US20190288660A1 - Joint - Google Patents
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- US20190288660A1 US20190288660A1 US16/422,322 US201916422322A US2019288660A1 US 20190288660 A1 US20190288660 A1 US 20190288660A1 US 201916422322 A US201916422322 A US 201916422322A US 2019288660 A1 US2019288660 A1 US 2019288660A1
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- tantalum
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- 239000000758 substrate Substances 0.000 claims abstract description 130
- 239000010955 niobium Substances 0.000 claims abstract description 35
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 35
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 33
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 20
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 claims description 4
- 229910012463 LiTaO3 Inorganic materials 0.000 claims 2
- 239000010410 layer Substances 0.000 description 77
- 238000000034 method Methods 0.000 description 23
- 239000010408 film Substances 0.000 description 19
- 238000010897 surface acoustic wave method Methods 0.000 description 17
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- WSMQKESQZFQMFW-UHFFFAOYSA-N 5-methyl-pyrazole-3-carboxylic acid Chemical compound CC1=CC(C(O)=O)=NN1 WSMQKESQZFQMFW-UHFFFAOYSA-N 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000001133 acceleration Effects 0.000 description 6
- 235000019687 Lamb Nutrition 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000005498 polishing Methods 0.000 description 5
- 238000004544 sputter deposition Methods 0.000 description 5
- 239000010409 thin film Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- GQYHUHYESMUTHG-UHFFFAOYSA-N lithium niobate Chemical compound [Li+].[O-][Nb](=O)=O GQYHUHYESMUTHG-UHFFFAOYSA-N 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052863 mullite Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000010884 ion-beam technique Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 2
- 230000000644 propagated effect Effects 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910017083 AlN Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910003564 SiAlON Inorganic materials 0.000 description 1
- GDFCWFBWQUEQIJ-UHFFFAOYSA-N [B].[P] Chemical compound [B].[P] GDFCWFBWQUEQIJ-UHFFFAOYSA-N 0.000 description 1
- -1 acryl Chemical group 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- RHDUVDHGVHBHCL-UHFFFAOYSA-N niobium tantalum Chemical compound [Nb].[Ta] RHDUVDHGVHBHCL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000000678 plasma activation Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B33/00—After-treatment of single crystals or homogeneous polycrystalline material with defined structure
- C30B33/06—Joining of crystals
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/02—Details
- H03H9/02535—Details of surface acoustic wave devices
- H03H9/02543—Characteristics of substrate, e.g. cutting angles
- H03H9/02574—Characteristics of substrate, e.g. cutting angles of combined substrates, multilayered substrates, piezoelectrical layers on not-piezoelectrical substrate
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/16—Oxides
- C30B29/22—Complex oxides
- C30B29/30—Niobates; Vanadates; Tantalates
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B33/00—After-treatment of single crystals or homogeneous polycrystalline material with defined structure
- C30B33/04—After-treatment of single crystals or homogeneous polycrystalline material with defined structure using electric or magnetic fields or particle radiation
-
- H01L41/18—
-
- H01L41/312—
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H3/00—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
- H03H3/007—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
- H03H3/08—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of resonators or networks using surface acoustic waves
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/02—Details
- H03H9/02007—Details of bulk acoustic wave devices
- H03H9/02015—Characteristics of piezoelectric layers, e.g. cutting angles
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/02—Details
- H03H9/02007—Details of bulk acoustic wave devices
- H03H9/02047—Treatment of substrates
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/02—Details
- H03H9/02007—Details of bulk acoustic wave devices
- H03H9/02086—Means for compensation or elimination of undesirable effects
- H03H9/02102—Means for compensation or elimination of undesirable effects of temperature influence
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/02—Details
- H03H9/02535—Details of surface acoustic wave devices
- H03H9/02543—Characteristics of substrate, e.g. cutting angles
- H03H9/02559—Characteristics of substrate, e.g. cutting angles of lithium niobate or lithium-tantalate substrates
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/02—Details
- H03H9/02535—Details of surface acoustic wave devices
- H03H9/02614—Treatment of substrates, e.g. curved, spherical, cylindrical substrates ensuring closed round-about circuits for the acoustical waves
- H03H9/02622—Treatment of substrates, e.g. curved, spherical, cylindrical substrates ensuring closed round-about circuits for the acoustical waves of the surface, including back surface
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/02—Details
- H03H9/05—Holders; Supports
- H03H9/058—Holders; Supports for surface acoustic wave devices
- H03H9/0585—Holders; Supports for surface acoustic wave devices consisting of an adhesive layer
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/02—Details
- H03H9/05—Holders; Supports
- H03H9/058—Holders; Supports for surface acoustic wave devices
- H03H9/059—Holders; Supports for surface acoustic wave devices consisting of mounting pads or bumps
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/25—Constructional features of resonators using surface acoustic waves
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
- H10N30/07—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base
- H10N30/072—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base by laminating or bonding of piezoelectric or electrostrictive bodies
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
- H10N30/07—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base
- H10N30/072—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base by laminating or bonding of piezoelectric or electrostrictive bodies
- H10N30/073—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base by laminating or bonding of piezoelectric or electrostrictive bodies by fusion of metals or by adhesives
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/80—Constructional details
- H10N30/85—Piezoelectric or electrostrictive active materials
Definitions
- a surface acoustic wave device functioning as a filter device or oscillator used in mobile phones or the like, and an acoustic wave device such as lamb wave device or film bulk acoustic resonator (FBAR) using a piezoelectric thin film.
- acoustic wave device it is known a device produced by adhering a supporting substrate and a piezoelectric substrate propagating a surface acoustic wave and by providing interdigitated electrodes capable of oscillating the surface acoustic wave on a surface of the piezoelectric substrate.
- the change of a size of the piezoelectric substrate responsive to temperature change is reduced so that the change of the frequency characteristics as the surface acoustic wave device is reduced.
- a surface acoustic wave device having the structure produced by adhering a piezoelectric substrate and silicon substrate with an adhesive layer composed of an epoxy adhering agent.
- a silicon oxide film is formed on a surface of the piezoelectric substrate and that a silicon substrate and the piezoelectric substrate are bonded through the silicon oxide film (patent document 2).
- plasma beam is irradiated onto the surfaces of the silicon oxide film and silicon substrate to activate the surfaces, followed by the direct boding (Plasma activation method).
- a surface of the piezoelectric substrate is made a roughened surface, a filler layer is provided on the roughened surface to provide a flattened surface and the filler layer is adhered onto a silicon substrate through an adhering layer (patent document 3).
- an epoxy-based or acryl-based resin is used for the filler layer and adhering layer, and the bonding surface of the piezoelectric substrate is made the roughened surface to reduce the reflection of bulk wave and to reduce spurious wave.
- a piezoelectric monocrystalline substrate is directly bonded to a supporting substrate made of a ceramic material (alumina, aluminum nitride, silicon nitride) and not to a silicon substrate, through an intermediate layer.
- the material of the intermediate layer is silicon, silicon oxide, silicon nitride or aluminum nitride.
- the present invention provides a bonded body comprising a supporting substrate, a piezoelectric monocrystalline substrate and a bonding layer provided between said supporting substrate and said piezoelectric monocrystalline substrate,
- said piezoelectric monocrystalline substrate comprises a material represented by LiAO 3 (A represents at least one element selected from the group consisting of niobium and tantalum),
- said bonding layer comprises a material comprising an oxide of at least one element selected from the group consisting of niobium and tantalum, and
- microstructure in which a piezoelectric monocrystalline substrate made of lithium niobite, lithium tantalate or the like and a supporting substrate strongly.
- FIG. 1( a ) is a diagram schematically showing a bonded body 7 according to an embodiment of the present invention
- FIG. 1( b ) is an enlarged view showing essential parts of the bonded body 7
- FIG. 1( c ) is a view showing essential parts of another bonded body.
- FIG. 2 is a photograph showing essential parts of a bonded body according to an embodiment of the present invention.
- FIG. 3( a ) shows the state that a bonded body 2 is provided on a supporting substrate 1
- FIG. 3( b ) shows the state that a surface 3 a of a bonding layer 3 is subjected to flattening process
- FIG. 3( c ) shows the state that a flat surface 4 is activated by neutralized beam A.
- FIG. 4( a ) shows the state that a surface 6 c of a piezoelectric monocrystalline substrate 6 is activated by neutralized beam A
- FIG. 4( b ) shows the state that the surface 6 a of the piezoelectric monocrystalline substrate 6 is activated.
- FIG. 5( a ) shows the state that the piezoelectric monocrystalline substrate 6 and supporting substrate 1 are bonded
- FIG. 5( b ) shows the state that a piezoelectric monocrystalline substrate 6 A is thinned by processing
- FIG. 5( c ) shows the state that electrodes 10 are provided on the piezoelectric monocrystalline substrate 6 A.
- the bonded body of the present invention includes a supporting substrate, a piezoelectric monocrystalline substrate and a bonding layer provided between the supporting substrate and piezoelectric monocrystalline substrate.
- a bonded body 7 shown in FIG. 1( a ) an activated surface 6 a of a piezoelectric monocrystalline substrate 6 is bonded onto a surface 1 a of a supporting substrate 1 through a bonding layer 3 A.
- 1 b represents a surface on the opposite side of the surface 1 a of the supporting substrate.
- the material of the piezoelectric monocrystalline substrate is made LiAO 3 .
- A represents at least one element selected from the group consisting of niobium and tantalum.
- LiAO 3 may be lithium niobate, lithium tantalate or lithium niobate-lithium tantalate solid solution.
- the material of the bonding layer is made an oxide of at least one element selected from the group consisting of niobium and tantalum.
- the oxide maybe an oxide of tantalum, an oxide of niobium or a composite oxide of niobium and tantalum.
- an interface layer having a composition of E x O (1-x) (E represents at least one element selected from the group consisting of niobium and tantalum, and 0.29 ⁇ x ⁇ 0.89), along an interface between the piezoelectric monocrystalline substrate and bonding layer.
- E represents at least one element selected from the group consisting of niobium and tantalum, and 0.29 ⁇ x ⁇ 0.89
- the element E of E x O (1-x) maybe niobium alone, tantalum alone, or both of niobium and tantalum.
- an interface layer 12 having a composition of E x O (1-x) (E represents at least one element selected from the group consisting of niobium and tantalum, and 0.29 ⁇ x ⁇ 0.89) between the activated surface 6 a of the piezoelectric monocrystalline substrate 6 and activated surface 4 of the bonding layer 3 A.
- E represents at least one element selected from the group consisting of niobium and tantalum, and 0.29 ⁇ x ⁇ 0.89
- a substrate-side intermediate layer having a composition of G y O (1-y) (G represents at least one element selected from the group consisting of niobium and tantalum, and x ⁇ y ⁇ 0.91), between the interface layer and piezoelectric monocrystalline substrate.
- G represents at least one element selected from the group consisting of niobium and tantalum, and x ⁇ y ⁇ 0.91
- a bonding layer-side intermediate layer having a composition of J z O (1-z) (J represents at least one element selected from the group consisting of niobium and tantalum, and x ⁇ z ⁇ 0.95), between the intermediate layer and bonding layer.
- the substrate-side intermediate layer 14 having a composition of the composition of G y O (1-y) , between the interface layer 12 and piezoelectric monocrystalline substrate 6 , and it is provided the bonding layer-side intermediate layer 13 having a composition of J z O (1-z) , between the interface layer 12 and bonding layer 3 A.
- the composition of the interface layer provided between the piezoelectric monocrystalline substrate and bonding layer is E x O (1-x) . It means that it is generated the interface layer whose Ta content or Nb content is higher than the Ta contents or Nb contents of the piezoelectric monocrystalline substrate and bonding layer. In the case that such interface layer is provided, it is found that the strength at the interface of the piezoelectric monocrystalline substrate and bonding layer is considerably improved and a high crack opening strength can be obtained.
- x is made 0.29 or higher and preferably 0.34 or higher. Further, on the viewpoint of the present invention, x is made 0.89 or lower and preferably 0.64 or lower.
- y and z are made higher than x, and the differences may be preferably be made 0.01 or larger and more preferably be made 0.02 or larger.
- y is preferably 0.30 or higher, and the upper limit of y is 0.91 and y may preferably be 0.89 or lower.
- z may preferably be made 0.35 or higher, and the upper limit of z is 0.95, z may preferably be made 0.89 or lower.
- FIG. 2 shows essential parts of a bonded body according to an embodiment of the present invention.
- the present example corresponds to the embodiment shown in FIG. 1( c ) . That is, the bonding layer 3 A is present on a lower side and the piezoelectric monocrystalline substrate 6 is present on an upper side. Then, it is provided a bonding layer-side intermediate layer 13 , interface layer 12 and substrate-side intermediate layer 14 are provided in the order from the bonding layer 3 A (lower side) to the piezoelectric monocrystalline substrate 6 (upper side).
- the intermediate layer 12 is brighter and the bonding layer-side intermediate layer 13 and substrate-side intermediate layer 14 are darker.
- this photograph is a bright-field image taken by a transmission type electron microscope under the following conditions.
- the microstructure is observed using a transmission type electron microscope (supplied by JEOL Ltd., “JEM-ARM200F”).
- a sample is thinned by FIB (Focused Ion Beam) method and observed at an acceleration voltage of 200 kV.
- the total ratios x, y and z of tantalum and niobium of E x O (1-x) , G y O (1-y) , and J z O (1-z) are determined as follows.
- a sample is thinned by FIB (Focused Ion Beam) method and observed at an acceleration voltage of 200 kV.
- Amounts of oxygen and tantalum (niobium) are measured at the respective parts of the piezoelectric monocrystalline substrate, substrate-side intermediate layer, interface layer and bonding layer-side intermediate layer.
- the ratio of the amount of oxygen and total amount of tantalum and niobium of the piezoelectric monocrystalline substrate are standardized as 3:1 in conformity with the chemical formula of LiAO 3 . That is, a correlation coefficient a is multiplied onto the total amount A of niobium and tantalum of the piezoelectric monocrystalline substrate so that the ratio of A is adjusted at 0.25 (25 atom %). Then, the correlation coefficient ⁇ is multiplied onto the measured amounts of A of the substrate-side intermediate layer, interface layer and bonding layer-side intermediate layer, respectively, to calculate x, y and z, respectively.
- FIGS. 3 to 5 are diagrams schematically illustrating a production example of providing a bonding layer on a supporting substrate and the bonding layer is bonded to a surface of a piezoelectric monocrystalline substrate by direct bonding.
- a bonding layer 2 is provided on a surface 1 a of a supporting substrate 1 .
- unevenness may be present on the surface 2 a of the bonding layer 2 .
- the surface 2 a of the bonding layer 2 is then subjected to flattening process to form a flat surface 3 a.
- the thickness of the bonding layer 2 is normally made smaller to provide a thinner bonding layer (refer to FIG. 3( b ) ).
- neutralized beam is irradiated onto the flat surface 3 a as shown in arrows A to activate the surface of the bonding layer 3 A to provide an activated surface 4 .
- neutralized beam A is irradiated onto the surface 6 c of the piezoelectric monocrystalline substrate 6 to activate it to provide a piezoelectric monocrystalline substrate 6 having the activated surface 6 a ( FIG. 4( b ) ).
- the activated surface 6 a of the piezoelectric monocrystalline substrate 6 and the activated surface 4 of the bonding layer 3 A are bonded by direct bonding, to obtain a bonded body 7 .
- the surface 6 b of the piezoelectric monocrystalline substrate of the bonded body 7 is further subjected to polishing process to made the thickness of the piezoelectric monocrystalline substrate 6 A smaller as shown in FIG. 5( b ) to obtain a bonded body 8 .
- 6 c represent a polished surface.
- electrodes 10 are formed on the polished surface 6 c of the piezoelectric monocrystalline substrate 6 A to produce a surface acoustic wave device 9 .
- bonded body of the present invention is not particularly limited, and the bonded body may be appropriately applied to an acoustic wave device and optical device, for example.
- a metal film may be provided on a bottom surface of the piezoelectric monocrystalline substrate.
- the metal film plays a role of improving the electro-mechanical coupling factor near the bottom surface of the piezoelectric substrate.
- the Lamb type device has the structure that interdigitated electrodes are formed on the surfaces of the piezoelectric monocrystalline surface and that the metal film on the piezoelectric monocrystalline substrate is exposed through a cavity provided in the supporting substrate.
- the material of such metal film includes aluminum, an aluminum alloy, copper, gold or the like, for example.
- the Lamb wave device it may be used a composite substrate having the piezoelectric monocrystalline substrate without the metal film on the bottom surface.
- the object of the present invention is a surface acoustic wave device and the material of the piezoelectric monocrystalline substrate is lithium tantalate, it may preferably be used the substrate in which it is rotated in an angle of 36 to 47° (for example 42°) from Y-axis toward Z-axis with respect to X-axis, the direction of propagation of surface acoustic wave, thanks to the low propagation loss.
- the method of film-forming the bonding layer is not particularly limited, it may be listed sputtering method, chemical vapor deposition (CVD) method and vapor deposition method. On the viewpoint of efficiently film-forming an oxide of at least one element selected from the group consisting of niobium and tantalum, sputtering or vapor deposition method is preferred.
- Sputtering method includes reaction sputtering of forming an oxide thin film in atmosphere containing oxygen using a metal target of at least one element selected from the group consisting of niobium and tantalum, and the method of film-forming using a target of an oxide of at least one element selected from the group consisting of niobium and tantalum.
- the surface of the bonding layer is flattened to obtain a flat surface.
- the method of flattening the surface of the bonding layer includes lapping, chemical mechanical polishing (CMP), and the like.
- the flat surface may preferably have Ra of 1 nm or lower and more preferably have Ra of 0.3 nm or lower.
- the surface of the piezoelectric monocrystalline substrate is flattened to obtain a flat surface.
- the method of flattening the surface of the piezoelectric monocrystalline substrate includes lapping, chemical mechanical polishing (CMP), and the like.
- the flat surface may preferably have Ra of 1 nm or lower and more preferably have Ra of 0.3 nm or lower.
- Atomic spices forming the beam may preferably be that from an inert gas (argon, nitrogen or the like).
- a voltage and current at the time of irradiation of the beam may preferably be made 0.5 to 2.0 kV and 50 to 200 mA, respectively.
- the activated surfaces are contacted and bonded with each other under vacuum atmosphere.
- This process is performed under ambient temperature, which is preferably 40° C. or lower and more preferably 30° C. or lower.
- the temperature during the bonding step may preferably be 20° C. or higher and more preferably be 25° C. or lower.
- the pressure during the bonding step may preferably be 100 to 20000N.
- LT lithium tantalate
- OF orientation flat
- the substrate 6 it was used 46° Y-cut X-propagation LT substrate, in which the direction of propagation of the surface acoustic wave (SAW) is X and the Y-cut plate is rotated in a cutting angle.
- the surface 6 c of the piezoelectric monocrystalline substrate 6 was mirror-polished to an arithmetic average roughness Ra of 1 nm.
- the supporting substrate 1 was then washed by a scrub washer. Mixed solution of acetone and IPA was used as washing liquid. It was then film-formed the bonding layer 2 of tantalum pentoxide in 0.2 ⁇ m on the surface 1 a of the supporting substrate 1 , using a magnetron and parallel plate type sputtering film-forming system. The film was formed using a target of tantalum pentoxide, under mixed atmosphere of argon and oxygen at a total pressure of 0.5 Pa. Ra after the film formation was 2.0 nm. The bonding layer 2 was then subjected to chemical mechanical polishing (CMP) to a film thickness of 0.15 ⁇ m and Ra of 0.3 nm.
- CMP chemical mechanical polishing
- the flat surface 3 a of the bonding layer 3 and the surface 6 a of the piezoelectric monocrystalline substrate 6 were washed to remove dirt thereon, followed by incorporation into a vacuum chamber. It was drawn to vacuum of an order of 10 ⁇ 6 Pa, and high-speed atomic beam (at an acceleration voltage of 1 kV and a flow rate of Ar of 27 sccm) was irradiated onto each of the bonding surfaces of the substrates over 120 sec. The surface with the beam irradiated (activated surface) of the bonding layer 3 A and the activated surface 6 a of the piezoelectric monocrystalline substrate 6 were then contacted with each other, followed by pressurizing at 10000 N over 2 minutes to bond the substrates ( FIG. 5( a ) ).
- the cross section of the bonded composite substrate was cut out from FIB, and the cross section was observed by TEM (supplied by JEOL Ltd., “JEM-ARM200F”) to confirm the microstructure and composition.
- the photograph of the cross section was shown in FIG. 2 . Further, the ratios (atom %) of the elements O and Ta in the respective parts were shown in table 1.
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Abstract
Description
- This application is a continuation application of PCT/JP2017/036133, filed Oct. 4, 2017, which claims priority to Japanese Application No. 2016-228903, filed Nov. 25, 2016, the entire contents all of which are incorporated hereby by reference.
- The present invention relates to a bonded body of a specific piezoelectric monocrystalline substrate and supporting substrate.
- It is known a surface acoustic wave device functioning as a filter device or oscillator used in mobile phones or the like, and an acoustic wave device such as lamb wave device or film bulk acoustic resonator (FBAR) using a piezoelectric thin film. As such acoustic wave device, it is known a device produced by adhering a supporting substrate and a piezoelectric substrate propagating a surface acoustic wave and by providing interdigitated electrodes capable of oscillating the surface acoustic wave on a surface of the piezoelectric substrate. By adhering the supporting substrate whose thermal expansion coefficient is lower than that of the piezoelectric substrate onto the piezoelectric substrate, the change of a size of the piezoelectric substrate responsive to temperature change is reduced so that the change of the frequency characteristics as the surface acoustic wave device is reduced.
- For example, it is proposed, in
patent document 1, that a surface acoustic wave device having the structure produced by adhering a piezoelectric substrate and silicon substrate with an adhesive layer composed of an epoxy adhering agent. - Here, it is known that, in bonding a piezoelectric substrate and silicon substrate, a silicon oxide film is formed on a surface of the piezoelectric substrate and that a silicon substrate and the piezoelectric substrate are bonded through the silicon oxide film (patent document 2). In the case of the bonding, plasma beam is irradiated onto the surfaces of the silicon oxide film and silicon substrate to activate the surfaces, followed by the direct boding (Plasma activation method).
- Further, it is known that a surface of the piezoelectric substrate is made a roughened surface, a filler layer is provided on the roughened surface to provide a flattened surface and the filler layer is adhered onto a silicon substrate through an adhering layer (patent document 3). According to this method, an epoxy-based or acryl-based resin is used for the filler layer and adhering layer, and the bonding surface of the piezoelectric substrate is made the roughened surface to reduce the reflection of bulk wave and to reduce spurious wave.
- Further, it is known direct bonding method of so-called FAB (Fast Atom Beam) system (patent document 4). According to this method, neutralized atomic beam is irradiated onto the respective bonding surfaces at ambient temperature to activate them, followed by the direct bonding.
- On the other hand, according to patent document 5, it is described that a piezoelectric monocrystalline substrate is directly bonded to a supporting substrate made of a ceramic material (alumina, aluminum nitride, silicon nitride) and not to a silicon substrate, through an intermediate layer. The material of the intermediate layer is silicon, silicon oxide, silicon nitride or aluminum nitride.
-
- (Patent document 1) Japanese patent publication No. 2010-187373A
- (Patent document 2) U.S. Pat. No. 7,213,314 B2
- (Patent document 3) Japanese Patent No. 5,814,727B
- (Patent document 4) Japanese Patent Publication No. 2014-086400A
- (Patent document 5) U.S. Pat. No. 3,774,782B
- However, it is particularly difficult to bond a piezoelectric monocrystalline substrate made of lithium niobate or tantalum niobate stably and strongly onto a supporting substrate.
- An object of the present invention is to provide microstructure in which a piezoelectric monocrystalline substrate made of lithium niobate or lithium tantalate and a supporting substrate strongly.
- The present invention provides a bonded body comprising a supporting substrate, a piezoelectric monocrystalline substrate and a bonding layer provided between said supporting substrate and said piezoelectric monocrystalline substrate,
- wherein said piezoelectric monocrystalline substrate comprises a material represented by LiAO3 (A represents at least one element selected from the group consisting of niobium and tantalum),
- wherein said bonding layer comprises a material comprising an oxide of at least one element selected from the group consisting of niobium and tantalum, and
-
- wherein said bonded body further comprises an interface layer along an interface between said piezoelectric monocrystalline substrate and said bonding layer, said interface layer comprising a composition of ExO(1-x) (E represents at least one element selected from the group consisting of niobium and tantalum and 0.29≤x≤0.89)
- According to the present invention, it is successfully provided microstructure in which a piezoelectric monocrystalline substrate made of lithium niobite, lithium tantalate or the like and a supporting substrate strongly.
-
FIG. 1(a) is a diagram schematically showing abonded body 7 according to an embodiment of the present invention,FIG. 1(b) is an enlarged view showing essential parts of thebonded body 7, andFIG. 1(c) is a view showing essential parts of another bonded body. -
FIG. 2 is a photograph showing essential parts of a bonded body according to an embodiment of the present invention. -
FIG. 3(a) shows the state that abonded body 2 is provided on a supportingsubstrate 1,FIG. 3(b) shows the state that asurface 3 a of abonding layer 3 is subjected to flattening process, andFIG. 3(c) shows the state that aflat surface 4 is activated by neutralized beam A. -
FIG. 4(a) shows the state that asurface 6 c of a piezoelectricmonocrystalline substrate 6 is activated by neutralized beam A, andFIG. 4(b) shows the state that thesurface 6 a of the piezoelectricmonocrystalline substrate 6 is activated. -
FIG. 5(a) shows the state that the piezoelectricmonocrystalline substrate 6 and supportingsubstrate 1 are bonded,FIG. 5(b) shows the state that a piezoelectricmonocrystalline substrate 6A is thinned by processing, andFIG. 5(c) shows the state thatelectrodes 10 are provided on the piezoelectricmonocrystalline substrate 6A. - The present invention will be described in detail below, appropriately referring to attached drawings.
- The bonded body of the present invention includes a supporting substrate, a piezoelectric monocrystalline substrate and a bonding layer provided between the supporting substrate and piezoelectric monocrystalline substrate. For example, according to a
bonded body 7 shown inFIG. 1(a) , an activatedsurface 6 a of a piezoelectricmonocrystalline substrate 6 is bonded onto asurface 1 a of a supportingsubstrate 1 through a bonding layer 3A. 1 b represents a surface on the opposite side of thesurface 1 a of the supporting substrate. - The material of the piezoelectric monocrystalline substrate is made LiAO3. Here, A represents at least one element selected from the group consisting of niobium and tantalum. Thus, LiAO3 may be lithium niobate, lithium tantalate or lithium niobate-lithium tantalate solid solution.
- Further, the material of the bonding layer is made an oxide of at least one element selected from the group consisting of niobium and tantalum. The oxide maybe an oxide of tantalum, an oxide of niobium or a composite oxide of niobium and tantalum.
- According to the present invention, it is provided an interface layer having a composition of ExO(1-x) (E represents at least one element selected from the group consisting of niobium and tantalum, and 0.29≤x≤0.89), along an interface between the piezoelectric monocrystalline substrate and bonding layer. Here, the element E of ExO(1-x) maybe niobium alone, tantalum alone, or both of niobium and tantalum.
- That is, according to an example shown in
FIG. 1(b) , it is provided aninterface layer 12 having a composition of ExO(1-x) (E represents at least one element selected from the group consisting of niobium and tantalum, and 0.29≤x≤0.89) between theactivated surface 6 a of the piezoelectricmonocrystalline substrate 6 and activatedsurface 4 of thebonding layer 3A. - Further, according to a preferred embodiment, it is provided a substrate-side intermediate layer having a composition of GyO(1-y) (G represents at least one element selected from the group consisting of niobium and tantalum, and x<y≤0.91), between the interface layer and piezoelectric monocrystalline substrate. Further, according to a preferred embodiment, it is provided a bonding layer-side intermediate layer having a composition of JzO(1-z) (J represents at least one element selected from the group consisting of niobium and tantalum, and x<z≤0.95), between the intermediate layer and bonding layer.
- That is, according to an example shown in
FIG. 1(c) , it is provided the substrate-sideintermediate layer 14 having a composition of the composition of GyO(1-y), between theinterface layer 12 and piezoelectricmonocrystalline substrate 6, and it is provided the bonding layer-sideintermediate layer 13 having a composition of JzO(1-z), between theinterface layer 12 andbonding layer 3A. - Here, the composition of the interface layer provided between the piezoelectric monocrystalline substrate and bonding layer is ExO(1-x). It means that it is generated the interface layer whose Ta content or Nb content is higher than the Ta contents or Nb contents of the piezoelectric monocrystalline substrate and bonding layer. In the case that such interface layer is provided, it is found that the strength at the interface of the piezoelectric monocrystalline substrate and bonding layer is considerably improved and a high crack opening strength can be obtained.
- On the viewpoint of the present invention, x is made 0.29 or higher and preferably 0.34 or higher. Further, on the viewpoint of the present invention, x is made 0.89 or lower and preferably 0.64 or lower.
- Further, in the substrate-side intermediate layer having a composition of GyO(1-y) and bonding layer-side intermediate layer having a composition of JzO(1-z), on the viewpoint of the present invention, y and z are made higher than x, and the differences may be preferably be made 0.01 or larger and more preferably be made 0.02 or larger. Further, according to the viewpoint of the present invention, y is preferably 0.30 or higher, and the upper limit of y is 0.91 and y may preferably be 0.89 or lower. Further, z may preferably be made 0.35 or higher, and the upper limit of z is 0.95, z may preferably be made 0.89 or lower.
-
FIG. 2 shows essential parts of a bonded body according to an embodiment of the present invention. - The present example corresponds to the embodiment shown in
FIG. 1(c) . That is, thebonding layer 3A is present on a lower side and the piezoelectricmonocrystalline substrate 6 is present on an upper side. Then, it is provided a bonding layer-sideintermediate layer 13,interface layer 12 and substrate-sideintermediate layer 14 are provided in the order from thebonding layer 3A (lower side) to the piezoelectric monocrystalline substrate 6 (upper side). - Here, according to a preferred embodiment, for example as shown in
FIG. 2 , theintermediate layer 12 is brighter and the bonding layer-sideintermediate layer 13 and substrate-sideintermediate layer 14 are darker. However, this photograph is a bright-field image taken by a transmission type electron microscope under the following conditions. - Measuring system:
- The microstructure is observed using a transmission type electron microscope (supplied by JEOL Ltd., “JEM-ARM200F”).
- Measurement conditions:
- A sample is thinned by FIB (Focused Ion Beam) method and observed at an acceleration voltage of 200 kV.
- Here, the total ratios x, y and z of tantalum and niobium of ExO(1-x), GyO(1-y), and JzO(1-z) are determined as follows.
- Measuring system:
- Elemental analysis system (supplied by JEOL Ltd., “JED-2300T”).
- Measurement conditions:
- A sample is thinned by FIB (Focused Ion Beam) method and observed at an acceleration voltage of 200 kV.
- Processing of measured values:
- Amounts of oxygen and tantalum (niobium) are measured at the respective parts of the piezoelectric monocrystalline substrate, substrate-side intermediate layer, interface layer and bonding layer-side intermediate layer. Here, the ratio of the amount of oxygen and total amount of tantalum and niobium of the piezoelectric monocrystalline substrate are standardized as 3:1 in conformity with the chemical formula of LiAO3. That is, a correlation coefficient a is multiplied onto the total amount A of niobium and tantalum of the piezoelectric monocrystalline substrate so that the ratio of A is adjusted at 0.25 (25 atom %). Then, the correlation coefficient α is multiplied onto the measured amounts of A of the substrate-side intermediate layer, interface layer and bonding layer-side intermediate layer, respectively, to calculate x, y and z, respectively.
- Preferred production examples of the bonded body of the present invention will be described below.
-
FIGS. 3 to 5 are diagrams schematically illustrating a production example of providing a bonding layer on a supporting substrate and the bonding layer is bonded to a surface of a piezoelectric monocrystalline substrate by direct bonding. - As shown in
FIG. 3(a) , abonding layer 2 is provided on asurface 1 a of a supportingsubstrate 1. At this time, unevenness may be present on the surface 2 a of thebonding layer 2. The surface 2 a of thebonding layer 2 is then subjected to flattening process to form aflat surface 3 a. By this flattening process, the thickness of thebonding layer 2 is normally made smaller to provide a thinner bonding layer (refer toFIG. 3(b) ). - Then, as shown in
FIG. 3(c) , neutralized beam is irradiated onto theflat surface 3 a as shown in arrows A to activate the surface of thebonding layer 3A to provide an activatedsurface 4. - Further, as shown in
FIG. 4(a) , neutralized beam A is irradiated onto thesurface 6 c of the piezoelectricmonocrystalline substrate 6 to activate it to provide a piezoelectricmonocrystalline substrate 6 having the activatedsurface 6 a (FIG. 4(b) ). Then, as shown inFIG. 5(a) , the activatedsurface 6 a of the piezoelectricmonocrystalline substrate 6 and the activatedsurface 4 of thebonding layer 3A are bonded by direct bonding, to obtain a bondedbody 7. - According to a preferred embodiment, the
surface 6 b of the piezoelectric monocrystalline substrate of the bondedbody 7 is further subjected to polishing process to made the thickness of the piezoelectricmonocrystalline substrate 6A smaller as shown inFIG. 5(b) to obtain a bondedbody 8. 6 c represent a polished surface. - In
FIG. 5(c) ,electrodes 10 are formed on thepolished surface 6 c of the piezoelectricmonocrystalline substrate 6A to produce a surfaceacoustic wave device 9. - It will be further described the respective constituents of the present invention below.
- Applications of the bonded body of the present invention is not particularly limited, and the bonded body may be appropriately applied to an acoustic wave device and optical device, for example.
- As an acoustic weave device, a surface acoustic wave device, Lamb wave-type device, thin film resonator (FBAR) or the like is known. For example, the surface acoustic wave device is produced by providing an input side IDT (Interdigital transducer) electrodes (also referred to as comb electrodes or interdigitated electrodes) for oscillating surface acoustic wave and IDT electrode on the output side for receiving the surface acoustic wave, on the surface of the piezoelectric monocrystalline substrate. By applying high frequency signal on the IDT electrode on the input side, electric field is generated between the electrodes, so that the surface acoustic wave is oscillated and propagated on the piezoelectric substrate. Then, the propagated surface acoustic wave is drawn as an electrical signal from the IDT electrodes on the output side provided in the direction of the propagation.
- A metal film may be provided on a bottom surface of the piezoelectric monocrystalline substrate. After the lamb type device is produced as the acoustic wave device, the metal film plays a role of improving the electro-mechanical coupling factor near the bottom surface of the piezoelectric substrate. In this case, the Lamb type device has the structure that interdigitated electrodes are formed on the surfaces of the piezoelectric monocrystalline surface and that the metal film on the piezoelectric monocrystalline substrate is exposed through a cavity provided in the supporting substrate. The material of such metal film includes aluminum, an aluminum alloy, copper, gold or the like, for example. Further, in the case that the Lamb wave device is produced, it may be used a composite substrate having the piezoelectric monocrystalline substrate without the metal film on the bottom surface.
- Further, a metal film and an insulating film may be provided on the bottom surface of the piezoelectric monocrystalline substrate. The metal film plays a role of electrodes in the case that the thin film resonator is produced as the acoustic wave device. In this case, the thin film resonator has the structure that electrodes are formed on the upper and bottom surfaces of the piezoelectric monocrystalline substrate and the insulating film is made a cavity to expose the metal film on the piezoelectric monocrystalline substrate. The material of such metal film includes molybdenum, ruthenium, tungsten, chromium, aluminum or the like, for example. Further, the material of the insulating film includes silicon dioxide, phosphorus silicate glass, boron phosphorus silicate glass or the like.
- Further, as the optical device, it may be listed an optical switching device, wavelength conversion device and optical modulating device. Further, a periodic domain inversion structure may be formed in the piezoelectric monocrystalline substrate.
- According to a preferred production example, neutralized beam may be used to activate the surface of the piezoelectric monocrystalline substrate. Particularly in the case that the surface of the piezoelectric monocrystalline substrate is a flat surface, the surface may be directly bonded to the bonding layer.
- In the case that the object of the present invention is a surface acoustic wave device and the material of the piezoelectric monocrystalline substrate is lithium tantalate, it may preferably be used the substrate in which it is rotated in an angle of 36 to 47° (for example 42°) from Y-axis toward Z-axis with respect to X-axis, the direction of propagation of surface acoustic wave, thanks to the low propagation loss.
- Further, in the case that the piezoelectric monocrystalline substrate is composed of lithium niobate, it may preferably be used the substrate in which it is rotated in an angle of 60 to 68° (for example 64°) from Y-axis toward Z-axis with respect to X-axis, the direction of propagation of surface acoustic wave, thanks to the low propagation loss. Further, although the size of the piezoelectric monocrystalline substrate is not particularly limited, the diameter is 50 to 150 mm and the thickness is 0.2 to 60 μm, for example.
- The material of the supporting substrate is made a single crystal or a ceramic material. It may preferably be listed a material selected from the group consisting of silicon, sapphire, mullite, cordierite, translucent alumina, SiAlON, AlN and Si3N4.
- In the case that the bonding layer is formed on the supporting substrate, although the method of film-forming the bonding layer is not particularly limited, it may be listed sputtering method, chemical vapor deposition (CVD) method and vapor deposition method. On the viewpoint of efficiently film-forming an oxide of at least one element selected from the group consisting of niobium and tantalum, sputtering or vapor deposition method is preferred.
- Sputtering method includes reaction sputtering of forming an oxide thin film in atmosphere containing oxygen using a metal target of at least one element selected from the group consisting of niobium and tantalum, and the method of film-forming using a target of an oxide of at least one element selected from the group consisting of niobium and tantalum.
- Then, preferably, the surface of the bonding layer is flattened to obtain a flat surface. Here, the method of flattening the surface of the bonding layer includes lapping, chemical mechanical polishing (CMP), and the like. Further, the flat surface may preferably have Ra of 1 nm or lower and more preferably have Ra of 0.3 nm or lower.
- Further, the surface of the piezoelectric monocrystalline substrate is flattened to obtain a flat surface. Here, the method of flattening the surface of the piezoelectric monocrystalline substrate includes lapping, chemical mechanical polishing (CMP), and the like. Further, the flat surface may preferably have Ra of 1 nm or lower and more preferably have Ra of 0.3 nm or lower.
- Then, according to a preferred embodiment, neutralized beam is irradiated onto the flat surface of the bonding layer to activate the flat surface. Further, neutralized beam is irradiated onto the surface of the piezoelectric monocrystalline substrate to activate the flat surface.
- In the case that neutralized beam is used to perform the surface activation, it is preferred to use a system described in
patent document 4 to generate the neutralized beam, which is then irradiated. That is, it is used a source of high-speed atomic beam of saddle field type as a beam source. Inert gas is then introduced into a chamber and a high voltage is applied onto electrodes from a direct current electric source. It is thus generated electric field of saddle-field type between the electrode (positive electrode) and a housing (negative electrode), so that electrons e is moved to generate beams of atoms and ions from the inert gas. Among the beams reaching a grid, the beam of the ions is neutralized at the grid so that the beam of the neutral atoms is emitted from the high-speed atomic beam source. Atomic spices forming the beam may preferably be that from an inert gas (argon, nitrogen or the like). - A voltage and current at the time of irradiation of the beam may preferably be made 0.5 to 2.0 kV and 50 to 200 mA, respectively.
- Then, the activated surfaces are contacted and bonded with each other under vacuum atmosphere. This process is performed under ambient temperature, which is preferably 40° C. or lower and more preferably 30° C. or lower. The temperature during the bonding step may preferably be 20° C. or higher and more preferably be 25° C. or lower. The pressure during the bonding step may preferably be 100 to 20000N.
- The bonded body shown in
FIGS. 1(c) and 2 was obtained, according to the method described referring toFIGS. 3 to 5 . - Specifically, it was prepared the piezoelectric
monocrystalline substrate 6 of lithium tantalate (LT) having an orientation flat (OF) part, a diameter of 4 inches and thickness of 250 μm. As thesubstrate 6, it was used 46° Y-cut X-propagation LT substrate, in which the direction of propagation of the surface acoustic wave (SAW) is X and the Y-cut plate is rotated in a cutting angle. Thesurface 6 c of the piezoelectricmonocrystalline substrate 6 was mirror-polished to an arithmetic average roughness Ra of 1 nm. - Further, as the supporting
substrate 1, it was prepared a mullite body having an OF part, a diameter of 4 inches, a thickness of 230 μm. Thesurfaces 1 a of the supportingsubstrate 1 of mullite had an arithmetic average roughness Ra of 2 nm. The arithmetic average roughness was evaluated by means of an atomic force microscope (AFM) in a square visual field of a length of 10 μm and a width of 10 μm. - The supporting
substrate 1 was then washed by a scrub washer. Mixed solution of acetone and IPA was used as washing liquid. It was then film-formed thebonding layer 2 of tantalum pentoxide in 0.2 μm on thesurface 1 a of the supportingsubstrate 1, using a magnetron and parallel plate type sputtering film-forming system. The film was formed using a target of tantalum pentoxide, under mixed atmosphere of argon and oxygen at a total pressure of 0.5 Pa. Ra after the film formation was 2.0 nm. Thebonding layer 2 was then subjected to chemical mechanical polishing (CMP) to a film thickness of 0.15 μm and Ra of 0.3 nm. - The
flat surface 3 a of thebonding layer 3 and thesurface 6 a of the piezoelectricmonocrystalline substrate 6 were washed to remove dirt thereon, followed by incorporation into a vacuum chamber. It was drawn to vacuum of an order of 10−6 Pa, and high-speed atomic beam (at an acceleration voltage of 1 kV and a flow rate of Ar of 27 sccm) was irradiated onto each of the bonding surfaces of the substrates over 120 sec. The surface with the beam irradiated (activated surface) of thebonding layer 3A and the activatedsurface 6 a of the piezoelectricmonocrystalline substrate 6 were then contacted with each other, followed by pressurizing at 10000 N over 2 minutes to bond the substrates (FIG. 5(a) ). - The
surface 6 b of the piezoelectricmonocrystalline substrate 6 was then subjected to grinding and polishing until the thickness was changed from the initial 250 μm to 20 μm. It was not confirmed the separation of the bonded part during the grinding and polishing steps. Further, the bonding strength was evaluated by crack opening method and proved to be 1.8 J/m2. - The cross section of the bonded composite substrate was cut out from FIB, and the cross section was observed by TEM (supplied by JEOL Ltd., “JEM-ARM200F”) to confirm the microstructure and composition. The photograph of the cross section was shown in
FIG. 2 . Further, the ratios (atom %) of the elements O and Ta in the respective parts were shown in table 1. - It was produced the bonded bodies according to the same procedure as the Inventive Example 1. However, the acceleration voltage of the high-speed electron beam irradiated onto the bonding surface of the substrate were changed to values described in table 1.
- The ratios of the elements of the respective parts and bonding strengths measured by crack opening method of the thus obtained bonded bodies were shown in table 1.
- The bonded body was produced according to the same procedure as the Inventive Example 1, except that the acceleration voltage of the high-speed electron beam irradiated onto the bonding surfaces of the substrates were changed as described in table 1.
- In the thus obtained bonded body, the inventive interface layer was not observed between the bonding layer and piezoelectric monocrystalline substrate. The bonding strength of the bonded body measured by crack opening method was shown in table 1.
-
TABLE 1 Unit of numerical values (mol %) Measurement Inventive Inventive Inventive Inventive Inventive Com. points Elements Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 1 Acceleration Voltage (kV) 1.0 0.8 0.9 1.4 1.8 2.0 Piezoelectric monocrystalline [O] 75 75 75 75 75 75 substrate 6 [Ta] 25 25 25 25 25 25 Substrate-side [O] 59 70 64 34 9 7 intermediate layer 14 [Ta] 40 30 36 66 91 93 Interface layer 12 [O] 61 71 66 36 11 9 [Ta] 39 29 34 64 89 91 Bonding-layer side [O] 55 65 60 30 5 3 Intermediate layer 13 [Ta] 45 35 40 70 95 97 Bonding strength (J/m2) 1.8 1.5 1.7 1.7 1.5 0.30
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US11631586B2 (en) | 2012-08-30 | 2023-04-18 | Adeia Semiconductor Bonding Technologies Inc. | Heterogeneous annealing method |
US11664357B2 (en) | 2018-07-03 | 2023-05-30 | Adeia Semiconductor Bonding Technologies Inc. | Techniques for joining dissimilar materials in microelectronics |
US12009338B2 (en) | 2020-03-19 | 2024-06-11 | Adeia Semiconductor Bonding Technologies Inc. | Dimension compensation control for directly bonded structures |
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US11631586B2 (en) | 2012-08-30 | 2023-04-18 | Adeia Semiconductor Bonding Technologies Inc. | Heterogeneous annealing method |
US11664357B2 (en) | 2018-07-03 | 2023-05-30 | Adeia Semiconductor Bonding Technologies Inc. | Techniques for joining dissimilar materials in microelectronics |
US11569434B2 (en) | 2019-12-18 | 2023-01-31 | Ngk Insulators, Ltd. | Vibrating plate-bonded-body |
US12009338B2 (en) | 2020-03-19 | 2024-06-11 | Adeia Semiconductor Bonding Technologies Inc. | Dimension compensation control for directly bonded structures |
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