US2222686A - Treatment of synthetic resins and materials containing same - Google Patents
Treatment of synthetic resins and materials containing same Download PDFInfo
- Publication number
- US2222686A US2222686A US133075A US13307537A US2222686A US 2222686 A US2222686 A US 2222686A US 133075 A US133075 A US 133075A US 13307537 A US13307537 A US 13307537A US 2222686 A US2222686 A US 2222686A
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- Prior art keywords
- resinous
- colloidal
- water
- sheet
- synthetic resins
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
- B29C65/481—Non-reactive adhesives, e.g. physically hardening adhesives
- B29C65/482—Drying adhesives, e.g. solvent based adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/737—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined
- B29C66/7379—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined degradable
- B29C66/73793—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined degradable soluble, e.g. water-soluble
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/82—Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps
- B29C66/822—Transmission mechanisms
- B29C66/8223—Worm or spindle mechanisms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
- B29C66/832—Reciprocating joining or pressing tools
- B29C66/8322—Joining or pressing tools reciprocating along one axis
- B29C66/83221—Joining or pressing tools reciprocating along one axis cooperating reciprocating tools, each tool reciprocating along one axis
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
- C08J3/215—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase at least one additive being also premixed with a liquid phase
Definitions
- Our invention relates to the treatment of materials containing synthetic or articial resins, in order to malte ⁇ therefrom moulded articles, such as parts of automobile bodies.
- soap becomes insoluble in the resin and ractionates saine owing to its avidity for water, thus i0 favouring its going over to the colloidal state.
- the colloidal resinous matter is used in admixture with a charge, which is preferably of fibrous nature and consists for example of cotton pulp.
- a charge which is preferably of fibrous nature and consists for example of cotton pulp.
- This pulp is put into suspension in water by stirring and into this suspension the resinous matter is introduced by injection or pouring.
- the resinous matter amalgamates with the cotton bres.
- the mass formed may be very'iluid. In that case we may separate the solid matters by floatation at the surface of the liquid by subjecting the mass to violent stirring and blowing.
- the separation may ⁇ be completed by a suction through filtering moulds on which the agglutinated fibres are deposited in a layer which is removed when it reaches a suitable thickness and strength.
- moulds made entirely of metal in order to Withstand the pressure, and we may use for instance a light metal wall such as la metal sheet shaped to the shape of the piece to be moulded, such metal sheet being supported by a base of reinforced concrete, which makes the mould very like, a colloidal kf'pressure and heat,
- the metal wall of the mould is well polished, or chromed, we may obtain directly from the mould finished articles having a smooth and polished surface.
- the pieces formed of colloidal resinous substance according to our invention are easily welded to each other and mended by applying at an elevated temperature a layer of the same substance between the pieces to be united or on the piece to be mended.
- Figs. 1 and 2 respectively show in longitudinal section on line I--Iof Fig. 2 and in cross section on line II-'II of Fig. 1 a heating and polymerising mould for carrying out our improved process.
- Figs. 3, 4 and 5 illustrate methods of connecting together and mending moulded pieces according to our invention.
- the mould is formedv of a steel sheet I shaped for example to the shape of the door of a motor car body, and a concrete base 2 cast under the metalsheet I so as to support same at all points.
- the concrete usedf may comprise Portland cement mixed with vmetal a little water we dilute a.
- the mould Before receiving the sheet 5 of resinous matter, the mould is heated by circulating steam through the tubes 3.
- the sheet 5 being placed in position, the remaining cavitz,1 6 in the mould is filled with a loose filler material.
- the cover 1 then is closed and the whole is subjected in a press to a pressure of 10 to 15 kg. per square centimeter.
- the cover is bolted or locked to the mould while the pressure is being exerted, and the polymerising heating process then is carried out outside the press by again circulating steam through the tubes 3.
- the material forming the sheet still contains a small proportion of the mother liquor from which it was produced, the porosity of the loose filler 6 serving as a counter die favours the elimination of vapors produced during the baking process.
- Fig. 3 shows by way of example two pieces 8, 8 of a motor car body, which have thus been moulded and are to be united together.
- a sheet 9 of calendered resinous matter having been inserted between said pieces, the whole is clamped between heated metal pieces I0, II by means of clamping members such as I2 which are removed when the welding is completed.
- Fig. 4 we have shown the mending of a piece I3 broken at I4. At the break we apply a sheet of resinous matter I5 and We heat by means of clamping members I6, l1 to weld the parts together.
- Fig. 5 illustrates how a hole in a piece I8 is mended by means of a resinous sheet I9 held by heated metal clamps 2B, 2 I
- the invention makes it possible to manufacture, unite and mend moulded pieces of resinous material of all sizes, with greater ease and less expense than heretofore; it is particularly applicable to the mechanical production of motor car bodies in small series, the moulded parts being as strong. lighter and more soundproof than ⁇ similar parts of sheet metal, and requiring much less expensive apparatus for their manufacture.
- Our invention of course is not limited to this application, nor is it limited to the details set forth by way oi example, the scope of the invention being defined by the appended claims.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Description
Noir. 26, 12940. L. ROBIN x-:rm` y 2,222,686 i v TREATMENT OF SYNTHETIC RESINS AND MATERIALS CONTAINING SAME Filed March 25, 1937 ff@ W x\\\\ m W y l// A( 2f 19 1 NVENTORS:
1 ,50 ROBIN M MATHIEU VAN RoGGe-,N
i ATTRNELY Patented Nov. 26, 1940 TREATMENT OF SYNTHETIC RESINS AND MATERIALS CONTAINING SAME Leo Robin and Mathieu Van Roggen, Sprimont, Belgium Application Marchas, 1937, serial Na. 133,075
In Belgium April l, 1936 Claims.
Our invention relates to the treatment of materials containing synthetic or articial resins, in order to malte` therefrom moulded articles, such as parts of automobile bodies.
As is well known the hardening of resinsds due to polymerisation, with an evolution from a liquid or viscous stateA, through a state B in which the partly polymerised resin is solid at ordinary temperature and soluble in a few solvents only, to a nal state C in which the resin is in solid, stable and insoluble form. Near state A, the resins are sticky, dimcult to be manipulated for moulding purpose and they require prolonged drying. When they are further evolved towards state B, for example in the powder form which is frequently used, they only possess a reduced cohesive power and in order to form homogeneous and strong bodies, they require such high moulding pressure that the power and the cost of the necessary presses become prohibitive when pieces of comparatively large size are to be moulded.
It is the object of our invention to avoid these inconveniences and to this end, in accord- 25 ance with our invention we use the resinous substances in a colloidal or reticular form, which makes it possible to produce by simple and economical means, with the use of relatively small pressures, moulded bodies which are strong 30 and homogeneous, whatever be their shape and their size. We have found that when resinous substances partly evolved between state A and state B are dispersed in colloidal form in a liquid carrier, they lose their sticky character and ac- 5 quire a high cohesive power, whereby the moulding pressures and the duration oi the heating required for polymerisation may be lessened to a surprising extent. n
In carrying out the invention, we use alcohol- 40 soluble synthetic resins partly evolved between state A and state B, and we have found that such resins are causedy to assume the colloidal form when mixed with a soap and dissolved in alcohol, 5 the solution then being dispersed in water. The soap is soluble in the resin only through the medium of the alcohol; in presence of water, the
soap becomes insoluble in the resin and ractionates saine owing to its avidity for water, thus i0 favouring its going over to the colloidal state.
It is also of advantage to add to the mixture a small amount of a heavy solvent, such as furfurol, which also acts as a plastier.
In order to form a dispersion in Water we may 5 use an injection device with acurrent of water under pressure into which the uid resinous mixture is introduced, the colloidal matter being collected in a receptacle. Good results are also obtained by gradually pouring the resinous preparation into a receptacle containing water, and suitably stirring the mixture.
For moulding purposes, the colloidal resinous matter is used in admixture with a charge, which is preferably of fibrous nature and consists for example of cotton pulp. This pulp is put into suspension in water by stirring and into this suspension the resinous matter is introduced by injection or pouring. When in the colloidal state the resinous matter amalgamates with the cotton bres. v
The mass formed may be very'iluid. In that case we may separate the solid matters by floatation at the surface of the liquid by subjecting the mass to violent stirring and blowing. The separation may` be completed by a suction through filtering moulds on which the agglutinated fibres are deposited in a layer which is removed when it reaches a suitable thickness and strength.
It is however usually preferable to start from a less fluid mass and to knead it between mixing rollers revolving at diierent speeds, in order to obtain directly the material to sheet form. Such sheets, after calendering and drying if necessary, are very similar to leather in appearance, suppleness and toughness. Any small excess of water is easily removed as the mass passes between the mixing rollers. The sheets can easily be moulded under lowpresure, in heated moulds in which they are softened. We mayI also, after kneading, roll or form the mass into a block, instead of delivering it in sheet form,l and then soften the mass by the action of heat and injectthe matter under low pressure into the forming moulds. I
With the use of material in sheet form we are enabled to usemoulds Without a counter die, the latter being replaced by loose material inserted between the sheet lying in the mould and the cover to which the pressure is applied. Thus a material saving is obtained when the moulds are of large size.
Moreover, as the requisite pressures are comparatively low, it is no longer necessary to use moulds made entirely of metal in order to Withstand the pressure, and we may use for instance a light metal wall such as la metal sheet shaped to the shape of the piece to be moulded, such metal sheet being supported by a base of reinforced concrete, which makes the mould very like, a colloidal kf'pressure and heat,
cheap. In order to heat the mould, wemay use as an armature for lthe concrete metal tubes connected together in order to permit the circulation of a heating fluid, such as steam.
If the metal wall of the mould is well polished, or chromed, we may obtain directly from the mould finished articles having a smooth and polished surface. We may also carry out in the mould the coloring and varnishing of the moulded pieces by applying within the mould, before placing therein the sheet of resinous matter to be moulded, one or more layers of colored or colorless varnish which, under the action of will adhere to the sheet and come out of the mould together with the finished article. p
Contrary to pieces of Bakelite and like materials which cannot be assembled or mended by welding, the pieces formed of colloidal resinous substance according to our invention are easily welded to each other and mended by applying at an elevated temperature a layer of the same substance between the pieces to be united or on the piece to be mended.
In order that our invention may be more fully understood we shall describe hereafter, by way of example, a manner of carrying it into practice. Referring to the accompanying drawing:
Figs. 1 and 2 respectively show in longitudinal section on line I--Iof Fig. 2 and in cross section on line II-'II of Fig. 1 a heating and polymerising mould for carrying out our improved process.
Figs. 3, 4 and 5 illustrate methods of connecting together and mending moulded pieces according to our invention.
In carrying out our invention, we prepare from synthetic or artificial resinous .substances, for example phenol-formaldehyde or urea-formaldehyde condensation products, aikyd resins or the dispersion or a reticular forma.- tion inl which said substances constitute the solid phase. To that end we use for example a mixture of 32% artificial resin in liquid form or partly evolved between state A and state B, 32% of hard varnish comprising synthetic resin evolved nearly to state B but still soluble in alcohol, 32% alcohol, 3% soap and 1% furfurol. .The mixture is effected after the varnish has dissolved in the alcohol. A viscous and very homogeneous liquid is obtained.
On the other hand in weight of cotton pulp equal to the weight of resinous mixture, while stirring until a uniform dilution is obtained. We then gradually pour therein the resinous mixture, while stirring the whole mixture.
'Ihe alcohol and the soap being water soluble separate from the resin which, on taking the colloidal form, agglutinates with the cotton libres and forms a thick` and tough mass which is then treated in a mixing mill having rollers revolving at different speeds, such as are used in the rubber industry. The paste then is calendered into sheets of suitable thickness, between rolls revolving at the same speed.
After further drying, if necessary, we cut the sheet into two or more sheets which are superposed, and we place into the mould the cut sheet or sheets.
As shown in Figs. 1 and 2, the mould is formedv of a steel sheet I shaped for example to the shape of the door of a motor car body, and a concrete base 2 cast under the metalsheet I so as to support same at all points. The concrete usedfmay comprise Portland cement mixed with vmetal a little water we dilute a.
A,resinous substances to assume shavings or cuttings to increase 'the thermal oonductibility and the strength. It is reinforced by iron tubes 3 connected with each other and surrounded by a metal frame 4.
Before receiving the sheet 5 of resinous matter, the mould is heated by circulating steam through the tubes 3. The sheet 5 being placed in position, the remaining cavitz,1 6 in the mould is filled with a loose filler material. The cover 1 then is closed and the whole is subjected in a press to a pressure of 10 to 15 kg. per square centimeter. The cover is bolted or locked to the mould while the pressure is being exerted, and the polymerising heating process then is carried out outside the press by again circulating steam through the tubes 3.
If, as is advantageous from the point of view of ductility and cohesive power, the material forming the sheet still contains a small proportion of the mother liquor from which it was produced, the porosity of the loose filler 6 serving as a counter die favours the elimination of vapors produced during the baking process.
Fig. 3 shows by way of example two pieces 8, 8 of a motor car body, which have thus been moulded and are to be united together. A sheet 9 of calendered resinous matter having been inserted between said pieces, the whole is clamped between heated metal pieces I0, II by means of clamping members such as I2 which are removed when the welding is completed.
In Fig. 4 we have shown the mending of a piece I3 broken at I4. At the break we apply a sheet of resinous matter I5 and We heat by means of clamping members I6, l1 to weld the parts together.
Fig. 5 illustrates how a hole in a piece I8 is mended by means of a resinous sheet I9 held by heated metal clamps 2B, 2 I
It is seen from the above that the invention makes it possible to manufacture, unite and mend moulded pieces of resinous material of all sizes, with greater ease and less expense than heretofore; it is particularly applicable to the mechanical production of motor car bodies in small series, the moulded parts being as strong. lighter and more soundproof than `similar parts of sheet metal, and requiring much less expensive apparatus for their manufacture. Our invention, of course is not limited to this application, nor is it limited to the details set forth by way oi example, the scope of the invention being defined by the appended claims.
We claim:
1. In a process of treating alcohol-soluble synthetic resins and matrlals containing same, dissolving partly polymerised non-solid resinous substances and a soap in alcohol, dispersing the solution in water containing a fibrous suspension thus causing the resinous substances to assume a colloidal form, amalgamating the resinous substances with said nbrous suspension into a paste, and separating the excess liquid from said paste to bring said paste into a moldable condition,
2. In a process oi treating alcohol-solubleb synthetic resins and materials containing same, dissolving partly polymerised non-solid resinous substances, .a heavy solvent and a soap ln alcohol, dispersing the solution in water thus causing the y V a colloidal form, mixing the obtained colloidal dispersion with a suspension of cotton fibres in water, amalgamating said resinous substances with said flbres into a paste, and expelling the excess liquid from said paste to bring sameinto a moldable condition.
3. In a process of treating alcohol-soluble synthetic resins and materials dissolving partly'polymerised non-solid resinous substances together with soap and iurfurol in alcohol. dispersing the solution in water thus separating said resinous substances from the water-soluble alcohol, soap and furfurcl and causing said resinous substances to assume the colloidal state, amalgamating said colloidal resinous substances with a suspension of fibrous material in water to form a pasty mixture, and expelling liquid from said pasty mixture to lbring said pasty mixture into a moldable condition.
4. In a process of treating alcohol-soluble synthetic resins and materials containing same, dissolving partly polymerised non-colloidal resinous substances and a soap in alcohol, preparing a l Aiiliorous suspension in water, causing said resinous containing sama.
substances to assume a colloidal form by dispersing said solution in water, and amalgamating said colloidal resinous substances with said 1ibrous suspension into a moldable paste.
5. In a process of treating synthetic resins and materials containing same, dissolving partly polymerised non-solid resinous substances and a soap in a solvent for said resinous substances, dispersing the solution in water thus causing the resinous substances to assume a colloidal form, mixing the resulting colloidal dispersion with a suspension oi -bres in water, amalgamating the colloidal resinous substances with said iibres into a paste, and expelling the excess liquid from said paste to bring same into a moldable 15 condition. v
LEO ROBIN. MA VAN ROGGEN.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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BE2222686X | 1936-04-01 |
Publications (1)
Publication Number | Publication Date |
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US2222686A true US2222686A (en) | 1940-11-26 |
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Application Number | Title | Priority Date | Filing Date |
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US133075A Expired - Lifetime US2222686A (en) | 1936-04-01 | 1937-03-25 | Treatment of synthetic resins and materials containing same |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3157339A (en) * | 1961-07-18 | 1964-11-17 | Continental Can Co | Paper cup with caulked bottom and method of making |
-
1937
- 1937-03-25 US US133075A patent/US2222686A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3157339A (en) * | 1961-07-18 | 1964-11-17 | Continental Can Co | Paper cup with caulked bottom and method of making |
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