US2401580A - Method of increasing the high temperature strength of heat-resisting alloys - Google Patents
Method of increasing the high temperature strength of heat-resisting alloys Download PDFInfo
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- US2401580A US2401580A US515924A US51592443A US2401580A US 2401580 A US2401580 A US 2401580A US 515924 A US515924 A US 515924A US 51592443 A US51592443 A US 51592443A US 2401580 A US2401580 A US 2401580A
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- 239000000956 alloy Substances 0.000 title description 33
- 229910045601 alloy Inorganic materials 0.000 title description 33
- 238000000034 method Methods 0.000 title description 17
- 238000010438 heat treatment Methods 0.000 description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- 238000011282 treatment Methods 0.000 description 14
- 238000010791 quenching Methods 0.000 description 9
- 229910052759 nickel Inorganic materials 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 7
- 230000032683 aging Effects 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 229910052804 chromium Inorganic materials 0.000 description 7
- 239000011651 chromium Substances 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 229910052750 molybdenum Inorganic materials 0.000 description 7
- 239000011733 molybdenum Substances 0.000 description 7
- 239000010955 niobium Substances 0.000 description 7
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 7
- 229910052721 tungsten Inorganic materials 0.000 description 7
- 239000010937 tungsten Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000012937 correction Methods 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 239000001996 bearing alloy Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
Definitions
- This invention relates to an improvement in heat-resisting alloy and has for an object to provide procedure for increasing the resistance to deformation of such alloys when subjected to stresses at high temperatures.
- a further object of the invention is to produce a. procedure for increasing the high temperature, creep strength of heat-resisting alloys.
- Heat-resisting alloy steels like other steels. are increasingly susceptible to deformation at higher temperatures, with the result that the creep strength and the rupture strength of such steels decrease as the temperature of the steel increases.
- An object of the present invention. therefore, is to improve the high temperature characteristics of heat-resisting steels in order that they will be more effective for the intended purposes when subjected to load while existing at temperatures ranging from about 1300 F. to about 1550 F.
- My invention involves the discovery that the strength of heat-resisting alloys is improved and that such alloys are rendered more resistant to distortion at high temperatures by being sphjected to a high temperature heat treatment followed by a rapid cooling such as is obtained by water quenching, where this procedure is followed by an aging treatment at .a temperature within the range of from about 1300 F. to about 1550 F. That is to say, I have discovered that a treatment, such as is herein defined, will improve the high temperature strengthlneluding the creep strengthof heat-resisting alloys.
- the graph reproduced in the accompanying drawing is based on the application of my invention to a ferrous alloy containing 0.46% carbon, 0.61% manganese, 0.69% silicon, 13.96% chromium. 20.23% nickel, 3.65% molybdenum, 3.74% tungsten and 4.20% columbium, with the remainder principally iron except for the usual impurities in common amounts.
- This alloy was partially fabricated by rolling and forging into sections of the desired size and shape which were then heated to the temperatures indicated by the following table, water quenched, and then machined to form test pieces of the desired size. The test pieces were aged for approximately sixteen hours at 1500 F. before testing.
- the high temperature heat treatment was in each instance accomplished within a gas mufile so furnace and the section treated was maintained at the high temperature for about one hour. While the quenching at the high temperature is preferably a Water quench, an oil or air quench may be employed. It should. however. be noted that rapid cooling is essential for satisfactory results and that a water quench appears to be the most effective.
- the aging is also an important and an essential tep in the procedure.
- the aging is accomplished at the temperature of use. That is to say, where the alloy is to be employed at a temperature of 1500 F., it is aged by being subjected to that temperature for approximately sixteen hours and then air-cooled.
- the aging treatment may be resorted to at any time after the high temperature solution treatment. The period of this treatment is not highly critical but about sixteen hours is indicated as desirable.
- the foregoing table discloses that the high temperature strength of the alloy is increased as the temperature of the heat treatment is increased. It also discloses that the percentage of elongation and the percentage of reduction in area decreases with the temperature of the high temperature or solution treatment, with the result that the exact temperature employed will be governed by the particular alloy involved and the characteristics to be developed in the alloy.
- a method of increasing the load carrying ability of an alloy consisting of chromium within the range of from about 12% to 22%, nickel within the range of from about 10% to 30%, molybdenum, tungsten and columbium each within the range of from about 2% to 6%. carbon within the range of from about 0.20% to about 0.60% with the remainder substantially all iron, which consists in subjecting the same to a temperature of at least 2150 F., followed by a quick cooling and then subjecting such alloy to an aging heat treatment within the range of from about 1350 F. to about 1550 F. and for approximately sixteen hours.
- GUNTHER MOI- LING made from an alloy consisting of chromium 15 Certificate of Correction Patent No. 2,401,580.
- nickel within the range of Irom about 10% to 30% molybdenum, tungsten and columbium each within the range of from about 2% to 6%, carbon within the range of from about 0.20% to 0.60% with the remainder substantially all iron, which consists in subjecting such article to a short time heat treatment within the range of from about 2150" F. to 2400 F.. followed by a water quench and then subjecting the same to an aging treatment for approximately sixteen hours at a temperature within the range of from about 1350 F. to about 1550 F.
- GUNTHER MOI- LING made from an alloy consisting of chromium 15 Certificate of Correction Patent No. 2,401,580.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
Description
June 4, 1946. G. MOHLING 2,401,530
METHOD OF INCREASING THE HIGH TEMPERATURE STRENGTH OF HEAT-RESISTING ALLDYS Filed Dec. 28, 1943 INVENTOR Patented June 4, 1946 .METHOD OF INCREASING THE HIGH TEM- PERATURE STRENGTH OF HEAT-RESIST- ING ALLOYS Gunther Mohling, Lo'udonvilie, N. Y., assignor to Allegheny Ludlum Steel Corporation, a corporation of Pennsylvania Application December 28, 1943, Serial No. 515,924
4 Claims. I
This invention relates to an improvement in heat-resisting alloy and has for an object to provide procedure for increasing the resistance to deformation of such alloys when subjected to stresses at high temperatures.
A further object of the invention is to produce a. procedure for increasing the high temperature, creep strength of heat-resisting alloys.
Heat-resisting alloy steels, like other steels. are increasingly susceptible to deformation at higher temperatures, with the result that the creep strength and the rupture strength of such steels decrease as the temperature of the steel increases. An object of the present invention. therefore, is to improve the high temperature characteristics of heat-resisting steels in order that they will be more effective for the intended purposes when subjected to load while existing at temperatures ranging from about 1300 F. to about 1550 F.
Thr above and other objects are accomplished by means of a procedure hereinafter set forth and defined.
In the drawing accompanying and forming a part hereof, I have included curves which visually indicate the improvement in the high temperature strength of heat-resisting alloys resulting from the treatment herein outlined as an embodiment of my invention.
This figure give the results in hours to rupture, when samples heat treated from a series of temperatures were subjected to constant loads at a temperature of 1500 F.
My invention involves the discovery that the strength of heat-resisting alloys is improved and that such alloys are rendered more resistant to distortion at high temperatures by being sphjected to a high temperature heat treatment followed by a rapid cooling such as is obtained by water quenching, where this procedure is followed by an aging treatment at .a temperature within the range of from about 1300 F. to about 1550 F. That is to say, I have discovered that a treatment, such as is herein defined, will improve the high temperature strengthlneluding the creep strengthof heat-resisting alloys.
While my invention may be effectively employed in connection with various types of heatresisting alloys, I have carried on extensive investigations in connection with alloys such as those including Percent Carbon 0.20- 0.60 Chromium 12.00-22.00 Nickel 10.00-30.00 Molybdenum 2.00- 6.00 Tungsten 2.00- 6.00 Columbium 2.00- 6.00
with the remainder principally iron, except for usual impurities in common amounts.
The graph reproduced in the accompanying drawing, is based on the application of my invention to a ferrous alloy containing 0.46% carbon, 0.61% manganese, 0.69% silicon, 13.96% chromium. 20.23% nickel, 3.65% molybdenum, 3.74% tungsten and 4.20% columbium, with the remainder principally iron except for the usual impurities in common amounts. This alloy was partially fabricated by rolling and forging into sections of the desired size and shape which were then heated to the temperatures indicated by the following table, water quenched, and then machined to form test pieces of the desired size. The test pieces were aged for approximately sixteen hours at 1500 F. before testing.
The high temperature heat treatment was in each instance accomplished within a gas mufile so furnace and the section treated was maintained at the high temperature for about one hour. While the quenching at the high temperature is preferably a Water quench, an oil or air quench may be employed. It should. however. be noted that rapid cooling is essential for satisfactory results and that a water quench appears to be the most effective.
The aging is also an important and an essential tep in the procedure. Where the material is to be employed at a temperature within the range of from 1350 F. to 1550 F'., the aging is accomplished at the temperature of use. That is to say, where the alloy is to be employed at a temperature of 1500 F., it is aged by being subjected to that temperature for approximately sixteen hours and then air-cooled. The aging treatment may be resorted to at any time after the high temperature solution treatment. The period of this treatment is not highly critical but about sixteen hours is indicated as desirable.
Load
Temperature of quench None (as rolled):
Hours Elongation Elongation-" Reduction do- 2175" F;
Hours Elongation .percent Rg duction do Hours. Elcngaiiom Reduction, .d
Hours Elongation. "percent.
Reduction do. 2300 7.:
Hours Elongation percenti Reduction .do 2325 F.:
Hours Elongation percent Reduction ..,.do.. 2375 F;
Hours i i Elongation. "U percut... 8 Reduction do. 2400" I";
Hurs. ElongatlOiL. Reduction.
The foregoing table discloses that the high temperature strength of the alloy is increased as the temperature of the heat treatment is increased. It also discloses that the percentage of elongation and the percentage of reduction in area decreases with the temperature of the high temperature or solution treatment, with the result that the exact temperature employed will be governed by the particular alloy involved and the characteristics to be developed in the alloy.
I have also employed the procedure above-outlined on alloys such as above-defined but which also include from about to about 30% of cobalt. The cobalt-bearing alloys respond effectively to the treatment, making it apparent that the rupture strength-at high temperatures-of austenitic chrome-nickel-cobalt, heat-resisting alloys is also improved by my procedure.
Analysis of the results discloses that the creep strength of the alloys is substantially increased by a short time temperature heat treatment at temperatures in excess of 2150 F. and that the creep strength is materially improved as the temperature of the short time heat treament is increased above 2200 F. The creep strength or the ability to resist distortion under load is progressively improved by a very high temperature heat treatment in excess of 2350' F. On the other hand, the material reduction in the ductility of the alloy occasioned by heat treatments above 2350 F. make it apparent that the range of utility of the alloy is somewhat reduced by such treatment, even though its rupture strength and its ability to resist distortion are increased.
For this reason, it is apparent that some further investigation may be required for the purpose of determining the particular temperature to be employed in connection with the high temperature solution treatment, in order to obtain the desired physical characteristics for each particular alloy. It, however, can be definitely stated that the high temperature strength of heat-resisting alloys of the chrome-nickel, austenitic type is materially improved by the treatment herein set forth, where the high temperatures employed are Within the range of from about 2200 F. to about 2350 F. The accompanying graph also indicates that some improvement is obtained by solution treatment at lower temperatures.
It might also be stated that it is preferable to subject articles made from heat-resisting alloys to the high temperature heat treatment after rolling and/ forging operations have been completed. This is made more or less apparent by the effect of the heat treatment. It, however, may be stated that such fabrication operations as machining, grinding and drilling may be performed after the high temperature heat treatment and either before or after the aging treatment.
While I have outlined a procedure for improving the high temperature strength of heat-resisting alloys, it will be apparent that various changes in some of the individual steps of my improved procedure may be resorted to without departing from the spirit and scope of my invention as defined by the appended claims.
What I claim is:
1. A method of increasing the high temperature creep strength of an alloy containing chromium within the range of from about 12% to 22%, nickel within the range of from about 10% to 30% molybdenum, tungsten and columbium each within the range of from about 2% to 6%, carbon within the range of from about 0.20% to 0.60% with the remainder substantially all iron, which consists in subjecting the same to a short time heat treatment at a temperature within the range of from about 2150 F. to 2400 F., followed by a rapid cooling and then subjecting the same to a heat treatment within the range of from about 1350-F. to about 1550 F. for approximately sixteen hours.
2. A method of increasing the load carrying ability of an alloy consisting of chromium within the range of from about 12% to 22%, nickel within the range of from about 10% to 30%, molybdenum, tungsten and columbium each within the range of from about 2% to 6%. carbon within the range of from about 0.20% to about 0.60% with the remainder substantially all iron, which consists in subjecting the same to a temperature of at least 2150 F., followed by a quick cooling and then subjecting such alloy to an aging heat treatment within the range of from about 1350 F. to about 1550 F. and for approximately sixteen hours.
3. A method of increasing the resistance to deformation. at elevated temperatures, of at least a partially fabricated article made from an alloy consisting of chromium within the range of from about 12% to 22%, nickel within the range of Irom about 10% to 30% molybdenum, tungsten and columbium each within the range of from about 2% to 6%, carbon within the range of from about 0.20% to 0.60% with the remainder substantially all iron, which consists in subjecting such article to a short time heat treatment within the range of from about 2150" F. to 2400 F.. followed by a water quench and then subjecting the same to an aging treatment for approximately sixteen hours at a temperature within the range of from about 1350 F. to about 1550 F.
4. A method of improving the high temperature, rupture and creep strength of an article 6 within the range of from about 12% to 22%, nickel within the range of from 10% to 30%. molybdenum, tungsten and columbium each within the range of from about 2% to 6%, carbon within the range of from about 0.20% to 0.60% with the remainder substantially all iron, which consists in subjecting such article to a. heat treatment at a temperature in excess of 2150 F., followed by a water quench and then, after complete 10 fabrication of such article, subjecting it to a heat treatment for approximately sixteen hours at about the temperature to which it will be subjected during use.
GUNTHER MOI- LING made from an alloy consisting of chromium 15 Certificate of Correction Patent No. 2,401,580.
June 4, 1946.
GUN THER MOHLING It is hereby certified that errors appear in the printed specification of the above numbered patent requiring correction as follows: Column 3, line 70, before the word temperature insert high; column 4 line 2?, for and/ read and/0r; and that the said Letters Patent should be read with these corrections therein that the same may conform to the record of the case in the Patent Oflice.
Signed and sealed this 6thday of August A. D. 1946.
LESLIE FRAZER,
First Assistant Commissioner of Patents.
about 12% to 22%, nickel within the range of Irom about 10% to 30% molybdenum, tungsten and columbium each within the range of from about 2% to 6%, carbon within the range of from about 0.20% to 0.60% with the remainder substantially all iron, which consists in subjecting such article to a short time heat treatment within the range of from about 2150" F. to 2400 F.. followed by a water quench and then subjecting the same to an aging treatment for approximately sixteen hours at a temperature within the range of from about 1350 F. to about 1550 F.
4. A method of improving the high temperature, rupture and creep strength of an article 6 within the range of from about 12% to 22%, nickel within the range of from 10% to 30%. molybdenum, tungsten and columbium each within the range of from about 2% to 6%, carbon within the range of from about 0.20% to 0.60% with the remainder substantially all iron, which consists in subjecting such article to a. heat treatment at a temperature in excess of 2150 F., followed by a water quench and then, after complete 10 fabrication of such article, subjecting it to a heat treatment for approximately sixteen hours at about the temperature to which it will be subjected during use.
GUNTHER MOI- LING made from an alloy consisting of chromium 15 Certificate of Correction Patent No. 2,401,580.
June 4, 1946.
GUN THER MOHLING It is hereby certified that errors appear in the printed specification of the above numbered patent requiring correction as follows: Column 3, line 70, before the word temperature insert high; column 4 line 2?, for and/ read and/0r; and that the said Letters Patent should be read with these corrections therein that the same may conform to the record of the case in the Patent Oflice.
Signed and sealed this 6thday of August A. D. 1946.
LESLIE FRAZER,
First Assistant Commissioner of Patents.
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US515924A US2401580A (en) | 1943-12-28 | 1943-12-28 | Method of increasing the high temperature strength of heat-resisting alloys |
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US515924A US2401580A (en) | 1943-12-28 | 1943-12-28 | Method of increasing the high temperature strength of heat-resisting alloys |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2528497A (en) * | 1946-10-23 | 1950-11-07 | Armco Steel Corp | Alloy steel |
US2905577A (en) * | 1956-01-05 | 1959-09-22 | Birmingham Small Arms Co Ltd | Creep resistant chromium steel |
US2984563A (en) * | 1957-12-18 | 1961-05-16 | Tanczyn Harry | Stainless steel and method |
US3198630A (en) * | 1961-09-21 | 1965-08-03 | Republic Steel Corp | Super strength steel alloy composition and product and process of preparing it |
-
1943
- 1943-12-28 US US515924A patent/US2401580A/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2528497A (en) * | 1946-10-23 | 1950-11-07 | Armco Steel Corp | Alloy steel |
US2905577A (en) * | 1956-01-05 | 1959-09-22 | Birmingham Small Arms Co Ltd | Creep resistant chromium steel |
US2984563A (en) * | 1957-12-18 | 1961-05-16 | Tanczyn Harry | Stainless steel and method |
US3198630A (en) * | 1961-09-21 | 1965-08-03 | Republic Steel Corp | Super strength steel alloy composition and product and process of preparing it |
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