US220449A - Improvement in the manufacture of chloride of zinc - Google Patents
Improvement in the manufacture of chloride of zinc Download PDFInfo
- Publication number
- US220449A US220449A US220449DA US220449A US 220449 A US220449 A US 220449A US 220449D A US220449D A US 220449DA US 220449 A US220449 A US 220449A
- Authority
- US
- United States
- Prior art keywords
- zinc
- chloride
- manufacture
- improvement
- dross
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title description 28
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title description 28
- 229910052725 zinc Inorganic materials 0.000 title description 28
- 239000011701 zinc Substances 0.000 title description 28
- 238000004519 manufacturing process Methods 0.000 title description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 241000282887 Suidae Species 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000000249 desinfective Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- -1 zinc-iron Chemical compound 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/04—Halides
Definitions
- Our invention consists of a new and cheap chloride of zinc, which can be used in many cases as an economical substitute for the more expensive chloride.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adornments (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
Description
UNITED STATES PATENT OEEIoE.
WILLIAM H. WAHL AND EDWARD Y. ELTONHEAD, OF PHILADELPHIA,
PENNSYLVANIA, ASSIGNORS OF ONE-THIRD OF THEIR RIGHT TO CALEB H. HORNE, OF SAME PLACE.
IMPROVEMENT. IN THE MANUFACTURE OF CHLORIDE OF ZINC.
Specification forming part of Letters Patent No. 220,449., dated October 7, 1879; application filed February 6, 1879.
To all whom it may concern:
Be it known that we, WILLIAM H. WAHL and EDWARD Y. ELTONHEAD, both of Philadelphia, Pennsylvania, have invented a new and useful Improvement in the Manufacture of Chloride of Zinc, of which the following is a specification.
Our invention consists of a new and cheap chloride of zinc, which can be used in many cases as an economical substitute for the more expensive chloride.
In galvanizingiron objects a zinc-iron alloy is formed, and this settles at the bottom of the vessel. This precipitate, which has been termed dross, and should not be confounded with the impurities which rise to the surface, represents a loss on the average of nearly thirty-three per cent. of the zinc used.
It-has been usual heretofore to remove this dross from the galvanizing-vessel at intervals and cast itinto pigs, which are sold to the refiners, who reconvert as much of it as possible into pure zinc by the expensive process of distillation.
We have found that this so-called precipitated dross can be converted into a cheap chloride, available for many purposes, but especially useful ingalvanizing operations, for the purpose of cleansing iron, in a manner described in a separate application for a patent,
preparatory to subjecting the iron to the bath of molten zinc.
In order to convert the dross into a chloride, proceed as follows: Wh'e'n it is removed from the bath-of molten zinc, which is usually accomplished by perforated ladles, it is of a slushy consistency, but when it becomes cool is quite as hard as, or harder than, ordinary zinc.
Instead of casting it into pigs, we let it fall while in its molten condition onto metal plates or stone slabs, or into water, so as to reduce it to that flaky or granular condition which will induce it to yield promptly to the action of the muriatic acid. As much of the latter must be used as will convert it into the chloride, the color of which distinguishes it from the ordinary commercial chloride of zinc. While the product thus obtained may not be as pure .as ordinary chloride of zinc, it is available-for many of the purposes to which ordinary chloride has been applied.
The importance of the invention appears most prominently when we take into account the fact that the zinc dross, most of which has heretofore only been utilized by expensive processes of refining, is converted into a chloride which can be sold much cheaper than commercial chloride of zinc, of which it must take the place in many branches of industry, for use as a cheap disinfectant, and for other purposes.
We claim as our invention- As a new article of manufacture and commerce, the within-described crude commercial chloride of zinc.
In testimony whereof we have signed our names to this specification in .the presence of two subscribing witnesses.
WILLIAM H. VVAHL. EDWARD Y. ELTONHEAD. Witnesses:
WILLIAM J. COOPER, HARRY SMITH.
Publications (1)
Publication Number | Publication Date |
---|---|
US220449A true US220449A (en) | 1879-10-07 |
Family
ID=2289850
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US220449D Expired - Lifetime US220449A (en) | Improvement in the manufacture of chloride of zinc |
Country Status (1)
Country | Link |
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US (1) | US220449A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3375069A (en) * | 1965-07-23 | 1968-03-26 | Leonard A. Duval | Process for removing zinc oxide from iron oxide flue dust by the use of spent pickle liquor |
US6036937A (en) * | 1998-11-18 | 2000-03-14 | Tetra Technologies, Inc. | Method for producing zinc bromide |
-
0
- US US220449D patent/US220449A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3375069A (en) * | 1965-07-23 | 1968-03-26 | Leonard A. Duval | Process for removing zinc oxide from iron oxide flue dust by the use of spent pickle liquor |
US6036937A (en) * | 1998-11-18 | 2000-03-14 | Tetra Technologies, Inc. | Method for producing zinc bromide |
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