US2765046A - Air purifying device - Google Patents

Air purifying device Download PDF

Info

Publication number
US2765046A
US2765046A US393460A US39346053A US2765046A US 2765046 A US2765046 A US 2765046A US 393460 A US393460 A US 393460A US 39346053 A US39346053 A US 39346053A US 2765046 A US2765046 A US 2765046A
Authority
US
United States
Prior art keywords
air
refrigerator
air purifying
purifying
cooling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US393460A
Inventor
Rondholz Fritz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of US2765046A publication Critical patent/US2765046A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/042Air treating means within refrigerated spaces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/04Treating air flowing to refrigeration compartments
    • F25D2317/041Treating air flowing to refrigeration compartments by purification

Definitions

  • the present invention relates to air purifying devices.
  • the present invention relates to a device for purifying the air in the storage space of refrigerators.
  • the present invention relates to a refrigerator device comprising a refrigerator housing providing an enclosed storage space adapted to receive material to be cooled therein, cooling means arranged in the refrigerator housing for cooling the storage space and the material adapted to be stored therein, means for purifying the air in the enclosed cold storage space by sorption of odorous gaseous substances produced 'by the material adapted tobe stored in the enclosed storage space, and means securing the purifying means in the refrigerator housing adjacent the cooling means therein.
  • the air purifying material of the present invention consists of granular adsorbing and absorbing air filtering compounds, the material being held in a container means which is provided with air permeable walls, and which may be easily removably attached to the interior of the refrigerator adjacent to the cooling means, i. e. the evaporator or cooling coil of the refrigeration apparatus.
  • the air filter material in another embodiment of the present invention, may be held in shaped form without the use of a container, the granular lter material being held together by a binding substance.
  • the latter 1 lCe 2 form of the device may also be provided with attaching means for removably securing the filter material in the interior of the refigerator, in a manner similar to the form which includes a container.
  • the area of condensation near or at the evaporator or cooling coil is a favorable location for the collection of odors which are evolved from the substances stored in the refrigerator cooling space. It is in that area that the highest air humidity, strongest odor intensity and lowest vapor tension prevail, due to the influences of the air currents produced by the temperature conditions or by mechanically induced circulation, e. g., by a fan in the closed cooling area. These conditions are favorable for the adsorbtion of cooling vapors in a localized area around the evaporator. For that reason the most favorable results are assured by providing a chemical or physical air purifier inthe region of the greatest condensation. In this connection, the capacity of regeneration of the air purifying material which is used must be considered, since its saturation depends upon the kind and quantity of the materials stored in the cooling space.
  • Figure 1 is a view of a refrigerator chamber showing an embodiment of an air purifying filter of the present invention arranged therein;
  • Figure 2 is a perspective view of the air purifying iilter shown in Figure 1 on an enlarged scale;
  • Figure 3 is a sectional view of the device shown in Figure 2 taken along the lines 2 2;
  • Figure 4 is a perspective view of another embodiment of an air purifying filter of the present invention.
  • Figure 5 is a sectional view of the embodiment shown in Figure 4.
  • a frame member 10 which may be made of aluminum and which has a U-shaped cross section, the open end of the U-shaped frame being directed inwardly, as more clearly shown in Figure 3.
  • Another frame 11 of smaller dimensions and of similar U-shaped cross-section is arranged within the outer frame 10 so that a spacing is left between the two frames in which an inner glass mesh 12 and an outer wire mesh 13 are clamped.
  • the frame 10 is covered on its upper portion by cover member 19.
  • Frame 10 and cover 19 have overlapping flange portions 101 and 191, which are clamped together by screws and bolts 14.
  • the container 2 which is thus formed constitutes an air permeable carrier for holding air filtering material, which is more fully described below.
  • the container is provided with apertures at the upper ends of the clamped flanges 101 and 191, the hook elements 15 are inserted in these apertures, the hook elements being in turn engaged by suction cup elements 16, by means of which the container 2 carrying the desired air purifying material may be suspended in the refrigerating chamber 1, as shown in Figure 1, with the suction cup elements 16 in engagement with the ceiling of the refrigerating chamber, so that the air purifying container 2 hangs adjacent to the evaporator 3 of the refrigerator.
  • Cover 19 is formed with an aperture 192, and frame 11 -is formed at its top portion with an aperture 112, the apertures being arranged ,in register with, one another.
  • Patented Oct. 2, 1956 l These apertures provide a means for filling the container 2, formedbythe above described frames and mesh members, with air filtering and purifying substances, which are 'preferably .of granular form.
  • Cover 19 is provided -with plate T7 for .covering apertures 19,2 and 112 after container ⁇ 2 ⁇ has been filled With'iiltering material 18.
  • Both the ⁇ frames v10 and *11 and the Wire mesh )13 may be made of aluminum or aluminum alloy, Orkpreferably of an aluminum-magnesium alloy, inorderito avoid corrosion of .these-metallic parts.
  • the air 'purifyingtilter material which may be effectively ⁇ used in VtheV present invention Lfor purifying refrigerator cooling areas may consist of -various adsorption and absorption substancesfor removing-the gaseous odorvproducing ⁇ substances levolved by the-food stuffs'stored in the-refrigerator.
  • Suitable-materials Vof-this type are activated carbon, alumina, silica gel, as -well as acid-com 'bining 'basic substances, such Vas Aburnt lime, magnesia ⁇ and :ion-exchange compositions. Examples of ⁇ the latter ⁇ compositions are Zeolites -and synthetic resin ion ⁇ exchangers.
  • a 'mixture 4'or aplurality of -layersof lt-Wo-or-moreof the abovementionedtilteringcompounds maybe used in suit- -able'quantities
  • the -adsorbing rair iiltermaterials which Vare described above may be regenerated for repeated use inthemanner Yalready known in the art, such regeneration being ithere :results an air-disinfecting ,effectiwhich may be carried out without lossiof the colloidalsilveror silver oxide, lsince 'the latter i materials4 may f also be regenerated as described above so as toindefinitelymaintain,the purifying effects thereof. .In the use of .the-silver materials mentioned,;particularly hygienic conditions inthe refrigerator chamber-.can beach
  • Example I 1D0-120 g. activated carbon, 80-100 g. of activated alumina, and 90H10() g.,of burnt lime.
  • Example III 110 g. of activated carbon,'90 g. of activated-silica gel, and 95 g. of magnesia.
  • Example IV l0() g. of activated carbon, 8O g. of activated alumina, and 9G g. of zeolite.
  • hygroscopic, deliquescent chemical compounds as for-example calciumchloride and magnesium chloride.
  • These chemicals deliquesce in absorbing'moistnre from the air, Vand* such deliquescence may impair the-etfectiveness of theadsorbing air purifying materials. Therefore, these chemicals areprovided in the -air-lterdevice kwithirran absorbent 'packing-'materiahas ltaking place in the enclosed cooling chamber. result the stored 'ifood stuffs retain their original -natural -odor Aand taste, ⁇ since they are not affected by foreign 4 for example, a porous ceramic material, in order to keep them separate from "the adsorbing air filter materials.
  • FIGS 4 and S illustrate another embodiment of the air purifying filter of the present invention.
  • a iilter device which is formed of the materials described above, but which, instead of being contained in an air permeable-container, is shaped into a rectangular form, the granular material of which the iilter is made being held together by any suitable binding material suchas glue, ⁇ synthetic resin, ;or other bindmedia.
  • Blockll thus serves as an air permeable ⁇ iilter- -ing diaphragm through which the air 'in the refrigerator may pass, uand'which'takes up by adsorptiorror absorption the odor-producing substances in the circulating air.
  • The'filter devices ofthe present invention maybeused Yin-any refrigerator chamber ⁇ for purifying the air therein,
  • the-tiltermaterial taking up by sorption i. e., by adsorption or absorption orlboth, the undesirable odors from the food stutfs or other -materials stored in the refrigerator, theiodors reaching-the-.lter device by the -air circulation As a odors :from adjacent food stuffs vwhich are removed Vby the iilter device.
  • the refrigerator apparatus remains Efrce .ofbdors -Whichmay detrimentally influence the ⁇ tasteof the stored materials.
  • The'draWing-oif of 'theexcesshufmidity, which ⁇ acts as acarrying-means -for Vthe odorous substances, bytheiilter device of the persent Iinvention has afurtheradvantage inthatithere is fless ice formation Aon theevaporator.orcooling coil of :therefrigerator apparatus, sov that the. output. of the :refrigerator .is :improved yand its :operation thereby-becomes more.economical.
  • An air purifying device for a refrigerator having an enclosed storage space and cooling means therein comprising in combination, a mixture of granulated air filter materials for sorption of odorous gaseous substances produced by material stored in the storage space of the refrigerator, each component of said mixture of granulated said air filter materials being coated with a substance selected from the group consisting of colloidal silver and colloidal silver oxide for disinfecting the air in said storage space, said mixture of air filter materials and said disinfecting substance being adapted to be regenerated for repeated use; means for retaining the thus coated mixture of air lter materials in shaped form; and attaching means for securing said mixture of lter materials in shaped form in the refrigerator storage space adjacent to the cooling means therein.
  • an air filter material comprising at least one substance selected from the group consisting of activated carbon, silica gel and activated alumina and being coated with a substance selected from the group consisting of colloidal silver and colloidal silver oxide.
  • an air lter comprising a mixture of granulated filter materials of at least one substance selected from the group consisting of activated carbon, silica gel and activated alumina and being coated with a substance selected from the group consisting of colloidal silver and colloidal silver oxide.

Description

0st. 2., 1956 F, RoNDHoLz AIR PURIFYING DEVICE Filed Nov. 20, 19515 mvE'HTDK. Fan?. Kon DHo z z. B
United States Patent O AIR PURIFYING DEVICE Fritz Rondliolz, Stuttgart, Germany p Application November 20, 1953, Serial No. 393,460
Claims priority, application Germany March 11, 195B 4 Claims. (Cl. 183-4) The present invention relates to air purifying devices.
More particularly, the present invention relates to a device for purifying the air in the storage space of refrigerators.
In the storage of various kinds of food stutfs together in the storage space of mechanically driven refrigerating devices, it is well known that the odors of the food stuffs are transmitted from one to the other, and that, in addition to this undesirable result, the strong odor of the air usually found in enclosed cooling areas or storage spaces can become exceedingly troublesome. Furthermore, volatile odors from certain food substances, as, for example, volatile acids evolved from cheese, may have an unfavorable elfect on the appearance of certain other food substances, as, for example, on meats.
In order to avoid these commonly known disadvantages, some aid can be found in the use of tight containers for the food to be stored in the refrigerator, or in covering the food with odor-tight, air-tight wrapping material, as for example, aluminum or plastic sheets or foils. However, these materials are inconvenient, inadequate, or uneconomical for bulky food stuffs, and it has been found that they have not been able to prevent excessive odor formation in the cooling storage space. Up to the present, there has not been achieved a means for eliminating from refrigerator cooling spaces the odors which are evolved from the food stuffs stored in the refrigerator.
It is an object, therefore, of the present invention to overcome the above disadvantages.
It is another object of the present invention to provide a simple, economical, and effective air purifying device for eliminating odors in refrigerator storage areas.
It is a further object of the present invention to provide a device which simultaneously de-odorizes the refrigerator chamber and removes humidity therein.
With the above objects in view, the present invention relates to a refrigerator device comprising a refrigerator housing providing an enclosed storage space adapted to receive material to be cooled therein, cooling means arranged in the refrigerator housing for cooling the storage space and the material adapted to be stored therein, means for purifying the air in the enclosed cold storage space by sorption of odorous gaseous substances produced 'by the material adapted tobe stored in the enclosed storage space, and means securing the purifying means in the refrigerator housing adjacent the cooling means therein.
Preferably, the air purifying material of the present invention consists of granular adsorbing and absorbing air filtering compounds, the material being held in a container means which is provided with air permeable walls, and which may be easily removably attached to the interior of the refrigerator adjacent to the cooling means, i. e. the evaporator or cooling coil of the refrigeration apparatus. The air filter material, in another embodiment of the present invention, may be held in shaped form without the use of a container, the granular lter material being held together by a binding substance.
The latter 1 lCe 2 form of the device may also be provided with attaching means for removably securing the filter material in the interior of the refigerator, in a manner similar to the form which includes a container.
In research on purification of the air in refrigerator storage spaces, it has been found that the area of condensation near or at the evaporator or cooling coil is a favorable location for the collection of odors which are evolved from the substances stored in the refrigerator cooling space. It is in that area that the highest air humidity, strongest odor intensity and lowest vapor tension prevail, due to the influences of the air currents produced by the temperature conditions or by mechanically induced circulation, e. g., by a fan in the closed cooling area. These conditions are favorable for the adsorbtion of cooling vapors in a localized area around the evaporator. For that reason the most favorable results are assured by providing a chemical or physical air purifier inthe region of the greatest condensation. In this connection, the capacity of regeneration of the air purifying material which is used must be considered, since its saturation depends upon the kind and quantity of the materials stored in the cooling space.
The novel features which are considered as characteristic for the invention are set forth in particular in the appended claims. The invention itself, however, both as to its construction and its method of operation, together with additional objects and advantages thereof, will be best understood from the following description of specific embodiments when read in connection with the accompanying drawings, in which:
Figure 1 is a view of a refrigerator chamber showing an embodiment of an air purifying filter of the present invention arranged therein;
Figure 2 is a perspective view of the air purifying iilter shown in Figure 1 on an enlarged scale;
Figure 3 is a sectional view of the device shown in Figure 2 taken along the lines 2 2;
Figure 4 is a perspective view of another embodiment of an air purifying filter of the present invention; and
Figure 5 is a sectional view of the embodiment shown in Figure 4.
Referring now to the drawings, and particularly to the form of the device shown in Figures l-3, there is shown a frame member 10 which may be made of aluminum and which has a U-shaped cross section, the open end of the U-shaped frame being directed inwardly, as more clearly shown in Figure 3. Another frame 11 of smaller dimensions and of similar U-shaped cross-section is arranged within the outer frame 10 so that a spacing is left between the two frames in which an inner glass mesh 12 and an outer wire mesh 13 are clamped. The frame 10 is covered on its upper portion by cover member 19. Frame 10 and cover 19 have overlapping flange portions 101 and 191, which are clamped together by screws and bolts 14. The container 2 which is thus formed constitutes an air permeable carrier for holding air filtering material, which is more fully described below.
The container is provided with apertures at the upper ends of the clamped flanges 101 and 191, the hook elements 15 are inserted in these apertures, the hook elements being in turn engaged by suction cup elements 16, by means of which the container 2 carrying the desired air purifying material may be suspended in the refrigerating chamber 1, as shown in Figure 1, with the suction cup elements 16 in engagement with the ceiling of the refrigerating chamber, so that the air purifying container 2 hangs adjacent to the evaporator 3 of the refrigerator.
Cover 19 is formed with an aperture 192, and frame 11 -is formed at its top portion with an aperture 112, the apertures being arranged ,in register with, one another.
Patented Oct. 2, 1956 l These apertures provide a means for filling the container 2, formedbythe above described frames and mesh members, with air filtering and purifying substances, which are 'preferably .of granular form. Cover 19 is provided -with plate T7 for .covering apertures 19,2 and 112 after container `2 `has been filled With'iiltering material 18.
Both the `frames v10 and *11 and the Wire mesh )13 may be made of aluminum or aluminum alloy, Orkpreferably of an aluminum-magnesium alloy, inorderito avoid corrosion of .these-metallic parts.
The air 'purifyingtilter material which may be effectively `used in VtheV present invention Lfor purifying refrigerator cooling areas may consist of -various adsorption and absorption substancesfor removing-the gaseous odorvproducing `substances levolved by the-food stuffs'stored in the-refrigerator. Suitable-materials Vof-this type are activated carbon, alumina, silica gel, as -well as acid-com 'bining 'basic substances, such Vas Aburnt lime, magnesia `and :ion-exchange compositions. Examples of `the latter `compositions are Zeolites -and synthetic resin ion `exchangers. ince a single one of the lnamedcompounds lis -usually not -su'fficient ltoovercome all -of the odors, a 'mixture 4'or aplurality of -layersof lt-Wo-or-moreof the abovementionedtilteringcompounds maybe used in suit- -able'quantities The -adsorbing rair iiltermaterials which Vare described above may be regenerated for repeated use inthemanner Yalready known in the art, such regeneration being ithere :results an air-disinfecting ,effectiwhich may be carried out without lossiof the colloidalsilveror silver oxide, lsince 'the latter i materials4 may f also be regenerated as described above so as toindefinitelymaintain,the purifying effects thereof. .In the use of .the-silver materials mentioned,;particularly hygienic conditions inthe refrigerator chamber-.can beachieved tosupplement and improve the odor-removing action of the other air purifying .agents mentioned above.
vThe 'following :examples ,are f given :as `illustrative vof -mixtures of air iilteringmaterial which may be used in the present invention for each V100 litersof refrigerator chamber space, it being'understood that theinvention is not limited to the lspecific examples :set forth:
Example I 1D0-120 g. activated carbon, 80-100 g. of activated alumina, and 90H10() g.,of burnt lime.
Example Il lOO g. of activated carbon, 100 g. Yof activated silica gel, and 100g. ofbasic ion exchange synthetic resin.
Example III 110 g. of activated carbon,'90 g. of activated-silica gel, and 95 g. of magnesia.
Example IV l0() g. of activated carbon, 8O g. of activated alumina, and 9G g. of zeolite.
In arranging the air purifying material in layers there may also be provided hygroscopic, deliquescent chemical compounds, as for-example calciumchloride and magnesium chloride. These chemicals deliquesce in absorbing'moistnre from the air, Vand* such deliquescence may impair the-etfectiveness of theadsorbing air purifying materials. Therefore, these chemicals areprovided in the -air-lterdevice kwithirran absorbent 'packing-'materiahas ltaking place in the enclosed cooling chamber. result the stored 'ifood stuffs retain their original -natural -odor Aand taste, `since they are not affected by foreign 4 for example, a porous ceramic material, in order to keep them separate from "the adsorbing air filter materials.
Figures 4 and S illustrate another embodiment of the air purifying filter of the present invention. In these figures, there is shown a iilter device which is formed of the materials described above, but which, instead of being contained in an air permeable-container, is shaped into a rectangular form, the granular material of which the iilter is made being held together by any suitable binding material suchas glue, `synthetic resin, ;or other bindmedia.
.In thedevices `shown in Figures .4 yand 5 ' bracketfmembers 22 and 23 .are provided .around yfilter block 21, ,the bracket members 'having upwardly extending 'ange portions With apertures in which hook lmembers and attaching elements similar to those described with respect to Figure 2 may be inserted, so that the iilter block 21 may be hung in a refrigerator in the manner described above. Blockll thus serves as an air permeable `iilter- -ing diaphragm through which the air 'in the refrigerator may pass, uand'which'takes up by adsorptiorror absorption the odor-producing substances in the circulating air.
The'filter devices ofthe present invention maybeused Yin-any refrigerator chamber `for purifying the air therein,
the-tiltermaterial taking up by sorption, i. e., by adsorption or absorption orlboth, the undesirable odors from the food stutfs or other -materials stored in the refrigerator, theiodors reaching-the-.lter device by the -air circulation As a odors :from adjacent food stuffs vwhich are removed Vby the iilter device.
|-Furthermore, the refrigerator apparatus remains Efrce .ofbdors -Whichmay detrimentally influence the `tasteof the stored materials. The'draWing-oif of 'theexcesshufmidity, which `acts as acarrying-means -for Vthe odorous substances, bytheiilter device of the persent Iinvention has afurtheradvantage inthatithere is fless ice formation Aon theevaporator.orcooling coil of :therefrigerator apparatus, sov that the. output. of the :refrigerator .is :improved yand its :operation thereby-becomes more.economical.
:it .will vbe understood .that :cach `of .the elements described .above, or :.two vor more together, `may .also iind a useful applicationin otherttypes of airpurifyingdevices differing ffromfthe types described above.
While the invention ,thas :been v.illustrated .and described as iembodied'in-ahousehold refrigeratorfit is notintended :to be limitedfto the details shown, .since variousmoditications and structural changes `may :be .made vwithout-departing in rany way .from the spirit .of the :present `invention.
Without further analysis, the :foregoing will so rfully "What-isclaimed as new:and desiredto be ysecuredby Letters .'Patent 1 is 1. 1An :air :purifying device for a `refrigerator.having .an :enclosed fstorage .space -and cooling means therein,
.comprisingin combination, Vair lter material for sorption of odorous gaseous `substances produced by .material :stored in the storage .space of the; refrigerator, :said .air iilter materiabbeing coated with a .substance selected from the .group consisting .of colloidal :silver and colloidal .silver oxide for disinfecting the air insaidstorage space, said lair filter .material .and `said disinfecting substance .beingadapted .to:-be regenerated'ifor. repeated.use;means for-:retaining theithus coated :air-:lter materialrintshaped 75 zform;.fan`d attaching means-:forssecuringisaid -lterfmaterial in shaped form in the refrigerator storage space adjacent to the cooling means therein.
2. An air purifying device for a refrigerator having an enclosed storage space and cooling means therein, comprising in combination, a mixture of granulated air filter materials for sorption of odorous gaseous substances produced by material stored in the storage space of the refrigerator, each component of said mixture of granulated said air filter materials being coated with a substance selected from the group consisting of colloidal silver and colloidal silver oxide for disinfecting the air in said storage space, said mixture of air filter materials and said disinfecting substance being adapted to be regenerated for repeated use; means for retaining the thus coated mixture of air lter materials in shaped form; and attaching means for securing said mixture of lter materials in shaped form in the refrigerator storage space adjacent to the cooling means therein.
3. In an air purifying device for refrigerators, and the like, an air filter material comprising at least one substance selected from the group consisting of activated carbon, silica gel and activated alumina and being coated with a substance selected from the group consisting of colloidal silver and colloidal silver oxide.
4. In an air purifying device for refrigerators, and the like, an air lter comprising a mixture of granulated filter materials of at least one substance selected from the group consisting of activated carbon, silica gel and activated alumina and being coated with a substance selected from the group consisting of colloidal silver and colloidal silver oxide.
References Cited in the file of this patent UNITED STATES PATENTS 1,950,502 Madan Mar. 13, 1934 2,104,589 Hartman Ian. 4, 1938 2,117,570 Philipp May 17, 1938 2,204,910 Randolph .Tune 18, 1940 2,206,705 Newman July 2, 1940 2,222,882 Shames Nov. 26, 1940 2,423,702 Hart July 8, 1947 2,638,179 Yard May 12, 1953

Claims (1)

  1. 3. IN AN AIR PURIFYING DEVICE FOR REFRIGERATORS, AND THE LIKE, AN AIR FILTER MATERIAL COMPRISING AT LEAST ONE SUBSTANCE SELECTED FROM THE GROUP CONSISTING OF ACTIVATED CARBON, SILICA GEL AND ACTIVATED ALUMINA AND BEING COATED WITH A SUBSTANCE SELECTED FROM THE GROUP CONSISTING OF COLLOIDAL SILVER AND COLLOIDAL SILVER OXIDE.
US393460A 1953-03-11 1953-11-20 Air purifying device Expired - Lifetime US2765046A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2765046X 1953-03-11

Publications (1)

Publication Number Publication Date
US2765046A true US2765046A (en) 1956-10-02

Family

ID=7997946

Family Applications (1)

Application Number Title Priority Date Filing Date
US393460A Expired - Lifetime US2765046A (en) 1953-03-11 1953-11-20 Air purifying device

Country Status (1)

Country Link
US (1) US2765046A (en)

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4290789A (en) * 1979-03-08 1981-09-22 Wing Industries, Inc. Total energy exchange apparatus
US4534775A (en) * 1982-03-02 1985-08-13 General Time Corp. Air treatment filter element and air treatment filter
DE3522185A1 (en) * 1984-06-22 1986-02-20 Karl 5200 Siegburg Müller Device for reducing the microbe count in the air
US4604110A (en) * 1984-04-19 1986-08-05 General Time Corporation Filter element, filter, and method for removing odors from indoor air
US4682992A (en) * 1984-06-25 1987-07-28 Potters Industries, Inc. Microbicidal coated beads
US4948567A (en) * 1988-02-22 1990-08-14 Kabushiki Kaisha Toshiba Deodorizer for refrigerators or the like
US5052188A (en) * 1990-10-24 1991-10-01 Gas Research Institute Desiccant materials for use in gas fired cooling and dehumidification equipment
US5332426A (en) * 1992-07-29 1994-07-26 Minnesota Mining And Manufacturing Company Agglomerated activated carbon air filter
US5492675A (en) * 1994-09-02 1996-02-20 Brizard; Cyril J. C. Deodorant system
US5500037A (en) * 1988-12-06 1996-03-19 Alhamad; Shaikh G. M. Y. Impact Absorber
US5624478A (en) * 1995-09-14 1997-04-29 Patapanian; Edward Ethylene absorption device
US5632954A (en) * 1994-06-20 1997-05-27 Engelhard/Icc Method for killing microorganisms
US5665148A (en) * 1994-12-01 1997-09-09 Firma Carl Freudenberg Adsorption air filter and method for its production
DE19748256A1 (en) * 1997-10-31 1999-05-06 Volkswagen Ag Prevention of unpleasant odors arising from air conditioning equipment
US6346143B1 (en) * 1999-02-25 2002-02-12 Mcgowan Kimberly F. Odor adsorptive filter for refrigerators and freezers
US20030136267A1 (en) * 2001-12-28 2003-07-24 Ku Joseph P. Air deodorizer
US20030221709A1 (en) * 2002-06-04 2003-12-04 Samsung Electronics., Ltd Dishwasher and method of controlling the same
US20040129142A1 (en) * 2003-01-07 2004-07-08 Wallace Wireman Deodorizer mounting
US20050183637A1 (en) * 2004-02-19 2005-08-25 Reeser Eileen L. Odor-adsorbing tray for under refrigerator shelves
US20060054023A1 (en) * 2004-09-03 2006-03-16 Raetz James A Air-permeable filtration media, methods of manufacture and methods of use
EP1952079A2 (en) * 2005-11-23 2008-08-06 LG Electronics Inc. Refrigerator
US20090056361A1 (en) * 2006-03-15 2009-03-05 Sud-Chemie Inc. Moisture absorbing product for use in containers
US20100218468A1 (en) * 2009-02-27 2010-09-02 Electrolux Home Products, Inc. Hanging air filter
US20110204762A1 (en) * 2010-02-25 2011-08-25 Whirlpool Corporation Modular system for a domestic refrigerator
US20130139692A1 (en) * 2011-12-02 2013-06-06 Alice Chang Odor killing charcoal box systems
US20140109608A1 (en) * 2011-08-05 2014-04-24 Tsang-Hung Hsu Separable sorption apparatus
US20150059198A1 (en) * 2013-09-02 2015-03-05 Samsung Electronics Co., Ltd. Dish washer
EP3123872A1 (en) * 2015-07-27 2017-02-01 Somez System for stabilising fresh products
DE102015121694A1 (en) * 2015-12-14 2017-06-14 Vorwerk & Co. Interholding Gmbh Air purifier with additional function
ES2677241A1 (en) * 2017-01-31 2018-07-31 Bolaseca, S.A. Anti-humidity replacement with deodorizing and sanitizing properties (Machine-translation by Google Translate, not legally binding)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1950502A (en) * 1933-02-09 1934-03-13 Edward K Madan Combination deodorizer and dehumidifier
US2104589A (en) * 1934-02-23 1938-01-04 Frank W Hartman Refrigerating apparatus
US2117570A (en) * 1935-11-01 1938-05-17 Nash Kelvinator Corp Refrigerating apparatus
US2204910A (en) * 1938-09-30 1940-06-18 Randolph Alfred Arthur Refrigerator odor absorbent
US2206705A (en) * 1939-04-22 1940-07-02 Gen Electric Refrigerating apparatus
US2222882A (en) * 1940-05-14 1940-11-26 Shames Harold Jay Air purifying composition and process therefor
US2423702A (en) * 1944-09-20 1947-07-08 Coleridge W Hart Molded block of activated carbon in a porous casing of fireproofed carbon
US2638179A (en) * 1950-01-06 1953-05-12 Edward M Yard Drying capsule

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1950502A (en) * 1933-02-09 1934-03-13 Edward K Madan Combination deodorizer and dehumidifier
US2104589A (en) * 1934-02-23 1938-01-04 Frank W Hartman Refrigerating apparatus
US2117570A (en) * 1935-11-01 1938-05-17 Nash Kelvinator Corp Refrigerating apparatus
US2204910A (en) * 1938-09-30 1940-06-18 Randolph Alfred Arthur Refrigerator odor absorbent
US2206705A (en) * 1939-04-22 1940-07-02 Gen Electric Refrigerating apparatus
US2222882A (en) * 1940-05-14 1940-11-26 Shames Harold Jay Air purifying composition and process therefor
US2423702A (en) * 1944-09-20 1947-07-08 Coleridge W Hart Molded block of activated carbon in a porous casing of fireproofed carbon
US2638179A (en) * 1950-01-06 1953-05-12 Edward M Yard Drying capsule

Cited By (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4290789A (en) * 1979-03-08 1981-09-22 Wing Industries, Inc. Total energy exchange apparatus
US4534775A (en) * 1982-03-02 1985-08-13 General Time Corp. Air treatment filter element and air treatment filter
US4604110A (en) * 1984-04-19 1986-08-05 General Time Corporation Filter element, filter, and method for removing odors from indoor air
DE3522185A1 (en) * 1984-06-22 1986-02-20 Karl 5200 Siegburg Müller Device for reducing the microbe count in the air
US4682992A (en) * 1984-06-25 1987-07-28 Potters Industries, Inc. Microbicidal coated beads
WO1986005120A1 (en) * 1985-02-28 1986-09-12 General Time Corporation Filter element, filter, and method for removing odors from indoor air
US4948567A (en) * 1988-02-22 1990-08-14 Kabushiki Kaisha Toshiba Deodorizer for refrigerators or the like
US5500037A (en) * 1988-12-06 1996-03-19 Alhamad; Shaikh G. M. Y. Impact Absorber
US5638662A (en) * 1988-12-06 1997-06-17 Alhamad; Shaikh Ghaleb Mohammad Yassin Impact absorber
US5052188A (en) * 1990-10-24 1991-10-01 Gas Research Institute Desiccant materials for use in gas fired cooling and dehumidification equipment
US5332426A (en) * 1992-07-29 1994-07-26 Minnesota Mining And Manufacturing Company Agglomerated activated carbon air filter
US5632954A (en) * 1994-06-20 1997-05-27 Engelhard/Icc Method for killing microorganisms
US5492675A (en) * 1994-09-02 1996-02-20 Brizard; Cyril J. C. Deodorant system
US5665148A (en) * 1994-12-01 1997-09-09 Firma Carl Freudenberg Adsorption air filter and method for its production
US5624478A (en) * 1995-09-14 1997-04-29 Patapanian; Edward Ethylene absorption device
DE19748256A1 (en) * 1997-10-31 1999-05-06 Volkswagen Ag Prevention of unpleasant odors arising from air conditioning equipment
US6346143B1 (en) * 1999-02-25 2002-02-12 Mcgowan Kimberly F. Odor adsorptive filter for refrigerators and freezers
US20030136267A1 (en) * 2001-12-28 2003-07-24 Ku Joseph P. Air deodorizer
US20030221709A1 (en) * 2002-06-04 2003-12-04 Samsung Electronics., Ltd Dishwasher and method of controlling the same
US7389782B2 (en) * 2002-06-04 2008-06-24 Samsung Electronics Co., Ltd. Dishwasher and method of controlling the same
US20040129142A1 (en) * 2003-01-07 2004-07-08 Wallace Wireman Deodorizer mounting
US6908502B2 (en) * 2003-01-07 2005-06-21 Wallace Wireman Deodorizer mounting
US20050183637A1 (en) * 2004-02-19 2005-08-25 Reeser Eileen L. Odor-adsorbing tray for under refrigerator shelves
US7416581B2 (en) 2004-09-03 2008-08-26 Point Source Solutions, Inc. Air-permeable filtration media, methods of manufacture and methods of use
US20060054023A1 (en) * 2004-09-03 2006-03-16 Raetz James A Air-permeable filtration media, methods of manufacture and methods of use
US20080271605A1 (en) * 2004-09-03 2008-11-06 Point Source Solutions, Inc. Air-permeable filtration media, methods of manufacture and methods of use
US8609191B2 (en) 2004-09-03 2013-12-17 Point Source Solutions, Inc. Air-permeable filtration media, methods of manufacture and methods of use
US7892326B2 (en) 2004-09-03 2011-02-22 Point Source Solutions, Inc. Air-permeable filtration media and related systems
US20110129603A1 (en) * 2004-09-03 2011-06-02 Point Source Solutions, Inc. Air-permeable filtration media, methods of manufacture and methods of use
EP1952079A4 (en) * 2005-11-23 2012-04-18 Lg Electronics Inc Refrigerator
US20090217694A1 (en) * 2005-11-23 2009-09-03 Dong-Kyu Kim Refrigerator
US8196417B2 (en) 2005-11-23 2012-06-12 Lg Electronics Inc. Refrigerator
EP1952079A2 (en) * 2005-11-23 2008-08-06 LG Electronics Inc. Refrigerator
US7857896B2 (en) * 2006-03-15 2010-12-28 Sud-Chemie Inc. Moisture absorbing product for use in containers
US20090056361A1 (en) * 2006-03-15 2009-03-05 Sud-Chemie Inc. Moisture absorbing product for use in containers
US20100218468A1 (en) * 2009-02-27 2010-09-02 Electrolux Home Products, Inc. Hanging air filter
US8157882B2 (en) 2009-02-27 2012-04-17 Electrolux Home Products, Inc. Hanging air filter
US20110204762A1 (en) * 2010-02-25 2011-08-25 Whirlpool Corporation Modular system for a domestic refrigerator
US8517483B2 (en) * 2010-02-25 2013-08-27 Whirlpool Corporation Modular system for a domestic refrigerator
US8956446B2 (en) * 2011-08-05 2015-02-17 Tsang-Hung Hsu Separable sorption apparatus
US20140109608A1 (en) * 2011-08-05 2014-04-24 Tsang-Hung Hsu Separable sorption apparatus
US8894746B2 (en) * 2011-12-02 2014-11-25 Alice Chang Odor killing charcoal box systems
US20130139692A1 (en) * 2011-12-02 2013-06-06 Alice Chang Odor killing charcoal box systems
US20150059198A1 (en) * 2013-09-02 2015-03-05 Samsung Electronics Co., Ltd. Dish washer
US9462929B2 (en) * 2013-09-02 2016-10-11 Samsung Electronics Co., Ltd. Dish washer
EP3123872A1 (en) * 2015-07-27 2017-02-01 Somez System for stabilising fresh products
FR3039364A1 (en) * 2015-07-27 2017-02-03 Somez DEVICE FOR STABILIZING A FRESH PRODUCT
EP3123872B1 (en) 2015-07-27 2018-04-18 Somez System for stabilising fresh products
DE102015121694A1 (en) * 2015-12-14 2017-06-14 Vorwerk & Co. Interholding Gmbh Air purifier with additional function
ES2677241A1 (en) * 2017-01-31 2018-07-31 Bolaseca, S.A. Anti-humidity replacement with deodorizing and sanitizing properties (Machine-translation by Google Translate, not legally binding)

Similar Documents

Publication Publication Date Title
US2765046A (en) Air purifying device
US3705480A (en) Dehydrator for gaseous fluids
US7797963B2 (en) Refrigerator with moisture adsorbing device
US20070234636A1 (en) Fishing box with removable desiccant container
US5035065A (en) Method and apparatus using molecular sieves for freeze drying
RU2426959C2 (en) Device for reducing frost deposition in refrigerator
US2217204A (en) Process and apparatus for conditioning air and other gases
KR100949052B1 (en) Dehumidifying device
JP2769213B2 (en) refrigerator
FI65139C (en) FUKTSAMLARANORDNING FOER EN FRYS
DE1017190B (en) Cold room air purifier
JP2763629B2 (en) refrigerator
EP2772291A1 (en) Ethylene absorption filter for refrigerated spaces
KR200393290Y1 (en) Vessel for containing desiccant and deodorant
JPH08303936A (en) Freezing refrigerator
JP2866664B2 (en) How to maintain freshness of agricultural products
JP2000039251A (en) Refrigerator
JPH06213556A (en) Freezer
JPS62297683A (en) Refrigerator
US1473593A (en) Evaporative refrigerator
JPS6240297Y2 (en)
SU428165A1 (en) DESORPTION REFRIGERATION INSTALLATION
JPS616579A (en) Vegetable storage vessel for refrigerator
US20190316816A1 (en) Cold energy storage
JPS63137285U (en)