US2435707A - Method of and apparatus for treating oil - Google Patents
Method of and apparatus for treating oil Download PDFInfo
- Publication number
- US2435707A US2435707A US396144A US39614441A US2435707A US 2435707 A US2435707 A US 2435707A US 396144 A US396144 A US 396144A US 39614441 A US39614441 A US 39614441A US 2435707 A US2435707 A US 2435707A
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- oil
- soap
- impurities
- particles
- agglomerating
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Links
- 238000000034 method Methods 0.000 title description 20
- 239000003921 oil Substances 0.000 description 104
- 235000019198 oils Nutrition 0.000 description 103
- 239000000344 soap Substances 0.000 description 76
- 239000012535 impurity Substances 0.000 description 70
- 239000002245 particle Substances 0.000 description 58
- 238000001914 filtration Methods 0.000 description 50
- 239000000463 material Substances 0.000 description 41
- 239000000203 mixture Substances 0.000 description 27
- 238000007670 refining Methods 0.000 description 21
- 239000003599 detergent Substances 0.000 description 17
- 235000014113 dietary fatty acids Nutrition 0.000 description 14
- 239000000194 fatty acid Substances 0.000 description 14
- 229930195729 fatty acid Natural products 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 14
- 229940090045 cartridge Drugs 0.000 description 13
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 11
- 229960004418 trolamine Drugs 0.000 description 11
- 239000002023 wood Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 150000007513 acids Chemical class 0.000 description 10
- 239000010687 lubricating oil Substances 0.000 description 10
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 239000007787 solid Substances 0.000 description 8
- 230000009471 action Effects 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 7
- 238000011109 contamination Methods 0.000 description 7
- 150000007524 organic acids Chemical class 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000010688 mineral lubricating oil Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 241000218657 Picea Species 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000010913 used oil Substances 0.000 description 2
- 241000272470 Circus Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- -1 above described Substances 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical class C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/02—Loose filtering material, e.g. loose fibres
- B01D39/04—Organic material, e.g. cellulose, cotton
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M175/00—Working-up used lubricants to recover useful products ; Cleaning
- C10M175/0016—Working-up used lubricants to recover useful products ; Cleaning with the use of chemical agents
Definitions
- Lubricating oils employed in the-oil circulating systems of such engines become contaminated during the use of the engines with-solid impurities including particles of carbon, meta-l; and foreign matter, such assili'ca or thefllke, taken up from the air, which part-icles'are of sufllci'ent' size to permit their removal at substantially the rate of their supply to the oil'- circulating system" by afilt'er interposed thereiir containing canton flannel or cotton waste:
- theoii in such a system becomes contaminated during? use of the engine by particles the small to lie-removed from the oil by such a filter; including particles of soot" from the oxidation ofthe fuel, particles of carbon from the breakdown of the lubricating" oil,
- inorganic abrasives such: as silica, from the air, and these minute particles? of impurities; referred to' herein as suspended or colloidal impurities, during their accumulation inthe lubricating oil form deposits, varnish-like and gum-my in nature; upon the bearing surfaces, cylinder and piston walls, and the piston: rings of the engine; greatly increasing friction and impairing the emcien'cy of the engine.
- agglomerati-ng material asuse'di mean any material having a tendencytocause suspended materials, usually present in: the lubricating oil of an internal combustion engine after some use, to coalesce, combine, or" agglomerate intomasses large enough to be readily filtered out.
- our invention contemplates such a continuous replenishment of the agglomerating material in the refining unit in the circulating system by a supply which is not coated or choked or rendered ineffective by the deposit of impurities within the unit so that such supply continually replenishes the agglomerating material consumed for the full life of the filter medium in the refining unit.
- the filter medium first contacted by the oil stream entering it and carrying solid and agglomerated impurities is rapidly coated with a slime bed of such impurities, so increas ing the resistance to the passage of oil through the refining unit as to render it ineffective in a short period of use and before the filtering properties of the filtering medium in the remainder of the unit have been exhausted.
- Still another object of our invention is to provide a refining apparatus for use in the circulating system of an internal combustion engine which is compact in form and inexpensive in manufacture.
- FIG. 1 is a vertical sectional view of the relining apparatus
- Figs. 2 and 3 are enlarged fragmentary sectional views taken as indicated by the lines 2-2 and 33, respectively, of Fig. 1.
- soaps of alkylolamines such as triethanolamine and tri-isopropanolamine are admirably suited for the purpose.
- the soaps of alkylamines or arylamines which are sufliciently alkaline to form a soap with an organic acid can be employed. While a soap of any alkylolamine may be employed, we prefer to employ a soap of triethanolamine.
- the soap is formed by mixing the tri-ethanolamine, forv example, with a.
- Soaps of which the foregoing are examples and which are referred to herein as agglomerating materials or soaps of limited solubility, are heated to liquefaction and then sprayed or sprinkled upon a carrier or supporting medium so as to present an extremely large surface.
- the purifying cartridge or unit of a mixture of a material in granule or particle form and a filtering material of a fibrous nature.
- the material in particle form may be porous cellulosic material, such as pressed walnut hulls, ground coconut shells, sawdust, or ground wood, or material of a substantially non-porous nature, such as sand, silica, or the like.
- the particle size be such as to pass a sixmesh per inch scheen and be retained on a twenty-four-mesh per inch screen.
- the filtering material is initially formed in one mass or a plurality of masses so that its fibres are loose, distended, and separated from each other.
- the materials capable of use as a filtering medium such as cotton waste or the like
- the paper, ground or beaten into one mass Or a plurality of masses so that the fibres thereof are distended and separated from each other, may be employed as the supporting vehicle for the agglomerating soap of limited solubility, the soap being sprayed or sprinkled thereon after being heated to liquefaction.
- results of commercial value may be achieved utilizing a mixture of particles such as above described, and fibrous material, with the latter bearing the agglomerating soap of limited solubility.
- such a mixture has the disadvantage that. the effectiveness of. the layer of soap upon the fibres of aper is impaired by the filtering or straining action of the paper, causing a.
- the agglomerating soap of limited solubility to material which is in particle form.
- Employing the particles as the Supporting vehicle for the agglomerating soap permits a more uniform distribution of the soap throughout the refining unit, since the very small quantity of such soap required for each unit may be better or more uniformly sprayed, sprinkled, or mixed with the lesser volume of particles than with the greater volume of filtering material.
- the soap is formed with a sufficient excess of tri ethanolamine to neutralize such acids, such acids being employed to form all or part of the soap.
- the particles of wood coated with the agglomerating soap which may be referred to as a granular oil refining medium or finely divided particles or refining medium, are then mixed with the mass or plurality of masses of the beaten or ground paper so that the particles are distributed throughout the mass or masses. While the proportions of the granular refining medium and the filtering material will vary with the conditions of use and the pressure within the oil circulating system, we have found that for use in a refining unit interposed in the circulating system of a Diesel engine a mixture of from 15 to 45% by weight of the granular refining material with the filtering material accomplishes excellent results. After the materials are mixed as above described, the mixture is subjected to pressure,
- the mixture may be formed into a cylindrical. car tridge II confined within a porous layer of cloth or metal l2 covering the exterior cylindrical wall and the end walls l3 and M, the cylindrical cartridge being provided with. a central cylindrical pipe l extending therethrough and with a plurality of openings It therein.
- a cylin-v drical cartridge is placed within a container ll of a diameter larger than that of the cartridge with its ends. is. and inyensasement with, the container and walls.
- the agglomeratingsoap such as hereinbefore described. has very limited solubility in the 011, being of the order or 0.001 per cent to a few hundredths of one per cent.
- some of the agglomerating soap enters into solution in the oil and is carried with the oil stream through the circulating system and engine. During this travel, the agglomerating soap in solution contacts colloidal and suspended impurities, agglomerating them and thus conditioning the oil for removal of the agglomerated masses of such impurities by the filter material 2?. which it contacts upon its entry into the container I1.
- the filtering medium 22 As the oil passes through the mixture, contacting the agslomerating soap upon the surfaces of the particles 23, it is repeatedly conditioned for furtherfiltration by the filtering medium 22. After each such conditioning step or a limited number of. conditioning steps, the 011 containing suspended and colloidal impurities agglomerated to masses of strainable or filterable dimensions is subjected to a step of filtration by passage through some of the adjacent filtering medium 22. By such a -mixture, therefore, the filtering medium 22 first fining mass of relatively small volume.
- any tendency for the agglomerated impurities to deposit upon the first portions or the filtering medium contacted by the oil stream after ent y nto the container I! and to form thereon an impervious slime bed before the filtering properties of the. remainder of the filtering medium 22 are exhausted is greatly diminished by the fact that only a very small part of the agglomeratlng soap is in solution in the oil within the circulating system and engine, so that the proportion of the suspended and colloidal impurities agglomerated to fllterable dimensions before the oil stream reaches such first portion of the filtering medium 22 is only a very small fraction of the colloidal or suspended impurities present in the oil stream. Further, such tendency is counteracted by variations in pressure upon th mixture within the container I!
- the presence of a large number of particles 23 in contact or proximity witheach other permits the oil to flow readily through the mixture.
- the fibres of filtering medium 22 are not bonded to or intertwined with the particles 23 so intimately as to exert a straining or filtering or flowimpeding action upon the stream of oil, as is t e case with the relation of the fibres to each other when a bed of impurities is deposited therein.
- the oil is permitted to flow in an almost infinite number of paths in thin streams or films along the surfaces of the particles incontact or close proximity with each other, with little resistance thereto, although the filtering medium thereadjacent, due to the entrapped impurities therein, may offer considerable resistance to the flow of oil therethrough.
- the presence and relationship of the particles 23, therefore, insures that the oil will readily flow through the mixture at a pressure customary in the oil circulating systems of internal combustion engines until the filtering property of all of the filtering medium 22 throughout the mixture is exhausted.
- the enormous number and the relation to each other of the particles 23 insure a most intimate contact of the coating of agglomerating soap thereon with the suspended and colloidal impurities in the extremely thin streams or films of oil flowing in contact therewith.
- results of commercial value may be secured by substituting for the agglomerating soap of limited solubility one of the alkylolamines', such as triethanolamine.
- the practical results in employing an agglomerating soap such as herein described are vastly superior, and we believe this to be due both to the fact that the soap has a greater solubility in the oil stream than the triethanolamine, the solubilities being of the order of 3 to 1, so that the soap better preconditions the oil in the circulating system and engine for refining by the mixture, and to the fact that the soap, having a very considerably greater volume than an equivalent amount of triethanolamine, may be more uniformly distributed throughout the refining mixture, afford- 8 ing an enormously greater surface for contact with the colloidal and suspended impurities.
- the method of facilitating the removal from a lubricating oil of the colloidal impurities produced therein during the operation of an internal combustion engine which comprises: adding a non-aqueous slightly oil-soluble agglomerating amino soap to an oil so contaminated; and thereafter filtering out the agglomerated masses produced by such addition, said addition and removal being rendered continuous during the use of the oil by circulating the contaminated oil through a supply of said agglomerating agent and a medium capable of producing such filtration.
- the method of facilitating the removal from a lubricating oil of the colloidal impurities produced therein during the operation of an internal combustion engine which comprises: adding to an oil so contaminated an agglomerating amino soap of a saponifiable organic acid; and thereafter filtering out the agglomerated masses produced by such addition.
- a method for removing minute impurities from mineral lubricating oil comprising the steps of alternately agglomerating said impurities to bodies of larger size by contacting such impurities while suspended in the oil with saponifiable organic acid amino soap disposed upon the surfaces of particles of porous material disposed in proximate relationship with bodies of fibrous filtering material; and removing said agglomerated bodies from the oil by entrapment within said fibrous material.
- a method of treating a flowing stream of used lubricating oil containing suspended colloidal impurities produced in use and of insufficient size for filtration comprises: alternately agglomerating such impurities to bodies of dimensions sufficient for removal by filtration by contacting the oil with slightly oil-s01- uble agglomeratin alkylolamine fatty acid soap disposed upon particles of relatively inert material; and removing such agglomerated bodies from the oil by passing oil bearing such agglomerated bodies through a filter medium adjacent said particles.
- Means for treating used mineral lubricating oil and for removal of colloidal particles therefrom comprising: a filtering medium incapable of removing substantial proportions of said col loidal particles; and carrier particles of relatively inert material carried adjacent said filtering medium and carrying thereon slightly oil-soluble saponifiable organic acid amino soaps adapted to agglomerate said colloidal particles to bodies of sufiicient size for removal by said filtering medium.
- agglomerating soap is alkylolamine soap of coconut oil fatty acids.
- agglomerating soap is alkylolamine soap of saponifiable fatty acids.
- Means for treating contaminated mineral lubricating oil and forremoval of colloidal particles therefrom comprising: a filtering medium incapable of removing substantial proportions of said. colloidal particles; and slightly oil-soluble amino soaps of saponifiable organic acids associated with said filtering medium and adapted to agglomerate said colloidal particles to bodies of suflicient sizes for removal by said filtering medium.
- agglomerating soap is an amino soap of synthetic acids from the oxidation of parafiins.
- An oil filter comprising a porous filtering medium having intimately admixed therewith prior to use an alkylolamine soap of a fatty acid.
- a filter adapted for treating an oil during contamination by particles of solid impurities and colloidal impurities of smaller size than said particles comprising: a filter mass of such porosity as to allow the oil and colloidal impurities to pass therethrough and to filter the solid particles therefrom; and an agglomerating amino soap of saponifiable fatty acid and having a slight solubility in oil, the soap being carried by said filter mass in a quantity sufiicient to agglomerate said colloidal impurities to bodies of dimensions filtered from the oil by said filter mass at substantially the rate of contamination of the oil by said colloidal impurities during the efiective life of said filter mass.
- a filter as in claim 16 wherein the soap has oil solubility in the order of 0.001 per cent to a few hundredths of 1 per cent.
- a filter adapted for treating an oil during contamination by particles of solid impurities and colloidal impurities of smaller size than said particles comprising: a filter mass of such porosity as to allow the oil and colloidal impurities to pass therethrough and to filter the solid particles therefrom; and an agglomerating soap of an alkylolamine carried by said filter mass in a quantity sufilcient to agglomerate said colloidal impurities to bodies of dimensions filtered from the oil by said filtermass at substantially the rate of contamination of the oil by said colloidal impurities during the effective life of said filter mass.
- a filter as in claim 18 wherein the soap is an alkylolamine soap Of saponifiable fatty acid.
- a filter as in claim 18 wherein the soap is an alkylolamine soap of acids naturally occurring in wood.
- a filter as in claim 18 wherein the soap is a triethanolamine soap of saponifiable organic acid.
- a filter as in claim 13 wherein the soap is a triethanolamine soap of acids naturally occurring in wood.
- a filter adapted for treating an oil during contamination by particles of solid impurities and colloidal impurities of smaller size than said particles comprising: a filter mass of such porosity as to allow the oil and colloidal impurities to pass l 10 therethrough and to filter the solid particles therefrom; and an agglomerating coconut oil fatty acid soap of triethanolamine carried by said filter mass in aquantity suificient to agglomerate said colloidal impurities to bodies of dimensions filtered from the oil by said filter mass at substantially the rate ofcontamination of the oil by said colloidal impurities during the effective life of said filter rhassr Y i 24.
- a process for treating mineral lubricating oil as it is used, said oil containing a detergent material comprising: circulating said used oil; dissolving in said oil a slightly oil-soluble agglomerating amino soap of sa-ponifiable organic acid, said soap being capable of agglomerating to filterable particle size colloidal impurities formed in said oil during use; and passing said oil and contained agglomerated particles through filtering means capable of removing said agglomerated particles and incapable of removing substantial proportions of said detergent.
- a process as in claim 25 wherein said soap is an alkylolamine soap of saponifiable fatty acid.
- the method of treating a flowing stream of non-acidic lubricating oil during contamination by colloidal impurities which includes the steps of: agglomerating the colloidal impurities in the oil flowing in the stream at substantially the rate at which they are formed to bodies of filterable dimensions with a coconut oil fatty acid soap of an alkylolamine in solution in said oil; filtering said agglomerated bodies from the oil at one locus in the stream; and maintaining said soap in solution in the oil at a concentration sufficient to agglomerate the colloidal impurities in the oil at substantially the rate at which they are formed.
- the method of treating a flowing stream of lubricating oil during contamination by 001- loidal impurities which includes the steps of: agglomerating in the oil along the stream such impurities of a particle size too small for removal by filtration to bodies of sufllcient size for removal by filtration with an alkylolamine soap of coconut oil fatty acids in solution in said oil; simultaneously filtering such agglomerated bodies from the oil by passing the oil through a filter mass interposed in the stream; and subjecting such oil to further agglomerating action by contact with said soap supported within said filter mass.
Description
Feb. 10, 1948. p, BRAY ET 2,435,707
METHOD OF AND APPARATUS FOR TREATING OIL Filed May 31, 1941 I. o I l ow I I Z 1 23 I l F7 I /Nl//VTO UMP/c 5. ERAS L/OHN K. Qua-561.1.
A 7'TORNE Y6.
Patented Feb. l0, 1948 METHOD OF" AND APPARATUS FOR TREATING OIL Ulric-Bi Bray, Paloslverdes Estates, and John K. Russell, Los Angeles, Calit.
Applioatlon May 31'; 1941', Serial No. 396144 30=GlaimSs- 1% 0111" invention relates: to a method: and. ape paratus for the refining: of: iubrihatlngsoiiirn the? oil: circulating systems of internala combustion engines," such as Dieseiengines; gasoline engines; employed in. passenger" vehicles; and: the: 11km. Certain. subject herein discioseds but. not; claimed. 18:? coveredzim our co-pending application. Serial No:v 396145.
Many of the: commercial" lubricating oils emplayed in: the: lubricating systems of? Diesel and; other engines; are: compounded? so that they are: initially alkaline and; remain.v so: during: their cI fective lives, or are compoundedi with: oxidation inhibiting. agents so. thatthey remain substantially non-acidic during their efi'ective lives, and for the purpose of illustrating the advantages of our invention we'hereinaf-ter describeits usefn connection with theoil circulatingsystem of a Diesel engine" employing such oils;
Lubricating oils employed in the-oil circulating systems of such engines become contaminated during the use of the engines with-solid impurities including particles of carbon, meta-l; and foreign matter, such assili'ca or thefllke, taken up from the air, which part-icles'are of sufllci'ent' size to permit their removal at substantially the rate of their supply to the oil'- circulating system" by afilt'er interposed thereiir containing canton flannel or cotton waste: Likewise, theoii in such a system" becomes contaminated during? use of the engine by particles the small to lie-removed from the oil by such a filter; including particles of soot" from the oxidation ofthe fuel, particles of carbon from the breakdown of the lubricating" oil,
and particlesof inorganic abrasives; such: as silica, from the air, and these minute particles? of impurities; referred to' herein as suspended or colloidal impurities, during their accumulation inthe lubricating oil form deposits, varnish-like and gum-my in nature; upon the bearing surfaces, cylinder and piston walls, and the piston: rings of the engine; greatly increasing friction and impairing the emcien'cy of the engine.
Iir some commercial lubricating oil's supplied for the lubricating: systems of lD'i'e'sel and other engines, there is provideda minute proportionof a detergent havingthe property of washing and owl'ciumzsoan'ofi oxidizedipetroieunc acids such as calcium Alon" calcium; salts of phenolic: bodies,
2e and calcium salts of" alkylated: phosphoric acid, and by the" term "detergent herein" is meant the" foregoing and such; othersubstances as may be: carried by the oil: in. the circulating system of an engine and whichipossess;the'property of removin'g'impurities from: and preventingitheir accumulation: upon the bearing surfaces of the. engine.
In the use of a filter made of canton flannel, cotton waste, or the like-in: such an oil circulating system containing detergent-bearing oil, we have foundithat the detergent. exercises; its property not only in washing from the bearing surfaces the accumulated deposits; of impurities, but: also in washing from and cleansing the filter medium of the impurities deposited and entrapped therein, with: the result that the intended function of the filter medium is impaired, the; accumulation of the impurities in the oil. circulating system: is; mpid-,. and the effective life of, the: oil is short.
One.- ot the? obdects; 0E our-mention is to prevent or-to reduce to thepoint where it is negligible the tendency of the: detergent in the lubrieating oil to. remove: from a filter and refining unit interposed in the: circulating. system the: deposited and. entrappedimpuritiesi During the. use 0! such a detergent-bearing oil, it is found that the detergent is consumed until the quantity in the system may" reach such a low value as to be: ineflective' before the lubricating qualities of the oil areexhausted. It is possible that the detergentiis consumed by its formation of a container or: envelope around each of the particles of suspended: or. colloidal impurities which it washes from the bearing surfaces or contacts in the oilstream.
It is an object of our invention to prevent such consumption of the: detergent or reduce its: consumption'to the point whereit isnegligible so that aminutequantity in the oil stream re:- mains: effective for the life" of the oiiL This we accomplish by supplying to the oil stream an agglomeratingmaterial which causes the suspended or colloidal impurities to coalesce, combine, or agglomerate. The words agglomerati-ng material asuse'di herein mean any material having a tendencytocause suspended materials, usually present in: the lubricating oil of an internal combustion engine after some use, to coalesce, combine, or" agglomerate intomasses large enough to be readily filtered out. possible that the great'reduction in the consumption" of the detergentresulting irom such a supply to the oilstreamtot such agglomerating materialrjs caused by the freeingof the detergent on or around the suspended or colloidal impurities by the agglomerating action of such material, with the result that the detergent is returned to the oil stream with its cleansing or washing property substantially undiminished. The coalescing or agglomeration of the suspended or colloidal impurities is continued by the agglomerating material until there are formed masses of such impurities of such dimensions as to cause their entrapment and retention by the filter medium in the circulating system and the prevention of washing therefrom by the action of the detergent in the oil.
In such a process it is desirable that an intimate frequent contact of the agglomerating material and the suspended or colloidal impurities be provided, both in the engine and oil cir-' culating system and within the refining unit interposed in the system. In accordance with our invention, such contact in the engine and circulating system is accomplished by utilizing an agglomerating material of SllfilClEnt solubility in the oil to exert an agglomerating action upon the impurities within the engine and circulating system, and such contact is accomplished within the refining unit by providing therein the agglomerating material with a very large surface area.
Since the agglomerating material is consumed in the process herein described, it is necessary to continuously replenish it, and our invention contemplates such a continuous replenishment of the agglomerating material in the refining unit in the circulating system by a supply which is not coated or choked or rendered ineffective by the deposit of impurities within the unit so that such supply continually replenishes the agglomerating material consumed for the full life of the filter medium in the refining unit.
When a filter of conventional construction containing only canton flannel, cotton waste, or
the like is used in such a circulating system, we have found that the filter medium first contacted by the oil stream entering it and carrying solid and agglomerated impurities is rapidly coated with a slime bed of such impurities, so increas ing the resistance to the passage of oil through the refining unit as to render it ineffective in a short period of use and before the filtering properties of the filtering medium in the remainder of the unit have been exhausted. Coupled with the object last stated, therefore, is our object of so combining in a refining unit a supply of agglomerating material and a filter medium as not only to prevent the coating of the agglomerating material with impurities, rendering such material ineffective, but also to insure that the filteringproperty of the entire mass of filtering material within the unit will be exhausted before the resistance to passage of oil through the unit has increased to an extent to render the unit ineffective.
During the passage of the oil bearing the suspended and colloidal impurities through the refining unit, it is desirable to contact such impurities with the agglomerating material and thereafter immediately pass the oil bearing such agglomerated masses through 2, filter medium capable of removing and entrapping them so that the agglomerating agent next contacting the oil stream may better agglomerate the colloidal or suspended impurities, and it is desirable that such alternate contacts of the oil stream bearing such impurities with the aggiomerating material and passages of the oil stream-through a filter medium should be very numerous within the refining unit in order that the suspended and colloidal impurities may be removed substantially at the rate at which they are formed and their accumulation in the oil stream prevented, and it is an object of our invention to provide such a process and apparatus for its practice.
Still another object of our invention is to provide a refining apparatus for use in the circulating system of an internal combustion engine which is compact in form and inexpensive in manufacture.
An embodiment of such apparatus of our invention adapted for use in a, circulating system containing a compounded detergent-bearing oil and connected to a Diesel engine is illustrated in the accompanying drawing, in which Fig. 1 is a vertical sectional view of the relining apparatus; and
Figs. 2 and 3 are enlarged fragmentary sectional views taken as indicated by the lines 2-2 and 33, respectively, of Fig. 1.
As agglomerating material, we have found that soaps of alkylolamines such as triethanolamine and tri-isopropanolamine are admirably suited for the purpose. The soaps of alkylamines or arylamines which are sufliciently alkaline to form a soap with an organic acid can be employed. While a soap of any alkylolamine may be employed, we prefer to employ a soap of triethanolamine. The soap is formed by mixing the tri-ethanolamine, forv example, with a. fatty acid having the formula in which a: is more than 10, coconut oil fatty acid, or hydroxylated fatty acids, such as castor oil fatty acid, or synthetic acids produced by catalytic oxidation of parafllns, forming a neutral soap so that the mixture does not react alkaline to phenolphthalein.
Soaps, of which the foregoing are examples and which are referred to herein as agglomerating materials or soaps of limited solubility, are heated to liquefaction and then sprayed or sprinkled upon a carrier or supporting medium so as to present an extremely large surface.
We prefer to form the purifying cartridge or unit of a mixture of a material in granule or particle form and a filtering material of a fibrous nature. The material in particle form may be porous cellulosic material, such as pressed walnut hulls, ground coconut shells, sawdust, or ground wood, or material of a substantially non-porous nature, such as sand, silica, or the like. We prefer when employing ground wood or sawdust that the particle size be such as to pass a sixmesh per inch scheen and be retained on a twenty-four-mesh per inch screen. The filtering material is initially formed in one mass or a plurality of masses so that its fibres are loose, distended, and separated from each other. 0f the materials capable of use as a filtering medium, such as cotton waste or the like, we prefer to employ beaten or ground paper. The paper, ground or beaten into one mass Or a plurality of masses so that the fibres thereof are distended and separated from each other, may be employed as the supporting vehicle for the agglomerating soap of limited solubility, the soap being sprayed or sprinkled thereon after being heated to liquefaction. While results of commercial value may be achieved utilizing a mixture of particles such as above described, and fibrous material, with the latter bearing the agglomerating soap of limited solubility. such a mixture has the disadvantage that. the effectiveness of. the layer of soap upon the fibres of aper is impaired by the filtering or straining action of the paper, causing a. deposition of. impurities upon the soap coating and diminishing thearea of such coating available for contact with the suspended or colloidal impurities in the oil stream. We prefer, therefore, to apply the agglomerating soap of limited solubility to material which is in particle form. Employing the particles as the Supporting vehicle for the agglomerating soap permits a more uniform distribution of the soap throughout the refining unit, since the very small quantity of such soap required for each unit may be better or more uniformly sprayed, sprinkled, or mixed with the lesser volume of particles than with the greater volume of filtering material. When employing particles of wood or other granular material having some acids therein or thereon, the soap is formed with a sufficient excess of tri ethanolamine to neutralize such acids, such acids being employed to form all or part of the soap.
The particles of wood coated with the agglomerating soap, which may be referred to as a granular oil refining medium or finely divided particles or refining medium, are then mixed with the mass or plurality of masses of the beaten or ground paper so that the particles are distributed throughout the mass or masses. While the proportions of the granular refining medium and the filtering material will vary with the conditions of use and the pressure within the oil circulating system, we have found that for use in a refining unit interposed in the circulating system of a Diesel engine a mixture of from 15 to 45% by weight of the granular refining material with the filtering material accomplishes excellent results. After the materials are mixed as above described, the mixture is subjected to pressure,
. rendering it sufiiciently compact to bring adjacent coated particles into contactor proximity with each other throughout the mixture in all directions. The mixture while thus compressed has a porosity such as to permit the ready flow of oil therethrough at pressures customary in the oil circulating system of an internal combustion engine. We have found, for example, that, if there be mixed 840 grams or 30 ounces of ground or beaten paper and 260 grams or 9 ounces of ground spruce or spruce sawdust, so that the mixture before compression has a volume of about 5,100 cubic inches, and this mixture is compressed to form a cartridge or cylinder with a diameter of 6 /56 inches and a length of 8 3/ inches and a volume of about 300 cubic inches, there is provided both the requisite porosity of the mass and the desired contact and proximity of the wood particles. The quantity of agglomerating soap of limited solubility contained in the mixture also varie somewhat with the conditions of use. In the example above referred to, such soap in the quantity of .1% to .3% by weight of the oil employed in the crank case charge is ample.
' As illustrated in Fig. i of the drawing, wherein the numeral l indicates the refining unit, the mixture may be formed into a cylindrical. car tridge II confined within a porous layer of cloth or metal l2 covering the exterior cylindrical wall and the end walls l3 and M, the cylindrical cartridge being provided with. a central cylindrical pipe l extending therethrough and with a plurality of openings It therein. When such a cylin-v drical cartridge is placed within a container ll of a diameter larger than that of the cartridge with its ends. is. and inyensasement with, the container and walls. lflr andlil, respectively, it will be seen that oil may be conveyed from the circu lat-ing system through an inlet pipe 20 to the space within the container I! around the cylindrical cartridge H, and through the cartridge II to the central cylindrical pipe l5. The treated and refined oil is led from the central pipe I! through. an outlet, pipe 2| back to the oil circulating system of the engine. As is illustrated in Figs. 2 and 3, the relative proportions of the filtering material; indicated by the numeral 22 and the particles 23 oiwood or the like, and the degree to which the mixture is compressed are so related that adjacent particles 23 are in contact with or in close proximity to each other. There being an extremely large number of the particles 23 distributed throughout the mixture. there is thus established a labyrinth of an enormous number of paths in all directions. on the surface of the particles 23, along which oil may travel through the mixture.
The agglomeratingsoap, such as hereinbefore described. has very limited solubility in the 011, being of the order or 0.001 per cent to a few hundredths of one per cent. During the passage of the oil through the mixture within the container I 1. some of the agglomerating soap enters into solution in the oil and is carried with the oil stream through the circulating system and engine. During this travel, the agglomerating soap in solution contacts colloidal and suspended impurities, agglomerating them and thus conditioning the oil for removal of the agglomerated masses of such impurities by the filter material 2?. which it contacts upon its entry into the container I1. As the oil passes through the mixture, contacting the agslomerating soap upon the surfaces of the particles 23, it is repeatedly conditioned for furtherfiltration by the filtering medium 22. After each such conditioning step or a limited number of. conditioning steps, the 011 containing suspended and colloidal impurities agglomerated to masses of strainable or filterable dimensions is subjected to a step of filtration by passage through some of the adjacent filtering medium 22. By such a -mixture, therefore, the filtering medium 22 first fining mass of relatively small volume.
We believe that, as each agglomerating step is performed, the detergent enveloping the col o dal and suspended particles is released and returned to the oil stream, available for continuing its washing and cleansing action to remove the deposited impurities from the bearing surfaces. Our tests demonstrate that when employing a mixture suchas described, the amount of deter s nt in the oil stream is not substantially (llminished, although the colloidal and suspended impurities are agglomerated and entrapped within the refining medium most efficiently.
Any tendency for the agglomerated impurities to deposit upon the first portions or the filtering medium contacted by the oil stream after ent y nto the container I! and to form thereon an impervious slime bed before the filtering properties of the. remainder of the filtering medium 22 are exhausted is greatly diminished by the fact that only a very small part of the agglomeratlng soap is in solution in the oil within the circulating system and engine, so that the proportion of the suspended and colloidal impurities agglomerated to fllterable dimensions before the oil stream reaches such first portion of the filtering medium 22 is only a very small fraction of the colloidal or suspended impurities present in the oil stream. Further, such tendency is counteracted by variations in pressure upon th mixture within the container I! caused by the stopping and starting of the engine and variations in the engine speed. This variation in pressure upon the mixture causes a relative movement of the particles 23 and adjacent filtering material 22, particularly near the outer surface of the cylindrical cartridge H where the slime bed forms in ordinary filters. The relative movement of the particles 23 and filtering medium 22 with the resilience possessed by the compressed fibres of the filtering medium 22 operates to dislodge any excess of deposited impurities from the filtering medium adjacent the exterior of the cylindrical cartridge II, the dislodged impurities being carried by the oil stream into the mixture and trapped and retained'by the filtering medium further within the cartridge.
Furthermore, if there are deposited upon the filtering material 22 adjacent the exterior of the cylindrical cartridge l l impurities in slight excess of such impurities within the interior of the cartridge I i, tending to impede the fiow of oil therethrough, the presence of a large number of particles 23 in contact or proximity witheach other permits the oil to flow readily through the mixture. The fibres of filtering medium 22 are not bonded to or intertwined with the particles 23 so intimately as to exert a straining or filtering or flowimpeding action upon the stream of oil, as is t e case with the relation of the fibres to each other when a bed of impurities is deposited therein. Thus the oil is permitted to flow in an almost infinite number of paths in thin streams or films along the surfaces of the particles incontact or close proximity with each other, with little resistance thereto, although the filtering medium thereadjacent, due to the entrapped impurities therein, may offer considerable resistance to the flow of oil therethrough. The presence and relationship of the particles 23, therefore, insures that the oil will readily flow through the mixture at a pressure customary in the oil circulating systems of internal combustion engines until the filtering property of all of the filtering medium 22 throughout the mixture is exhausted. At the same time the enormous number and the relation to each other of the particles 23 insure a most intimate contact of the coating of agglomerating soap thereon with the suspended and colloidal impurities in the extremely thin streams or films of oil flowing in contact therewith.
Results of commercial value may be secured by substituting for the agglomerating soap of limited solubility one of the alkylolamines', such as triethanolamine. However, we have found that the practical results in employing an agglomerating soap such as herein described are vastly superior, and we believe this to be due both to the fact that the soap has a greater solubility in the oil stream than the triethanolamine, the solubilities being of the order of 3 to 1, so that the soap better preconditions the oil in the circulating system and engine for refining by the mixture, and to the fact that the soap, having a very considerably greater volume than an equivalent amount of triethanolamine, may be more uniformly distributed throughout the refining mixture, afford- 8 ing an enormously greater surface for contact with the colloidal and suspended impurities.
While those embodiments of our invention hereinbefore illustrated and described are fully capable of performing the objects and providing the advantages primarily stated, and while that use of our invention specifically described herein demonstrates the accomplishment of such objects and the importance of such advantages, our invention, it is understood, is not restricted to the specific embodiment or uses herein set forth.
We claim as our invention:
1. The method of facilitating the removal from a lubricating oil of the colloidal impurities produced therein during the operation of an internal combustion engine, which comprises: adding a non-aqueous slightly oil-soluble agglomerating amino soap to an oil so contaminated; and thereafter filtering out the agglomerated masses produced by such addition, said addition and removal being rendered continuous during the use of the oil by circulating the contaminated oil through a supply of said agglomerating agent and a medium capable of producing such filtration.
2. The method of facilitating the removal from a lubricating oil of the colloidal impurities produced therein during the operation of an internal combustion engine, which comprises: adding to an oil so contaminated an agglomerating amino soap of a saponifiable organic acid; and thereafter filtering out the agglomerated masses produced by such addition.
3. A method for removing minute impurities from mineral lubricating oil comprising the steps of alternately agglomerating said impurities to bodies of larger size by contacting such impurities while suspended in the oil with saponifiable organic acid amino soap disposed upon the surfaces of particles of porous material disposed in proximate relationship with bodies of fibrous filtering material; and removing said agglomerated bodies from the oil by entrapment within said fibrous material.
4. A method of treating a flowing stream of used lubricating oil containing suspended colloidal impurities produced in use and of insufficient size for filtration, which method comprises: alternately agglomerating such impurities to bodies of dimensions sufficient for removal by filtration by contacting the oil with slightly oil-s01- uble agglomeratin alkylolamine fatty acid soap disposed upon particles of relatively inert material; and removing such agglomerated bodies from the oil by passing oil bearing such agglomerated bodies through a filter medium adjacent said particles.
5. Means for treating used mineral lubricating oil and for removal of colloidal particles therefrom, comprising: a filtering medium incapable of removing substantial proportions of said col loidal particles; and carrier particles of relatively inert material carried adjacent said filtering medium and carrying thereon slightly oil-soluble saponifiable organic acid amino soaps adapted to agglomerate said colloidal particles to bodies of sufiicient size for removal by said filtering medium.
6. Means according to claim 5 wherein the agglomerating soap is alkylolamine soap of coconut oil fatty acids.
7. Means according to claim 5 wherein the agglomerating soap is alkylolamine soap of saponifiable fatty acids.
8. Means according to claim 5 wherein the carrier particles are particles of wood and the agn -aw glomerating soaps are amino soaps of acids naturally occurring in the wood.
1 9. Means for treating contaminated mineral lubricating oil and forremoval of colloidal particles therefrom, comprising: a filtering medium incapable of removing substantial proportions of said. colloidal particles; and slightly oil-soluble amino soaps of saponifiable organic acids associated with said filtering medium and adapted to agglomerate said colloidal particles to bodies of suflicient sizes for removal by said filtering medium.
10. Means according to claim 9 wherein the agglomerating soap is an amino soap of synthetic acids from the oxidation of parafiins.
11. An oil filter comprising a porous filtering medium having intimately admixed therewith prior to use an alkylolamine soap of a fatty acid.
12. Means according to claim 9 in which the soaps are soaps of coconut oil fatty acid.
13. Means according to claim 9 wherein the soaps are amino soaps of acids naturally occurring in wood.
14. Means as in claim 9 wherein the filtering medium comprises wood sawdust.
15. Means according to claim 9 wherein the filtering medium comprises fibrous materials.
16. A filter adapted for treating an oil during contamination by particles of solid impurities and colloidal impurities of smaller size than said particles, comprising: a filter mass of such porosity as to allow the oil and colloidal impurities to pass therethrough and to filter the solid particles therefrom; and an agglomerating amino soap of saponifiable fatty acid and having a slight solubility in oil, the soap being carried by said filter mass in a quantity sufiicient to agglomerate said colloidal impurities to bodies of dimensions filtered from the oil by said filter mass at substantially the rate of contamination of the oil by said colloidal impurities during the efiective life of said filter mass.
17. A filter as in claim 16 wherein the soap has oil solubility in the order of 0.001 per cent to a few hundredths of 1 per cent.
18. A filter adapted for treating an oil during contamination by particles of solid impurities and colloidal impurities of smaller size than said particles, comprising: a filter mass of such porosity as to allow the oil and colloidal impurities to pass therethrough and to filter the solid particles therefrom; and an agglomerating soap of an alkylolamine carried by said filter mass in a quantity sufilcient to agglomerate said colloidal impurities to bodies of dimensions filtered from the oil by said filtermass at substantially the rate of contamination of the oil by said colloidal impurities during the effective life of said filter mass.
19. A filter as in claim 18 wherein the soap is an alkylolamine soap Of saponifiable fatty acid.
20. A filter as in claim 18 wherein the soap is an alkylolamine soap of acids naturally occurring in wood.
21. A filter as in claim 18 wherein the soap is a triethanolamine soap of saponifiable organic acid.
22. A filter as in claim 13 wherein the soap is a triethanolamine soap of acids naturally occurring in wood.
23. A filter adapted for treating an oil during contamination by particles of solid impurities and colloidal impurities of smaller size than said particles, comprising: a filter mass of such porosity as to allow the oil and colloidal impurities to pass l 10 therethrough and to filter the solid particles therefrom; and an agglomerating coconut oil fatty acid soap of triethanolamine carried by said filter mass in aquantity suificient to agglomerate said colloidal impurities to bodies of dimensions filtered from the oil by said filter mass at substantially the rate ofcontamination of the oil by said colloidal impurities during the effective life of said filter rhassr Y i 24. A process for treating mineral lubricating oil as it is used, said oil containing a detergent material, said process comprising: circulating said used oil; and passing said oil through filter means containing an amino soap capable of causing removal of colloidal impurities from the oil, the filter being incapable of removing substantial roportions of said detergent.
25. A process for treating mineral lubricating oil as it is used, said oil containing a detergent material, the process comprising: circulating said used oil; dissolving in said oil a slightly oil-soluble agglomerating amino soap of sa-ponifiable organic acid, said soap being capable of agglomerating to filterable particle size colloidal impurities formed in said oil during use; and passing said oil and contained agglomerated particles through filtering means capable of removing said agglomerated particles and incapable of removing substantial proportions of said detergent.
26. A process as in claim 25 wherein said organic acid is a fatty acid.
27. A process as in claim 25 wherein said soap is an alkylolamine soap of saponifiable fatty acid.
28. The method of treating a flowing stream of non-acidic lubricating oil during contamination by colloidal impurities, which includes the steps of: agglomerating the colloidal impurities in the oil flowing in the stream at substantially the rate at which they are formed to bodies of filterable dimensions with a coconut oil fatty acid soap of an alkylolamine in solution in said oil; filtering said agglomerated bodies from the oil at one locus in the stream; and maintaining said soap in solution in the oil at a concentration sufficient to agglomerate the colloidal impurities in the oil at substantially the rate at which they are formed.
29. The method of treating a flowing stream of lubricating oil during contamination by 001- loidal impurities, which includes the steps of: agglomerating in the oil along the stream such impurities of a particle size too small for removal by filtration to bodies of sufllcient size for removal by filtration with an alkylolamine soap of coconut oil fatty acids in solution in said oil; simultaneously filtering such agglomerated bodies from the oil by passing the oil through a filter mass interposed in the stream; and subjecting such oil to further agglomerating action by contact with said soap supported within said filter mass.
30. A process as in claim 25 wherein the amino soap is a triethanolamine soap.
ULRIC B. BRAY. JOHN K. RUSSELL.
REFERENCES CITED UNITED STATES PATENTS Name Date Dietrich Oct. 11, 1932 (Other references on following page) Number Number 11 UNITED STATES PATENTS Name Date Maverick June 20, 1933 Vobach May 18, 1937 Franklin et a1 Sept. 21, 1937 Vobach Oct. 12, 1937 Miller Oct. 18, 1938 Sutton May 9, 1939 Alton May 28, 1940 Blair et a1 July 16, 1940 Number 12 Name Date Johnson Nov. 1'l,-'1942 Greger Dec. 1; 1942 Ashworth Dec. 15,4942 Allam et a1. Dec. 22, 1942 Miller et a1. Feb. 9, 1943 South May 25, 1943 Allam June 15, 1943 Wells et a1 Mar. '7, 1944
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US396144A US2435707A (en) | 1941-05-31 | 1941-05-31 | Method of and apparatus for treating oil |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US396144A US2435707A (en) | 1941-05-31 | 1941-05-31 | Method of and apparatus for treating oil |
Publications (1)
Publication Number | Publication Date |
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US2435707A true US2435707A (en) | 1948-02-10 |
Family
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US396144A Expired - Lifetime US2435707A (en) | 1941-05-31 | 1941-05-31 | Method of and apparatus for treating oil |
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US (1) | US2435707A (en) |
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US2675919A (en) * | 1951-12-04 | 1954-04-20 | Albert R White | Compressible oil filter pack |
US3156648A (en) * | 1962-03-16 | 1964-11-10 | Gen Motors Corp | Filter cartridge for a dry cleaning system |
US3156647A (en) * | 1962-02-26 | 1964-11-10 | Gen Motors Corp | Filter for a dry cleaning apparatus |
US3198334A (en) * | 1962-02-26 | 1965-08-03 | Gen Motors Corp | Filter for a dry cleaning apparatus |
US5067455A (en) * | 1989-11-04 | 1991-11-26 | Nippondenso Co., Ltd. | Method and apparatus for adding additives to lubricating oil |
WO2005111181A1 (en) | 2004-05-17 | 2005-11-24 | Viatech Systems Ab | Process for the purification of spent process oil |
US20100252509A1 (en) * | 2009-04-01 | 2010-10-07 | Kipers Kenneth C | Filter Medium for Metal-Working Liquids |
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US20100252509A1 (en) * | 2009-04-01 | 2010-10-07 | Kipers Kenneth C | Filter Medium for Metal-Working Liquids |
US9302209B2 (en) * | 2009-04-01 | 2016-04-05 | Kageht Llc | Filter medium for metal-working liquids |
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