US2803542A - Xerographic plate - Google Patents
Xerographic plate Download PDFInfo
- Publication number
- US2803542A US2803542A US524478A US52447855A US2803542A US 2803542 A US2803542 A US 2803542A US 524478 A US524478 A US 524478A US 52447855 A US52447855 A US 52447855A US 2803542 A US2803542 A US 2803542A
- Authority
- US
- United States
- Prior art keywords
- selenium
- plate
- arsenic
- insulating layer
- photoconductive insulating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/08—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic
- G03G5/082—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic and not being incorporated in a bonding material, e.g. vacuum deposited
- G03G5/08207—Selenium-based
Definitions
- This invention relates in general to the art of electrophotography, now known as xerography, and, in particular, to a sensitive plate therefor. More specifically, the invention relates to a new xerographic or electrophotographic member comprising a conductive backing having on at least one surface thereof a mixture of a photoconductive insulating coating consisting of a mixture of seleniun'rand arsenic which member is known as a xerographic plate.
- a member or plate which comprises aconductive backing member such as, for example, a metallic surface having a photoconductive insulating surface thereon.
- a suitable plate for this purpose is a metallic member having a layer of vitreous selenium.
- Such a plate is characterized by being capable of receiving a satisfactory electrostatic charge and selectively dissipating such a charge when exposed to alight pattern and, in general, is largelysensitive to light in the blue-green-s'pectral range.
- an improved xerographic plate can be prepared by incorporation in the photoconductive insulating coating of a minor amount of arsenic.
- the plates as thus modified are characterized by a broader range of spectral sensitivity, particularly toward the red end of the spec- 'ti'uin, and by an increased overall photographic speed.
- other advantages exist.
- the presence of arsenic in a selenium coating markedly inhibits crystallization of the selenium layer.
- extra thick layers of selenium namely, about 80-300 microns are needed. The presence of such thick layers results in the trapping of charges in the layer during exposure.
- the permissible range of concentration or proportion of arsenic in the selenium layer is relatively broad and may extend from about 0.5 percent to about 20 percent and preferably lies in the range of about 1 percent to about percent by weight.
- the new and improved plates of the present invention can be prepared by a variety of methods.
- arsenic and selenium in the desired proportions may be mixed and, in molten form, sprayed on the desired surface, or they may be evaporated onto the plate under high vacuum as from a mixture in a single evaporation source or optionally from two separate sources operating to volatilize their contents at the desired speed ratio.
- the mixed ingredients may be placed in a suitable film-forming binder and applied to the surface in the form of a selenium-arsenic lacquer.
- Application of molten selenium-arsenic to the conductive backing may also lie used.
- a transparent insulating coating as of vinyl resin, a cellulose ether or ester, a silicone resin, etc. may be coated on top of the xerographic plate toprotect the surface thereof from abrasion and mechanical damage.
- the figure is a graph showing the spectral response curves of a selenium xerographic plate contrasted with an arsenic-selenium xerographic plate. 7 I
- a brass plate was polished with Glass Wax (a trade name of the Gold Seal Company, Bismarck, North Dakota, for a composition comprising about 75 percent water, percent naptha, 7.5 percent abrasive, and the balance ammonia, emulsifier, and coloring agent), rinsed in isopropyl alcohol and then degreased in hot isopropyl alcohol vapor.
- the brass plate so treated was approximately 2 inches wide, 4 inches long, and inch thick. After this cleaning the plate was then attached to a temperature controlled platen about 6 inches above a procelain crucible.
- the arsenic-selenium mixture was then heated in the porcelain crucible and thus evaporated onto the brass plate. Deposition took about minutes.
- the arsenic-selenium layer so obtained was approximately microns thick.
- a plate containing only seleniumon a brass backing member was prepared by the same process and also was approximately 50 microns thick.
- the spectral response of the two plates was then tested by keeping the plates in darkness for at least about 8 hours. A charge of about 200 volts was then placed on the plate by means of a corona charging unit such as is disclosed in U. S. patent application Serial No. 154,295, filed April 6, 1950, by Lewis E. Walkup.
- the spectral sensitivity data for the graph was then obtained by calculating the reciprocal of the time in seconds required for the plate potential to drop from 200 volts to volts under illumination having an intensity of 0.027 microwatt per square centimeter.
- the spectral response of the plate having arsenic-selenium as the photoconductive insulator is definitely shifted toward the red end of the spectrum as compared to the plate having only selenium as the photoconductive insulator and the overall sensitivity is greater for all wave lengths measured up to about 580 millimicrons.
- the arsenic-selenium plate has approximately 40 percent more sensitivity than the plate having only selenium as the photoconductive insulator and at a wave length of about 525 millimicrons the arsenic-selenium plate is almost 100 percent more sensitive than the plate having only selenium as the photoconductive insulator.
- the selenium used in the preparation of xerographic plates should be free of impurities which adversely affect of less than about 10 ohm-centimeter.
- amorphous selenium available in pellet form inch to /8 inch size under the name A. R. Q. (ammonia reduced in quartz from selenium oxide) as manufactured, for this grade of selenium is essentially pure, containing less than about twenty parts per million of impurities. If purified, other grades of selenium, i. e. D. D. Q. (double distilled in quartz) and C. C. R. (commercial grade) as manufactured can likewise be employed in the process disclosed herein. To purify these grades of selenium, they are first freed of copper, lead, iron, and bismuth by distillation. The selenium is next heated to about 250 degrees C.,
- the base plate be preheated to a temperature of at least about 75 degrees C. although lower temperatures may be used if desired.
- a conductive base plate is usually required for xerographic plates and metal forms the most suitable material.
- terials having electrical resistivities about 10 ohm-centimeter are generally satisfactory for the base plates of this invention although it is more desirable to use materials Any gross surface irregularities, i. e. burns, tool marks, are removed from the base plate by grinding or polishing, although it is unnecessary to polish the plate until it has a mirror-like surface.
- the plate surface is cleaned before coating with the selenium-arsenic in order to remove grease, dirt, and
- Suitable base plate materials are 4 aluminum, glass having a conductive coating thereon as of tin oxide or aluminum, stainless steel, nickel, chromium, zinc, and steel.
- conductive plastic, conductively coated paper, or other web or film-like member may be used as the con- 'ductive supporting surface as desired.
- the backing member selected for this plate may be in the form of a flat plate or may equally be in the form of a cylinder, flexible sheet, or other member having a surface suitable for the xerographic process.
- An electrophotographic process comprising placing an electrostatic charge on the surface of an electrophotographic member comprising a photoconductive insulating layer being a substantially vitreous uniform mixture of between about 0.5% and 20% by Weight of arsenic and the remainder substantially vitreous selenium overlying and in electrically conductive contact with a conductive backing member, selectively dissipating electric charge fromthe surface of the charged photoconductive insulating layer by exposing the charged layer to a light image thereby creating an electrostatic latent image on the surface of the photoconductive insulating layer, and developing said electrostatic latent image with electrically charged powder particles.
- p v I 4 A process according to claim 1 in which the photoconductive'insulating layer is about 1% to about 10% by weight arsenic and the remainder substantially vitreous selenium, the conductive backing member comprising brass.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
Aug. 20, 1957 o, A. ULLRICH, JR XEROGRAPHIC PLATE Filed July 26, 1955 o.|oo
SENSlTlVlTY, RECIPROCAL SECONDS 0 Se ONLY PLATE A Se-As PLATE WAVELENGTH, MILLIMICRONS IN V EN TOR. v
' OSMAR A. ULLRICH, JR.
BYF Q ATTORNEY United States PatentO 4 Claims. (Cl. 96-4 This invention relates in general to the art of electrophotography, now known as xerography, and, in particular, to a sensitive plate therefor. More specifically, the invention relates to a new xerographic or electrophotographic member comprising a conductive backing having on at least one surface thereof a mixture of a photoconductive insulating coating consisting of a mixture of seleniun'rand arsenic which member is known as a xerographic plate.
In the art of xerography it is usual to form an electrostatic latent image on a member or plate which comprises aconductive backing member such as, for example, a metallic surface having a photoconductive insulating surface thereon. It has previously been found that a suitable plate for this purpose is a metallic member having a layer of vitreous selenium. Such a plate is characterized by being capable of receiving a satisfactory electrostatic charge and selectively dissipating such a charge when exposed to alight pattern and, in general, is largelysensitive to light in the blue-green-s'pectral range.
Now in accordance with the present invention it has been found that an improved xerographic plate can be prepared by incorporation in the photoconductive insulating coating of a minor amount of arsenic. The plates as thus modified are characterized by a broader range of spectral sensitivity, particularly toward the red end of the spec- 'ti'uin, and by an increased overall photographic speed. In addition, other advantages exist. Thus, the presence of arsenic in a selenium coating markedly inhibits crystallization of the selenium layer. Thus, in the field of xeroradiography, extra thick layers of selenium, namely, about 80-300 microns are needed. The presence of such thick layers results in the trapping of charges in the layer during exposure. As a result, residual charge builds up rapidly in the plate due to the presence of such trapped charges. These charges are removed by heating the plate. Unfortunately, heating promotes the growth of crystals in the selenium layer which, in turn, destroys the photoconductive insulating properties of the selenium. This places a strict limit on the number of times it is possible to regenerate, i. e. relieve fatigue from, a plate. The inclusion of a minor amount of arsenic in the selenium layer inhibits this crystallization thereby increasing the amount of use obtainable from a xeroradiographic plate. Furthermore, this same mechanism also makes possible the manufacture of xerographic plates by spreading molten selenium-arsenic on the conductive backing.
In general, the permissible range of concentration or proportion of arsenic in the selenium layer is relatively broad and may extend from about 0.5 percent to about 20 percent and preferably lies in the range of about 1 percent to about percent by weight.
The new and improved plates of the present invention can be prepared by a variety of methods. For example, arsenic and selenium in the desired proportions may be mixed and, in molten form, sprayed on the desired surface, or they may be evaporated onto the plate under high vacuum as from a mixture in a single evaporation source or optionally from two separate sources operating to volatilize their contents at the desired speed ratio. Likewise, the mixed ingredients may be placed in a suitable film-forming binder and applied to the surface in the form of a selenium-arsenic lacquer. Application of molten selenium-arsenic to the conductive backing may also lie used. If desired, a transparent insulating coating, as of vinyl resin, a cellulose ether or ester, a silicone resin, etc. may be coated on top of the xerographic plate toprotect the surface thereof from abrasion and mechanical damage.
The figure is a graph showing the spectral response curves of a selenium xerographic plate contrasted with an arsenic-selenium xerographic plate. 7 I
The general scope and nature of the invention having been set forth, the following example is given as a typical illustration of a method by which the desired plates may be prepared. A brass plate was polished with Glass Wax (a trade name of the Gold Seal Company, Bismarck, North Dakota, for a composition comprising about 75 percent water, percent naptha, 7.5 percent abrasive, and the balance ammonia, emulsifier, and coloring agent), rinsed in isopropyl alcohol and then degreased in hot isopropyl alcohol vapor. The brass plate so treated was approximately 2 inches wide, 4 inches long, and inch thick. After this cleaning the plate was then attached to a temperature controlled platen about 6 inches above a procelain crucible.
In preparing the charge for evaporation, a mixture of ARQ grade (ammonia reduced selenium oxide in quartz) selenium and approximately 2 percent by weight of arsenic were heated together for 2 hours in air with frequent stirring with a Pyrex rod. Most of the arsenic dissolved but a small amount did not go into solution. The excess arsenic was decanted leaving a homogeneous molten mixture. This charge was then placed in the porcelain crucible. The platen backing the brass plate was then heated to place the brass plate itself at a temperature of about 70 degrees C. A bell jar was placed over the assembly and the air evacuated from the system to give a pressure of about 0.2 micron. The arsenic-selenium mixture was then heated in the porcelain crucible and thus evaporated onto the brass plate. Deposition took about minutes. The arsenic-selenium layer so obtained was approximately microns thick. A plate containing only seleniumon a brass backing member was prepared by the same process and also was approximately 50 microns thick.
The spectral response of the two plates was then tested by keeping the plates in darkness for at least about 8 hours. A charge of about 200 volts was then placed on the plate by means of a corona charging unit such as is disclosed in U. S. patent application Serial No. 154,295, filed April 6, 1950, by Lewis E. Walkup. The spectral sensitivity data for the graph was then obtained by calculating the reciprocal of the time in seconds required for the plate potential to drop from 200 volts to volts under illumination having an intensity of 0.027 microwatt per square centimeter. As can be seen from the figure, the spectral response of the plate having arsenic-selenium as the photoconductive insulator is definitely shifted toward the red end of the spectrum as compared to the plate having only selenium as the photoconductive insulator and the overall sensitivity is greater for all wave lengths measured up to about 580 millimicrons. Thus, at a wave length of about 450 millimicrons the arsenic-selenium plate has approximately 40 percent more sensitivity than the plate having only selenium as the photoconductive insulator and at a wave length of about 525 millimicrons the arsenic-selenium plate is almost 100 percent more sensitive than the plate having only selenium as the photoconductive insulator.
The selenium used in the preparation of xerographic plates should be free of impurities which adversely affect of less than about 10 ohm-centimeter.
its ability to hold electrostatic charges, that is by forming conducting paths in the film or promoting the formation of conducting hexagonal selenium so that electrostatic charges leak ofr rapidly even in the dark and electrostatic deposition of powder or other finely-divided material can- 'not be obtained. Preferably, there should be used amorphous selenium available in pellet form inch to /8 inch size under the name A. R. Q. (ammonia reduced in quartz from selenium oxide) as manufactured, for this grade of selenium is essentially pure, containing less than about twenty parts per million of impurities. If purified, other grades of selenium, i. e. D. D. Q. (double distilled in quartz) and C. C. R. (commercial grade) as manufactured can likewise be employed in the process disclosed herein. To purify these grades of selenium, they are first freed of copper, lead, iron, and bismuth by distillation. The selenium is next heated to about 250 degrees C.,
slightly above its melting point, and, while molten, is then dropped through a shot tower (or in the laboratory by means of an eye dropper) into water to form pellets. The pellets are subsequently treated with petroleum ether to remove water and allowed to air dry. If desired, the purified selenium can be remelted and cast in boats to form sticks. It can also be reduced in size by grinding or micropulverizing to facilitate melting and mixing with the arsenic. Where the plates are prepared either by vacuum evaporationof the selenium and arsenic or by spraying in molten form, it is desirable that the base plate be preheated to a temperature of at least about 75 degrees C. although lower temperatures may be used if desired.
A conductive base plate is usually required for xerographic plates and metal forms the most suitable material.
However, a high conductivity is not required and almost any structurally satisfactory material which is more conductive than the selenium-arsenic layer can be used. Ma-
terials having electrical resistivities about 10 ohm-centimeter are generally satisfactory for the base plates of this invention although it is more desirable to use materials Any gross surface irregularities, i. e. burns, tool marks, are removed from the base plate by grinding or polishing, although it is unnecessary to polish the plate until it has a mirror-like surface. The plate surface is cleaned before coating with the selenium-arsenic in order to remove grease, dirt, and
other impurities which might prevent firm adherence of the coating to the base plate. This is readily accomplished by washing the plate with any suitable alkali cleaner or with a hydrocarbon solvent, such as benzene, followed by rinsing and drying. Suitable base plate materials are 4 aluminum, glass having a conductive coating thereon as of tin oxide or aluminum, stainless steel, nickel, chromium, zinc, and steel.
Also, conductive plastic, conductively coated paper, or other web or film-like member may be used as the con- 'ductive supporting surface as desired. It is to be understood that the backing member selected for this plate may be in the form of a flat plate or may equally be in the form of a cylinder, flexible sheet, or other member having a surface suitable for the xerographic process.
I claim:
1. An electrophotographic process comprising placing an electrostatic charge on the surface of an electrophotographic member comprising a photoconductive insulating layer being a substantially vitreous uniform mixture of between about 0.5% and 20% by Weight of arsenic and the remainder substantially vitreous selenium overlying and in electrically conductive contact with a conductive backing member, selectively dissipating electric charge fromthe surface of the charged photoconductive insulating layer by exposing the charged layer to a light image thereby creating an electrostatic latent image on the surface of the photoconductive insulating layer, and developing said electrostatic latent image with electrically charged powder particles.
2. A process according to claim 1 in which the photoconductiveinsulating layer is about 1% to about 10% by weight arsenic and the'remainder substantially vitreous selenium. i
3. A process according to claim 1 in which the photoconductive insulating layer is about 1% to about 10% by weight arsenic and the remainder substantially vitreous selenium, the conductive backing member comprising aluminum. p v I 4. A process according to claim 1 in which the photoconductive'insulating layer is about 1% to about 10% by weight arsenic and the remainder substantially vitreous selenium, the conductive backing member comprising brass.
References Cited in the file of this patent UNITED STATES PATENTS 2,199,104 Johnson et a1. Apr. 30, 1940 2,657,152 Mengali et al. Oct. 27, 1953 2,662,832 Middleton .et al Dec. 15, 1953 FOREIGN-PATENTS r 314,838 Great Britain July 3, 1929
Claims (1)
1. AN ELECTROPHOTOGRAPHIC PROCESS COMPRISING PLACING AN ELECTROSTATIC CHARGE ON THE SURFACE OF AN ELECTROPHOTOGRAPHIC MEMBER COMPRISING A PHOTOCONDUCTIVE INSULATING LAYER BEING A SUBSTANTIALLY VITREOUS UNIFORM MIXTURE OF BETWEEN ABOUT 0.5% AND 20% BY WEIGHT OF ARSENIC AND THE REMAINDER SUBSTANTIALLY VITREOUS SELENIUM OVERLYING AND IN ELECTRICALLY CONDUCTIVE CONTACT WITHH A CONDUCTIVE BACKING MEMBER, SELECTIVELY DISSIPATING ELECTRIC CHARGE FROM THE SURFACE OF THE CHARGED PHOTOCONDUCTIVE INSULATING LAYER BY EXPOSING THE CHARGED LAYER TO A LIGHT IMAGE THEREBY CREATING AN ELECTROSTATIC LATENT IMAGE ON THE SURFACE OF THE PHOTOCONDUCTIVE INSULATING LAYER, AND DEVELOPING SAID ELECTROSTATIC LATENT IMAGE WITH ELECTRICALLY CHARGED POWDER PARTICLES.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US524478A US2803542A (en) | 1955-07-26 | 1955-07-26 | Xerographic plate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US524478A US2803542A (en) | 1955-07-26 | 1955-07-26 | Xerographic plate |
Publications (1)
Publication Number | Publication Date |
---|---|
US2803542A true US2803542A (en) | 1957-08-20 |
Family
ID=24089369
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US524478A Expired - Lifetime US2803542A (en) | 1955-07-26 | 1955-07-26 | Xerographic plate |
Country Status (1)
Country | Link |
---|---|
US (1) | US2803542A (en) |
Cited By (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2901349A (en) * | 1957-05-23 | 1959-08-25 | Haloid Xerox Inc | Xerographic plate |
US2917385A (en) * | 1955-08-26 | 1959-12-15 | Haloid Xerox Inc | Reflex xerography |
US2937944A (en) * | 1957-11-20 | 1960-05-24 | Haloid Xerox Inc | Xerographic light-sensitive member and process therefor |
US2962375A (en) * | 1956-05-02 | 1960-11-29 | Haloid Xerox Inc | Color xerography |
US2962376A (en) * | 1958-05-14 | 1960-11-29 | Haloid Xerox Inc | Xerographic member |
US2962374A (en) * | 1956-05-01 | 1960-11-29 | Haloid Xerox Inc | Color xerography |
US3009402A (en) * | 1957-06-03 | 1961-11-21 | Xerox Corp | Xerographic processing apparatus |
US3112197A (en) * | 1956-06-27 | 1963-11-26 | Azoplate Corp | Electrophotographic member |
US3124456A (en) * | 1958-10-30 | 1964-03-10 | figure | |
US3140174A (en) * | 1955-01-19 | 1964-07-07 | Xerox Corp | Process for overcoating a xerographic plate |
US3170790A (en) * | 1959-01-08 | 1965-02-23 | Xerox Corp | Red sensitive xerographic plate and process therefor |
US3188208A (en) * | 1959-05-04 | 1965-06-08 | Xerox Corp | Spectral contrast control in xerography |
US3238150A (en) * | 1962-09-12 | 1966-03-01 | Xerox Corp | Photoconductive cadmium sulfide powder and method for the preparation thereof |
US3251686A (en) * | 1960-07-01 | 1966-05-17 | Xerox Corp | Xerographic process |
US3434832A (en) * | 1964-10-30 | 1969-03-25 | Xerox Corp | Xerographic plate comprising a protective coating of a resin mixed with a metallic stearate |
US3467548A (en) * | 1963-07-08 | 1969-09-16 | Xerox Corp | Method of making xerographic plate by vacuum evaporation of selenium alloy |
US3511649A (en) * | 1966-05-02 | 1970-05-12 | Xerox Corp | Process of reducing fatigue in photoconductive glasses |
US3524745A (en) * | 1967-01-13 | 1970-08-18 | Xerox Corp | Photoconductive alloy of arsenic,antimony and selenium |
US3629000A (en) * | 1965-02-12 | 1971-12-21 | Crown Zellerbach Corp | Electrographic printing element |
JPS496227B1 (en) * | 1970-03-31 | 1974-02-13 | ||
US3850632A (en) * | 1971-07-26 | 1974-11-26 | Konishiroku Photo Ind | Electrophotographic photosensitive plate |
US3887367A (en) * | 1973-12-26 | 1975-06-03 | Xerox Corp | Method for temperature stabilizing photoreceptors |
US3904408A (en) * | 1969-11-14 | 1975-09-09 | Canon Kk | Electrophotographic member with graded tellurium content |
US3971169A (en) * | 1974-10-04 | 1976-07-27 | Xerox Corporation | Method for repairing selenium photoreceptors |
US3973960A (en) * | 1973-02-03 | 1976-08-10 | Licentia Patent-Verwaltungs-G.M.B.H. | Electrophotographic element having a selenium layer containing arsenic in varying concentrations across the layer thickness |
US4008082A (en) * | 1973-02-19 | 1977-02-15 | Licentia Patent-Verwaltungs-G.M.B.H. | Method for producing an electrophotographic recording material |
US4076564A (en) * | 1974-09-16 | 1978-02-28 | Xerox Corporation | Roughened imaging surface for cleaning |
US4088483A (en) * | 1974-02-13 | 1978-05-09 | Minolta Camera Kabushiki Kaisha | Electrophotographic plate with charge transport overlayer |
US4094675A (en) * | 1973-07-23 | 1978-06-13 | Licentia Patent-Verwaltungs-G.M.B.H. | Vapor deposition of photoconductive selenium onto a metallic substrate having a molten metal coating as bonding layer |
US4097277A (en) * | 1973-01-31 | 1978-06-27 | Canon Kabushiki Kaisha | Photosensitive member having layer of vinyl carbazole polymer containing antimony chalcogen compound of antimony and sulfur |
US4126457A (en) * | 1973-05-30 | 1978-11-21 | Xerox Corporation | Evaporation technique for producing high temperature photoreceptor alloys |
US4296191A (en) * | 1980-06-16 | 1981-10-20 | Minnesota Mining And Manufacturing Company | Two-layered photoreceptor containing a selenium-tellurium layer and an arsenic-selenium over layer |
US4414179A (en) * | 1981-12-03 | 1983-11-08 | Xerox Corporation | Process for making photoreceptors |
US4440803A (en) * | 1979-11-01 | 1984-04-03 | Xerox Corporation | Process for preparing arsenic-selenium photoreceptors |
US4513072A (en) * | 1981-09-05 | 1985-04-23 | Licentia Patent-Verwaltungs-Gmbh | Dual layer electrophotographic recording material containing a layer of selenium, arsenic and halogen, and thereabove a layer of selenium and tellurium |
US4513031A (en) * | 1983-09-09 | 1985-04-23 | Xerox Corporation | Process for forming alloy layer |
US4661428A (en) * | 1981-01-14 | 1987-04-28 | Ricoh Co., Ltd. | Composite photosensitive elements for use in electrophotography and process of forming images using same |
US4877700A (en) * | 1982-03-20 | 1989-10-31 | Licentia Patent-Verwaltungs-Gmbh | Layered electrophotographic recording material containing selenium, arsenic and bismuth or tellurium |
US5436101A (en) * | 1993-08-20 | 1995-07-25 | Xerox Corporation | Negative charging selenium photoreceptor |
US5503904A (en) * | 1993-01-19 | 1996-04-02 | Canon Kabushiki Kaisha | Invisible information recorded medium |
US5535185A (en) * | 1993-01-21 | 1996-07-09 | Canon Kabushiki Kaisha | Information recording/reproduction apparatus using probe |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB314838A (en) * | 1928-04-03 | 1929-07-03 | Charles Ruzicka | Improvements in or relating to light sensitive cells |
US2199104A (en) * | 1936-02-27 | 1940-04-30 | Gen Electric Co Ltd | Manufacture of selenium surfaces |
US2657152A (en) * | 1950-03-31 | 1953-10-27 | Haloid Co | Process of producing an electrophotographic plate |
US2662832A (en) * | 1950-04-08 | 1953-12-15 | Haloid Co | Process of producing an electrophotographic plate |
-
1955
- 1955-07-26 US US524478A patent/US2803542A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB314838A (en) * | 1928-04-03 | 1929-07-03 | Charles Ruzicka | Improvements in or relating to light sensitive cells |
US2199104A (en) * | 1936-02-27 | 1940-04-30 | Gen Electric Co Ltd | Manufacture of selenium surfaces |
US2657152A (en) * | 1950-03-31 | 1953-10-27 | Haloid Co | Process of producing an electrophotographic plate |
US2662832A (en) * | 1950-04-08 | 1953-12-15 | Haloid Co | Process of producing an electrophotographic plate |
Cited By (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3140174A (en) * | 1955-01-19 | 1964-07-07 | Xerox Corp | Process for overcoating a xerographic plate |
US2917385A (en) * | 1955-08-26 | 1959-12-15 | Haloid Xerox Inc | Reflex xerography |
US2962374A (en) * | 1956-05-01 | 1960-11-29 | Haloid Xerox Inc | Color xerography |
US2962375A (en) * | 1956-05-02 | 1960-11-29 | Haloid Xerox Inc | Color xerography |
US3112197A (en) * | 1956-06-27 | 1963-11-26 | Azoplate Corp | Electrophotographic member |
US2901349A (en) * | 1957-05-23 | 1959-08-25 | Haloid Xerox Inc | Xerographic plate |
US3009402A (en) * | 1957-06-03 | 1961-11-21 | Xerox Corp | Xerographic processing apparatus |
US2937944A (en) * | 1957-11-20 | 1960-05-24 | Haloid Xerox Inc | Xerographic light-sensitive member and process therefor |
US2962376A (en) * | 1958-05-14 | 1960-11-29 | Haloid Xerox Inc | Xerographic member |
US3124456A (en) * | 1958-10-30 | 1964-03-10 | figure | |
US3170790A (en) * | 1959-01-08 | 1965-02-23 | Xerox Corp | Red sensitive xerographic plate and process therefor |
US3188208A (en) * | 1959-05-04 | 1965-06-08 | Xerox Corp | Spectral contrast control in xerography |
US3251686A (en) * | 1960-07-01 | 1966-05-17 | Xerox Corp | Xerographic process |
US3238150A (en) * | 1962-09-12 | 1966-03-01 | Xerox Corp | Photoconductive cadmium sulfide powder and method for the preparation thereof |
DE1522711A1 (en) * | 1963-07-08 | 1969-10-30 | Rank Xerox Ltd | Method of making a xerographic imaging plate |
US3467548A (en) * | 1963-07-08 | 1969-09-16 | Xerox Corp | Method of making xerographic plate by vacuum evaporation of selenium alloy |
US3434832A (en) * | 1964-10-30 | 1969-03-25 | Xerox Corp | Xerographic plate comprising a protective coating of a resin mixed with a metallic stearate |
US3629000A (en) * | 1965-02-12 | 1971-12-21 | Crown Zellerbach Corp | Electrographic printing element |
US3511649A (en) * | 1966-05-02 | 1970-05-12 | Xerox Corp | Process of reducing fatigue in photoconductive glasses |
US3524745A (en) * | 1967-01-13 | 1970-08-18 | Xerox Corp | Photoconductive alloy of arsenic,antimony and selenium |
US3904408A (en) * | 1969-11-14 | 1975-09-09 | Canon Kk | Electrophotographic member with graded tellurium content |
JPS496227B1 (en) * | 1970-03-31 | 1974-02-13 | ||
US3850632A (en) * | 1971-07-26 | 1974-11-26 | Konishiroku Photo Ind | Electrophotographic photosensitive plate |
US4097277A (en) * | 1973-01-31 | 1978-06-27 | Canon Kabushiki Kaisha | Photosensitive member having layer of vinyl carbazole polymer containing antimony chalcogen compound of antimony and sulfur |
US3973960A (en) * | 1973-02-03 | 1976-08-10 | Licentia Patent-Verwaltungs-G.M.B.H. | Electrophotographic element having a selenium layer containing arsenic in varying concentrations across the layer thickness |
US4008082A (en) * | 1973-02-19 | 1977-02-15 | Licentia Patent-Verwaltungs-G.M.B.H. | Method for producing an electrophotographic recording material |
US4126457A (en) * | 1973-05-30 | 1978-11-21 | Xerox Corporation | Evaporation technique for producing high temperature photoreceptor alloys |
US4094675A (en) * | 1973-07-23 | 1978-06-13 | Licentia Patent-Verwaltungs-G.M.B.H. | Vapor deposition of photoconductive selenium onto a metallic substrate having a molten metal coating as bonding layer |
US3887367A (en) * | 1973-12-26 | 1975-06-03 | Xerox Corp | Method for temperature stabilizing photoreceptors |
US4088483A (en) * | 1974-02-13 | 1978-05-09 | Minolta Camera Kabushiki Kaisha | Electrophotographic plate with charge transport overlayer |
US4076564A (en) * | 1974-09-16 | 1978-02-28 | Xerox Corporation | Roughened imaging surface for cleaning |
US3971169A (en) * | 1974-10-04 | 1976-07-27 | Xerox Corporation | Method for repairing selenium photoreceptors |
US4440803A (en) * | 1979-11-01 | 1984-04-03 | Xerox Corporation | Process for preparing arsenic-selenium photoreceptors |
US4296191A (en) * | 1980-06-16 | 1981-10-20 | Minnesota Mining And Manufacturing Company | Two-layered photoreceptor containing a selenium-tellurium layer and an arsenic-selenium over layer |
US4661428A (en) * | 1981-01-14 | 1987-04-28 | Ricoh Co., Ltd. | Composite photosensitive elements for use in electrophotography and process of forming images using same |
US4513072A (en) * | 1981-09-05 | 1985-04-23 | Licentia Patent-Verwaltungs-Gmbh | Dual layer electrophotographic recording material containing a layer of selenium, arsenic and halogen, and thereabove a layer of selenium and tellurium |
USRE32744E (en) * | 1981-09-05 | 1988-09-06 | Licentia Patent-Verwaltungs- Gmbh | Dual layer electrophotographic recording material containing a layer of selenium, arsenic and halogen, and thereabove a layer of selenium and tellurium |
US4414179A (en) * | 1981-12-03 | 1983-11-08 | Xerox Corporation | Process for making photoreceptors |
US4877700A (en) * | 1982-03-20 | 1989-10-31 | Licentia Patent-Verwaltungs-Gmbh | Layered electrophotographic recording material containing selenium, arsenic and bismuth or tellurium |
US4513031A (en) * | 1983-09-09 | 1985-04-23 | Xerox Corporation | Process for forming alloy layer |
US5503904A (en) * | 1993-01-19 | 1996-04-02 | Canon Kabushiki Kaisha | Invisible information recorded medium |
US6153879A (en) * | 1993-01-19 | 2000-11-28 | Canon Kabushiki Kaisha | Invisible information detecting apparatus |
US5535185A (en) * | 1993-01-21 | 1996-07-09 | Canon Kabushiki Kaisha | Information recording/reproduction apparatus using probe |
US5436101A (en) * | 1993-08-20 | 1995-07-25 | Xerox Corporation | Negative charging selenium photoreceptor |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2803542A (en) | Xerographic plate | |
US2663636A (en) | Electrophotographic plate and method of producing same | |
US2803541A (en) | Xerographic plate | |
US2886434A (en) | Protected photoconductive element and method of making same | |
US2901349A (en) | Xerographic plate | |
US2962376A (en) | Xerographic member | |
US2946682A (en) | Electrostatic printing | |
US3251686A (en) | Xerographic process | |
US2954291A (en) | Method for preparing a spirit duplicating master | |
US3121007A (en) | Photo-active member for xerography | |
US2863768A (en) | Xerographic plate | |
US2745327A (en) | Electrophotographic process | |
US3170790A (en) | Red sensitive xerographic plate and process therefor | |
US3524745A (en) | Photoconductive alloy of arsenic,antimony and selenium | |
US3712810A (en) | Ambipolar photoreceptor and method | |
JPH0549235B2 (en) | ||
US3077386A (en) | Process for treating selenium | |
US4296191A (en) | Two-layered photoreceptor containing a selenium-tellurium layer and an arsenic-selenium over layer | |
US3498835A (en) | Method for making xerographic plates | |
US2844543A (en) | Transparent photoconductive composition | |
US3453141A (en) | Method for making a high-speed reusable x-ray plate using orthorhombic lead oxide and resulting article | |
US3966470A (en) | Photo-conductive coating containing Ge, S, and Pb or Sn | |
US2862817A (en) | Crystalline selenium plate | |
US3709683A (en) | Infrared sensitive image retention photoreceptor | |
US3619153A (en) | Photoconductive element and process employing a substituted silylisobutylethylenediamine adhesive interlayer |