US2847202A - Method of mining salt using two wells connected by fluid fracturing - Google Patents

Method of mining salt using two wells connected by fluid fracturing Download PDF

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US2847202A
US2847202A US564417A US56441756A US2847202A US 2847202 A US2847202 A US 2847202A US 564417 A US564417 A US 564417A US 56441756 A US56441756 A US 56441756A US 2847202 A US2847202 A US 2847202A
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Jr Milton W Pullen
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FMC Corp
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    • E—FIXED CONSTRUCTIONS
    • E21—EARTH OR ROCK DRILLING; MINING
    • E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/28—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent
    • E21B43/283—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent in association with a fracturing process

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  • One of the objects of this invention is to provide'a method of joining adjacent wells by a passage along the underside of a deposit of soluble salt, in such a way that at least one gallery is produced, Iwhereby a solventmay be introduced into one well and brine produced from a connected well.
  • adjacent salt wells are joined by formation fracturing Aa dense salt bed either along the interface between the lowermost surface of the bed of salt and an underlying nonsalt stratum or along a shale or othr lithological parting j or stratum in the lower part of the salt bed.
  • the fracturing in accordance with this invention can be carried out even if the adjacent wells are situated on opposite sides of a syncline.
  • salt is used hereinafter to include various soluble salts, such as sodium chloride; borax, potash and the like.
  • Figure l is a sectional view, somewhat diagrammatic in character, showing adjacent wells connected in accordance with an illustrative embodiment of the method of this invention.
  • Fig. 2 illustrates an ⁇ embodiment of this invention wherein a plurality of wells are drilled to communicate with the fracture from a centrally disposed well.
  • the well 10 extends a short ydistance into the shale bed 3.
  • the lowermost end of the well, in the shale bed, may be plugged with cement, if desired.
  • a casing 12 extends from the surface of the earth 5 to a point in the salt bed near the salt-shale interface. ⁇
  • clear water 18 is shown as being pumped by a pump 20 from a reservoir 22 down the casing 12.'
  • the water 18, issuing from the casing 12 passes alonga gallery 25 between the bed of shale 3 and the bottom of the salt bed 1. In the course of its passage through the gallery 25, the water 18 dissolves salt from the bed 1 and thus becomes brine 27.
  • the brine 27 is forced up, or is pumped by a .pump 29, out of the well 15.
  • the well 10 is drilled from the surface of the earth 5 through the bed of salt 1 and a short distance into the bed of shale 3.
  • a packer 30, shown in dotted lines, is set in the casing 12 of the well 10 a :short ⁇ distance above the bottom of the salt bed 1. Fluid, under a pressure higher than the hydrostatic and geostatic head above the bottom of the salt bed or stratum above which the salt to be mined lies, is then introduced below the packer through a pipe 31.
  • Any suitable tluid may be used, such, for example, as water, brine, kerosene, napalm, mineral oil, or compressed air.
  • the pressure of fluid between the packer and the bottom of the Well is such that the salt bed and shale bed are fractured along their interface as indicated at I32. Ordinarily, a pressure in pounds per square inch of about 1.8 times the depth in feet will be adequ'ate to produce the fracture.
  • the salt being dense-and-soluble, and lying in regular beds., frac tures laterally i'n a very ysatisfactory manner.
  • the packer 30 and pipe 31 are removed'and a solvent,V in this case, the water 18, is pumped down the well 10, throughthe space produced by the fracturing of the formations with respect to one another, and out through the well 15.
  • the fracturing is not blocked by the existence of the syncline, the line of cleavage or fracture followingthe interface down the one side of the syncline and up'the other.
  • Figure 2 illustrates an embodimentl of this invention wherein a plurality of Wells are drilled to communicate withthe fracture from a centrally disposed well.
  • brine well 15 cau be utilized, since the fracture generally extends radially from the fracturing well 10, in every direction.
  • Brine wells 15 canbe-positioned at any number of points within the compass of the fracture.
  • the well maybe in the center, with eight or ten brine wells arranged in a circle around it.
  • FIG. 2 the central well from which the fracture emanates is indicated at 10 and a plurality of outlet wells15k areindicated around the well 10 and communicatingwith'the well 10 through the fracture at the interface of the salt bed and the underlying shale layer 3 andthrough galleries dissolved inthe bottom of the salt bed.
  • Fresh water may be pumped down one or more of the wellsglS, and :brine recovered from the well 10. This will :tend to equalize the size of the cavities and galleries at thewells 15 andi10, since otherwise, the fresh water introduced at the well 10 will tend to dissolve salt more rapidly thanthe brine ⁇ at the well 15. Furthermore, when several wells 15 are used, the volume of liquid pumped from each-of the wells 15 is only a fraction of the volume of fresh .water introduced at the well 10.
  • the method of mining a soluble dense underground salt formation lying above an insoluble formation and forming an interface therewith, substantially from the bottom upwardly which comprises sinking a Well through said soluble salt formation to be removed to the interface between said soluble formation and the underlying insoluble formation and into the insoluble formation, sinking another well at a spaced distance through said soluble formation to said interface, casing said wells to a point in the salt formation near to but above said interface, applying a fluid fracturing pressure to the formation through the casing of said well extending into the insoluble formation near to but above and below said interface to fracture the formation substantially at the said interface forming an underground passage between the fractured well and the well spaced therefrom and circulating a dissolving liquid between said wells to dissolve the soluble salt formation from the bottom upwardly between said Wells.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
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Description

Aug. 12T, 1958 L MQ WQPULL EN, JR 2,847,202 METHOD 0F MINING SALT .USING TWO WELLS Y CONNECTED BY FLUID FRACTURING 'Il x L -.".`-:.k.";-.
2 Sheets-Sheet 1 Filed Feb. 9. 1956 /fWf/rrae MM ra/y MPMan/JZ 2 0 :2. 7 w. s u ma om mm Rem JNM ,I 4 NMF Tm L U www. v .mm MF 0 D m T m 8 5 9 1I. 2, 1 A
2 sheets-sheet 2 CONNECTED Filed Feb. 9, 1956 INVENTOR' wl uen AGE-NT United States Patent O METHOD OF MINING SALT USING TWO WELLS CONNECTED BY FLUID FRACTURING Milton W. Pullen, '.lr., Urbana, Ill., assigner, by mesne assignments, t'o Food Machinery and Chemical 'Corporation, New York, N. Y., a corporation of Delaware Application February 9, '1956, Serial No. 564,417 s claims. (c1. zz-s) This invention relates to the solution mining of soluble minerals of which common salt is the prime example. It is also applicable to such minerals as borax, potash and the like.
In mining soluble salt, it is common practice to drill a well into an underground layer of salt, case the Well to a point near its bottom, and insert in the well bore a central pipe or tubing to the bottom of the well. Wateris pumped or dumped down the central tubing, where it dissolves the salt, and the produced brine is forced upwardly, by the pressure of incoming fresh water, between the casing and the central tubing. Alternatively, the water is pumped or dumped down the casing and the brine produced upwardly through the central tubing. Either method produces a cavity in lthe salt which becomes inverted pear-shaped in vertical section because the heavier brine tends to stay below, while the fresh water rises to the top and dissolves `more salt. This produces a rather weak structure with respect to the non-salt roof of the salt deposit, and leads to caving of the roof, clogging of the well and contaminating of the brine. i Another disadvantage of such a system is that as the cavity enlarges, the flow velocity of the liquid with respect to the walls of the cavity lessens, which leads to the deposit of insoluble materials on the surface of the salt, so that further solution is inhibited. The deposit of insoluble materials is particularly marked on the bottom of the cavity, but also occurs on the sides. t
The desirability of joining two or more adjacent wells through a passage in the salt, to form a gallery, so that water may be introduced into one well and brine produced from ano-ther, has been recognized. In such a situation, the velocity of the water with respect tothe walls of the cavity can be maintained high, and a much greater effective surface can be developed. Stratification of the brine is also minimized. However, in wells which have heretofore been connected, the gallery has been made immediately beneath the roof of the salt deposit. This has been true because the only way of joining adjacent wells heretofore has 'been to produce suticiently large cavities about the respective wells so that the cavities meet. Inasmuch as the cavities assume an inverted cone or .pear shape, the joining of the cavities takes place near their tops. This arrangement aggravates the caving problem, since more of lthe roof is unsupported than with the cavities alone, and the roof is subjected to the scouring action of the water.
A way in which adjacent wells have been connected more or less fortuitously in the past is by sinking one well below another in an inclined stratum of salt. Because of the fact that the heavier brine remains on the lower side of the cavity while the fresh water rises to the top, the cavity follows the upward inclination of the bed so that the cavity from the lower of the two wells will eventually progress up the inclined bed to the higher of the two wells. This arrangement, although it makes the joining of the two wells more easily accomplished, is still subject to the same difficulties so far as the roof support 2,847,202 Patented Aug. 12, 1958 ryice Z is concerned, and also as far as the deposit of insoluble materials on the surface of the salt is concerned (although this problem is much less marked in gallery-type wells than in the cavity-type). Furthermore, the arrangement is only feasible when the stratum is inclined andthe wells can be properly positioned. t
Where two adjacent wells happen to be on opposite slopes of a syncline, it has heretofore proved impossible to join' them, since, as has been pointed out, the cavities extend upwardly along the inclined beds, hence away from one another.
One of the objects of this invention is to provide'a method of joining adjacent wells by a passage along the underside of a deposit of soluble salt, in such a way that at least one gallery is produced, Iwhereby a solventmay be introduced into one well and brine produced from a connected well.
Other objects will become apparent to those skilledv in the art in the light of the following description.
In accordance with this invention, generally stated, adjacent salt wells are joined by formation fracturing Aa dense salt bed either along the interface between the lowermost surface of the bed of salt and an underlying nonsalt stratum or along a shale or othr lithological parting j or stratum in the lower part of the salt bed. The fracturing in accordance with this invention can be carried out even if the adjacent wells are situated on opposite sides of a syncline. The term salt is used hereinafter to include various soluble salts, such as sodium chloride; borax, potash and the like.
In the drawing,
Figure l is a sectional view, somewhat diagrammatic in character, showing adjacent wells connected in accordance with an illustrative embodiment of the method of this invention.
Fig. 2 illustrates an` embodiment of this invention wherein a plurality of wells are drilled to communicate with the fracture from a centrally disposed well.
Referring to the drawing for an illustrative application of the method of this invention, reference numeral 1 indicates a bed of salt. The salt bed 1 illustrated, lies between a bed of shale 3 upon which it rests, andan overlying roof of rock strata 6 and intervening geologic formations to the surface of the earth 5. The shale is shown as laid down in two strata meeting to form a syncline 7. A `well 10 extends from the surface of the earth 5 to the shale bed 3 on one side of the syncline 7, while a second well 15 extends from the surface of the earth 5 to the bed of `shale 3 on the opposite side of the syncline 7.
The well 10 extends a short ydistance into the shale bed 3. The lowermost end of the well, in the shale bed, may be plugged with cement, if desired. A casing 12 extends from the surface of the earth 5 to a point in the salt bed near the salt-shale interface.` In the illustration, clear water 18 is shown as being pumped by a pump 20 from a reservoir 22 down the casing 12.' The water 18, issuing from the casing 12, passes alonga gallery 25 between the bed of shale 3 and the bottom of the salt bed 1. In the course of its passage through the gallery 25, the water 18 dissolves salt from the bed 1 and thus becomes brine 27. The brine 27 is forced up, or is pumped by a .pump 29, out of the well 15.
In producing the gallery 25, the well 10 is drilled from the surface of the earth 5 through the bed of salt 1 and a short distance into the bed of shale 3. A packer 30, shown in dotted lines, is set in the casing 12 of the well 10 a :short `distance above the bottom of the salt bed 1. Fluid, under a pressure higher than the hydrostatic and geostatic head above the bottom of the salt bed or stratum above which the salt to be mined lies, is then introduced below the packer through a pipe 31.
Any suitable tluid may be used, such, for example, as water, brine, kerosene, napalm, mineral oil, or compressed air. The pressure of fluid between the packer and the bottom of the Well is such that the salt bed and shale bed are fractured along their interface as indicated at I32. Ordinarily, a pressure in pounds per square inch of about 1.8 times the depth in feet will be adequ'ate to produce the fracture.
Unlike the fracturing produced in oil sands, which, being porous, dissipate the forces of the fluid so that the fracture may not run laterally satisfactorily, the salt, being dense-and-soluble, and lying in regular beds., frac tures laterally i'n a very ysatisfactory manner.
. While it-is contemplated that the fracturing shall be accomplished from only one of the adjacent wells, it is Within the contemplation of this invention to apply pressure;alternately or, if necessary, simultaneously to more than one well.
When the formation has thus been fractured suiciently to enable'afsolutionI to reach the well 15 from the well 10, the packer 30 and pipe 31 are removed'and a solvent,V in this case, the water 18, is pumped down the well 10, throughthe space produced by the fracturing of the formations with respect to one another, and out through the well 15. The fracturing is not blocked by the existence of the syncline, the line of cleavage or fracture followingthe interface down the one side of the syncline and up'the other.
By producing the fracture, hence the connecting gallery, along the underside or lower part of the salt bed, afnumber of very important advantages are realized. Since the lighter fresh water tends to rise to the top, the fresh Water is always in contact with the superincumbent salt. In this way, not only is solution facilitated, but there is no tendency to deposit insoluble materialscntheV working surface. On the contrary, the insolnblesitendto settle out along the underlying rock, hence to protectl the rock from the scouring and dissolving action of the water.
Another'important. advantage is that if any caving occurs, it will occur from the salt roof into the gallery. This, ofcourse, will simply aid in the recovery of the salt and in no Awaycontamina'te the brine.
Figure 2 illustrates an embodimentl of this invention wherein a plurality of Wells are drilled to communicate withthe fracture from a centrally disposed well.
Itcan be seen that more than one brine well 15 cau be utilized, since the fracture generally extends radially from the fracturing well 10, in every direction. Brine wells 15 canbe-positioned at any number of points within the compass of the fracture. Thus, for example, the well maybe in the center, with eight or ten brine wells arranged in a circle around it.
Thus in Fig. 2 the central well from which the fracture emanates is indicated at 10 and a plurality of outlet wells15k areindicated around the well 10 and communicatingwith'the well 10 through the fracture at the interface of the salt bed and the underlying shale layer 3 andthrough galleries dissolved inthe bottom of the salt bed.
Fresh water may be pumped down one or more of the wellsglS, and :brine recovered from the well 10. This will :tend to equalize the size of the cavities and galleries at thewells 15 andi10, since otherwise, the fresh water introduced at the well 10 will tend to dissolve salt more rapidly thanthe brine` at the well 15. Furthermore, when several wells 15 are used, the volume of liquid pumped from each-of the wells 15 is only a fraction of the volume of fresh .water introduced at the well 10.
Numerous variations in the mechanics of the fracturing and they introduction and withdrawal of the solvent, within-the scope of the appended claims, will occur to those'skilled in the art in the light ofthe foregoing disclosure.
The orderin which'the wells are drilled, and whether the wells 15 are drilled before or after the fracturing has been accomplished are also matters of choice, within the purview of those skilled in the art.
Having thus described the invention, what is claimed and desired to be secured by Letters Patent is:
l. The process of mining a bed soluble in a liquid, said bed lying in a dense underground formation and in a stratum immediately above a vlithologic stratum insoluble in said liquid land having a clear parting line interface between said strata, comprising sinking a well into said lower stratum, casing the well to a point in the soluble bed near to but above the said parting line, applying a fluid fracturing pressure through said casing, above and below said interface to fracture the said strata substantially at their parting line interface, sinking another well substantially so said parting line interface, communicating with said fracture and providing communication between said wells substantially at said parting line interface, introducing a liquid solvent through one of said wells to the parting line interface at one place along the fracture and withdrawing the solvent through another of said wells at a point remote from the place at which the solvent is introduced but within the compass of the fracture causing the solvent to flow along the fracture and to dissolve said soluble mineral formation substantially from the bottom upwardly.
2. The method of mining a soluble dense underground salt formation lying above an insoluble formation and forming an interface therewith, substantially from the bottom upwardly, which comprises sinking a Well through said soluble salt formation to be removed to the interface between said soluble formation and the underlying insoluble formation and into the insoluble formation, sinking another well at a spaced distance through said soluble formation to said interface, casing said wells to a point in the salt formation near to but above said interface, applying a fluid fracturing pressure to the formation through the casing of said well extending into the insoluble formation near to but above and below said interface to fracture the formation substantially at the said interface forming an underground passage between the fractured well and the well spaced therefrom and circulating a dissolving liquid between said wells to dissolve the soluble salt formation from the bottom upwardly between said Wells.
3. The method of mining a soluble dense underground salt formation lying above an insoluble formation and forming an interface therewith, substantially from the bottom upwardly, which comprises sinking a Well through said soluble salt formation and into the insoluble formation therebelow, inserting a casing in said well to a point near the bottom of the salt formation, applying a fracturing pressure, through said casing, above and below said interface to fracture the said formation substantially along said interface at the bottom of said salt formation, sinking another Well at a spaced distance through said soluble formation to said interface, forming an underground passage between the fractured well and the well spaced therefrom, and circulating a dissolving liquid between said wells to dissolve the soluble salt formation from the bottom upwardly between said Wells.
4. The method of mining a soluble dense underground salt formation lying above an insoluble formation and forming an interface therewith, substantially from the bottom upwardly, which comprises sinking a well through said soluble salt formation to be removed substantially to the interface between said soluble formation and into the underlying insoluble formation, sinking another well at a spaced distance through said soluble formation to said interface and into the underlying insoluble formation, casing said wells substantially to the bottom of but slightly above said salt formation, applying a fracturing pressure to the formation, through the casing of one of said wells, above and below said interface, said fracturing pressure being applied substantially at the line of said interface, to fracture the formation substantially at the said interface, forming an underground passage between the fractured well and the Well spaced therefrom, and circulating a dissolving liquid between said wells to dissolve the 'soluble salt formation from the bottom upwardly between said wells.
5. The process of mining an underground mineral, said mineral being removable in liquid form by the use of a removal liquid, and lying in a dense underground formation in a stratum immediately above a lithologic stratum insoluble in said removal liquid, and having a clear parting line interface between said strata, comprising sinking a well into said lower stratum, casing the well to a point in the removable mineral stratum near to but above said parting line, applying a fluid fracturing pressure to said formation through said casing above and below said interface to fracture the said strata substantially at their parting line interface, sinking another well substantially to said parting line interface, communicat- Cil References Cited in the file of this patent UNITED STATES PATENTS 1,960,932 Tracy May 29, 1934 2,584,605 Merriam et al Feb. 5, 1952 2,695,163 Pearce et al Nov. 23, 1954 2,712,355 Holi .lune 5, 1955 2,796,129 Brandon June 18, 1957

Claims (1)

1. THE PROCESS OF MINING A BED SOLUBLE IN A LIQUID, SAID BED LYING IN A DENSE UNDERGROUND FORMATION AND IN A STRATUM IMMEDIATELY ABOVE A LITHOLOGIC STRATUM INSOLUBLE IN SAID LIQUID AND HAVING A CLEAR PARTING LINE INTERFACE BETWEEN SAID STRAT, COMPRISING SINKING A WELL INTO SAID LOWER STRATUM, CASING THE WELL TO A POINT IN THE SOLUBLE BED NEAR TO BUT ABOVE THE SAID PARTING LINE, APPLYING A FLUID FRACTURING PRESSURE THROUGH SAID CASING, ABOVE AND BELOW SAID INTERFACE TO FRACTURE THE SAID STRATA SUBSTANTIALLY AT THEIR PARTING LINE INTERFACE, SINKING ANOTHER WELL SUBSTANTIALLY SO THEIR PARTING LINE INTERFACE, COMMUNICATING WITH SAID FRACTURE AND PROVIDING COMMUNICATION BETWEEN SAID WELLS SUBSTANTIALLY AT SAID PARTING LINE INTERFACE, INTRODUCING A LIQUID SOLVENT THROUGH ONE OF SAID WELLS TO THE PARTING LINE INTERFACE AT ONE PLACE ALONG THE FRACTURE AND WITHDRAWING THE SOLVENT THROUGH ANOTHER OF SAID WELLS AT A POINT REMOTE FROM THE PLACE AT WHICH THE SOLVENT IS INTRODUCED MBUT WITHIN THE COMPASS OF THE FRACTURE CAUSING THE SOLVENT TO FLOW ALONG THE FRACTURE AND TO DISSOLVE SAID SOLUBLE MINERAL FORMATION SUBSTANTIALLY FROM THE BOTTOM UPWARDLY.
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Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2919909A (en) * 1958-03-27 1960-01-05 Fmc Corp Controlled caving for solution mining methods
US2952449A (en) * 1957-02-01 1960-09-13 Fmc Corp Method of forming underground communication between boreholes
US2966346A (en) * 1959-04-30 1960-12-27 Gulf Research Development Co Process for removal of minerals from sub-surface stratum by liquefaction
US2979317A (en) * 1959-08-12 1961-04-11 Fmc Corp Solution mining of trona
US3018095A (en) * 1958-07-23 1962-01-23 Fmc Corp Method of hydraulic fracturing in underground formations
US3050290A (en) * 1959-10-30 1962-08-21 Fmc Corp Method of recovering sodium values by solution mining of trona
US3058730A (en) * 1960-06-03 1962-10-16 Fmc Corp Method of forming underground communication between boreholes
US3064957A (en) * 1959-04-20 1962-11-20 Internat Salt Company Inc Method of well completion
US3086760A (en) * 1960-05-25 1963-04-23 Fmc Corp Method of creating an underground communication
US3148000A (en) * 1962-02-28 1964-09-08 Pittsburgh Plate Glass Co Solution mining of potassium chloride
US3215471A (en) * 1963-02-28 1965-11-02 Exxon Production Research Co Enhancing potassium chloride dissolution by the addition of ferro- and ferricyanides
DE1224232B (en) * 1963-05-03 1966-09-08 Pittsburgh Plate Glass Co Process for dismantling underground potassium chloride deposits
US3353870A (en) * 1965-06-01 1967-11-21 Pittsburgh Plate Glass Co Method and apparatus for recovering a naturally occurring brine containing sodium carbonate
US3405974A (en) * 1966-02-21 1968-10-15 Intermountain Res & Dev Corp Process of underground salt recovery
US3407003A (en) * 1966-01-17 1968-10-22 Shell Oil Co Method of recovering hydrocarbons from an underground hydrocarbon-containing shale formation
FR2064112A1 (en) * 1969-10-02 1971-07-16 Occidental Petroleum Corp
US3822916A (en) * 1972-11-16 1974-07-09 Akzona Inc In-situ extraction of mineral values from ore deposits
US3998492A (en) * 1975-05-23 1976-12-21 Bechtel International Corporation Method for selectively extracting magnesium chloride hexahydrate from magnesium chloride hexahydrate bearing materials in situ by solution mining
US4264104A (en) * 1979-07-16 1981-04-28 Ppg Industries Canada Ltd. Rubble mining
EP0066972A2 (en) * 1981-05-20 1982-12-15 Texasgulf Inc. Solution mining of an inclined structure
US4508389A (en) * 1981-03-16 1985-04-02 Hodges Everett L Apparatus and method for hydraulically mining unconsolidated subterranean mineral formations
CN1069732C (en) * 1999-05-15 2001-08-15 洪泽县化工(集团)总公司 Mirabilite exploiting water-dissolution process with two wells communicated by horizontal hole
US20060039842A1 (en) * 2004-08-17 2006-02-23 Sesqui Mining, Llc Methods for constructing underground borehole configurations and related solution mining methods
EP2924233A1 (en) 2014-03-14 2015-09-30 Solvay SA Multi-well solution mining exploitation of an evaporite mineral stratum
US9638017B2 (en) 2012-10-25 2017-05-02 Solvay Sa Batch solution mining using lithological displacement of an evaporite mineral stratum and mineral dissolution with stationary solvent
US9803458B2 (en) 2013-03-13 2017-10-31 Tronox Alkali Wyoming Corporation Solution mining using subterranean drilling techniques
US10012064B2 (en) 2015-04-09 2018-07-03 Highlands Natural Resources, Plc Gas diverter for well and reservoir stimulation
US10344204B2 (en) 2015-04-09 2019-07-09 Diversion Technologies, LLC Gas diverter for well and reservoir stimulation
US10422210B1 (en) 2018-05-04 2019-09-24 Sesqui Mining, Llc. Trona solution mining methods and compositions
US10982520B2 (en) 2016-04-27 2021-04-20 Highland Natural Resources, PLC Gas diverter for well and reservoir stimulation
US11634978B2 (en) 2020-02-18 2023-04-25 Canatech Management Services Inc. Methods for recovering a mineral from a mineral-bearing deposit

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US1960932A (en) * 1933-07-21 1934-05-29 Solvay Process Co Method of mining
US2584605A (en) * 1948-04-14 1952-02-05 Edmund S Merriam Thermal drive method for recovery of oil
US2695163A (en) * 1950-12-09 1954-11-23 Stanolind Oil & Gas Co Method for gasification of subterranean carbonaceous deposits
US2712355A (en) * 1949-12-20 1955-07-05 Standard Oil Co Hydraulic fracturing of earth formations
US2796129A (en) * 1951-08-13 1957-06-18 Orpha B Brandon Oil recovery process

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US1960932A (en) * 1933-07-21 1934-05-29 Solvay Process Co Method of mining
US2584605A (en) * 1948-04-14 1952-02-05 Edmund S Merriam Thermal drive method for recovery of oil
US2712355A (en) * 1949-12-20 1955-07-05 Standard Oil Co Hydraulic fracturing of earth formations
US2695163A (en) * 1950-12-09 1954-11-23 Stanolind Oil & Gas Co Method for gasification of subterranean carbonaceous deposits
US2796129A (en) * 1951-08-13 1957-06-18 Orpha B Brandon Oil recovery process

Cited By (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2952449A (en) * 1957-02-01 1960-09-13 Fmc Corp Method of forming underground communication between boreholes
US2919909A (en) * 1958-03-27 1960-01-05 Fmc Corp Controlled caving for solution mining methods
US3018095A (en) * 1958-07-23 1962-01-23 Fmc Corp Method of hydraulic fracturing in underground formations
US3064957A (en) * 1959-04-20 1962-11-20 Internat Salt Company Inc Method of well completion
US2966346A (en) * 1959-04-30 1960-12-27 Gulf Research Development Co Process for removal of minerals from sub-surface stratum by liquefaction
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