US2823988A - Composite matter - Google Patents
Composite matter Download PDFInfo
- Publication number
- US2823988A US2823988A US534626A US53462655A US2823988A US 2823988 A US2823988 A US 2823988A US 534626 A US534626 A US 534626A US 53462655 A US53462655 A US 53462655A US 2823988 A US2823988 A US 2823988A
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- United States
- Prior art keywords
- metal
- refractory material
- micron
- slip
- powder
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000002131 composite material Substances 0.000 title description 16
- 229910052751 metal Inorganic materials 0.000 claims description 60
- 239000002184 metal Substances 0.000 claims description 60
- 239000000203 mixture Substances 0.000 claims description 43
- 239000000843 powder Substances 0.000 claims description 43
- 239000011819 refractory material Substances 0.000 claims description 32
- 238000002844 melting Methods 0.000 claims description 24
- 230000008018 melting Effects 0.000 claims description 21
- 239000011159 matrix material Substances 0.000 claims description 20
- 239000011246 composite particle Substances 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 13
- 230000002401 inhibitory effect Effects 0.000 claims description 11
- 238000011084 recovery Methods 0.000 claims description 11
- 238000005245 sintering Methods 0.000 claims description 10
- 239000004615 ingredient Substances 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 8
- 230000004927 fusion Effects 0.000 claims description 7
- 230000001427 coherent effect Effects 0.000 claims description 4
- 238000007493 shaping process Methods 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 description 34
- 239000000956 alloy Substances 0.000 description 34
- 239000000047 product Substances 0.000 description 30
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 18
- 239000002245 particle Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 10
- 229910052804 chromium Inorganic materials 0.000 description 10
- 239000011651 chromium Substances 0.000 description 10
- 239000003112 inhibitor Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 229910052759 nickel Inorganic materials 0.000 description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 229910000601 superalloy Inorganic materials 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 235000010210 aluminium Nutrition 0.000 description 6
- 239000010941 cobalt Substances 0.000 description 6
- 229910017052 cobalt Inorganic materials 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- 238000004663 powder metallurgy Methods 0.000 description 5
- 238000004881 precipitation hardening Methods 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002923 metal particle Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- 238000012937 correction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- -1 zircomium Chemical compound 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LTPBRCUWZOMYOC-UHFFFAOYSA-N Beryllium oxide Chemical compound O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910052790 beryllium Inorganic materials 0.000 description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 238000001192 hot extrusion Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 241000183024 Populus tremula Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000001996 bearing alloy Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 229940035427 chromium oxide Drugs 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S75/00—Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
- Y10S75/95—Consolidated metal powder compositions of >95% theoretical density, e.g. wrought
- Y10S75/951—Oxide containing, e.g. dispersion strengthened
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S75/00—Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
- Y10S75/956—Producing particles containing a dispersed phase
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12181—Composite powder [e.g., coated, etc.]
Definitions
- Thepresent invention relates to finely divided composition of matter having particular utility in the powder metallurgical production of reinforced heat resistant metal products capable of sustaining high strength proper'ties and high resistance to creep at elevated temperaturesup .to 1000 C. and higher for prolonged periods of time. .
- the invention also contemplates a method for producing heat resistant articles.
- the typical wrought super-alloy usually comprises awrought solid solution alloy containing chromium and at least one metal of the iron group as essential alloying ingredients together with hardening elements to stiffen the alloy for use at high temperatures.
- the stiffening may be achieved in several ways:- (1) by hardening the solid solution matrix by employing such matrix hardening. elements as molybdenum, tungsten, columbium-, etc., (2) by employing special elements capable of'forrning compounds of low solubility which precipitation-harden. the alloy, for example titanium, aluminum, zirconium, etc., (3) by employing other elements which form a second phase upon solidification which hardens the alloy, etc.
- the hardening by the second method is achieved by heat treatment and may be employed to augment the hardening of the first method.
- the hardening by the third method is achieved by casting. Most of the conventional super-alloys are cast nowadays.
- the wrought super-alloys are susceptible to precipitation hardening.
- the precipitation hardening elements in the alloy are taken into solids'olution by heating the alloy to a high solution temperature, for example 1000 C. to 1250 C., followed by rapid cooling to keep the precipitation hardening elements in solution' .
- the precipitation hardening is then achieved by reheating the alloy at a lower temperature, for example within the range of about 550 C. to 850 C., for a time sufficient to produce a critical dispersion of a fine precipitate throughout the matrix which is generally invisible, even at a magnification of 2000 times and higher when achieving maximum benefit.
- Such alloys in the hardened condition exhibit improved resistance to creep at elevated service temperatures up to about 900 C.
- thealloys tend to soften due to two effects. If the service temperature is in the neighborhood of about 850 C. to 900 C. and slightly higher, the alloys tend to soften due to over-aging. This 2,823,983 Patented Feb. 18, 1958 phenomenon is believed to be due to a coalescence of the fine precipitate to large, coarse particles which is generally accompanied by a falling off in hardness and hence lower resistance to creep. Moreover, when the service temperature is in the neighborhood of 1000 C. to
- a slip inhibiting refractory compound as the hardener having a high melting point and characterized by a low degree of solubility in the solid solution matrix of the heat resistant alloy in which it was contained.
- the compound had the property of behaving like a recovery inhibitor, that is, it acted as a deterrent to recrystallization and to abnormal grain growth.
- the compound was stable and was not prone to decompose substantially at elevated temperatures and, when uniformly dispersed throughout the matrix of a heat resistant alloy, the alloy was capable of sustaining its mechanical properties for prolonged periods of time at elevated temperatures that normally caused similar heat resistant alloys to soften and creep appreciably.
- the slip inhibitors contemplated in the copending case comprised mainly the carbides, borides, sili cides and nitrides of titanium, zirconium, columbium, tantalum, hafnium and vanadium, and also the disilicides of molybdenum and tungsten.
- the compound was incorporated into the matrix by utilizing powder metallurgy techniques. In the copending case this was achieved by in a com-. their cause mixing finely divided slip and recovery inhibitor compound with finely divided heat resistant matrix metal and shaped to a desired configuration by pressing the powder mixture in a die mold by employing a pressure varying from the about 30 to l50tons per square inch.
- the resulting body was then sintered at an elevated temperature to consolidate it sufficiently so it could be subsequently hot worked, the sintering being conducted at a temperature of at least about ll C. but not exceeding about below the point of incipient fusion at a subatmospheric pressure generally not exceeding about 100 microns and preferably notexceeding about 50 microns.
- the sintered body was then hot worked, for example by hot extrusion, forging, swaging, etc., until its cross-section had been reduced at least 50% and preferably at least 90% to 95% so that substantially .all of the voids had been eliminated after which the hot worked body was'fabricated into the desired finished product.
- the slipinhibitor phase ranged from about 5% to 20% by volumeof the total composition, the balance of which was made up of a ductile nickel or cobalt-base heat .resistant alloy.
- The'heat resistant alloys comprised about 5 to 30% by weight of chromium and up to about 25% by'weig'ht of iron, substantially the balance of the alloy being at least one metal selected from the group consistihg of up to about 90% nickel and up to 70% cobalt, the sum of nickel and cobalt contents being at least 40%, and preferably 50%, of the total alloy composition, allowancesbeing made for the presence of optionalamounts of other elements commonly employed in heat resisting alloys.
- finely divided powder of the heat resistant matrix alloy was used, the maximum particle size not exceeding 40 microns and preferably not exceeding about 5 microns.
- the slip inhibitor was controlled at a particle size not exceeding microns, and preferably not exceeding two or even one micron. It was found that'the uniform dispersion of the slip inhibitor throughout the matrix metal was very important and that prolonged mixing times had to be resorted to in order to achieve as uniform a dispersion as possible.
- the powders were stored for any length of time and subjected inadvertently to extraneous vibration usually prevailing in buildings containing large presses, reciprocating vacuum pumps, and the like, the powders tended to segregate due to the marked differences in density'between the slip inhibitor phase and the matrix metal.- Unless this segregation was caught in the nick of time and the powders re-mixed, the resulting product would not have the best attainable dispersion of the slip in hibito'r phase. Where the slip inhibitor phase was deficie'ntin" a" portion of the final product, the product would be soft, and where the phase was unduly concentrated in another portion of the final product, the product would be hard and somewhat brittle.
- the present invention overcomes the foregoing disadvantages by providing a novel powder composition comprised of composite particles of'controlled composition and size which powders, during storage, are substantially non-segregatabie with respect to composition.
- the composition ofmatter contemplated by the invention comprises a free flowing mass of finely divided com? posite particles in which substantially all of the particles each contain as essential constituents a strong high melting point refractory material, for example high melting point refractory oxides, and a relatively high melting point ductile metal, for example a-heat resisting alloy,,in integral relation therewith, the composite structure of the powder being of the type where one constituent is substantially covered by the other.
- the composition ofthe powder is controlled to contain about 0.5% to by volume'of the refractory material, substantially the balance being made up of the ductile metal. It is'preferred in practicing the invention that the refractory material be employed over a narrow range of 2% to 15% by volume, the most preferred range being 5% to 10%.
- the size of the composite powder particles should not exceed 40 microns, with the desired size not exceeding 10 microns and preferably not exceeding 5 microns.
- the most uniform substantially non-segregatable composite powder with respect to composition and dispersion of the refractory material is obtained at sizes at or below 5 microns.
- the high melting point refractory material contemplated by the'invention as an essential ingredient of the compositepowder includes oxides of calcium, beryllium, magnesium, aluminum, titanium, zirconium, silicon, chromium, thorium, cerium, etc.
- These and similar refractory materials which also include the silicides, borides, nitrides and carbides of the refractory metals tungsten, molybdenum, chromium, titanium, zircomium, tantalum, columbium, hafnium, etc., are relatively stable at elevated temperatures and have melting or softening points in excess of about 1600 C.
- Ductile metals contemplated by the invention as an essential ingredient of the composite particles include metals having melting points in excess of about 1250 C. Such metals include the iron group metals, iron, nickel and cobalt as well as ductile heat resistant alloys based on these and other metals such as chromium.
- the ductile metals vor alloys'which have been found preferably suited for the powder composition include a composition comprising about 5 to by weight of chromium and up to about 25% by weight of iron, substantially the balance'of the alloy containing up to about 90% nickel and up to 70% cobalt, the sum of the nickel and cobalt contents'b'eing at least about 40%, and preferably of the total alloy composition. The term substantially the balance when.
- theia'lloy- may contain in addition to chromium, either tungsten or molybdenum, or both, in amounts not inconsistent with maintaining the ductile properties of the matrix metal.
- sma1l' :amounts of ,.other elements' may be present either incidentally or asregular additions such as manganese, silicon, boron, etc. With respect to the carbon and nitrogen contents, these elements generally do not exceed about 0.25% and about 0.1%, respectively; and preferably should be maintained as low as possible;
- the composite particles comprise a nucleus of the refractory oxide substantially covered by a controlled layer of ductile metal.
- the average composition of the refractory oxide by volume making up the particle may range broadly from about 0.5% to 25% with the intermediate range controlled from about 2% to and the preferred range'froin about 5% to 10%.
- the sizes of the phases in the composite particles preferably suitable in forming the desiredpowder composition for composite particle sizes below 5 microns :are given in microns as follows:
- Composite powder of the foregoing type is particularly advantageous because of its substantially non-segregatable characteristics and does not require the prolonged mixing times mentioned in the copending case.
- the composite powder of the aforementioned characteristics may be produced by methods well known in the art.
- finely divided aluminum oxide, or other hard phases may be coated with an appropriate thickness of nickel or cobalt by chemical deposition under'controlled conditions from a suitable aqueous solution containing either one of the metals.
- the hard phase may be coated with either of these metals by the thermal decomposition of their respective gaseous carbonyls; or by the thermal decomposition of their halides.
- the hardphase particles may also be coated with a ductile metal.
- ductile metal particles are each substantially covered with an integral layer of a hard refractory phase, for example a 1 yet of. aluminum oxide.
- Such a layer may be obtained by coating a ductile metal'particle with metallic aluminum, for example by vapor deposition, or by the decomposition of an aluminum halide, etc., followed by an oxidizing treat ment at an elevated temperature in an atmosphere oxidizing to aluminum.
- the powder is briquetted or shaped at room temperature into ingots at pressures ranging from about 30 to 150 tons per square inch. They; may also be hot pressed at temperatures which case the pressures can be below'30tons per square inch.
- An example of 'a' powder that can be pressed in this manner is one ,com-.
- I prising composite particles having a hard phase nucleus of aluminum oxide covered by miumall oy, e. g. nickel and 20% chromiu'm,the composite particles not exceeding about 5 microns in diameter with the composition of the hard phase acre rte ing to about 5% by volume of the total composition.
- miumall oy e. g. nickel and 20% chromiu'm
- the ingots formed are sintered under substantially nonreactive conditions at an elevated temperature to consolidate them sufficiently so they can be subsequently hot worked.
- the sintering is preferably conducted at a tem-' peratureof at least about 1100 C. but not exceeding about 5'' below the point of incipient fusion, e. g. at a subatmospheric pressure generally 100 microns and preferably not exceeding about 50 microns. If necessary, sintering may be carried outintwo stages, the first stage being carried out at a lower temperature range than the second stage which may em- 2 temperature range of up to about 5 C.”
- the sintered ingots are then hot worked, for example by hot extrusion, forging, swaging, etc., until their crosssections have been reduced at least 50% and preferably at least to so that substantially all of thevoids have been eliminated after which the hot are fabricated into the desired finished products.
- test comprises heating a test specimen to an elevated temperature, say 1000 C.
- the alloy contains elemental titanium and/or alum'inumias age hardeners, the alloysoftens due'to ove'r perature range between 850 C. and l050 C. for prolonged periods of time.
- the novel compositeipowder composition iof the invention insures :the obtaining of uniform products because of its ease of handling and its substantiallyxnon+segregatable characteristics.
- a composition of matter suitable .forthe powder metallurgy production of wroughtf reinforced products comprising free flowingfinely divided composite particles in which substantially each of the particlescontain as 'essential constituents a strong highmelting point hard and substantially insoluble refractory material and a ductile metal of melting point above 1250 C.
- the refractory material ranging from about 0.5% to 25% by volume of the total composition for a particle size of the composite powder of up to about five microns .for composite powder in which the metal forms a coating on the refractory material and for composite powder in which the refractory material forms acoating on the metal, the thickness of the metal coating on the refractory material ranging from.
- the thickness of the refractory' material coating on'the ductile metal ranging up to about 0.3 micron.
- a composition of matter suitable for the powder metallurgy production of wrought reinforced products comprising free flowing finely divided composite particles containing a strong high melting point refractory material integrally coated with a ductile metal of melting point above 1250 C., the amount of refractory oxide ranging from about 2% to by volume of the total composition for a particle size of the composite particles of up to about five microns, the thickness of the ductile metal coating on the refractory material ranging from about 0.05
- the thickness of the ductile metal coating on the refractory material ranges from about 0.05 to 0.5 micron.
- a composition of matter suitable for the powder metallurgy production of wrought reinforced products comprising'free flowing finely divided composite particles in'which ductile metal particles of melting point above 1250.”
- C. are each substantially coated with a layer of a strong high melting point refractory material, the amount of refractory material in the powder ranging from about 2% to 15% 'by volume of the total composition for a particle sizeof the composite particles of up to about five microns, the thickness of the oxide coating on the ductile metal ranging up to about 0.3 micron.
- a methodfor producing reinforced metal products capable of sustaining highstrength-properties at elevated temperatures which comprises providing free flowing, ne y di id d o p s epa c es ot xcee i g 0 m crons in size containing as essential ingredients a strong high-melting.
- the refractory material coats the ductile metal its thickness ranges up to about0l3 micron, the amount of the hard refractory material ranging from about 0.5% to about 25% by volume of the total powder composition, shapirig said powder mixture to a coherent body, sintering the shaped body at a temperature of at least about '1'100' C.
- a method for producing reinforced metal products capable of sustaining high strength properties at elevated temperatures which comprises providing free flowing, finely divided composite particles ranging in size up to about'5 microns containing 'as essential ingredients a strong high meltingpoint hard and substantially insolublerefractory material as a slip and recovery inhibiting phase integrally coat'ed with ;a ductile metal layer "of melting point above 1250* C. of thickness ranging from about 0.'05;to one micron, theamoun't of the hard refractory material ranging from about 2% to about 15 by volume of the total powder composition, shaping said powder mixture -to a 'coherent body, sintering the shaped body at a temperature of at least about ll00 C.
- a method for producing reinforced metal products capable of sustaining high strength properties at elevated temperatures which comprises providing free flowing, finely divided composite particles ranging in size up to about 5 microns containing as essential ingredients a strong high melting point hard and substantially insoluble refractory material as a slip and recovery inhibiting phase forming an integral coating on a ductile metal particle of melting point above 1250 C., the thickness of the refractory material coating ranging up to about 0.3 micron, the amount of the hard refra tory material ranging from about 2% to about 15% by volume of the total powder composition, shaping said powder mixture to a coherent body, sintering the shaped body at a temperature of at least about 1100 C.
- a wrought reinforced powder metallurgy metal product capable of sustaining high strength properties and high resistance to creep at elevated temperatures up to about 1000 C. and higher for prolonged periods of time which comprises about 0.5% to 25% by volume of discrete substantially insoluble slip and recovery inhibiting refractory material of up to about 3 microns in size dispersed substantially uniformly through a ductile matrix metal of melting point above 1250 C., the distance between the discrete particles being less than 2 microns.
Description
COMPOSITE MATTER Nicholas J. Grant, Winchester, Mass, and Claus G- Goetzel, Hastings-on-Hndson, N. Y., assignors to Sintercast Corporation of America, Yonkers, N. Y., a corporation of New York No Drawing. Application September 15, 1955 Serial No. 534,626
14 Claims. (Cl. 75.5)
Thepresent invention relates to finely divided composition of matter having particular utility in the powder metallurgical production of reinforced heat resistant metal products capable of sustaining high strength proper'ties and high resistance to creep at elevated temperaturesup .to 1000 C. and higher for prolonged periods of time. .The invention also contemplates a method for producing heat resistant articles.
'It is well known that considerable progress has been The typical wrought super-alloy usually comprises awrought solid solution alloy containing chromium and at least one metal of the iron group as essential alloying ingredients together with hardening elements to stiffen the alloy for use at high temperatures. Generally, the stiffening may be achieved in several ways:- (1) by hardening the solid solution matrix by employing such matrix hardening. elements as molybdenum, tungsten, columbium-, etc., (2) by employing special elements capable of'forrning compounds of low solubility which precipitation-harden. the alloy, for example titanium, aluminum, zirconium, etc., (3) by employing other elements which form a second phase upon solidification which hardens the alloy, etc. The hardening by the second method is achieved by heat treatment and may be employed to augment the hardening of the first method. The hardening by the third method is achieved by casting. Most of the conventional super-alloys are cast nowadays.
;Generally, most of the wrought super-alloys are susceptible to precipitation hardening. The precipitation hardening elements in the alloy are taken into solids'olution by heating the alloy to a high solution temperature, for example 1000 C. to 1250 C., followed by rapid cooling to keep the precipitation hardening elements in solution' ,The precipitation hardening is then achieved by reheating the alloy at a lower temperature, for example within the range of about 550 C. to 850 C., for a time sufficient to produce a critical dispersion of a fine precipitate throughout the matrix which is generally invisible, even at a magnification of 2000 times and higher when achieving maximum benefit. Such alloys in the hardened condition exhibit improved resistance to creep at elevated service temperatures up to about 900 C.
However, at higher temperatures, thealloys tend to soften due to two effects. If the service temperature is in the neighborhood of about 850 C. to 900 C. and slightly higher, the alloys tend to soften due to over-aging. This 2,823,983 Patented Feb. 18, 1958 phenomenon is believed to be due to a coalescence of the fine precipitate to large, coarse particles which is generally accompanied by a falling off in hardness and hence lower resistance to creep. Moreover, when the service temperature is in the neighborhood of 1000 C. to
1100 C. and higher, the precipitate begins to go into,
and clearances of rotating and stationary members of' thermal engines must be kept extremely small, any variation from normal creep can be dangerous and lead to serious damage of the power plant, even to the extent where the whole engine may be temporarily stalled or possibly totally destroyed.
In an attempt to overcome the foregoing difiiculties, super-alloys were proposed with higher amounts of hardening elements, e. g. carbon, to further stiffen them so as to increase their sustaining power at elevated temperatures. While this was helpful to a certain extent, the stiffened alloys generally had lower ductility which was accompanied by a low resistance to impact. Moreover, the alloys could not be worked easily and generally were subject to cracking during the hot working operations. This was especially true when the super-alloys contained particularly high amounts of matrix hardening elements, e. g. tungsten, molybdenum, etc., and high amounts of precipitation-hardening elements such as titanium, alumi-- num, zirconium, etc. Although many attempts were made to overcome the foregoing difliculties, none as far as we are aware, was entirely successful when carried into practice commercially.
In copending application U. S. Serial No. 452,595, filed August 27, 1954, and assigned to the same assignee, it was shown that heat resistant super-alloys with improved sustaining power at elevated temperature, espe cially sustained resistance to creep at elevated temperatures, well above 800 C. and even above 1000 C., in combination with high resistance to impact, could be produced by employing substantial amounts of a hardening constituent which would normally embrittle the alloy. By employing the hardening constituent special manner, it was pointed out that heat resistant positions could be produced capable of maintaining stiffness at elevated temperatures which normally conventional alloys to soften and creep substantially.
It was proposed in the copending case to use a slip inhibiting refractory compound as the hardener having a high melting point and characterized by a low degree of solubility in the solid solution matrix of the heat resistant alloy in which it was contained. The compound had the property of behaving like a recovery inhibitor, that is, it acted as a deterrent to recrystallization and to abnormal grain growth. The compound was stable and was not prone to decompose substantially at elevated temperatures and, when uniformly dispersed throughout the matrix of a heat resistant alloy, the alloy was capable of sustaining its mechanical properties for prolonged periods of time at elevated temperatures that normally caused similar heat resistant alloys to soften and creep appreciably. The slip inhibitors contemplated in the copending case comprised mainly the carbides, borides, sili cides and nitrides of titanium, zirconium, columbium, tantalum, hafnium and vanadium, and also the disilicides of molybdenum and tungsten. The compound was incorporated into the matrix by utilizing powder metallurgy techniques. In the copending case this was achieved by in a com-. their cause mixing finely divided slip and recovery inhibitor compound with finely divided heat resistant matrix metal and shaped to a desired configuration by pressing the powder mixture in a die mold by employing a pressure varying from the about 30 to l50tons per square inch. The resulting body was then sintered at an elevated temperature to consolidate it sufficiently so it could be subsequently hot worked, the sintering being conducted at a temperature of at least about ll C. but not exceeding about below the point of incipient fusion at a subatmospheric pressure generally not exceeding about 100 microns and preferably notexceeding about 50 microns. The sintered body was then hot worked, for example by hot extrusion, forging, swaging, etc., until its cross-section had been reduced at least 50% and preferably at least 90% to 95% so that substantially .all of the voids had been eliminated after which the hot worked body was'fabricated into the desired finished product.
The slipinhibitor phase ranged from about 5% to 20% by volumeof the total composition, the balance of which was made up of a ductile nickel or cobalt-base heat .resistant alloy. The'heat resistant alloys comprised about 5 to 30% by weight of chromium and up to about 25% by'weig'ht of iron, substantially the balance of the alloy being at least one metal selected from the group consistihg of up to about 90% nickel and up to 70% cobalt, the sum of nickel and cobalt contents being at least 40%, and preferably 50%, of the total alloy composition, allowancesbeing made for the presence of optionalamounts of other elements commonly employed in heat resisting alloys. In producing the requisite powder mixture in order to obtain as uniform a dispersion of the slip inhibitor compound as possible, finely divided powder of the heat resistant matrix alloy was used, the maximum particle size not exceeding 40 microns and preferably not exceeding about 5 microns. The slip inhibitor was controlled at a particle size not exceeding microns, and preferably not exceeding two or even one micron. It was found that'the uniform dispersion of the slip inhibitor throughout the matrix metal was very important and that prolonged mixing times had to be resorted to in order to achieve as uniform a dispersion as possible. Wet mixing times of the order of about 120 hours and higher in a liquid vehicle, such as xylene, trichlorethylene or carbon tetrachloride, in carbide-lined ball mills containing cemented tungsten carbide balls were usually necessary. The results achieved by the reinforced product of the invention described in the copending case'indicated a considerable improvement over conventional type wrought super-alloys. The product was not only stiffer but was also stronger and resisted softening at high operating elevated temperatures.
The primary disadvantage and short coming of the foregoing'method was the fact that even when extremely long mixing times were employed, and exceptionally large batches of the powder ingredients were blended in the mixing mills, a perfect mixture could never be obtained. As a result, it was not possible to obtain an ideal dispersion of the slip inhibitor hard phase in the matrix of the ultimate product produced from the mixed powders. Even when the powders were blended under the best possible mixing conditions, there was still the problem of segregation of the mixed powders during storage, han dling, processing, pressing and'other steps of the manufacture leading to the ultimate reinforced product. For example, if the powders were stored for any length of time and subjected inadvertently to extraneous vibration usually prevailing in buildings containing large presses, reciprocating vacuum pumps, and the like, the powders tended to segregate due to the marked differences in density'between the slip inhibitor phase and the matrix metal.- Unless this segregation was caught in the nick of time and the powders re-mixed, the resulting product would not have the best attainable dispersion of the slip in hibito'r phase. Where the slip inhibitor phase was deficie'ntin" a" portion of the final product, the product would be soft, and where the phase was unduly concentrated in another portion of the final product, the product would be hard and somewhat brittle. Such non-uniformity tended to result in unpredictable behavior of the product at elevated temperatures. According to the copending case it was important that the spacing of the hard phase be preferably maintained at an average distance ranging from about 0.1 to 0.5 micron. However, it was not al-' ways possible to insure such uniform dispersion without taking infinite care and subjecting the powders to prolonged mixing times. 1
The present invention overcomes the foregoing disadvantages by providing a novel powder composition comprised of composite particles of'controlled composition and size which powders, during storage, are substantially non-segregatabie with respect to composition.
The composition ofmatter contemplated by the invention comprisesa free flowing mass of finely divided com? posite particles in which substantially all of the particles each contain as essential constituents a strong high melting point refractory material, for example high melting point refractory oxides, and a relatively high melting point ductile metal, for example a-heat resisting alloy,,in integral relation therewith, the composite structure of the powder being of the type where one constituent is substantially covered by the other. The composition ofthe powder is controlled to contain about 0.5% to by volume'of the refractory material, substantially the balance being made up of the ductile metal. It is'preferred in practicing the invention that the refractory material be employed over a narrow range of 2% to 15% by volume, the most preferred range being 5% to 10%. The size of the composite powder particles should not exceed 40 microns, with the desired size not exceeding 10 microns and preferably not exceeding 5 microns. The most uniform substantially non-segregatable composite powder with respect to composition and dispersion of the refractory material is obtained at sizes at or below 5 microns.
The high melting point refractory material contemplated by the'invention as an essential ingredient of the compositepowder includes oxides of calcium, beryllium, magnesium, aluminum, titanium, zirconium, silicon, chromium, thorium, cerium, etc. These and similar refractory materials, which also include the silicides, borides, nitrides and carbides of the refractory metals tungsten, molybdenum, chromium, titanium, zircomium, tantalum, columbium, hafnium, etc., are relatively stable at elevated temperatures and have melting or softening points in excess of about 1600 C.
Ductile metals contemplated by the invention as an essential ingredient of the composite particles include metals having melting points in excess of about 1250 C. Such metals include the iron group metals, iron, nickel and cobalt as well as ductile heat resistant alloys based on these and other metals such as chromium. The ductile metals vor alloys'which have been found preferably suited for the powder composition include a composition comprising about 5 to by weight of chromium and up to about 25% by weight of iron, substantially the balance'of the alloy containing up to about 90% nickel and up to 70% cobalt, the sum of the nickel and cobalt contents'b'eing at least about 40%, and preferably of the total alloy composition. The term substantially the balance when. applied to the aforementioned composition does not exclude the presence of other elements in amounts which do not adversely affect the basic characteristics of the ductile alloy used in forming the composite powder. Thus, theia'lloy-may contain in addition to chromium, either tungsten or molybdenum, or both, in amounts not inconsistent with maintaining the ductile properties of the matrix metal. This is also true for other elements which may be present in the ductile metal, such as columbium, tantalum, titanium, aluminum, etc, provided these and the other elements are not present in amounts that produce phases detrimental to the properties of the alloy, such as Sthebrittle sigma phase in chromium-bearing alloys or other phases; Asthosej skilled in the art will readily understand, sma1l' :amounts of ,.other elements'may be present either incidentally or asregular additions such as manganese, silicon, boron, etc. With respect to the carbon and nitrogen contents, these elements generally do not exceed about 0.25% and about 0.1%, respectively; and preferably should be maintained as low as possible;
. The structure and the composition and size of the composite particle are important in achieving the results of the invention. In a preferred embodiment, the composite particles comprise a nucleus of the refractory oxide substantially covered by a controlled layer of ductile metal. As stated hereinbefore, the average composition of the refractory oxide by volume making up the particle may range broadly from about 0.5% to 25% with the intermediate range controlled from about 2% to and the preferred range'froin about 5% to 10%.- The sizes of the phases in the composite particles preferably suitable in forming the desiredpowder composition for composite particle sizes below 5 microns :are given in microns as follows:
' Thickness Range Diameter of Oxide Phase 7 of Metal Coating Working Up to 3 (preferably not exceeding 1)- 0.05 to 1 0 Preferred 0.06 to 0. 0.05 to 0 5 ptimum 0.05 to 0.3 0.05 to 0 2 Utilization of the foregoing type of composite powder enables the production of a reinforced wrought product in which the average distance between the oxide nuclei may be maintained relatively uniformly throughout the product, the interparticle distance being maintained less than 2 microns and usually below 1 micron. The preferred interparticle distance between the oxide nuclei. ranges from about 0.025 -to 0.5 micron with the most preferred distance for optimum combination of properties in the reinforced product ranging from about 0.05 to 0.4 micron.
Composite powder of the foregoing type is particularly advantageous because of its substantially non-segregatable characteristics and does not require the prolonged mixing times mentioned in the copending case. The composite powder of the aforementioned characteristics may be produced by methods well known in the art. For example finely divided aluminum oxide, or other hard phases, may be coated with an appropriate thickness of nickel or cobalt by chemical deposition under'controlled conditions from a suitable aqueous solution containing either one of the metals. Or, if desired, the hard phase may be coated with either of these metals by the thermal decomposition of their respective gaseous carbonyls; or by the thermal decomposition of their halides. The hardphase particles may also be coated with a ductile metal. by thermal vaporization in a vacuum, for example with .a heat resistant alloy comprising 80% nickel and chromium or other similarheat resistant alloys coming within the broad definition of. such ductile alloys: disclosed herein. In other words any convenient method for coating the hard phase with a ductile metal may be used in producing the novel powder composition of the invention. Another type of composite powder composition con: templated by the invention is one in which ductile metal particles are each substantially covered with an integral layer of a hard refractory phase, for example a 1 yet of. aluminum oxide. Such a layer may be obtained by coating a ductile metal'particle with metallic aluminum, for example by vapor deposition, or by the decomposition of an aluminum halide, etc., followed by an oxidizing treat ment at an elevated temperature in an atmosphere oxidizing to aluminum. In similar manner other types of integral hard phase layers may be produced on ductile metal particles from such metals as beryllium' to form beryllia) where the metal is still solid in reinforced product of the invention can ,6 magnesium (to form magnesia), calcium (to form calcia), silicon: (toform silica), titanium (to form titania), zirco- (to'form-zirconia), chromium (to form chromiumoxide), cerium (to form ceri'a), etc. The foregoing type of oxide coatings are characterized in that they are brittle; This is very important as it is this characteristic that enables the composite powders to be utilized in the production of sintered wrought articles of optimum density. By subjecting such powders to high compacting pressures, the hard phase coating is fractured sufficiently to achieve: metal to metal bonding which through high temperature. sintering and hot working results in consolidation of the reinforced product. g.
The sizes of'the phases'in the foregoing type of com-2 posite powder preferably suitable for the production of; reinforced metal produc'tsare given in microns as follows Thickness of Hard 5 Phase Coating 1 Diameter otDuctile' Range 1 Metal Phase Up to 0.3 (preferably U v to 5 (preferably not p 'g not exceeding 0.15) 0.001 to 0.1. 1
exeeedin 2). .05 to 1 fragmented or lamellar structure as compared to the other type of composite particle in which the hard phase forms? a discrete nucleus surrounded substantially completely by ductile metal forming the matrix. I f
In producing reinforced metal products from either of these composite powder 'compositions,.the powder is briquetted or shaped at room temperature into ingots at pressures ranging from about 30 to 150 tons per square inch. They; may also be hot pressed at temperatures which case the pressures can be below'30tons per square inch. An example of 'a' powder that can be pressed in this manner is one ,com-.
I prising composite particles having a hard phase nucleus of aluminum oxide covered by miumall oy, e. g. nickel and 20% chromiu'm,the composite particles not exceeding about 5 microns in diameter with the composition of the hard phase amour rte ing to about 5% by volume of the total composition.
The ingots formed are sintered under substantially nonreactive conditions at an elevated temperature to consolidate them sufficiently so they can be subsequently hot worked. The sintering is preferably conducted at a tem-' peratureof at least about 1100 C. but not exceeding about 5'' below the point of incipient fusion, e. g. at a subatmospheric pressure generally 100 microns and preferably not exceeding about 50 microns. If necessary, sintering may be carried outintwo stages, the first stage being carried out at a lower temperature range than the second stage which may em- 2 temperature range of up to about 5 C."
ploy 1a sintering below the temperature of incipient fusion.
The sintered ingots are then hot worked, for example by hot extrusion, forging, swaging, etc., until their crosssections have been reduced at least 50% and preferably at least to so that substantially all of thevoids have been eliminated after which the hot are fabricated into the desired finished products.
In evaluating the capability of the reinforced productof the invention to sustain itself under stress at elevated temperatures, high temperature creep rupture tests are employed. The test comprises heating a test specimen to an elevated temperature, say 1000 C.,
perature in the conventional manner.
similar product produced by conventional methods. Tests have shown that an 80-20 nickel-chromium alloy containing no hard above 600 alayer of a nickel-chronot exceeding about] worked ingots.
and determining its rupture life and creep resistance at that tem In this way the be compared to a,
phase already softens appreciably j C. and has unsatisfactory resistance to creep."
Even if the alloy contains elemental titanium and/or alum'inumias age hardeners, the alloysoftens due'to ove'r perature range between 850 C. and l050 C. for prolonged periods of time. The novel compositeipowder composition iof the invention insures :the obtaining of uniform products because of its ease of handling and its substantiallyxnon+segregatable characteristics.
Although the present invention' has been described in conjunction with preferred embodiments, it is tobe understood that modifications and variations may be resorted to without departing from the spirit and scope of the invention, as those skilled-in the art will readily understand. Such modifications and'var iationsare considered to be within the purview and scope of the invention andappended claims. 1 a
f l. A composition of matter suitable .forthe powder metallurgy production of wroughtf reinforced products comprising free flowingfinely divided composite particles in whichsubstantially each of the particlescontain as 'essential constituents a strong highmelting point hard and substantially insoluble refractory material and a ductile metal of melting point above 1250 C. in "integral relation therewith in which one constituent is substantially covered by the other, the particles being substantially non-segregatablewith respect to composition, the refractory material ranging from about 0.5% to 25% by volume of the total composition for a particle size of the composite powder of up to about five microns .for composite powder in which the metal forms a coating on the refractory material and for composite powder in which the refractory material forms acoating on the metal, the thickness of the metal coating on the refractory material ranging from.
about 0.05 to one micron and the thickness of the refractory' material coating on'the ductile metal ranging up to about 0.3 micron.
2. A composition of matter suitable for the powder metallurgy production of wrought reinforced products comprising free flowing finely divided composite particles containing a strong high melting point refractory material integrally coated with a ductile metal of melting point above 1250 C., the amount of refractory oxide ranging from about 2% to by volume of the total composition for a particle size of the composite particles of up to about five microns, the thickness of the ductile metal coating on the refractory material ranging from about 0.05
to one micron.
3. The composition of matter as defined in claim 2,
characterized in that the thickness of the ductile metal coating on the refractory material ranges from about 0.05 to 0.5 micron.
'4. A composition of matter suitable for the powder metallurgy production of wrought reinforced products comprising'free flowing finely divided composite particles in'which ductile metal particles of melting point above 1250." C. are each substantially coated with a layer of a strong high melting point refractory material, the amount of refractory material in the powder ranging from about 2% to 15% 'by volume of the total composition for a particle sizeof the composite particles of up to about five microns, the thickness of the oxide coating on the ductile metal ranging up to about 0.3 micron.
5 A methodfor producing reinforced metal products capable of sustaining highstrength-properties at elevated temperatures which comprises providing free flowing, ne y di id d o p s epa c es ot xcee i g 0 m crons in size containing as essential ingredients a strong high-melting. point :lrarr'l and-substantially :insolubl'e 'reffacto'ry material as a slip and irecovery inhibiting phase and a'ductileg metal of melting pointfabove 12-5 0' in integral relation the'rewi'th, whereby one c'onstituent is substantially cov'er'ed by the other, the amount" of the hard refractory materialranging from about 035% 'to about 25% by yol'umeor the total powder composition, shaping said composite powder 'to a coherentbody, sintering the shaped body-at an elevated temperature under substantially non-reactive conditions to'produce a substantially dense body,'hot workin'g 'said sintered body to reduce its cross-sectional area at least about to eliminate substantially' the voids in said-body, and then fabricatingsaid hot worked body into a heat resistant article of manufacture, said fabricatedarticle being characterized by a microstructure having a substantially discontinuous and random dispersion'of thefinely divided slip and recovery inhibiting phase throughout. the matrix 'of the reinforced metal.
'6'; 'A'me'thod "forprodu'cing reinforced metal products capable ofsustaining high strength properties at elevated temperatures which comprises providing free flowing, finely divided composite particles ranging in size up to about five microns containing as essential ingredients a strong'high-melting point'hard and substantially insoluble refractorymaterial as aslip and recoveryinhibitingphase and a'ductile metal 'of-rnelting point about. 1250 C. 'in integral relation therewith, whereby one constituent substantially coats the other so that when the metal coats the refractory material its thickness ranges from about 0.05
too'ne micron, 'and'when the refractory material coats the ductile metal its thickness ranges up to about0l3 micron, the amount of the hard refractory material ranging from about 0.5% to about 25% by volume of the total powder composition, shapirig said powder mixture to a coherent body, sintering the shaped body at a temperature of at least about '1'100' C. to not greater than about 5 below the point of incipient fusion under substantially non-reactiveconditions to produce a substantially dense body, hot working said sintered body to reduce its cross-sectional areaat least about 50% to eliminate substantially the voids in said body, and then fabricating said hot worked body into a heat resistant article ofm anu facture, said fabricated article being characterized by a microstructure having a substantiallydiscontinuous and random dispersion of the finely divided slip and recovery inhibiting phase throughout the matrix of the reinforced metal.
7. The method of claim 6, characterized in that the amount of refractory material by volume ranges from.
about 2% to 15%.
8. The method of claim 7, characterized in that when the ductile metal covers the refractory material its thickness ranges from about 0.05 to 0.5 micron and that when the refractory material covers the ductile metal its thickness ranges up to about 0.15 micron.
9. A method for producing reinforced metal products capable of sustaining high strength properties at elevated temperatures which comprises providing free flowing, finely divided composite particles ranging in size up to about'5 microns containing 'as essential ingredients a strong high meltingpoint hard and substantially insolublerefractory material as a slip and recovery inhibiting phase integrally coat'ed with ;a ductile metal layer "of melting point above 1250* C. of thickness ranging from about 0.'05;to one micron, theamoun't of the hard refractory material ranging from about 2% to about 15 by volume of the total powder composition, shaping said powder mixture -to a 'coherent body, sintering the shaped body at a temperature of at least about ll00 C. tonot greater than about 5 below t he point of incipient fusion under substantially non-reactive conditions to produce a substantially-den'se body, hot working said sintered body to reduce its cross-sectionaLarea at;least-about 50% to eliminate substantially the voids in said body, and then fabricating said hot worked body into a heat resistant article of manufacture, said fabricated article being characterized by a microstructure having a substantially discontinuous and random dispersion of the finely divided slip and recovery inhibiting phase throughout the matrix of the reinforced metal.
10. A method for producing reinforced metal products capable of sustaining high strength properties at elevated temperatures which comprises providing free flowing, finely divided composite particles ranging in size up to about 5 microns containing as essential ingredients a strong high melting point hard and substantially insoluble refractory material as a slip and recovery inhibiting phase forming an integral coating on a ductile metal particle of melting point above 1250 C., the thickness of the refractory material coating ranging up to about 0.3 micron, the amount of the hard refra tory material ranging from about 2% to about 15% by volume of the total powder composition, shaping said powder mixture to a coherent body, sintering the shaped body at a temperature of at least about 1100 C. to not greater than about 5 below the point of in cipient fusion under substantially non-reactive conditions to produce a substantially dense body, hot working said sintered body to reduce its cross-sectional area at least about 50% to eliminate substantially the voids in said body, and then fabricating said hot worked body into a heat resistant article of manufacture, said fabricated article being characterized by a microstructure having a substantially discontinuous and random dispersion of the finely divided slip and recovery inhibiting phase throughout the matrix of the reinforced metal.
11. A wrought reinforced powder metallurgy metal product capable of sustaining high strength properties and high resistance to creep at elevated temperatures up to about 1000 C. and higher for prolonged periods of time which comprises about 0.5% to 25% by volume of discrete substantially insoluble slip and recovery inhibiting refractory material of up to about 3 microns in size dispersed substantially uniformly through a ductile matrix metal of melting point above 1250 C., the distance between the discrete particles being less than 2 microns.
12. The product of claim 11, characterized in that the amount of discrete insoluble refractory material ranges from about 2% to 15 by volume of the total composition.
13. The product of claim 11 wherein the distance between the discrete particles is less than one micron.
14. The product of claim 13 wherein the distance between the discrete particles ranges from about 0.025 to 0.5 micron.
Sachse July 23, 1946 Hagglund et al. Dec. 25, 1951 U. S. DEPARTMENT OF COMMERCE PATENT OFFICE CETIFICATE OF COECTIQN Patent No: 2,823,988 February l8 1958 Nicholas J, Grant et a1,
It is hereby certified that error appears in the printed specification of the above numbered patent requiring correction and that the said Let uers Patent should read as corrected below.
0 C. read of melting point above 1250 C a Signed end sealed this 22nd day of April 1958 (SEAL) Attest:
KARL AXLINE ROBERT C. WATSON Attesting Officer rrmissioner of Patents KARL a. AXLINE Atteeting Officer U. S. DEPARTMENT OF COMMERCE PATENT OFFICE CERTIFICATE OF CORRECTION Patent Non 2,823,988 February 1958 Nicholas J., Grant et al,
It is hereby certified that error appears in the printed specification of the above numbered patent requiring correction and that the said Let oers Patent should read as corrected below.
Column 8, line 27, for "of melting point about 1250 0.," read m of melting point above 1250 CD 6 Signed and sealed this 22nd day of April 1958 (SEAL) Attest:
ROBERT C. WATSON Commissioner of Patents
Claims (1)
- 6. A METHOD FOR PRODUCING REINFORCED METAL PRODUCTS CAPABLE OF SUSTAINING HIGH STRENGTH PROPERTIES AT ELEVATED TEMPERATURES WHICH COMPRISES PROVIDING FREE FLOWING, FINELY DIVIDED COMPOSITE PARTICLES RANGING IN SIZE UP TO ABOUT FIVE MICRONS CONTAINING AS ESSENTIALLY INGREDIENTS A STRONG HIGH-MELTING POINT HARD AND SUBSTANTIALLY INSOLUBLE REFRACTORY MATERIAL AS A SLIP AND RECOVERY INHIBITING PHASE AND A DUCTILE METAL OF MELTING POINT ABOUT 1250* C. IN INTEGRAL RELATION THEREWITH, WHEREBY ONE CONSTITUENT SUBSTANTIALLY COATS THE OTHER SO THAT WHEN THE METAL COATS THE REFRACTORY MATERIAL ITS THICKNESS RANGES FROM ABOUT 0.05 TO ONE MICRON, AND WHEN THE REFRACTORY MATERIAL COATS THE DUCTILE METAL ITS THICKNESS RANGES UP TO ABOUT 0.3 MICRON, THE AMOUNT OF THE HARD REFRACTORY MATERIAL RANGING FROM ABOUT 0.5% TO ABOUT 25% BY VOLUME OF THE TOTAL POWDER COMPOSITION, SHAPING SAID POWDER MIXTURE TO A COHERENT BODY, SINTERING THE SHAPED BODY AT A TEMPERATURE OF AT LEAST ABOUT 1100* C. TO NOT GREATER THAN ABOUT 5* BELOW THE POINT OF INCIPIENT FUSION UNDER SUBSTANTIALLY NON-REACTIVE CONDITIONS TO PRODUCE A SUBSTANTIALLY DENSE BODY, HOT WORKING SAID SINTERED BODY TO REDUCE ITS CROSS-SECTIONAL AREA AT LEAST ABOUT 50% TO ELIMINATE SUBSTANTIALLY THE VOIDS IN SAID BODY, AND THEN FABRICATING SAID HOT WORKED BODY INTO A HEAT RESISTANT ARTICLE OF MANUFACTURE, SAID FABRICATED ARTICLE BEING CHARACTERIZED BY A MICROSTRUCTURE HAVING A SUBSTANTIALLY DISCONTINUOUS AND RANDOM DISPERSION OF THE FINELY DIVIDED SLIP AND RECOVERY INHIBITING PHASE THROUGHOUT THE MATRIX OF THE REINFORCED METAL.
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US534626A US2823988A (en) | 1955-09-15 | 1955-09-15 | Composite matter |
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US534626A US2823988A (en) | 1955-09-15 | 1955-09-15 | Composite matter |
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US2823988A true US2823988A (en) | 1958-02-18 |
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US534626A Expired - Lifetime US2823988A (en) | 1955-09-15 | 1955-09-15 | Composite matter |
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Cited By (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2878113A (en) * | 1958-04-17 | 1959-03-17 | Du Pont | Fe-si-ti composition or product and process of preparing same |
US2949358A (en) * | 1957-09-23 | 1960-08-16 | Du Pont | Reinforced heat resistant refractorymetal alloys |
US2952903A (en) * | 1957-11-12 | 1960-09-20 | Washken Edward | High temperature composition |
US2972529A (en) * | 1958-05-12 | 1961-02-21 | Du Pont | Metal oxide-metal composition |
US3000734A (en) * | 1956-10-11 | 1961-09-19 | 134 Woodworth Corp | Solid state fabrication of hard, high melting point, heat resistant materials |
US3019103A (en) * | 1957-11-04 | 1962-01-30 | Du Pont | Process for producing sintered metals with dispersed oxides |
US3028234A (en) * | 1961-03-03 | 1962-04-03 | Du Pont | Process for producing mixture of refractory metal oxides and metal and product thereof |
US3037857A (en) * | 1959-06-09 | 1962-06-05 | Union Carbide Corp | Aluminum-base alloy |
US3044867A (en) * | 1957-05-15 | 1962-07-17 | Messrs Aktiebolaget Svenska Me | Method for the production of metallicceramic materials |
US3061482A (en) * | 1959-09-16 | 1962-10-30 | Nicholas J Grant | Ceramic coated metal bodies |
US3069292A (en) * | 1958-07-16 | 1962-12-18 | Du Pont | Composition comprising particles of refractory oxide, coated with an oxide of a transition metal |
US3070439A (en) * | 1960-03-15 | 1962-12-25 | New England Materials Lab Inc | Method for processing dispersion strengthened metals |
US3069759A (en) * | 1960-04-27 | 1962-12-25 | Grant | Production of dispersion strengthened metals |
US3070468A (en) * | 1958-10-29 | 1962-12-25 | Nicholas J Grant | Method of producing dispersion hardened titanium alloys |
US3087234A (en) * | 1960-03-14 | 1963-04-30 | Du Pont | Iron group metals having submicron particles of refractory oxides uniformly dispersed therein |
US3128541A (en) * | 1959-06-04 | 1964-04-14 | Du Pont | High temperature resistant metal |
US3129497A (en) * | 1960-05-12 | 1964-04-21 | Honeywell Regulator Co | Beryllium metal products |
US3150443A (en) * | 1959-12-07 | 1964-09-29 | Du Pont | Process of incorporating a refractory metal oxide in a metal and product resulting therefrom |
US3152389A (en) * | 1960-05-09 | 1964-10-13 | Du Pont | Metal composition |
US3180727A (en) * | 1962-02-20 | 1965-04-27 | Du Pont | Composition containing a dispersionhardening phase and a precipitation-hardening phase and process for producing the same |
US3184835A (en) * | 1961-10-02 | 1965-05-25 | Handy & Harman | Process for internally oxidationhardening alloys, and alloys and structures made therefrom |
US3244506A (en) * | 1964-09-08 | 1966-04-05 | Allegheny Ludhum Steel Corp | Cutting tool material |
DE1264073B (en) * | 1960-06-10 | 1968-03-21 | Du Pont | Process for producing a powdery metal-metal oxide dispersion and for processing it into a material |
US3382051A (en) * | 1964-09-25 | 1968-05-07 | Fansteel Metallurgical Corp | Dispersion-strengthened iron-group metal alloyed with a small amount of zirconium, hafnium or magnesium and process of making |
DE1280559B (en) * | 1960-06-10 | 1968-10-17 | Fansteel Metallurgical Corp | A method for producing a metal powder in which difficult-to-melt metal oxide particles are dispersed |
US3409417A (en) * | 1964-06-01 | 1968-11-05 | Du Pont | Metal bonded silicon nitride |
DE1283547B (en) * | 1963-02-26 | 1968-11-21 | Fansteel Metallurgical Corp | Process for increasing the tensile strength, yield strength and creep rupture strength and for stabilizing the grain orientation of dispersion-hardened alloys |
DE1286303B (en) * | 1960-06-10 | 1969-01-02 | Fansteel Metallurgical Corp | Process for the production of a metal powder with finely dispersed, difficult-to-melt oxide particles |
DE1288318B (en) * | 1960-06-10 | 1969-01-30 | Fansteel Metallurgical Corp | Process for producing a metal powder with finely dispersed, difficult-to-melt oxide particles |
US3434830A (en) * | 1965-10-22 | 1969-03-25 | Nicholas J Grant | Dispersion strengthening of metals and alloys |
DE1533236B1 (en) * | 1965-02-09 | 1970-04-30 | English Electric Co Ltd | Process for the production of dispersion hardened materials |
US3655365A (en) * | 1970-05-01 | 1972-04-11 | Iit Res Inst | High speed tool alloys and process |
US3776704A (en) * | 1968-03-01 | 1973-12-04 | Int Nickel Co | Dispersion-strengthened superalloys |
US3888663A (en) * | 1972-10-27 | 1975-06-10 | Federal Mogul Corp | Metal powder sintering process |
US3914507A (en) * | 1970-03-20 | 1975-10-21 | Sherritt Gordon Mines Ltd | Method of preparing metal alloy coated composite powders |
US4004891A (en) * | 1973-03-22 | 1977-01-25 | Gte Sylvania Incorporated | Superalloys containing nitrides and process for producing same |
US4314007A (en) * | 1976-08-26 | 1982-02-02 | Bbc Brown, Boveri & Company Limited | Composite shaped articles |
US4419130A (en) * | 1979-09-12 | 1983-12-06 | United Technologies Corporation | Titanium-diboride dispersion strengthened iron materials |
US4919718A (en) * | 1988-01-22 | 1990-04-24 | The Dow Chemical Company | Ductile Ni3 Al alloys as bonding agents for ceramic materials |
US5015290A (en) * | 1988-01-22 | 1991-05-14 | The Dow Chemical Company | Ductile Ni3 Al alloys as bonding agents for ceramic materials in cutting tools |
US5288228A (en) * | 1989-11-17 | 1994-02-22 | Kubota Corporation | Heat-resistant materials |
US20070034048A1 (en) * | 2003-01-13 | 2007-02-15 | Liu Shaiw-Rong S | Hardmetal materials for high-temperature applications |
US20070119276A1 (en) * | 2005-03-15 | 2007-05-31 | Liu Shaiw-Rong S | High-Performance Friction Stir Welding Tools |
US20080257107A1 (en) * | 2003-01-13 | 2008-10-23 | Genius Metal, Inc. | Compositions of Hardmetal Materials with Novel Binders |
US20100180514A1 (en) * | 2003-01-13 | 2010-07-22 | Genius Metal, Inc. | High-Performance Hardmetal Materials |
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US2404598A (en) * | 1944-08-23 | 1946-07-23 | Metals Disintegrating Co | Method of making abrasive articles |
US2580171A (en) * | 1945-03-10 | 1951-12-25 | Kanthal Ab | Heat-resistant ferritic alloy |
Cited By (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3000734A (en) * | 1956-10-11 | 1961-09-19 | 134 Woodworth Corp | Solid state fabrication of hard, high melting point, heat resistant materials |
US3044867A (en) * | 1957-05-15 | 1962-07-17 | Messrs Aktiebolaget Svenska Me | Method for the production of metallicceramic materials |
US2949358A (en) * | 1957-09-23 | 1960-08-16 | Du Pont | Reinforced heat resistant refractorymetal alloys |
US3019103A (en) * | 1957-11-04 | 1962-01-30 | Du Pont | Process for producing sintered metals with dispersed oxides |
US2952903A (en) * | 1957-11-12 | 1960-09-20 | Washken Edward | High temperature composition |
US2878113A (en) * | 1958-04-17 | 1959-03-17 | Du Pont | Fe-si-ti composition or product and process of preparing same |
US2972529A (en) * | 1958-05-12 | 1961-02-21 | Du Pont | Metal oxide-metal composition |
US3069292A (en) * | 1958-07-16 | 1962-12-18 | Du Pont | Composition comprising particles of refractory oxide, coated with an oxide of a transition metal |
US3070468A (en) * | 1958-10-29 | 1962-12-25 | Nicholas J Grant | Method of producing dispersion hardened titanium alloys |
US3128541A (en) * | 1959-06-04 | 1964-04-14 | Du Pont | High temperature resistant metal |
US3037857A (en) * | 1959-06-09 | 1962-06-05 | Union Carbide Corp | Aluminum-base alloy |
US3061482A (en) * | 1959-09-16 | 1962-10-30 | Nicholas J Grant | Ceramic coated metal bodies |
US3150443A (en) * | 1959-12-07 | 1964-09-29 | Du Pont | Process of incorporating a refractory metal oxide in a metal and product resulting therefrom |
US3087234A (en) * | 1960-03-14 | 1963-04-30 | Du Pont | Iron group metals having submicron particles of refractory oxides uniformly dispersed therein |
US3070439A (en) * | 1960-03-15 | 1962-12-25 | New England Materials Lab Inc | Method for processing dispersion strengthened metals |
US3069759A (en) * | 1960-04-27 | 1962-12-25 | Grant | Production of dispersion strengthened metals |
US3152389A (en) * | 1960-05-09 | 1964-10-13 | Du Pont | Metal composition |
US3129497A (en) * | 1960-05-12 | 1964-04-21 | Honeywell Regulator Co | Beryllium metal products |
DE1264073B (en) * | 1960-06-10 | 1968-03-21 | Du Pont | Process for producing a powdery metal-metal oxide dispersion and for processing it into a material |
DE1280559B (en) * | 1960-06-10 | 1968-10-17 | Fansteel Metallurgical Corp | A method for producing a metal powder in which difficult-to-melt metal oxide particles are dispersed |
DE1288318B (en) * | 1960-06-10 | 1969-01-30 | Fansteel Metallurgical Corp | Process for producing a metal powder with finely dispersed, difficult-to-melt oxide particles |
DE1286303B (en) * | 1960-06-10 | 1969-01-02 | Fansteel Metallurgical Corp | Process for the production of a metal powder with finely dispersed, difficult-to-melt oxide particles |
US3028234A (en) * | 1961-03-03 | 1962-04-03 | Du Pont | Process for producing mixture of refractory metal oxides and metal and product thereof |
US3184835A (en) * | 1961-10-02 | 1965-05-25 | Handy & Harman | Process for internally oxidationhardening alloys, and alloys and structures made therefrom |
US3180727A (en) * | 1962-02-20 | 1965-04-27 | Du Pont | Composition containing a dispersionhardening phase and a precipitation-hardening phase and process for producing the same |
DE1283547B (en) * | 1963-02-26 | 1968-11-21 | Fansteel Metallurgical Corp | Process for increasing the tensile strength, yield strength and creep rupture strength and for stabilizing the grain orientation of dispersion-hardened alloys |
US3409417A (en) * | 1964-06-01 | 1968-11-05 | Du Pont | Metal bonded silicon nitride |
US3244506A (en) * | 1964-09-08 | 1966-04-05 | Allegheny Ludhum Steel Corp | Cutting tool material |
US3382051A (en) * | 1964-09-25 | 1968-05-07 | Fansteel Metallurgical Corp | Dispersion-strengthened iron-group metal alloyed with a small amount of zirconium, hafnium or magnesium and process of making |
DE1533236B1 (en) * | 1965-02-09 | 1970-04-30 | English Electric Co Ltd | Process for the production of dispersion hardened materials |
US3434830A (en) * | 1965-10-22 | 1969-03-25 | Nicholas J Grant | Dispersion strengthening of metals and alloys |
US3776704A (en) * | 1968-03-01 | 1973-12-04 | Int Nickel Co | Dispersion-strengthened superalloys |
US3914507A (en) * | 1970-03-20 | 1975-10-21 | Sherritt Gordon Mines Ltd | Method of preparing metal alloy coated composite powders |
US3655365A (en) * | 1970-05-01 | 1972-04-11 | Iit Res Inst | High speed tool alloys and process |
US3888663A (en) * | 1972-10-27 | 1975-06-10 | Federal Mogul Corp | Metal powder sintering process |
US4004891A (en) * | 1973-03-22 | 1977-01-25 | Gte Sylvania Incorporated | Superalloys containing nitrides and process for producing same |
US4314007A (en) * | 1976-08-26 | 1982-02-02 | Bbc Brown, Boveri & Company Limited | Composite shaped articles |
US4419130A (en) * | 1979-09-12 | 1983-12-06 | United Technologies Corporation | Titanium-diboride dispersion strengthened iron materials |
US4919718A (en) * | 1988-01-22 | 1990-04-24 | The Dow Chemical Company | Ductile Ni3 Al alloys as bonding agents for ceramic materials |
US5015290A (en) * | 1988-01-22 | 1991-05-14 | The Dow Chemical Company | Ductile Ni3 Al alloys as bonding agents for ceramic materials in cutting tools |
US5288228A (en) * | 1989-11-17 | 1994-02-22 | Kubota Corporation | Heat-resistant materials |
US20070034048A1 (en) * | 2003-01-13 | 2007-02-15 | Liu Shaiw-Rong S | Hardmetal materials for high-temperature applications |
US20080257107A1 (en) * | 2003-01-13 | 2008-10-23 | Genius Metal, Inc. | Compositions of Hardmetal Materials with Novel Binders |
US20100180514A1 (en) * | 2003-01-13 | 2010-07-22 | Genius Metal, Inc. | High-Performance Hardmetal Materials |
US20070119276A1 (en) * | 2005-03-15 | 2007-05-31 | Liu Shaiw-Rong S | High-Performance Friction Stir Welding Tools |
US7857188B2 (en) | 2005-03-15 | 2010-12-28 | Worldwide Strategy Holding Limited | High-performance friction stir welding tools |
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