US2295958A - Composition suitable for impregnating fibrous materials - Google Patents
Composition suitable for impregnating fibrous materials Download PDFInfo
- Publication number
- US2295958A US2295958A US252150A US25215039A US2295958A US 2295958 A US2295958 A US 2295958A US 252150 A US252150 A US 252150A US 25215039 A US25215039 A US 25215039A US 2295958 A US2295958 A US 2295958A
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- US
- United States
- Prior art keywords
- vinsol
- cellulose acetate
- solution
- coil
- fibrous materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/185—Substances or derivates of cellulose
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/32—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes natural resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/48—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances fibrous materials
- H01B3/485—Other fibrous materials fabric
Definitions
- This invention relates to compositions suitable for impregnatiug fibrous materials, and is a division of my copending application Serial No. ⁇
- Objects of the invention are to providematerials having good non-hygroscopic and insulating properties for use in electrical apparatus and to provide improved compositions for impregnating fibrous materials.
- a fibrous material suitable for filling or encasing electrical coils is impregnated with a solution of Vinsol and cellulose derivatives to insulate the coil and prevent corrosion of the electrical conductors.
- FIG. 1 is a perspective view, partly in section
- Fig. 2 is a modified form of coil embodying the invention.
- Fig. 3 is a. fragmentary detail viewA of the covering for the coil shown in Fig. 2 ⁇
- the coil may be provided with a rectangular core 5 of fibrous material or the core may be made of a phenol condensation product, of cellulose acetate, or of a phenol condensation product faced with cellulose acetate.
- the convolutions of wire are wound in layers on the core and each layer is separated by a nbrous sheet of paper,v
- the wire may be bare, if suitably spaced, but preferably comprises ⁇ enameled wireor wire having a fibrous insulation.
- Vinsol is a hard dark-colored resinous material comprising a gasoline-insoluble pine wood resin, produced by extracting resinous wood with a coal tar hydrocarbon, removing said hydrocarbon by evaporation, extracting the residue with a petroleum hydrocarbon, and recovering the gasoline-insoluble resin.
- a solution of the Vinsol may be made by dissolving a quantity of this material in the proportion of 100 parts of the material to 75 parts by weight of acetone.
- the amount of solvent used is not critical, but excess solvent. should be, avoided as uneconomical.
- Such a solution has been found to have a high penetrating power and will thoroughly impregnate the fibrous ma.- terial .in the coil. Tests made on .coils made in this manner have beenl found to have a very low -hygroscopicity and high corrosion resistance and due to the high insulation resistance and low dielectric constant of the impregnated brous material, the material is excellently suited for insulating coils.
- a coilA made as described above may be dipped in a solution of cellulose acetate and Vinsol to provide a more elastic covering for the outside of thel coil or it may be dipped in such a solution without previously dipping ,it in a solution of the Vinsol.
- a solution of cellulose acetate in acetone by itself ⁇ has poor impregnating properties since it in effect coats only the surface of the accessible fibers of the fibrous material.
- the cellulose acetate is mixed with a solution of Vinsol in acetone, the cellulose acetate is dissolved, and the Vinsol serves as a carrier to carry the cellulose acetate into the fiber.
- the addition of the cellulose acetate tothe Vinsol raises the melting point of the composition over that of the Vinsol alone and the composition containing the two ingredients is, therefore, more suitable for coils which are operated at high temperatures.
- 100 parts of the Vinsol may be first disl solved in about '75 parts of acetone ⁇ and 100 partsl of cellulose acetate may be dissolved in 400 parts of acetone and the materials then mixed together, or Vinsol may be added directly to a solution of cellulose acetate in lacetone.
- the cellulose acetate may constitute an amount equal to thev amount of Vinsol, although these materials are soluble in all proportions. It appears that when less than 3% of Vinsol is used, the property of causing the cellulose acetate to penetrate fiber becomes negligible and when more than of Vinsol is used, the product becomes brittle and tends to flake.
- Vinsol alone is quite brittle and tends to become powdery when dry.
- a solution of this material with a cellulose ester makes a more plastic or less brittle material for many uses.
- This composition is thermoplastic and can be formed into sheets orr articles in a mold under heat and pressure.
- the material can be prepared for molding bydissolving the ingredients in acetone, as previously described. evaporating the solvent, and pulverizing the residue into particles of suitable size.
- a relatively viscous solution can be used to reduce the quantity of acetone required for the impregnating solution. It is also feasible to reduce this solution to sheets or molding slugs by evaporating the solvent from solution contained in forms of the proper contour.
- the cellulose ester and Vinsol may be mixed in powdered form, placed in a mold, and subjected to heat and pressure to consolidate the material and form a solid solution.
- the Vinsol is characterized by its insolubility in petroleum hydrocarbons and turpentines; and,
- coils made as described above may be used where they come in contact with lubricat ing oils or transformer cooling oils without impairing the effectiveness of the insulation.
- Fig. 2 illustrates a coil having a core I comprised of cellulose acetate or a phenol liber condensation product faced with cellulose acetate.
- the coil is wound on the core in layers and the layers are separated from each other by sheets of fibrous material. After the coil has been wound, it is impregnated with a solution of Vinsol or the coil may -be impregnated with a solution of Vinsol and cellulose acetate. After the coil is impregnated, heads l of cellulose acetate or phenol fiber faced with cellulose acetate are adhered to the core by applying a solution of cellulose acetate in acetone to the ends of the core and pressing the head against the core until the solvent dries.
- an outer sheet 8 may be applied to the coil.
- This sheet is made by impregnating a brous sheet l vith a Vinsol or a solution o! Vinsol and cellulose acetatc and then applying a sheet ll of cellulose acetate to each face of the impregnated sheet l.
- the cellulose acetate sheets may be adhered to the impregnated sheet 9 by subjecting the coniposite sheet to heat and pressure to plasticize the cellulose acetate and mold it integral with the impregnated fibrous sheet. This procedure insures thorough impregnation of the nbrous material so that when the sheet is cut, it will not expose the raw or unimpregnated ber.
- a piece of this composite sheet is cut so that its edges will overlap when wound about the coil and the ends will abut the heads 1.
- a solution of cellulose acetate in acetone may then be applied between the overlapping edges and along the ends where they abut the heads to completely and hermetically seal the coil.
- a composition for impregnating brous electrical insulating materials comprising substantially equal parts of a cellulose acetate and Vinsol, and a solvent comprising acetone.
- a composition for impregnating fibrous insulators employed in electrical apparatus comprising from a substantial amount up to the order of ,of a cellulose acetate, and the balance substantially Vinsol.
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- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Insulating Of Coils (AREA)
Description
sept. 15, 1942. R. P. I u-rz `2,295,958
COMPOSITION- SUITABLE Foa IMPREGNATINO FIBRous MATERIALS orIginaI File'd Oct. 31, 19:56
y F/G. 2
ATTORNEY Patented Sept. 15V, 1942 COMPOSITION SUITABLE FOR IMPREGNAT- FIBROUS MATERIALS Raymond P. Lutz, Oak Park, Ill., assignor to Western' Electric Company, Incorporated, New York, N. Y., a corporation of New York Original application October 31', 1936, Serial No.
Divided and this application January- 21, 1939, Serial No. 252,150
(Cl. G-173) 2 Claims.
This invention relates to compositions suitable for impregnatiug fibrous materials, and is a division of my copending application Serial No.`
108,610, filed October 31, 1936, now issued as Patent 2,172,445.
Objects of the invention are to providematerials having good non-hygroscopic and insulating properties for use in electrical apparatus and to provide improved compositions for impregnating fibrous materials.
In accordance with oneembodiment of the invention, a fibrous material suitable for filling or encasing electrical coils is impregnated with a solution of Vinsol and cellulose derivatives to insulate the coil and prevent corrosion of the electrical conductors.
Other objects and advantages will appear as the description proceeds.
A complete understanding of the invention may be had by reference to the following description taken in conjunction with the accompanying drawing, in which Fig. 1 is a perspective view, partly in section,
I of a coil embodying the invention;
Fig. 2 is a modified form of coil embodying the invention; and
Fig. 3 is a. fragmentary detail viewA of the covering for the coil shown in Fig. 2`
Referringnow more particularly to Fig. 1, the coil may be provided with a rectangular core 5 of fibrous material or the core may be made of a phenol condensation product, of cellulose acetate, or of a phenol condensation product faced with cellulose acetate. The convolutions of wire are wound in layers on the core and each layer is separated by a nbrous sheet of paper,v
cloth, or the like and a similar sheet is wrapped around the outer layer of wire. The wiremay be bare, if suitably spaced, but preferably comprises` enameled wireor wire having a fibrous insulation.
After the coil is woun'd, it may be immersed in a solution of a resin of the type sold von the market under the trade-name-of Vinsol by the Hercules Powder Company. Vinsol is a hard dark-colored resinous material comprising a gasoline-insoluble pine wood resin, produced by extracting resinous wood with a coal tar hydrocarbon, removing said hydrocarbon by evaporation, extracting the residue with a petroleum hydrocarbon, and recovering the gasoline-insoluble resin. v
A solution of the Vinsol may be made by dissolving a quantity of this material in the proportion of 100 parts of the material to 75 parts by weight of acetone. The amount of solvent used is not critical, but excess solvent. should be, avoided as uneconomical. Such a solution has been found to have a high penetrating power and will thoroughly impregnate the fibrous ma.- terial .in the coil. Tests made on .coils made in this manner have beenl found to have a very low -hygroscopicity and high corrosion resistance and due to the high insulation resistance and low dielectric constant of the impregnated brous material, the material is excellently suited for insulating coils. For some purposes a coilA made as described above may be dipped in a solution of cellulose acetate and Vinsol to provide a more elastic covering for the outside of thel coil or it may be dipped in such a solution without previously dipping ,it in a solution of the Vinsol. It has been found that a solution of cellulose acetate in acetone by itself `has poor impregnating properties since it in effect coats only the surface of the accessible fibers of the fibrous material. However, when the cellulose acetate is mixed with a solution of Vinsol in acetone, the cellulose acetate is dissolved, and the Vinsol serves as a carrier to carry the cellulose acetate into the fiber. The addition of the cellulose acetate tothe Vinsol raises the melting point of the composition over that of the Vinsol alone and the composition containing the two ingredients is, therefore, more suitable for coils which are operated at high temperatures. f
In preparing a solution of cellulose acetate and Vinsol, 100 parts of the Vinsol may be first disl solved in about '75 parts of acetone` and 100 partsl of cellulose acetate may be dissolved in 400 parts of acetone and the materials then mixed together, or Vinsol may be added directly to a solution of cellulose acetate in lacetone.
Preferably the cellulose acetate may constitute an amount equal to thev amount of Vinsol, although these materials are soluble in all proportions. It appears that when less than 3% of Vinsol is used, the property of causing the cellulose acetate to penetrate fiber becomes negligible and when more than of Vinsol is used, the product becomes brittle and tends to flake.
Vinsol alone is quite brittle and tends to become powdery when dry. However, a solution of this material with a cellulose ester makes a more plastic or less brittle material for many uses. This composition is thermoplastic and can be formed into sheets orr articles in a mold under heat and pressure. The material can be prepared for molding bydissolving the ingredients in acetone, as previously described. evaporating the solvent, and pulverizing the residue into particles of suitable size. In preparing thismaterial, a relatively viscous solution can be used to reduce the quantity of acetone required for the impregnating solution. It is also feasible to reduce this solution to sheets or molding slugs by evaporating the solvent from solution contained in forms of the proper contour. For other applications the cellulose ester and Vinsol may be mixed in powdered form, placed in a mold, and subjected to heat and pressure to consolidate the material and form a solid solution.
The Vinsol is characterized by its insolubility in petroleum hydrocarbons and turpentines; and,
therefore, coils made as described above may be used where they come in contact with lubricat ing oils or transformer cooling oils without impairing the effectiveness of the insulation.
Fig. 2 illustrates a coil having a core I comprised of cellulose acetate or a phenol liber condensation product faced with cellulose acetate. The coil is wound on the core in layers and the layers are separated from each other by sheets of fibrous material. After the coil has been wound, it is impregnated with a solution of Vinsol or the coil may -be impregnated with a solution of Vinsol and cellulose acetate. After the coil is impregnated, heads l of cellulose acetate or phenol fiber faced with cellulose acetate are adhered to the core by applying a solution of cellulose acetate in acetone to the ends of the core and pressing the head against the core until the solvent dries. If it is desired to have a hermetically sealed coil, an outer sheet 8 may be applied to the coil. This sheet is made by impregnating a brous sheet l vith a Vinsol or a solution o! Vinsol and cellulose acetatc and then applying a sheet ll of cellulose acetate to each face of the impregnated sheet l. The cellulose acetate sheets may be adhered to the impregnated sheet 9 by subjecting the coniposite sheet to heat and pressure to plasticize the cellulose acetate and mold it integral with the impregnated fibrous sheet. This procedure insures thorough impregnation of the nbrous material so that when the sheet is cut, it will not expose the raw or unimpregnated ber. In covering a coil, as shown in Fig. 2, a piece of this composite sheet is cut so that its edges will overlap when wound about the coil and the ends will abut the heads 1. A solution of cellulose acetate in acetone may then be applied between the overlapping edges and along the ends where they abut the heads to completely and hermetically seal the coil.
While the invention has been described in connection with particular embodiments thereof, it will be understood that many changes and modincations may be made without departing from the spirit and scope of the invention.
What is claimed is:
l. A composition for impregnating brous electrical insulating materials comprising substantially equal parts of a cellulose acetate and Vinsol, and a solvent comprising acetone.
2. A composition for impregnating fibrous insulators employed in electrical apparatus comprising from a substantial amount up to the order of ,of a cellulose acetate, and the balance substantially Vinsol.
R YMOND P. LU'IZ.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US252150A US2295958A (en) | 1936-10-31 | 1939-01-21 | Composition suitable for impregnating fibrous materials |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10861036 US2172445A (en) | 1936-10-31 | 1936-10-31 | Impregnated fibrous material and composition suitable for impregnating such material |
US252150A US2295958A (en) | 1936-10-31 | 1939-01-21 | Composition suitable for impregnating fibrous materials |
Publications (1)
Publication Number | Publication Date |
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US2295958A true US2295958A (en) | 1942-09-15 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US252150A Expired - Lifetime US2295958A (en) | 1936-10-31 | 1939-01-21 | Composition suitable for impregnating fibrous materials |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2526330A (en) * | 1946-03-01 | 1950-10-17 | Gen Electric | Cellulose acetate coated dielectric paper for electrical devices |
US3305697A (en) * | 1963-11-12 | 1967-02-21 | Gen Electric | Ballast apparatus with air-core inductor |
US3396356A (en) * | 1965-11-01 | 1968-08-06 | Gen Electric | Cross-wound open mesh coil |
US3621430A (en) * | 1970-04-02 | 1971-11-16 | Sanyo Electric Co | Flyback transformer coil for television receiver |
-
1939
- 1939-01-21 US US252150A patent/US2295958A/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2526330A (en) * | 1946-03-01 | 1950-10-17 | Gen Electric | Cellulose acetate coated dielectric paper for electrical devices |
US3305697A (en) * | 1963-11-12 | 1967-02-21 | Gen Electric | Ballast apparatus with air-core inductor |
US3396356A (en) * | 1965-11-01 | 1968-08-06 | Gen Electric | Cross-wound open mesh coil |
US3621430A (en) * | 1970-04-02 | 1971-11-16 | Sanyo Electric Co | Flyback transformer coil for television receiver |
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