US2258435A - Electrode - Google Patents

Electrode Download PDF

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Publication number
US2258435A
US2258435A US110520A US11052036A US2258435A US 2258435 A US2258435 A US 2258435A US 110520 A US110520 A US 110520A US 11052036 A US11052036 A US 11052036A US 2258435 A US2258435 A US 2258435A
Authority
US
United States
Prior art keywords
platinum
anode
sheath
tantalum
copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US110520A
Other languages
English (en)
Inventor
Adolph Gustav
Max E Bretschger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BUFFALO ELECTRO CHEM CO
BUFFALO ELECTRO-CHEMICAL COMPANY Inc
Original Assignee
BUFFALO ELECTRO CHEM CO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL84919D priority Critical patent/NL84919C/xx
Application filed by BUFFALO ELECTRO CHEM CO filed Critical BUFFALO ELECTRO CHEM CO
Priority to US110520A priority patent/US2258435A/en
Priority to GB30523/37A priority patent/GB486728A/en
Priority to FR828957D priority patent/FR828957A/fr
Priority to CH201280D priority patent/CH201280A/de
Application granted granted Critical
Publication of US2258435A publication Critical patent/US2258435A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/28—Per-compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form

Definitions

  • This invention relates to an electrode andparof percompounds by anodic oxidation.
  • percompounds such as per-sulfuric acid, perboricacid, etc., and their salts
  • platinum anodes must always be employed as all other metals do not permit of a deposit of the desired anion on the acid or its salt, such as $04 on sulfuric acid or a salt thereof, even though the metal might be sufliciently stable against attack by the electrolytic solution;
  • the drawing shows a view in perspective of the improved anode.
  • the anode of the present invention is formed of a central conducting core or rod- III of a common. metal, as, for instance, copper. Electrical contact and connection is made between rod- 10 and a conducting element H of metallic tantalum.
  • a hard rubber sheath l2 formed with lips l3 which engage the tantalum member H.
  • the anode is completed by connecting the platinum tip M to the tantalum member II.
  • An anode for the production of percom- I pounds comprising a-core of conducting material, a sheathof non-conducting material stable toward the electrolyte of the bathin which the anode is used surrounding the corepa platinum tip'upon which nascent oxygen develops when the anode is used in the production of percompounds spaced from the sheath, and a memberof tantalum extending through the sheath and being co the platinum tip so that when in use no nascent oxygen-develops in contact with the sheath.
  • An anode for the production of percom pounds comprising a core of copper, a sheath of non-conducting material surrounding "the cop- ,per core, a platinum tip spaced from the sheath and a member of tantalum extending through the sheath and having electrical contact with the core and the platinum tip so that when the anode I is used for the production of percompounds nascent oxygen'develops only upon the platinum tip and not in contact withthe sheath.
  • an elongate elementof conducting material In an electrode, an elongate elementof conducting material, a second elongate elementoi electrochemically active conductingmlaterial ex-' tending parallel thereto and spaced therefrom, an insulating sheath surrounding said first element, and a plurality of electrochemically inactive conductors extending through said insulati ng sheath and between said two elements for maintaining rigid relation and for establishing electrical communication tlrierebetween.
  • an elongate element of a .metallic conducting material a second elongate element comprising electrochemically active conducting tnaterial of platinum extending parallel to said first element and spaced therefrom, an insulating sheath surrounding said first element,
  • the present invention provides an anode wherein a' ductors formed of tantalum and extending between laicl two elements for maintaining rigid relation and for establishing electrical communication therebetween.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
US110520A 1936-11-12 1936-11-12 Electrode Expired - Lifetime US2258435A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
NL84919D NL84919C (xx) 1936-11-12
US110520A US2258435A (en) 1936-11-12 1936-11-12 Electrode
GB30523/37A GB486728A (en) 1936-11-12 1937-11-06 Improvements in electrodes for the production of per-compounds
FR828957D FR828957A (fr) 1936-11-12 1937-11-10 électrode
CH201280D CH201280A (de) 1936-11-12 1937-11-10 Elektrode.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US110520A US2258435A (en) 1936-11-12 1936-11-12 Electrode

Publications (1)

Publication Number Publication Date
US2258435A true US2258435A (en) 1941-10-07

Family

ID=22333464

Family Applications (1)

Application Number Title Priority Date Filing Date
US110520A Expired - Lifetime US2258435A (en) 1936-11-12 1936-11-12 Electrode

Country Status (5)

Country Link
US (1) US2258435A (xx)
CH (1) CH201280A (xx)
FR (1) FR828957A (xx)
GB (1) GB486728A (xx)
NL (1) NL84919C (xx)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2726201A (en) * 1950-08-02 1955-12-06 Int Nickel Co Anodic pickling and nickel plating of tank interior using single electrolyte
US3104220A (en) * 1960-04-27 1963-09-17 Herman S Preiser Flexible trailing anode
US3271289A (en) * 1959-07-22 1966-09-06 Oronzio De Nora Impianti Mercury cathode electrolytic cell having an anode with high corrosionresistance and high electrical and heat conductivity
US3476675A (en) * 1966-03-22 1969-11-04 Simplex Mfg Co An electrolytic cell for chlorine production
US3960695A (en) * 1974-02-22 1976-06-01 Roller Paul S Apparatus for the electrolytic production of insoluble metal hydroxide
US4619752A (en) * 1984-02-24 1986-10-28 Conradty Gmbh & Co. Metallelektroden Kg Electrode for electrolytic extraction of metals or metal oxides

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2726201A (en) * 1950-08-02 1955-12-06 Int Nickel Co Anodic pickling and nickel plating of tank interior using single electrolyte
US3271289A (en) * 1959-07-22 1966-09-06 Oronzio De Nora Impianti Mercury cathode electrolytic cell having an anode with high corrosionresistance and high electrical and heat conductivity
US3104220A (en) * 1960-04-27 1963-09-17 Herman S Preiser Flexible trailing anode
US3476675A (en) * 1966-03-22 1969-11-04 Simplex Mfg Co An electrolytic cell for chlorine production
US3960695A (en) * 1974-02-22 1976-06-01 Roller Paul S Apparatus for the electrolytic production of insoluble metal hydroxide
US4619752A (en) * 1984-02-24 1986-10-28 Conradty Gmbh & Co. Metallelektroden Kg Electrode for electrolytic extraction of metals or metal oxides

Also Published As

Publication number Publication date
GB486728A (en) 1938-06-09
FR828957A (fr) 1938-06-07
NL84919C (xx)
CH201280A (de) 1938-11-30

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