US20210104780A1 - Mixing element and accumulator - Google Patents
Mixing element and accumulator Download PDFInfo
- Publication number
- US20210104780A1 US20210104780A1 US17/109,761 US202017109761A US2021104780A1 US 20210104780 A1 US20210104780 A1 US 20210104780A1 US 202017109761 A US202017109761 A US 202017109761A US 2021104780 A1 US2021104780 A1 US 2021104780A1
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- Prior art keywords
- mixing element
- accumulator
- housing
- securing
- mixing
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/12—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4214—Arrangements for moving electrodes or electrolyte
-
- H01M2/0237—
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- H01M2/024—
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- H01M2/38—
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/112—Monobloc comprising multiple compartments
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/70—Arrangements for stirring or circulating the electrolyte
-
- H01M2/0242—
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Definitions
- the invention relates to a mixing element designed to be installed into a housing of a liquid electrolyte-operated electrochemical accumulator in accordance with claim 1 .
- the invention further relates to a range of mixing elements in accordance with claim 11 as well as an accumulator comprising at least one mixing element in accordance with claim 12 .
- the invention relates to the field of liquid electrolyte-operated accumulators; i.e. rechargeable electrochemical batteries, for example in the form of lead-acid batteries.
- accumulators are used for example as starter batteries for motor vehicles.
- Mixing elements of the generic type are known for example from WO 2011/029035 A2 and DE 10 2010 048 428 A1.
- the invention is based on the task of specifying a universally applicable mixing element for an electrochemical accumulator.
- a range of mixing elements applicable to different types of accumulators as well as an accumulator having such a mixing element are further to be specified.
- a mixing element which is designed to be installed in a housing of an electrochemical accumulator operated by liquid electrolyte in order to mix the electrolyte as a result of forces and/or motion exerted on the accumulator during operation, whereby the mixing element is designed as a hollow body provided with at least one respective opening at opposite end regions such that a channel is formed in the hollow body which leads into the at least one respective opening at the opposite end regions and is circumferentially delimited there by the material of the mixing element, wherein the mixing element comprises one or more securing and/or spacer ribs protruding from the external side of the mixing element and designed to contact parts of the accumulator housing in order to fix the mixing element in the accumulator and/or set a specific position of the mixing element relative to the housing parts.
- the invention has the advantage of the inventive mixing element being able to be universally applicable with respect to all possible types, sizes and designs of electrochemical accumulators due to the externally arranged securing and/or spacer ribs protruding from the external side of the mixing element.
- the securing and/or spacer ribs facilitate the securing of the mixing element in a cell chamber of the accumulator. Insertion of the mixing element into the cell chamber is also facilitated.
- the securing and/or spacer ribs can ensure a defined positioning, making installation a quick and easy process even for less experienced personnel.
- the improved design of the mixing element with the securing and/or spacer ribs is also advantageous to automated accumulator production.
- the entire mixing element as a whole to be structurally modified for different types, sizes and designs of accumulators, but rather only the dimensions of one or more of the external securing and/or spacer ribs.
- the proportions of the mixing element which are essential to the mixing function remain the same such that there is also no change in the mixing element's performance and effectiveness.
- the central functional body of the mixing element can thus be of uniform design and realization such that it can be consistently used and installed in differently sized accumulators having diverse retaining rib variations.
- the mixing element can be installed into the housing of the accumulator without any material bonding procedure, e.g. by clamping via one, some or all of the securing and/or spacer ribs.
- the mixing element is designed to be stackable with other mixing elements.
- the geometrical shape of the mixing element is configured such that it can be at least partly set into another mixing element and thus multiple mixing elements can be stacked one inside the other. This stackability reduces the space required to store the mixing elements and enables better handling during automated assembly of accumulators.
- the mixing element to have a volumetric space in the area of an upper end region designed to be arranged above an oppositely disposed lower end region when installed in the housing, the circumference of which is significantly larger than the circumference of the mixing element sections below it so that the mixing element sections underneath form at least one thin flow channel compared to the cross-sectional area of the volumetric body.
- This has the advantage of further improving the inventive mixing element's desirable electrolyte mixing. Acid stratification in the accumulator can thereby be eliminated or at least significantly reduced. Acid stratification refers to different acid densities over the height of the accumulator.
- the mixing element according to the invention enables electrolyte mixing at a higher functional effectiveness as a result of the reduced circumference and the thereby associated decreased flow area of the hollow body in the area of the thin flow channel.
- the mixing element according to the invention already provides comparable mixing effects to prior art mixing elements even at lower motion loads on the accumulator.
- the mixing element can be made for example from polypropylene or another suitable flexible and acid-proof material.
- the mixing element according to the invention can be designed so as to yield a cyclic circulation of electrolyte upon motion loads on the accumulator such that electrolyte spills over the upper edge of the mixing element and drains again via the lower opening as described for example in U.S. Pat. No. 5,096,787.
- the mixing element has the function of a hydrostatic pump.
- the mixing element extends at least as far upward so as to prevent liquid electrolyte from overflowing over the upper edge region of the mixing element upon specification-compliant motion load on the accumulator such as occurs in a moving vehicle. So doing enables being able to advantageously realize the principle of communicating vessels.
- a communicating connection forces a back-and-forth motion of electrolyte in the lower region of the mixing element between the volumetric space of the mixing element and the surrounding cell chamber of the accumulator; i.e. by way of the lower opening, and not an electrolyte circulation as with the hydrostatic pump principle.
- This has the advantage of the sludge which has accumulated on the bottom of the accumulator remaining in place since there is no circulation of electrolyte.
- the electrolyte motion thereby compelled is sufficient enough to mix the electrolyte to the extent of eliminating or at least greatly reducing acid stratification.
- the communicating connection in the lower region of the mixing element i.e. the lower opening through which the liquid electrolyte can flow, can exhibit a number of different configurations, e.g. in the form of a gap or in the form of one or more openings in the lower region of the mixing element.
- the above-cited openings can be arranged at different positions on the mixing element, preferably of course in the lower area of the flow channel.
- the mixing element is manufactured as a separate component which is not set into the accumulator housing until the accumulator is assembled.
- the mixing element can be configured for example as a component insertable into a cell chamber of the accumulator. This has the advantage of the mixing element being able to be manufactured separately and inserted as needed into the cell chamber of the accumulator. Accumulators can thus be economically manufactured both with the mixing element as well as without the mixing element without the need for different injection molds to produce the housing parts of the two versions of the accumulator, as would be necessary with an integrally formed wall element. Additionally, accumulators manufactured in previous series production runs can also be easily converted to accumulators having integrated mixing in the form of a mixing element; i.e. without high expenditures for manufacturing equipment.
- the mixing element can in particular have the form of a ring-shaped hollow body, whereby ring shape in this case does not refer exclusively to an annular shape but also any other circular ring form.
- the mixing element can be for example formed as, with the exception of the openings provided in the oppositely disposed end regions, a substantially closed hollow body. This enables the mixing element to be easily produced, e.g. from a plastic material.
- the mixing element can be advantageously manufactured with an internal mandrel and an external form, for example by injection molding.
- the mixing element can also be manufactured as a hollow body via a blow process or deep-drawing process.
- the thin flow channel tapering toward the lower end region with respect to circumference has the further advantage of improving the demoldability of the mixing element during the manufacturing process.
- the circumference in the area of the thin flow channel decreases discontinuously over the longitudinal extension of the mixing element by means of one or more discontinuities. This results in a type of incremental decrease to the hollow body circumference. Doing so can further improve the mixing element's functional effectiveness in terms of the liquid electrolyte mixing effect.
- Providing one or more discontinuities over the course of the flow channel results in one or more graduated transitions of the flow resistance and thus a deceleration or acceleration in the electrolyte exchange between the volumetric space of the mixing element and the interior of the accumulator. It Is for example advantageous for two or three such discontinuities to be provided in the region of the thin flow channel.
- the discontinuities also further improve the demoldability of the mixing element during the manufacturing process.
- one or more discontinuities extend linearly over the longitudinal extension of the mixing element; i.e. depending on the embodiment, the circumferential decrease or cross-sectional reduction in these areas is linear.
- the mixing element comprises at least two separated thin flow channels connected to the common volumetric space.
- One, multiple or all of the separated thin flow channels can be configured in accordance with the above-cited features of the thin flow channel, particularly with one or more discontinuities.
- the mixing element comprises an indentation on at least one side of the hollow body which runs in the longitudinal direction of the mixing element and is designed to receive an accumulator housing rib.
- This allows simple and reliable mechanical securing of the mixing element in the accumulator housing, provided same is configured with internal housing ribs. In this case, no additional mechanical securing means are necessary.
- the indentation can in particular be provided in the region of the volumetric space or respectively extend into this space such that the volumetric space is divided.
- the indentation is at least as deep as the extension of the thin flow channel in the same direction; i.e. in the direction of extension of the indentation. This enables a particularly sturdy mechanical securing of the mixing element to the housing rib of the accumulator housing. Additionally, at least two separate thin flow channels are thereby created.
- the mixing element comprises at least one securing and/or spacer rib protruding in the direction of the housing cover of the accumulator housing.
- a securing and/or spacer rib can fix the position of the mixing element relative to the housing cover and also secure the mixing element relative to the housing cover.
- the mixing element comprises at least one securing and/or spacer rib protruding in the direction of the bottom of the accumulator housing.
- Said securing and/or spacer rib can for example be arranged on the mixing element at the lower side of the volumetric space.
- the securing and/or spacer rib protruding in the direction of the bottom of the accumulator housing can ensure a defined downward positioning and securing of the mixing element.
- the downward protruding securing and/or spacer rib can rest on the electrodes or the separators encasing the electrodes respectively, thereby defining the mixing element's installation height in the housing.
- the mixing element comprises one or more outer circumferential securing and/or spacer ribs on one, some or all of its external sides facing the side walls of the accumulator housing.
- This has the advantage of the mixing element being able to be disposed at a defined horizontal position within a free space of a cell chamber, thereby preventing improper installation in the wrong position.
- the side walls of the accumulator housing are thereby the accumulator's lateral external walls as well as the accumulator housing's internal walls constituting the partition walls between different cell chambers.
- the mixing element can in each case have one or more securing and/or spacer ribs on all four external sides or only on some or only one of the external sides.
- one or more securing and/or spacer ribs are arranged within the above-described indentation.
- one or more securing and/or spacer ribs can be arranged at respective oppositely disposed external sides of the mixing element within the indentation.
- Such securing and/or spacer ribs arranged within the indentation enable the mixing element to be pressed in wedge-like manner against an inner housing rib of the accumulator housing and secured to said housing rib.
- the securing and/or spacer ribs provided within the indentation can exhibit an outer contour which increases in the direction of insertion onto the housing rib so that the outer contour forms a wedge relative to the housing rib.
- At least two securing and/or spacer ribs are arranged to form a V-shaped pair.
- This has the advantage of the V-shaped construction being able to prevent a kinking of the spacer ribs when being fit into the housing or during the later actual operation of the accumulator.
- the securing and/or spacer ribs arranged in V-shaped pairs can thereby join and combine into a V-shaped rib or be arranged at a certain distance from one another.
- the initially specified task is solved in accordance with claim 11 by a range of mixing elements of the above-described type, whereby the range comprises mixing elements of varying designs which differ from one another in the arrangement and/or dimensions of the securing and/or spacer ribs.
- the range comprises mixing elements of varying designs which differ from one another in the arrangement and/or dimensions of the securing and/or spacer ribs.
- the initially specified task is solved in accordance with claim 12 by an accumulator having a housing in which at least one accumulator cell is formed, whereby the accumulator cell comprises a plurality of adjacently arranged plated-shaped electrodes within the accumulator cell as well as liquid electrolyte, wherein at least one mixing element of the above-described type is additionally arranged in a free space within the accumulator cell.
- the inventive accumulator already provides a greater mixing effect at comparatively lower motion load and thereby prevents or at least substantially reduces acid stratification.
- the mixing element is arranged laterally to a flat side of a plate-shaped electrode in the accumulator cell.
- the mixing element is hereby not held by the force of the protruding welded ends of the separator pocket as described in DE 10 2010 048 428 A1 since it is disposed at the flat side of the plate-shaped electrode.
- a component integrated into the housing of the accumulator can be provided as the retaining means for mechanically fixing the mixing element in the accumulator cell.
- an internal housing rib of the accumulator housing can be used as a retaining means.
- the mixing element can be also connected to the housing of the accumulator or the internal housing rib respectively, and thereby positionally fixed, by way of a known bonding process, e.g. plastic welding.
- the mixing element is arranged between a plate-shaped electrode and the housing wall or an internal housing rib formed on the housing wall.
- the housing exhibits a longitudinal extension which is the largest dimension of the housing's height, width and length dimensions
- the electrode plates exhibit a longitudinal extension which is the largest dimension of the individual electrode plates' height, width and length dimensions
- the electrode plates are orientationally positioned in a battery cell such that the longitudinal extension of the electrode plates runs substantially in the direction of the housing's longitudinal extension.
- FIG. 1 a cross-sectional view of an accumulator with mixing element
- FIGS. 2 and 3 the accumulator according to FIG. 1 under motion load
- FIGS. 4-6 a first embodiment of a mixing element without external ribs
- FIGS. 7-9 a second embodiment of a mixing element without external ribs
- FIGS. 10-11 a third embodiment of a mixing element with external ribs
- FIGS. 12-13 a fourth embodiment of a mixing element with external ribs
- FIGS. 14-17 side sectional views of accumulators
- FIG. 18 a plan view of an accumulator from above.
- FIG. 19 stackable mixing elements.
- FIGS. 1 to 3 and 18 depict the accumulator without a cover part; i.e. in a state in which the accumulator's upper side is still open. To complete manufacture, the accumulator housing is normally closed in the usual way with a cover part.
- FIG. 1 shows an accumulator 2 with a mixing element 1 arranged in its housing 3 .
- Electrode plates 5 are additionally arranged in the housing 3 , or in a cell chamber 4 of the housing respectively, which are partially enclosed by (not shown) separators.
- the housing 3 or cell chamber 4 additionally contains liquid electrolyte 7 , wherein the electrolyte 7 is filled up to level 8 .
- a housing rib 6 is further provided in the housing 3 or in cell chamber 4 respectively.
- the mixing element 1 is fixed to the housing rib 6 , e.g. clamped to same.
- the mixing element 1 comprises a volumetric space 13 at its upper end region which transitions downward into a thin flow channel 17 having a substantially smaller cross-sectional area compared to volumetric space 13 .
- the flow channel 17 ends in one or more openings 11 in a lower region of the mixing element.
- the volumetric space 13 is likewise open upwardly; i.e. an opening 10 is provided therein.
- the upper and the lower openings 10 , 11 enable the pressure between the interior of the mixing element 1 and the surrounding area of the accumulator housing 3 to be equalized at any time.
- An electrolyte level 9 is thus set in the mixing element 1 which corresponds to the electrolyte level 8 of the accumulator 2 and/or the respective cell chamber 4 .
- FIGS. 2 and 3 show the function of the mixing element 1 under accumulator 2 motion load.
- the accumulator is tipped at an angle to the left. From the originally equally high levels 8 , 9 , the tilting first results in a level difference 12 since the electrolyte retained in the mixing element 1 can only flow out through the thin flow channel 17 at a decelerated rate.
- the arrows depict the outflow of electrolyte into the accumulator's cell chamber 4 . It is now assumed that the equalizing process of the accumulator tilted to the left in FIG. 2 Is finished so that the level 9 in the mixing element again corresponds to level 8 .
- the accumulator is then tilted for example somewhat to the right as depicted in FIG. 3 .
- the electrolyte is thus mixed and acid stratification thereby prevented or reduced.
- the mixing element 1 is thereby constructed tall enough relative to the wall height of the volumetric space 13 such that electrolyte is prevented from spilling over the upper edge of the mixing element 1 directly into the volumetric space 13 under normal motion load.
- overspillage is allowed for up to a tilt angle of 20° relative to horizontal.
- a further embodiment allows for electrolyte overspillage up to a tilt angle of 35° relative to horizontal.
- FIGS. 4 to 6 show a first embodiment of the mixing element 1 .
- FIG. 4 thereby shows an isometric view
- FIG. 5 a rear view
- FIG. 6 a side view.
- the mixing element 1 comprises an indentation 15 which divides the volumetric space 13 into two sub-areas, albeit connected together over a relatively large cross section.
- the indentation 15 can serve in fitting the mixing element 1 onto the housing rib 6 , as can be seen in FIGS. 1 and 16 .
- the mixing element can simply be set onto the housing rib and wedged there by means of the indentation 15 .
- a floor 16 limits the volumetric space 13 in the downward direction.
- the volumetric space 13 has an open design upward by means of opening 10 .
- the volumetric space 13 transitions into a thin flow channel 17 which extends downward to opening 11 .
- the thin flow channel 17 is divided into two sub-channels 40 , 50 , each having a respective lower opening 11 , 14 .
- the openings 11 , 14 can be configured as individual openings or as a combination of multiple openings.
- the mixing element can terminate in the area of the openings 11 , 14 as a straight surface or, as visible in the figures, as a chamfer.
- the thin flow channel 17 , or sub-channels 40 , 50 respectively have two linear discontinuities 41 , 42 , 51 , 52 below transition 60 . These discontinuities doubly reduce the circumference and thus also the inner cross-sectional area of the hollow body in the direction of the lower end region toward opening 11 , 14 .
- FIGS. 7 to 9 show a second embodiment of the mixing element 1 .
- FIG. 7 shows an isometric view
- FIG. 8 a rear view
- FIG. 9 a side view.
- the mixing element 1 depicted here has in each case further divided sub-channels 43 , 44 , 53 , 54 , e.g. in the form of channels of circular cross section, in the lower regions of the flow channels 40 , 50 .
- Each of the sub-channels 43 , 44 , 53 , 54 has its own circumference-reducing discontinuity 42 , 52 as well as a lower opening 11 , 14 .
- FIGS. 1 to 9 will be used to illustrate the basic function and design of the inventive mixing element by way of embodiments in which the mixing element does not comprise any securing and/or spacer ribs, referred to only as ribs in the following for short.
- FIGS. 10 to 19 will be used in the following in describing mixing elements comprising the respective external ribs.
- FIGS. 10 and 11 show two different isometric views of a mixing element 1 corresponding to the mixing element according to FIGS. 7 to 9 and additionally comprising external ribs. Depicted in each case is only the respective upper area of the mixing element provided with the ribs; the sections underneath correspond to FIGS. 7 to 9 .
- the mixing element embodiments comprising ribs described in the following can also, however, be of any other desired design with respect to the lower flow channels, e.g. as per FIGS. 4 to 6 or the like.
- the mixing element 1 according to FIGS. 10 and 11 comprises an upward protruding rib 133 at the upper edge of the rear wall 30 of volumetric space 13 , the ends of which can be angled toward the side wall regions 131 , 132 of said volumetric space 13 .
- the rib 133 extends in the direction of a housing cover of the accumulator housing so that the mixing element 1 , when set into the housing, can be vertically fixed by the housing cover by way of the rib 133 .
- ribs 61 are provided below at the lower side 60 of the volumetric space 13 which form a counter bearing to the upper rib 133 for fixing the mixing element 1 in an accumulator housing.
- the mixing element 1 can thus be clamped between the housing cover and the electrode plates, or their separators respectively, by means of the upper rib 133 and the downward-facing ribs 61 disposed at the bottom of the housing or an electrode plate pack of the accumulator respectively.
- the mixing element comprises ribs 134 , 135 on the respective side walls 131 , 132 which protrude from the sides toward the side walls of the accumulator housing. Ribs 136 , 137 are furthermore provided on the side of the volumetric space 13 opposite the rear wall 130 which are each arranged to form a V-shaped pair when the side of the volumetric space 13 to which they are fixed is viewed from above.
- the ribs 61 , 134 , 135 , 136 , 137 have a downward tapering and then rounded design.
- Outward pointing ribs 152 , 153 can be arranged within the indentation 15 on respective opposite walls 150 , 151 of the volumetric space 13 by means of which the mixing element can be clamped to the housing rib 6 .
- the various ribs described with reference to FIGS. 10 and 11 do not always need to be realized fully in the mixing element or in the depicted dimensions.
- the ribs allow the mixing element to be adapted to other accumulator housing designs, for example by modifying the dimensions of the ribs or omitting individual ribs.
- the mixing element 1 only comprises ribs 61 , 134 , 135 , 152 , 153 . Ribs 61 are hereby configured at a shorter overall height than in FIGS. 10 and 11 . The mixing element can thereby be installed for example into a housing of shorter overall height than the housing applicable to FIGS. 10 and 11 . This is depicted in the following referencing FIGS. 14 to 17 .
- FIG. 14 and FIG. 17 respectively show a side view of an accumulator looking toward the rear wall 130 of the volumetric space 13 of the mixing element 1 , FIGS. 15 and 16 respectively showing a view of side wall 131 / 132 .
- FIGS. 14 and 15 hereby reflect the mixing element according to FIGS. 10 and 11 ; FIGS. 16 and 17 , the mixing element according to FIGS. 12 and 13 .
- the accumulator according to FIGS. 14 and 15 has a housing of larger overall height than the accumulator in FIGS. 16 and 17 . It can be seen that the mixing element is in each case set onto a housing rib 6 and clamped between an electrode plate pack 5 and a housing cover 100 of the accumulator and thereby vertically fixed.
- FIG. 18 shows a six-celled accumulator 2 in plan view, whereby the accumulator's housing cover has again not yet been positioned into place, thus visible being the six individual accumulator cells 90 , 91 , 92 , 93 , 94 , 95 with the electrode plates 5 arranged therein.
- An electrode plate group 5 is only depicted in cell chamber 94 by way of example. It can be seen that as far as their greatest dimension LE, the electrode plates 5 extend in the same direction as the greatest dimension LG of the housing 3 of the accumulator 2 . It can further be seen that the housing 3 comprises housing ribs 6 .
- a mixing element 1 fit onto a housing rib 6 is exemplarily depicted in each cell chamber 90 , 91 , 92 , 93 , 94 , 95 .
- the housing 3 of the accumulator 2 thereby has external side walls 101 and internal walls 102 .
- the internal walls 102 divide the interior of the housing 3 into cell chambers for the accumulator cells 90 , 91 , 92 , 93 , 94 , 95 .
- FIG. 19 shows an example stackable design of the mixing elements 1 into one another using the mixing elements of FIGS. 10 and 11 (left) and FIGS. 12 and 13 (right). Such a design can thereby save space and simplify automated assembly of mixing elements.
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Filling, Topping-Up Batteries (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Secondary Cells (AREA)
Abstract
Description
- The invention relates to a mixing element designed to be installed into a housing of a liquid electrolyte-operated electrochemical accumulator in accordance with
claim 1. The invention further relates to a range of mixing elements in accordance withclaim 11 as well as an accumulator comprising at least one mixing element in accordance withclaim 12. - In general terms, the invention relates to the field of liquid electrolyte-operated accumulators; i.e. rechargeable electrochemical batteries, for example in the form of lead-acid batteries. Such accumulators are used for example as starter batteries for motor vehicles. Mixing elements of the generic type are known for example from WO 2011/029035 A2 and DE 10 2010 048 428 A1.
- The invention is based on the task of specifying a universally applicable mixing element for an electrochemical accumulator. A range of mixing elements applicable to different types of accumulators as well as an accumulator having such a mixing element are further to be specified.
- The task is solved according to
claim 1 by a mixing element which is designed to be installed in a housing of an electrochemical accumulator operated by liquid electrolyte in order to mix the electrolyte as a result of forces and/or motion exerted on the accumulator during operation, whereby the mixing element is designed as a hollow body provided with at least one respective opening at opposite end regions such that a channel is formed in the hollow body which leads into the at least one respective opening at the opposite end regions and is circumferentially delimited there by the material of the mixing element, wherein the mixing element comprises one or more securing and/or spacer ribs protruding from the external side of the mixing element and designed to contact parts of the accumulator housing in order to fix the mixing element in the accumulator and/or set a specific position of the mixing element relative to the housing parts. - Insofar as the terms “above” and “below” are used, these indications refer to the position of the accumulator when operated in specification-compliant use; i.e. a substantially horizontal position in which the cover of the accumulator as well as its filler openings for the liquid electrolyte are situated at the top. A certain deviation from the horizontal position is permissible upon normal specification-compliant motion load on the accumulator such as occurs for example when the accumulator is operated in a motor vehicle. Operating positions which are not specification-compliant are for example positions rotated 90° or 180° relative to the horizontal position.
- The invention has the advantage of the inventive mixing element being able to be universally applicable with respect to all possible types, sizes and designs of electrochemical accumulators due to the externally arranged securing and/or spacer ribs protruding from the external side of the mixing element. The securing and/or spacer ribs facilitate the securing of the mixing element in a cell chamber of the accumulator. Insertion of the mixing element into the cell chamber is also facilitated. Moreover, the securing and/or spacer ribs can ensure a defined positioning, making installation a quick and easy process even for less experienced personnel. The improved design of the mixing element with the securing and/or spacer ribs is also advantageous to automated accumulator production. It is thereby unnecessary for the entire mixing element as a whole to be structurally modified for different types, sizes and designs of accumulators, but rather only the dimensions of one or more of the external securing and/or spacer ribs. The proportions of the mixing element which are essential to the mixing function remain the same such that there is also no change in the mixing element's performance and effectiveness. The central functional body of the mixing element can thus be of uniform design and realization such that it can be consistently used and installed in differently sized accumulators having diverse retaining rib variations. In particular, the mixing element can be installed into the housing of the accumulator without any material bonding procedure, e.g. by clamping via one, some or all of the securing and/or spacer ribs.
- According to one advantageous further development of the invention, the mixing element is designed to be stackable with other mixing elements. To this end, the geometrical shape of the mixing element is configured such that it can be at least partly set into another mixing element and thus multiple mixing elements can be stacked one inside the other. This stackability reduces the space required to store the mixing elements and enables better handling during automated assembly of accumulators.
- One advantageous further development of the invention provides for the mixing element to have a volumetric space in the area of an upper end region designed to be arranged above an oppositely disposed lower end region when installed in the housing, the circumference of which is significantly larger than the circumference of the mixing element sections below it so that the mixing element sections underneath form at least one thin flow channel compared to the cross-sectional area of the volumetric body. This has the advantage of further improving the inventive mixing element's desirable electrolyte mixing. Acid stratification in the accumulator can thereby be eliminated or at least significantly reduced. Acid stratification refers to different acid densities over the height of the accumulator. The mixing element according to the invention enables electrolyte mixing at a higher functional effectiveness as a result of the reduced circumference and the thereby associated decreased flow area of the hollow body in the area of the thin flow channel. The mixing element according to the invention already provides comparable mixing effects to prior art mixing elements even at lower motion loads on the accumulator.
- The mixing element can be made for example from polypropylene or another suitable flexible and acid-proof material.
- As regards its height, i.e. its longitudinal extension in the vertical direction when in the intended installed position in the accumulator, the mixing element according to the invention can be designed so as to yield a cyclic circulation of electrolyte upon motion loads on the accumulator such that electrolyte spills over the upper edge of the mixing element and drains again via the lower opening as described for example in U.S. Pat. No. 5,096,787. In this case, the mixing element has the function of a hydrostatic pump.
- According to one advantageous further development of the invention, the mixing element extends at least as far upward so as to prevent liquid electrolyte from overflowing over the upper edge region of the mixing element upon specification-compliant motion load on the accumulator such as occurs in a moving vehicle. So doing enables being able to advantageously realize the principle of communicating vessels. A communicating connection forces a back-and-forth motion of electrolyte in the lower region of the mixing element between the volumetric space of the mixing element and the surrounding cell chamber of the accumulator; i.e. by way of the lower opening, and not an electrolyte circulation as with the hydrostatic pump principle. This has the advantage of the sludge which has accumulated on the bottom of the accumulator remaining in place since there is no circulation of electrolyte. The electrolyte motion thereby compelled is sufficient enough to mix the electrolyte to the extent of eliminating or at least greatly reducing acid stratification.
- The communicating connection in the lower region of the mixing element; i.e. the lower opening through which the liquid electrolyte can flow, can exhibit a number of different configurations, e.g. in the form of a gap or in the form of one or more openings in the lower region of the mixing element. The above-cited openings can be arranged at different positions on the mixing element, preferably of course in the lower area of the flow channel.
- According to one advantageous further development of the invention, the mixing element is manufactured as a separate component which is not set into the accumulator housing until the accumulator is assembled. The mixing element can be configured for example as a component insertable into a cell chamber of the accumulator. This has the advantage of the mixing element being able to be manufactured separately and inserted as needed into the cell chamber of the accumulator. Accumulators can thus be economically manufactured both with the mixing element as well as without the mixing element without the need for different injection molds to produce the housing parts of the two versions of the accumulator, as would be necessary with an integrally formed wall element. Additionally, accumulators manufactured in previous series production runs can also be easily converted to accumulators having integrated mixing in the form of a mixing element; i.e. without high expenditures for manufacturing equipment.
- The mixing element can in particular have the form of a ring-shaped hollow body, whereby ring shape in this case does not refer exclusively to an annular shape but also any other circular ring form. The mixing element can be for example formed as, with the exception of the openings provided in the oppositely disposed end regions, a substantially closed hollow body. This enables the mixing element to be easily produced, e.g. from a plastic material.
- The mixing element can be advantageously manufactured with an internal mandrel and an external form, for example by injection molding. The mixing element can also be manufactured as a hollow body via a blow process or deep-drawing process. In conjunction hereto, the thin flow channel tapering toward the lower end region with respect to circumference has the further advantage of improving the demoldability of the mixing element during the manufacturing process.
- According to one advantageous further development, the circumference in the area of the thin flow channel decreases discontinuously over the longitudinal extension of the mixing element by means of one or more discontinuities. This results in a type of incremental decrease to the hollow body circumference. Doing so can further improve the mixing element's functional effectiveness in terms of the liquid electrolyte mixing effect. Providing one or more discontinuities over the course of the flow channel results in one or more graduated transitions of the flow resistance and thus a deceleration or acceleration in the electrolyte exchange between the volumetric space of the mixing element and the interior of the accumulator. It Is for example advantageous for two or three such discontinuities to be provided in the region of the thin flow channel. The discontinuities also further improve the demoldability of the mixing element during the manufacturing process.
- According to one advantageous further development of the invention, one or more discontinuities extend linearly over the longitudinal extension of the mixing element; i.e. depending on the embodiment, the circumferential decrease or cross-sectional reduction in these areas is linear. This enables simple and economical manufacture of the mixing element as well as improves the mechanical stability of the thin flow channel.
- According to one advantageous further development of the invention, the mixing element comprises at least two separated thin flow channels connected to the common volumetric space. One, multiple or all of the separated thin flow channels can be configured in accordance with the above-cited features of the thin flow channel, particularly with one or more discontinuities.
- According to one advantageous further development of the invention, the mixing element comprises an indentation on at least one side of the hollow body which runs in the longitudinal direction of the mixing element and is designed to receive an accumulator housing rib. This allows simple and reliable mechanical securing of the mixing element in the accumulator housing, provided same is configured with internal housing ribs. In this case, no additional mechanical securing means are necessary. The indentation can in particular be provided in the region of the volumetric space or respectively extend into this space such that the volumetric space is divided.
- According to one advantageous further development of the invention, the indentation is at least as deep as the extension of the thin flow channel in the same direction; i.e. in the direction of extension of the indentation. This enables a particularly sturdy mechanical securing of the mixing element to the housing rib of the accumulator housing. Additionally, at least two separate thin flow channels are thereby created.
- According to one advantageous further development of the invention, the mixing element comprises at least one securing and/or spacer rib protruding in the direction of the housing cover of the accumulator housing. Such a securing and/or spacer rib can fix the position of the mixing element relative to the housing cover and also secure the mixing element relative to the housing cover.
- According to one advantageous further development of the invention, the mixing element comprises at least one securing and/or spacer rib protruding in the direction of the bottom of the accumulator housing. Said securing and/or spacer rib can for example be arranged on the mixing element at the lower side of the volumetric space. The securing and/or spacer rib protruding in the direction of the bottom of the accumulator housing can ensure a defined downward positioning and securing of the mixing element. Thus, the downward protruding securing and/or spacer rib can rest on the electrodes or the separators encasing the electrodes respectively, thereby defining the mixing element's installation height in the housing.
- According to one advantageous further development of the invention, the mixing element comprises one or more outer circumferential securing and/or spacer ribs on one, some or all of its external sides facing the side walls of the accumulator housing. This has the advantage of the mixing element being able to be disposed at a defined horizontal position within a free space of a cell chamber, thereby preventing improper installation in the wrong position. Regarded as the side walls of the accumulator housing are thereby the accumulator's lateral external walls as well as the accumulator housing's internal walls constituting the partition walls between different cell chambers. In the substantially rectangular external cross section when viewed from above, the mixing element can in each case have one or more securing and/or spacer ribs on all four external sides or only on some or only one of the external sides.
- According to one advantageous further development of the invention, one or more securing and/or spacer ribs are arranged within the above-described indentation. In particular, one or more securing and/or spacer ribs can be arranged at respective oppositely disposed external sides of the mixing element within the indentation. Such securing and/or spacer ribs arranged within the indentation enable the mixing element to be pressed in wedge-like manner against an inner housing rib of the accumulator housing and secured to said housing rib. To this end, the securing and/or spacer ribs provided within the indentation can exhibit an outer contour which increases in the direction of insertion onto the housing rib so that the outer contour forms a wedge relative to the housing rib.
- According to one advantageous further development of the invention, at least two securing and/or spacer ribs are arranged to form a V-shaped pair. This has the advantage of the V-shaped construction being able to prevent a kinking of the spacer ribs when being fit into the housing or during the later actual operation of the accumulator. The securing and/or spacer ribs arranged in V-shaped pairs can thereby join and combine into a V-shaped rib or be arranged at a certain distance from one another.
- The initially specified task is solved in accordance with
claim 11 by a range of mixing elements of the above-described type, whereby the range comprises mixing elements of varying designs which differ from one another in the arrangement and/or dimensions of the securing and/or spacer ribs. By so doing, respectively suitable mixing elements can be made available for different accumulator types, sizes and designs without any further modifications being needed. The respective mixing element matching the given type of accumulator can thereby be installed without any material bonding procedure and fixed solely by means of clamping the securing and/or spacer ribs to the housing walls and/or housing ribs of the accumulator housing. - The initially specified task is solved in accordance with
claim 12 by an accumulator having a housing in which at least one accumulator cell is formed, whereby the accumulator cell comprises a plurality of adjacently arranged plated-shaped electrodes within the accumulator cell as well as liquid electrolyte, wherein at least one mixing element of the above-described type is additionally arranged in a free space within the accumulator cell. The inventive accumulator already provides a greater mixing effect at comparatively lower motion load and thereby prevents or at least substantially reduces acid stratification. - According to one advantageous further development of the invention, the mixing element is arranged laterally to a flat side of a plate-shaped electrode in the accumulator cell. The mixing element is hereby not held by the force of the protruding welded ends of the separator pocket as described in
DE 10 2010 048 428 A1 since it is disposed at the flat side of the plate-shaped electrode. According to one advantageous further development of the invention, a component integrated into the housing of the accumulator can be provided as the retaining means for mechanically fixing the mixing element in the accumulator cell. In particular, an internal housing rib of the accumulator housing can be used as a retaining means. - The mixing element can be also connected to the housing of the accumulator or the internal housing rib respectively, and thereby positionally fixed, by way of a known bonding process, e.g. plastic welding.
- According to one advantageous further development of the invention, the mixing element is arranged between a plate-shaped electrode and the housing wall or an internal housing rib formed on the housing wall.
- According to one advantageous further development of the invention, the housing exhibits a longitudinal extension which is the largest dimension of the housing's height, width and length dimensions, and the electrode plates exhibit a longitudinal extension which is the largest dimension of the individual electrode plates' height, width and length dimensions, and the electrode plates are orientationally positioned in a battery cell such that the longitudinal extension of the electrode plates runs substantially in the direction of the housing's longitudinal extension. This allows advantageously accommodating a large number of electrode plates in the housing with good use of the available installation space coupled with a simultaneously advantageous accommodation of one or more mixing elements in the housing.
- The following will reference the drawings in describing the invention in greater detail by way of embodiments.
- Shown are:
-
FIG. 1 a cross-sectional view of an accumulator with mixing element; -
FIGS. 2 and 3 the accumulator according toFIG. 1 under motion load; -
FIGS. 4-6 a first embodiment of a mixing element without external ribs; -
FIGS. 7-9 a second embodiment of a mixing element without external ribs; -
FIGS. 10-11 a third embodiment of a mixing element with external ribs; -
FIGS. 12-13 a fourth embodiment of a mixing element with external ribs; -
FIGS. 14-17 side sectional views of accumulators; -
FIG. 18 a plan view of an accumulator from above; and -
FIG. 19 stackable mixing elements. - The figures make use of the same reference numerals for equivalent elements.
FIGS. 1 to 3 and 18 depict the accumulator without a cover part; i.e. in a state in which the accumulator's upper side is still open. To complete manufacture, the accumulator housing is normally closed in the usual way with a cover part. -
FIG. 1 shows an accumulator 2 with a mixingelement 1 arranged in its housing 3.Electrode plates 5 are additionally arranged in the housing 3, or in a cell chamber 4 of the housing respectively, which are partially enclosed by (not shown) separators. The housing 3 or cell chamber 4 additionally containsliquid electrolyte 7, wherein theelectrolyte 7 is filled up tolevel 8. Ahousing rib 6 is further provided in the housing 3 or in cell chamber 4 respectively. The mixingelement 1 is fixed to thehousing rib 6, e.g. clamped to same. - As can be seen, the mixing
element 1 comprises avolumetric space 13 at its upper end region which transitions downward into athin flow channel 17 having a substantially smaller cross-sectional area compared tovolumetric space 13. Theflow channel 17 ends in one ormore openings 11 in a lower region of the mixing element. Thevolumetric space 13 is likewise open upwardly; i.e. anopening 10 is provided therein. The upper and thelower openings element 1 and the surrounding area of the accumulator housing 3 to be equalized at any time. Anelectrolyte level 9 is thus set in themixing element 1 which corresponds to theelectrolyte level 8 of the accumulator 2 and/or the respective cell chamber 4. -
FIGS. 2 and 3 show the function of the mixingelement 1 under accumulator 2 motion load. According toFIG. 2 , the accumulator is tipped at an angle to the left. From the originally equallyhigh levels level difference 12 since the electrolyte retained in themixing element 1 can only flow out through thethin flow channel 17 at a decelerated rate. The arrows depict the outflow of electrolyte into the accumulator's cell chamber 4. It is now assumed that the equalizing process of the accumulator tilted to the left inFIG. 2 Is finished so that thelevel 9 in the mixing element again corresponds tolevel 8. It is now assumed that the accumulator is then tilted for example somewhat to the right as depicted inFIG. 3 . This again results in alevel difference 12 betweenlevels level 9 being lower thanlevel 8 as perFIG. 3 . This results in electrolyte flowing back into the mixingelement 1 throughopening 11, as depicted by the arrows. The electrolyte is thus mixed and acid stratification thereby prevented or reduced. Advantageously, the mixingelement 1 is thereby constructed tall enough relative to the wall height of thevolumetric space 13 such that electrolyte is prevented from spilling over the upper edge of the mixingelement 1 directly into thevolumetric space 13 under normal motion load. When the accumulator is filled according to specification, such overspillage is allowed for up to a tilt angle of 20° relative to horizontal. A further embodiment allows for electrolyte overspillage up to a tilt angle of 35° relative to horizontal. - In regular operation; i.e. when the accumulator 2 is installed in a vehicle, the motion of the vehicle for example generates the motion load on the accumulator 2. Except for vehicle motion caused by road unevenness, longitudinal and lateral accelerations, e.g. when cornering, also result in the described accumulator 2 motion load.
-
FIGS. 4 to 6 show a first embodiment of the mixingelement 1.FIG. 4 thereby shows an isometric view,FIG. 5 a rear view, andFIG. 6 a side view. As can be seen, the mixingelement 1 comprises anindentation 15 which divides thevolumetric space 13 into two sub-areas, albeit connected together over a relatively large cross section. Theindentation 15 can serve in fitting the mixingelement 1 onto thehousing rib 6, as can be seen inFIGS. 1 and 16 . The mixing element can simply be set onto the housing rib and wedged there by means of theindentation 15. - A
floor 16 limits thevolumetric space 13 in the downward direction. Thevolumetric space 13 has an open design upward by means of opening 10. Intransition region 60 beneathfloor 16, thevolumetric space 13 transitions into athin flow channel 17 which extends downward toopening 11. Because of the partitioning created by theindentation 15, thethin flow channel 17 is divided into two sub-channels 40, 50, each having a respectivelower opening openings openings - As further indicated in the drawings, the
thin flow channel 17, or sub-channels 40, 50 respectively, have twolinear discontinuities transition 60. These discontinuities doubly reduce the circumference and thus also the inner cross-sectional area of the hollow body in the direction of the lower end region toward opening 11, 14. -
FIGS. 7 to 9 show a second embodiment of the mixingelement 1.FIG. 7 shows an isometric view,FIG. 8 a rear view, andFIG. 9 a side view. In contrast to the mixing element according toFIGS. 4 to 6 , the mixingelement 1 depicted here has in each case further divided sub-channels 43, 44, 53, 54, e.g. in the form of channels of circular cross section, in the lower regions of theflow channels discontinuity lower opening -
FIGS. 1 to 9 will be used to illustrate the basic function and design of the inventive mixing element by way of embodiments in which the mixing element does not comprise any securing and/or spacer ribs, referred to only as ribs in the following for short.FIGS. 10 to 19 will be used in the following in describing mixing elements comprising the respective external ribs. -
FIGS. 10 and 11 show two different isometric views of amixing element 1 corresponding to the mixing element according toFIGS. 7 to 9 and additionally comprising external ribs. Depicted in each case is only the respective upper area of the mixing element provided with the ribs; the sections underneath correspond toFIGS. 7 to 9 . The mixing element embodiments comprising ribs described in the following can also, however, be of any other desired design with respect to the lower flow channels, e.g. as perFIGS. 4 to 6 or the like. - The mixing
element 1 according toFIGS. 10 and 11 comprises an upwardprotruding rib 133 at the upper edge of the rear wall 30 ofvolumetric space 13, the ends of which can be angled toward theside wall regions volumetric space 13. Therib 133 extends in the direction of a housing cover of the accumulator housing so that the mixingelement 1, when set into the housing, can be vertically fixed by the housing cover by way of therib 133. - For the additional downward vertical fixing,
ribs 61 are provided below at thelower side 60 of thevolumetric space 13 which form a counter bearing to theupper rib 133 for fixing the mixingelement 1 in an accumulator housing. The mixingelement 1 can thus be clamped between the housing cover and the electrode plates, or their separators respectively, by means of theupper rib 133 and the downward-facingribs 61 disposed at the bottom of the housing or an electrode plate pack of the accumulator respectively. - For the horizontal fixing and positioning, the mixing element comprises
ribs respective side walls Ribs volumetric space 13 opposite therear wall 130 which are each arranged to form a V-shaped pair when the side of thevolumetric space 13 to which they are fixed is viewed from above. To simplify the introduction of the mixingelement 1 into the accumulator housing from above, theribs - Outward pointing
ribs 152, 153 can be arranged within theindentation 15 on respectiveopposite walls volumetric space 13 by means of which the mixing element can be clamped to thehousing rib 6. - The various ribs described with reference to
FIGS. 10 and 11 do not always need to be realized fully in the mixing element or in the depicted dimensions. In fact, the ribs allow the mixing element to be adapted to other accumulator housing designs, for example by modifying the dimensions of the ribs or omitting individual ribs. An example of this Is illustrated in the following referencing an alternative embodiment as depicted inFIGS. 12 and 13 . - The mixing
element 1 according toFIGS. 12 and 13 only comprisesribs Ribs 61 are hereby configured at a shorter overall height than inFIGS. 10 and 11 . The mixing element can thereby be installed for example into a housing of shorter overall height than the housing applicable toFIGS. 10 and 11 . This is depicted in the following referencingFIGS. 14 to 17 . -
FIG. 14 andFIG. 17 respectively show a side view of an accumulator looking toward therear wall 130 of thevolumetric space 13 of the mixingelement 1,FIGS. 15 and 16 respectively showing a view ofside wall 131 / 132.FIGS. 14 and 15 hereby reflect the mixing element according toFIGS. 10 and 11 ;FIGS. 16 and 17 , the mixing element according toFIGS. 12 and 13 . The accumulator according toFIGS. 14 and 15 has a housing of larger overall height than the accumulator inFIGS. 16 and 17 . It can be seen that the mixing element is in each case set onto ahousing rib 6 and clamped between anelectrode plate pack 5 and ahousing cover 100 of the accumulator and thereby vertically fixed. -
FIG. 18 shows a six-celled accumulator 2 in plan view, whereby the accumulator's housing cover has again not yet been positioned into place, thus visible being the sixindividual accumulator cells electrode plates 5 arranged therein. Anelectrode plate group 5 is only depicted incell chamber 94 by way of example. It can be seen that as far as their greatest dimension LE, theelectrode plates 5 extend in the same direction as the greatest dimension LG of the housing 3 of the accumulator 2. It can further be seen that the housing 3 compriseshousing ribs 6. A mixingelement 1 fit onto ahousing rib 6 is exemplarily depicted in eachcell chamber external side walls 101 andinternal walls 102. Theinternal walls 102 divide the interior of the housing 3 into cell chambers for theaccumulator cells -
FIG. 19 shows an example stackable design of themixing elements 1 into one another using the mixing elements ofFIGS. 10 and 11 (left) andFIGS. 12 and 13 (right). Such a design can thereby save space and simplify automated assembly of mixing elements.
Claims (12)
Priority Applications (1)
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US201615036974A | 2016-05-16 | 2016-05-16 | |
US17/109,761 US20210104780A1 (en) | 2014-01-24 | 2020-12-02 | Mixing element and accumulator |
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US15/036,974 Continuation US10886571B2 (en) | 2014-01-24 | 2014-11-04 | Modification of truck mixing element for manual and automatic assembly |
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- 2014-11-04 US US15/036,974 patent/US10886571B2/en active Active
- 2014-11-04 EP EP14793132.3A patent/EP3097597B1/en active Active
- 2014-11-04 BR BR112016007582-0A patent/BR112016007582B1/en active IP Right Grant
- 2014-11-04 JP JP2016529448A patent/JP6602758B2/en active Active
- 2014-11-04 CN CN201480048423.9A patent/CN105765754B/en active Active
- 2014-11-04 CN CN201910266127.0A patent/CN110247126B/en active Active
- 2014-11-04 KR KR1020217024079A patent/KR102422806B1/en active IP Right Grant
- 2014-11-04 WO PCT/EP2014/073661 patent/WO2015110192A1/en active Application Filing
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CN110247126A (en) | 2019-09-17 |
US10886571B2 (en) | 2021-01-05 |
WO2015110192A1 (en) | 2015-07-30 |
CN105765754B (en) | 2019-04-26 |
BR112016007582A2 (en) | 2017-08-01 |
KR20210096699A (en) | 2021-08-05 |
BR112016007582B1 (en) | 2021-12-14 |
CN110247126B (en) | 2024-05-07 |
MX2016009418A (en) | 2016-09-16 |
EP3097597A1 (en) | 2016-11-30 |
KR20160113091A (en) | 2016-09-28 |
DE102014100806A1 (en) | 2015-07-30 |
US20160294020A1 (en) | 2016-10-06 |
MX2021008556A (en) | 2021-08-24 |
JP6602758B2 (en) | 2019-11-06 |
KR102285864B1 (en) | 2021-08-05 |
JP2017505506A (en) | 2017-02-16 |
DE102014100806B4 (en) | 2019-02-07 |
KR102422806B1 (en) | 2022-07-20 |
CN105765754A (en) | 2016-07-13 |
EP3097597B1 (en) | 2018-09-26 |
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