US20110073255A1 - Composite structures having reinforced edge bonded joints and method for making the same - Google Patents
Composite structures having reinforced edge bonded joints and method for making the same Download PDFInfo
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- US20110073255A1 US20110073255A1 US12/961,166 US96116610A US2011073255A1 US 20110073255 A1 US20110073255 A1 US 20110073255A1 US 96116610 A US96116610 A US 96116610A US 2011073255 A1 US2011073255 A1 US 2011073255A1
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- bridging
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- layer
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
- C04B37/008—Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of an organic adhesive, e.g. phenol resin or pitch
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/18—Aircraft
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/62—Forming laminates or joined articles comprising holes, channels or other types of openings
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/76—Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1052—Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
- Y10T156/1056—Perforating lamina
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24149—Honeycomb-like
Definitions
- This disclosure generally relates to composite structures, and deals more particularly with a ceramic matrix composite sandwich, and rib stiffened structures having reinforced edge bonded joints.
- Edge bonding is widely employed in composite structures, such as honeycomb core sandwich panels or grid stiffened shells suitable for various applications, such as those used in the aerospace industry.
- the elements of the structures may be formed from polymeric matrix composites reinforced with various types of fibers. Core elements or stiffeners are joined to facesheets or skins using edge bonds.
- a polymeric matrix composite structure 20 includes spaced facesheets 22 , 24 joined together by web-like stiffeners 26 that are edge bonded at 27 to the facesheets 22 , 24 . Since the stiffeners 26 are required to transmit compressive, tensile and shear loads, it may be necessary to reinforce the edge bonded joints 27 using fillets 28 which may comprise a polymeric adhesive.
- the fillets 28 adhere to both the facesheets 22 , 24 and the sides of the stiffeners 26 , covering the bond line (not shown) at the edge bonded joints 27 .
- the structure 20 shown in FIG. 1 is well suited for forming honeycomb sandwich structures that distribute loads to peripheral members or carry in-plane loads while resisting buckling. Moreover these structures are relatively economical to fabricate, due in part to the simplicity of the edge bonded joints 27 .
- the polymeric-based construction shown in FIG. 1 is not suitable, due to the fact that polymeric matrix materials lose strength and stiffness at high temperatures.
- CMC ceramic matrix composites
- CMOS complementary metal-oxide-semiconductor
- a matrix material often referred to as a prepreg
- ceramic fibers are available in a variety of other forms, including tape, tows and three dimensional woven preforms.
- Several methods may be used to fabricate CMC's, including for example, hand-layup, filament winding, tow placement and dry fiber preforms with vacuum assisted matrix infusion. The construction shown in FIG.
- CMC structures having reinforced, edge bonded joints capable of carrying tensile, compressive and shear loads.
- CMC constructions having edge bonded core elements are made possible by reinforcing the edge bonded joints between the core elements and the facesheets of the sandwich construction.
- the edge bonded joints are reinforced by bridge members that cover the bond lines and abut opposite sides of the core elements in order to improve the resistance of the core elements to shear forces.
- the bridge members may be economically manufactured by depositing a continuous layer of rigid foam on a facesheet and then forcing edges of the core elements through the foam layer.
- a ceramic composite structure comprising: at least one ceramic matrix composite sheet; a stiffener extending transverse to the sheet and having at least one edge; an edge bonded joint between edge of the sheet; and bridging members on opposite sides of the stiffener for reinforcing the edge bonded joint.
- the bridging members abut opposite sides of the stiffener and cover bond lines between the stiffener and the facesheet.
- the sheet and the stiffener may comprise a ceramic matrix composite.
- the bridging members may be formed of rigid foam having a density less than the density of the stiffener.
- the bridging members may be a ceramic foam or a sintered ceramic fiber felt. Spacers of low density or fugitive materials may be placed in the volume between bridging members.
- a ceramic matrix composite structure comprising: first and second spaced apart ceramic matrix composite sheets; a core sandwiched between the first and second composite sheets, including a rigid web extending transverse to the first and second sheets and having opposite ends respectively bonded to the first and second sheets; and, first and second reinforcement layers abutting opposite sides of the web for reinforcing the bonds between the opposite ends of the webs and the first and second composite sheets.
- the composite sheets may include multiple plies of fiber fabric held in a ceramic matrix.
- the reinforcement layers may include a rigid ceramic foam having a density less than the density of the web.
- Each of the first and second reinforcement layers may include a bridging member having a bottom bonded to a corresponding one of the facesheets and a side abutting one of the opposite sides of the web.
- a ceramic matrix composite structure may be formed by the steps comprising: forming first and second layers of bridging material; forcing a first edge of a web through the first layer of bridging material; forcing a second opposite edge of the web through the second layer of bridging material; applying first and second facesheets to opposite sides of the web; and bonding the first and second edges respectively to the first and second facesheets.
- the method may further comprise bonding the first and second layers of bridging material respectively to the first and second facesheets.
- the bonding may include bonding the first and second layers of bridging material to the first and second facesheets substantially concurrently.
- a ceramic matrix composite structure may be fabricated by the steps comprising: forming first and second layers of bridging material; forcing a first edge of a web through the first layer of bridging material; forcing a second opposite edge of the web through the second layer of bridging material; applying first and second facesheets to opposite sides of the web; and bonding the first and second edges respectively to the first and second facesheets.
- a ceramic matrix composite structure may be fabricated by the steps comprising: placing a reinforcing core in a layer of foam; forming a first layer of bridging material on a first side of the foam layer bridging the sides of the core; bonding a first facesheet to the first side of the foam layer; forming a second layer of bridging material on a second side of the foam layer bridging the sides of the core; bonding a second facesheet to a second side of the foam layer.
- a ceramic matrix composite structure may be fabricated by the steps comprising: forming structural stiffeners; forming bridging members for laterally reinforcing the stiffeners; forcing the stiffeners through the bridging members; laying up a facesheet; and, bonding the facesheet to the combination of the stiffeners and the bridging members.
- FIG. 1 is a perspective illustration of a prior art polymeric matrix composite structure employing fillets for reinforcing edge bonded joints;
- FIG. 2 is a perspective illustration of a CMC structure having reinforced core stiffening members according to an advantageous embodiment of the disclosure
- FIG. 3 is a sectional view of the area designated as “A” in FIG. 2 ;
- FIG. 4 is a perspective illustration similar to FIG. 2 but showing an alternate advantageous embodiment of the CMC structure employing a foam core;
- FIG. 5 is a perspective illustration of a further advantageous embodiment of the CMC structure
- FIG. 7 is a sectional illustration similar to FIG. 6 but showing the web having penetrated the bridging material and edge bonded to the facesheet;
- FIG. 8 is a perspective illustration of a honeycomb-type core
- FIG. 9 is a perspective illustration of a CMC structure having an open pattern of stiffeners in which areas of the bridging material has been removed;
- FIG. 10 is a block diagram illustrating one method of forming a CMC sandwich structure having a stiffened web
- FIG. 11 is a block diagram illustrating another method for forming a CMC sandwich structure having a stiffened web
- FIG. 12 is a block diagram illustrating one method for forming a rib-stiffened CMC shell structure
- FIG. 13 is a block diagram illustrating another method for forming a rib-stiffened CMC shell structure
- FIG. 14 is a flow diagram of an aircraft production and service methodology
- FIG. 15 is a block diagram of an aircraft.
- advantageous embodiments of the disclosure provide reinforcement of edge bonded joints in a variety of CMC structures.
- Edge bonding is widely employed in composite structures, such as honeycomb core sandwich panels or grid stiffened shells.
- These CMC structures typically comprise the following basic structural elements: (1) a shell element which may comprise the facesheet of a sandwich structure, the outer skin of a vehicle, the web of a stiffened panel, etc., (2) stiffeners, for example the core of a sandwich structure, ribs supporting the skin of a vehicle, or flanges stabilizing the web of a stiffened panel, and (3) bridging elements, which reinforce edge bonded joints between (1) and (2) above, and provide an alternate load paths between shell and stiffener outside the edge bond faying surface between the two.
- a CMC structure 30 broadly comprises a pair of spaced apart facesheets 22 , 24 between which there is sandwiched a core 25 .
- Each of the facesheets 22 , 24 may comprise multiple layers or plies of ceramic fiber material impregnated with a matrix material or “prepreg”.
- prepreg a matrix material
- the term “ceramic” refers to the conventionally known and commercially available ceramic materials that are fabricated in a fiber form.
- the ceramic fibers may include, but are not limited to, silicon carbide, silica, TYRANNO®, alumina, aluminoborosilicate, silicon nitride, silicon boride, silicon boronitride, and similar materials.
- the core 25 includes a plurality of spaced webs 26 , which have their opposite edges “edge bonded” at 27 to the facesheets 22 , 24 using commercially available, high temperature adhesives.
- the webs 26 extend substantially orthogonal to the facesheets 22 , 24 and function to transfer compressive, tensile and/or shear loads between facesheets 22 , 24 .
- the webs 26 forming the core 25 are shown as parallel, straight walls; however the core 25 comprise other configurations.
- the core 25 may comprise a honeycomb structure 26 b , which also acts as a spacer during the manufacturing process to hold the bridging members 32 against the facesheets 22 , 24 .
- the webs 26 may transfer compressive, tensile and/or shear loads between the facesheets 22 , 24 .
- shear loads on facesheet 22 indicated by the arrows 34 are transmitted through the web 26 to facesheet 24 , as indicated by the arrows 36 .
- the edge bonded joints 27 are laterally reinforced by bridging members 32 that are bonded to the facesheets 22 , 24 , and abut opposite sides of each end of the web 26 .
- the bridging members 32 are placed in the corners between the web 26 and the facesheets 22 , 24 so as to cover the bond lines 29 (see FIG. 3 ) between the webs 26 and the facesheets 22 , 24 at the joints 27 .
- the thickness of the bridging members 32 will depend on the requirements of the particular application, and the strength of the material forming the bridging members 32 . Generally, the bridging members 32 should have a thickness sufficient to reinforce the web 26 enough to transmit the desired level of shear force to facesheets 22 , 24 . In the advantageous embodiment shown in FIGS. 2 and 3 , the bridging members 32 are rectangular in shape, however other shapes are possible, and the particular geometry will depend upon the shape of the webs 26 and other core materials. The bridging members 32 extend between opposing ones of the webs 26 so that a single bridging element reinforces the edge bonded joints 27 on two adjacent webs 26 .
- the bridging members 32 may be made of a low density, high temperature material which may be high temperature foam, such as ceramic foams or fused filamentary materials such as the rigid foam insulation disclosed in U.S. Pat. No. 6,716,782 issued Apr. 6, 2004 and assigned to the Boeing Company.
- the rigid foam insulation described in this prior patent is a combination of ceramic fibers which are sintered together to form a low density, highly porous material with low thermal conductivity. This foam exhibits high tensile strength and good dimensional stability.
- the material forming the bridging members 32 should have an acceptable ratio of strength-to-density and should be suitable for being sheared by the web 26 so that hand fitting is not required.
- bridging members 26 may be made from materials other than a foam.
- the bridging members 26 may be formed from a low density felt of sintered ceramic fibers.
- the bridging material may be seated in position by cutting through it with the shear carrying web 26 during the assembly process.
- the density of the bridging members 32 generally should be less than the density of web 26 and/or the facesheets 22 , 24 .
- bridging members 32 providing useful results may be formed from material having a density approaching that of the web 26 , depending on the application and the loads to be carried by the web 26 .
- the bridging material must be strong enough to carry the loads for the intended application, but sufficiently friable that the core 25 can be forced through it to form the joint geometry.
- FIG. 4 illustrates an alternate CMC construction 30 a in which a filler material 38 is used to facilitate the fabrication process.
- a layer of filler material 38 is then formed over the foam layer 32 a , following which the web 26 a or other grid core is forced through both the filler layer 38 a and the foam layer 32 a .
- a second layer 32 a of bridging material is then deposited over the filler material 38 , following which the second facesheet 22 is applied.
- the filler material 38 may comprise high temperature, rigid foam which may have a density less than that of the bridging members 32 .
- the foam filler material 38 may serve the purpose of bridging members 32 , thus eliminating the need for the individual layers 32 a of bridging material.
- the filler material 38 acts as a spacer between the bridging members on the opposite facesheets 12 , 14 .
- the filler material may comprise low density or fugitive materials that are placed in the volume between bridging members 32 . In some applications a relatively high thermal conductivity material may be chosen. Since the filler material 38 need not be bonded to surrounding materials, it need not be a ceramic or a material with a coefficient of thermal expansion close to that of the structural elements. It is also possible that the low density spacer 38 being used to facilitate the manufacturing process may be a fugitive material. Many materials sublimate at the high temperatures used for sintering ceramic matrix composites. These materials may be used as temporary tooling while building CMC structures. During the sintering phase of curing the CMC structure, the temporary element turns to gas and is vented out of the structure.
- FIG. 5 illustrates another advantageous embodiment of a CMC structure 30 b in which relatively thick, stiffening ribs 26 a form the core of the structure 30 b .
- the stiffening ribs are edge bonded to a single facesheet 24 , or shell, to form a stiffened shell structure 30 b .
- the facesheet 24 may comprise for example, the outer skin of an aerospace vehicle.
- the spacing between adjacent ribs 26 a may be greater than the spacing of the webs 26 in the advantageous embodiments shown in FIGS. 1-4 .
- the bridging members 32 may not span the entire distance between adjacent ribs 26 a , so that each rib 26 a has an edge bonded joint reinforced by a pair of bridging members 32 .
- the width of the bridging members 32 should be at least equal to or greater than their thickness in order to provide adequate reinforcement of the web 26 a .
- Using bridging members 32 having a reduced width may reduce the weight of the structure 30 b , which may be desirable in applications such as aircraft.
- FIGS. 6 and 7 illustrate another advantageous embodiment in which the bridging members 32 are formed from a continuous layer of material such as high temperature rigid foam that is deposited and bonded to the inside face of each of the facesheets 22 , 24 .
- the material characteristics, including the density of the foam layer 32 a should be such that it may be cut or penetrated by a web 26 a during the fabrication process.
- the rigid foam layer 32 a having been bonded to the facesheets 22 , 24 , the web 26 a is then moved in the direction of the arrow 42 and is forced through the foam layer 32 a until the corresponding facesheet 22 , 24 a is contacted to create an edge bonded joint.
- portions of the foam layer 32 a abut the sides of the web 26 a and thereby laterally reinforce the edge bonded joint 27 against shear loads.
- the use of a continuous layer 32 a of rigid foam allows a wide variety of web geometries and shapes to be employed, including regular or irregular honeycomb configurations and grids since, during fabrication, the layer 32 a of foam will conform to all sides of the web 26 a , regardless of the web geometry.
- the material used as the bridging members 32 should be bonded to both the adjacent facesheet and web. This may be done by wetting the joints with an appropriate slurry before curing the assembly. Other methods of forming the bridging members are possible. For example, a thin layer of bridging material may be bonded to a facesheet or a skin. Alternatively, a thick layer of bridging material maybe bonded to a facesheet or skin, following which the bridging material may be machined down to a final desired thickness. In another method, core material may be pressed into a sheet of bridging material to form a subassembly (held together only by friction), following which a facesheet or skin is bonded to the assembly.
- FIG. 9 illustrates a grid reinforced shell 30 c in which a grid of stiffening ribs 26 c are edge bonded to a facesheet 24 or other shell element.
- Reinforcing bridging members 32 c cover the bond lines between the stiffening ribs 26 c and the facesheet 24 .
- the bridging members 32 c may be formed by bonding a formed or cut piece of bridging material to the facesheet 24 , and then removing portions of the material in central areas 40 , as by machining, for example, in order to reduce the weight of the structure 30 c .
- the remaining width of the bridging members 32 c should be sufficient to carry the load for the particular application of the CMC structure 30 c.
- FIG. 10 illustrates the basic steps of one method for fabricating a web stiffened CNC sandwich structure.
- the web is formed, following which the bridging members 32 are formed or cut to size, as shown at step 46 .
- a first side of the web is forced through a first set of bridging material, following which, at step 50 , the second side of the web is forced through the second set of bridging members 32 .
- the facesheets 22 , 24 are laid up on the respective sides of the web with the attached bridging members, and the edges of the web are edge bonded to both facesheets, concurrently.
- the assembled CMC structure is cured.
- FIG. 11 An alternate method of fabricating a web stiffened CMC sandwich structure is shown in FIG. 11 .
- the web and reinforcements around the foam filler are formed.
- a first rigid foam layer and bridging material is applied to the first side of the first web and foam filler core (or forced through the web).
- the first facesheet is bonded to the core with the attached bridging material.
- the second rigid foam layer and bridging material is applied to the second side of the combination of the web and foam filler core, or forced through the web.
- the second facesheet is then bonded to the opposite side of the core having the attached bridging material.
- the assembled CMC structure is cured.
- FIG. 12 illustrates the steps of one method for fabricating a rib stiffened shell type CMC structure.
- the stiffeners or web are formed at step 68 , following which the bridging members are formed or cut to size, as shown at step 70 .
- the stiffeners are forced through the bridging members as shown at step 72 .
- the shell element or facesheets are laid up, following which the assembled CMC structure is cured at step 76 .
- FIG. 13 illustrates the steps of another method for fabricating a rib stiffened, shell type CMC structure.
- the shell element or facesheets are laid up.
- the bridging members are formed or cut to size at step 80 .
- the bridging members are bonded to the shell element (or facesheets).
- the stiffeners or web are formed.
- the stiffeners or web are forced through the bridging members and are edge bonded to the shell element.
- the assembled CMC structure is cured.
- exemplary method 90 may include specification and design 92 of the aircraft 106 and material procurement 94 .
- component and subassembly manufacturing 96 and system integration 98 of the aircraft 106 takes place.
- the aircraft 106 may go through certification and delivery 100 in order to be placed in service 102 .
- the aircraft 106 is scheduled for routine maintenance and service 102 (which may include modification, reconfiguration, refurbishment, and so on).
- a system integrator may include without limitation any number of aircraft manufacturers and major-system subcontractors; a third party may include without limitation any number of venders, subcontractors, and suppliers; and an operator may be an airline, leasing company, military entity, service organization, and so on.
- the aircraft 106 produced by exemplary method 90 may include an airframe 108 with a plurality of systems 96 and an interior 112 .
- high-level systems 110 include one or more of a propulsion system 114 , an electrical system 116 , a hydraulic system 118 and an environmental system 120 . Any number of other systems may be included.
- an aerospace example is shown, the principles of the invention may be applied to other industries, such as the automotive industry.
- Structures and methods embodied herein may be employed during any one or more of the stages of the production and service method 90 .
- components or subassemblies corresponding to production process 90 may be fabricated or manufactured in a manner similar to components or subassemblies produced while the aircraft 106 is in service.
- one or more advantageous apparatus embodiments, method embodiments, or a combination thereof may be utilized during the production stages 96 and 98 , for example, by substantially expediting assembly of or reducing the cost of an aircraft 106 .
- one or more of advantageous apparatus embodiments, method embodiments, or a combination thereof may be utilized while the aircraft 106 is in service, for example and without limitation, to maintenance and service 104 .
Abstract
A ceramic matrix composite structure has a reinforced core for carrying loads. The core includes a web connected between the facesheets by edge bonded joints for transmitting compressive, tensile and shear loads. The edge bonded joints are laterally reinforced by bridging members bonded to the facesheets, on opposite sides of the webs. The bridging members may comprise low density, high temperature rigid foam.
Description
- This application is a divisional of application Ser. No. 11/770,157, filed Jun. 28, 2007, status pending.
- 1. Field
- This disclosure generally relates to composite structures, and deals more particularly with a ceramic matrix composite sandwich, and rib stiffened structures having reinforced edge bonded joints.
- 2. Background
- Edge bonding is widely employed in composite structures, such as honeycomb core sandwich panels or grid stiffened shells suitable for various applications, such as those used in the aerospace industry. In moderate and lower temperature range applications, the elements of the structures may be formed from polymeric matrix composites reinforced with various types of fibers. Core elements or stiffeners are joined to facesheets or skins using edge bonds. For example, as shown in
FIG. 1 , a polymericmatrix composite structure 20 includes spacedfacesheets like stiffeners 26 that are edge bonded at 27 to thefacesheets stiffeners 26 are required to transmit compressive, tensile and shear loads, it may be necessary to reinforce the edge bondedjoints 27 usingfillets 28 which may comprise a polymeric adhesive. Thefillets 28 adhere to both thefacesheets stiffeners 26, covering the bond line (not shown) at the edge bondedjoints 27. Thestructure 20 shown inFIG. 1 is well suited for forming honeycomb sandwich structures that distribute loads to peripheral members or carry in-plane loads while resisting buckling. Moreover these structures are relatively economical to fabricate, due in part to the simplicity of the edge bondedjoints 27. - In higher temperature applications however, such as those in which parts are subjected to high temperature exhaust gasses and/or atmospheric friction during re-entry of space vehicles, the polymeric-based construction shown in
FIG. 1 is not suitable, due to the fact that polymeric matrix materials lose strength and stiffness at high temperatures. - In higher temperature applications, such as the aerospace applications mentioned above, ceramic matrix composites (CMC) are commonly used because they are better suited to withstanding higher operating temperatures. Typically, CMC's comprise multiple layers of fiber fabric impregnated with a matrix material, often referred to as a prepreg, although ceramic fibers are available in a variety of other forms, including tape, tows and three dimensional woven preforms. Several methods may be used to fabricate CMC's, including for example, hand-layup, filament winding, tow placement and dry fiber preforms with vacuum assisted matrix infusion. The construction shown in
FIG. 1 however, is not directly reproducible using CMC materials because the production of CMC's involves a sintering step in which unfilled ceramic matrix material, such as that in fillets, tends to sublimate. Prior attempts to make honeycomb sandwich structures using CMC's have left a ceramic matrix bondline only in the small area where the edges of the honeycomb form a faying surface with the adjacent facesheets. The resulting bond is may be weak, even at very low loads. - Accordingly, there is a need for CMC structures employing edge bonded joints having improved joint strength in order to carry heavier loads. There is also a need for CMC structures having edge bonded joints that can be easily and economically fabricated. The disclosed advantageous embodiments are intended to satisfy these needs.
- Advantageous embodiments of the disclosure provide CMC structures having reinforced, edge bonded joints capable of carrying tensile, compressive and shear loads. CMC constructions having edge bonded core elements are made possible by reinforcing the edge bonded joints between the core elements and the facesheets of the sandwich construction. The edge bonded joints are reinforced by bridge members that cover the bond lines and abut opposite sides of the core elements in order to improve the resistance of the core elements to shear forces. The bridge members may be economically manufactured by depositing a continuous layer of rigid foam on a facesheet and then forcing edges of the core elements through the foam layer.
- According to one advantageous embodiment of the disclosure, a ceramic composite structure is provided comprising: at least one ceramic matrix composite sheet; a stiffener extending transverse to the sheet and having at least one edge; an edge bonded joint between edge of the sheet; and bridging members on opposite sides of the stiffener for reinforcing the edge bonded joint. The bridging members abut opposite sides of the stiffener and cover bond lines between the stiffener and the facesheet. The sheet and the stiffener may comprise a ceramic matrix composite. The bridging members may be formed of rigid foam having a density less than the density of the stiffener. The bridging members may be a ceramic foam or a sintered ceramic fiber felt. Spacers of low density or fugitive materials may be placed in the volume between bridging members.
- According to another disclosed advantageous embodiment, a ceramic matrix composite structure is provided, comprising: first and second spaced apart ceramic matrix composite sheets; a core sandwiched between the first and second composite sheets, including a rigid web extending transverse to the first and second sheets and having opposite ends respectively bonded to the first and second sheets; and, first and second reinforcement layers abutting opposite sides of the web for reinforcing the bonds between the opposite ends of the webs and the first and second composite sheets. The composite sheets may include multiple plies of fiber fabric held in a ceramic matrix. The reinforcement layers may include a rigid ceramic foam having a density less than the density of the web. Each of the first and second reinforcement layers may include a bridging member having a bottom bonded to a corresponding one of the facesheets and a side abutting one of the opposite sides of the web.
- According to one disclosed advantageous method embodiment, a ceramic matrix composite structure may be formed by the steps comprising: forming first and second layers of bridging material; forcing a first edge of a web through the first layer of bridging material; forcing a second opposite edge of the web through the second layer of bridging material; applying first and second facesheets to opposite sides of the web; and bonding the first and second edges respectively to the first and second facesheets. The method may further comprise bonding the first and second layers of bridging material respectively to the first and second facesheets. The bonding may include bonding the first and second layers of bridging material to the first and second facesheets substantially concurrently.
- According to another advantageous method embodiment, a ceramic matrix composite structure may be fabricated by the steps comprising: forming first and second layers of bridging material; forcing a first edge of a web through the first layer of bridging material; forcing a second opposite edge of the web through the second layer of bridging material; applying first and second facesheets to opposite sides of the web; and bonding the first and second edges respectively to the first and second facesheets.
- According to a further advantageous method embodiment, a ceramic matrix composite structure may be fabricated by the steps comprising: placing a reinforcing core in a layer of foam; forming a first layer of bridging material on a first side of the foam layer bridging the sides of the core; bonding a first facesheet to the first side of the foam layer; forming a second layer of bridging material on a second side of the foam layer bridging the sides of the core; bonding a second facesheet to a second side of the foam layer.
- According to still another advantageous method embodiment, a ceramic matrix composite structure may be fabricated by the steps comprising: forming structural stiffeners; forming bridging members for laterally reinforcing the stiffeners; forcing the stiffeners through the bridging members; laying up a facesheet; and, bonding the facesheet to the combination of the stiffeners and the bridging members.
- Other features, benefits and advantages of the disclosed advantageous embodiments will become apparent from the following description of advantageous embodiments, when viewed in accordance with the attached drawings and appended claims.
-
FIG. 1 is a perspective illustration of a prior art polymeric matrix composite structure employing fillets for reinforcing edge bonded joints; -
FIG. 2 is a perspective illustration of a CMC structure having reinforced core stiffening members according to an advantageous embodiment of the disclosure; -
FIG. 3 is a sectional view of the area designated as “A” inFIG. 2 ; -
FIG. 4 is a perspective illustration similar toFIG. 2 but showing an alternate advantageous embodiment of the CMC structure employing a foam core; -
FIG. 5 is a perspective illustration of a further advantageous embodiment of the CMC structure; -
FIG. 6 is a sectional illustration of a web positioned to be forced through a layer of bridging material; -
FIG. 7 is a sectional illustration similar toFIG. 6 but showing the web having penetrated the bridging material and edge bonded to the facesheet; -
FIG. 8 is a perspective illustration of a honeycomb-type core; -
FIG. 9 is a perspective illustration of a CMC structure having an open pattern of stiffeners in which areas of the bridging material has been removed; -
FIG. 10 is a block diagram illustrating one method of forming a CMC sandwich structure having a stiffened web; -
FIG. 11 is a block diagram illustrating another method for forming a CMC sandwich structure having a stiffened web; -
FIG. 12 is a block diagram illustrating one method for forming a rib-stiffened CMC shell structure; -
FIG. 13 is a block diagram illustrating another method for forming a rib-stiffened CMC shell structure; -
FIG. 14 is a flow diagram of an aircraft production and service methodology; and -
FIG. 15 is a block diagram of an aircraft. - As will be discussed below in more detail, advantageous embodiments of the disclosure provide reinforcement of edge bonded joints in a variety of CMC structures. Edge bonding is widely employed in composite structures, such as honeycomb core sandwich panels or grid stiffened shells. These CMC structures typically comprise the following basic structural elements: (1) a shell element which may comprise the facesheet of a sandwich structure, the outer skin of a vehicle, the web of a stiffened panel, etc., (2) stiffeners, for example the core of a sandwich structure, ribs supporting the skin of a vehicle, or flanges stabilizing the web of a stiffened panel, and (3) bridging elements, which reinforce edge bonded joints between (1) and (2) above, and provide an alternate load paths between shell and stiffener outside the edge bond faying surface between the two.
- Referring first to
FIGS. 2 and 3 , aCMC structure 30 broadly comprises a pair of spaced apart facesheets 22, 24 between which there is sandwiched acore 25. Each of thefacesheets - In the example illustrated in
FIGS. 2 and 3 , thecore 25 includes a plurality of spacedwebs 26, which have their opposite edges “edge bonded” at 27 to thefacesheets webs 26 extend substantially orthogonal to thefacesheets facesheets webs 26 forming the core 25 are shown as parallel, straight walls; however the core 25 comprise other configurations. For example, as shown inFIG. 8 , thecore 25 may comprise ahoneycomb structure 26 b, which also acts as a spacer during the manufacturing process to hold the bridgingmembers 32 against thefacesheets - As mentioned above, the
webs 26 may transfer compressive, tensile and/or shear loads between thefacesheets FIG. 3 , shear loads onfacesheet 22 indicated by thearrows 34 are transmitted through theweb 26 to facesheet 24, as indicated by thearrows 36. In accordance with one advantageous embodiment of the disclosure, the edge bondedjoints 27 are laterally reinforced by bridgingmembers 32 that are bonded to thefacesheets web 26. The bridgingmembers 32 are placed in the corners between theweb 26 and thefacesheets FIG. 3 ) between thewebs 26 and thefacesheets joints 27. - The thickness of the bridging
members 32 will depend on the requirements of the particular application, and the strength of the material forming the bridgingmembers 32. Generally, the bridgingmembers 32 should have a thickness sufficient to reinforce theweb 26 enough to transmit the desired level of shear force to facesheets 22, 24. In the advantageous embodiment shown inFIGS. 2 and 3 , the bridgingmembers 32 are rectangular in shape, however other shapes are possible, and the particular geometry will depend upon the shape of thewebs 26 and other core materials. The bridgingmembers 32 extend between opposing ones of thewebs 26 so that a single bridging element reinforces the edge bondedjoints 27 on twoadjacent webs 26. - The bridging
members 32 may be made of a low density, high temperature material which may be high temperature foam, such as ceramic foams or fused filamentary materials such as the rigid foam insulation disclosed in U.S. Pat. No. 6,716,782 issued Apr. 6, 2004 and assigned to the Boeing Company. The rigid foam insulation described in this prior patent is a combination of ceramic fibers which are sintered together to form a low density, highly porous material with low thermal conductivity. This foam exhibits high tensile strength and good dimensional stability. The material forming the bridgingmembers 32 should have an acceptable ratio of strength-to-density and should be suitable for being sheared by theweb 26 so that hand fitting is not required. As used herein, “high temperature” material is generally intended to refer to temperatures above which polymeric materials may exhibit diminished capacity. The bridgingmembers 26 may be made from materials other than a foam. For example, the bridgingmembers 26 may be formed from a low density felt of sintered ceramic fibers. - As will be discussed in more detail below, in one advantageous embodiment, the bridging material may be seated in position by cutting through it with the
shear carrying web 26 during the assembly process. Thus, the density of the bridgingmembers 32 generally should be less than the density ofweb 26 and/or thefacesheets members 32 providing useful results may be formed from material having a density approaching that of theweb 26, depending on the application and the loads to be carried by theweb 26. Generally, the bridging material must be strong enough to carry the loads for the intended application, but sufficiently friable that the core 25 can be forced through it to form the joint geometry. -
FIG. 4 illustrates analternate CMC construction 30 a in which afiller material 38 is used to facilitate the fabrication process. During fabrication, after thelayer 32 a of bridging material is deposited, a layer offiller material 38 is then formed over thefoam layer 32 a, following which theweb 26 a or other grid core is forced through both the filler layer 38 a and thefoam layer 32 a. Asecond layer 32 a of bridging material is then deposited over thefiller material 38, following which thesecond facesheet 22 is applied. Thefiller material 38 may comprise high temperature, rigid foam which may have a density less than that of the bridgingmembers 32. Depending on the strength-to-weight ratio requirements of the particular application, thefoam filler material 38 may serve the purpose of bridgingmembers 32, thus eliminating the need for theindividual layers 32 a of bridging material. - The
filler material 38 acts as a spacer between the bridging members on the opposite facesheets 12, 14. The filler material may comprise low density or fugitive materials that are placed in the volume between bridgingmembers 32. In some applications a relatively high thermal conductivity material may be chosen. Since thefiller material 38 need not be bonded to surrounding materials, it need not be a ceramic or a material with a coefficient of thermal expansion close to that of the structural elements. It is also possible that thelow density spacer 38 being used to facilitate the manufacturing process may be a fugitive material. Many materials sublimate at the high temperatures used for sintering ceramic matrix composites. These materials may be used as temporary tooling while building CMC structures. During the sintering phase of curing the CMC structure, the temporary element turns to gas and is vented out of the structure. -
FIG. 5 illustrates another advantageous embodiment of aCMC structure 30 b in which relatively thick, stiffeningribs 26 a form the core of thestructure 30 b. In this advantageous embodiment, the stiffening ribs are edge bonded to asingle facesheet 24, or shell, to form a stiffenedshell structure 30 b. Thefacesheet 24 may comprise for example, the outer skin of an aerospace vehicle. The spacing betweenadjacent ribs 26 a may be greater than the spacing of thewebs 26 in the advantageous embodiments shown inFIGS. 1-4 . In this advantageous embodiment, the bridgingmembers 32 may not span the entire distance betweenadjacent ribs 26 a, so that eachrib 26 a has an edge bonded joint reinforced by a pair of bridgingmembers 32. Generally, the width of the bridgingmembers 32 should be at least equal to or greater than their thickness in order to provide adequate reinforcement of theweb 26 a. Using bridgingmembers 32 having a reduced width may reduce the weight of thestructure 30 b, which may be desirable in applications such as aircraft. - Reference is now made to
FIGS. 6 and 7 which illustrate another advantageous embodiment in which thebridging members 32 are formed from a continuous layer of material such as high temperature rigid foam that is deposited and bonded to the inside face of each of thefacesheets foam layer 32 a should be such that it may be cut or penetrated by aweb 26 a during the fabrication process. Therigid foam layer 32 a having been bonded to thefacesheets web 26 a is then moved in the direction of thearrow 42 and is forced through thefoam layer 32 a until the correspondingfacesheet 22, 24 a is contacted to create an edge bonded joint. - With the
web 26 a edge bonded to afacesheet 24 at 27 as shown inFIG. 7 , portions of thefoam layer 32 a abut the sides of theweb 26 a and thereby laterally reinforce the edge bonded joint 27 against shear loads. The use of acontinuous layer 32 a of rigid foam allows a wide variety of web geometries and shapes to be employed, including regular or irregular honeycomb configurations and grids since, during fabrication, thelayer 32 a of foam will conform to all sides of theweb 26 a, regardless of the web geometry. - The material used as the bridging
members 32 should be bonded to both the adjacent facesheet and web. This may be done by wetting the joints with an appropriate slurry before curing the assembly. Other methods of forming the bridging members are possible. For example, a thin layer of bridging material may be bonded to a facesheet or a skin. Alternatively, a thick layer of bridging material maybe bonded to a facesheet or skin, following which the bridging material may be machined down to a final desired thickness. In another method, core material may be pressed into a sheet of bridging material to form a subassembly (held together only by friction), following which a facesheet or skin is bonded to the assembly. -
FIG. 9 illustrates a grid reinforcedshell 30 c in which a grid of stiffeningribs 26 c are edge bonded to afacesheet 24 or other shell element. Reinforcing bridgingmembers 32 c cover the bond lines between the stiffeningribs 26 c and thefacesheet 24. The bridgingmembers 32 c may be formed by bonding a formed or cut piece of bridging material to thefacesheet 24, and then removing portions of the material incentral areas 40, as by machining, for example, in order to reduce the weight of thestructure 30 c. The remaining width of the bridgingmembers 32 c should be sufficient to carry the load for the particular application of theCMC structure 30 c. -
FIG. 10 illustrates the basic steps of one method for fabricating a web stiffened CNC sandwich structure. First, atstep 44, the web is formed, following which thebridging members 32 are formed or cut to size, as shown atstep 46. Next, atstep 48, a first side of the web is forced through a first set of bridging material, following which, atstep 50, the second side of the web is forced through the second set of bridgingmembers 32. Then, atstep 52, thefacesheets step 44, the assembled CMC structure is cured. - An alternate method of fabricating a web stiffened CMC sandwich structure is shown in
FIG. 11 . First, atstep 56, the web and reinforcements around the foam filler are formed. Next, atstep 58, a first rigid foam layer and bridging material is applied to the first side of the first web and foam filler core (or forced through the web). Next, atstep 60, the first facesheet is bonded to the core with the attached bridging material. Atstep 62, the second rigid foam layer and bridging material is applied to the second side of the combination of the web and foam filler core, or forced through the web. As shown atstep 64, the second facesheet is then bonded to the opposite side of the core having the attached bridging material. Finally,step 66, the assembled CMC structure is cured. -
FIG. 12 illustrates the steps of one method for fabricating a rib stiffened shell type CMC structure. The stiffeners or web are formed atstep 68, following which the bridging members are formed or cut to size, as shown atstep 70. Then, the stiffeners are forced through the bridging members as shown atstep 72. Atstep 74, the shell element or facesheets are laid up, following which the assembled CMC structure is cured atstep 76. -
FIG. 13 illustrates the steps of another method for fabricating a rib stiffened, shell type CMC structure. Atstep 78, the shell element or facesheets are laid up. Then, the bridging members are formed or cut to size atstep 80. Atstep 82, the bridging members are bonded to the shell element (or facesheets). Next, atstep 84, the stiffeners or web are formed. Then, atstep 86, the stiffeners or web are forced through the bridging members and are edge bonded to the shell element. Finally, atstep 88, the assembled CMC structure is cured. - The advantageous embodiments of the disclosure described above may be used in an aircraft manufacturing and
service method 90 as shown inFIG. 14 and anaircraft 106 as shown inFIG. 15 . During pre-production,exemplary method 90 may include specification anddesign 92 of theaircraft 106 andmaterial procurement 94. During production, component andsubassembly manufacturing 96 andsystem integration 98 of theaircraft 106 takes place. Thereafter, theaircraft 106 may go through certification anddelivery 100 in order to be placed inservice 102. While in service by a customer, theaircraft 106 is scheduled for routine maintenance and service 102 (which may include modification, reconfiguration, refurbishment, and so on). - Each of the processes of
method 90 may be performed or carried out by a system integrator, a third party, and/or an operator (e.g., a customer). For the purposes of this description, a system integrator may include without limitation any number of aircraft manufacturers and major-system subcontractors; a third party may include without limitation any number of venders, subcontractors, and suppliers; and an operator may be an airline, leasing company, military entity, service organization, and so on. - As shown in
FIG. 14 , theaircraft 106 produced byexemplary method 90 may include anairframe 108 with a plurality ofsystems 96 and an interior 112. Examples of high-level systems 110 include one or more of apropulsion system 114, anelectrical system 116, ahydraulic system 118 and anenvironmental system 120. Any number of other systems may be included. Although an aerospace example is shown, the principles of the invention may be applied to other industries, such as the automotive industry. - Structures and methods embodied herein may be employed during any one or more of the stages of the production and
service method 90. For example, components or subassemblies corresponding toproduction process 90 may be fabricated or manufactured in a manner similar to components or subassemblies produced while theaircraft 106 is in service. Also, one or more advantageous apparatus embodiments, method embodiments, or a combination thereof may be utilized during the production stages 96 and 98, for example, by substantially expediting assembly of or reducing the cost of anaircraft 106. Similarly, one or more of advantageous apparatus embodiments, method embodiments, or a combination thereof may be utilized while theaircraft 106 is in service, for example and without limitation, to maintenance andservice 104. - Although the advantageous embodiments of this disclosure have been described with respect to certain exemplary advantageous embodiments, it is to be understood that the specific advantageous embodiments are for purposes of illustration and not limitation, as other variations will occur to those of skill in the art.
Claims (18)
1. A method of forming a ceramic matrix composite structure, comprising the steps of:
(A) forming first and second layers of bridging material;
(B) forcing a first edge of a web through the first layer of bridging material;
(C) forcing a second opposite edge of the web through the second layer of bridging material;
(D) applying first and second facesheets to opposite sides of the web; and
(E) bonding the first and second edges respectively to the first and second facesheets.
2. The method of claim 1 , further comprising the step of:
(F) bonding the first and second layers of bridging material respectively to the first and second facesheets.
3. The method of claim 1 , wherein step (E) includes bonding the first and second layers of bridging material to the first and second facesheets substantially concurrently.
4. The method of claim 1 , further comprising the step of:
(F) curing the ceramic matrix composite structure after step (E) has been completed.
5. The method of claim 1 , further comprising the step of:
(F) manufacturing aircraft subassemblies using the ceramic composite matrix composite structure.
6. A method of forming a ceramic matrix composite structure, comprising the steps of:
(A) forming first and second layers of bridging material;
(B) forcing a first edge of a web through the first layer of bridging material;
(C) forcing a second opposite edge of the web through the second layer of bridging material;
(D) applying first and second facesheets to opposite sides of the web; and
(E) bonding the first and second edges respectively to the first and second facesheets.
7. The method of claim 6 , wherein steps (A) and (B) each include depositing rigid foam on the corresponding facesheet.
8. The method of claim 6 , further comprising the step of:
(F) curing the structure after steps (A) through (E) have been performed.
9. The method of claim 6 , further comprising the step of:
(F) filling space between the first and second layers of reinforcement material with a rigid foam.
10. A method of forming a ceramic composite sandwich structure, comprising the steps of:
(A) placing reinforcing core in a layer of foam;
(B) forming a first layer of bridging material on a first side of the foam layer bridging the sides of the core;
(C) bonding a first facesheet to the first side of the foam layer;
(D) forming a second layer of bridging material on a second side of the foam layer bridging the sides of the core;
(E) bonding a second facesheet to a second side of the foam layer.
11. The method of claim 10 , further comprising the step of:
(F) curing the ceramic composite sandwich structure.
12. The method of claim 10 , wherein steps (B) and (D) each include forcing the core through a layer of the bridging material.
13. The method of claim 10 , further comprising the step of:
(F) performing aircraft maintenance using the ceramic composite sandwich structure.
14. A method of forming a ceramic composite sandwich structure, comprising the steps of:
(A) forming structural stiffeners;
(B) forming bridging members for laterally reinforcing the stiffeners;
(C) forcing the stiffeners through the bridging members;
(D) laying up a facesheet; and,
(E) bonding the facesheet to the combination of the stiffeners and the bridging members.
15. The method of claim 14 , further comprising the step of:
(F) removing a portion of the bridging members after step (E) has been performed
16. The method of claim 14 , further comprising the step of:
(F) specifying materials used in the ceramic composite sandwich structure.
17. The method of claim 14 , further comprising the step of:
(F) curing the ceramic composite sandwich structure.
18. The method of claim 14 , further comprising the step of:
(F) manufacturing aircraft subassemblies using the ceramic composite sandwich structure.
Priority Applications (1)
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US12/961,166 US20110073255A1 (en) | 2007-06-28 | 2010-12-06 | Composite structures having reinforced edge bonded joints and method for making the same |
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US11/770,157 US8097106B2 (en) | 2007-06-28 | 2007-06-28 | Method for fabricating composite structures having reinforced edge bonded joints |
US12/961,166 US20110073255A1 (en) | 2007-06-28 | 2010-12-06 | Composite structures having reinforced edge bonded joints and method for making the same |
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US12/961,166 Abandoned US20110073255A1 (en) | 2007-06-28 | 2010-12-06 | Composite structures having reinforced edge bonded joints and method for making the same |
US13/174,428 Abandoned US20110252742A1 (en) | 2007-06-28 | 2011-06-30 | Composite Structures Having Reinforced Edge Bonded Joints and Method for Making the Same |
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US8097106B2 (en) | 2012-01-17 |
US20110252742A1 (en) | 2011-10-20 |
US20090005232A1 (en) | 2009-01-01 |
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