US2119876A - Shot - Google Patents

Shot Download PDF

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Publication number
US2119876A
US2119876A US117518A US11751836A US2119876A US 2119876 A US2119876 A US 2119876A US 117518 A US117518 A US 117518A US 11751836 A US11751836 A US 11751836A US 2119876 A US2119876 A US 2119876A
Authority
US
United States
Prior art keywords
shot
aluminum
zinc
lead
spherical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US117518A
Inventor
Corson Michael George
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Remington Arms Co LLC
Original Assignee
Remington Arms Co LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Remington Arms Co LLC filed Critical Remington Arms Co LLC
Priority to US117518A priority Critical patent/US2119876A/en
Application granted granted Critical
Publication of US2119876A publication Critical patent/US2119876A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • C22C18/04Alloys based on zinc with aluminium as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B7/00Shotgun ammunition
    • F42B7/02Cartridges, i.e. cases with propellant charge and missile
    • F42B7/04Cartridges, i.e. cases with propellant charge and missile of pellet type
    • F42B7/046Pellets or shot therefor

Definitions

  • This invention relates to shot as used primarily in shot shells designed for target shooting and game hunting and in air rifles.
  • the present application is a continuation of my prior co-pend- 5 ing application, Serial No. 72,112,1filed April 1, 1936, as to so much of the subject matter as is common to both applications.
  • shot have been made essentially of lead, the lead being alloyed with quantities of such ingredients as antimony and arsenic sufficient to control the hardness and likewise control the fluidity and surface tension characteristics of the molten metal in such a manner as to enable the manufacture of shot by the usual method.
  • This method comprises the melting of the metal, the pouring of. the molten metal through a suitable screen upon which it is formed into droplets of the desired size, which droplets fall through the air a distance of about 120 feet during which they become solid.
  • the falling shot are,-for the purpose of cushioning impact and retaining sphericity, received in a-tank of water; the shot however are fully formed and; substantially hardened prior to impact with the water.
  • Lead shot are subject to certain disadvantages, one of which is the poisoning of wild fowl due to the consumption by the wild fowl of shot which has accumulated .in feeding grounds where a substantial amount of shooting has occurred over a considerable period of time. In-recent years this factor in the maintenance of supplies of game birds, particularly wild fowl, has become of suflicient importance to receive the attention of the United States Biological Survey, as well as 4 the manufacturers of shot, and certain efforts have beenmade to render lead shot non-poisonous.
  • Another disadvantage of lead shot is that, due to the great density of lead,-the shot are for most purposes undesirably heavy. This is par- 'ticularly true of air rifle shot and shot designed for short range use. With a given load of powder,
  • a given number ofpellets of a lighter material may be given a. substantially higher initial velocity, and a charge of such pellets is more effective except at the longer ranges.
  • the present invention contemplates the manufacture by dropping of shot ofanon-poisonous and materially lighter metal, and particularly from a relatively light metallic alloy, It has been found that shot may be dropped from a meltof metal consisting of or more per cent of zinc, the remainder being substantially all aluminum. It is. diflicult to drop shot consisting of zinc exclusively, the difiiculties being due to the ready oxidation of zinc causing the formation of an excessive amount of.
  • a spherical dropped shot suitable for use in. a: shot shell consisting of an alloy containing from 5%, to 5% of aluminum, the remainder being substantially all zinc.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Catching Or Destruction (AREA)

Description

Patented June 7, 1938 SHOT Michael George Corson, New York, N. Y., as signor to Remington Arms Company, Inc., a corporation of Delaware No Drawing.- Application December 24, 1936, Serial No. 117,518
4 Claims.
This invention relates to shot as used primarily in shot shells designed for target shooting and game hunting and in air rifles. The present application is a continuation of my prior co-pend- 5 ing application, Serial No. 72,112,1filed April 1, 1936, as to so much of the subject matter as is common to both applications.
For a great many years shot have been made essentially of lead, the lead being alloyed with quantities of such ingredients as antimony and arsenic sufficient to control the hardness and likewise control the fluidity and surface tension characteristics of the molten metal in such a manner as to enable the manufacture of shot by the usual method. This method comprises the melting of the metal, the pouring of. the molten metal through a suitable screen upon which it is formed into droplets of the desired size, which droplets fall through the air a distance of about 120 feet during which they become solid. At the bottom of the dropping tower the falling shot are,-for the purpose of cushioning impact and retaining sphericity, received in a-tank of water; the shot however are fully formed and; substantially hardened prior to impact with the water. The
enormous numbers of shot manufactured and? used require a manufacturing method of this character, such methods as casting, swaging and rolling being altogether too expensive.
Lead shot are subject to certain disadvantages, one of which is the poisoning of wild fowl due to the consumption by the wild fowl of shot which has accumulated .in feeding grounds where a substantial amount of shooting has occurred over a considerable period of time. In-recent years this factor in the maintenance of supplies of game birds, particularly wild fowl, has become of suflicient importance to receive the attention of the United States Biological Survey, as well as 4 the manufacturers of shot, and certain efforts have beenmade to render lead shot non-poisonous. Another disadvantage of lead shot is that, due to the great density of lead,-the shot are for most purposes undesirably heavy. This is par- 'ticularly true of air rifle shot and shot designed for short range use. With a given load of powder,
a given number ofpellets of a lighter material may be given a. substantially higher initial velocity, and a charge of such pellets is more effective except at the longer ranges.
The present invention contemplates the manufacture by dropping of shot ofanon-poisonous and materially lighter metal, and particularly from a relatively light metallic alloy, It has been found that shot may be dropped from a meltof metal consisting of or more per cent of zinc, the remainder being substantially all aluminum. It is. diflicult to drop shot consisting of zinc exclusively, the difiiculties being due to the ready oxidation of zinc causing the formation of an excessive amount of. dross in the melting kettle 10 and dropping pans, to the attack of the iron of the melting kettle and dropping pans by the active molten zinc, and to the poor surface tension characteristics of zinc, preventing the formation of spherical pellets or causing the break-up of 15 such pellets as have been formed while falling through the tower. The presence of aluminum in amounts up to about 5% has been found beneficialin contr lling both the formation of dross and the attac on the material of the melt containers. Byv regulating the quantity of aluminum beneficial effects on the dropping char-.- acteristics are likewise secured. While aluminum in any quantity up to 5% is beneficial, the optimumaluminum content has been found, to be 25 about 3%. The minimum practicable quantity is about .5 of 1%, it being difficult to secureuniform distribution of aluminum in a lesser amount.
The present invention is believed to constitute the first discovery of the beneficial effects of 0 aluminum in the manufacture of shot and upon the shot themselves; henceflthe appended claims are to be broadly construed. Q
What, is claimed is: p
1. A spherical dropped shot suitable for use in 35 a shot shell consisting of an alloy of zinc and aluminum.
2. A spherical dropped shot suitable for use in a ,shot shell consisting of an alloy of not less than 95% zinc, the remainder being substantially all aluminum. 4o 3. A spherical dropped shot suitable for use in a shot shell consisting of an alloy of substantially 97% zinc, the balance being substantially all aluminum.
4. A spherical dropped shot suitable for use in. a: shot shell consisting of an alloy containing from 5%, to 5% of aluminum, the remainder being substantially all zinc. v
mcnm GEORGE consort.
US117518A 1936-12-24 1936-12-24 Shot Expired - Lifetime US2119876A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US117518A US2119876A (en) 1936-12-24 1936-12-24 Shot

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US117518A US2119876A (en) 1936-12-24 1936-12-24 Shot

Publications (1)

Publication Number Publication Date
US2119876A true US2119876A (en) 1938-06-07

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Family Applications (1)

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2356117A1 (en) * 1976-06-21 1978-01-20 Olin Corp DEGRADABLE HUNTING LEAD AND ITS CYNEGETIC APPLICATIONS
WO1991000491A1 (en) * 1989-06-23 1991-01-10 Brown John E Non-toxic shot and shot shell containing same
US5713981A (en) * 1992-05-05 1998-02-03 Teledyne Industries, Inc. Composite shot
EP0838655A1 (en) * 1996-10-24 1998-04-29 Grillo-Werke AG Shotgun pellet
US6248150B1 (en) 1999-07-20 2001-06-19 Darryl Dean Amick Method for manufacturing tungsten-based materials and articles by mechanical alloying
US6270549B1 (en) 1998-09-04 2001-08-07 Darryl Dean Amick Ductile, high-density, non-toxic shot and other articles and method for producing same
US6527880B2 (en) 1998-09-04 2003-03-04 Darryl D. Amick Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same
US6749802B2 (en) 2002-01-30 2004-06-15 Darryl D. Amick Pressing process for tungsten articles
US20040112243A1 (en) * 2002-01-30 2004-06-17 Amick Darryl D. Tungsten-containing articles and methods for forming the same
US20040216589A1 (en) * 2002-10-31 2004-11-04 Amick Darryl D. Tungsten-containing articles and methods for forming the same
US20050008522A1 (en) * 2001-01-09 2005-01-13 Amick Darryl D. Tungsten-containing articles and methods for forming the same
US20050034558A1 (en) * 2003-04-11 2005-02-17 Amick Darryl D. System and method for processing ferrotungsten and other tungsten alloys, articles formed therefrom and methods for detecting the same
US6884276B2 (en) 2000-01-14 2005-04-26 Darryl D. Amick Methods for producing medium-density articles from high-density tungsten alloys
US7000547B2 (en) 2002-10-31 2006-02-21 Amick Darryl D Tungsten-containing firearm slug
US20070119523A1 (en) * 1998-09-04 2007-05-31 Amick Darryl D Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same
US7399334B1 (en) 2004-05-10 2008-07-15 Spherical Precision, Inc. High density nontoxic projectiles and other articles, and methods for making the same
US20100034686A1 (en) * 2005-01-28 2010-02-11 Caldera Engineering, Llc Method for making a non-toxic dense material
US8122832B1 (en) 2006-05-11 2012-02-28 Spherical Precision, Inc. Projectiles for shotgun shells and the like, and methods of manufacturing the same
US9677860B2 (en) 2011-12-08 2017-06-13 Environ-Metal, Inc. Shot shells with performance-enhancing absorbers
US10260850B2 (en) 2016-03-18 2019-04-16 Environ-Metal, Inc. Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same
US10690465B2 (en) 2016-03-18 2020-06-23 Environ-Metal, Inc. Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same

Cited By (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2356117A1 (en) * 1976-06-21 1978-01-20 Olin Corp DEGRADABLE HUNTING LEAD AND ITS CYNEGETIC APPLICATIONS
WO1991000491A1 (en) * 1989-06-23 1991-01-10 Brown John E Non-toxic shot and shot shell containing same
EP0558161A1 (en) * 1989-06-23 1993-09-01 BROWN, John E. Non-toxic shot and shot shell containing same
AU644370B2 (en) * 1989-06-23 1993-12-09 John E. Brown Non-toxic shot and shot shell containing same
US5713981A (en) * 1992-05-05 1998-02-03 Teledyne Industries, Inc. Composite shot
EP0838655A1 (en) * 1996-10-24 1998-04-29 Grillo-Werke AG Shotgun pellet
US6071359A (en) * 1996-10-24 2000-06-06 Grillo-Werke Ag Shot for use as ammunition
US6270549B1 (en) 1998-09-04 2001-08-07 Darryl Dean Amick Ductile, high-density, non-toxic shot and other articles and method for producing same
US6890480B2 (en) 1998-09-04 2005-05-10 Darryl D. Amick Ductile medium- and high-density, non-toxic shot and other articles and method for producing the same
US6527880B2 (en) 1998-09-04 2003-03-04 Darryl D. Amick Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same
US20030172775A1 (en) * 1998-09-04 2003-09-18 Amick Darryl D. Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same
US7640861B2 (en) 1998-09-04 2010-01-05 Amick Darryl D Ductile medium- and high-density, non-toxic shot and other articles and method for producing the same
US7267794B2 (en) 1998-09-04 2007-09-11 Amick Darryl D Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same
US20070119523A1 (en) * 1998-09-04 2007-05-31 Amick Darryl D Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same
US20050211125A1 (en) * 1998-09-04 2005-09-29 Amick Darryl D Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same
US6527824B2 (en) 1999-07-20 2003-03-04 Darryl D. Amick Method for manufacturing tungsten-based materials and articles by mechanical alloying
US6248150B1 (en) 1999-07-20 2001-06-19 Darryl Dean Amick Method for manufacturing tungsten-based materials and articles by mechanical alloying
US20050188790A1 (en) * 2000-01-14 2005-09-01 Amick Darryl D. Methods for producing medium-density articles from high-density tungsten alloys
US6884276B2 (en) 2000-01-14 2005-04-26 Darryl D. Amick Methods for producing medium-density articles from high-density tungsten alloys
US7329382B2 (en) 2000-01-14 2008-02-12 Amick Darryl D Methods for producing medium-density articles from high-density tungsten alloys
US20050008522A1 (en) * 2001-01-09 2005-01-13 Amick Darryl D. Tungsten-containing articles and methods for forming the same
US7217389B2 (en) 2001-01-09 2007-05-15 Amick Darryl D Tungsten-containing articles and methods for forming the same
US6749802B2 (en) 2002-01-30 2004-06-15 Darryl D. Amick Pressing process for tungsten articles
US6823798B2 (en) 2002-01-30 2004-11-30 Darryl D. Amick Tungsten-containing articles and methods for forming the same
US20040112243A1 (en) * 2002-01-30 2004-06-17 Amick Darryl D. Tungsten-containing articles and methods for forming the same
US7000547B2 (en) 2002-10-31 2006-02-21 Amick Darryl D Tungsten-containing firearm slug
US7059233B2 (en) 2002-10-31 2006-06-13 Amick Darryl D Tungsten-containing articles and methods for forming the same
US20040216589A1 (en) * 2002-10-31 2004-11-04 Amick Darryl D. Tungsten-containing articles and methods for forming the same
US7383776B2 (en) 2003-04-11 2008-06-10 Amick Darryl D System and method for processing ferrotungsten and other tungsten alloys, articles formed therefrom and methods for detecting the same
US20050034558A1 (en) * 2003-04-11 2005-02-17 Amick Darryl D. System and method for processing ferrotungsten and other tungsten alloys, articles formed therefrom and methods for detecting the same
US7399334B1 (en) 2004-05-10 2008-07-15 Spherical Precision, Inc. High density nontoxic projectiles and other articles, and methods for making the same
US7422720B1 (en) 2004-05-10 2008-09-09 Spherical Precision, Inc. High density nontoxic projectiles and other articles, and methods for making the same
US20100034686A1 (en) * 2005-01-28 2010-02-11 Caldera Engineering, Llc Method for making a non-toxic dense material
US8122832B1 (en) 2006-05-11 2012-02-28 Spherical Precision, Inc. Projectiles for shotgun shells and the like, and methods of manufacturing the same
US9677860B2 (en) 2011-12-08 2017-06-13 Environ-Metal, Inc. Shot shells with performance-enhancing absorbers
US9897424B2 (en) 2011-12-08 2018-02-20 Environ-Metal, Inc. Shot shells with performance-enhancing absorbers
US10209044B2 (en) 2011-12-08 2019-02-19 Environ-Metal, Inc. Shot shells with performance-enhancing absorbers
US10260850B2 (en) 2016-03-18 2019-04-16 Environ-Metal, Inc. Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same
US10690465B2 (en) 2016-03-18 2020-06-23 Environ-Metal, Inc. Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same
US11280597B2 (en) 2016-03-18 2022-03-22 Federal Cartridge Company Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same
US11359896B2 (en) 2016-03-18 2022-06-14 Federal Cartridge Company Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same

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