US20130104531A1 - Static mixer for mixing urea aqueous solution and engine exhaust gas - Google Patents

Static mixer for mixing urea aqueous solution and engine exhaust gas Download PDF

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Publication number
US20130104531A1
US20130104531A1 US13/808,759 US201113808759A US2013104531A1 US 20130104531 A1 US20130104531 A1 US 20130104531A1 US 201113808759 A US201113808759 A US 201113808759A US 2013104531 A1 US2013104531 A1 US 2013104531A1
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Prior art keywords
static mixer
urea solution
exhaust gas
internal tube
tube
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Abandoned
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US13/808,759
Inventor
Young Jin Cho
Ji Woong Park
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Hyundai Doosan Infracore Co Ltd
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Doosan Infracore Co Ltd
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Assigned to DOOSAN INFRACORE CO., LTD. reassignment DOOSAN INFRACORE CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CHO, YOUNG JIN, PARK, JI WOONG
Publication of US20130104531A1 publication Critical patent/US20130104531A1/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/21Mixing gases with liquids by introducing liquids into gaseous media
    • B01F23/213Mixing gases with liquids by introducing liquids into gaseous media by spraying or atomising of the liquids
    • B01F23/2132Mixing gases with liquids by introducing liquids into gaseous media by spraying or atomising of the liquids using nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • B01F25/31Injector mixers in conduits or tubes through which the main component flows
    • B01F25/314Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit
    • B01F25/3141Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit with additional mixing means other than injector mixers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B01F25/4315Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being deformed flat pieces of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B01F25/4316Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being flat pieces of material, e.g. intermeshing, fixed to the wall or fixed on a central rod
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/08Other arrangements or adaptations of exhaust conduits
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/20Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a flow director or deflector
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/02Adding substances to exhaust gases the substance being ammonia or urea
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present disclosure relates to a static mixer for mixing a urea solution and engine exhaust gas, and more particularly, to a static mixer for mixing a urea solution and engine exhaust gas capable of finely and evenly mixing exhaust gas discharged from an exhaust manifold of a diesel engine to an inlet portion of an SCR (Selective Catalytic Reduction) of an exhaust pipe and a urea solution supplied from a urea solution injector of the exhaust pipe to the inlet portion of the SCR in order to decrease an amount of exhaust gas generated during a combustion process of mixed gas of the diesel engine and accompanying nitrogen oxide (NOx) discharged to the atmosphere.
  • SCR Selective Catalytic Reduction
  • a diesel engine injects fuel, such as diesel, into a combustion chamber in a state where air supplied from the outside to the combustion chamber is compressed at a high temperature and high pressure, to generate output by turning force of a crank shaft connected with a connecting rod of a vertically moving piston by explosive force generated during a process of combusting and exploding mixed gas of air and fuel.
  • fuel such as diesel
  • a recent diesel engine has employed an exhaust gas post-treatment method of increasing the amount of air supplied to the combustion chamber to be larger than of the fuel supplied to the combustion chamber to considerably increase output, and making mixed gas of a urea solution and exhaust gas pass through an SCR by injecting the urea solution to the inlet portion of the SCR to change nitrogen oxide (NOx) accompanied by the exhaust gas to innoxious water (H 2 O) and nitrogen (N 2 ).
  • NOx nitrogen oxide
  • H 2 O innoxious water
  • N 2 nitrogen
  • a mixer of the diesel engine serving to mix a urea solution and exhaust gas for the exhaust gas post-treatment includes an exhaust pipe including a urea solution injector adapter in which a urea solution injector is simply mounted, and a channel unit installed inside the exhaust pipe and including a plurality of guiding channels.
  • exhaust gas generated in a combustion chamber and the urea solution injected from the urea solution injector are mixed together while passing through the plurality of guiding channels of the channel unit, to be guided to an SCR disposed at a rear side of the mixer, and the nitrogen oxide (NOx) accompanied by the exhaust gas generates catalytic reduction reaction with the urea solution while passing through the SCR to be changed to innoxious water and nitrogen.
  • NOx nitrogen oxide
  • the mixer of the diesel engine in the related art has a structure in which the channel unit including the plurality of guiding channels is simply accommodated inside the exhaust pipe, there is a problem in that the exhaust gas discharged from an exhaust manifold of the engine to the mixer is not finely and evenly mixed well with the urea solution supplied from the urea solution injector, so that an amount of nitrogen oxide (NOx) discharged to the atmosphere is not largely decreased.
  • NOx nitrogen oxide
  • the exhaust pipe accommodating the channel unit has a form of a single duct, when the urea solution is in direct contact with an inner wall surface of the exhaust pipe directly exposed to the air, the urea solution is not evaporated and flows down along the inner wall surface of the exhaust pipe, so that there is a problem in that the urea solution is not appropriately used for decreasing nitrogen oxide (NOx) and is directly discharged to the outside.
  • NOx nitrogen oxide
  • the present disclosure provides a static mixer for mixing a urea solution and engine exhaust gas, by which exhaust gas before passing through an SCR and the urea solution can be finely and evenly mixed in order to considerably decrease an amount of nitrogen oxide (NOx) discharged to the atmosphere.
  • a static mixer for mixing a urea solution and engine exhaust gas, by which exhaust gas before passing through an SCR and the urea solution can be finely and evenly mixed in order to considerably decrease an amount of nitrogen oxide (NOx) discharged to the atmosphere.
  • NOx nitrogen oxide
  • the present disclosure provides a static mixer for mixing a urea solution and engine exhaust gas, by which exhaust gas and a urea solution can be finely and evenly mixed by improving an evaporation environment of the urea solution supplied from a urea solution injector to an input portion of an SCR, thereby decreasing an amount of nitrogen oxide (NOx) discharged to the atmosphere and removing waste of the urea solution.
  • a static mixer for mixing a urea solution and engine exhaust gas, by which exhaust gas and a urea solution can be finely and evenly mixed by improving an evaporation environment of the urea solution supplied from a urea solution injector to an input portion of an SCR, thereby decreasing an amount of nitrogen oxide (NOx) discharged to the atmosphere and removing waste of the urea solution.
  • NOx nitrogen oxide
  • the present disclosure provides a static mixer for mixing a urea solution and engine exhaust gas, including: an external tube including one end portion connected to an exhaust manifold of a diesel engine, the other end portion connected to an SCR (Selective Catalytic Reduction), and a part with which a urea solution injection adaptor is provided; an internal tube installed inside the external tube so as to have a constant gap between at least a part of an outer wall surface and an inner wall surface of the external tube; and a channel unit including a plurality of guiding channels provided inside the internal tube in a longitudinal direction, and having a inlet portion facing a lower end portion of the urea solution injector adaptor.
  • SCR Selective Catalytic Reduction
  • present disclosure further provides detailed exemplary embodiments for the exemplary embodiment of the present disclosure below.
  • the internal tube may include at least one protrusion at an outer peripheral portion.
  • the channel unit may include a plurality of first channel plates arranged in the internal tube with predetermined intervals therebetween, and a plurality of second channel plates inclined at a predetermined angle with respect to the plurality of first plates and disposed to cross the plurality of first plates with predetermined intervals therebetween.
  • an exposed portion of at least one of the plurality of first and second channel plates may have at least one through hole so as to achieve a fine and even mixing behavior between the exhaust gas and the urea solution.
  • a plurality of blades may be provided at an end portion of an outlet side of at least one of the plurality of first and second channel plates so as to achieve a fine and even mixing behavior between the exhaust gas and the urea solution.
  • the plurality of blades may be inclinedly arranged in an opposite direction for each layer of the first and second channel plates.
  • the inlet portion of the channel unit may include a first inclined portion having a predetermined angle with respect to a longitudinal direction of the internal tube, and a second inclined portion having a predetermined angle with respect to the first inclined portion.
  • an orientation angle of the first inclined portion may be 0 to 30° in an outside direction with respect to a virtual axial line perpendicular to the longitudinal direction of the internal tube.
  • each of end surfaces of the first and second inclined portions at an end surface of an inlet side may have a shape of a straight line, a curved line, or a combination thereof.
  • the respective three first and second channel plates are included so as to form four rooms in one direction and the other direction, respectively.
  • the gap between the internal tube and the external tube is 5 to 10 mm.
  • the present disclosure may form fine and even mixed gas by providing the channel unit having the plurality of guiding channels and the inlet portion inside the internal tube shaped like a dual tube including the external tube surrounding the internal tube at a predetermined gap, and making the exhaust gas and the urea solution before passing through the SCR pass through the inlet portion and the plurality of guiding channels of the channel unit, thereby largely decreasing an amount of nitride oxide (NOx) discharged to the outside by improving a catalytic reduction reaction ratio in the SCR.
  • NOx nitride oxide
  • the present disclosure provides the channel unit including the plurality of guiding channels and the inlet portion inside the internal tube shaped like a dual tube to insulate the internal tube against the external tube directly exposed to the outside, so that an evaporation ratio of the urea solution supplied from the urea solution injector to the inlet portion and the plurality of guiding channels of the channel unit, thereby decreasing an amount of nitride oxide (NOx) discharged to the outside and removing waste of the urea solution.
  • NOx nitride oxide
  • FIG. 1 is a schematic perspective view illustrating a static mixer for mixing a urea solution and engine exhaust gas according to the present disclosure.
  • FIG. 2 is a schematic perspective view illustrating an end portion of an outlet of the static mixer according to the present disclosure.
  • FIG. 3 is a schematic perspective view illustrating an internal tube and a channel unit provided inside the internal tube of the static mixer according to the present disclosure.
  • FIG. 4 is a schematic cross-sectional view illustrating an angle orientation relation between a first inclined portion of a inlet portion provided at the channel unit and an external tube of the static mixer according to the present disclosure.
  • Static mixer 102 External tube 3: Internal tube 3a: Protrusion 5: Urea solution injector adaptor 10: Channel unit 11: Guiding channel 12: Bent inlet portion 12a: First inclined portion 12b: Second inclined portion 13: First channel plate 14: Second channel plate 15: Through-hole 16: Blade
  • FIGS. 1 to 4 an exemplary embodiment of a static mixer for mixing a urea solution and engine exhaust gas according to the present disclosure will be described with reference to FIGS. 1 to 4 .
  • a term “static mixer” is an expression widely used in a corresponding business field and is a counterpart concept to a dynamic mixer, and means a mixer (or a mixing device) for finely and evenly mixing exhaust gas and a urea solution without a dynamic motion.
  • two terms of “a plurality of” and “multiple” are discriminatingly used.
  • the term of “a plurality of” is used so as to emphasize a case in which a technical meaning is significant when the number of corresponding constituent elements is two or more, and the term of “multiple” is used so as to represent a case in which there are simply a lot of corresponding constituent elements.
  • the static mixer 1 of the present disclosure includes, as illustrated in FIGS. 1 to 3 , an external tube 2 , an internal tube 3 , and a channel unit 10 .
  • one end portion of the external tube 2 is connected to an exhaust manifold (not illustrated) of a diesel engine, and the other end portion is connected to an SCR (not illustrated), and a urea solution injector adaptor 5 is provided at a part of the external tube 2 .
  • the external tube 2 may be connected to an exhaust pipe (not illustrated) by a welding method or a detachable method.
  • the internal tube 3 is fixed while being accommodated inside the external tube 2 so that at least one portion of an outer wall surface of the internal tube 3 has a constant gap from an inner wall surface of the external tube 2 .
  • the channel unit 10 is provided inside the internal tube 3 and includes multiple guiding channels 11 in a longitudinal direction, and has a inlet portion 12 facing a lower end portion of the urea solution injector adaptor 5 .
  • exhaust gas discharged from the exhaust manifold to the static mixer 1 of the diesel engine and the urea solution supplied from a urea solution injector (not illustrated) installed in the urea solution injector adaptor 5 of the static mixer 1 to the static mixer 1 are finely and evenly mixed with each other while passing through the channel unit 10 including the bent inlet portion 12 and the multiple guiding channels 11 .
  • the urea solution supplied from the urea solution injector (not illustrated) installed in the urea solution injector adaptor 5 to the static mixer 1 may be injected to the channel unit 10 inside the internal tube 3 , thereby solving a problem of the related art in that the urea solution is in directly contact with the inner wall surface of the external tube 2 to be changed in a liquid state and flow down along the inner wall surface of the external tube 2 .
  • the static mixer 1 of the present disclosure enables mixed gas of the exhaust gas and the urea solution finely and evenly mixed well while passing through the static mixer to well have a catalytic reduction reaction when passing through the SCR (not illustrated), thereby eventually greatly decreasing an amount of nitrogen oxide (NOx) discharged to the air and decreasing waste of the urea solution.
  • NOx nitrogen oxide
  • the channel unit 10 may include a plurality of first channel plates 13 arranged in the internal tube 3 with predetermined intervals therebetween, and a plurality of second channel plates 14 inclined with respect to the plurality of first plates 13 at a predetermined angle, and disposed to cross the plurality of first plates 13 with predetermined intervals therebetween.
  • the plurality of guiding channels 11 for guiding the exhaust gas, the urea solution, or mixed gas in which the exhaust gas is mixed with the urea solution may be conveniently formed by a structure of the plurality of first and second channel plates.
  • an exposed portion of at least one of the plurality of first and second channel plates 13 and 14 may be provided in a form having at least one through-hole 15 so that the exhaust gas and the urea solution are evenly mixed.
  • the through hole 15 may have various shapes, such as a circular shape, an elliptical shape, a slit, or a slot.
  • a structure of the through-hole of the plurality of first and second channel plates improves an active mixing behavior between the exhaust gas and the urea solution guided to the adjacent guiding channels among the plurality of guiding channels 11 .
  • a plurality of blades 16 may be provided at an end portion of an outlet side of at least one of the plurality of first and second channel plates 13 and 14 so that the exhaust gas and the urea solution are finely and evenly mixed.
  • the plurality of blades 16 may be inclinedly arranged in an opposite direction for each layer of the first and second channel plates 13 and 14 . This is because an active mixing behavior between the exhaust gas and the urea solution is improved by creating a vortex phenomenon in the exhaust gas and the urea solution passing through the end portions of the outlet sides of the plurality of first and second channels plates 13 and 14 .
  • the internal tube 3 may be fixed concentrically or eccentrically with respect to the external tube 2 .
  • a structure in which the internal tube 3 is disposed concentrically with respect to the external tube 2 has an advantage in that the gap between the internal tube 3 and the external tube 2 may be regularly formed.
  • a structure in which the internal tube 3 is disposed eccentrically with respect to the external tube 2 has an advantage in that the internal tube 3 may be simply and conveniently fixed to the external tube 2 .
  • the gap between the internal tube 3 and the external tube 2 may be 5 to 10 mm. This is because there is a disadvantage in that an insulation effect of the internal tube 3 against the external tube 2 is decreased when the gap between the internal tube 3 and the external tube 2 is less than 5 mm, and there are high concerns regarding the direct discharge of a part of the exhaust toward the SCR without the mixing behavior with the urea solution when the gap between the internal tube 3 and the external tube 2 exceeds 10 nm.
  • the bent inlet portion 12 of the channel unit 10 may include a first inclined portion 12 a having a predetermined angle with respect to a longitudinal direction of the internal tube 3 , and a second inclined portion 12 b having a predetermined angle with respect to the first inclined portion 12 a.
  • an orientation angle of the first inclined portion 12 a may be 0 to 30° in an outside direction with respect to a virtual axial line perpendicular to the longitudinal direction of the internal tube 3 .
  • the three first channel plates 13 and the three second channel plates 14 may be included so as to have four rooms in one direction and the other direction, respectively.
  • the structure of the plurality of first and second channel plates having the aforementioned arrangement improves the mixing behavior between the exhaust gas and the urea solution compared to a case where the number of each of the first and second channels plates is smaller than 3 or exceeds 3. This is because discharge pressure of the exhaust gas and/or mixing power between the exhaust gas and the urea solution is changed according to a dense arrangement or sparse arrangement of the plurality of first and second channel plates 13 and 14 .
  • urea solution is simultaneously injected from the urea solution injector (not illustrated) installed in the urea solution injector adaptor 5 of the external tube 2 of the static mixer 1 to the inlet portion of the channel unit 10 of the static mixer 1 .
  • the exhaust gas and the urea solution are primarily finely and evenly mixed together while flowing inside the plurality of guiding channels 11 through the bent inlet portion 12 of the channel unit 10 .
  • the through-hole 15 is further provided at the exposed portions of the first and second channel plates 13 and 14 of the channel unit 10 , the mixing behavior between the exhaust gas and the urea solution passing through the plurality of guiding channels 11 may be more actively performed.
  • the exhaust gas and the urea solution discharged to the end portion of the outlet side of the channel unit 10 through the plurality of guiding channels 11 of the channel unit 10 generate a vortex while crashing against the plurality of blades 16 of the channel unit 10 , thereby being more finely and evenly mixed secondarily.
  • the static mixer for mixing a urea solution and engine exhaust gas is installed at a side of an exhaust pipe of a diesel engine to change nitrogen oxide (NOx) accompanied by the exhaust gas into innoxious water (H2O) and nitrogen (N2), so that the static mixer is usable for decreasing atmosphere environmental pollution.
  • NOx nitrogen oxide
  • H2O innoxious water
  • N2 nitrogen

Abstract

The present disclosure relates to a static mixer for mixing a urea solution and engine exhaust gas. The static mixer includes: an external tube including one end portion connected to an exhaust manifold of a diesel engine, the other end portion connected to an SCR (Selective Catalytic Reduction), and a part with which a urea solution injection adaptor is provided; an internal tube installed inside the external tube so as to have a constant gap between at least a part of an outer wall surface and an inner wall surface of the external tube; and a channel unit comprising a plurality of guiding channels provided inside the internal tube in a longitudinal direction, and having an inlet portion facing a lower end portion of the urea solution injector adaptor. The present disclosure may make the exhaust gas and the urea solution before passing through the SCR pass through the inlet portion and the plurality of guiding channels of the channel unit to form fine and even mixed gas, thereby largely decreasing an amount of nitride oxide (NOx) discharged to the air by improving a catalytic reduction reaction ratio in the SCR.

Description

  • This Application is a Section 371 National Stage Application of International Application No. PCT/KR2011/004979, filed Jul. 7, 2011 and published, not in English, as WO2012/005527 on Jan. 12, 2012.
  • FIELD OF THE DISCLOSURE
  • The present disclosure relates to a static mixer for mixing a urea solution and engine exhaust gas, and more particularly, to a static mixer for mixing a urea solution and engine exhaust gas capable of finely and evenly mixing exhaust gas discharged from an exhaust manifold of a diesel engine to an inlet portion of an SCR (Selective Catalytic Reduction) of an exhaust pipe and a urea solution supplied from a urea solution injector of the exhaust pipe to the inlet portion of the SCR in order to decrease an amount of exhaust gas generated during a combustion process of mixed gas of the diesel engine and accompanying nitrogen oxide (NOx) discharged to the atmosphere.
  • BACKGROUND OF THE DISCLOSURE
  • In general, a diesel engine injects fuel, such as diesel, into a combustion chamber in a state where air supplied from the outside to the combustion chamber is compressed at a high temperature and high pressure, to generate output by turning force of a crank shaft connected with a connecting rod of a vertically moving piston by explosive force generated during a process of combusting and exploding mixed gas of air and fuel.
  • In general, in the diesel engine, fuel efficiency is considerably changed according to a mixture ratio (for example, an air-fuel ratio) of the air and the fuel supplied to the combustion chamber. When the amount of air supplied to the combustion chamber is larger than that of the fuel supplied to the combustion chamber, output is greatly increased, but the air supplied to the combustion chamber the air and is harmful to the human body, and an amount of generation of nitrogen oxide (NOx) which is the cause of acid rain, photochemical smog phenomenon, and the like is increased. Contrary to this, when the amount of air supplied to the combustion chamber is smaller than that of the fuel supplied to the combustion chamber, output deteriorates and a PM (particulate matter) or soot is increased.
  • Because of the aforementioned combustion characteristic of the diesel engine, a recent diesel engine has employed an exhaust gas post-treatment method of increasing the amount of air supplied to the combustion chamber to be larger than of the fuel supplied to the combustion chamber to considerably increase output, and making mixed gas of a urea solution and exhaust gas pass through an SCR by injecting the urea solution to the inlet portion of the SCR to change nitrogen oxide (NOx) accompanied by the exhaust gas to innoxious water (H2O) and nitrogen (N2).
  • In general, a mixer of the diesel engine serving to mix a urea solution and exhaust gas for the exhaust gas post-treatment includes an exhaust pipe including a urea solution injector adapter in which a urea solution injector is simply mounted, and a channel unit installed inside the exhaust pipe and including a plurality of guiding channels.
  • Accordingly, when the diesel engine is operated, exhaust gas generated in a combustion chamber and the urea solution injected from the urea solution injector are mixed together while passing through the plurality of guiding channels of the channel unit, to be guided to an SCR disposed at a rear side of the mixer, and the nitrogen oxide (NOx) accompanied by the exhaust gas generates catalytic reduction reaction with the urea solution while passing through the SCR to be changed to innoxious water and nitrogen.
  • However, since the mixer of the diesel engine in the related art has a structure in which the channel unit including the plurality of guiding channels is simply accommodated inside the exhaust pipe, there is a problem in that the exhaust gas discharged from an exhaust manifold of the engine to the mixer is not finely and evenly mixed well with the urea solution supplied from the urea solution injector, so that an amount of nitrogen oxide (NOx) discharged to the atmosphere is not largely decreased.
  • Further, in the mixer of the diesel engine in the related art, since the exhaust pipe accommodating the channel unit has a form of a single duct, when the urea solution is in direct contact with an inner wall surface of the exhaust pipe directly exposed to the air, the urea solution is not evaporated and flows down along the inner wall surface of the exhaust pipe, so that there is a problem in that the urea solution is not appropriately used for decreasing nitrogen oxide (NOx) and is directly discharged to the outside.
  • The discussion above is merely provided for general background information and is not intended to be used as an aid in determining the scope of the claimed subject matter.
  • SUMMARY
  • This summary and the abstract are provided to introduce a selection of concepts in a simplified form that are further described below in the Detailed Description. The summary and the abstract are not intended to identify key features or essential features of the claimed subject matter, nor are they intended to be used as an aid in determining the scope of the claimed subject matter.
  • Accordingly, the present disclosure provides a static mixer for mixing a urea solution and engine exhaust gas, by which exhaust gas before passing through an SCR and the urea solution can be finely and evenly mixed in order to considerably decrease an amount of nitrogen oxide (NOx) discharged to the atmosphere.
  • Further, the present disclosure provides a static mixer for mixing a urea solution and engine exhaust gas, by which exhaust gas and a urea solution can be finely and evenly mixed by improving an evaporation environment of the urea solution supplied from a urea solution injector to an input portion of an SCR, thereby decreasing an amount of nitrogen oxide (NOx) discharged to the atmosphere and removing waste of the urea solution.
  • In order to achieve the above object, the present disclosure provides a static mixer for mixing a urea solution and engine exhaust gas, including: an external tube including one end portion connected to an exhaust manifold of a diesel engine, the other end portion connected to an SCR (Selective Catalytic Reduction), and a part with which a urea solution injection adaptor is provided; an internal tube installed inside the external tube so as to have a constant gap between at least a part of an outer wall surface and an inner wall surface of the external tube; and a channel unit including a plurality of guiding channels provided inside the internal tube in a longitudinal direction, and having a inlet portion facing a lower end portion of the urea solution injector adaptor.
  • Further, the present disclosure further provides detailed exemplary embodiments for the exemplary embodiment of the present disclosure below.
  • According to the exemplary embodiment of the present disclosure, the internal tube may include at least one protrusion at an outer peripheral portion.
  • According to the exemplary embodiment of the present disclosure, the channel unit may include a plurality of first channel plates arranged in the internal tube with predetermined intervals therebetween, and a plurality of second channel plates inclined at a predetermined angle with respect to the plurality of first plates and disposed to cross the plurality of first plates with predetermined intervals therebetween.
  • According to the exemplary embodiment of the present disclosure, an exposed portion of at least one of the plurality of first and second channel plates may have at least one through hole so as to achieve a fine and even mixing behavior between the exhaust gas and the urea solution.
  • According to the exemplary embodiment of the present disclosure, a plurality of blades may be provided at an end portion of an outlet side of at least one of the plurality of first and second channel plates so as to achieve a fine and even mixing behavior between the exhaust gas and the urea solution.
  • According to the exemplary embodiment of the present disclosure, the plurality of blades may be inclinedly arranged in an opposite direction for each layer of the first and second channel plates.
  • According to the exemplary embodiment of the present disclosure, the inlet portion of the channel unit may include a first inclined portion having a predetermined angle with respect to a longitudinal direction of the internal tube, and a second inclined portion having a predetermined angle with respect to the first inclined portion.
  • According to the exemplary embodiment of the present disclosure, an orientation angle of the first inclined portion may be 0 to 30° in an outside direction with respect to a virtual axial line perpendicular to the longitudinal direction of the internal tube.
  • According to the exemplary embodiment of the present disclosure, each of end surfaces of the first and second inclined portions at an end surface of an inlet side may have a shape of a straight line, a curved line, or a combination thereof.
  • According to the exemplary embodiment of the present disclosure, the respective three first and second channel plates are included so as to form four rooms in one direction and the other direction, respectively.
  • According to the exemplary embodiment of the present disclosure, the gap between the internal tube and the external tube is 5 to 10 mm.
  • According to the present disclosure, the present disclosure may form fine and even mixed gas by providing the channel unit having the plurality of guiding channels and the inlet portion inside the internal tube shaped like a dual tube including the external tube surrounding the internal tube at a predetermined gap, and making the exhaust gas and the urea solution before passing through the SCR pass through the inlet portion and the plurality of guiding channels of the channel unit, thereby largely decreasing an amount of nitride oxide (NOx) discharged to the outside by improving a catalytic reduction reaction ratio in the SCR.
  • Further, the present disclosure provides the channel unit including the plurality of guiding channels and the inlet portion inside the internal tube shaped like a dual tube to insulate the internal tube against the external tube directly exposed to the outside, so that an evaporation ratio of the urea solution supplied from the urea solution injector to the inlet portion and the plurality of guiding channels of the channel unit, thereby decreasing an amount of nitride oxide (NOx) discharged to the outside and removing waste of the urea solution.
  • DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic perspective view illustrating a static mixer for mixing a urea solution and engine exhaust gas according to the present disclosure.
  • FIG. 2 is a schematic perspective view illustrating an end portion of an outlet of the static mixer according to the present disclosure.
  • FIG. 3 is a schematic perspective view illustrating an internal tube and a channel unit provided inside the internal tube of the static mixer according to the present disclosure.
  • FIG. 4 is a schematic cross-sectional view illustrating an angle orientation relation between a first inclined portion of a inlet portion provided at the channel unit and an external tube of the static mixer according to the present disclosure.
  • Description of Main Reference Numerals of Drawings
    1: Static mixer 102: External tube
    3: Internal tube 3a: Protrusion
    5: Urea solution injector adaptor 10: Channel unit
    11: Guiding channel 12: Bent inlet portion
    12a: First inclined portion 12b: Second inclined portion
    13: First channel plate 14: Second channel plate
    15: Through-hole 16: Blade
  • DETAILED DESCRIPTION
  • Hereinafter, an exemplary embodiment of a static mixer for mixing a urea solution and engine exhaust gas according to the present disclosure will be described with reference to FIGS. 1 to 4.
  • First, a term “static mixer” is an expression widely used in a corresponding business field and is a counterpart concept to a dynamic mixer, and means a mixer (or a mixing device) for finely and evenly mixing exhaust gas and a urea solution without a dynamic motion.
  • Further, in a description of the present disclosure, two terms of “a plurality of” and “multiple” are discriminatingly used. The term of “a plurality of” is used so as to emphasize a case in which a technical meaning is significant when the number of corresponding constituent elements is two or more, and the term of “multiple” is used so as to represent a case in which there are simply a lot of corresponding constituent elements.
  • The static mixer 1 of the present disclosure includes, as illustrated in FIGS. 1 to 3, an external tube 2, an internal tube 3, and a channel unit 10. Here, one end portion of the external tube 2 is connected to an exhaust manifold (not illustrated) of a diesel engine, and the other end portion is connected to an SCR (not illustrated), and a urea solution injector adaptor 5 is provided at a part of the external tube 2. The external tube 2 may be connected to an exhaust pipe (not illustrated) by a welding method or a detachable method.
  • The internal tube 3 is fixed while being accommodated inside the external tube 2 so that at least one portion of an outer wall surface of the internal tube 3 has a constant gap from an inner wall surface of the external tube 2.
  • The channel unit 10 is provided inside the internal tube 3 and includes multiple guiding channels 11 in a longitudinal direction, and has a inlet portion 12 facing a lower end portion of the urea solution injector adaptor 5.
  • According to the static mixer 1 of the present disclosure, exhaust gas discharged from the exhaust manifold to the static mixer 1 of the diesel engine and the urea solution supplied from a urea solution injector (not illustrated) installed in the urea solution injector adaptor 5 of the static mixer 1 to the static mixer 1 are finely and evenly mixed with each other while passing through the channel unit 10 including the bent inlet portion 12 and the multiple guiding channels 11.
  • Further, according to the static mixer 1 of the present disclosure, the urea solution supplied from the urea solution injector (not illustrated) installed in the urea solution injector adaptor 5 to the static mixer 1 may be injected to the channel unit 10 inside the internal tube 3, thereby solving a problem of the related art in that the urea solution is in directly contact with the inner wall surface of the external tube 2 to be changed in a liquid state and flow down along the inner wall surface of the external tube 2.
  • Accordingly, the static mixer 1 of the present disclosure enables mixed gas of the exhaust gas and the urea solution finely and evenly mixed well while passing through the static mixer to well have a catalytic reduction reaction when passing through the SCR (not illustrated), thereby eventually greatly decreasing an amount of nitrogen oxide (NOx) discharged to the air and decreasing waste of the urea solution.
  • Further, the static mixer for mixing the urea solution and the engine exhaust gas according to the present disclosure may be implemented as a form further defined by detailed exemplary embodiments below in addition to the aforementioned fundamental configuration.
  • As an exemplary embodiment, the internal tube 3 may be provided in a form having at least one or more protrusions 3 a at an outer peripheral portion so as to maintain a constant gap from the external tube 2. The protrusion 3 a may be formed at one point, two points, three points, or more points than three points in the external surface of the internal tube 3 while having a predetermined interval therebetween. The gap between the internal tube 3 and the external tube 2 may be conveniently formed by a structure of the protrusion of the internal tube. The gap between the internal tube 3 and the external tube 2 may be formed by interposing a separate insulating spacer (not illustrated).
  • As the exemplary embodiment, the channel unit 10 may include a plurality of first channel plates 13 arranged in the internal tube 3 with predetermined intervals therebetween, and a plurality of second channel plates 14 inclined with respect to the plurality of first plates 13 at a predetermined angle, and disposed to cross the plurality of first plates 13 with predetermined intervals therebetween. The plurality of guiding channels 11 for guiding the exhaust gas, the urea solution, or mixed gas in which the exhaust gas is mixed with the urea solution may be conveniently formed by a structure of the plurality of first and second channel plates.
  • As the exemplary embodiment, an exposed portion of at least one of the plurality of first and second channel plates 13 and 14 may be provided in a form having at least one through-hole 15 so that the exhaust gas and the urea solution are evenly mixed. In this case, the through hole 15 may have various shapes, such as a circular shape, an elliptical shape, a slit, or a slot. A structure of the through-hole of the plurality of first and second channel plates improves an active mixing behavior between the exhaust gas and the urea solution guided to the adjacent guiding channels among the plurality of guiding channels 11.
  • As the exemplary embodiment, a plurality of blades 16 may be provided at an end portion of an outlet side of at least one of the plurality of first and second channel plates 13 and 14 so that the exhaust gas and the urea solution are finely and evenly mixed. In this case, the plurality of blades 16 may be inclinedly arranged in an opposite direction for each layer of the first and second channel plates 13 and 14. This is because an active mixing behavior between the exhaust gas and the urea solution is improved by creating a vortex phenomenon in the exhaust gas and the urea solution passing through the end portions of the outlet sides of the plurality of first and second channels plates 13 and 14.
  • As the exemplary embodiment, the internal tube 3 may be fixed concentrically or eccentrically with respect to the external tube 2. In this case, a structure in which the internal tube 3 is disposed concentrically with respect to the external tube 2 has an advantage in that the gap between the internal tube 3 and the external tube 2 may be regularly formed. A structure in which the internal tube 3 is disposed eccentrically with respect to the external tube 2 has an advantage in that the internal tube 3 may be simply and conveniently fixed to the external tube 2.
  • Otherwise, the gap between the internal tube 3 and the external tube 2 may be 5 to 10 mm. This is because there is a disadvantage in that an insulation effect of the internal tube 3 against the external tube 2 is decreased when the gap between the internal tube 3 and the external tube 2 is less than 5 mm, and there are high concerns regarding the direct discharge of a part of the exhaust toward the SCR without the mixing behavior with the urea solution when the gap between the internal tube 3 and the external tube 2 exceeds 10 nm.
  • As the exemplary embodiment, the bent inlet portion 12 of the channel unit 10 may include a first inclined portion 12 a having a predetermined angle with respect to a longitudinal direction of the internal tube 3, and a second inclined portion 12 b having a predetermined angle with respect to the first inclined portion 12 a. In this case, as illustrated in FIG. 4, an orientation angle of the first inclined portion 12 a may be 0 to 30° in an outside direction with respect to a virtual axial line perpendicular to the longitudinal direction of the internal tube 3. This is because there is a disadvantage in that when the orientation angle of the first inclined portion 12 a is smaller than 0° (that is, the first inclined portion 12 a is inwardly formed with respect to the vertical axial line of the internal tube), or exceeds 30°, the mixture ratio of the exhaust gas to the urea solution is remarkably decreased compared to a case where the orientation angle of the first inclined portion 12 a has the aforementioned range. Otherwise, end surfaces of the first and second inclined portions 12 a and 12 b at the inlet side may be formed in a shape of a straight line, a curved line, or a combination thereof.
  • As the exemplary embodiment, the three first channel plates 13 and the three second channel plates 14 may be included so as to have four rooms in one direction and the other direction, respectively. The structure of the plurality of first and second channel plates having the aforementioned arrangement improves the mixing behavior between the exhaust gas and the urea solution compared to a case where the number of each of the first and second channels plates is smaller than 3 or exceeds 3. This is because discharge pressure of the exhaust gas and/or mixing power between the exhaust gas and the urea solution is changed according to a dense arrangement or sparse arrangement of the plurality of first and second channel plates 13 and 14.
  • An operation of the static mixer for mixing the urea solution and the exhaust gas configured as described above will be described with reference to FIGS. 1 to 4 below.
  • When the static mixer 1 according to the present disclosure is installed at the inlet side of the SCR so as to form a partial portion of the exhaust pipe connecting the exhaust manifold (not illustrated) and the SCR (not illustrated) of the diesel engine and a diesel engine is operated, exhaust gas generated at the time of combustion and explosion in the combustion chamber of the diesel engine during the operation of the diesel engine is discharged toward the inlet portion of the channel unit 10 of the static mixer 1 through the exhaust manifold.
  • Further, a urea solution is simultaneously injected from the urea solution injector (not illustrated) installed in the urea solution injector adaptor 5 of the external tube 2 of the static mixer 1 to the inlet portion of the channel unit 10 of the static mixer 1.
  • In this case, the exhaust gas and the urea solution are primarily finely and evenly mixed together while flowing inside the plurality of guiding channels 11 through the bent inlet portion 12 of the channel unit 10. In the meantime, in a case of the exemplary embodiment in which the through-hole 15 is further provided at the exposed portions of the first and second channel plates 13 and 14 of the channel unit 10, the mixing behavior between the exhaust gas and the urea solution passing through the plurality of guiding channels 11 may be more actively performed.
  • Subsequently, the exhaust gas and the urea solution discharged to the end portion of the outlet side of the channel unit 10 through the plurality of guiding channels 11 of the channel unit 10 generate a vortex while crashing against the plurality of blades 16 of the channel unit 10, thereby being more finely and evenly mixed secondarily.
  • Mixed gas of the exhaust gas and the urea solution, which become fine and even in an optimum state while passing through the channel unit 10 of the static mixer 1 according to the present disclosure, is guided to the SCR. Then, the nitrogen oxide (NOx) accompanied by the exhaust gas incurs a catalytic reduction reaction with the urea solution while passing through the SCR to be changed to innoxious water (H2O) and nitrogen (N2) and discharged to the air.
  • The aforementioned present disclosure is not limited to the aforementioned exemplary embodiments and the accompanying drawings, and simple substitution, change, and modification within the technical spirit of the present disclosure are obvious to those skilled in the art.
  • The static mixer for mixing a urea solution and engine exhaust gas according to the present disclosure is installed at a side of an exhaust pipe of a diesel engine to change nitrogen oxide (NOx) accompanied by the exhaust gas into innoxious water (H2O) and nitrogen (N2), so that the static mixer is usable for decreasing atmosphere environmental pollution.
  • Although the present disclosure has been described with reference to exemplary and preferred embodiments, workers skilled in the art will recognize that changes may be made in form and detail without departing from the spirit and scope of the disclosure.

Claims (13)

1-11. (canceled)
12. A static mixer for mixing a urea solution and engine exhaust gas, comprising:
an external tube including one end portion connected to an exhaust manifold of a diesel engine, the other end portion connected to an SCR (Selective Catalytic Reduction), and a part with which a urea solution injection adaptor is provided; and
a channel unit provided inside the external tube, comprising a plurality of guiding channels in a longitudinal direction, and having an inlet portion facing a lower end portion of the urea solution injector adaptor.
13. The static mixer for mixing a urea solution and engine exhaust gas of claim 12, further comprising:
an internal tube installed inside the external tube so as to have a constant gap between at least a part of an outer wall surface and an inner wall surface of the external tube,
wherein the inlet portion is installed inside the internal tube.
14. The static mixer of claim 13, wherein the internal tube includes at least one protrusion at an outer peripheral portion.
15. The static mixer of claim 13, wherein the channel unit comprises a plurality of first channel plates arranged in the internal tube with predetermined intervals therebetween, and a plurality of second channel plates inclined at a predetermined angle with respect to the plurality of first plates and disposed to cross the plurality of first plates with predetermined intervals therebetween.
16. The static mixer of claim 15, wherein an exposed portion of at least one of the plurality of first and second channel plates has at least one through hole so as to achieve a fine and even mixing behavior between the exhaust gas and the urea solution.
17. The static mixer of claim 15, wherein a plurality of blades is provided at an end portion of an outlet side of at least one of the plurality of first and second channel plates so as to achieve a fine and even mixing behavior between the exhaust gas and the urea solution.
18. The static mixer of claim 17, wherein the plurality of blades is inclinedly arranged in an opposite direction for each layer of the first and second channel plates.
19. The static mixer of claim 13, wherein the inlet portion of the channel unit includes a first inclined portion having a predetermined angle with respect to a longitudinal direction of the internal tube, and a second inclined portion having a predetermined angle with respect to the first inclined portion.
20. The static mixer of claim 19, wherein an orientation angle of the first inclined portion is 0 to 30° in an outside direction with respect to a virtual axial line perpendicular to the longitudinal direction of the internal tube.
21. The static mixer of claim 19, wherein each of end surfaces of the first and second inclined portions at an end surface of an inlet side has a shape of a straight line, a curved line, or a combination thereof.
22. The static mixer of claim 15, wherein the respective three first and second channel plates are included so as to form four rooms in one direction and the other direction, respectively.
23. The static mixer of claim 13, wherein the gap between the internal tube and the external tube is 5 to 10 mm.
US13/808,759 2010-07-08 2011-07-07 Static mixer for mixing urea aqueous solution and engine exhaust gas Abandoned US20130104531A1 (en)

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KR1020100065983A KR101664494B1 (en) 2010-07-08 2010-07-08 Static mixer for mixing urea aqueous solution and engine exhaust gas
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EP2592246A4 (en) 2016-03-02
KR20120005304A (en) 2012-01-16
WO2012005527A3 (en) 2012-05-03
EP2592246B1 (en) 2020-10-14
KR101664494B1 (en) 2016-10-13
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CN102985654A (en) 2013-03-20
WO2012005527A2 (en) 2012-01-12

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