US2343016A - Flexible wood product - Google Patents
Flexible wood product Download PDFInfo
- Publication number
- US2343016A US2343016A US425867A US42586742A US2343016A US 2343016 A US2343016 A US 2343016A US 425867 A US425867 A US 425867A US 42586742 A US42586742 A US 42586742A US 2343016 A US2343016 A US 2343016A
- Authority
- US
- United States
- Prior art keywords
- wood
- product
- flexible
- urea
- wood product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/15—Impregnating involving polymerisation including use of polymer-containing impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
Definitions
- My invention relates to processes for rendering dry wood flexible at all temperatures.
- Another object of my invention relates to a secondary treatment, whereby the wood complex is converted from a product of no elasticity to one having a high degree of elasticity.
- thermoplastic product that becomes plastic on heating is obviously undesirable for certain purposes.
- efiorts were made to develop a process for resinltying the plastic wood, thus converting the thermoplastic product into a thermosetting product.
- This change is brought about by treating the compressed urea treated wood with an aldehyde, preferably formaldehyde, either as an aqueous solution or as ages.
- aldehyde preferably formaldehyde
- the present invention difiers'fromthe above in that the treated wood of any thickness or length, whether laminated or not, unlike the product disclosed in Patent No. 2,298,017 is exceedingly flexible, even when cold.
- a specific method that may be employed in producing the product covered by this invention is as follows:
- I may soak green sweetgum veneer for two days in an aqueous urea solution that is saturated at room temperature. It may then be dried to a weight which is in equilibrium with C. and. 40 percent relative humidity-which would ultimately dry normal Wood to a moisture content of 6 percent.
- the treated sheets either separately or laminated, are placed in a female form or chase and subjected to a slight pressure while their temperature is raised to about 175 C. when a maximum pressure of substantially 500 pounds per square inch is applied at right angles to the grain. Before the pressure is finally re-. leased, the product is cooled to a temperature of about 60 C. These conditions of maximum pressure and temperature are maintained for a period which varies with the thickness and species of material being pressed. I have found that with thicknesses of about one-half inch, about 15 minutes at maximum temperature and pressure is sufficient to produce a panel which is surprisingly plastic at all temperatures, even when maintained at'a moisture content that is in equilibrium with normal room atmosphere.
- the product treated as above can be curved, or otherwise deformed, and while being held to the desired shape, placed in a bath of commercial formaldehyde solution, or a saturated solution of dimethanal urea, or treated-in formaldehyde in the gaseous state, or treated in any aldehyde which, in combination with urea, forms a thermosetting resin.
- I may produce (1) a wood product that is flexible at all temperatures, the flexibility having been brought about by a urea treatment and by restraining transverse and longitudinal flow when subjected to a suitable press schedule of temperature and pressure; (2) a process of making wood flexible at all temperatures by first soaking it in a urea solution, drying it, and finally placing it in a suitable female form or chase and compressing it to about half of its original thickness at elevated temperatures, and finally cooling under pressure; (3) a wood product or great strength and stillness produced by subjecting the flexible wood, as described in (l), to an aldehyde; and (4) a process tor'making the flexible woodprodnot, described in (1), into a product of great strength and stillness;
- a process of making wood flexible at all temperatur'es comprising the steps or first saturat- 10 in: the wood in an aqueous urea solution at room 1 temperature; thence drying to awelsht which is in equilibrium with substantially 60 C. and 40 percent relatirc humidity; thence subjecting the treated wood in the form of veneer or boards toatemperat'ure of substantially 175 C. and a pressure of substantially 500 pounds per square inch, thence cooling the product to a tempera-
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
. Patented F ebo 29, ran
. errant HEXEIE W001i) PRODUCT William Karl llioughborough, Madison, Wis.; dedicated to the free use of the People in the territory or the United States No Drawing. Application January 7, 1942, Serial No. 425,867
1 Claim. (@i, IVA-09) (Granted under the act oi ldarch 3, 1883, as
. amended iipril 30, l
. This application is made under the act of March 3,1883, as amended by the act'of April 39, 3.928, and the invention herein described and claimed, if patented, may be manufactured and used by or for the Government of. the United States of America for governmental purposes without the payment to me of any royalty thereon.
I hereby dedicate the invention herein, de-
scribed to the free use 01 the People in, the territory or the United States to take effect on the granting of a patent-to me. I
My invention relates to processes for rendering dry wood flexible at all temperatures.
Another object of my invention relates to a secondary treatment, whereby the wood complex is converted from a product of no elasticity to one having a high degree of elasticity.
In my prior Patent No. 2,298,017, datedOctoher 6, 1942, there is taught'that when green southern swamp white oak is impregnated with a suitable amount of urea and then dried to a low moisture content, it becomes so soft and flexible that it may be very easily-bent, twisted or otherwise deformed when heated to atemperature of about 215 F. It is further disclosed that any form given the wood when hot is retained by the product when cooled to room temperatures. In other words, the urea comrbines with some or all of the elements of the natural wood to form a thermoplastic resin. A a
product that becomes plastic on heating is obviously undesirable for certain purposes. Hence, efiorts were made to develop a process for resinltying the plastic wood, thus converting the thermoplastic product into a thermosetting product. This change is brought about by treating the compressed urea treated wood with an aldehyde, preferably formaldehyde, either as an aqueous solution or as ages. This invention is disclosed in my prior Patent No; 2,313,953, dated March 16, 1943.
The present invention difiers'fromthe above in that the treated wood of any thickness or length, whether laminated or not, unlike the product disclosed in Patent No. 2,298,017 is exceedingly flexible, even when cold.
1 am also familiar with another process which renders wood permanently plastic by the application of a compression parallel to the grain load in excess of the elastic limit. My present invention differs from this process, in that the load is applied to the urea treated wood at right angles to the grain. Moreover, according to the present invention. the wood is not rendered per-- manently plastic., It can be given greater strength and stiffness by the secondary aldehyde treatment.
A specific method that may be employed in producing the product covered by this invention is as follows:
I may soak green sweetgum veneer for two days in an aqueous urea solution that is saturated at room temperature. It may then be dried to a weight which is in equilibrium with C. and. 40 percent relative humidity-which would ultimately dry normal Wood to a moisture content of 6 percent. The treated sheets, either separately or laminated, are placed in a female form or chase and subjected to a slight pressure while their temperature is raised to about 175 C. when a maximum pressure of substantially 500 pounds per square inch is applied at right angles to the grain. Before the pressure is finally re-. leased, the product is cooled to a temperature of about 60 C. These conditions of maximum pressure and temperature are maintained for a period which varies with the thickness and species of material being pressed. I have found that with thicknesses of about one-half inch, about 15 minutes at maximum temperature and pressure is sufficient to produce a panel which is surprisingly plastic at all temperatures, even when maintained at'a moisture content that is in equilibrium with normal room atmosphere.
The product treated as above can be curved, or otherwise deformed, and while being held to the desired shape, placed in a bath of commercial formaldehyde solution, or a saturated solution of dimethanal urea, or treated-in formaldehyde in the gaseous state, or treated in any aldehyde which, in combination with urea, forms a thermosetting resin.
In order to produce my product, via, a resinified sheet wood material, it is first necessary to remove any excess moisture, then heat the urea aldehyde product to a temperature of about Accordingly, it will be seen that I may produce (1) a wood product that is flexible at all temperatures, the flexibility having been brought about by a urea treatment and by restraining transverse and longitudinal flow when subjected to a suitable press schedule of temperature and pressure; (2) a process of making wood flexible at all temperatures by first soaking it in a urea solution, drying it, and finally placing it in a suitable female form or chase and compressing it to about half of its original thickness at elevated temperatures, and finally cooling under pressure; (3) a wood product or great strength and stillness produced by subjecting the flexible wood, as described in (l), to an aldehyde; and (4) a process tor'making the flexible woodprodnot, described in (1), into a product of great strength and stillness;
Having thus described mi invention, what I claim for Letters Patent is:
A process of making wood flexible at all temperatur'es, comprising the steps or first saturat- 10 in: the wood in an aqueous urea solution at room 1 temperature; thence drying to awelsht which is in equilibrium with substantially 60 C. and 40 percent relatirc humidity; thence subjecting the treated wood in the form of veneer or boards toatemperat'ure of substantially 175 C. and a pressure of substantially 500 pounds per square inch, thence cooling the product to a tempera-
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US425867A US2343016A (en) | 1942-01-07 | 1942-01-07 | Flexible wood product |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US425867A US2343016A (en) | 1942-01-07 | 1942-01-07 | Flexible wood product |
Publications (1)
Publication Number | Publication Date |
---|---|
US2343016A true US2343016A (en) | 1944-02-29 |
Family
ID=23688362
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US425867A Expired - Lifetime US2343016A (en) | 1942-01-07 | 1942-01-07 | Flexible wood product |
Country Status (1)
Country | Link |
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US (1) | US2343016A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2595335A (en) * | 1949-02-26 | 1952-05-06 | American Viscose Corp | Molding powders from urea and gaseous formaldehyde |
US2974697A (en) * | 1958-01-10 | 1961-03-14 | Elmendorf Res Inc | Method and apparatus for making a veneer product |
US4108226A (en) * | 1977-01-03 | 1978-08-22 | Georgia-Pacific Corporation | Veneer production |
US4606388A (en) * | 1985-03-28 | 1986-08-19 | Peter Favot | Process for densifying low density woods |
US20090004495A1 (en) * | 2007-06-29 | 2009-01-01 | Marc Henry Schneider | High weight percent gain (WPG) furfural-urea modification of wood |
-
1942
- 1942-01-07 US US425867A patent/US2343016A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2595335A (en) * | 1949-02-26 | 1952-05-06 | American Viscose Corp | Molding powders from urea and gaseous formaldehyde |
US2974697A (en) * | 1958-01-10 | 1961-03-14 | Elmendorf Res Inc | Method and apparatus for making a veneer product |
US4108226A (en) * | 1977-01-03 | 1978-08-22 | Georgia-Pacific Corporation | Veneer production |
US4606388A (en) * | 1985-03-28 | 1986-08-19 | Peter Favot | Process for densifying low density woods |
US20090004495A1 (en) * | 2007-06-29 | 2009-01-01 | Marc Henry Schneider | High weight percent gain (WPG) furfural-urea modification of wood |
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