US2833677A - Recording paper for spark recorders - Google Patents

Recording paper for spark recorders Download PDF

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US2833677A
US2833677A US51371655A US2833677A US 2833677 A US2833677 A US 2833677A US 51371655 A US51371655 A US 51371655A US 2833677 A US2833677 A US 2833677A
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layer
paper
spark
recording paper
metal
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/24Ablative recording, e.g. by burning marks; Spark recording
    • B41M5/245Electroerosion or spark recording
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31703Next to cellulosic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31971Of carbohydrate
    • Y10T428/31975Of cellulosic next to another carbohydrate
    • Y10T428/31978Cellulosic next to another cellulosic
    • Y10T428/31982Wood or paper

Definitions

  • the conductive backing acts as counter electrode for the marking electrode and the current is supplied, if desired but not necessarily, by providing a metal support, for example a drum at the place of marking.
  • the metal layer fulfills no electrical function but acts only as combustion material for the sparks. Therefore it does not need to have high conductivity and it may consist of discrete metal particles, the particle size and density of distribution corresponding to the solvent power of the record.
  • the advantage of the use of the metal. layer as a mark creating medium consists in the high heat absorption coefficient, the local overheating at only momentary heating and thereby making possible a sharp and quick marking with substantially weaker spark energy.
  • the insulating intermediate layer avoids the disadvantages of known record paper regarding action between the metal layer and the counter electrode.
  • the sparks traverse the space between the spark or marking electrode and the counter electrode always along the shortest path, that is vertically to the paper and not wandering laterally since their point of contact imparted on the counter electrode remains conductive.
  • the spark heat in the metal particles in the spark path is scattered in the insulating layer and the paper backing layer.
  • the metal coated record paper of this invention differs in that the marking is facilitated by the absence of moisture in the spark developing layer whereby the capacity for sorting and use of the record paper is improved.
  • the new record paper differs from known metallized condenser paper with a filling varnish layer for the uneven ness in the paper backing which cannot be present in condenser paper, apart from the dilferent purpose to be served.
  • paper instead of paper, other sheet material for example plastics, fabrics, etc. may be used to which the necessary electric conductivity has been imparted by impregnation or addition of. the material.
  • the paper backing may be made by known paper making methods.
  • finely divided carbon for example soot or lampblack.
  • finely divided metals and preferably oxidation preventing additions such as high atent O Patented May 6, 1958 molecular carbohydrates may be added to the paper mass and if desired also dark colored dyes or pigments.
  • the insulating intermediate layer is preferably made from a viscous solution of a cellulose derivative, and artificial materials, for example acetylcellulose of the linear polymer type.
  • the varnish may have dyes or pigments embodied therein in order to increase the optical contrast against the metal layer at the marking track.
  • the metal layer may be formed in various known Ways, for example spraying by compressed air (the Schoop method), thermal vaporizing, cathonic spraying and thermal decomposition, for example of carbonyls, acetylene acetones, etc.
  • the metal used may be light colored as zinc, aluminum and nickel, deposited on a dark colored base or binding. It is also possible to use a colored metal such as copper, bronze, etc. with a complementary colored backing, for example with a greenish or bluish color.
  • the record paper of Fig. 1 consists of a paper backing layer 1 made of equal parts by weight of paper pulp and soot along with conventional sizing agents as known in the art. it is coated on one side with a colorless layer 2; of acetylcellulose which serves as insulator and to smooth out the paper irregularities.
  • a colorless layer 2 of acetylcellulose which serves as insulator and to smooth out the paper irregularities.
  • the paper backing 1' also consists of soot containing pulp.
  • the intermediate layer 2 consists of polystyrol varnish containing a white pigment such as titanium oxide.
  • the record producing metal layer 3 consists of copper deposited by decomposition of copper acetic acetone.
  • the record paper of this invention is used in natural air dried condition with the metal layer moving opposite the spark electrode of the printing device.
  • the marking track is produced by a sharp edge burning oil or vaporization of the metal layer lying in the path of the sparks and is easily perceptible owing to contrast between the exposed paper backing and the undisturbed metal layer.
  • the air resistance of the metal layer is unlimited but if desired the printing can be fixed by spraying thcreover a varnish layer or other fixing medium.
  • a multi-layer recording paper for use in spark recording by printing intelligence by electrically burning away a metal coating comprising a basic paper layer which is conductive, a metallic top layer having a low electric conductance across its plane, and a uniform and continuous dielectric layer interposed between the two layers and throughout electrically separating said basic layer and said top layer.

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  • Duplication Or Marking (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)

Description

y 1958 w. H. e. BAUMLEIN 2,833,677
RECORDING PAPERFOR SPARK RECORDERS Filed June 7. 1955 Fly. 2
United. states RECORDING PAPER FDR SPARK REQORDERS Wilhelm Hermann Gunther Eaumlein, Gcrnsbach, Baden, Germany, assignor to Sch-oeller & Hoesch, Gernshacli, Baden, West-Germany This invention relates to record paper for use in apparatus of the kind in which writing designs and other intelligence is marked on paper by means of an electric spark.
It is therefore an object of the invention to provide a record paper in which a paper backing is electrically conductive and an insulating layer is interposed between the metal layer and the paper. in such a record paper the conductive backing acts as counter electrode for the marking electrode and the current is supplied, if desired but not necessarily, by providing a metal support, for example a drum at the place of marking. The metal layer fulfills no electrical function but acts only as combustion material for the sparks. Therefore it does not need to have high conductivity and it may consist of discrete metal particles, the particle size and density of distribution corresponding to the solvent power of the record. The advantage of the use of the metal. layer as a mark creating medium consists in the high heat absorption coefficient, the local overheating at only momentary heating and thereby making possible a sharp and quick marking with substantially weaker spark energy.
The insulating intermediate layer avoids the disadvantages of known record paper regarding action between the metal layer and the counter electrode. In the record paper according to the invention the sparks traverse the space between the spark or marking electrode and the counter electrode always along the shortest path, that is vertically to the paper and not wandering laterally since their point of contact imparted on the counter electrode remains conductive. Thus even at slow speed of paper travel there is a sharp marking track whereby the spark heat in the metal particles in the spark path is scattered in the insulating layer and the paper backing layer.
As compared with known record paper with conductive paper backing layer and electrolytically sensitive covering layer, the metal coated record paper of this invention differs in that the marking is facilitated by the absence of moisture in the spark developing layer whereby the capacity for sorting and use of the record paper is improved. The new record paper differs from known metallized condenser paper with a filling varnish layer for the uneven ness in the paper backing which cannot be present in condenser paper, apart from the dilferent purpose to be served.
Instead of paper, other sheet material for example plastics, fabrics, etc. may be used to which the necessary electric conductivity has been imparted by impregnation or addition of. the material.
The paper backing may be made by known paper making methods. Preferably there should be added to the paper mass in the hollander finely divided carbon, for example soot or lampblack. Also finely divided metals and preferably oxidation preventing additions such as high atent O Patented May 6, 1958 molecular carbohydrates may be added to the paper mass and if desired also dark colored dyes or pigments.
The insulating intermediate layer is preferably made from a viscous solution of a cellulose derivative, and artificial materials, for example acetylcellulose of the linear polymer type. The varnish may have dyes or pigments embodied therein in order to increase the optical contrast against the metal layer at the marking track.
The metal layer may be formed in various known Ways, for example spraying by compressed air (the Schoop method), thermal vaporizing, cathonic spraying and thermal decomposition, for example of carbonyls, acetylene acetones, etc.
The metal used may be light colored as zinc, aluminum and nickel, deposited on a dark colored base or binding. It is also possible to use a colored metal such as copper, bronze, etc. with a complementary colored backing, for example with a greenish or bluish color.
The drawing shows two embodiments of the invention enlarged scale in which Figures 1 and 2 are cross sections of the record paper.
The record paper of Fig. 1 consists of a paper backing layer 1 made of equal parts by weight of paper pulp and soot along with conventional sizing agents as known in the art. it is coated on one side with a colorless layer 2; of acetylcellulose which serves as insulator and to smooth out the paper irregularities. On this intermediate layer 2 is a thin skin layer about I'LL thick of metal 3, for example nickel formed by blowing or projecting nickel carbonyl vapor and then decomposing it by heat.
in the record paper of Fig. 2 the paper backing 1' also consists of soot containing pulp. The intermediate layer 2 consists of polystyrol varnish containing a white pigment such as titanium oxide. The record producing metal layer 3 consists of copper deposited by decomposition of copper acetic acetone.
The record paper of this invention is used in natural air dried condition with the metal layer moving opposite the spark electrode of the printing device.
The marking track is produced by a sharp edge burning oil or vaporization of the metal layer lying in the path of the sparks and is easily perceptible owing to contrast between the exposed paper backing and the undisturbed metal layer. The air resistance of the metal layer is unlimited but if desired the printing can be fixed by spraying thcreover a varnish layer or other fixing medium.
I claim as my invention:
1. A multi-layer recording paper for use in spark recording by printing intelligence by electrically burning away a metal coating, comprising a basic paper layer which is conductive, a metallic top layer having a low electric conductance across its plane, and a uniform and continuous dielectric layer interposed between the two layers and throughout electrically separating said basic layer and said top layer.
2. A multi-layer recording paper according to claim 1, in which said insulating layer contains a substance contrasting in color from said top layer.
3. A multi-layer recording paper according to claim 1, in which said top layer consists of a nickel deposit.
References Cited in the file of this patent UNITED STATES PATENTS 2,310,946 Finch Feb. 16, 1943 2,471,607 Calhin May 31, 1949 2,687,361 Traub Aug. 24, 1954- 2,726,l68 Roddin et a1. Dec. 6, 1955 2,726,179 Ortlieb et al. Dec. 6, 1955

Claims (1)

1. A MULTI-LAYER RECORDING PAPER FOR USE IN SPARK RECORDING BY PRINTING INTELLIGENCE BY ELECTRICALLY BURNING AWAY A METAL COATING, COMPRISING A BASIC PAPER LAYER WHICH IS CONDUCTIVE, A METALLIC TOP LAYER HAVING A LOW ELECTRIC CONDUCTANCE ACROSS ITS PLANE, AND A UNIFORM AND CONTINUOUS DIELECTRIC LAYER INTERPOSED BETWEEN THE TWO LAYERS AND THROUGHOUT ELECTRICALLY SEPARATING SAID BASIC LAYER AND SAID TOP LAYER.
US51371655 1954-06-09 1955-06-07 Recording paper for spark recorders Expired - Lifetime US2833677A (en)

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DE1125811X 1954-06-09

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2935369A (en) * 1956-08-23 1960-05-03 Little Inc A Record sustaining structures and methods for manufacturing same
US3113888A (en) * 1961-03-03 1963-12-10 Nat Starch Chem Corp Direct method for metalization of cast-coated paper
US3299433A (en) * 1964-10-21 1967-01-17 Reis electrosbnsitive recording
US3483074A (en) * 1965-06-08 1969-12-09 Grace W R & Co Matrix material for molding duplicate printing plates
US3657721A (en) * 1969-09-11 1972-04-18 Bosch Gmbh Robert Recording tape with partially oxidized aluminum film
US3831179A (en) * 1972-02-01 1974-08-20 Bosch Gmbh Robert Electrographic tape recording medium
US3861952A (en) * 1971-01-30 1975-01-21 Sony Corp Recording medium for a spark burning recorder
US4024546A (en) * 1971-03-09 1977-05-17 Robert Bosch G.M.B.H. Metal-coated carrier for recordings and process for determining the oxygen-attached aluminum contents in the coating
FR2406525A1 (en) * 1977-10-22 1979-05-18 Bosch Gmbh Robert REGISTRATION MEDIA FOR RECORDING DEVICES AND METHOD FOR ITS MANUFACTURING
US4319255A (en) * 1979-12-14 1982-03-09 International Business Machines Corporation Tinted metallized recording medium
US4419392A (en) * 1981-08-21 1983-12-06 International Business Machines Corporation Process for producing compact lacquer layers for record carriers
US4483902A (en) * 1980-02-27 1984-11-20 International Business Machines Corporation Record carrier

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2310946A (en) * 1939-04-07 1943-02-16 William G H Finch Facsimile recording paper
US2471607A (en) * 1947-01-09 1949-05-31 Finch Telecommunications Inc Facsimile recording papers
US2687361A (en) * 1949-04-04 1954-08-24 Bosch Gmbh Robert Metal coated recording medium for recording instruments
US2726168A (en) * 1951-07-11 1955-12-06 Western Union Telegraph Co Electrosensitive recording and duplicating blank
US2726179A (en) * 1952-01-07 1955-12-06 Bosch Gmbh Robert Recording tapes having a metal layer applied by vapour deposition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2310946A (en) * 1939-04-07 1943-02-16 William G H Finch Facsimile recording paper
US2471607A (en) * 1947-01-09 1949-05-31 Finch Telecommunications Inc Facsimile recording papers
US2687361A (en) * 1949-04-04 1954-08-24 Bosch Gmbh Robert Metal coated recording medium for recording instruments
US2726168A (en) * 1951-07-11 1955-12-06 Western Union Telegraph Co Electrosensitive recording and duplicating blank
US2726179A (en) * 1952-01-07 1955-12-06 Bosch Gmbh Robert Recording tapes having a metal layer applied by vapour deposition

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2935369A (en) * 1956-08-23 1960-05-03 Little Inc A Record sustaining structures and methods for manufacturing same
US3113888A (en) * 1961-03-03 1963-12-10 Nat Starch Chem Corp Direct method for metalization of cast-coated paper
US3299433A (en) * 1964-10-21 1967-01-17 Reis electrosbnsitive recording
US3483074A (en) * 1965-06-08 1969-12-09 Grace W R & Co Matrix material for molding duplicate printing plates
US3657721A (en) * 1969-09-11 1972-04-18 Bosch Gmbh Robert Recording tape with partially oxidized aluminum film
US3861952A (en) * 1971-01-30 1975-01-21 Sony Corp Recording medium for a spark burning recorder
US4024546A (en) * 1971-03-09 1977-05-17 Robert Bosch G.M.B.H. Metal-coated carrier for recordings and process for determining the oxygen-attached aluminum contents in the coating
US3831179A (en) * 1972-02-01 1974-08-20 Bosch Gmbh Robert Electrographic tape recording medium
FR2406525A1 (en) * 1977-10-22 1979-05-18 Bosch Gmbh Robert REGISTRATION MEDIA FOR RECORDING DEVICES AND METHOD FOR ITS MANUFACTURING
US4319255A (en) * 1979-12-14 1982-03-09 International Business Machines Corporation Tinted metallized recording medium
US4483902A (en) * 1980-02-27 1984-11-20 International Business Machines Corporation Record carrier
US4419392A (en) * 1981-08-21 1983-12-06 International Business Machines Corporation Process for producing compact lacquer layers for record carriers

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FR1125811A (en) 1956-11-08
LU33625A1 (en)

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