US2198660A - Treatment of textile and other materials - Google Patents

Treatment of textile and other materials Download PDF

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US2198660A
US2198660A US105927A US10592736A US2198660A US 2198660 A US2198660 A US 2198660A US 105927 A US105927 A US 105927A US 10592736 A US10592736 A US 10592736A US 2198660 A US2198660 A US 2198660A
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materials
cellulose
foils
yarns
films
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Dreyfus Henry
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Henry Dreyfuss Associates LLC
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D06M11/385—Saponification of cellulose-acetate
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
    • D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate

Definitions

  • This invention relates to improvements in the treatment of textile and other materials and is more particularly concerned with increasing the tensile strength of certain esterified or etherified cellulose products.
  • the appropriate pressure may be used either to maintain the steam in a saturated or wet condition or to maintain the water in the liquid state
  • regenerated cellulose materials which have been acetylated in suspension (so as not to lose their fibrous form) in presence of hydrolytic agents, for example sulphuric acid, phosphoric acid or strongly acid salts such as bisulphates, zinc chloride, ferric chloride and the like, are more amenable to the stretching treatment than are similar materials which have been acetylated in the presence of catalytic agents such as sodium or potassium acetate or tertiary organic bases which have no substantial hydrolytic action upon cellulose.
  • catalytic agents such as sodium or potassium acetate or tertiary organic bases which have no substantial hydrolytic action upon cellulose.
  • the degree of esterification also has an effect. Acetylation to the mono-acetate stage only produces a material which is not very amenable to the stretching treatment in the steam or hot water.
  • Saponification may be carried out to such an extent that the materials are insoluble in organic solvents, or it may be interrupted before this stage is reached and while the materials are still soluble in organic solvents, and the process of the present invention is applicable to the sapon'ified materials whether they are soluble or insoluble in organic solvents.
  • Saponifying the ordinary acetone-soluble cellulose acetate filaments and threads to produce a loss in weight of, say, 5% to 10% on the initial weight of the materials, 25 does not produce any marked change in the extent to which the materials may be stretched.
  • the saponification is carried further, say to a loss in weight of 10% or 20% or more, the ability to stretch in the steam or hot water progressively decreases.
  • the process of the present invention is also applicable to the stretching of artificial materials, whether soluble or insoluble in organic solvents, obtained by esterifying or etherifying natural or 35 regenerated cellulose filaments, fibres, foils and other materials while maintaining the materials in their original form, e. g., by acetylating in benzene or other non-solvent liquid.
  • Stretching in the presence of steam or hot 40 water also improves the properties, and particularly the tensile strength of artificial filaments, yarns, foils, films and similar materials obtained by subjecting to esterification or etherification, for example in the presence of ferric chloride, 45 sodium acetate or zinc chloride, artificial filaments, yarns, foils, films and similar materials having a basis of a cellulose ester or ether, and the processes described in the present application are also applicable to such materials.
  • high degrees of stretch may be obtained, e. g., stretches up to several hundreds per cent. Ifi general, the higher the stretch required or the greater the rate of stretching required, the higher will be the temperature of the treatment.
  • the materials to be treated according to the invention may initially have any desired lustre from a high lustre to medium lustre or approximately the lustre of natural silk or even a dull lustre or no lustre at all. Thus, the materials may have a low lustre due to the presence therein of titanium dioxide or other pigments.
  • the stretching operation may be carried out upon the materials during the course of their travel from one point to another, i. e., upon the running materials.
  • the treatment may be applied to a single thread, e. g., during winding from a cake or cheese or bobbin on to a bobbin, or it may be applied to a number of threads simultaneously.
  • threads may be stretched while running from one creel of bobbins to another creel.
  • Example 1 Cellulose acetate yarn having an acetyl content of about 56 to 58% obtained by the acetylation of an ordinary commercial cellulose acetate yarn in the presence, for example, of ferric chloride, sodium acetate or zinc chloride as catalyst is stretched while passing through wet steam at a temperature of 150 to 155 C.
  • Example 2 Cellulose acetate yarn which has been saponified with aqueous methylamine until its acetyl content has been reduced to about 45 to 48% is stretched while passing through hot water at a temperature of to C.
  • Example 3 Cellulose acetate yarn which is insoluble in organic solvents and has been obtained by the acetylation of regenerated cellulose yarn in the presence of, for example, zinc chloride as catalyst, and which contains 1 to 2 acetyl groups per C6H1005 molecule is stretched while passing through wet steam at a temperature of to C.
  • the yarn treated according to each of the above examples has an improved tensile strength.
  • Stretched cellulose derivative materials may be subjected to any desired after-treatment processes.
  • the stretched materials may be treated with shrinking agents to modify their properties, and particularly to improve their extensibility. Suitable processes for this purpose are described in U. S. application S. No. 611,240 filed May 13, 1932.
  • the latent solvents referred to in that specification for example a mixture of methylene chloride and benzene.
  • stretched cellulose ester materials may be subjected to processes of saponification.
  • the saponification may be such as to lead to a relatively small loss in weight, for example sufiicient to give the materials an afilnity for cotton dyestufis, or may be complete or substantially complete, i. e., so as to eliminate all or substantially all of the ester content.
  • the saponification may be effected under such conditions of tension that shrinkage takes place during or immediately after the saponification, this being advantageous from the point of view of the extensibility of the products.
  • Such further treatments may be carried out as operations separate from the stretching or may be carried out continuously with stretching.
  • the invention includes a continuous operation which involves first stretching and then shrinking.
  • Process for improving the tenacity of artificial materials which comprises subjecting artificial filaments, yarns, foils, films and similar materials, made of soluble organic derivatives of cellulose which have been rendered insoluble in organic solvents by a change in the number of free hydroxy groups in the organic derivative of cellulose molecule, to a stretching operation in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C.
  • Process for improving the tenacity of artificial materials which comprises subjecting artificial filaments, yarns, foils, films and similar materials, made of soluble organic derivatives of cellulose which have been rendered insoluble in organic solvents by a change in the number of free hydroxy groups in the organic derivative of cellulose molecule, to a stretching operation in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 120 C.
  • Process for improving the tenacity of artificial materials which comprises subjecting artificial filaments, yarns, foils, films and similar materials, insoluble in organic solvents, obtained by the partial saponification of filaments, yarns, foils, films and similar materials made of organic esters of cellulose which are soluble in organic solvents, to a stretching operation in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C.
  • Process for improving the tenacity oi artificial materials which comprises subjecting to a stretching operation, in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C., artificial filaments, yarns, foils, films and similar materials obtained by reacting soluble organic derivative of cellulose filaments, yarns, foils, films and similar materials with an esterifying agent until they are insoluble in organic solvents.
  • Process for improving the tenacity of artificial materials which comprises subjecting to a stretching operation, in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C., artificial filaments, yarns, foils, films and similar materials obtained by reacting soluble organic derivative of cellulose filaments, yarns, foils, films and similar materials with an etherifying agent until they are insoluble in organic solvents.
  • Process for improving the tenacity oi artificial materials which comprises subjecting to a stretching operation, in the presence of an TREATMENT & CHEVMIFCAL MODiFl- CATION OF TEXTILES & FIBERS.
  • agent selected from the group consisting of wet steam and hot water at a temperature above 120 (7., artificial filaments, yarns, foils, films and similar materials obtained by reacting soluble organic derivative of cellulose filaments, yarns, foils, films and similar materials with an etherifying agent until they are insoluble in organic solvents.
  • Process for improving the tenacity of artificial materials which comprises subjecting to a stretching operation, in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C., artificial filaments, yarns, foils, films and similar materials obtained by reacting insoluble cellulose filaments, yarns, foils, films and similar materials with an esteriiying agent, while retaining their insolubility and maintaining the materials in their original form.
  • an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C.
  • Process for improving the tenacity of Search Room artificial materials which comprises subjecting artificial filaments, yarns, foils, films and similar materials made of aliphatic acid esters of cellulose which are insoluble in organic solvents to a stretching operation in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C.
  • Process for improving the tenacity of artificial materials which comprises subjecting to a stretching operation, in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C., artificial filaments, yarns, foils, films and similar materials obtained by reacting soluble organic derivative of cellulose filaments, yarns, foils, films and similar materials with an esterifying agent containing an aliphatic acid radicle until they are insoluble in organic solvents.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Artificial Filaments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Description

Patented Apr. 30, 1940 UNITED STATES Search From;
PATENT OFFICE TREATMENT OF TEXTILE AND OTHER MATERIALS Henry Dreyfus, London, England 9 Claims.
This invention relates to improvements in the treatment of textile and other materials and is more particularly concerned with increasing the tensile strength of certain esterified or etherified cellulose products.
In U. S. Letters Patents Nos. 2,142,721, 2,142,722 and 2,142,909 processes are described for increasing the tensile strength of continuous filaments and threads thereof, of spun yarns and of other materials such as ribbons, foils, films or the like of cellulose acetate or other cellulose ester or ether, which consists in subjecting the materials to a stretching operation in the presence of steam I or in hot Water. Though improvement in the properties can be obtained with dry steam, the steam employed is preferably saturated or wet since the best results are obtained with the steam in this condition. The temperature may, for example, be 110, 120 or 130 C., or more, and
the appropriate pressure may be used either to maintain the steam in a saturated or wet condition or to maintain the water in the liquid state,
for example pressures of 10, 20, 30 pounds or more per square inch above atmospheric pressure.
It has now been found that by stretching the materials in steam or hot water as described in the above specifications an improvement in the tensile strength may be obtained also of artificial filaments, yarns, foils, films and similar materials made of cellulose derivatives which are insoluble in organic solvents. Such materials may be obtained by partially saponifying artificial materials made of cellulose derivatives which are soluble in organic solvents or by the esterification or etherification of natural or regenerated cellulose materials. The stretch obtainable in these materials under any particular conditions of steam or hot water treatment varies with the character of the material under treatment, and particularly with the ester or ether content of the material and with the conditions under which the esterification, etherification or saponificat on has been carried out. For example, regenerated cellulose materials which have been acetylated in suspension (so as not to lose their fibrous form) in presence of hydrolytic agents, for example sulphuric acid, phosphoric acid or strongly acid salts such as bisulphates, zinc chloride, ferric chloride and the like, are more amenable to the stretching treatment than are similar materials which have been acetylated in the presence of catalytic agents such as sodium or potassium acetate or tertiary organic bases which have no substantial hydrolytic action upon cellulose. Similarly, the degree of esterification also has an effect. Acetylation to the mono-acetate stage only produces a material which is not very amenable to the stretching treatment in the steam or hot water. When, however, the acetylation is carried further, say to the di-acetate stage or to a stage between 5 the diand tri-acetates, especially in the presence of hydrolytic agents, a product is produced which is eminently amenable to the stretching treatment in the presence of the steam or in the hot water. Similarly, where a saponified cellulose 10 ester material has been treated, the degree of saponification has a marked efiect upon the extent to which such materials can be stretched in the presence of steam or hot water.
Saponification may be carried out to such an extent that the materials are insoluble in organic solvents, or it may be interrupted before this stage is reached and while the materials are still soluble in organic solvents, and the process of the present invention is applicable to the sapon'ified materials whether they are soluble or insoluble in organic solvents. Saponifying the ordinary acetone-soluble cellulose acetate filaments and threads to produce a loss in weight of, say, 5% to 10% on the initial weight of the materials, 25 does not produce any marked change in the extent to which the materials may be stretched. When, however, the saponification is carried further, say to a loss in weight of 10% or 20% or more, the ability to stretch in the steam or hot water progressively decreases.
The process of the present invention is also applicable to the stretching of artificial materials, whether soluble or insoluble in organic solvents, obtained by esterifying or etherifying natural or 35 regenerated cellulose filaments, fibres, foils and other materials while maintaining the materials in their original form, e. g., by acetylating in benzene or other non-solvent liquid.
Stretching in the presence of steam or hot 40 water also improves the properties, and particularly the tensile strength of artificial filaments, yarns, foils, films and similar materials obtained by subjecting to esterification or etherification, for example in the presence of ferric chloride, 45 sodium acetate or zinc chloride, artificial filaments, yarns, foils, films and similar materials having a basis of a cellulose ester or ether, and the processes described in the present application are also applicable to such materials.
By suitably choosing the conditions of acetylation or other esterification or of etherification or of saponification in the manufacture of the initial materials, high degrees of stretch may be obtained, e. g., stretches up to several hundreds per cent. Ifi general, the higher the stretch required or the greater the rate of stretching required, the higher will be the temperature of the treatment.
The materials to be treated according to the invention may initially have any desired lustre from a high lustre to medium lustre or approximately the lustre of natural silk or even a dull lustre or no lustre at all. Thus, the materials may have a low lustre due to the presence therein of titanium dioxide or other pigments.
The stretching operation may be carried out upon the materials during the course of their travel from one point to another, i. e., upon the running materials. The treatment may be applied to a single thread, e. g., during winding from a cake or cheese or bobbin on to a bobbin, or it may be applied to a number of threads simultaneously. Thus, threads may be stretched while running from one creel of bobbins to another creel. When simultaneously stretching a number of threads, it is advantageous to arrange the threads in parallel alignment in the form of a sheet or, if desired, in the form of two paralle sheets.
Apparatus suitable for the treatment either of threads or yarns or of ribbons, foils, films or the like, is described in U. S. applications S. Nos. 48,084, filed November 4, 1935; 47,798, filed November 1, 1935, and 69,282, filed March 17, 1936.
The following examples illustrate the invention but are not to be regarded as limiting it.
Example 1 Cellulose acetate yarn having an acetyl content of about 56 to 58% obtained by the acetylation of an ordinary commercial cellulose acetate yarn in the presence, for example, of ferric chloride, sodium acetate or zinc chloride as catalyst is stretched while passing through wet steam at a temperature of 150 to 155 C.
Example 2 Cellulose acetate yarn which has been saponified with aqueous methylamine until its acetyl content has been reduced to about 45 to 48% is stretched while passing through hot water at a temperature of to C.
Example 3 Cellulose acetate yarn which is insoluble in organic solvents and has been obtained by the acetylation of regenerated cellulose yarn in the presence of, for example, zinc chloride as catalyst, and which contains 1 to 2 acetyl groups per C6H1005 molecule is stretched while passing through wet steam at a temperature of to C.
The yarn treated according to each of the above examples has an improved tensile strength.
Stretched cellulose derivative materials may be subjected to any desired after-treatment processes. Thus, the stretched materials may be treated with shrinking agents to modify their properties, and particularly to improve their extensibility. Suitable processes for this purpose are described in U. S. application S. No. 611,240 filed May 13, 1932. In particular reference is made to the latent solvents referred to in that specification, for example a mixture of methylene chloride and benzene.
Again, stretched cellulose ester materials may be subjected to processes of saponification. The saponification may be such as to lead to a relatively small loss in weight, for example sufiicient to give the materials an afilnity for cotton dyestufis, or may be complete or substantially complete, i. e., so as to eliminate all or substantially all of the ester content. The saponification may be effected under such conditions of tension that shrinkage takes place during or immediately after the saponification, this being advantageous from the point of view of the extensibility of the products.
Such further treatments may be carried out as operations separate from the stretching or may be carried out continuously with stretching. Thus, for example, the invention includes a continuous operation which involves first stretching and then shrinking.
Having described my invention what I desire to secure by Letters Patent is:
1. Process for improving the tenacity of artificial materials, which comprises subjecting artificial filaments, yarns, foils, films and similar materials, made of soluble organic derivatives of cellulose which have been rendered insoluble in organic solvents by a change in the number of free hydroxy groups in the organic derivative of cellulose molecule, to a stretching operation in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C.
2. Process for improving the tenacity of artificial materials, which comprises subjecting artificial filaments, yarns, foils, films and similar materials, made of soluble organic derivatives of cellulose which have been rendered insoluble in organic solvents by a change in the number of free hydroxy groups in the organic derivative of cellulose molecule, to a stretching operation in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 120 C.
3. Process for improving the tenacity of artificial materials, which comprises subjecting artificial filaments, yarns, foils, films and similar materials, insoluble in organic solvents, obtained by the partial saponification of filaments, yarns, foils, films and similar materials made of organic esters of cellulose which are soluble in organic solvents, to a stretching operation in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C.
4. Process for improving the tenacity oi artificial materials, which comprises subjecting to a stretching operation, in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C., artificial filaments, yarns, foils, films and similar materials obtained by reacting soluble organic derivative of cellulose filaments, yarns, foils, films and similar materials with an esterifying agent until they are insoluble in organic solvents.
5. Process for improving the tenacity of artificial materials, which comprises subjecting to a stretching operation, in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C., artificial filaments, yarns, foils, films and similar materials obtained by reacting soluble organic derivative of cellulose filaments, yarns, foils, films and similar materials with an etherifying agent until they are insoluble in organic solvents.
6. Process for improving the tenacity oi artificial materials, which comprises subjecting to a stretching operation, in the presence of an TREATMENT & CHEVMIFCAL MODiFl- CATION OF TEXTILES & FIBERS.
agent selected from the group consisting of wet steam and hot water at a temperature above 120 (7., artificial filaments, yarns, foils, films and similar materials obtained by reacting soluble organic derivative of cellulose filaments, yarns, foils, films and similar materials with an etherifying agent until they are insoluble in organic solvents.
7. Process for improving the tenacity of artificial materials, which comprises subjecting to a stretching operation, in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C., artificial filaments, yarns, foils, films and similar materials obtained by reacting insoluble cellulose filaments, yarns, foils, films and similar materials with an esteriiying agent, while retaining their insolubility and maintaining the materials in their original form.
8. Process for improving the tenacity of Search Room artificial materials, which comprises subjecting artificial filaments, yarns, foils, films and similar materials made of aliphatic acid esters of cellulose which are insoluble in organic solvents to a stretching operation in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C.
9. Process for improving the tenacity of artificial materials, which comprises subjecting to a stretching operation, in the presence of an agent selected from the group consisting of wet steam and hot water at a temperature above 100 C., artificial filaments, yarns, foils, films and similar materials obtained by reacting soluble organic derivative of cellulose filaments, yarns, foils, films and similar materials with an esterifying agent containing an aliphatic acid radicle until they are insoluble in organic solvents.
HENRY names.
US105927A 1935-11-08 1936-10-16 Treatment of textile and other materials Expired - Lifetime US2198660A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2447567A (en) * 1944-10-17 1948-08-24 Dreyfus Camille Stretching of cellulose ester yarn
US2862785A (en) * 1953-01-01 1958-12-02 British Celanese Cellulose triacetate fabrics of improved safe ironing temperature and process of heat treatment to obtain said fabrics
US2925641A (en) * 1956-02-09 1960-02-23 Deering Milliken Res Corp Method for processing cellulose ester yarns
US2976601A (en) * 1955-10-07 1961-03-28 Celanese Corp Production of a cellulose staple fiber batting
US2993749A (en) * 1958-05-23 1961-07-25 William G Sloan Cellulose esters with dimensional stability
US3012396A (en) * 1955-07-05 1961-12-12 Celanese Corp Process for producing voluminous yarn
US3025128A (en) * 1953-11-25 1962-03-13 British Celanese Process for increasing the crystallinity and safe ironing temperature of cellulose triacetate textiles with aromatic chemical swelling agents

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2447567A (en) * 1944-10-17 1948-08-24 Dreyfus Camille Stretching of cellulose ester yarn
US2862785A (en) * 1953-01-01 1958-12-02 British Celanese Cellulose triacetate fabrics of improved safe ironing temperature and process of heat treatment to obtain said fabrics
US3025128A (en) * 1953-11-25 1962-03-13 British Celanese Process for increasing the crystallinity and safe ironing temperature of cellulose triacetate textiles with aromatic chemical swelling agents
US3012396A (en) * 1955-07-05 1961-12-12 Celanese Corp Process for producing voluminous yarn
US2976601A (en) * 1955-10-07 1961-03-28 Celanese Corp Production of a cellulose staple fiber batting
US2925641A (en) * 1956-02-09 1960-02-23 Deering Milliken Res Corp Method for processing cellulose ester yarns
US2993749A (en) * 1958-05-23 1961-07-25 William G Sloan Cellulose esters with dimensional stability

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