US2378548A - Ferrous alloys containing bismuth - Google Patents

Ferrous alloys containing bismuth Download PDF

Info

Publication number
US2378548A
US2378548A US517842A US51784244A US2378548A US 2378548 A US2378548 A US 2378548A US 517842 A US517842 A US 517842A US 51784244 A US51784244 A US 51784244A US 2378548 A US2378548 A US 2378548A
Authority
US
United States
Prior art keywords
bismuth
steel
tool
alloys containing
containing bismuth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US517842A
Inventor
James L Gregg
Eric R Jette
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bethlehem Steel Corp
Original Assignee
Bethlehem Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bethlehem Steel Corp filed Critical Bethlehem Steel Corp
Priority to US517842A priority Critical patent/US2378548A/en
Application granted granted Critical
Publication of US2378548A publication Critical patent/US2378548A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur

Definitions

  • This invention relates to steels and particularly to steels which are to be subjected to machining operations.
  • the essence of the invention lies in the discovery that the addition of bismuth to steels of various compositions has a beneficial effect upon their machining characteristics, as will be more fully pointed out hereinafter.
  • a further object of this invention is to provide ferrous materials containing effective amounts of bismuth and exhibiting superior machinability characteristics to similar alloys not containing bismuth.
  • a tool force test and a cutting speed test have been arbitrarily selected in order to compare the machinability of steels embodying the present invention with those of the prior art.
  • the tool force test samples were machined at a constant speed and rate of feed, using a tool of standard shape mounted at one end of a pivoted arm, the other end of the arm being connected to a hydraulic gauge by which the force upon the tool was measured.
  • the samples under test were machined with a tool of standard shape and at a standard depth of cut and rate of feed until tool failure occurred. This test was carried out at various speeds and the results plotted graphically, from which graph the rate of speed for an arbitrarily chosen tool life could be determined.
  • the symbol v is used to indicate the machining speed, in surface feet per minute, which will result in tool failure after ten minutes of operation.
  • this invention is based on the discovery that the addition of bismuth to steel has a pronounced beneficial efiect on its machining characteristics.
  • the amount of bismuth necessary to produce such benefit is very small, as little as .045% being markedly efiective.
  • the bismuth may be added to the steel in the furnace, or in the ladle, or while pouring the steel into the mold.
  • the bismuth is added while the steel is being poured into the mold since this method of addition seems to result in a larger recovery of the bismuth and to reduce the amount of segregation.
  • metallic bismuth in finely divided form (20-30 mesh) gives the maxbe used.
  • 111% bismuth may be added as a pure metal or in e form of enemies. compounds of bismuth (sulfide, etc.) or alloyed with other metals, such as a bismuth-lead alloy or a bismum-manganese alloy.
  • Table I illustrates some of the advantages of the invention.
  • bismuth was added in varying amounts to steel containing about .12% carbon.
  • heats 3 and 4 the bismuth was added in the form of a bismuth-lead alloy and in heats 5 and 6 the bismuth was added in the form of a bismuth.- manganese alloy.
  • the results of tool force tests on the resulting alloys are shown in Table I, and indicate the decreased tool force characteristics of the steels containing bismuth in comparison with the bismuth-free steel.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Description

Patented June 19, 1945 UNITED STATES txamm PATENT OFFICE FEKROUS ALLOYS CONTAINING BISMUTH Pennsylvania No Drawing. Application January 11, 1944, Serial No. 517,842
- imum recovery. However, larger particles may 4 Claims.
This invention relates to steels and particularly to steels which are to be subjected to machining operations.
The essence of the invention lies in the discovery that the addition of bismuth to steels of various compositions has a beneficial effect upon their machining characteristics, as will be more fully pointed out hereinafter.
It is therefore an object of this invention to provide a steel which has improved machining characteristics in comparison with ordinary steels.
A further object of this invention is to provide ferrous materials containing effective amounts of bismuth and exhibiting superior machinability characteristics to similar alloys not containing bismuth.
Other objects of this invention will appear from the following detailed description thereof.
For the purposes hereof, a tool force test and a cutting speed test have been arbitrarily selected in order to compare the machinability of steels embodying the present invention with those of the prior art. In the tool force test, samples were machined at a constant speed and rate of feed, using a tool of standard shape mounted at one end of a pivoted arm, the other end of the arm being connected to a hydraulic gauge by which the force upon the tool was measured. In the tool life test, the samples under test were machined with a tool of standard shape and at a standard depth of cut and rate of feed until tool failure occurred. This test was carried out at various speeds and the results plotted graphically, from which graph the rate of speed for an arbitrarily chosen tool life could be determined. In the following tables the symbol v is used to indicate the machining speed, in surface feet per minute, which will result in tool failure after ten minutes of operation.
As heretofore stated, this invention is based on the discovery that the addition of bismuth to steel has a pronounced beneficial efiect on its machining characteristics. The amount of bismuth necessary to produce such benefit is very small, as little as .045% being markedly efiective.
The bismuth may be added to the steel in the furnace, or in the ladle, or while pouring the steel into the mold. Preferably the bismuth is added while the steel is being poured into the mold since this method of addition seems to result in a larger recovery of the bismuth and to reduce the amount of segregation. It has been found that the addition of metallic bismuth in finely divided form (20-30 mesh) gives the maxbe used. 111% bismuth may be added as a pure metal or in e form of enemies. compounds of bismuth (sulfide, etc.) or alloyed with other metals, such as a bismuth-lead alloy or a bismum-manganese alloy.
Table I illustrates some of the advantages of the invention. In the heats reported in Table I, bismuth was added in varying amounts to steel containing about .12% carbon. In heats 3 and 4 the bismuth was added in the form of a bismuth-lead alloy and in heats 5 and 6 the bismuth was added in the form of a bismuth.- manganese alloy. The results of tool force tests on the resulting alloys are shown in Table I, and indicate the decreased tool force characteristics of the steels containing bismuth in comparison with the bismuth-free steel.
Table I Heat No 0 Mn s Bl Pb ,'g},ffg
In addition to decreasing the tool force, the addition of bismuth increases the permissible machining speed for a given tool life. Table 11 illustrates the efiect of bismuth addition to a number of heats of steel, containing sulphur in amounts usual in so-called free cutting steels.
The results shown in Table II are:
Table II Vw (surface Heat No. 0 Mn Si 5 Bi feet per minute) 1 Estimated. 1 Estimated from amount of blsmuth added to heat.
By way of further example, it has been found that SAE X-lll2 steel containing .10% carbon,
.83% manganese, .089% phosphorus and 32% sulphur shows 9. vii) value of 266 surface feet per minute, while a steel of the same composition, but containing .18% bismuth, shows a V10 value of 323 surface feet per minute.
From the foregoing, it is apparent that the addition of small quantities of bismuth to ferrous materials has a marked beneficial effect on the machinability ofsuch materials.
Having thus described our invention, what we claim as new and desire to secure by Letters Patent is:
1. A steel containing carbon in effective amounts up to 1.7%, from .10% to .50% sulphur, and from .01% to 1.0% bismuth.
2. A steel containing carbon in effective amounts up to 1.7%, from .10% to .50% sulphur, from .01% to 2.0% manganese and from .01% to 1.0% bismuth.
3. A steel containing between .05% and 25% carbon, between .30% and .75% manganese, between .05% and .15% silicon, between .10% and .50% sulphur and between .01% and 20% bismuth.
4. A steel containing carbon in effective amounts up to 1.7%, between .01% and 2.0% manganese, between .06% and .50% sulphur and between .01% and .50% bismuth.
JAMES L. GREGG. ERIC R. M.
US517842A 1944-01-11 1944-01-11 Ferrous alloys containing bismuth Expired - Lifetime US2378548A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US517842A US2378548A (en) 1944-01-11 1944-01-11 Ferrous alloys containing bismuth

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US517842A US2378548A (en) 1944-01-11 1944-01-11 Ferrous alloys containing bismuth

Publications (1)

Publication Number Publication Date
US2378548A true US2378548A (en) 1945-06-19

Family

ID=24061450

Family Applications (1)

Application Number Title Priority Date Filing Date
US517842A Expired - Lifetime US2378548A (en) 1944-01-11 1944-01-11 Ferrous alloys containing bismuth

Country Status (1)

Country Link
US (1) US2378548A (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2492019A (en) * 1947-01-30 1949-12-20 American Steel & Wire Co Steel wool steel
US2493251A (en) * 1946-09-02 1950-01-03 Hellefors Bruks Aktiebolag Methods of introducing bismuth into steel or iron baths
US2515822A (en) * 1946-11-30 1950-07-18 Dayton Malleable Iron Co Gray iron castings
DE1073521B (en) * 1960-01-21 Gebr. Böhler &. Co. Aktiengesellschaft, Wien, handelnd durch die Zweigniederlassung, Stuttgart-Untertürkheim Metalworking tools
US3010823A (en) * 1959-08-07 1961-11-28 American Brake Shoe Co Easily machinable, non-magnetic, manganese steel
US3239388A (en) * 1962-07-11 1966-03-08 Kawasaki Steel Co Cold rolled rimmed steel sheet and strip having preferred orientation adapted for press forming and production of the same
US4014688A (en) * 1972-05-10 1977-03-29 Siemens Aktiengesellschaft Contact material for high-power vacuum circuit breakers
US4247326A (en) * 1979-08-29 1981-01-27 Inland Steel Company Free machining steel with bismuth
US4255188A (en) * 1979-08-29 1981-03-10 Inland Steel Company Free machining steel with bismuth and manganese sulfide
US4255187A (en) * 1979-08-29 1981-03-10 Inland Steel Company Bismuth-containing steel
EP0027509A1 (en) * 1979-08-29 1981-04-29 Inland Steel Company Method and alloy for introducing machinability increasing ingredients to steel
EP0045815A1 (en) * 1980-08-11 1982-02-17 Inland Steel Company Semi-finished steel article and method for producing same
US4333776A (en) * 1979-01-24 1982-06-08 Inland Steel Company Semi-finished steel article
EP0919636A1 (en) * 1997-12-01 1999-06-02 Lucchini Centro Ricerche E Sviluppo S.r.l. Free-cutting steel with improved machinability

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1073521B (en) * 1960-01-21 Gebr. Böhler &. Co. Aktiengesellschaft, Wien, handelnd durch die Zweigniederlassung, Stuttgart-Untertürkheim Metalworking tools
US2493251A (en) * 1946-09-02 1950-01-03 Hellefors Bruks Aktiebolag Methods of introducing bismuth into steel or iron baths
US2515822A (en) * 1946-11-30 1950-07-18 Dayton Malleable Iron Co Gray iron castings
US2492019A (en) * 1947-01-30 1949-12-20 American Steel & Wire Co Steel wool steel
US3010823A (en) * 1959-08-07 1961-11-28 American Brake Shoe Co Easily machinable, non-magnetic, manganese steel
US3239388A (en) * 1962-07-11 1966-03-08 Kawasaki Steel Co Cold rolled rimmed steel sheet and strip having preferred orientation adapted for press forming and production of the same
US3239389A (en) * 1962-07-11 1966-03-08 Kawasaki Steel Co Deep drawing cold rolled rimmed steel sheet and strip and production of the same
US4014688A (en) * 1972-05-10 1977-03-29 Siemens Aktiengesellschaft Contact material for high-power vacuum circuit breakers
US4333776A (en) * 1979-01-24 1982-06-08 Inland Steel Company Semi-finished steel article
US4247326A (en) * 1979-08-29 1981-01-27 Inland Steel Company Free machining steel with bismuth
US4255187A (en) * 1979-08-29 1981-03-10 Inland Steel Company Bismuth-containing steel
EP0027165A1 (en) * 1979-08-29 1981-04-22 Inland Steel Company Free machining steel with bismuth
EP0027510A1 (en) * 1979-08-29 1981-04-29 Inland Steel Company Bismuth containing steel
EP0027509A1 (en) * 1979-08-29 1981-04-29 Inland Steel Company Method and alloy for introducing machinability increasing ingredients to steel
US4255188A (en) * 1979-08-29 1981-03-10 Inland Steel Company Free machining steel with bismuth and manganese sulfide
EP0045815A1 (en) * 1980-08-11 1982-02-17 Inland Steel Company Semi-finished steel article and method for producing same
EP0919636A1 (en) * 1997-12-01 1999-06-02 Lucchini Centro Ricerche E Sviluppo S.r.l. Free-cutting steel with improved machinability

Similar Documents

Publication Publication Date Title
US2378548A (en) Ferrous alloys containing bismuth
US3850621A (en) High-speed tool steels
US3846186A (en) Stainless steel having improved machinability
US3933480A (en) Method of making stainless steel having improved machinability
US2311878A (en) Method of attaching high chromium ferrous alloys to other metals
US2938787A (en) Nickel-base alloy containing boron
US3192039A (en) Free machining alloy
US2102388A (en) Copper-sulphur alloy
US2400566A (en) Alloy
US2270716A (en) Copper alloy
US2297687A (en) Alloy and cutting tool
US3158470A (en) Copper base alloys and the method of treating the same to improve their machinability
US2224448A (en) Wear resisting alloy
US2858243A (en) Process for production of improved free machining steels
JPS59116348A (en) Wear-resistant cu alloy having high strength and high toughness
US2598714A (en) Machinable high cobalt low carbon alloys for die-casting molds
US2026540A (en) Free cutting alloys
US2281460A (en) Method of manufacturing chilled cast iron and product thereof
US2026567A (en) Free cutting alloys
US2026544A (en) Free cutting alloys
US2231940A (en) Alloy
US2026571A (en) Free cutting alloys
US3094440A (en) Steels having zinc additives for improved machinability
US2327561A (en) Silver-containing free-machining die steel
US2159086A (en) Manufacture of high speed steels