US2510496A - Furfurylated urea resins and method of preparation - Google Patents

Description

Patented June 6, 1950 UNITED STATESPATENT OFFICE FURFURYLATED UREA RESINS AND METHOD OF PREPARATION Frank J. Carlin, Jr., Saddle River, N. J., assignor to American Cyana-mid Company, New York, N. Y., a corporation of Maine No Drawing. Application December 24, 1946, Serial No. 718,264

9Clalms. (01.260-70) solution of sodium hydroxide.

to those of the non-furfurylated urea resins.

However, the preparation of the furfuryl alcoholmodified urea resins, which are suitable for use as film-forming compositions, as well as for other uses, such as in laminating processes and the like, is accomplished by numerous adverse characteristics. One of the undesirable characteristics is that of discoloration during the process of preparation. Another undesirable characteristic is the lack of stability of the prepared furfuryl alcohol-modiiied urea resins. Still another undesirable factor is the lack of compatibility of furfurylated resins with oil-modified alkyds.

An object of the present invention is to prepare improved furfuryl alcohol-modified urea resins.

Another object is to prepare furfurylated urea resins which are stable upon storage.

A further object is to prepare clear, lightcolored furfurylated urea resins which are compatible with oil-modified alkyd resins.

A still further object is to prepare furfurylated N urea resins which are soluble in organic solvents, such as methanol, iso-propanol, butanol, xylol, ethylene glycol ethers and the like.

According to the present invention, improved furfurylated urea resins areobtained by reacting iurfuryl alcohol with one or more alkyl ethers of dimethylol urea in the presence of an alkaline catalyst, and optionally, partially pqlymerizing the resulting product in the presence of acid.

The following examples are given for the purpose of illustration and not in limitation. The term parts" is used to express parts by weight, unless otherwise indicated.

Example 1 The urea resin A and the iurfuryl alcohol are charged, into a suitable vessel equipped with an agitator and heated for about a half hoiir at about 100 C.. followed by addition of the Heating is con-; tinued for about a half hour, and the batch is then allowed to distill at a vapor temperature of about -85 C. for a period of about one hour.'

The batch is then concentrated by heating at 130 C. under atmospheric pressure until the volatile liquids have been substantially removed. The resulting product is a clear, light-colored, viscous resin which is soluble in butanol, xylol, the methy ether of ethylene glycol and the like. I

Example 2 246 parts of di-methoxymethyl urea 196 parts of furfuryl alcohol 2.7 parts of a 5 N aqueous solution of sodiumhydroxide The di-methoxymethyl urea and the furfuryl alcohol are charged 'into a suitable vessel equipped with an agitator and heated to about 70 0., followed by the addition of the solution of sodium hydroxide. The batch is refluxed at a temperature varying. from about -100 C. for about one hour. Distillation is then initiated and continued until the batch reaches a temperature of 130 C., and until no more distillate is obtained. A clear, light-colored, viscous resin remains;

Example 3 136.5 parts of dirnethylol urea 275 parts of methyl alcohol 0.55 part of phthalic acid 7.4 parts of a 37% aqueous solution I 1.8 parts of a 5 N aqueous solution of sodium hydroxide w 98 parts of iurfuryl alcohol The dimethylol urea, the methyl alcohol, the phthalic acid and the formaldehyde solution are charged into a suitable vessel equipped with an agitator and heated to reflux whereupon a clear solution results. The batch is then adjusted to a pH of about 7.7 with the sodium hydroxide solution and heated to about 100 C. to distill oil? the excess methanol and water. The furfuryl alcohol and 1.8 parts of a 5 N aqueous sodium hydroxide solution are added, and the batch is refluxed for about 2 hours. Distillation is then formaldehyde conducted to a final batch temperature of at least C. under atmospheric pressure until all of the volatile materials are substantially removed. A clear, light-colored, viscous liquid is obtained which is cut with butanol to give a solution having a 70% solids content. One part of this solution is dilutable with up to two parts of xylol.

- 3 Example 4 819 parts of dimethylol urea .1650 parts of methanol 3.3 parts of phthalic acid 44.3 parts of a 37% aqueous formaldehyde solution 7.8 parts of a 5 N aqueous solution of sodium hydroxide 588 parts of furfuryl alcohol The dimethylol urea, the methanol, the phthalic acid and the formaldehyde solution are charged into a suitable vessel equipped with an agitator, and heated to reflux or until a clear solution is obtained. The mixture is adjusted to a pH of about 8.4 with a 5 N aqueous sodium hydroxide solution (about 9.6 parts being required), followed by distillation under a pressure of about 20 inches of mercury to a batch temperature of about 100 C. The furfuryl alcohol and the 7.8 parts of a 5 N aqueous solution of sodium hydroxide are added and refluxed for 2 hours. The product is concentrated by distilling to a final batch temperature of at least 130 C. under atmospheric pressure until no distillateis obtained. A light, clear resin remains, and it may be diluted to an 80% solids content with butanol.

Example 5 492 parts of di-methoxymethyl urea 392 parts of furfuryl alcohol 5.3 parts of a 5 N aqueous solution of sodium hydroxide The di-methoxymethyl urea and the furfuryl alcohol are charged into a suitable vessel equipped with an agitatorand heated to about 90 C. The aqueous sodium hydroxide solution is added, and the batch is refluxed for about 2 hours. The mixture is distilled under atmospheric pressure at a batch temperature of 130 C., and further concentrated by distillation under a pressure of about 20 inches of mercury, the vapor temperature being about 90 C.' A clear, lightcolored liquid is obtained.

' Example 6 135.5 parts of dimethylol urea 275 parts of methanol 0.55 part of phthalic acid 7.4 parts of a 37% aqueous formaldehyde solution 2.4 parts of a 5 N aqueous solution of sodium hydroxide 117.4 parts of furfuryl alcohol by distillation at a temperature of 130 C. A-

clear liquid is obtained which is dilutable with butanol or the monoethyl ether of ethylene glycol.

Example 7 207 parts of furfurylated di-methoxymethyl urea prepared as in Example 4 0.21 part of sulfuric acid 1.6 parts of butanol The above materials are thoroughly mixed and parts of polymerized furfurylated di-methoxymethyl urea prepared as in Example 7 40 parts of alkyd resin A 0.5 part of 100% sulfuric acid The above materials are thoroughly mixed to form a clear solution, and then applied in the form of fllms on wood and steel, followed by baking at about 140 F. for about 1 to 2 hours. The resulting film is clear, glossy, hard and shows goods adhesion and no brittleness.

Example 9 60 parts of furfurylated di-methoxymethyl urea from Example 4 40 parts of alkyd resin A 1 part of 88% sulfuric acid The above materials are thoroughly mixed to form a clear solution, and then applied to wood and steel surfaces in the form of films, followed by heating at about 140 F. for a period of 2 hours. The resulting films are clear, glossy, show good adhesion and no brittleness.

Example 10 50 parts of the furfurylated resin Example 6 40 parts of alkyd resin "3 0.5 part of sulfuric acid The above materials are mixed and diluted to a 45% solids content with a 1:1 butanol-xylol solvent. The solution is sprayed on wooden panels and baked at 140 F. for about an hour, followed by a conventional method of sanding. Another coat of solution is sprayed over the sanded surface, and baked at 140 F. for about 2 hours. After rubbing and polishing, the fllm' shows excellent properties of gloss, hardness, toughness and clarity. Other -furfurylated products prepared according to the other examples may be substituted for the one used herein.

Preparation of area resin "4 100 parts of dimethylol urea 200 parts of methanol prepared in 0.5 part of oxalic acid The above materials are charged into a vessel equipped with a stirrer and heated to reflux.

After refluxing for about V4 hour, the batch is' treated with a 25% sodium hydroxide solution to give a pH of about 9. The batch is then concentrated by distilling at about C. under a pressure of 7 inches of mercury. 4

Preparation of alkyd resin "4 parts of castor oil 148 parts of phthalic anhydride 380 parts of glycerol I Preparation of alkyd resin "B" 120 parts oi. castor oil 148 parts of phthalic acid 98 parts of glycerol The above materials are charged into a vessel equipped with a stirrer and heated at about 220 -C. until an acid number of 8.5 is attained. The

methyl urea, mono-methoxymethyl urea, di-

ethoxymethyl urea, di-amyloxymethyl urea, and the like. When the reaction is initiated by reacting dimethylol urea with an aliphatic alcohol, part or all of the alcohol may be likewise replaced by one or more aliphatic alcohols containing less than '7 carbon atoms. Examples of such alcohols are: ethyl alcohol, iso-propyl alcohol, propyl alcohol, n-butanol, iso-butanol, n-amyl alcohol, iso-amyl alcohol, n-hexanol, and the like.

The furfurylation may be accomplished under alkaline conditions by the use of alkaline catalysts, e. g., sodium hydroxide, potassium hydroxide, sodium carbonate or any of the organic bases, such as triethylamine, diethanolamine, triethanolamine; pyridine, and the like. The amount of catalyst used may vary within relatively wide ranges, but the catalyst is preferably kept within the range of about A to based on the combined weight of the alkyl ether of 'dimethylol urea and iurfuryl alcohol. In addition, sufficient amounts of the alkaline catalyst may be added to neutralize any acid which may be present, as for example, that in the Formalin or that which may be used in the preparationof the alkyl ether of dimethylol urea when such is used.

The amount of furfuryl alcohol used to react with the alkyl ethers of dimethylol urea may vary widely, for example, from about one-tenth mol to about two mols of furfuryl alcohol per mol of the urea compound, the ratio being determined by the use to which the reaction product is to be directed. When the furfurylated urea resin is to be utilized as a coating or film-forming composition, optimum results are obtained by reacting from 1 to 1.25 mols of furfuryl alcohol per mol of the urea compound. Ithas been found that clear, stable products are consistently obtained by concentrating the furfurylated resin at a batch temperature of at least 130 C. Subsequent vacuum distillation at a batch temperature of about 100 C. under reduced pressure may be resorted to for a more complete removal of volatile materials. For other uses, such as in bonding or molding compositions, the amount of furfuryl alcohol may vary according to the properties which the final product is desired to have.

The curing catalysts most suitable for use in conjunction with the film-forming compositions of the present invention have been found to be strong acids, e. g., sulfuric acid, hydrochloric acid, phthalic acid, or salts of such acids, such as, for example, ammonium chloride, ammonium sulfate and aluminum'chloride. When used inamounts varying from about to 5% based on the weight of the resin, excellent results are obtained. It is preferable, however, to remain within the limits of k to 2% by weight of catalyst based on the weight of resin to impart optimum properties to the films.

The resin compositions of the present invention may be used in conjunction with other resins, such as alkylated and non-alkylated aminotriazine-formaldehyde resins, phenol-formaldehyde resins, resorcinol formaldehyde resins, 1inzidified and unmodified alkyd resins, and the My products may be used for molding or casting purposes in which case there may be incorporated various fillers, such as asbestos, glass fibres, cotton flock, silica, and the like. There may also be included various coloring pigments, such as titanium dioxide, chromic oxide, ferric oxide, and the like, as well as various plasticizers and lubricants. Curing catalysts, such as phthalic anhydride, a mixture of cis-endomethylene tetrahydro phthalic anhydride and paratoluene sulfonamide, and the like, may be incorporated into the compositions.

My products may be used as adhesives for paper, wood and other substances with or without fillers and extenders, such as cellulosic fillers, including wood flour, and with or without the customary acidic catalysts or the catalytic salts,

such as ammonium chloride, ferric chloride, etc.

The compatibility of the resins of the present invention, obtained by reacting from 1 to 1.25 mols of furfuryl alcohol with alkyl ethers of dimethylol urea or with the partially polymerized alkyl ethers of dimethylol urea, with oil-modified alkyds gives rise to unique, clear, light-colored solutions and clear, light-colored, cured films. Such compatibility is of importance since unmodified alkyd resins do not impart suflicient flexibility to cured furfurylated urea resins for some specific uses. The alkyds suitable for use in conjunction with furfuryl alcohol-modified resins are those obtained by reacting a polycarboxylic acid with a polyhydric alcohol. The alkyd resins so prepared may then be modified with natural or synthetic non-drying or drying oils, such as castor oil, linseed oil, soya bean oil and the like, or the polycarboxylic acids and polyhydric alcohols may be reacted in the presence of a drying or non-drying oil. In place of the oils, the fatty acid constituents of such oils may be used, among which are: stearic, oleic, recinoleic, linoleic, myristic, capric and the like. Some of the polyhydric alcohols which may be used in the preparation of the'alkyd resins are:

dicarboxylic acid used in the alkyd resins.

glycol, diethylene glycol, pentaerythritol, sorbitol andthe like. Among the suitable polybasic acids which may be used are: maleic, fumaric, succinic, adipic, sebacic and the like. The oil lengths of the alkyd resins used with the furfurylated urea resins may vary within a range of 75450. The term oil length as used herein denotes parts by weight of oil per mol weight of preparation of the The alkyd resins and my furfurylated resins may be used in any desired proportions, for ex- Obviously many variations and deviations may be made without departing from the spirit and scope of the present invention as defined in the appended claims.

I claim:

1. A process for the preparation of a furfurylated alkyl urea ether resin comprising heating under alkaline conditions an alkyl ether of dimethylol urea with furfuryl alcohol in the presence of an alkaline catalyst, the alkyl 01 said ether having less than 7 carbon atoms.

2. A process for the preparation of a Iurturylated alkyl urea ether resin comprising heating under alkaline conditions an alkyl ether of dimethylol urea with furfuryl alcohol in the presence of sodium hydroxide, the alkyl or said ether having less than 7 carbon atoms.

3. A process for the preparation 01' a furturylated alkyl urea ether resin comprising heating under alkaline conditions di-methoxymethyl urea with furfuryl "alcohol in the presence of an alkaline catalyst.

4. A process for the preparation of a furfurylated alkyl urea ether resin comprising heating under alkaline conditions a partially-polymerized alkylated dimethylol urea resin with Iurfuryl alcohol in the presence of an alkaline catalyst, the urea resin being alkylated with an aliphatic alcohol having less than '7 carbon atoms.

5. A process for the preparation of a lightcolored, clear furfurylated alkyl urea ether ,resin comprising heating under alkaline conditions from 1 to 1.25 m01s of furfuryl alcohol with one mol of an alkyl ether of dimethylol urea in the presence otanalkaline catalyst, the alkyl of said ether having less than '7 carbon atoms.

6.. A process for the preparation or a lightcolored,v partially-polymerized furturylated alkyl urea ether resin comprising heating a turturylated urea resin prepared according to claim 1 at a temperature of less than C. in the presence of less than one-halt per cent by weight 01' an acidic catalyst.

'7. A turfurylated alkyl urea ether resin pre- I pared as in claim 3.

8. A light-colored, clear furturylated alkyl urea ether resin prepared as in claim 5.

9. A partially-polymerized turturylated urea resin prepared by heating under alkaline conditions an alkyl ether of dimethylol urea with furiuryl alcohol in' the presence of an alkaline catalyst, the alkyl of said ether having less than 7 carbon atoms, then heating the resulting reaction product with an acidic catalyst at a temperature of less than 100 C. until the resin is partially polymerized, whereby the xylol tolerance of said reaction product is increased.

FRANK J. CARLIN, JR.

REFERENCES CITED The following references are of record in the file of this patent:

UNITED STATES PATENTS Number Name Date 2,197,357 Widmer Apr. 16, 1940 2,213,921 Sorenson Sept. 3, 1940 2,335,701 Root Nov. 30, 1943 2,386,744 Myers Oct. 9, 1945 2,397,451 West Mar. 26, 1946

Claims (1)

1. A PROCESS FOR THE PREPARATION OF A FURFURYLATED ALKYL UREA ETHER RESIN COMPRISING HEATING UNDER ALKALINE CONDITIONS AN ALKYL ETHER OF DIMETHYLOL UREA WITH FURFURYL ALCOHOL IN THE PRESENCE OF AN ALKALINE CATALYST, THE ALKYL OF SAID ETHER HAVING LESS THAN 7 CARBON ATOMS.