US20210102340A1 - Production of highly stretchable paper having satisfactory surface properties - Google Patents

Production of highly stretchable paper having satisfactory surface properties Download PDF

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Publication number
US20210102340A1
US20210102340A1 US16/500,320 US201816500320A US2021102340A1 US 20210102340 A1 US20210102340 A1 US 20210102340A1 US 201816500320 A US201816500320 A US 201816500320A US 2021102340 A1 US2021102340 A1 US 2021102340A1
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Prior art keywords
paper
iso
pulp
paper web
refining
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US16/500,320
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English (en)
Inventor
Nils NORDLING
Fredrik Nordsröm
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Billerudkorsnas AB
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Billerudkorsnas AB
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Assigned to BILLERUDKORSNÄS AB reassignment BILLERUDKORSNÄS AB ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: Nordling, Nils, Nordström, Fredrik
Publication of US20210102340A1 publication Critical patent/US20210102340A1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F17/00—Printing apparatus or machines of special types or for particular purposes, not otherwise provided for
    • B41F17/003—Special types of machines for printing textiles
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00—Methods of beating or refining; Beaters of the Hollander type
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00—Methods of beating or refining; Beaters of the Hollander type
    • D21D1/20—Methods of refining
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F9/00—Complete machines for making continuous webs of paper
    • D21F9/02—Complete machines for making continuous webs of paper of the Fourdrinier type
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G1/00—Calenders; Smoothing apparatus
    • D21G1/002—Opening or closing mechanisms; Regulating the pressure
    • D21G1/004—Regulating the pressure
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G1/00—Calenders; Smoothing apparatus
    • D21G1/006—Calenders; Smoothing apparatus with extended nips
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
    • D21H11/04—Kraft or sulfate pulp
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/18—Highly hydrated, swollen or fibrillatable fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/005—Mechanical treatment
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper

Definitions

  • the invention relates to the production of a highly stretchable paper having satisfactory surface properties.
  • FibreForm® BillerudKorsnäs AB (Sweden) has marketed a highly stretchable paper under the name FibreForm® since 2009. The stretchability of FibreForm® allows it to replace plastics in many applications. FibreForm has been produced on paper machine comprising an Expanda unit that compacts/creps the paper in the machine direction to improve the stretchability.
  • the object of the present disclosure is to provide a method of producing a highly stretchable uncoated paper that is not a typical porous sack paper on a paper machine comprising a Clupak unit without compromising with printability.
  • step d) diluting the pulp from step c) and adding the diluted pulp to a forming wire to obtain a paper web having a dry content of 15-25%, such as 17-23%;
  • step d) pressing the paper web from step d) to a dry content of 30-50%, such as 36-46%;
  • step f) compacting the paper web from step f) in a Clupak unit at a moisture content of 20-50%, such as 30-49%, such as 35-49%;
  • step h) calendering the paper web from step h) in a soft nip calender or a long nip calender at a moisture content of 4 -20%, such as 5-12%, such as 5-10%.
  • FIG. 1 is a schematic illustration of a Clupak unit.
  • the present disclosure relates to a method of producing uncoated paper. Subsequent to the method of the present disclosure, the paper may be coated, e.g. to improve printing properties and/or to obtain barrier properties.
  • the paper obtained by the method is characterized by its stretchability, which is at least 9 % in the machine direction (MD).
  • the stretchability in MD is even higher than 9 %, such as at least 10% or at least 11%.
  • the stretchability enables formation of three-dimensional (double curvature) shapes in the paper, e.g. by press forming, vacuum forming or deep drawing.
  • the formability of the paper in such processes is further improved if the stretchability is relatively high also in the cross direction (CD).
  • the stretchability in CD is at least 7 %, such as at least 9 %.
  • An upper limit for the stretchability in MD may for example be 20% or 25%.
  • An upper limit for the stretchability in CD may for example be 15%.
  • the stretchability (in both MD and CD) is determined according to the standard ISO 1924-3.
  • the paper of the present disclosure is not particularly porous. Instead, relatively low porosity may be preferred in the applications intended for the paper of the present disclosure. For example, glue and some coatings have a lower tendency to bleed through a paper of low porosity. Further, some printing properties are improved when the porosity is reduced.
  • the air resistance according to Gurley i.e. the Gurley porosity
  • Gurley porosity is a measurement of the time (s) taken for 100 ml of air to pass through a specified area of a paper sheet. Short time means highly porous paper.
  • the Gurley porosity of the paper of the present disclosure is above 15 s.
  • the Gurley porosity is preferably at least 20 s and more preferably 25 s, such as at least 35 s. An upper limit may for example be 120 s or 150 s.
  • the Gurley porosity (herein also referred to as the “Gurley value”) is determined according to ISO 5636-5.
  • the grammage of the paper of the present disclosure is 50-250 g/m 2 . If a stretchable material having a grammage above 250 g/m 2 is desired, a laminate can be produced from a plurality of paper layers each having a grammage in the range of 50-250 g/m 2 . Below 50 g/m 2 the strength and rigidity is typically insufficient.
  • the grammage is preferably 60-220 g/m 2 and more preferably 80-200 g/m 2 , such as 80-160 g/m 2 , such as 80-130 g/m 2 .
  • the standard ISO 536 is used to determine the grammage. The Bendtsen roughness is typically lower when the grammage is lower.
  • the density of the paper is typically between 700 and 1000 kg/m 3 .
  • a long nip calender (further discussed below) can be selected.
  • Preferred density ranges are 700-800 kg/m 3 and 710-780 kg/m 3 .
  • the paper of the present disclosure is preferably white.
  • its brightness according to ISO 2470 may be at least 80%, such as at least 82%.
  • the paper may also be unbleached (“brown”).
  • the method of the present disclosure comprises the step of:
  • the pulp is preferably a sulphate pulp (sometimes referred to as a “Kraft pulp”), which provides high tensile strength.
  • the starting material used for preparing the pulp preferably comprises softwood (which has long fibers and forms a strong paper). Accordingly, the pulp may comprise at least 50% softwood pulp, preferably at least 75% softwood pulp and more preferably at least 90% softwood pulp. The percentages are based of the dry weight of the pulp.
  • the tensile strength is the maximum force that a paper will withstand before breaking. In the standard test ISO 1924-3, a stripe having a width of 15 mm and a length of 100 mm is used with a constant rate of elongation.
  • Tensile energy absorption (TEA) is sometimes considered to be the paper property that best represents the relevant strength of a paper.
  • the tensile strength is one parameter in the measurement of the TEA and another parameter is stretchability.
  • the tensile strength, the stretchability and the TEA value are obtained in the same test.
  • the TEA index is the TEA value divided by the grammage. In the same manner, the tensile index is obtained by dividing the tensile strength by the grammage.
  • a dry strength agent such as starch
  • the amount of starch may for example be 1-15 kg per ton paper, preferably 1-10 or 2-8 kg per ton paper.
  • the starch is preferably cationic starch.
  • per ton paper refers to per ton of dried paper from the paper making process. Such dried paper normally has a dry matter content (w/w) of 90-95%.
  • the TEA index of the paper obtained by the method of the present disclosure may for example be at least 3.5 J/g in the MD (e.g. 3.5-7.5 J/g) and/or at least 2.9 J/g (e.g. 2.9-3.9 J/g) in the CD. In one embodiment, the TEA index is above 4.5 J/g (e.g. 4.6-7.5 J/g) in MD.
  • One or more sizing agent may also be added to the pulp.
  • sizing agents are AKD, ASA and rosin size.
  • Rosin size and alum is preferably added in a weight ratio between 1:1 and 1:2. Rosin size can for example be added in an amount of 0.5-4 kg per ton paper, preferably 0.7-2.5 kg per ton paper.
  • the method further comprises the step of:
  • the consistency of the pulp subjected to HC refining is typically 25-42% or 25-40%, such as 30-40%, preferably 33-40%.
  • the HC refining is typically carried out to the extent that the pulp obtains a Schopper-Riegler (SR) number of 13-19, such as 13-18.
  • the SR number is measured according to ISO 5267-1.
  • the energy supply in the HC refining may be at least 100 kWh per ton paper, such as 150-220 kWh per ton paper.
  • the method further comprises the step of:
  • the consistency of the pulp subjected to LC refining is typically 2-6%, preferably 3-5%.
  • the LC refining is typically carried out to the extent that the pulp obtains a Schopper-Riegler (SR) number of 18-40, preferably 19-35, such as 23-35.
  • SR Schopper-Riegler
  • the energy supply in the LC refining may be 20-200 kWh per ton paper, such as 30-150 kWh per ton paper, such as 40-120 kWh per ton paper.
  • LC refining increases the SR number.
  • the HC refining and the LC refining increase the stretchability in both MD and CD.
  • the method comprises a step of adding broke pulp, preferably to the pulp from step b) or c).
  • the broke pulp is preferably obtained from the same method.
  • the method further comprises the step of:
  • step d) diluting the pulp from step c) and adding the diluted pulp to a forming wire to obtain a paper web having a dry content of 15-25%, such as 17-23%.
  • the diluted pulp is thus dewatered on the forming wire and a paper web is formed.
  • the diluted pulp typically has a pH of 5-6 and a consistency of 0.2-0.5%.
  • the method further comprises the step of:
  • step d) pressing the paper web from step d) to a dry content of 30-50%, such as 36-46%.
  • the pressing section used for step e) typically has one, two or three press nips.
  • a shoe press is used.
  • the nip of the shoe press can be the only nip of the pressing section.
  • a benefit of using a shoe press is improved bending stiffness in the final product.
  • the method further comprises the step of:
  • step f) compacting the paper web from step f) in a Clupak unit at a moisture content of 20-50%.
  • the compacting in the Clupak unit increases the stretchability of the paper, in particular in the MD, but also in the CD.
  • the moisture content of the paper is preferably at least 3 0% (e.g. 30-50%), such as at least 35% (e.g. 35-49%), when entering the Clupak unit. Higher moisture contents have also been shown to correlate with higher stretchabilities in the MD.
  • the inventors have found that the increase in stretchability is facilitated by a relatively high nip bar line load, i.e. at least 20 kN/m, in the Clupak unit.
  • the nip bar line load is at least 2 5 kN/m or at least 28 kN/m.
  • a typical upper limit may be 38 kN/m.
  • the nip bar line load is controlled by the adjustable hydraulic cylinder pressure exerted on the nip bar.
  • the nip bar is sometimes referred to as the “nip roll”.
  • the rubber belt tension in the Clupak unit is at least 5 kN/m (such as 5-9 kN/m), preferably at least 6 kN/m (such as 6-9 kN/m), such as about 7 kN/m.
  • the rubber belt tension is controlled by the adjustable hydraulic cylinder pressure exerted on the tension roll stretching the rubber belt.
  • the Clupak unit typically comprises a steel cylinder or a chromed cylinder.
  • the release liquid may be water or water-based.
  • the water-based release liquid may comprise a friction-reducing agent, such as polyethylene glycol or a silicone-based agent.
  • the release liquid is water comprising at least 0.5%, preferably at least 1%, such as 1-4%, polyethylene glycol.
  • a Clupak unit is also described below with reference to FIG. 1 .
  • the method further comprises the step of h) drying the paper web from step g).
  • Step h) thus comprises subjecting the paper web to drying in at least one dryer group.
  • the speed of the paper web in the first dryer group of step h) is preferably 8-14% lower than the speed of the paper web entering the Clupak unit in step g).
  • the reason for lowering the speed in this manner is to maintain the MD stretchability obtained by the paper web in the Clupak unit.
  • the paper web is preferably allowed to dry freely during part of step h). During such “free drying”, which improves the stretchability, the paper web is not in contact with a dryer screen (often referred to as a dryer fabric).
  • a forced, optionally heated, air flow (sometimes referred to as “impingement drying”) may be used in the free drying, which means that the free drying may comprise fan drying.
  • the method further comprises the step of:
  • long nip calender includes what is referred to in the art as shoe calenders, extended nip calenders and belt calenders.
  • calendering improves surface properties.
  • a soft nip calender or a long nip calender is used as such calenders better preserves the bending resistance of the paper than hard nip calenders.
  • the long nip calender is the most preferred option.
  • the line load may be 20-700 kN/m.
  • Preferred line load ranges are 20-450 kN/m and 100-400 kN/m.
  • the bending resistance index is obtained by dividing the bending resistance by the cube of the grammage.
  • the bending resistance index in the MD of the paper is preferably at least 30 Nm 6 /kg 3 (e.g. 30-43 Nm 6 /kg 3 ), such as at least 35 Nm 6 /kg 3 (e.g. 35-43 Nm 6 /kg 3 ).
  • the bending resistance in the CD is preferably at least 40 Nm 6 /kg 3 (e.g. 40-56 Nm 6 /kg 3 ), such as at least 45 Nm 6 /kg 3 (e.g. 45-56 Nm 6 /kg 3 ).
  • the bending resistance is measured according to ISO 2493 using a bending angle of 15° and a test span length of 10 mm.
  • the bending resistance index is at least 39 Nm 6 /kg 3 in the MD and at least 51 Nm 6 /kg 3 in the CD.
  • a soft nip calender at a line load below 150 kN/m or a long nip calender.
  • a paper having a bending resistance index of at least 44 Nm 6 /kg 3 e.g. 44-56 Nm 6 /kg 3
  • at least 54 Nm 6 /kg 3 e.g. 54-62 Nm 6 /kg 3
  • the calendering of step i) is carried out using a long nip calender with a nip length in the machine direction of 30-400 mm, such as 30-250 mm. Further, a metal roll heated to a temperature between 140 and 260° C., preferably between 200 and 250° C., is used in the long nip calendering of step i).
  • the nip length of the shoe calender is just 30-50 mm, while the temperature of the metal roll of the shoe calender is above 200° C. and the line load is at least 100 kN/m.
  • Such an embodiment may efficiently reduce undesirable surface patterns formed in the Clupak unit.
  • the Bendtsen roughness of at least one side of the paper from step i) is 1900 ml/min or lower, such as 1700 ml/min or lower.
  • the Bendtsen roughness of the at least one side of the paper is 1200 ml/min or lower, such as 900 ml/min or lower. In one embodiment, it is 700 ml/min or lower, such as 600 ml/min or lower.
  • a typical lower limit may be 300 ml/min or 400 ml/min.
  • the Bendtsen roughness of both sides of the paper is below 1000 ml/min.
  • the method of the present disclosure further comprises the step of:
  • step j) may be on any side of the paper, but it may be preferred to print the side that contacts the steel/chromed cylinder in the
  • FIG. 1 illustrates a Clupak unit 105 , comprising an endless rubber belt 107 (sometimes referred to as a “rubber blanket”) contacted by two blanket rolls 108 , 109 , a guide roll 110 , a tension roll 111 and a nip bar 112 .
  • a first hydraulic arrangement 113 exerts pressure on the tension roll 111 to stretch the rubber belt 107 .
  • a second hydraulic arrangement 114 exerts pressure on the nip bar 112 to press the rubber belt 107 , which in turns presses the paper web 117 against a steel cylinder 115 .
  • a release liquid spray nozzle 116 is arranged to apply a release liquid to the steel cylinder 115 .
  • a bleached softwood sulphate pulp was provided.
  • the pulp was subjected to high consistency (HC) refining (180 kWh per ton paper) at a consistency of about 39% and low consistency (LC) refining (65 kWh per ton paper) at a consistency of about 4.3%.
  • Cationic starch (7 kg per ton paper), rosin size (2.4 kg per ton paper) and alum (3.5 kg per ton paper) were added to the pulp.
  • the pH of the pulp/furnish was about 5.8 and the consistency of the pulp/furnish was about 0.3%.
  • a paper web was formed on a wire section. The dry content of the paper web leaving the wire section was about 19%.
  • the paper web was dewatered in a press section having two nips to obtain a dry content of about 38%.
  • the dewatered paper web was then dried in a subsequent drying section having nine dryer groups, including one Clupak unit, arranged in series.
  • the Clupak unit was thus considered to be a “dryer group”.
  • the Clupak unit was arranged as dryer group seven, which means that the paper web was dried in the drying section both before and after being compacted in the Clupak unit.
  • the moisture content of the paper web was 40%.
  • the hydraulic cylinder pressure exerted on the nip bar was set to 30 bar, resulting in a line load of 33 kN/m.
  • the hydraulic cylinder pressure stretching the rubber belt was set to 31 bar, resulting in a belt tension of 7 kN/m.
  • a release liquid (1.5% polyetylene glycol) was added in an amount of 250 litre/hour.
  • the speed of the paper web in the dryer group directly downstream the Clupak was 11% lower than the speed of the paper web entering the Clupak unit
  • the inventive paper was subjected to calendering in a soft nip calender having a hard roll (steel surface) and a soft roll (surface covered with rubber).
  • the line load in the soft nip calender was 145 kN/m.
  • the temperature and moisture content of the paper entering the soft nip calender was 80° C. and 6.5%, respectively.
  • the reference paper was not calendered.
  • the visual impression of the quality of the print on the steel side (SS) and the rubber side (RS) of the calendered (inventive) paper was compared to that of the non-calendered (reference) paper.
  • the same type of comparison was also made after the papers had been subjected to 3 D-forming. According to the comparison, the print quality was significantly better on both sides of the calendered (inventive) paper than on the reference paper before and after 3 D-forming.
  • the comparison also showed that the print quality was better on the side that contacted the steel cylinder in the Clupak unit.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Paper (AREA)
US16/500,320 2017-04-06 2018-04-05 Production of highly stretchable paper having satisfactory surface properties Abandoned US20210102340A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17165160.7 2017-04-06
EP17165160.7A EP3385445B1 (en) 2017-04-06 2017-04-06 Production of highly stretchable paper having satisfactory surface properties
PCT/EP2018/058720 WO2018185216A1 (en) 2017-04-06 2018-04-05 Production of highly stretchable paper having satisfactory surface properties

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US (1) US20210102340A1 (pl)
EP (2) EP3385445B1 (pl)
CN (1) CN110249094A (pl)
AU (1) AU2018248870B2 (pl)
BR (1) BR112019017757B1 (pl)
CA (1) CA3048107A1 (pl)
FI (1) FI3607143T3 (pl)
PL (1) PL3385445T3 (pl)
RU (1) RU2765135C2 (pl)
WO (1) WO2018185216A1 (pl)

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AT526106A1 (de) * 2022-05-03 2023-11-15 Mondi Ag Kraftpapier

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AT524609B1 (de) * 2020-12-29 2022-10-15 Mondi Ag Tray-Packungseinheits-Umverpackungspapier und Verfahren zur Herstellung
AT18074U1 (de) * 2022-09-30 2023-12-15 Mondi Ag Verpackungsmaterial
EP4353902A1 (en) * 2022-10-12 2024-04-17 Tetra Laval Holdings & Finance S.A. Use of a paper substrate, the barrier-coated paper substrate, a laminated packaging material and packaging container comprising it
EP4353901A1 (en) 2022-10-12 2024-04-17 Billerud Aktiebolag (publ) Stretchable high-density paper
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* Cited by examiner, † Cited by third party
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EP4101980A1 (de) * 2021-06-10 2022-12-14 Mondi AG Verpackungspapier sowie verfahren zur herstellung desselben
EP4101979A1 (de) * 2021-06-10 2022-12-14 Mondi AG Verpackungspapier sowie verfahren zur herstellung desselben
US11965291B2 (en) 2021-06-10 2024-04-23 Mondi Ag Packing paper
AT526106A1 (de) * 2022-05-03 2023-11-15 Mondi Ag Kraftpapier
AT526106B1 (de) * 2022-05-03 2024-02-15 Mondi Ag Kraftpapier

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BR112019017757B1 (pt) 2023-04-25
FI3607143T3 (fi) 2024-04-19
EP3385445A1 (en) 2018-10-10
WO2018185216A1 (en) 2018-10-11
EP3385445B1 (en) 2019-06-05
CA3048107A1 (en) 2018-10-11
AU2018248870A1 (en) 2019-03-14
EP3607143A1 (en) 2020-02-12
AU2018248870B2 (en) 2022-09-29
CN110249094A (zh) 2019-09-17
RU2019122468A (ru) 2021-05-06
PL3385445T3 (pl) 2019-12-31
RU2765135C2 (ru) 2022-01-25
BR112019017757A2 (pt) 2020-03-31
RU2019122468A3 (pl) 2021-07-13

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