US2898334A - Cellulose slurry-steeping - Google Patents
Cellulose slurry-steeping Download PDFInfo
- Publication number
- US2898334A US2898334A US524324A US52432455A US2898334A US 2898334 A US2898334 A US 2898334A US 524324 A US524324 A US 524324A US 52432455 A US52432455 A US 52432455A US 2898334 A US2898334 A US 2898334A
- Authority
- US
- United States
- Prior art keywords
- pulp
- steeping
- slurry
- cellulose
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B1/00—Preparatory treatment of cellulose for making derivatives thereof, e.g. pre-treatment, pre-soaking, activation
- C08B1/08—Alkali cellulose
Definitions
- This invention relates to the co yecsiomof chemical cellulosepulp ipto alkali cellulose in a steeping operation with an aqueous exchangeitiori ofls tgd tjini hydroxide (steeping liquor) and has fSi-Tt? object the provision of an improved process for the formation of alkali cellulose in slurry steeping.
- Chemical eellulose pulp as the term is used hereimrefersfd wood ulp, cotton linter pulp, or mixtures thereof, whichiar e u sed in chemical conversions or in chemical processing.
- the slurry-steeping of chemical cellulose pulp is usually carried out by feeding small rectangular sheets or continuous sheets of the cellulose pulp into a suitable vessel containing steeping liquor, containing, say, from 16% to around 20% of sodium hydroxide in which a mechanically operated device, such as paddles or blades, beat the cellulose into a slurry.
- a mechanically operated device such as paddles or blades, beat the cellulose into a slurry.
- the operations are frequently carried out at cellulose consistencies of around 2% to 6% and at temperatures of about 20 to 50 C.
- Chemical cellulose pulp formed from wood usually contains up to 0.35% (based on the dry weight of the pulp) of residual natural and ether extractable resins. Highly refined chemical cellulose pulp usually contains up to 0.15% of such resins.
- This ether extractable matter, loosely called resins, is mainly in the nature of waxes, fats and true resins, the latter often being present in small amount, a part being saponifiable and a part being unsaponifiable.
- chemical cellulose pulp which is a highly refined Wood pulp it is not practical to remove all the resins from the pulp.
- Some of these resins have certain specific surface active properties or form with the sodium hydroxide in the steeping operation soaps that have certain surface active properties and these may cause or contribute to the cause of foaming, floating and clumping.
- the fibers of the pulp may also have certain physical properties such as inherent kinkiness which cause an affinity for gas bubbles, presumably small bubbles of air, to be formed on and entrapped within the mass of fibers.
- R is a nucleus of an organic hydrophobic compound of low water solubility having from 2 to 4 active hydrogens and in which x varies from 1.6 to 700 and n equals 2 to 4.
- block copolymers As used herein, willb'" understood to be the block copolymers of polyethylene oxide and polypropylene oxide which may be represented by the formula:
- 1: and y have average values for particular copolymers of 10 and 19; 3.3 and 28; 6 and 28; 15.5 and 28; and 106 and 28, respectively.
- the average values of x and y are 15.5 and 28 respectively, x varying from 11 to 17 depending upon the total molecular weight, and the value of y varying from 26 to 31 depending upon the total molecular weight and the value of x.
- Block copolymers of the aforementioned types are manufactured and sold under the names of Pluronic L-44, Pluronie L-61, Pluronic L-62, Pluronic L-64, and Pluronic F68.
- Pluronic L-64 which is believed to have average values for x and y of 15.5 and 28 respectively, is outstandingly effective for the purpose of the invention.
- R is also represented by the nucleus:
- Tetronics 304, 504, 701, 702, 704, 707, 904 and 908 having average values of x and y of 3.5 and 3.0, 8.1 and 7.3, 2.8 and 11.6, 5.2 and 11.6, 12.8 and 11.6, 47.0 and 11.6, 18.3
- the surfactant may be incorporated in the slurry in any suitable way, for example, it may be most conveniently added to the chemical cellulose pulp during its preparation, or to the steeping liquor or aaaerm the slurry. Only a relatively small amount" of the surfactant is necessary, varying from about 0.02% to 0.25% by weight based on the dry weight of the pulp. Amounts of the surfactants in excess of 0.25% are not believed to be detrimental, but only unnecessary.
- the word dry means substantially dry and refers to pulp either bone dry or containing that small moisture content (e.g. 6%) which the pulp, being a hygroscopic substance, has taken up from the air. Roughly, this will refer to pulp containing from zero to 10% of moisture.
- the accompanying drawing was reproduced from a photograph of samples of chemical cellulose taken of pulp undergoing slurry-steeping.
- the photograph is of glass vessels taken against a black background; the white part is the alkali cellulose while the dark part is steeping liquor from which the alkali cellulose has separated.
- each of the samples of pulp shown in the drawing was slurry-steeped by mechanically treating identical pulp sheets of 96% alpha cellulose containing 0.12% ether extractable matter. The pulp was slurried at 2.2% consistency in a steeping liquor containing 18.6% sodium hydroxide and 1.5% hemicellulose at 45' C. In each of the slurry samples shown in the drawing, 0.1% of a surfactant based on the dry weight of the pulp was incorporated in the slurry as follows and the samples were left at rest for four hours:
- the surfactants are especially effective because they do not cause adverse effects in the subsequent viscose process operations. Some of the other steps in the viscose process are actually improved by the use of these surfactants.
- Jordanning or other mechanical treatment of pulp fibers is helpful in straightening out kinky fibers and making them less susceptible to entrapment or retention of air when slurried in solutions of strong caustic soda.
- Such treatment makes it possible to use smaller amounts of added surfactant and still obtain smooth slurries that do not foam or clump.
- use of such surfactants may be made in reducing floating and clumping of pulp fibers in pulp refining operations in which the cellulose fibe s are be ipg egitracted, purified yyashgd with smionsTo'ritaimng sodium hydroxide or gther 1.
- the process of slurry-steeping chemical cellulose pulp containing up to 0.35% based on the weight of the pulp of natural ether extractable matter in aqueous sodium hydroxide solution to form alkali cellulose comprising carrying out the slurry-steeping with from about 0.02% to about 0.25% based on the weight of the dry pulp of an added surfactant in the steeping solution and substantially eliminating foaming, floating, flocculation and clumping of the pulp during the slurry-steeping, said surfactant being a water soluble substantially non-ionic compound which consists of the product of a polypropylene oxide containing hydrophobic compound of low water solubility containing at least 2 active hydrogens substituted by at least 2 terminal polyethylene oxide groups each containing from 1.6 to 700 ethylene oxide units.
- moornorn a400,151,) om o ornonzmm N-C H CH -N in which x and y have average values of from 2.8 to 437 and 3 to 17.2 respectively.
- x and y have average values of about 12.8 and 11.6 respectively.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Description
GR 295989339 EX EXAMINER Aug. 4, 1959 2,898,334
R. L. MITCHELL EI'AL CELLULOSE SLURRY-STEEPING Filed July 26. 1955 INVENTORS Q5122 "I n qcm ATTORNBS United States Patent CELLULOSE SLURRY-STEEPING Reid Logan Mitchell, James Wesley Berry, and Moody Bacon, Jr., Shelton, Wash, assignors to Rayonler Incorporated, Shelton, Wash., a corporation of Delaware Application July 26, 1955, Serial No. 524,324
7 Claims. (Cl. 260-233) This invention relates to the co yecsiomof chemical cellulosepulp ipto alkali cellulose in a steeping operation with an aqueous soititiori ofls tgd tjini hydroxide (steeping liquor) and has fSi-Tt? object the provision of an improved process for the formation of alkali cellulose in slurry steeping. Chemical eellulose pulp, as the term is used hereimrefersfd wood ulp, cotton linter pulp, or mixtures thereof, whichiar e u sed in chemical conversions or in chemical processing.
The slurry-steeping of chemical cellulose pulp is usually carried out by feeding small rectangular sheets or continuous sheets of the cellulose pulp into a suitable vessel containing steeping liquor, containing, say, from 16% to around 20% of sodium hydroxide in which a mechanically operated device, such as paddles or blades, beat the cellulose into a slurry. The operations are frequently carried out at cellulose consistencies of around 2% to 6% and at temperatures of about 20 to 50 C.
While such steeping operations are commonly carried out to form alkali cellulose for use in the viscose process they may also be carried out to form alkali cellulose for use in other processes, such as in the production of hydroxyethoxycellulose. In the slurry-steeping of such chemical cellulose pulp considerable difficulties have been encountered mainly due to foaming of the steeping liquor and floating and clumping of the fibers which have a very deleterious eflect in the steeping and pressing operations as well as in subsequent processing. It appears that small bubbles of gas (presumably air) form on 'the fibers of pulp causing the undesirable foaming, floating, flocculation and clumping.
Chemical cellulose pulp formed from wood usually contains up to 0.35% (based on the dry weight of the pulp) of residual natural and ether extractable resins. Highly refined chemical cellulose pulp usually contains up to 0.15% of such resins. This ether extractable matter, loosely called resins, is mainly in the nature of waxes, fats and true resins, the latter often being present in small amount, a part being saponifiable and a part being unsaponifiable. In the production of chemical cellulose pulp which is a highly refined Wood pulp it is not practical to remove all the resins from the pulp.
Some of these resins have certain specific surface active properties or form with the sodium hydroxide in the steeping operation soaps that have certain surface active properties and these may cause or contribute to the cause of foaming, floating and clumping. The fibers of the pulp may also have certain physical properties such as inherent kinkiness which cause an affinity for gas bubbles, presumably small bubbles of air, to be formed on and entrapped within the mass of fibers. These possible theories are offered as a plausible explanation of the objectionable conditions encountered in the slurry-steeping of such pulp without any intention of predicating the invention thereon. The amazing fact is that the addition to the slurry of well known and otherwise effective antifoamants and emulsifiers does not overcome these difficulties.
2,898,334 Patented Aug. 4, 1959 We have made the surprising discovery that certain water-soluble substantially non-ionic surfactants have the property of substantially or completely overcoming these objectionable conditions when incorporated in the slurrysteeping constituents, either by addition to the pulp or in the steering liquor. Such compounds for use in our process are water soluble substantially non-ionic compounds which consist of the products of a hydrophobic compound of low water solubility containing at least 2 active hydrogens substituted by at least 2 terminal polyethylene oxide groups each containing from 1.6 to 700 ethylene oxide units.
The compounds used in the process of the invention may be represented by the formula:
wherein R is a nucleus of an organic hydrophobic compound of low water solubility having from 2 to 4 active hydrogens and in which x varies from 1.6 to 700 and n equals 2 to 4.
When R is -(OC H y varies from 19 to 31, and has two terminal polyethylene oxide groups the compound is of the class 'knowna s plolyglkylene block co polymers. The term block copolymers, as used herein, willb'" understood to be the block copolymers of polyethylene oxide and polypropylene oxide which may be represented by the formula:
in which 1: and y have average values for particular copolymers of 10 and 19; 3.3 and 28; 6 and 28; 15.5 and 28; and 106 and 28, respectively. In one especially eflective block copolymer, the average values of x and y are 15.5 and 28 respectively, x varying from 11 to 17 depending upon the total molecular weight, and the value of y varying from 26 to 31 depending upon the total molecular weight and the value of x. Block copolymers of the aforementioned types are manufactured and sold under the names of Pluronic L-44, Pluronie L-61, Pluronic L-62, Pluronic L-64, and Pluronic F68. Pluronic L-64, which is believed to have average values for x and y of 15.5 and 28 respectively, is outstandingly effective for the purpose of the invention. R is also represented by the nucleus:
( s rO) I in which y represents average values of from 3 to 17.2. When said nucleus R is combined with four polyethylene oxide radicals the compound is represented by the formula:
in which x and y have average values of from 2.8 to 437 and 3 to 17.2 respectively, the compound is effective for use in the process of the invention. Such compounds are sold under the trademark Tetronics. Tetronics 304, 504, 701, 702, 704, 707, 904 and 908 having average values of x and y of 3.5 and 3.0, 8.1 and 7.3, 2.8 and 11.6, 5.2 and 11.6, 12.8 and 11.6, 47.0 and 11.6, 18.3
and 17.2, and 437 and 17.2 respectively, are especially suitable for use in the invention.
The foregoing compounds may be identified further with reference to the following table:
Molecular Weights Percent Compound Ethylene Oxide Range Average Pluronlc L-44 1, 667-2, 400 2, 000 40-50 Pluronlc L-fil 1, 667-2, 250 1, 941 10-20 Pluronic 11-02 1, 875-2, 571 2, 200 20-30 Pluronie 11-64 2, 500-3, 3, 000 40-50 Pluronic F-6B 7, 500-18,!) 11, 000 80-90 Pluronic P-75 3, 600-5, 250 4, 333 50-60 Tetronie 304 834-2,000 1,363 40-50 Tetronic 604.- 500-4, 3, 182 40-50 Tetmntc 701 2, 777-3, 750 3, 235 -20 Tetmnlc 702 3, 125-4, 286 3, 607 20-30 Tetronlc 704- 4, 167-6, 000 6, 000 40-50 Tetronic 707-- 8, 334-15, 000 11, 000 70-80 Tetronic 904. 000-9, 7, 364 40-50 Tetronlc 908 36, 000-450, 000 B1, 000 90-100 In carrying out a process of the invention the surfactant may be incorporated in the slurry in any suitable way, for example, it may be most conveniently added to the chemical cellulose pulp during its preparation, or to the steeping liquor or aaaerm the slurry. Only a relatively small amount" of the surfactant is necessary, varying from about 0.02% to 0.25% by weight based on the dry weight of the pulp. Amounts of the surfactants in excess of 0.25% are not believed to be detrimental, but only unnecessary. As used herein, the word dry means substantially dry and refers to pulp either bone dry or containing that small moisture content (e.g. 6%) which the pulp, being a hygroscopic substance, has taken up from the air. Roughly, this will refer to pulp containing from zero to 10% of moisture.
The accompanying drawing was reproduced from a photograph of samples of chemical cellulose taken of pulp undergoing slurry-steeping. The photograph is of glass vessels taken against a black background; the white part is the alkali cellulose while the dark part is steeping liquor from which the alkali cellulose has separated.
Each of the samples of pulp shown in the drawing was slurry-steeped by mechanically treating identical pulp sheets of 96% alpha cellulose containing 0.12% ether extractable matter. The pulp was slurried at 2.2% consistency in a steeping liquor containing 18.6% sodium hydroxide and 1.5% hemicellulose at 45' C. In each of the slurry samples shown in the drawing, 0.1% of a surfactant based on the dry weight of the pulp was incorporated in the slurry as follows and the samples were left at rest for four hours:
(A) Tetronic 304 (B) Tetronic 504 (C) Tetronic 701 (D) Tetronic 702 (E) Tetronic 704 (F) Tetronic 707 (G) Tetronic 904 (H) Tetronic 908 (I) Pluronic L-64 (1) Control The aforementioned Tetronics and the Pluronics, are very effective surfactants in the process of the invention. The very effective improvement in slurrying is shown by the drawings in which it will be noted that the upper surfaces of the samples A to I are about at the same height and fiat on top in comparison with the elevated or floated pulp of the control which has an irregular top. Moreover, samples A to I show no appreciable separation of pulp from the water while the control shows very appreciable separation of the pulp from the water.
When the cellulose is slurried to form alkali cellulose 4 for conversion to viscose the surfactants are especially effective because they do not cause adverse effects in the subsequent viscose process operations. Some of the other steps in the viscose process are actually improved by the use of these surfactants.
Jordanning or other mechanical treatment of pulp fibers is helpful in straightening out kinky fibers and making them less susceptible to entrapment or retention of air when slurried in solutions of strong caustic soda. Such treatment makes it possible to use smaller amounts of added surfactant and still obtain smooth slurries that do not foam or clump. In another aspect, use of such surfactants may be made in reducing floating and clumping of pulp fibers in pulp refining operations in which the cellulose fibe s are be ipg egitracted, purified yyashgd with smionsTo'ritaimng sodium hydroxide or gther 1. The process of slurry-steeping chemical cellulose pulp containing up to 0.35% based on the weight of the pulp of natural ether extractable matter in aqueous sodium hydroxide solution to form alkali cellulose, comprising carrying out the slurry-steeping with from about 0.02% to about 0.25% based on the weight of the dry pulp of an added surfactant in the steeping solution and substantially eliminating foaming, floating, flocculation and clumping of the pulp during the slurry-steeping, said surfactant being a water soluble substantially non-ionic compound which consists of the product of a polypropylene oxide containing hydrophobic compound of low water solubility containing at least 2 active hydrogens substituted by at least 2 terminal polyethylene oxide groups each containing from 1.6 to 700 ethylene oxide units.
2. In the process of claim 1, using as a surfactant a block copolymer having the formula:
in which the average values of x and y vary from 3.3 to 106 and from 19 to 31 respectively.
3. In the process of claim 1, using as a surfactant a block copolymer having the formula:
in which the average values for x and y are about 15.5 and 28 respectively.
4. In the process of claim 1, using as a surfactant a compound having the formula:
moornorn) a400,151,) om o ornonzmm N-C H CH -N in which x and y have average values of from 2.8 to 437 and 3 to 17.2 respectively.
5. In the process of claim 1, using as a surfactant a compound represented by the formula:
s 31150) (CHgCHgO); Ii
in which x and y have average values of about 12.8 and 11.6 respectively.
n the Process of claim 1, forming the slurry of a 5 6 wood pulp which had been subjected to a mechanical 2,677,700 Jackson May 4, 1954 operation to straighten the fibers and thereby reduce the 2,692,877 Gray et al Oct. 26, 1954 amount of surfactant required. 2,710,861 Charles ct al. June 14, 1955 2,716,058 Rapson et al Aug. 23, 1955 References Cited in the file of this patent 5 UNITED STATES PATENTS OTHER REFERENCES 2,114,605 Nico APR 19, 1938 Pluronics, Wyandotte Chemicals C0rp., pages 10 and 2,481,693 Schlosser et al Sept. 13, 1949 12, 1952- 2,674,619 Lundsted Apr. 6, 1954 10
Claims (1)
1. THE PROCESS OF SLURRY-STEEPING CHEMICAL CELLULOSE PULP CONTAINING UP TO 0.35% BASED ON THE WEIGHT OF THE PULP OF NATURAL ETHER EXTRACTABLE MATTER IN AQUEOUS SODIUM HYDROXIDE SOLUTION TO FORM ALKALI CELLULOSE, COMPRISING CARRYING OUT THE SLURRY-STEEPING WITH FROM ABOUT 0.02% TO ABOUT 0.25% BASED ON THE WEIGHT OF THE DRY PULP OF AN ADDED SURFACTANT IN THE STEEPING SOLUTION AND SUBSTANTIALLY ELIMINATING FOAMING, FLOATING, FLOCULATION AND CLUMPING OF THE PULP DURING THE SLURRY-STEEPING, SAID SURFACTANT BEING A WATER SOLUBLE SUSTANTIALLY NON-IONIC COMPOUND WHICH CONSISTS OF THE PRODUCT OF A POLYPROPYLENE OXIDE CONTAINING HYDROPHOBIC COMPOUND OF LOW WATER SOLUBILITY CONTAINING AT LEAST 2 ACTIVE HYDROGENS SUBSTITUTED BY AT LEAST 2 TERMINAL POLYETHYLENE OXIDE GROUPS EACH CONTAINING FROM 1.6 TO 700 ETHYLENE OXIDE UNITS.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US524324A US2898334A (en) | 1955-07-26 | 1955-07-26 | Cellulose slurry-steeping |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US524324A US2898334A (en) | 1955-07-26 | 1955-07-26 | Cellulose slurry-steeping |
Publications (1)
Publication Number | Publication Date |
---|---|
US2898334A true US2898334A (en) | 1959-08-04 |
Family
ID=24088709
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US524324A Expired - Lifetime US2898334A (en) | 1955-07-26 | 1955-07-26 | Cellulose slurry-steeping |
Country Status (1)
Country | Link |
---|---|
US (1) | US2898334A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2710309A1 (en) * | 1976-03-10 | 1977-09-15 | Kemira Oy | PROCESS FOR THE PRODUCTION OF ALKALICELLULOSE |
US4210747A (en) * | 1976-03-10 | 1980-07-01 | Kemira Oy | Process for the preparation of viscose |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2114605A (en) * | 1934-11-23 | 1938-04-19 | Du Pont | Cellulose derivative manufacture |
US2481693A (en) * | 1944-04-29 | 1949-09-13 | Rayonier Inc | Raw cotton for conversion into rayon |
US2674619A (en) * | 1953-10-19 | 1954-04-06 | Wyandotte Chemicals Corp | Polyoxyalkylene compounds |
US2677700A (en) * | 1951-05-31 | 1954-05-04 | Wyandotte Chemicals Corp | Polyoxyalkylene surface active agents |
US2692877A (en) * | 1951-05-11 | 1954-10-26 | Rayonier Inc | Acetylation of wood pulp |
US2710861A (en) * | 1951-08-20 | 1955-06-14 | Int Paper Canada | Treatment of cellulose with the reaction product of primary aliphatic amines and ethylene oxide |
US2716058A (en) * | 1950-06-24 | 1955-08-23 | Int Paper Canada | Deresination of wood pulp |
-
1955
- 1955-07-26 US US524324A patent/US2898334A/en not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2114605A (en) * | 1934-11-23 | 1938-04-19 | Du Pont | Cellulose derivative manufacture |
US2481693A (en) * | 1944-04-29 | 1949-09-13 | Rayonier Inc | Raw cotton for conversion into rayon |
US2716058A (en) * | 1950-06-24 | 1955-08-23 | Int Paper Canada | Deresination of wood pulp |
US2692877A (en) * | 1951-05-11 | 1954-10-26 | Rayonier Inc | Acetylation of wood pulp |
US2677700A (en) * | 1951-05-31 | 1954-05-04 | Wyandotte Chemicals Corp | Polyoxyalkylene surface active agents |
US2710861A (en) * | 1951-08-20 | 1955-06-14 | Int Paper Canada | Treatment of cellulose with the reaction product of primary aliphatic amines and ethylene oxide |
US2674619A (en) * | 1953-10-19 | 1954-04-06 | Wyandotte Chemicals Corp | Polyoxyalkylene compounds |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2710309A1 (en) * | 1976-03-10 | 1977-09-15 | Kemira Oy | PROCESS FOR THE PRODUCTION OF ALKALICELLULOSE |
FR2343753A1 (en) * | 1976-03-10 | 1977-10-07 | Kemira Oy | ALKALI-CELLULOSE PREPARATION PROCESS |
US4210747A (en) * | 1976-03-10 | 1980-07-01 | Kemira Oy | Process for the preparation of viscose |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2368527A (en) | Treatment of cellulosic pulp | |
US2535690A (en) | Fibrous dielectric compositions | |
US2891921A (en) | Stabilization of polytetrafluoroethylene filler slurries | |
US2898334A (en) | Cellulose slurry-steeping | |
US2822581A (en) | Amylose films | |
DE2402314A1 (en) | PROCESS FOR MANUFACTURING SINTERABLE, FINE-PARTED POLYVINYL CHLORIDE MOLDING COMPOUNDS | |
GB576657A (en) | Improvements relating to the manufacture of micro-porous material | |
US2539451A (en) | Method of preparing sulfuric acid esters of cellulose | |
DE1949335C2 (en) | Process for the production of cellulose xanthate or cellulose acetate | |
US2392103A (en) | Mixed thio ethers | |
US1955092A (en) | Production of cellulose for viscosemaking | |
US2912431A (en) | Preparation of carboxyalkyl cellulose derivatives | |
US2068631A (en) | Preparation of cellulose xanthate solutions | |
US2168375A (en) | Chitin xanthate | |
US3032548A (en) | Methods of treating cellulose | |
US2117038A (en) | Process of making cellulose xanthate solutions | |
US20120214983A1 (en) | Method for producing cellulose ether | |
US2178630A (en) | Method for the purification of cellulose ethers | |
US2134895A (en) | Cellulose hydroxy ethers | |
US3620912A (en) | Mercerization of cellulosic materials using a solution containing a mercerizing concentration of alkali and a barium compound | |
US1814543A (en) | Manufacture of viscose | |
US2789902A (en) | Refining of wood pulp | |
US2366880A (en) | Production of nitrocellulose | |
US2558054A (en) | Purification of cellulosic materials | |
DE1801553A1 (en) | Carboxymethyl cellulose production |