric before treatment and the molecular proportions of formaldeh
- linen fabric with resin-forming condensation product in two stages of which only the first stage includes a subsequent swelling, or swelling and shrinking, process, to obtain better dry crease-resisting properties than are :obtained by the same quantity of resin insolubilised in a single stage which includes such subsequent swelling, or
- the total amount of resin formed on the fabric should be at least 7%, or better at least 9%.
- Linen fabrics which have not been mercerized and which have received the first resin treatment and then 4 been subjected to a swelling, or swelling and shrinking, process, may then be dyed.
- a better colour yield is frequently obtained in comparison with the same fabric which has been dyed before resin treatment, thereby reducing dyestuff costs, and since the fabrics are not subsequently subjected to a severe caustic alkali treatment the range of dyestufis which may be used is increased.
- the treatment of linen fabrics according to this invention may include treatment with a lubricating agent for example as described in our British application No. 31150/55, filed November 1, 1955.
- Suitable lubricating agents are a methylol derivative of a condensation product of a higher fatty acid chloride with a polyethylene polyamine sold under the trade name Sapamine WP, or a dimethylol stearyl melamine sold under the trade name Phobotex PT.
- the resin may be formed in either or both stages of the treatment in atmospheres containing more than 50% of superheated steam, for example as described in our prior U.S. specification No. 529,774, filed August 22, 1955, now U.S. Patent 2,859,136.
- the catalyst present in the impregnating mixtures may be a weak acid, such as tartaric acid, or a potential acid, such as ammonium dihydrogen phosphate, which liberates acid on heating in the presence of the impregnating mixture.
- a weak acid such as tartaric acid
- a potential acid such as ammonium dihydrogen phosphate
- such catalyst is preferably one which does not develop sufiicient acidity during the low temperature drying to form more than a very small proportion of the total resin formed on the fabric to ensure that as much as possible of the resin is formed in the presence of superheated steam.
- the low viscosity resin forming condensation products formed from urea and formaldehyde which are used in the present invention may be alkylated to form alkylated methylol ureas and then used to impregnate linen textile fabrics according to the present invention.
- linen textile fabric we mean fabric containing at least 25% by weight of flax.
- the present invention therefore includes the treatment of mixture fabrics containing at least 25% by weight of flax and also containing other cellulosic fibre such as cotton or regenerated cellulose or non-cellulosic fibres such as nylon.
- EXAMPLE 1 2 gallons of aqueous formaldehyde solution containing 40 grammes of formaldehyde per ccs. of solution, 10 lb. of urea (molecular proportion of formaldehyde to urea 1.621) and 40S ccs. of ammonia (specific gravity 0.88) were allowed to stand at room temperature until the mixture reached equilibrium in density and viscosity. This mixture was diluted until the density was 19 Tw. (approximately 5% gallons).
- Mixture A was further diluted with water until its density was 7 Tw., Mixture B.
- the fabric was then squeezed and whilst still wet run into a bath of 65 Tw. caustic soda. It was then lightly squeeied so as to leave caustic soda on the fabric and was allowed to stand without tension either in warp or Wait far minutes during which time it was allowed to shrink in both direc tions. The fabric was then washed with water over a r'nercerizing stenter until neutral and dried on stem heated cylinders. At this stage the fabric contained 4.7% of resin.
- Second stage impregnation The treated fabric was then impregnated with Mixture B, dried and heated in the same way as iii the first stage impregnation. It was then washed at 80 C. for 30 seconds in /2% soda ash, washed in water and mangled and passed through a bath containing 1% of a mixture of 3 parts of stearin to l of bora'x, and dried on steam heated cylinders. It was then damped with water and cold and calendered and finished on a controlled compressive shrinkage machine.
- the fabric was treated with a further 4.3% of resin and the total resin content of the finished fabric was 9.0%.
- the finished fabric showed excellent dry crease-resistance and dresses made of the fabric could be worn, washed, squeezed free of excess water and when dried by hanging on a clothes hanger they could be worn without being ironed.
- the fabric had these properties to a greater degree than a similar fabric treated so as to contain 9.0% of resin by a single impregnation followed by a swelling and shrinkage treatment.
- Specimen strips of the fabric under test are cut in both warp and weft directions. These are weadom, squeezed through a small domestic mangle, and inserted in the crease maker in order to forth a sharp double crease. The specimen is next dried for half an hohr and during drying the crease inserted iii the wet fabric diminishes. The S.D. I. figni're is obtained from the extent of this recovery and it indicates 'the ability of the fabric to recover from creases formed during hormal domestic washing.
- EXAMPLE 2 Different samples of a fabric as in Example 1 were treated as described in Example 1, but suitable adjustments were made in the quantities of urea and formaldehyde used and in the extent of dilution of the partially condensed mixture, to form on the samples different quantities of resin. Mangle adjustment so as to leave about of liquor on the fabric after impreg- I claim:
- a process for improving the crease resisting and smooth drying properties of a linen textile fabric contain ing at least 25% by weight of flax comprising the steps of impregnating said fabric with a low viscosity resin forming solution comprising formaldehyde, urea and a catalyst for the reaction of said formaldehyde and said urea, the molecular proportion of said formaldehyde to '7 said urea being from 1.4:1 to 2.5 :1, applying heat to the impregnated fabric to insolubilize the ureaformaldehyde reaction product-within-the fibres of the fabric,
- said fabric having a urea-formaldehyde resin content of from 1 to 13% inclusive based on the weight of the dry fabric prior to treatment, further impregnating said treated fabric with said low viscosity resin-forming solution, heating said impregnated fabric to insolubilize additional ureaformaldehyde resin within the fibres of said fabric, said additional resin being present in an amount of from 1 to 9% based upon the'weight of the dry fabric, the total weight of the resin on the fabric being within the range of 4 to 18% inclusive, said fabric being held in a flat .position after each of said impregnating steps while said resin is being insolubilized thereon.
- a process for improving the crease resisting and smooth drying properties of a linen textile fabric containing at least 25% by weight of flax comprisingthe steps of impregnating said fabric with a low viscosity resin-forming aqueous solution comprising formaldehyde, urea and a catalyst for the reaction of said formaldehyde and said urea, the molecular proportion of said formaldehyde to said urea being from 1.4:1 to 20:1,
- said fabric having a ur ea-formaldehyde resin content of from 3 to 8% inclusive based on the weight of the dry fabric prior to treatment, further impregnating said treated fabric with said low viscosity resin-forming solution, heating said impregnated fabric to insolubilize additional urea-formaldehyde resin, said additional resin being within the range of 3 to 6% based upon the weight of the dry fabric, the total weight of the resin on the fabric being within the range of 6 to 14% inclusive, said fabric being held in a flat position after each of said impregnating steps while said resin is being insolubilized thereon.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1189656A GB871105A (en) | 1956-04-19 | 1956-04-19 | Improvements in the incorporation of thermosetting synthetic resins in linen textilefabrics |
Publications (1)
Publication Number | Publication Date |
---|---|
US2988416A true US2988416A (en) | 1961-06-13 |
Family
ID=9994644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US65376057 Expired - Lifetime US2988416A (en) | 1956-04-19 | 1957-04-19 | Process of creaseproofing linen fabric by applying resin, mercerizing and reapplyingresin and product produced thereby |
Country Status (7)
Country | Link |
---|---|
US (1) | US2988416A (de) |
BE (1) | BE556699A (de) |
DE (1) | DE1109134B (de) |
ES (1) | ES234979A1 (de) |
FR (1) | FR1214826A (de) |
GB (1) | GB871105A (de) |
NL (2) | NL216480A (de) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1277800B (de) * | 1963-03-08 | 1968-09-19 | Heberlein & Co Ag | Verfahren zur Verbesserung der textilen Eigenschaften, insbesondere der Nass- und Trockenknitterfestigkeit von cellulosehaltigem Textilgut |
US4137357A (en) * | 1977-10-25 | 1979-01-30 | Uop Inc. | Plastic thermoset laminates |
EP0044172A1 (de) * | 1980-07-03 | 1982-01-20 | Lintrend Licensing Company Limited | Viskose enthaltendes Fasererzeugnis |
WO1983000172A1 (en) * | 1981-07-01 | 1983-01-20 | Sloan, Frederick, Richard, Wilfred | Dyeing of fibrous materials |
US4451262A (en) * | 1979-07-16 | 1984-05-29 | Ciba-Geigy Corporation | After-treatment of finished, cellulose-containing fibrous materials with liquid ammonia |
US4486197A (en) * | 1981-06-03 | 1984-12-04 | Lintrend Licensing Company Limited | Fibrous product containing viscose |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1734516A (en) * | 1926-12-01 | 1929-11-05 | Tootal Broadhurst Lee Co Ltd | Textile material and the production thereof |
GB437361A (en) * | 1934-01-25 | 1935-10-25 | Tootal Broadhurst Lee Co Ltd | Improvements in the treatment of textile materials |
GB607582A (en) * | 1946-02-08 | 1948-09-01 | William Ewart & Son Ltd | Improvements in the production of crease-resisting mercerised linen textile materials |
US2859136A (en) * | 1950-07-08 | 1958-11-04 | Tootal Broadhurst Lee Co Ltd | Process for the treatment of fabrics with resinous condensation products |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB517890A (en) * | 1938-08-15 | 1940-02-12 | Courtaulds Ltd | Improvements in and relating to the treatment of cellulosic textile materials |
BE500669A (de) * | 1950-01-17 |
-
0
- BE BE556699D patent/BE556699A/xx unknown
- NL NL109573D patent/NL109573C/xx active
- NL NL216480D patent/NL216480A/xx unknown
-
1956
- 1956-04-19 GB GB1189656A patent/GB871105A/en not_active Expired
-
1957
- 1957-04-17 DE DET13499A patent/DE1109134B/de active Pending
- 1957-04-18 FR FR736746A patent/FR1214826A/fr not_active Expired
- 1957-04-18 ES ES0234979A patent/ES234979A1/es not_active Expired
- 1957-04-19 US US65376057 patent/US2988416A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1734516A (en) * | 1926-12-01 | 1929-11-05 | Tootal Broadhurst Lee Co Ltd | Textile material and the production thereof |
GB437361A (en) * | 1934-01-25 | 1935-10-25 | Tootal Broadhurst Lee Co Ltd | Improvements in the treatment of textile materials |
US2158494A (en) * | 1934-01-25 | 1939-05-16 | Tootal Broadburst Lee Company | Treatment of textile materials |
GB607582A (en) * | 1946-02-08 | 1948-09-01 | William Ewart & Son Ltd | Improvements in the production of crease-resisting mercerised linen textile materials |
US2859136A (en) * | 1950-07-08 | 1958-11-04 | Tootal Broadhurst Lee Co Ltd | Process for the treatment of fabrics with resinous condensation products |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1277800B (de) * | 1963-03-08 | 1968-09-19 | Heberlein & Co Ag | Verfahren zur Verbesserung der textilen Eigenschaften, insbesondere der Nass- und Trockenknitterfestigkeit von cellulosehaltigem Textilgut |
US4137357A (en) * | 1977-10-25 | 1979-01-30 | Uop Inc. | Plastic thermoset laminates |
US4451262A (en) * | 1979-07-16 | 1984-05-29 | Ciba-Geigy Corporation | After-treatment of finished, cellulose-containing fibrous materials with liquid ammonia |
EP0044172A1 (de) * | 1980-07-03 | 1982-01-20 | Lintrend Licensing Company Limited | Viskose enthaltendes Fasererzeugnis |
WO1982000164A1 (en) * | 1980-07-03 | 1982-01-21 | Sloan F | Fibrous product containing viscose |
US4486197A (en) * | 1981-06-03 | 1984-12-04 | Lintrend Licensing Company Limited | Fibrous product containing viscose |
WO1983000172A1 (en) * | 1981-07-01 | 1983-01-20 | Sloan, Frederick, Richard, Wilfred | Dyeing of fibrous materials |
Also Published As
Publication number | Publication date |
---|---|
BE556699A (de) | 1900-01-01 |
GB871105A (en) | 1961-06-21 |
ES234979A1 (es) | 1957-11-16 |
NL216480A (de) | 1900-01-01 |
DE1109134B (de) | 1961-06-22 |
FR1214826A (fr) | 1960-04-12 |
NL109573C (de) | 1900-01-01 |
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