US2264353A - Lubricant - Google Patents
Lubricant Download PDFInfo
- Publication number
- US2264353A US2264353A US255452A US25545239A US2264353A US 2264353 A US2264353 A US 2264353A US 255452 A US255452 A US 255452A US 25545239 A US25545239 A US 25545239A US 2264353 A US2264353 A US 2264353A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- grease
- oil
- lubricant
- naphthenate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M5/00—Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/06—Groups 3 or 13
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/06—Instruments or other precision apparatus, e.g. damping fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Definitions
- the present invention relates to an improved lubricant and more specifically to a. semi-fluid grease principally for automative chassis lubrication and for similar purposes.
- the invention will be fully understood from the following description.
- nongelling aluminum soaps such as aluminum naphthenate or aluminum oleate containing approximately 20% of free stearic acid.
- the commercial aluminum stearates vary in the percentage of free acid'from approximately 5 to 15 to even greater amounts.
- the soaps having the greater percentage of aluminum tend to form firmer gels and it has been found that by increasing the percentage of free stcaric acid to 20% (total) or using the aluminum stearates containing this amount of free acid, a softer and more adaptable grease is formed. It has also been found that this additional free fatty acid during storage also prevents the grease from setting back to its original firmness after working.
- the amount of aluminum naphthenate or oleate varies from about 0.25 to 1.5%; that is to say, the amount is ordinarily about t; to /5 of the amount of the aluminum stearate.
- the aluminum soaps and enough free stearic acid to bring the fatty acid content of the aluminum soap to 20% free fatty acid are added and thoroughly admixed with a small portion of the oil, say .about 10 to 20% of the total quantity to be used, and the ingredients are Worked together in a thick paste.
- the paste is then stirred into the balance of the oil which is heated during the stirring to a temperature of 280 to 350 F., and held at that temperature until all of the soap is thoroughly incorporated into a smooth homogeneous mixture.
- Aluminum naphthenate of commerce varies considerably according to its water content and if it is very well dried, it generally requires a higher temperature in order to bring it into the solution.
- the hot mixture is then allowed to cool and sets into a soft body which may be worked down by tirring into a smooth fluid grease. It should be fluid enough so as to just flow under its own weight while at room temperature and ordinarily has an A. S. T. M. penetration of about.300 to 400 at '77 F.
- a grease of this type can be dispensed readily in grease guns of the ordinary type at temperatures as low as 0 F., and is at the same time possessed of the desired high degree of adhesivity.
- the grease described above may contain other ingredients if desired; for example, the viscosity may be considerably increased by the addition of thickeners, such as the polymers of olefins especially iso-olefins, iso-butylene and iso-amylene.
- thickeners such as the polymers of olefins especially iso-olefins, iso-butylene and iso-amylene.
- the polymers having molecular weights of 30,000 to 200,000 are to be preferred and they are ordinarily used in proportions from about.0.05 to 0.25%, depending upon the molecular weight of the polymer used.
- Oxidation inhibitors of various types may be added to the oil as well as dyes, anti-corrosion or extreme pressure agents and the like, which may be employed in order to give other qualities.
- the ingredients were stirred together into a thick paste and after thorough incorporation 78.5 parts of the same lubricating oil previously used were added and the mixture was heated while stirring to about 300 F. The stirring continued for about 2 hours and the mixture was found to be completely homogeneous. While still fluid, one part by weight of an oil solution of a linear polymer of isobutylene, having a molecular Weight of about 55,000 was added for the purpose of thickening the oil. On cooling the mixture set into a soft solid body which was then worked into a smooth semi-fluid grease which was just soft enough to flow under its own weight at room temperature.
- the semi-fluid grease had an A. S. T. M. penetration of 300 at 77 F. It was highly adhesive and showed little or no tendency to drop off the shackles or sprin bolts or to spatter. It could be readily dispensed at F., with an ordinary grease gun.
- the following table will show the eifect of the free stearic acid on the consistency of the greases after storage:
- An improved lubricant for automotive chassis comprising a viscous hydrocarbon .oil, 3 to 8% of aluminum stearate, and from about 0.25 to 1.5% of aluminum naphthenate, the same being incorporated so as to form a homogeneous semi-fluid grease jus't capable of flowing under its own weight at room temperature.
- An improved lubricantfor automotive chassis comprising mineral lubricating oil having a viscosity of from to sec. Saybolt at 210, 3 to 8% of aluminum stearate, about 0.25 to 1.5% of aluminum naphthenate, the same being worked into a homogeneous semi-fluid grease having a penetration of about 300 to 400 at 77 F. i
- An improved lubricant for automotive chassis comprising a lubricating oil of 150 to 200 sec. Saybolt at 210 F., about 5% of aluminum stearate, about .5% of aluminum naphthenate and about 0.1% of polyisobutylene as a thickener, the whole being worked into a homogeneous semi-fluid grease having a penetration of from 300 to 400 at 77 F., and just capable of flow under its own weight at ordinary temperature.
- An improved chassis lubricant comprising a viscous lubricating oil derived from a naphthenic type crude, about 3 to 8%. of an aluminum soap of a saturated fatty acid and not more than about 1% of aluminum naphthenate.
- An improved lubricant for automotive chassis comprising a lubricating oil of 150 to 200 seconds Saybolt at 210 F., about 5% of aluminum stearate containing at least 5-30% of free stearic acid, about 0.5% of aluminum naphthenate and about 0.1% of polyisobutylene as a thickener, the whole being worked into a homogeneous semi-fluid greasehaving a penetration of from 300-400 at 77 F., and just capable of flow under its own weight at ordinary temperatures.
- An improved lubricant for automotive chassis comprising a lubricating oil derived from a naphthenic type crude and of 150-200 seconds Saybolt at 210 F., about 5% of aluminum stearate containing at least 530% of free stearic acid, about 0.5% of aluminum naphthenate and about 0.1% of polyisobutylene as a thickener, the whole being worked into a homogeneous semifiuid grease having a penetration of from 300-400 at 77 F., and just capable of flow under its own weight at ordinary temperatures.
- An improved chassis lubricant according to claim 1 in which the amount of aluminum naphthenate is about of the amount of the aluminum soap of the saturated fatty acid.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
Patented Dec. 2, 1941 LUBRICANT John C. Zimme Hillside, and Arnold J. Morway,
Roselle, N. J., assignors to Standard Oil Development Company, a corporation of Delaware No Drawing.
Application February 9, 1939,
Serial No. 255,452
9 Claims.
The present invention relates to an improved lubricant and more specifically to a. semi-fluid grease principally for automative chassis lubrication and for similar purposes. The invention will be fully understood from the following description.
In the lubrication of automotive chassis, it has been found desirable to provide a semi-fluid grease which has a high degree of adhesivity in order to withstand the continual pounding of the shackles, spring bolts and other parts, which pounding tends to cause the grease to be squeezed out of the bearing and lost by spattering. At the same time, this adhesivity cannot be gained by excessive hardening of the grease since this result would greatly increase the dispensing difficulties. It is necessary therefore that the grease be highly adhesive, but soft enough to be dispensed with the usual type of grease guns.
It has been found that the above results can best be achieved by adding certain specific aluminum soaps to viscous petroleum oils in certain specific proportions. this purpose is derived from a naphthenic base, for example, from oils of the Coastal type with a high viscosity, that is, above 150 seconds Saybolt at 210 F., and preferably in the range from 160 to 220 seconds. The most suitable soaps to be added are those of aluminum. In making up the lubricant, from 3 to 8%, and preferably about The oil preferred for v 5% of aluminum stearate is used, but it will be understood that similar aluminum soaps of saturated fatty acids may be substituted. The aluminum stearate is readily dissolved in the oil, but it causes the latter to set into firm gel which is undesirable. This result can be avoided by the addition of a relatively small amount of nongelling aluminum soaps, such as aluminum naphthenate or aluminum oleate containing approximately 20% of free stearic acid. The commercial aluminum stearates vary in the percentage of free acid'from approximately 5 to 15 to even greater amounts. The soaps having the greater percentage of aluminum tend to form firmer gels and it has been found that by increasing the percentage of free stcaric acid to 20% (total) or using the aluminum stearates containing this amount of free acid, a softer and more adaptable grease is formed. It has also been found that this additional free fatty acid during storage also prevents the grease from setting back to its original firmness after working. The amount of aluminum naphthenate or oleate varies from about 0.25 to 1.5%; that is to say, the amount is ordinarily about t; to /5 of the amount of the aluminum stearate.
In manufacturing the grease, the aluminum soaps and enough free stearic acid to bring the fatty acid content of the aluminum soap to 20% free fatty acid are added and thoroughly admixed with a small portion of the oil, say .about 10 to 20% of the total quantity to be used, and the ingredients are Worked together in a thick paste. The paste is then stirred into the balance of the oil which is heated during the stirring to a temperature of 280 to 350 F., and held at that temperature until all of the soap is thoroughly incorporated into a smooth homogeneous mixture. Aluminum naphthenate of commerce varies considerably according to its water content and if it is very well dried, it generally requires a higher temperature in order to bring it into the solution. In such a case, it is found preferable to add aluminum naphthenate to the oil and to heat up toa temperature of 350 to 450 F., while stirring, and then to add the aluminum stearate to this mixture just as indicated before at a temperature from about 280 to 350 F.
The hot mixture is then allowed to cool and sets into a soft body which may be worked down by tirring into a smooth fluid grease. It should be fluid enough so as to just flow under its own weight while at room temperature and ordinarily has an A. S. T. M. penetration of about.300 to 400 at '77 F. A grease of this type can be dispensed readily in grease guns of the ordinary type at temperatures as low as 0 F., and is at the same time possessed of the desired high degree of adhesivity.
The grease described above may contain other ingredients if desired; for example, the viscosity may be considerably increased by the addition of thickeners, such as the polymers of olefins especially iso-olefins, iso-butylene and iso-amylene. For this purpose, the polymers having molecular weights of 30,000 to 200,000 are to be preferred and they are ordinarily used in proportions from about.0.05 to 0.25%, depending upon the molecular weight of the polymer used. Oxidation inhibitors of various types may be added to the oil as well as dyes, anti-corrosion or extreme pressure agents and the like, which may be employed in order to give other qualities.
Example naphthenic acid obtained from a Venezuelan gas oil) to about 15 parts of a naphthenic lubricating oil which had an initial viscosity of 170 seconds Saybolt at 210 F. The ingredients were stirred together into a thick paste and after thorough incorporation 78.5 parts of the same lubricating oil previously used were added and the mixture was heated while stirring to about 300 F. The stirring continued for about 2 hours and the mixture was found to be completely homogeneous. While still fluid, one part by weight of an oil solution of a linear polymer of isobutylene, having a molecular Weight of about 55,000 was added for the purpose of thickening the oil. On cooling the mixture set into a soft solid body which was then worked into a smooth semi-fluid grease which was just soft enough to flow under its own weight at room temperature.
The semi-fluid grease had an A. S. T. M. penetration of 300 at 77 F. It was highly adhesive and showed little or no tendency to drop off the shackles or sprin bolts or to spatter. It could be readily dispensed at F., with an ordinary grease gun. The following table will show the eifect of the free stearic acid on the consistency of the greases after storage:
A. S. T. M. penetration Grease freshly After 2 Free stearic acid in the aluminum prepared as weeks stearate de sggi bad Storage aluminum soap of a saturated fatty acid andnot more than about 1% of aluminum naphthenate.
2. An improved lubricant for automotive chassis, comprising a viscous hydrocarbon .oil, 3 to 8% of aluminum stearate, and from about 0.25 to 1.5% of aluminum naphthenate, the same being incorporated so as to form a homogeneous semi-fluid grease jus't capable of flowing under its own weight at room temperature.
3. An improved lubricantfor automotive chassis, comprising mineral lubricating oil having a viscosity of from to sec. Saybolt at 210, 3 to 8% of aluminum stearate, about 0.25 to 1.5% of aluminum naphthenate, the same being worked into a homogeneous semi-fluid grease having a penetration of about 300 to 400 at 77 F. i
4. Product according to claim 1 in which the oil is a naphthenic base crude distillate containing a small amount of an added linear iso-olefin polymer as a thickener.
5. An improved lubricant for automotive chassis, comprising a lubricating oil of 150 to 200 sec. Saybolt at 210 F., about 5% of aluminum stearate, about .5% of aluminum naphthenate and about 0.1% of polyisobutylene as a thickener, the whole being worked into a homogeneous semi-fluid grease having a penetration of from 300 to 400 at 77 F., and just capable of flow under its own weight at ordinary temperature.
6. An improved chassis lubricant comprising a viscous lubricating oil derived from a naphthenic type crude, about 3 to 8%. of an aluminum soap of a saturated fatty acid and not more than about 1% of aluminum naphthenate.
7. An improved lubricant for automotive chassis comprising a lubricating oil of 150 to 200 seconds Saybolt at 210 F., about 5% of aluminum stearate containing at least 5-30% of free stearic acid, about 0.5% of aluminum naphthenate and about 0.1% of polyisobutylene as a thickener, the whole being worked into a homogeneous semi-fluid greasehaving a penetration of from 300-400 at 77 F., and just capable of flow under its own weight at ordinary temperatures.
8. An improved lubricant for automotive chassis comprising a lubricating oil derived from a naphthenic type crude and of 150-200 seconds Saybolt at 210 F., about 5% of aluminum stearate containing at least 530% of free stearic acid, about 0.5% of aluminum naphthenate and about 0.1% of polyisobutylene as a thickener, the whole being worked into a homogeneous semifiuid grease having a penetration of from 300-400 at 77 F., and just capable of flow under its own weight at ordinary temperatures.
9. An improved chassis lubricant according to claim 1 in which the amount of aluminum naphthenate is about of the amount of the aluminum soap of the saturated fatty acid.
JOHN C. ZIMMER. ARNOLD J. MORWAY.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US255452A US2264353A (en) | 1939-02-09 | 1939-02-09 | Lubricant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US255452A US2264353A (en) | 1939-02-09 | 1939-02-09 | Lubricant |
Publications (1)
Publication Number | Publication Date |
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US2264353A true US2264353A (en) | 1941-12-02 |
Family
ID=22968391
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US255452A Expired - Lifetime US2264353A (en) | 1939-02-09 | 1939-02-09 | Lubricant |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2521395A (en) * | 1948-04-07 | 1950-09-05 | Standard Oil Dev Co | Aluminum soap greases |
US2596845A (en) * | 1948-05-28 | 1952-05-13 | Stanolind Oil & Gas Co | Treatment of wells |
US2596844A (en) * | 1949-12-31 | 1952-05-13 | Stanolind Oil & Gas Co | Treatment of wells |
US2596843A (en) * | 1949-12-31 | 1952-05-13 | Stanolind Oil & Gas Co | Fracturing formations in wells |
US2606107A (en) * | 1943-11-01 | 1952-08-05 | Louis F Fieser | Incendiary gels |
US2708974A (en) * | 1951-08-20 | 1955-05-24 | Union Oil Co | Treatment of oil-bearing formation |
US2978411A (en) * | 1956-10-22 | 1961-04-04 | Exxon Research Engineering Co | Aluminum soap hydrocarbon thickener with increased solvation |
US2998385A (en) * | 1959-07-17 | 1961-08-29 | Gulf Oil Corp | Aluminum soap thickened lubricating oil |
-
1939
- 1939-02-09 US US255452A patent/US2264353A/en not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2606107A (en) * | 1943-11-01 | 1952-08-05 | Louis F Fieser | Incendiary gels |
US2521395A (en) * | 1948-04-07 | 1950-09-05 | Standard Oil Dev Co | Aluminum soap greases |
US2596845A (en) * | 1948-05-28 | 1952-05-13 | Stanolind Oil & Gas Co | Treatment of wells |
US2596844A (en) * | 1949-12-31 | 1952-05-13 | Stanolind Oil & Gas Co | Treatment of wells |
US2596843A (en) * | 1949-12-31 | 1952-05-13 | Stanolind Oil & Gas Co | Fracturing formations in wells |
US2708974A (en) * | 1951-08-20 | 1955-05-24 | Union Oil Co | Treatment of oil-bearing formation |
US2978411A (en) * | 1956-10-22 | 1961-04-04 | Exxon Research Engineering Co | Aluminum soap hydrocarbon thickener with increased solvation |
US2998385A (en) * | 1959-07-17 | 1961-08-29 | Gulf Oil Corp | Aluminum soap thickened lubricating oil |
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