US20220235496A1 - Thread - Google Patents
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- US20220235496A1 US20220235496A1 US17/719,024 US202217719024A US2022235496A1 US 20220235496 A1 US20220235496 A1 US 20220235496A1 US 202217719024 A US202217719024 A US 202217719024A US 2022235496 A1 US2022235496 A1 US 2022235496A1
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- 239000000835 fiber Substances 0.000 claims abstract description 261
- 239000004626 polylactic acid Substances 0.000 claims description 22
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 19
- 230000003068 static effect Effects 0.000 claims description 3
- 230000005684 electric field Effects 0.000 description 27
- 241000233866 Fungi Species 0.000 description 16
- 230000000843 anti-fungal effect Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000004744 fabric Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 230000035755 proliferation Effects 0.000 description 4
- 238000010008 shearing Methods 0.000 description 4
- RBMHUYBJIYNRLY-UHFFFAOYSA-N 2-[(1-carboxy-1-hydroxyethyl)-hydroxyphosphoryl]-2-hydroxypropanoic acid Chemical compound OC(=O)C(O)(C)P(O)(=O)C(C)(O)C(O)=O RBMHUYBJIYNRLY-UHFFFAOYSA-N 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229920001434 poly(D-lactide) Polymers 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 210000004243 sweat Anatomy 0.000 description 3
- 206010027476 Metastases Diseases 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000009401 metastasis Effects 0.000 description 2
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- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
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- 210000000805 cytoplasm Anatomy 0.000 description 1
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- 238000010438 heat treatment Methods 0.000 description 1
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- 230000000813 microbial effect Effects 0.000 description 1
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- 229920001778 nylon Polymers 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000005616 pyroelectricity Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- UQDJGEHQDNVPGU-UHFFFAOYSA-N serine phosphoethanolamine Chemical compound [NH3+]CCOP([O-])(=O)OCC([NH3+])C([O-])=O UQDJGEHQDNVPGU-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/449—Yarns or threads with antibacterial properties
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/38—Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
- D10B2331/041—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET] derived from hydroxy-carboxylic acids, e.g. lactones
Definitions
- the present invention relates to a thread formed by twisting different fibers.
- the fibers having antifungal properties are, for example, charge generating fibers that exhibit antifungal properties by charge generated by a piezoelectric effect.
- the piezoelectric thread disclosed in Patent Document 1 is an example of charge generating fiber. When tension is applied to the piezoelectric thread, charge is generated on the surface of the piezoelectric thread, and an electric field is generated in a space formed between fibers by the charge. The piezoelectric thread exerts an effect such as an antifungal effect by the generated electric field.
- an object of the invention is to provide a thread having a better antifungal effect than a conventional charge generating thread having antifungal properties.
- a thread of the invention includes a first fiber having at least one groove extending in a length direction thereof; and at least one second fiber constructed to generate a potential by external energy.
- the second fiber is disposed in a region corresponding to the groove of the first fiber such that a space is between the first fiber and the second fiber.
- the second fiber is disposed in the region corresponding to the groove of the first fiber, and a space is formed between the first fiber and the second fiber, so that an electric field can be generated in the space.
- the groove is formed in the first fiber, the surface area of the first fiber increases, and a fungus easily adhere to the first fiber.
- the thread including the first fiber and the second fiber exhibits a good antifungal effect.
- a thread that gives a space in which a good electric field is generated can be realized.
- FIG. 1(A) is a view illustrating a configuration of a thread according to one embodiment of the present invention.
- FIG. 1(B) is a sectional view taken along the line I-I in FIG. 1(A) .
- FIG. 1(C) is a view illustrating applying a twist to a first fiber and second fibers of the thread.
- FIGS. 2(A) to 2(C) are views showing a sectional shape of the first fiber, respectively.
- FIGS. 3(A) and 3(B) are views showing a relation among deformation, a uniaxial stretching direction, and an electric field direction of a second fiber when the second fiber is a polylactic acid (PLLA) uniaxially stretched.
- PLLA polylactic acid
- FIG. 4(A) is a view illustrating a configuration of a thread according to one embodiment of the invention.
- FIG. 4(B) is a sectional view taken along the line II-II of FIG. 4(A) .
- FIG. 4(C) is a view illustrating applying a twist to a first fiber and a second fiber of the thread.
- FIG. 5 is a view illustrating an electric field in a thread.
- FIG. 6 is a sectional view of a thread according to one embodiment of the invention.
- FIG. 7 is a sectional view of a thread according to one embodiment of the invention.
- FIG. 1(A) is a view illustrating a configuration of a thread 1 according to one embodiment of the invention.
- FIG. 1(B) is a sectional view taken along the line I-I in FIG. 1(A) .
- FIG. 1(C) is a view illustrating applying a twist to a first fiber 10 and second fibers 20 of the thread 1 .
- the thread 1 is composed of a first fiber 10 and second fibers 20 .
- the first fiber 10 has at least one a groove 12 extending in a length direction, and is surrounded by a plurality of second fibers 20 .
- charge is generated.
- the second fibers 20 are disposed to fit within the groove 12 of the first fiber 10 , and are twisted together with the first fiber 10 .
- FIG. 1(B) as an example, a cross section of one first fiber 10 and six second fibers 20 is illustrated in a cross section taken along the line I-I, but the number of first fibers 10 and the number of second fibers 20 are not limited to this, and are actually set as appropriate in consideration of the application and the like.
- the thread 1 of the embodiment When the thread 1 of the embodiment receives external energy (for example, when a tension is applied in an axial direction of the thread 1 ), charge is generated, and an electric field is generated. Alternatively, when the thread 1 receiving external energy is brought close to a thing having a predetermined potential (including a ground potential) such as a human body, an electric field is also generated between the thread 1 and the thing. When the thread 1 receives external energy and is close to a thing having a predetermined potential (including a ground potential) such as a human body, a current flows between the thread 1 of the present invention and the thing through a liquid such as sweat.
- a predetermined potential including a ground potential
- Disruption of a cell of a fungus and degeneration of the cytoplasm occur by an electric field or an electric current. Therefore, the cell of the fungus and the electron transmission system for maintaining the life of the fungus are disturbed, and the fungus is killed or the fungus itself is weakened.
- oxygen contained in a liquid such as sweat or water may be changed into an active oxygen species by an electric field or a current. Active oxygen species includes an oxygen radical, and these effects kill or weaken a fungus.
- the thread 1 has a remarkable antifungal effect.
- the “antifungal effect” is a concept including both an effect of killing a fungus and an effect of weakening a fungus.
- the first fiber 10 is a modified cross-section fiber (modified filament) made of a fiber material such as a polyester, a nylon, or an acrylic.
- FIGS. 2(A) to 2(C) are views showing a sectional shape of the first fiber 10 , respectively.
- the sectional shape of the first fiber 10 is a cross shape, a star polygon, or a concave polygon.
- the first fiber 10 has the groove 12 and protrusion 14 extending in the longitudinal direction.
- the second fiber 20 is made of, for example, a piezoelectric polymer.
- the piezoelectric polymer include a polyvinylidene fluoride (PVDF) and a polylactic acid (PLA), and any of them can be used as a raw material of the second fiber 20 .
- the polylactic acid (PLA) is a piezoelectric polymer having no pyroelectricity. The polylactic acid is uniaxially stretched to generate piezoelectricity.
- the polylactic acid includes PLLA having a right-handed helical structure obtained by polymerizing an L-form monomer and PDLA having a left-handed helical structure obtained by polymerizing a D-form monomer and having a polarity of a piezoelectric constant opposite to that of PLLA.
- FIGS. 3(A) and 3(B) are views showing a relation among deformation, a uniaxial stretching direction, and an electric field direction of the second fiber 20 when the second fiber 20 is a polylactic acid (PLLA) uniaxially stretched.
- FIGS. 3(A) and 3(B) are views when the second fiber 20 is assumed to have a film shape as a model case.
- the second fiber 20 is a circular cross section fiber (circular filament).
- the polylactic acid (PLA) is a chiral polymer, and its main chain has a helical structure.
- PLA polylactic acid
- the second fiber 20 made of a uniaxially stretched polylactic acid has a tensor component of d 14 and d 25 as the piezoelectric strain constant when a thickness direction is defined as a first axis, a stretching direction 900 is defined as a third axis, and a direction orthogonal to both the first axis and the third axis is defined as a second axis. Therefore, when the second fiber 20 made of a uniaxially stretched polylactic acid is distorted in a direction of 45 degrees with respect to the uniaxially stretched direction, charge is generated.
- the polylactic acid has piezoelectricity due to orientation of molecules by stretching, and thus does not need poling unlike other piezoelectric polymers such as PVDF or piezoelectric ceramics.
- the piezoelectric constant of the uniaxially stretched polylactic acid is about 5 to 30 pC/N, and has a very high piezoelectric constant among polymers. Furthermore, the piezoelectric constant of the polylactic acid does not vary with time and is extremely stable.
- the second fibers 20 having the characteristics are twisted together with the first fiber 10 to the left to obtain the thread 1 .
- the thread 1 is S-twisted (right-twisted).
- the stretching direction (length direction) 900 of each second fiber 20 is inclined obliquely with respect to the stretching direction of the thread 1 .
- the stretching direction 900 of the second fibers 20 is inclined to the left on the paper surface with respect to the stretching direction of the thread 1 .
- the angle (twist angle of the second fibers 20 ) between stretching direction 900 of the second fibers 20 and the stretching direction of the thread 1 is preferably 45 degrees.
- the second fibers 20 are stretched along the axial direction of the thread 1 , and are shrunk along the width direction of the thread 1 . Therefore, the axial direction of the thread 1 corresponds to the second diagonal line 910 B illustrated in FIG. 3(A) , and the width direction of the thread 1 corresponds to the first diagonal line 910 A illustrated in FIG. 3(A) .
- the angle (twist angle of the second fibers 20 ) between stretching direction 900 of the second fibers 20 and the stretching direction of the thread 1 is preferably 45 degrees.
- the second fiber 20 stretches in the direction corresponding to the second diagonal line 910 B and shrinks in the direction corresponding to the direction of the first diagonal line 910 A. Therefore, a negative charge is generated on the surface of the second fiber 20 , and a positive charge is generated on the inner side. That is, in the second fiber 20 , charge is generated by external energy.
- the inclination of the second fiber 20 with respect to the axial direction of the thread 1 is not limited to 45 degrees to the left.
- the stretching direction 900 of the second fiber 20 may cross at least the axial direction of the thread 1 .
- the twist angle of the second fiber 20 may be larger than 0 degrees and smaller than 90 degrees to the left.
- the twist angle of the second fiber 20 approaches 45 degrees to the left, the charge generation efficiency is improved.
- the thread is used for knitted fabrics, textile fabrics, and sewing, and the direction in which the thread extends may not be constant. That is, since an external force is not necessarily applied in the long axis direction of the thread, the twist angle of the second fiber 20 is not limited to the above.
- the surface area of the first fiber 10 is larger than that of a fiber having no groove, and the possibility that fungus adheres to the first fiber 10 is relatively high.
- the groove 12 extends helically.
- the shape of the groove 12 is a shape along a surface of the second fiber 20 . In such a configuration, when the second fiber 20 is twisted, the second fiber 20 is twisted along the groove 12 of the first fiber 10 . In other words, the second fiber 20 is twisted while being guided by the groove 12 of the first fiber 10 .
- the opening width of the groove 12 is substantially equal to or larger 20 than the diameter length of the second fiber 20 .
- a space SP is formed between the groove 12 of the first fiber 10 and the second fiber 20 disposed in the region formed in the groove 12 .
- the cross section of the groove 12 is V-shaped, but the cross section of the second fiber 20 is circular form. Therefore, since the second fiber 20 and the groove 12 are not engaged exactly with each other, the space SP is generated. With such a space SP, a leakage electric field is likely to be formed. Therefore, the thread 1 exerts a good antifungal effect.
- the shape of the space SP can be changed by changing the shape of the groove 12 of the first fiber 10 , and the optimum leakage electric field can be changed in combination with the second fiber 20 .
- the cross section of the space SP is smaller than the cross section of the thread 1 .
- the space SP may be smaller than the cross section of the first fiber 10 or smaller than the cross section of the second fiber 20 .
- FIG. 4(A) is a view illustrating a configuration of a thread 2 according to one embodiment of the invention.
- FIG. 4(B) is a sectional view taken along line II-II of FIG. 4(A) .
- FIG. 4(C) is a view illustrating applying a twist to a first fiber 10 and second fibers 20 of the thread 2 .
- the second fibers 20 are twisted rightward together with the first fiber 10 . That is, the thread 2 is Z-twisted (left-twisted).
- the stretching direction 900 of the second fibers 20 is inclined to the right on the paper surface with respect to the stretching direction of the thread 2 .
- the angle between the stretching direction 900 of the second fiber 20 and the stretching direction of the thread 2 is ideally preferably 45 degrees.
- the second fibers 20 are stretched along the axial direction of the thread 2 , and are shrunk along the width direction of the thread 2 . Therefore, the stretching direction of the thread 2 corresponds to the first diagonal line 910 A illustrated in FIG. 3(B) , and the width direction of the thread 2 corresponds to the second diagonal line 910 B illustrated in FIG. 3(B) .
- the stretching direction of the thread 2 corresponds to the first diagonal line 910 A illustrated in FIG. 3(B)
- the width direction of the thread 2 corresponds to the second diagonal line 910 B illustrated in FIG. 3(B) .
- the second fiber 20 stretches in the direction corresponding to the first diagonal line 910 A and shrinks in the direction corresponding to the direction of the second diagonal line 910 B. Therefore, a positive charge is generated on the surface of the thread 2 , and a negative charge is generated on the inner side.
- the inclination with respect to the stretching direction of the thread 2 is not limited to 45 degrees to the right, and may at least intersect with the stretching direction of the thread 2 .
- the twist angle of the second fiber 20 approaches 45 degrees to the right, the charge generation efficiency is improved.
- the groove 12 of the first fiber 10 is a V-shaped groove, and a surface of the second fiber 20 is arcuate. That is, the shape of the groove 12 of the first fiber 10 is a shape that is not along the surface of the second fiber 20 .
- the shape of the groove 12 of the first fiber 10 may be a shape along the surface of the second fiber 20 .
- the groove 12 of the first fiber 10 is a semicircular groove, and the surface of the second fiber 20 is arcuate.
- the thread is used for knitted fabrics, textile fabrics, and sewing, and the direction in which the thread extends may not be constant. That is, since an external force is not necessarily applied in the long axis direction of the thread, the twist angle of the second fiber 20 is not limited to the above.
- the thread 2 has the same good antifungal effect as the thread 1 .
- FIG. 5 is a view illustrating an electric field in the thread 1 and the thread 2 .
- the surface In the thread 1 alone, the surface has a negative potential and the inside has a positive potential when tension is applied. In the thread 2 alone, the surface has a positive potential and the inside has a negative potential when tension is applied.
- the close portions When the thread 1 and the thread 2 are brought close to each other, the close portions (surfaces) tend to have the same potential. In this case, the proximity portion between the thread 1 and the thread 2 becomes 0 V, and the positive potential inside the thread 1 is further increased so as to maintain the original potential difference. Similarly, the negative potential inside the thread 2 is further lowered.
- An electric field directed mainly from the inside to the outside of the thread 1 is formed in the cross section of the thread 1
- an electric field directed mainly from the outside to the inside the thread 2 is formed in the cross section of the thread 2 .
- these electric fields leak out into the air and are synthesized, and an electric field is formed by a potential difference between the thread 1 and the thread 2 as illustrated in FIG. 5 .
- an electric field is generated between the thread 1 (or the thread 2 ) and the thing close to the thread 1 (or the thread 2 ).
- a current may flow through a current path formed by moisture between the thread 1 and the thread 2 , or a circuit formed by a micro discharge phenomenon. Even when the thread 1 or the thread 2 and a thing having a predetermined potential close to each other are brought close to each other, a current may flow through a current path formed by moisture, or a circuit formed by a micro discharge phenomenon.
- the thread 1 and the thread 2 do not need to have potentials of opposite polarity. Even if the thread 1 and the thread 2 have potentials of the same polarity, an electric field or a current is generated if there is a potential difference between them. That is, the thread 1 and the thread 2 may have different potentials when charges are generated.
- a Z thread using PDLA is also conceivable in addition to an S thread using PLLA.
- the S thread using PDLA is also conceivable in addition to the Z thread using PLLA.
- the second fiber 20 contains the polylactic acid.
- the first fiber 10 may also contain the polylactic acid. Then, when the first fiber 10 is twisted, charge is generated.
- FIG. 6 is a sectional view of a thread according to one embodiment of the invention. As shown in FIG. 6 , a plurality of first fibers 10 are disposed so as to be surrounded by second fibers 20 . The bundle of first fibers 10 has more grooves 12 than the single first fiber 10 . In such a configuration, when the first fibers 10 and the second fibers 20 are twisted, the bundle of the first fibers 10 can guide more the second fibers 20 .
- the first fiber 10 and the second fiber 20 are long fibers (filaments), and the thread 1 and the thread 2 are twisted threads made of long fibers.
- the thread 1 and thread 2 are not limited to the twisted threads made of long fibers.
- the first fiber 10 and the second fiber 20 may be short fibers (spans), and the thread 1 and the thread 2 may be spun threads made of short fibers.
- the first fiber 10 and the second fiber 20 may be long fibers and short fibers (or short fibers and long fibers), respectively, and the thread 1 and the thread 2 may be twisted threads made of two types of fibers.
- the first fibers 10 are heteromorphic modified cross-section fibers (modified filaments) and the second fibers 20 are circular cross-section fibers (circular filaments).
- the second fibers 20 are not limited to the circular cross-section fibers.
- the second fibers 20 are a modified cross-section fibers like the first fibers 10 .
- both the first fiber 10 and the second fiber 20 may be charge generating fibers that generate charge. Furthermore, when both the first fiber 10 and the second fiber 20 are charge generating fibers, either one may have a lower elastic modulus than the other, and when only one of the first fiber 10 and the second fiber 20 is charge generating fiber, the other may have a lower elastic modulus than the one. In this case, since the fiber has a low elastic modulus, the thread tends to stretch, and the shearing stress tends to be applied to the charge generating fiber.
- both of the first fiber 10 and the second fiber 20 are charge generating fibers
- either one may have a lower coefficient of static friction than the other, and when only one of the first fiber 10 and the second fiber 20 is charge generating fiber, the other may have a higher coefficient of static friction. In this case, the shearing stress tends to be applied to the charge generating fiber.
- FIG. 7 is a sectional view of a thread 3 according to one embodiment of the invention.
- a thread 3 is composed of the first fiber 10 and the second fiber 20 which are modified cross-section fibers, and the first fiber 10 and the second fiber 20 have the same sectional shape.
- the first fiber 10 and the second fibers 20 in the thread 3 may have different sectional shapes.
- the second fiber 20 has at least one protrusion 24 extending in the length direction.
- the second fiber 20 is disposed such that the protrusion 24 of the second fiber 20 engages with the groove 12 of the first fiber 10 .
- the protrusion 24 of the second fiber 20 is twisted along the groove 12 of the first fiber 10 , and extends helically. That is, the second fiber 20 is twisted while being guided by the groove 12 of the first fiber 10 .
- the thread 3 is S-twisted or Z-twisted depending on the direction of twisting.
- the twist angle of the second fiber 20 can be made close to a desired angle (45 degrees to the left or 45 degrees to the right), and the thread 3 can be made into a medium twisted thread or a hard twisted thread. Since the shape and size of the internal space of the groove 12 do not exactly fit the shape and size of the protrusion 24 , the space SP exists between the first fiber 10 and the second fiber 20 . Therefore, a leakage electric field is easily formed.
- Such a thread 3 has the same good antifungal effect as the thread 1 and the thread 2 .
- the groove 12 of the first fiber 10 is parallel to the length direction of the first fiber 10 as shown in FIG. 1(C) .
- the groove 12 is not limited to the linear groove.
- the groove 12 of the first fiber 10 is a groove formed in a helical shape with respect to the axial direction of the first fiber 10 .
- the number of turns and the helical angle of the second fiber 20 are determined by the installation state of the helical groove. Therefore, if the number of turns and the helical angle are appropriate, the thread obtained in this embodiment can also exhibit a good antifungal effect.
- the above-mentioned threads can be applied to daily life products such as medical parts and clothing.
- the thread can be applied to a mask, underwear (in particular, socks), a towel, insoles such as shoes and boots, sportswear in general, a hat, bedding (bedclothes, a mattress, a sheet, a pillow, a pillow cover, and the like), a toothbrush, a froth, a water purifier, a filter for an air conditioner or an air cleaner, a stuffed toy, a pet-related product (a mat for a pet, clothing for a pet, and an innerwear for a pet), various mat products (a foot, a hand, and a toilet seat), s curtain, s kitchen utensil (s sponge or s cloth), seats (a seats for a car, a train, an airplane, etc.), a cushioning material for a mask, underwear (in particular, socks), a towel, insoles such as shoes and boots, sportswear in general, a hat
- socks or supporters always expand and contract along a joint by movement such as walking, and thus the thread (thread 1 , thread 2 , thread 3 , etc.) generates charge with high frequency.
- socks absorb moisture such as sweat and become a hotbed for proliferation of a fungus, but the threads (thread 1 , thread 2 , thread 3 , etc.) can suppress proliferation of a fungus, and thus exert a remarkable effect as a fungus-countermeasure application for odor prevention.
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- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
A thread that includes a first fiber having at least one groove extending in a length direction thereof; and at least one second fiber constructed to generate a potential by external energy. The second fiber is disposed in a region corresponding to the groove of the first fiber such that a space is between the groove of the first fiber and the second fiber.
Description
- The present application is a continuation of International application No. PCT/JP2020/043598, filed Nov. 24, 2020, which claims priority to Japanese Patent Application No. 2019-212975, filed Nov. 26, 2019, the entire contents of each of which are incorporated herein by reference.
- The present invention relates to a thread formed by twisting different fibers.
- In recent years, in order to realize a comfortable and healthy life style, various daily life products with improved comfort, health, or hygiene have been devised. In particular, clothing made of fibers having antifungal properties have been devised. The fibers having antifungal properties are, for example, charge generating fibers that exhibit antifungal properties by charge generated by a piezoelectric effect. The piezoelectric thread disclosed in
Patent Document 1 is an example of charge generating fiber. When tension is applied to the piezoelectric thread, charge is generated on the surface of the piezoelectric thread, and an electric field is generated in a space formed between fibers by the charge. The piezoelectric thread exerts an effect such as an antifungal effect by the generated electric field. - Patent Document 1: International Publication No. 2017/212836
- There is room for improvement in a conventional charge generating fiber in terms of constraining a fungus in the vicinity of the space where an electric field is generated.
- Therefore, an object of the invention is to provide a thread having a better antifungal effect than a conventional charge generating thread having antifungal properties.
- A thread of the invention includes a first fiber having at least one groove extending in a length direction thereof; and at least one second fiber constructed to generate a potential by external energy. The second fiber is disposed in a region corresponding to the groove of the first fiber such that a space is between the first fiber and the second fiber.
- In the thread of the invention, the second fiber is disposed in the region corresponding to the groove of the first fiber, and a space is formed between the first fiber and the second fiber, so that an electric field can be generated in the space. In addition, since the groove is formed in the first fiber, the surface area of the first fiber increases, and a fungus easily adhere to the first fiber. Thus, the thread including the first fiber and the second fiber exhibits a good antifungal effect.
- According to the present invention, a thread that gives a space in which a good electric field is generated can be realized.
-
FIG. 1(A) is a view illustrating a configuration of a thread according to one embodiment of the present invention.FIG. 1(B) is a sectional view taken along the line I-I inFIG. 1(A) .FIG. 1(C) is a view illustrating applying a twist to a first fiber and second fibers of the thread. -
FIGS. 2(A) to 2(C) are views showing a sectional shape of the first fiber, respectively. -
FIGS. 3(A) and 3(B) are views showing a relation among deformation, a uniaxial stretching direction, and an electric field direction of a second fiber when the second fiber is a polylactic acid (PLLA) uniaxially stretched. -
FIG. 4(A) is a view illustrating a configuration of a thread according to one embodiment of the invention.FIG. 4(B) is a sectional view taken along the line II-II ofFIG. 4(A) .FIG. 4(C) is a view illustrating applying a twist to a first fiber and a second fiber of the thread. -
FIG. 5 is a view illustrating an electric field in a thread. -
FIG. 6 is a sectional view of a thread according to one embodiment of the invention. -
FIG. 7 is a sectional view of a thread according to one embodiment of the invention. -
FIG. 1(A) is a view illustrating a configuration of athread 1 according to one embodiment of the invention.FIG. 1(B) is a sectional view taken along the line I-I inFIG. 1(A) .FIG. 1(C) is a view illustrating applying a twist to afirst fiber 10 andsecond fibers 20 of thethread 1. - The
thread 1 is composed of afirst fiber 10 andsecond fibers 20. Thefirst fiber 10 has at least one agroove 12 extending in a length direction, and is surrounded by a plurality ofsecond fibers 20. When energy is applied to thesecond fibers 20, charge is generated. In thethread 1 of the present embodiment, thesecond fibers 20 are disposed to fit within thegroove 12 of thefirst fiber 10, and are twisted together with thefirst fiber 10. InFIG. 1(B) , as an example, a cross section of onefirst fiber 10 and sixsecond fibers 20 is illustrated in a cross section taken along the line I-I, but the number offirst fibers 10 and the number ofsecond fibers 20 are not limited to this, and are actually set as appropriate in consideration of the application and the like. - Conventionally, it has been known that proliferation and metastasis of a bacterium, a fungus, and the like can be suppressed by an electric field (See, for example, Tetsuaki Tsuchido, Hiroki Kourai, Hideaki Matsuoka, Junichi Koizumi, Kodansha: Microbial Control—Science and Engineering. In addition, see, for example, Koichi Takaki, Application of High Voltage and Plasma Technology to Agricultural and Food Field, J. HTSJ, Vol. 51, No. 216). In addition, a potential generating the electric field may cause a current to flow through a current path formed by moisture or a circuit formed by a micro discharge phenomenon. It is considered that this current weakens a fungus and suppresses proliferation and metastasis of the fungus.
- When the
thread 1 of the embodiment receives external energy (for example, when a tension is applied in an axial direction of the thread 1), charge is generated, and an electric field is generated. Alternatively, when thethread 1 receiving external energy is brought close to a thing having a predetermined potential (including a ground potential) such as a human body, an electric field is also generated between thethread 1 and the thing. When thethread 1 receives external energy and is close to a thing having a predetermined potential (including a ground potential) such as a human body, a current flows between thethread 1 of the present invention and the thing through a liquid such as sweat. - Disruption of a cell of a fungus and degeneration of the cytoplasm occur by an electric field or an electric current. Therefore, the cell of the fungus and the electron transmission system for maintaining the life of the fungus are disturbed, and the fungus is killed or the fungus itself is weakened. In addition, oxygen contained in a liquid such as sweat or water may be changed into an active oxygen species by an electric field or a current. Active oxygen species includes an oxygen radical, and these effects kill or weaken a fungus. Thus, the
thread 1 has a remarkable antifungal effect. In the present description, the “antifungal effect” is a concept including both an effect of killing a fungus and an effect of weakening a fungus. - In the embodiment, the
first fiber 10 is a modified cross-section fiber (modified filament) made of a fiber material such as a polyester, a nylon, or an acrylic.FIGS. 2(A) to 2(C) are views showing a sectional shape of thefirst fiber 10, respectively. As illustrated inFIGS. 2(A) to 2(C) , the sectional shape of thefirst fiber 10 is a cross shape, a star polygon, or a concave polygon. In any example, thefirst fiber 10 has thegroove 12 andprotrusion 14 extending in the longitudinal direction. - Furthermore, in the embodiment, the
second fiber 20 is made of, for example, a piezoelectric polymer. Examples of the piezoelectric polymer include a polyvinylidene fluoride (PVDF) and a polylactic acid (PLA), and any of them can be used as a raw material of thesecond fiber 20. Among them, the polylactic acid (PLA) is a piezoelectric polymer having no pyroelectricity. The polylactic acid is uniaxially stretched to generate piezoelectricity. The polylactic acid includes PLLA having a right-handed helical structure obtained by polymerizing an L-form monomer and PDLA having a left-handed helical structure obtained by polymerizing a D-form monomer and having a polarity of a piezoelectric constant opposite to that of PLLA. -
FIGS. 3(A) and 3(B) are views showing a relation among deformation, a uniaxial stretching direction, and an electric field direction of thesecond fiber 20 when thesecond fiber 20 is a polylactic acid (PLLA) uniaxially stretched.FIGS. 3(A) and 3(B) are views when thesecond fiber 20 is assumed to have a film shape as a model case. In the embodiment, thesecond fiber 20 is a circular cross section fiber (circular filament). - The polylactic acid (PLA) is a chiral polymer, and its main chain has a helical structure. When the polylactic acid is uniaxially stretched and molecules are oriented, piezoelectricity appears. When heat treatment is further performed to increase the crystallinity, the piezoelectric constant increases. The
second fiber 20 made of a uniaxially stretched polylactic acid has a tensor component of d14 and d25 as the piezoelectric strain constant when a thickness direction is defined as a first axis, a stretchingdirection 900 is defined as a third axis, and a direction orthogonal to both the first axis and the third axis is defined as a second axis. Therefore, when thesecond fiber 20 made of a uniaxially stretched polylactic acid is distorted in a direction of 45 degrees with respect to the uniaxially stretched direction, charge is generated. - As shown in
FIG. 3(A) , when thesecond fiber 20 shrinks in the direction of the firstdiagonal line 910A and extends in the direction of the seconddiagonal line 910B orthogonal to the firstdiagonal line 910A, an electric field is generated in a direction from the back side to the front side of the paper surface. That is, in the state ofFIG. 3(A) , a negative charge is generated on the front side of the paper surface. As shown inFIG. 3(B) , when thesecond fiber 20 extends in the direction of the firstdiagonal line 910A and shrinks in the direction of the seconddiagonal line 910B, charge is also generated. In this case, the polarity is reversed, and an electric field is generated in a direction from the surface to the back side of the paper surface. That is, in the state ofFIG. 3(B) , a positive charge is generated on the front side of the paper surface. - The polylactic acid has piezoelectricity due to orientation of molecules by stretching, and thus does not need poling unlike other piezoelectric polymers such as PVDF or piezoelectric ceramics. The piezoelectric constant of the uniaxially stretched polylactic acid is about 5 to 30 pC/N, and has a very high piezoelectric constant among polymers. Furthermore, the piezoelectric constant of the polylactic acid does not vary with time and is extremely stable.
- As illustrated in
FIG. 1(C) , thesecond fibers 20 having the characteristics are twisted together with thefirst fiber 10 to the left to obtain thethread 1. Thethread 1 is S-twisted (right-twisted). InFIG. 1(A) , since the plurality ofsecond fibers 20 are twisted, the stretching direction (length direction) 900 of eachsecond fiber 20 is inclined obliquely with respect to the stretching direction of thethread 1. In other words, the stretchingdirection 900 of thesecond fibers 20 is inclined to the left on the paper surface with respect to the stretching direction of thethread 1. - Ideally, the angle (twist angle of the second fibers 20) between stretching
direction 900 of thesecond fibers 20 and the stretching direction of thethread 1 is preferably 45 degrees. When such athread 1 is stretched under tension, thesecond fibers 20 are stretched along the axial direction of thethread 1, and are shrunk along the width direction of thethread 1. Therefore, the axial direction of thethread 1 corresponds to the seconddiagonal line 910B illustrated inFIG. 3(A) , and the width direction of thethread 1 corresponds to the firstdiagonal line 910A illustrated inFIG. 3(A) . As in the example shown inFIG. 3(A) , thesecond fiber 20 stretches in the direction corresponding to the seconddiagonal line 910B and shrinks in the direction corresponding to the direction of the firstdiagonal line 910A. Therefore, a negative charge is generated on the surface of thesecond fiber 20, and a positive charge is generated on the inner side. That is, in thesecond fiber 20, charge is generated by external energy. - Of course, the inclination of the
second fiber 20 with respect to the axial direction of thethread 1 is not limited to 45 degrees to the left. When a shearing stress is applied to thesecond fiber 20, charge is generated. Therefore, the stretchingdirection 900 of thesecond fiber 20 may cross at least the axial direction of thethread 1. Considering this, the twist angle of thesecond fiber 20 may be larger than 0 degrees and smaller than 90 degrees to the left. In general, as the twist angle of thesecond fiber 20 approaches 45 degrees to the left, the charge generation efficiency is improved. However, usually, the thread is used for knitted fabrics, textile fabrics, and sewing, and the direction in which the thread extends may not be constant. That is, since an external force is not necessarily applied in the long axis direction of the thread, the twist angle of thesecond fiber 20 is not limited to the above. - In the embodiment, since the
first fiber 10 has thegroove 12, the surface area of thefirst fiber 10 is larger than that of a fiber having no groove, and the possibility that fungus adheres to thefirst fiber 10 is relatively high. As shown inFIG. 1(C) , when thefirst fiber 10 having thegroove 12 in the length direction is twisted, thegroove 12 extends helically. The shape of thegroove 12 is a shape along a surface of thesecond fiber 20. In such a configuration, when thesecond fiber 20 is twisted, thesecond fiber 20 is twisted along thegroove 12 of thefirst fiber 10. In other words, thesecond fiber 20 is twisted while being guided by thegroove 12 of thefirst fiber 10. The opening width of thegroove 12 is substantially equal to or larger 20 than the diameter length of thesecond fiber 20. At this time, by increasing the friction coefficient of one of thefirst fiber 10 and thesecond fiber 20, when thefirst fiber 10 and thesecond fiber 20 are stressed against each other, stress can be efficiently applied to the other, and generation of charge can be improved. - Further, as shown in
FIG. 1(C) , in the embodiment, a space SP is formed between thegroove 12 of thefirst fiber 10 and thesecond fiber 20 disposed in the region formed in thegroove 12. InFIG. 1(C) , the cross section of thegroove 12 is V-shaped, but the cross section of thesecond fiber 20 is circular form. Therefore, since thesecond fiber 20 and thegroove 12 are not engaged exactly with each other, the space SP is generated. With such a space SP, a leakage electric field is likely to be formed. Therefore, thethread 1 exerts a good antifungal effect. The shape of the space SP can be changed by changing the shape of thegroove 12 of thefirst fiber 10, and the optimum leakage electric field can be changed in combination with thesecond fiber 20. - The cross section of the space SP is smaller than the cross section of the
thread 1. The space SP may be smaller than the cross section of thefirst fiber 10 or smaller than the cross section of thesecond fiber 20. -
FIG. 4(A) is a view illustrating a configuration of athread 2 according to one embodiment of the invention.FIG. 4(B) is a sectional view taken along line II-II ofFIG. 4(A) .FIG. 4(C) is a view illustrating applying a twist to afirst fiber 10 andsecond fibers 20 of thethread 2. In thethread 2 of the embodiment, thesecond fibers 20 are twisted rightward together with thefirst fiber 10. That is, thethread 2 is Z-twisted (left-twisted). InFIG. 4(A) , the stretchingdirection 900 of thesecond fibers 20 is inclined to the right on the paper surface with respect to the stretching direction of thethread 2. - As in the
thread 1, in thethread 2, the angle between the stretchingdirection 900 of thesecond fiber 20 and the stretching direction of thethread 2 is ideally preferably 45 degrees. When such athread 2 is stretched under tension, thesecond fibers 20 are stretched along the axial direction of thethread 2, and are shrunk along the width direction of thethread 2. Therefore, the stretching direction of thethread 2 corresponds to the firstdiagonal line 910A illustrated inFIG. 3(B) , and the width direction of thethread 2 corresponds to the seconddiagonal line 910B illustrated inFIG. 3(B) . As in the example shown inFIG. 3(B) , thesecond fiber 20 stretches in the direction corresponding to the firstdiagonal line 910A and shrinks in the direction corresponding to the direction of the seconddiagonal line 910B. Therefore, a positive charge is generated on the surface of thethread 2, and a negative charge is generated on the inner side. - Since charge generates when the shearing stress is applied in the
second fiber 20, the inclination with respect to the stretching direction of thethread 2 is not limited to 45 degrees to the right, and may at least intersect with the stretching direction of thethread 2. However, as the twist angle of thesecond fiber 20 approaches 45 degrees to the right, the charge generation efficiency is improved. In the embodiment, thegroove 12 of thefirst fiber 10 is a V-shaped groove, and a surface of thesecond fiber 20 is arcuate. That is, the shape of thegroove 12 of thefirst fiber 10 is a shape that is not along the surface of thesecond fiber 20. However, in other embodiments, the shape of thegroove 12 of thefirst fiber 10 may be a shape along the surface of thesecond fiber 20. For example, thegroove 12 of thefirst fiber 10 is a semicircular groove, and the surface of thesecond fiber 20 is arcuate. Furthermore, usually, the thread is used for knitted fabrics, textile fabrics, and sewing, and the direction in which the thread extends may not be constant. That is, since an external force is not necessarily applied in the long axis direction of the thread, the twist angle of thesecond fiber 20 is not limited to the above. - As shown in
FIG. 4(C) , since there is a space SP between thegroove 12 of thefirst fiber 10 and thesecond fiber 20 disposed to fit thegroove 12, a leakage electric field is easily formed. Therefore, thethread 2 has the same good antifungal effect as thethread 1. -
FIG. 5 is a view illustrating an electric field in thethread 1 and thethread 2. In thethread 1 alone, the surface has a negative potential and the inside has a positive potential when tension is applied. In thethread 2 alone, the surface has a positive potential and the inside has a negative potential when tension is applied. When thethread 1 and thethread 2 are brought close to each other, the close portions (surfaces) tend to have the same potential. In this case, the proximity portion between thethread 1 and thethread 2 becomes 0 V, and the positive potential inside thethread 1 is further increased so as to maintain the original potential difference. Similarly, the negative potential inside thethread 2 is further lowered. - An electric field directed mainly from the inside to the outside of the
thread 1 is formed in the cross section of thethread 1, and an electric field directed mainly from the outside to the inside thethread 2 is formed in the cross section of thethread 2. When thethread 1 and thethread 2 are brought close to each other, these electric fields leak out into the air and are synthesized, and an electric field is formed by a potential difference between thethread 1 and thethread 2 as illustrated inFIG. 5 . Alternatively, when the thread 1 (or the thread 2) and a thing having a predetermined potential (including a ground potential) such as a human body are brought close to each other, an electric field is generated between the thread 1 (or the thread 2) and the thing close to the thread 1 (or the thread 2). - Alternatively, a current may flow through a current path formed by moisture between the
thread 1 and thethread 2, or a circuit formed by a micro discharge phenomenon. Even when thethread 1 or thethread 2 and a thing having a predetermined potential close to each other are brought close to each other, a current may flow through a current path formed by moisture, or a circuit formed by a micro discharge phenomenon. - Furthermore, the
thread 1 and thethread 2 do not need to have potentials of opposite polarity. Even if thethread 1 and thethread 2 have potentials of the same polarity, an electric field or a current is generated if there is a potential difference between them. That is, thethread 1 and thethread 2 may have different potentials when charges are generated. - As the fiber that generates a negative charge on the surface, a Z thread using PDLA is also conceivable in addition to an S thread using PLLA. Furthermore, as the fiber that generates a positive charge on the surface, the S thread using PDLA is also conceivable in addition to the Z thread using PLLA.
- In the embodiment, only the
second fiber 20 contains the polylactic acid. However, in other embodiments, thefirst fiber 10 may also contain the polylactic acid. Then, when thefirst fiber 10 is twisted, charge is generated. - In the embodiment, the number of the
first fibers 10 in thethread 1 or thethread 2 is 1, but in other embodiments, the number of thefirst fibers 10 may be plural.FIG. 6 is a sectional view of a thread according to one embodiment of the invention. As shown inFIG. 6 , a plurality offirst fibers 10 are disposed so as to be surrounded bysecond fibers 20. The bundle offirst fibers 10 hasmore grooves 12 than the singlefirst fiber 10. In such a configuration, when thefirst fibers 10 and thesecond fibers 20 are twisted, the bundle of thefirst fibers 10 can guide more thesecond fibers 20. - In the embodiment, the
first fiber 10 and thesecond fiber 20 are long fibers (filaments), and thethread 1 and thethread 2 are twisted threads made of long fibers. However, thethread 1 andthread 2 are not limited to the twisted threads made of long fibers. In another embodiment, thefirst fiber 10 and thesecond fiber 20 may be short fibers (spans), and thethread 1 and thethread 2 may be spun threads made of short fibers. In other embodiments, thefirst fiber 10 and thesecond fiber 20 may be long fibers and short fibers (or short fibers and long fibers), respectively, and thethread 1 and thethread 2 may be twisted threads made of two types of fibers. - In the embodiment, the
first fibers 10 are heteromorphic modified cross-section fibers (modified filaments) and thesecond fibers 20 are circular cross-section fibers (circular filaments). However, thesecond fibers 20 are not limited to the circular cross-section fibers. In another embodiment, thesecond fibers 20 are a modified cross-section fibers like thefirst fibers 10. - In other embodiments, both the
first fiber 10 and thesecond fiber 20 may be charge generating fibers that generate charge. Furthermore, when both thefirst fiber 10 and thesecond fiber 20 are charge generating fibers, either one may have a lower elastic modulus than the other, and when only one of thefirst fiber 10 and thesecond fiber 20 is charge generating fiber, the other may have a lower elastic modulus than the one. In this case, since the fiber has a low elastic modulus, the thread tends to stretch, and the shearing stress tends to be applied to the charge generating fiber. Furthermore, when both of thefirst fiber 10 and thesecond fiber 20 are charge generating fibers, either one may have a lower coefficient of static friction than the other, and when only one of thefirst fiber 10 and thesecond fiber 20 is charge generating fiber, the other may have a higher coefficient of static friction. In this case, the shearing stress tends to be applied to the charge generating fiber. -
FIG. 7 is a sectional view of athread 3 according to one embodiment of the invention. In this embodiment, athread 3 is composed of thefirst fiber 10 and thesecond fiber 20 which are modified cross-section fibers, and thefirst fiber 10 and thesecond fiber 20 have the same sectional shape. However, in other embodiments, thefirst fiber 10 and thesecond fibers 20 in thethread 3 may have different sectional shapes. - As illustrated in
FIG. 7 , thesecond fiber 20 has at least oneprotrusion 24 extending in the length direction. Thesecond fiber 20 is disposed such that theprotrusion 24 of thesecond fiber 20 engages with thegroove 12 of thefirst fiber 10. In such a configuration, when thesecond fiber 20 is twisted, theprotrusion 24 of thesecond fiber 20 is twisted along thegroove 12 of thefirst fiber 10, and extends helically. That is, thesecond fiber 20 is twisted while being guided by thegroove 12 of thefirst fiber 10. - The
thread 3 is S-twisted or Z-twisted depending on the direction of twisting. In the embodiment, by using thegroove 12 of thefirst fiber 10 and theprotrusion 24 of thesecond fiber 20, the twist angle of thesecond fiber 20 can be made close to a desired angle (45 degrees to the left or 45 degrees to the right), and thethread 3 can be made into a medium twisted thread or a hard twisted thread. Since the shape and size of the internal space of thegroove 12 do not exactly fit the shape and size of theprotrusion 24, the space SP exists between thefirst fiber 10 and thesecond fiber 20. Therefore, a leakage electric field is easily formed. Such athread 3 has the same good antifungal effect as thethread 1 and thethread 2. - In the embodiment, the
groove 12 of thefirst fiber 10 is parallel to the length direction of thefirst fiber 10 as shown inFIG. 1(C) . However, thegroove 12 is not limited to the linear groove. In another embodiment, thegroove 12 of thefirst fiber 10 is a groove formed in a helical shape with respect to the axial direction of thefirst fiber 10. When thesecond fiber 20 is wound along the helical groove, a thread having an appearance similar to that of the twisted thread is obtained. In this embodiment, it is not necessary to twist thefirst fiber 10. The number of turns and the helical angle of thesecond fiber 20 are determined by the installation state of the helical groove. Therefore, if the number of turns and the helical angle are appropriate, the thread obtained in this embodiment can also exhibit a good antifungal effect. - The above-mentioned threads (
thread 1,thread 2,thread 3, etc.) can be applied to daily life products such as medical parts and clothing. For example, the thread (thread 1, thread 2, thread 3, etc.) can be applied to a mask, underwear (in particular, socks), a towel, insoles such as shoes and boots, sportswear in general, a hat, bedding (bedclothes, a mattress, a sheet, a pillow, a pillow cover, and the like), a toothbrush, a froth, a water purifier, a filter for an air conditioner or an air cleaner, a stuffed toy, a pet-related product (a mat for a pet, clothing for a pet, and an innerwear for a pet), various mat products (a foot, a hand, and a toilet seat), s curtain, s kitchen utensil (s sponge or s cloth), seats (a seats for a car, a train, an airplane, etc.), a cushioning material for a motorbike helmet and an exterior material thereof, a sofa, a bandage, a gauze, a suture, clothes for a doctor and a patient, a supporter, a sanitary product, a sporting good (an inner of a wear and a glove, an arm guard used in a martial art, or the like), a filter for an air conditioner or an air cleaner, a packaging material, and a screen door. - Of the clothing, in particular, socks (or supporters) always expand and contract along a joint by movement such as walking, and thus the thread (
thread 1,thread 2,thread 3, etc.) generates charge with high frequency. In addition, socks absorb moisture such as sweat and become a hotbed for proliferation of a fungus, but the threads (thread 1,thread 2,thread 3, etc.) can suppress proliferation of a fungus, and thus exert a remarkable effect as a fungus-countermeasure application for odor prevention. - Finally, description of this embodiment should be considered to be exemplary in all respects and not restrictive. The scope of the present invention is defined not by the embodiments but by the claims. Furthermore, the scope of the invention is intended to include all modifications within the meaning and scope equivalent to the claims.
-
-
- 1, 2, 3: Thread
- 10: First fiber
- 20: Second fiber
- 12: Groove
- 14, 24: Protrusion
- SP: Space
- 900: Stretching direction
- 910A: First diagonal line
- 910B: Second diagonal line
Claims (20)
1. A thread comprising:
a first fiber having at least one groove extending in a length direction thereof; and
at least one second fiber constructed to generate a potential by external energy,
the second fiber disposed in a region corresponding to the groove of the first fiber such that a space is between the groove of the first fiber and the second fiber.
2. The thread according to claim 1 , wherein a cross section of the space between the first fiber and the second fiber is smaller than a cross section of the thread.
3. The thread according to claim 1 , wherein a shape of the groove of the first fiber corresponds to a shape along a surface of the second fiber.
4. The thread according to claim 1 , wherein a shape of the groove of the first fiber does not correspond to a shape along a surface of the second fiber.
5. The thread according to claim 1 , wherein the first fiber and the second fiber are modified cross-section fibers, the second fiber has at least one protrusion extending in the length direction thereof, and the second fiber is disposed such that the protrusion engages with the groove of the first fiber.
6. The thread according to claim 1 , wherein the first fiber has a lower elastic modulus than the second fiber.
7. The thread according to claim 1 , wherein the first fiber has a higher coefficient of static friction than the second fiber.
8. The thread according to claim 1 , wherein an opening width of the groove substantially matches a diameter of the second fiber.
9. The thread according to claim 1 , wherein an opening width of the groove is larger than a diameter of the second fiber.
10. The thread according to claim 1 , wherein the second fiber contains a polylactic acid.
11. The thread according to claim 1 , wherein the first fiber is longer than the second fiber.
12. The thread according to claim 1 , wherein the first fiber is shorter than the second fiber.
13. The thread according to claim 1 , wherein the first fiber and the second fiber are twisted together.
14. The thread according to claim 1 , wherein the first fiber has a plurality of grooves extending in the length direction thereof; and a plurality of second fibers, a respective second fiber of the plurality of second fibers being disposed in a region corresponding to a respective groove of the plurality of grooves of the first fiber.
15. The thread according to claim 1 , wherein a sectional shape of the first fiber is a cross shape, a star polygon, or a concave polygon.
16. The thread according to claim 1 , wherein a cross section of the at least one groove is V-shaped, and a cross section of the at least one second fiber is circular.
17. The thread according to claim 1 , wherein the thread comprises a plurality of the first fibers and a plurality of the second fibers arranged to surround the plurality of first fibers.
18. The thread according to claim 1 , wherein both the first fiber and the second fiber are constructed to generate a potential by external energy.
19. The thread according to claim 1 , wherein the first fiber and the second fiber have the same sectional shape.
20. The thread according to claim 1 , wherein the at least one groove is parallel to the length direction of the first fiber.
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WO2021106842A1 (en) | 2021-06-03 |
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CN114729474A (en) | 2022-07-08 |
EP4043626A1 (en) | 2022-08-17 |
JPWO2021106842A1 (en) | 2021-06-03 |
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