US237899A - pollard - Google Patents
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- US237899A US237899A US237899DA US237899A US 237899 A US237899 A US 237899A US 237899D A US237899D A US 237899DA US 237899 A US237899 A US 237899A
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- Prior art keywords
- steam
- chemicals
- pipe
- valve
- chamber
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- 239000000126 substance Substances 0.000 description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 235000011149 sulphuric acid Nutrition 0.000 description 10
- 239000001117 sulphuric acid Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000007664 blowing Methods 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 235000011089 carbon dioxide Nutrition 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 231100000078 corrosive Toxicity 0.000 description 2
- 231100001010 corrosive Toxicity 0.000 description 2
- 230000001066 destructive Effects 0.000 description 2
- 230000003467 diminishing Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 230000001264 neutralization Effects 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001105 regulatory Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 150000003385 sodium Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C13/00—Portable extinguishers which are permanently pressurised or pressurised immediately before use
- A62C13/02—Portable extinguishers which are permanently pressurised or pressurised immediately before use with pressure gas produced by chemicals
- A62C13/22—Portable extinguishers which are permanently pressurised or pressurised immediately before use with pressure gas produced by chemicals with incendiary substances producing pressure gas
Definitions
- the letter B indicates a pipe extending longitudinally along the lower part of the generator, provided with a valve, S, and connecting with a steam-boiler, preferably the main boiler of the engine, or the boiler ot' the donkey-engine of a ship, or in some instances with both.
- a steam-boiler preferably the main boiler of the engine, or the boiler ot' the donkey-engine of a ship, or in some instances with both.
- the letter C indicates a valve located in the pipe R between the branch pipes l) and F, which lead from pipe R to the respective compartments B and O.
- the branch pipes D and F respectively, are provided with valves G and I, by which communication with the pipe R and the respective compartments may be cut off or established at will, as more fully hereinafter explained.
- the pipe 11 is bent downwardly from the pipe R, and enters the compartment B at the bottom, and is provided with a valve, K.
- the branch pipes D and F after euteri n g the respective compartments, are bent laterally, as indicated in Fig. 2, for the purpose to be hereinafter explained.
- The'operation of my invention is as follows: Into the smaller compartment of the generator the sulphate of alumina is introduced so as to completely fill the same-say one thousand pounds of the same, or thereabout. Into the larger eompartmentan equivalentofsodium bicarbonate,-say seven kegs, or seven hundred and eighty-fourpoundsis placed. The man or hand holes, which have been previously opened for the introduction of the chemicals, are now closed and the machine is ready for use, with the chemicals separate from each other and hermetically sealed from contact with the atmosphere.
- valves G and S are opened, permitting hot water from the boiler to flow through pipe B and branches D to chamber B, the confined air being permitted to escape through the open pet-cocks successively, which are closed one after the other as the water reaches their respective levels.
- valve S is closed and the valve W opened, permitting steam from the boiler to exert its pressure directly upon the solution in chamber B.
- the valves G are then closed and the valves 0, K, and I opened, the steampressure in the chamber B rapidly forcing the chemical solution from said chamber through pipes H R and branches F to chamber and into intimate contact with the sodium bicarbonate therein.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Description
(No Model.)
I. M. POLLARD. Process of, and Apparatus for, Extinguishingf'ires.
No. 237,899. Patented Feb. 15,1881.
u liest: v liwen tonm v 'jiznnes J Pollard;
rhFeTens, FHOTO-UTHOGHAFHER, WASHINGTON 01c.
' UNITED STATES PATENT EFICE.
JAMES M. POLLARD, OF NEW ORLEANS, LOUISIANA, ASSIGNOR TO'GEORGE H. ROBINSON, IN TRUST FOR THE FIRE EXTINGUISHER MANUFACTUR- ING COMPANY, OF NEW YORK, N. Y.
PROCESS OF AND APPARATUS FOR EXTINGUISHING FIRES.
SPECIFICATION forming part of Letters Patent No. 237,899, dated February 15, 1881.
Application filed March 31, [880. (No model.)
To all whom it may concern Be it known that I, JAMES MADISON POL- LARD, a citizen of the United States, residing at New Orleans, in the parish of Orleans and State of Louisiana, have invented new and useful Improvements in Process of and Apparatus for Extinguishing Fires, of which the following is a specification.
My invcntionrelates to that class of processcs and apparatus in which carbonic-acid gas in large volume is evolved and employed to extinguish fires by its direct application thereto; and it is especially designed and intended for use on shipboard and in places where it'can be practically confined, such as in mines, tunnels, and tightly closed warehouses or buildings.
Owing to the very large quantity of chemicals which are necessarily employed to sup 2'0 ply the required volume of carbonic-acid gas, it has been long desirable to dispense with the use of free sulphuric acid in extinguishers of this class. It is troublesome to handle or transport the free acid in large quantities,and
2 5 the constant pressure of several hundred gallons on a vessel would prove almost as great an element of danger as the contingency of fire on shipboard. It'also ultimately corrodes and destroys the apparatus in which it is used,
0 so that its use under the requisite pressure is unsafe.
Of the plans or devices designed to obviate the above-mentioned difficulties and objections, that set forth in Patent No. 196,562, granted to 5 J. H. Connolly, October 30, 1877, is by far the most practicable and meritorious. It consists in the employment of the sulphuric acid in chemical combination with a base for which it has less affinity than for sodium,and in which 4.0 condition, being perfectly inert and neutral, it
is harmless and non-corrosive. 111 this condition, also,it possesses theveryimportant advantage that, while the reaction is in every way as complete and perfect ,as though free sulphuric acid were used, it is not so energetic and violently sudden in liberating carbonic acid as when'free sulphuric acid in largevolume is used on equivalent quantities of carbonates.
In carrying out my'inven tion I employ the sulphuric acid,'in combination with a base, as above, preferably the salt known as sulphate of alumina, deprived of mostof its water. In this form it is a white porous powder, extremeily soluble, requiring but its own volume, by
measure, of cold water and less than half its 5 5 weight of hot water to form a perfect solution.
The object of my invention is to provide an apparatus in which the carbonate of soda and sulphate of alumina, or equivalent salts, may
be kept indefinitely without being in contact with each other, and mingled at pleasure in such quantities and with such rapidity as may be desired, the pressure, however, always antomatically stopping the process whenever it reaches a fixed limit-say the safe workingpressure of the apparatus.
I am aware that it is not new to carry these or similar chemical agents inclosed separately in a fire-extingisher with devices for mingling them and generating the gas, when required, the distinction between my invention and machines of this class beingin the quantities of material that may be used.
All machines in which a liquid compound of the chemicals used is forced by the pressure generated by their reaction upon the tire are designed to use only sufficient chemicals to produce the pressure found most desirable and effective, and to this end all the chemicals are mixed at once and agitated together. This plan is inadmissible in a dry-gas machine, in which it is necessary, owing to the large volumeofcarbonic-acid gas compared with its containing-vessel, that the chemicals should be gradually min glcd and the pressure kept with- 8 5 in certain limits; hence I dispense entirely with all plans in which the chemicals are mingled by the action of gravity, such as where 'one reagent is elevated above the other and dropped into the latter, or where an elevated 0 acid-receptacle is used and supplied to the generating-vessel by means of a conducting-pipe and a suitable equalizing-pipe, as in either case the pressure can go on increasing to a dangerous or destructive degree.
My invention consists in a process of mingling the chemicals employed in the production of carbonic acid by blowing or forcing, by
steam or other aeriform fluid, one of the materials employed into contact or admixture with the other in confinement, the dilference in pressure between the gas and the power employed causing the chemicals to mingle gradually, equalization of pressure automatically stopping the further mingling of the chemicals until, by using or otherwise disposing of the generated carbonic acid, the equilibrium is disturbed and mingling resumed.
My invention further consists in certain improvements in apparatus by which the process is carried into effect, as more fully hereinafter specified.
Referring to the drawings, Figure 1 shows a side elevation of one of the cylinders or generators of myimproved fire-extinguisher; and Fig. 2, a transverse vertical section of two generators, with side elevation of the connecting drum or receptacle above them. Fig. 3 represents a top view of the man-hole or hand-hole, showing the method of inserting the cover through the same. Fig. 4: represents a top view of the man-hole with the cover secured against its seat; and Fig. 5, a view, partly in section and partly in elevation, of the manhole and cover.
In practice two generators are generally employed, connected together by a dome; but it is not, however, essential that the generators should be in pairs, as such arrangement is simply for convenience in maintaining a constant supply of gas by recharging one generator while the otheris used. As the generators are identical, a description of one will suffice for both.
The letter A indicates the generator, consisting of a strong vessel of steel, boiler-plate, or other suitable material, and is generally nine feet in length by three feet in diameter, or thereabout. It is divided into two compartments, B O, of unequal size, by means of the partition D, (indicated by the dotted line, Fig. 1.) Each compartment is provided with a suitable manhole or hand-hole, as at E, which may be closed by a suitable door, preferably arranged to open inwardly.
The letter B indicates a pipe extending longitudinally along the lower part of the generator, provided with a valve, S, and connecting with a steam-boiler, preferably the main boiler of the engine, or the boiler ot' the donkey-engine of a ship, or in some instances with both.
The letter T indicates a pipe connecting with the steam-dome of the boiler or boilers, and with the chambers B U of the generator by means of branch pipes U V, which are provided with valves V Z.
The pipes It and T are connected by means of a pipe, A, provided with a valve, B, by means of which communication can be estabtablished between the two or cut off from the same.
The letter C indicates a valve located in the pipe R between the branch pipes l) and F, which lead from pipe R to the respective compartments B and O. The branch pipes D and F, respectively, are provided with valves G and I, by which communication with the pipe R and the respective compartments may be cut off or established at will, as more fully hereinafter explained. The pipe 11 is bent downwardly from the pipe R, and enters the compartment B at the bottom, and is provided with a valve, K. The branch pipes D and F, after euteri n g the respective compartments, are bent laterally, as indicated in Fig. 2, for the purpose to be hereinafter explained.
The letter L indicates a transverse drum extending over the generators A, when two of the same are employed, and connected with the same by means of the pipes M, (shown in dotted lines, Fig. 1,) the said pipes being provided with valves N, by means of which either of said generators may be put into communication with the dome.
0 indicates a vertical receiver connected to the drum, and to a transverse pipe, 1 at its lower end, the said pipe being connected to the compartments B and G at their bottoms by means of branch pipes It, as shown. The reservoir and branch pipes are provided with valves M, by means of which communication with either of the compartments 0 or the receiver 0 may be established to draw oft the contents of the same, as more fully hereinafter specified. The lower end of the reservoir 0 is provided with a valve, T, by which its contents may be discharged, and the drum L with an escape-pipe, 1
The letter U indicates two pressure-gages, one applied to each compartment 0 and B. The letter a indicates a series of pet-cocks extending from the chamber B, through which the air may be expelled from the same, as more fully hereinafter explained.
The'operation of my invention is as follows: Into the smaller compartment of the generator the sulphate of alumina is introduced so as to completely fill the same-say one thousand pounds of the same, or thereabout. Into the larger eompartmentan equivalentofsodium bicarbonate,-say seven kegs, or seven hundred and eighty-fourpoundsis placed. The man or hand holes, which have been previously opened for the introduction of the chemicals, are now closed and the machine is ready for use, with the chemicals separate from each other and hermetically sealed from contact with the atmosphere. The valve 0 being closed, valves G and S are opened, permitting hot water from the boiler to flow through pipe B and branches D to chamber B, the confined air being permitted to escape through the open pet-cocks successively, which are closed one after the other as the water reaches their respective levels. When the said chamber B is completely filled the valve S is closed and the valve W opened, permitting steam from the boiler to exert its pressure directly upon the solution in chamber B. The valves G are then closed and the valves 0, K, and I opened, the steampressure in the chamber B rapidly forcing the chemical solution from said chamber through pipes H R and branches F to chamber and into intimate contact with the sodium bicarbonate therein. The gas liberated by the reaction of the two reagents creates a pressure in the chamber 0 and connections, which continually approximates to the steam-pressure in the chamber B, thus diminishing the force of the flow of the alumina solution until an equilibrium is established between the two chambers, when no more alumina solution will be forced into chamber G, except when required or caused to do so by using a portion of the gas contained in O, and thus destroying the equilibrium. The evolution of gas is thus automatically regulated by the rapidity with which it is used. When the alumina solution is all forced into the chamber 0 the steam will follow from the chamber B and thoroughly agitate and mingle the chemicals in said chamber C. This will be indicated by the sound of the steam in passing through valve K, which valve should be then closed and the valve S opened, allowing an additional volume of Water to flow into chamber 0, which should be filled up to the pet-cock s, when the valve S is to be closed and the valve B opened. This permits steam to flowthrough pipes A R and branches F to chamber 0 and thoroughly agitate the chemicals therein. This agitation should continue for a few moments, during'which time the valves 1 should be alternatel y closed and opened, so that the steam will enter chamber 0, first at one end and then at the other, thus thoroughly moving and mingling the chemicals, after which the valve 0 should be closed.
7 It will be borne in mind that the valves G, K, and I do not interrupt the passage-way through pipe R, but simply close and open the branches D, H, and F at theirjunctions with said pipe.
When the gas in O is all evolved,which will be indicated by the pressure-gage, the valve Z is opened and steam admitted, which will serve the double purpose of driving the gas from thechamber G and drum L out of the apparatus, and by opening the valve S will expel the residuum or sulphate of soda and hydrate of alumina remaining in the vessel. When the residuum is entirely expelled the valves W and Z are closed, when the remaining steam in the vessel will pass off through S, leaving the vessel empty and in condition to be recharged.
The pipes I), which enter the chambers some distance from their central portions, being bent at sharp or right angles to the bottom, prevent the chemicals from entering said pipes when the apparatus is not in use, and,
"blowing or forcing, by steam or other aeriform fluid, one of the materials employed into contact or admixture with the other in confinement, the difference in pressure between the gas and the power employed causing thechemicals to mingle gradually, and equalization of pressure automatically stopping the further mingling of the chemicals until,by using or otherwise disposing of the generated carbonic acid, the equilibrium is destroyed and the mingling resumed, essentially as set forth.
2. In a chemical fire-extinguisher, the combination of the two compartments for containing the reagents, and a pipe connecting the same with the lower part of the steam-boiler, and the connecting-pipes leading to the respective compartments, the said pipes being provided with suitable valves, whereby hot water may be admitted to one compartment and the contents, when dissolved, transferred to the second compartment, substantially as specified.
3. In combination with the compartments for containing the reagents, the hot-water pipes and steam-pipes proceeding from the steam and water portions of the boiler to the upper and lower parts of the respective compartments, and provided with suitable valves, whereby either hot water or steam may be ad'- mitted to either of the compartments, substantially as and for the purposes specified.
4. The combination, in a fire-extinguisher, of the two vessels constructed with separate compartments for the reagents, and provided with suitable connections extending from a steam-boiler, and suitable valves for supplying the compartments with water and steam, the connecting-pipes leading to the exits of the gas and waste solutions, and the controlling-valves, whereby the vessels may be alternately used and recharged, substantially as specified.
In testimony whereof I have hereunto set my hand in the presence of two subscribing witnesses.
J. M. POLLARD.
Witnesses:
JAMES L. NORRIS, JAMES A. RUTHERFORD.
Publications (1)
Publication Number | Publication Date |
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US237899A true US237899A (en) | 1881-02-15 |
Family
ID=2307255
Family Applications (1)
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US237899D Expired - Lifetime US237899A (en) | pollard |
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US (1) | US237899A (en) |
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- US US237899D patent/US237899A/en not_active Expired - Lifetime
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