US2442762A - Methods of improving the magnetic quality of anisotropic permanent magnets containing iron, nickel, cobalt, and aluminum - Google Patents
Methods of improving the magnetic quality of anisotropic permanent magnets containing iron, nickel, cobalt, and aluminum Download PDFInfo
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- US2442762A US2442762A US501674A US50167443A US2442762A US 2442762 A US2442762 A US 2442762A US 501674 A US501674 A US 501674A US 50167443 A US50167443 A US 50167443A US 2442762 A US2442762 A US 2442762A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
Definitions
- This invention relates to the production of permanent magnets, more especially of the types which consist principally of iron, nickel, cobalt, andalu-mi-num, andspeoifically the types which are cooled in a magnetic field to give them increased values of magnetic energy.
- magnets having a nominal composition of 51 per cent iron, 13 /2 per cent nickel, 24 per cent cobalt, 8 per cent aluminum and 3 per cent copper were found to vary in (BI'Dmax value from .25 10 to 4.6x 10
- virgin commercial aluminum, electrolytic copper, electrolytic nickel, and cobalt in the form of rondelles refined from African ore were employed. The product was unexpectedly variable and much of it unsatisfactory in quality.
- the magnets were cast, then maintained for from one to two hours at a temperature of from 1290 to 1320 C. and then cooled in a magnetic field of about 1,000 oersteds at a rate such that they reached a temperature of about 600 C. in nine months.
- the specimens were covered with an' asbestos shield or other suitable protective material wnne'appud to the poles of an electromagnet. After'being taken from the electromagnet at around500ito 600 C-.- the specimens were'cooledin air at room temperature and then treated by aging for'eight hours at 595 C; It is not necessary, howeveiflto cool the magnets to room-temperature bfore aging at 595 C.
- the mechanism by which carbon is removed from the alloy during heat treating is believed to be by oxidation to carbon monoxide and the effusion of carbon monoxide along grain boundaries.
- the oxygen supply is believed to be obtained from the oxides which form in the alloy during melting and casting. This heat treating operation may be carried out at temperatures between about 1,200 C. and about 1,350 C.
- the fullness factor is the ratio Dm, B,H,
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Hard Magnetic Materials (AREA)
Description
Patented June 8, 1948 METHQDS- QF IMLROVINGF THE MAGNETIC- QUALITY OF ANISOTROPIC PERMANENT. MAGNETS CONTAINING. IRON NICKEL, GOBAIIIT', AND ALUMINUM William, 0. Ellis, Maplewood, and Lawrence Ferguson, South Orange, N. .L, assignors to Bell Telephone Laboratories, Incorporated, New York, N. Y., acorporationd NewYork No Drawing. Application-September 9, 1943,
ser al No. 501,674;
2 Claims. (01. 148-10) This invention relates to the production of permanent magnets, more especially of the types which consist principally of iron, nickel, cobalt, andalu-mi-num, andspeoifically the types which are cooled in a magnetic field to give them increased values of magnetic energy.
In a patent to G. V. Jonas, 2,295,082, dated September 8, 1942, are described improved permanent magnets having a tBI Dmx valuejlyin between 3,000,000- and 5,0009% 38 com ared to previously produced permanent magnets inwhich the (3K)max value generally didnot exceedabout 2,000,000 or at the most 3,000,000. Magnets prepared according to the Jonas method comprise variousproportions of between 16 per cent to 30 per cent cobalt, 12 per cent to 20 per cent nickel, 6 per cent to 11 per cent aluminum, and the balance chiefly iron. The compositions may, however, include copper or titanium in amounts up to 7 per cent copper or per cent titanium or both, of these elements. The general subject,- matteroj. the Jonas patent has been known for some time, having become available by the publication of British Patent 522,731, accepted June 26, 1940. During this time considerable efiorts have been expended in producing magnets of various sizes and dimensions with high values of (BH)msX. In many cases where size or weight is an important consideration in a piece of apparatus or equipment, a correspondingly high value of (BI'Dmax is likewise of importance. These attempts to produce products such as one would expect to produce did not achieve a uniform degree of success. It was found, for example, that there were unexpected variations in quality of magnets and that the expected high values of (BH)max were not always achieved.
Thus, for example, magnets having a nominal composition of 51 per cent iron, 13 /2 per cent nickel, 24 per cent cobalt, 8 per cent aluminum and 3 per cent copper were found to vary in (BI'Dmax value from .25 10 to 4.6x 10 For these magnets, virgin commercial aluminum, electrolytic copper, electrolytic nickel, and cobalt in the form of rondelles refined from African ore were employed. The product was unexpectedly variable and much of it unsatisfactory in quality.
As part of a manufacturing process the magnets were cast, then maintained for from one to two hours at a temperature of from 1290 to 1320 C. and then cooled in a magnetic field of about 1,000 oersteds at a rate such that they reached a temperature of about 600 C. in nine months. In order to insure this rate of cooling, the specimens were covered with an' asbestos shield or other suitable protective material wnne'appud to the poles of an electromagnet. After'being taken from the electromagnet at around500ito 600 C-.- the specimens were'cooledin air at room temperature and then treated by aging for'eight hours at 595 C; It is not necessary, howeveiflto cool the magnets to room-temperature bfore aging at 595 C.
The non-uniformity of the product led to the supposition that the heat treatment at 1290" to 1320 C. had been unsatisfactorily or ineifectively P m d an i -memes le ei s a i s we eretreaiecl 9 or-mare rees wi h; he resu t that n alm st; a in a s themsenet c r n ri e' were rea y inn dv d-l In n tances, imp o em n w s. noted f om ea h reaction' of t e hea ieil ent un i immanen qual y o th specimen be ame x ellen It! the earl s ages Q hi deve eem e the re son; t r th n qvementli ual t attribu d w more fective he t r atment we er i 'wa found that this assumption was erroneous and the discovery upon which the present invention is based was made.
It was discovered that the improvement which was achieved by reheat-treating specimens resulted from the elimination of carbon which was contained as an impurity. It has been established by controlled experiments that harmful amounts of carbon in the alloys can be removed by suitable heat treatment. For instance, in the composition, 51 per cent Fe, 13 per cent Ni, 24 per cent Co, 8 per cent Al, and 3 per cent Cu, 0.1 per cent carbon reduces the (BH) max value from a normal of 5.0) (10 (for nearly carbon free material) to approximately 1.0 10 Maintaining the specimens for about six hours at 1315 0., however, reduces the carbon content of the alloy to below .02 per cent and brings the (BI'Dmax value back to normal. The mechanism by which carbon is removed from the alloy during heat treating is believed to be by oxidation to carbon monoxide and the effusion of carbon monoxide along grain boundaries. The oxygen supply is believed to be obtained from the oxides which form in the alloy during melting and casting. This heat treating operation may be carried out at temperatures between about 1,200 C. and about 1,350 C.
- So far as is known at the present time the difference between 0.012 per cent carbon and the smallest amount which has been achieved, namely 0.005 per cent carbon, does not appear to be substantial as the difference in (BH) max at 0.012
per cent carbon and the smallest carbon content which could be achieved is no greater than about per cent. As the carbon content increases, the magnetic quality decreases rapidly so that at about 0.084 per cent carbon the value of (BI-l) max is less than one-fourth of that achieved when the carbon content is kept low. As the carbon content increases, a further rapid reduction in the magnetic quality occurs.
Some typical experimental data are given in the following table.
Fullness Factor Ha Oersteds Per C ent Carbon 13., (BHM Gausses Specimen No. G-O X PPS"? cm- HO cut-paws In the above table:
Bm, measured in gausses, is maximum magnetiza- V tiona Hc, measured in oersteds, is coercive force.
Br, measured in gausses, is residual magnetization.
(BH) max, measured in millions of gaussesoerstads, is maximum energy product.
The fullness factor is the ratio Dm, B,H,
What is claimed is:
1. A method of improving the magnetic quality of a magnet formed of an alloy consisting essentially of about 51 /2 per cent iron, 13 /2 per cent nickel, 24 per cent cobalt, 8 per cent aluminum and 3 per cent copper and having initially a carbon content greater than .012 per cent, said magnet having been produced by subjecting a body of said alloy to a cycle comprising heating at a temperature between about 1290 C. and about 1320 C. for a period of time between about 4 1 hour and about 2 hours, cooling said body to about 600 C. in a magnetic field having a strength of about 1000 oersteds at a rate such that it reached600 C. in about 9 minutes and aging at about 595 C. for about 8 hours, which .method comprises again subjecting said magnet body to said cycle by reheating said magnet and again maintaining it at a temperature between about 1290 OJand about 1320 C. for between about 1 hour and about 2 hours, cooling said body to about 600 C. in a magnetic field having a field strength of about 1000 oersteds at a rate such that it reaches 600 C. in about 9 minutes and aging said body at about 595 C. for about 8 hours. J x
, 2. The method defined in claim 1 wherein the .magnet is subjected to more than one repetition of the heat treating cycle set forth in said claim;
WILLIAM C. ELLIS. LAWRENCE FERGUSON.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US501674A US2442762A (en) | 1943-09-09 | 1943-09-09 | Methods of improving the magnetic quality of anisotropic permanent magnets containing iron, nickel, cobalt, and aluminum |
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US501674A US2442762A (en) | 1943-09-09 | 1943-09-09 | Methods of improving the magnetic quality of anisotropic permanent magnets containing iron, nickel, cobalt, and aluminum |
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US2442762A true US2442762A (en) | 1948-06-08 |
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US501674A Expired - Lifetime US2442762A (en) | 1943-09-09 | 1943-09-09 | Methods of improving the magnetic quality of anisotropic permanent magnets containing iron, nickel, cobalt, and aluminum |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3203838A (en) * | 1962-09-28 | 1965-08-31 | Foundation The Res Inst Of Ele | Method of manufacturing permanent magnets having large coercive force |
US3259530A (en) * | 1963-09-18 | 1966-07-05 | Permag Corp | Method of double ageing a magnetic hysteresis alloy |
EP3470828A2 (en) | 2017-05-29 | 2019-04-17 | Elegant Mathematics Limited | Real-time methods for magnetic resonance spectra acquisition |
Citations (12)
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US1358810A (en) * | 1919-04-04 | 1920-11-16 | Westinghouse Electric & Mfg Co | Process of treating magnetizable material |
US1542233A (en) * | 1920-12-09 | 1925-06-16 | Commentry Fourchambault & Deca | Alloy |
US1621523A (en) * | 1917-12-18 | 1927-03-22 | Ludlum Steel Co | Titanium alloy |
US1947274A (en) * | 1933-02-01 | 1934-02-13 | Gen Electric | Permanent magnet and method of making it |
US1955141A (en) * | 1931-10-19 | 1934-04-17 | Warner Electric Brake Corp | Heat treatment of magnetic parts |
US1978221A (en) * | 1932-09-13 | 1934-10-23 | Allegheny Steel Co | Method of and apparatus for treating metallic materials |
US2002689A (en) * | 1934-03-02 | 1935-05-28 | Bell Telephone Labor Inc | Magnetic material and method of treating magnetic materials |
US2048166A (en) * | 1931-10-01 | 1936-07-21 | Int Nickel Co | Copper-nickel-titanium alloys |
GB522731A (en) * | 1938-12-07 | 1940-06-26 | Philips Nv | Improvements in or relating to permanent magnets and processes of treating alloys for such magnets |
US2207685A (en) * | 1939-07-17 | 1940-07-09 | Indiana Steel Products Co | Permanent magnet alloy and method of making the same |
US2293240A (en) * | 1939-04-12 | 1942-08-18 | Bosch Gmbh Robert | Permanent magnet |
US2295082A (en) * | 1938-12-06 | 1942-09-08 | Hartford Nat Bank & Trust Co | Permanent magnet and method of making the same |
-
1943
- 1943-09-09 US US501674A patent/US2442762A/en not_active Expired - Lifetime
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1621523A (en) * | 1917-12-18 | 1927-03-22 | Ludlum Steel Co | Titanium alloy |
US1358810A (en) * | 1919-04-04 | 1920-11-16 | Westinghouse Electric & Mfg Co | Process of treating magnetizable material |
US1542233A (en) * | 1920-12-09 | 1925-06-16 | Commentry Fourchambault & Deca | Alloy |
US2048166A (en) * | 1931-10-01 | 1936-07-21 | Int Nickel Co | Copper-nickel-titanium alloys |
US1955141A (en) * | 1931-10-19 | 1934-04-17 | Warner Electric Brake Corp | Heat treatment of magnetic parts |
US1978221A (en) * | 1932-09-13 | 1934-10-23 | Allegheny Steel Co | Method of and apparatus for treating metallic materials |
US1947274A (en) * | 1933-02-01 | 1934-02-13 | Gen Electric | Permanent magnet and method of making it |
US2002689A (en) * | 1934-03-02 | 1935-05-28 | Bell Telephone Labor Inc | Magnetic material and method of treating magnetic materials |
US2295082A (en) * | 1938-12-06 | 1942-09-08 | Hartford Nat Bank & Trust Co | Permanent magnet and method of making the same |
GB522731A (en) * | 1938-12-07 | 1940-06-26 | Philips Nv | Improvements in or relating to permanent magnets and processes of treating alloys for such magnets |
US2293240A (en) * | 1939-04-12 | 1942-08-18 | Bosch Gmbh Robert | Permanent magnet |
US2207685A (en) * | 1939-07-17 | 1940-07-09 | Indiana Steel Products Co | Permanent magnet alloy and method of making the same |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3203838A (en) * | 1962-09-28 | 1965-08-31 | Foundation The Res Inst Of Ele | Method of manufacturing permanent magnets having large coercive force |
US3259530A (en) * | 1963-09-18 | 1966-07-05 | Permag Corp | Method of double ageing a magnetic hysteresis alloy |
EP3470828A2 (en) | 2017-05-29 | 2019-04-17 | Elegant Mathematics Limited | Real-time methods for magnetic resonance spectra acquisition |
EP3495806A2 (en) | 2017-05-29 | 2019-06-12 | Elegant Mathematics Limited | Real-time methods for magnetic resonance spectra acquisition, imaging and non-invasive ablation |
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