US20080063323A1 - Moisture-Repellent Receptacle and Method for the Production Thereof - Google Patents
Moisture-Repellent Receptacle and Method for the Production Thereof Download PDFInfo
- Publication number
- US20080063323A1 US20080063323A1 US10/566,020 US56602004A US2008063323A1 US 20080063323 A1 US20080063323 A1 US 20080063323A1 US 56602004 A US56602004 A US 56602004A US 2008063323 A1 US2008063323 A1 US 2008063323A1
- Authority
- US
- United States
- Prior art keywords
- sheet
- receptacle
- plastic layer
- layer
- hot melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000005871 repellent Substances 0.000 title abstract description 13
- 239000004568 cement Substances 0.000 claims abstract description 50
- 239000013590 bulk material Substances 0.000 claims abstract description 19
- 238000004806 packaging method and process Methods 0.000 claims abstract description 11
- 239000004831 Hot glue Substances 0.000 claims description 36
- 239000011248 coating agent Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 7
- 238000005520 cutting process Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 3
- 239000004753 textile Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 7
- 238000005507 spraying Methods 0.000 claims 2
- 238000007789 sealing Methods 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 62
- 239000012530 fluid Substances 0.000 description 12
- 239000003570 air Substances 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 239000012790 adhesive layer Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 230000035699 permeability Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D33/00—Details of, or accessories for, sacks or bags
- B65D33/01—Ventilation or drainage of bags
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/12—Applying particulate materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
- B05D1/265—Extrusion coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/10—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an adhesive surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/12—Paper, e.g. cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
Definitions
- the invention concerns a container, in particular a bag, for packaging bulk material such as cement.
- the invention further concerns a device for producing containers, in particular bags, for packaging bulk material such as cement, comprising a cutting tool for cutting a carrier web into portions and a shaping tool for shaping a container from a respective one of the portions.
- the invention also concerns a method of manufacturing containers, in particular bags, for packaging bulk material such as cement, in which a carrier web is cut into portions and each portion is formed into a respective at least one container wall substantially forming a container.
- the invention further concerns a method of filling containers, in particular bags, with bulk material, in which the bulk material, in particular cement, is introduced into the open container by means of a filling connection and the container is sealed off with respect to the filling connection.
- cement and other bulk material is conventionally sold and transported in paper bags.
- the cement is packaged in the paper bag as in a pack.
- the paper bag is obtained from a portion of paper web.
- the paper wall of the paper bag is slightly air-permeable and also moisture-permeable.
- a disadvantage with the known cement bags that, during the filling operation, the air which accumulates in the bottom region of the cement bags cannot escape sufficiently quickly and completely from the cement bag so that unwanted air spaces occur in the cement bag.
- moisture can penetrate into the cement bag through the paper from the exterior.
- cement bags are used in the open air, particularly when building houses, they are there frequently exposed without protection to the weather. It is therefore necessary for the cement bags to be stored in protection spaces which are constructed especially for them, under shelters or in closed containers on the building site.
- the object of the present invention is to provide an inexpensive container suitable for the packaging of bulk material such as cement.
- Another object of the present invention is to provide a device for the inexpensive manufacture of containers suitable for the packaging of bulk material such as cement.
- a further object of the present invention is to provide an inexpensive method of manufacturing containers which are suitable for the packaging of bulk material such as cement.
- yet another object of the invention is to provide a method of densely filling containers, in particular bags, with bulk material such as cement.
- a container as set forth in the opening part of this specification, comprising at least one gas-permeable and moisture-repellent container wall which substantially forms the container and which has a carrier layer and a plastic layer having openings.
- the at least double-layer configuration of the container wall comprising a carrier layer and a plastic layer having openings.
- the moisture-repellent property of the container wall which is repellent in particular for moisture which acts on the container from the exterior protects the bulk material packaged in the container from being soaked through.
- the plastic layer has openings.
- the openings in the plastic layer are so small that gas can admittedly flow through the plastic layer, preferably from the inside outwardly, but no moisture penetrates therethrough from the outside inwardly. Moisture is present in drop form in the ambient air.
- the drop size is also determined by the cohesion forces of the liquid forming them. So that moisture drops cannot penetrate.through the openings in the plastic layer, the openings should not exceed a given maximum size. The maximum size of the openings should therefore be below the drop size.
- the plastic layer can be arranged on the carrier layer on the outside and on the inside. If the carrier layer is disposed on the plastic layer on the inside, the plastic layer also protects the carrier layer from moisture penetration therethrough from the outside.
- the carrier layer is disposed on the plastic layer on the outside, that is to say it does not have direct contact with the bulk material, moisture can admittedly pass through the carrier layer from the outside but the bulk material nonetheless remains protected by the plastic layer, and dry.
- the carrier layer can therefore be arranged on the plastic layer on the inside or on the outside and it also does not necessarily need to be moisture-repellent itself so that the container wall is overall moisture-repellent.
- the gas permeability of the container wall permits gas enclosed in the container to escape through the container wall and thus permits denser packing of the bulk material in the container.
- the carrier layer is gas-permeable. That makes it possible for gas and in particular air to escape from the container and through the carrier layer.
- the carrier layer can be for example a paper layer or a textile fabric layer.
- the paper layer should as thin as possible so that it is gas-permeable. It is also conceivable for the paper layer to be perforated.
- the gas can also escape through the openings in the plastic layer which is preferably arranged on the carrier layer on the outside but can also be arranged on the carrier layer on the inside.
- the container wall is thus overall gas-permeable. Unwanted gas in the container can escape to the exterior.
- the double-layer configuration of the container wall in spite of its air-permeability, affords a high level of tearing strength.
- the thin nature or the perforation of the carrier layer admittedly reduces the tearing strength thereof, but it is required for the gas-permeability thereof.
- Those conflicting demands on the thickness of the carrier layer are satisfied here by the application of a plastic layer which is not closed but which nonetheless increases the level of tearing strength.
- a plurality of carrier layers to be arranged in mutually superposed relationship to form the container, with plastic layers arranged between them. That provides a particularly tear-resistant container wall.
- the adhesive layer is a hot melt adhesive layer.
- the hot melt adhesive layer can be applied to carrier layers, in particular paper layers, for example in production equipment in the form which is required for the invention and which has openings.
- the hot melt adhesive layer having openings can be porous, it is even possible for the hot melt adhesive to be applied to the carrier layer in the form of a mesh or in stripes which are arranged in closely mutually spaced juxtaposed and preferably parallel relationship.
- Hot melt adhesive is relatively inexpensive and is commercially available in different kinds.
- the hot melt adhesive makes it possible to inexpensively provide containers which are adapted to differing requirements, for example in respect of tearing strength and weight.
- the object of the invention is also attained by a device as set forth in the opening part of this specification, which has at least one coating tool for the application of adhesive to a carrier web, and which has at least one transporting tool for transporting the carrier web past the at least one coating tool.
- the device according to the invention serves in particular for manufacture of the above-mentioned containers, in particular bags.
- the device has at least one coating tool which is intended to apply a non-closed plastic layer to the carrier web.
- the at least one transporting tool serves for transporting the carrier web past the coating tool.
- the device according to the invention is inexpensive and quick to construct because it is only the additional fitment of the at least one transport means and the at least one coating tool that is necessary. Both components are basically known for example from EP 0 568 812 A1.
- the coating tool has a fluid applicator with a slot nozzle arranged at the carrier web side.
- the slot nozzle is subdivided into slot nozzle portions which can be supplied with liquid hot melt adhesive by individual pumps or groups of pumps associated with slot nozzle portions.
- the pumps are controllable by means of a control device.
- the coating tool permits an application of a stripe-shaped plastic layer to the carrier layer. In that situation the carrier layer is continuously moved past the fluid applicator and a hot melt adhesive stripe can be applied from each slot nozzle portion in the width of the portion, to the carrier web. If the hot melt adhesive flow to each slot nozzle portion is great, a great deal of adhesive is applied to the carrier web in relation to surface area and the layer of adhesive becomes thicker.
- the device can be operated to produce coated carrier webs for the containers at high speed.
- the coating tool has at least one dispersing tool for dispersing adhesive powder on to the carrier web and, in the transport direction of the carrier web, downstream of the at least one dispersing tool, at least one heating element for subsequently heating and for melting the plastic powder and for producing an adhesive layer having openings.
- the application in powder form makes it possible to produce a porous adhesive layer on the carrier material.
- the carrier web can desirably be pre-heated in order thereby to promote good adhesion of the adhesive powder thereto. That device permits the manufacture of particularly reliably moisture-repellent plastic layers.
- the coated carrier web can be cut by means of the cutting tool into portions which can be respectively shaped by means of the shaping tool to afford a container, in particular a bag.
- the cement bag wall can be of a multi-layer nature to produce particularly strong cement bags. Strong cement bags can be necessary when a large amount of cement is to be accommodated therein.
- laminating rollers for applying a further carrier web to the adhesive side of the coated carrier web.
- the second carrier web can be pre-heated prior to being brought together with the coated carrier web.
- the object of the invention is further attained by a method as set forth in the opening part of this specification, insofar as a carrier web is coated with an adhesive layer having openings in order to produce an air-permeable and moisture-repellent container wall.
- the method according to the invention can be carried into effect in particular by the above-described device.
- the adhesive layer having openings is applied to the carrier web in particular by means of the slot nozzle of a fluid applicator.
- Preferably inexpensive hot melt adhesive is applied to the carrier web.
- the object of the invention is further attained by a method as set forth in the opening part of this specification, insofar as air enclosed in the container escapes during the filling operation through the at least one gas-permeable and moisture-repellent container wall.
- the bulk material which is introduced into the container by means of a filling connection generally includes air. That included air can already escape through the walls of the container during the operation of filling it.
- the method according to the invention therefore permits dense packaging of the bulk material in the container.
- FIG. 1 shows a cement bag according to the invention
- FIG. 2 shows a view in cross-section through the cement bag of FIG. 1 along line II-II,
- FIG. 3 shows a diagrammatic view of a device according to the invention for the manufacture of cement bags as shown in FIG. 1 ,
- FIG. 4 shows a coating tool in a device as shown in FIG. 3 .
- FIG. 5 is a diagrammatic section through a slot nozzle taken along line V-V in FIG. 4 .
- the cement bag. 1 shown in FIG. 1 is a cement-filled cuboidal container having a gas-permeable and moisture-repellent cement bag wall 2 .
- the cement bag wall 2 encloses the cement pack-like and it is folded at its top side and its underside.
- FIG. 2 The cross-sectional view shown in FIG. 2 , taken along line II-II in FIG. 1 , shows the double-layer configuration of the cement bag wall 2 of the cement bag 1 .
- a carrier layer 3 arranged at the inside in the cement bag and comprising air-permeable paper is in contact with the cement in the bag.
- the carrier layer 3 however can also comprise air-permeable textile fabric.
- a porous hot melt adhesive layer 4 is applied to the paper layer 3 on the outside.
- That hot melt adhesive layer 4 has openings 5 and it is of a very low weight of about 8 g/m 2 : the openings 5 are of such dimensions that moisture cannot penetrate therethrough into the paper layer 3 , but it nonetheless remains air-permeable.
- the cement bag wall 2 provided in that way is moisture-repellent and air-permeable.
- FIG. 3 of a device for cement bags shows a first roll 6 with an unrollable, air-permeable paper web 7 .
- the paper web 7 is transported past a fluid applicator 9 by way of direction-changing rollers or drive rollers 8 .
- the fluid applicator 9 is arranged stationarily and is connected by way of a hose to a gear pump 10 .
- the gear pump 10 supplies the fluid applicator 9 with liquid hot melt adhesive from a storage container 11 .
- the amount of fluid applied to the paper web 7 per unit of surface area can be controlled by setting a reduced or increased rotary speed for the gear pump 10 .
- a further control option is afforded by setting the transport speed of the paper web 7 .
- the device shown in FIG. 3 permits an application of the hot melt adhesive to the paper web 7 , the application of adhesive having openings.
- the paper web 7 is pre-heated with a first heating element 12 .
- the liquid hot melt adhesive is applied to the pre-heated paper web 7 by the fluid applicator 9 .
- the amount applied per surface area is so selected that a hot melt adhesive layer 13 having openings is produced on the paper web 7 .
- the pre-heating effect promotes for example evaporation of the solvents of the liquid hot melt adhesive and slower setting.
- the hot melt adhesive can thus penetrate into the paper web 7 for longer and produce a firm join thereto.
- the coated paper web is then post-heated by a second heating element 14 in order to cause the hot melt adhesive to produce an even firmer join to the paper web 7 .
- the coated paper web is then fed by way of deflection rollers 8 to a cutting tool 15 which cuts the coated paper web into portions 16 of equal size.
- the portions 16 are shaped to provide cement bag walls 2 and filled with cement.
- the cement is introduced into the cement bag 1 by way of a filling connection (not shown).
- the cement bag is then closed.
- the air which is enclosed in the cement bag in the filling operation escapes through the air-permeable cement bag walls 2 .
- FIG. 4 shows a diagrammatic view of a fluid applicator 9 suitable for application of the hot melt adhesive.
- Application of the hot melt adhesive is effected by way of a slot nozzle 17 which is arranged on the fluid applicator 9 at the paper web side.
- FIG. 4 shows the fluid applicator with a heating element arranged upstream thereof in the transport direction.
- the paper web 7 is transported past the first heating element 12 and heated there.
- a further deflection roller 8 a Arranged downstream of the first heating element 12 in the transport direction is a further deflection roller 8 a which is also a drive roller.
- the paper web 7 is transported through a narrow gap between the further deflection roller 8 a and the fluid applicator 9 .
- the slot nozzle 17 permits the hot melt adhesive to be applied to the paper web 7 .
- the hot melt adhesive layer 13 is air-permeable. The openings thereof however are so small and are so far spaced from each other that moisture impinging on the layer from the outside cannot penetrate therethrough into the paper web 7 .
- the paper web 7 coated with the hot melt adhesive layer 13 is further transported by way of deflection rollers 8 and is further processed as already described with reference to FIG. 3 to provide cement bags.
- FIG. 5 shows a diagrammatic section taken along line V-V in FIG. 4 .
- the slot nozzle 17 is arranged above the paper web 7 .
- the slot nozzle 17 tapers perpendicularly to the plane of the drawing towards the edge at the paper web side.
- the slot nozzle 17 has slot nozzle portions 18 a , 18 b of differing lengths which are separated from each other by intermediate walls 19 , along the longitudinal direction of the slot nozzle.
- the slot nozzle portions 18 a, 18 b are only connected together along their outermost edge towards the paper web.
- Each of the slot nozzle portions 18 a, 18 b can be supplied with liquid hot melt adhesive by way of a respective C-shaped passage 20 at its outer ends in the longitudinal direction of the slot nozzle.
- Some adjacent C-shaped passages 20 can be supplied together through common passages 21 .
- Each of the common passages 21 has a gear pump 10 which is controllable centrally by way of a control device 22 .
- the control device 22 makes it possible for the individual slot nozzle portions 18 a , 18 b to be controllably supplied with hot melt adhesive by the associated gear pump 10 .
- the flow of the hot melt adhesive is metered in such a way that the hot melt adhesive layer applied to the paper web 7 is not closed, that is to say it has openings.
- the described slot nozzle 17 permits application of the hot melt adhesive to the paper web 7 , in stripe form.
- each of the slot nozzle portions 18 a , 18 b is a stripe to be applied, of the width of the associated portion 18 a , 18 b .
- the paper web 7 moves along below the slot nozzle 17 in perpendicular relationship to the plane of the drawing.
- the stripes are consequently formed along the paper web 7 also in perpendicular relationship to the plane of the drawing.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Bag Frames (AREA)
- Packages (AREA)
- Laminated Bodies (AREA)
Abstract
The invention concerns a container, in particular a bag, for packaging bulk material such as cement, comprising at least one gas-permeable and moisture-repellent container wall 1 which essentially forms the container and which has a carrier layer 2 and a plastic layer 3 which is not closed.
Description
- The invention concerns a container, in particular a bag, for packaging bulk material such as cement.
- The invention further concerns a device for producing containers, in particular bags, for packaging bulk material such as cement, comprising a cutting tool for cutting a carrier web into portions and a shaping tool for shaping a container from a respective one of the portions.
- The invention also concerns a method of manufacturing containers, in particular bags, for packaging bulk material such as cement, in which a carrier web is cut into portions and each portion is formed into a respective at least one container wall substantially forming a container.
- The invention further concerns a method of filling containers, in particular bags, with bulk material, in which the bulk material, in particular cement, is introduced into the open container by means of a filling connection and the container is sealed off with respect to the filling connection.
- Cement and other bulk material is conventionally sold and transported in paper bags. In that case the cement is packaged in the paper bag as in a pack. The paper bag is obtained from a portion of paper web. The paper wall of the paper bag is slightly air-permeable and also moisture-permeable. A disadvantage with the known cement bags that, during the filling operation, the air which accumulates in the bottom region of the cement bags cannot escape sufficiently quickly and completely from the cement bag so that unwanted air spaces occur in the cement bag. In addition, particularly during storage of the cement bag, moisture can penetrate into the cement bag through the paper from the exterior. As cement bags are used in the open air, particularly when building houses, they are there frequently exposed without protection to the weather. It is therefore necessary for the cement bags to be stored in protection spaces which are constructed especially for them, under shelters or in closed containers on the building site.
- In devices for the production of cement bags from paper which can be part of complex manufacturing equipment, the paper web is cut into portions, from each of which a respective paper bag is folded. The cement is introduced into the folded paper bags while still open. In that case, air is enclosed between the paper bag and the cement, and that air cannot escape sufficiently quickly to permit dense filling. The only loose cement bag filling is a disadvantage as it occupies an unnecessarily large volume.
- The object of the present invention is to provide an inexpensive container suitable for the packaging of bulk material such as cement.
- In accordance with a second aspect another object of the present invention is to provide a device for the inexpensive manufacture of containers suitable for the packaging of bulk material such as cement.
- In accordance with a third aspect a further object of the present invention is to provide an inexpensive method of manufacturing containers which are suitable for the packaging of bulk material such as cement.
- In accordance with a fourth aspect yet another object of the invention is to provide a method of densely filling containers, in particular bags, with bulk material such as cement.
- In its first aspect that object is attained by a container as set forth in the opening part of this specification, comprising at least one gas-permeable and moisture-repellent container wall which substantially forms the container and which has a carrier layer and a plastic layer having openings.
- Both properties of the container wall, gas permeability and the moisture-repellent property, are provided in accordance with the invention by the at least double-layer configuration of the container wall comprising a carrier layer and a plastic layer having openings.
- The moisture-repellent property of the container wall which is repellent in particular for moisture which acts on the container from the exterior protects the bulk material packaged in the container from being soaked through.
- The plastic layer has openings. The openings in the plastic layer however are so small that gas can admittedly flow through the plastic layer, preferably from the inside outwardly, but no moisture penetrates therethrough from the outside inwardly. Moisture is present in drop form in the ambient air. The drop size is also determined by the cohesion forces of the liquid forming them. So that moisture drops cannot penetrate.through the openings in the plastic layer, the openings should not exceed a given maximum size. The maximum size of the openings should therefore be below the drop size. The plastic layer can be arranged on the carrier layer on the outside and on the inside. If the carrier layer is disposed on the plastic layer on the inside, the plastic layer also protects the carrier layer from moisture penetration therethrough from the outside. If the carrier layer is disposed on the plastic layer on the outside, that is to say it does not have direct contact with the bulk material, moisture can admittedly pass through the carrier layer from the outside but the bulk material nonetheless remains protected by the plastic layer, and dry. The carrier layer can therefore be arranged on the plastic layer on the inside or on the outside and it also does not necessarily need to be moisture-repellent itself so that the container wall is overall moisture-repellent.
- The gas permeability of the container wall permits gas enclosed in the container to escape through the container wall and thus permits denser packing of the bulk material in the container.
- The carrier layer is gas-permeable. That makes it possible for gas and in particular air to escape from the container and through the carrier layer. The carrier layer can be for example a paper layer or a textile fabric layer. In particular the paper layer should as thin as possible so that it is gas-permeable. It is also conceivable for the paper layer to be perforated. The gas can also escape through the openings in the plastic layer which is preferably arranged on the carrier layer on the outside but can also be arranged on the carrier layer on the inside. The container wall is thus overall gas-permeable. Unwanted gas in the container can escape to the exterior.
- The double-layer configuration of the container wall, in spite of its air-permeability, affords a high level of tearing strength. The thin nature or the perforation of the carrier layer admittedly reduces the tearing strength thereof, but it is required for the gas-permeability thereof. Those conflicting demands on the thickness of the carrier layer are satisfied here by the application of a plastic layer which is not closed but which nonetheless increases the level of tearing strength.
- Basically it is also possible for a plurality of carrier layers to be arranged in mutually superposed relationship to form the container, with plastic layers arranged between them. That provides a particularly tear-resistant container wall.
- In a particularly preferred embodiment of the invention the adhesive layer is a hot melt adhesive layer. The hot melt adhesive layer can be applied to carrier layers, in particular paper layers, for example in production equipment in the form which is required for the invention and which has openings. The hot melt adhesive layer having openings can be porous, it is even possible for the hot melt adhesive to be applied to the carrier layer in the form of a mesh or in stripes which are arranged in closely mutually spaced juxtaposed and preferably parallel relationship. Hot melt adhesive is relatively inexpensive and is commercially available in different kinds. The hot melt adhesive makes it possible to inexpensively provide containers which are adapted to differing requirements, for example in respect of tearing strength and weight.
- In its second aspect the object of the invention is also attained by a device as set forth in the opening part of this specification, which has at least one coating tool for the application of adhesive to a carrier web, and which has at least one transporting tool for transporting the carrier web past the at least one coating tool.
- The device according to the invention serves in particular for manufacture of the above-mentioned containers, in particular bags. The device has at least one coating tool which is intended to apply a non-closed plastic layer to the carrier web. The at least one transporting tool serves for transporting the carrier web past the coating tool. In addition, there can be provided a plurality of deflection rollers and transporting rollers which correctly position the carrier web, in particular in the region of the coating tool. The device according to the invention is inexpensive and quick to construct because it is only the additional fitment of the at least one transport means and the at least one coating tool that is necessary. Both components are basically known for example from EP 0 568 812 A1.
- In a preferred embodiment of the device the coating tool has a fluid applicator with a slot nozzle arranged at the carrier web side. Preferably the slot nozzle is subdivided into slot nozzle portions which can be supplied with liquid hot melt adhesive by individual pumps or groups of pumps associated with slot nozzle portions. The pumps are controllable by means of a control device. The coating tool permits an application of a stripe-shaped plastic layer to the carrier layer. In that situation the carrier layer is continuously moved past the fluid applicator and a hot melt adhesive stripe can be applied from each slot nozzle portion in the width of the portion, to the carrier web. If the hot melt adhesive flow to each slot nozzle portion is great, a great deal of adhesive is applied to the carrier web in relation to surface area and the layer of adhesive becomes thicker. The device can be operated to produce coated carrier webs for the containers at high speed.
- In a further advantageous configuration of the device the coating tool has at least one dispersing tool for dispersing adhesive powder on to the carrier web and, in the transport direction of the carrier web, downstream of the at least one dispersing tool, at least one heating element for subsequently heating and for melting the plastic powder and for producing an adhesive layer having openings. With the correct metering effect, the application in powder form makes it possible to produce a porous adhesive layer on the carrier material. The carrier web can desirably be pre-heated in order thereby to promote good adhesion of the adhesive powder thereto. That device permits the manufacture of particularly reliably moisture-repellent plastic layers.
- The coated carrier web can be cut by means of the cutting tool into portions which can be respectively shaped by means of the shaping tool to afford a container, in particular a bag.
- The cement bag wall can be of a multi-layer nature to produce particularly strong cement bags. Strong cement bags can be necessary when a large amount of cement is to be accommodated therein. In a further embodiment of the device therefore arranged in the transport direction downstream of the at least one coating tool are laminating rollers for applying a further carrier web to the adhesive side of the coated carrier web. The second carrier web can be pre-heated prior to being brought together with the coated carrier web. In addition, for fixedly adhering the two carrier webs, it may be conducive for the carrier webs which have been brought together to be post-heated.
- In its third aspect the object of the invention is further attained by a method as set forth in the opening part of this specification, insofar as a carrier web is coated with an adhesive layer having openings in order to produce an air-permeable and moisture-repellent container wall. The method according to the invention can be carried into effect in particular by the above-described device. In that case, the adhesive layer having openings is applied to the carrier web in particular by means of the slot nozzle of a fluid applicator. Preferably inexpensive hot melt adhesive is applied to the carrier web.
- In its fourth aspect the object of the invention is further attained by a method as set forth in the opening part of this specification, insofar as air enclosed in the container escapes during the filling operation through the at least one gas-permeable and moisture-repellent container wall. The bulk material which is introduced into the container by means of a filling connection generally includes air. That included air can already escape through the walls of the container during the operation of filling it. The method according to the invention therefore permits dense packaging of the bulk material in the container.
- The invention is described by means of preferred embodiments by way of example. In the drawing:
-
FIG. 1 shows a cement bag according to the invention, -
FIG. 2 shows a view in cross-section through the cement bag ofFIG. 1 along line II-II, -
FIG. 3 shows a diagrammatic view of a device according to the invention for the manufacture of cement bags as shown inFIG. 1 , -
FIG. 4 shows a coating tool in a device as shown inFIG. 3 , and -
FIG. 5 is a diagrammatic section through a slot nozzle taken along line V-V inFIG. 4 . - The cement bag. 1 shown in
FIG. 1 is a cement-filled cuboidal container having a gas-permeable and moisture-repellentcement bag wall 2. Thecement bag wall 2 encloses the cement pack-like and it is folded at its top side and its underside. - The cross-sectional view shown in
FIG. 2 , taken along line II-II inFIG. 1 , shows the double-layer configuration of thecement bag wall 2 of thecement bag 1. Acarrier layer 3 arranged at the inside in the cement bag and comprising air-permeable paper is in contact with the cement in the bag. Thecarrier layer 3 however can also comprise air-permeable textile fabric. A porous hot meltadhesive layer 4 is applied to thepaper layer 3 on the outside. - That hot melt
adhesive layer 4 hasopenings 5 and it is of a very low weight of about 8 g/m2: theopenings 5 are of such dimensions that moisture cannot penetrate therethrough into thepaper layer 3, but it nonetheless remains air-permeable. Thecement bag wall 2 provided in that way is moisture-repellent and air-permeable. - The diagrammatic view shown in
FIG. 3 of a device for cement bags shows a first roll 6 with an unrollable, air-permeable paper web 7. Thepaper web 7 is transported past afluid applicator 9 by way of direction-changing rollers or driverollers 8. Thefluid applicator 9 is arranged stationarily and is connected by way of a hose to agear pump 10. Thegear pump 10 supplies thefluid applicator 9 with liquid hot melt adhesive from astorage container 11. The amount of fluid applied to thepaper web 7 per unit of surface area can be controlled by setting a reduced or increased rotary speed for thegear pump 10. A further control option is afforded by setting the transport speed of thepaper web 7. - The device shown in
FIG. 3 permits an application of the hot melt adhesive to thepaper web 7, the application of adhesive having openings. Thepaper web 7 is pre-heated with afirst heating element 12. The liquid hot melt adhesive is applied to thepre-heated paper web 7 by thefluid applicator 9. In that case the amount applied per surface area is so selected that a hot meltadhesive layer 13 having openings is produced on thepaper web 7. The pre-heating effect promotes for example evaporation of the solvents of the liquid hot melt adhesive and slower setting. The hot melt adhesive can thus penetrate into thepaper web 7 for longer and produce a firm join thereto. The coated paper web is then post-heated by asecond heating element 14 in order to cause the hot melt adhesive to produce an even firmer join to thepaper web 7. The coated paper web is then fed by way ofdeflection rollers 8 to acutting tool 15 which cuts the coated paper web intoportions 16 of equal size. Theportions 16 are shaped to providecement bag walls 2 and filled with cement. - The cement is introduced into the
cement bag 1 by way of a filling connection (not shown). The cement bag is then closed. The air which is enclosed in the cement bag in the filling operation escapes through the air-permeablecement bag walls 2. -
FIG. 4 shows a diagrammatic view of afluid applicator 9 suitable for application of the hot melt adhesive. Application of the hot melt adhesive is effected by way of aslot nozzle 17 which is arranged on thefluid applicator 9 at the paper web side.FIG. 4 shows the fluid applicator with a heating element arranged upstream thereof in the transport direction. Thepaper web 7 is transported past thefirst heating element 12 and heated there. Arranged downstream of thefirst heating element 12 in the transport direction is a further deflection roller 8a which is also a drive roller. Thepaper web 7 is transported through a narrow gap between the further deflection roller 8a and thefluid applicator 9. Theslot nozzle 17 permits the hot melt adhesive to be applied to thepaper web 7. The hot meltadhesive layer 13 is air-permeable. The openings thereof however are so small and are so far spaced from each other that moisture impinging on the layer from the outside cannot penetrate therethrough into thepaper web 7. Thepaper web 7 coated with the hot meltadhesive layer 13 is further transported by way ofdeflection rollers 8 and is further processed as already described with reference toFIG. 3 to provide cement bags. -
FIG. 5 shows a diagrammatic section taken along line V-V inFIG. 4 . Theslot nozzle 17 is arranged above thepaper web 7. Theslot nozzle 17 tapers perpendicularly to the plane of the drawing towards the edge at the paper web side. Theslot nozzle 17 hasslot nozzle portions 18 a, 18 b of differing lengths which are separated from each other byintermediate walls 19, along the longitudinal direction of the slot nozzle. Theslot nozzle portions 18a, 18b are only connected together along their outermost edge towards the paper web. Each of theslot nozzle portions 18a, 18b can be supplied with liquid hot melt adhesive by way of a respective C-shapedpassage 20 at its outer ends in the longitudinal direction of the slot nozzle. Some adjacent C-shapedpassages 20 can be supplied together throughcommon passages 21. Each of thecommon passages 21 has agear pump 10 which is controllable centrally by way of acontrol device 22. Thecontrol device 22 makes it possible for the individualslot nozzle portions 18 a, 18 b to be controllably supplied with hot melt adhesive by the associatedgear pump 10. The flow of the hot melt adhesive is metered in such a way that the hot melt adhesive layer applied to thepaper web 7 is not closed, that is to say it has openings. The describedslot nozzle 17 permits application of the hot melt adhesive to thepaper web 7, in stripe form. In that case, associated with each of theslot nozzle portions 18 a, 18 b is a stripe to be applied, of the width of the associatedportion 18 a, 18 b. InFIG. 5 thepaper web 7 moves along below theslot nozzle 17 in perpendicular relationship to the plane of the drawing. The stripes are consequently formed along thepaper web 7 also in perpendicular relationship to the plane of the drawing.
Claims (19)
1-15. (canceled)
16. A receptacle for packaging bulk material, comprising:
a body having an internal cavity defined by a folded sheet of material with a carrier layer and a plastic layer, said carrier layer being formed from a fibrous web that is permeable to gas and impermeable to water, said plastic layer having openings that are permeable to gas and impermeable to water.
17. The receptacle of claim 16 , wherein said carrier layer is disposed between said internal cavity and said plastic layer.
18. The receptacle of claim 16 , wherein said carrier layer is a textile fabric.
19. The receptacle of claim 16 , wherein said carrier layer is paper.
20. The receptacle of claim 19 , wherein the carrier layer further includes perforations.
21. The receptacle of claim 16 , wherein said plastic layer is defined by strips of hot melt adhesive applied to said carrier layer.
22. A method of manufacturing receptacles for packaging bulk materials, comprising the steps of:
transporting a sheet of material in a machine direction, the sheet of material being a fibrous web that is permeable to gas and impermeable to water;
applying a plastic layer to the sheet of material, the plastic layer having openings that are permeable to gas and impermeable to water;
cutting the sheet of material into separate portions; and
shaping the separate portions to form individual receptacles.
23. The method of claim 22 , wherein applying the plastic layer further comprises:
supplying liquid hot melt adhesive to a slot nozzle; and
spraying strips of the hot melt adhesive onto the sheet of material.
24. The method of claim 22 , wherein applying the plastic layer further comprises spraying plastic powder onto the sheet of material.
25. The method of claim 22 , further comprising:
heating the sheet of material with a first heating element before applying the plastic layer.
26. The method of claim 25 , further comprising:
heating the sheet of material with a second heating element after applying the plastic layer.
27. The method of claim 22 , further comprising:
applying a second sheet of material to the plastic layer, the second sheet of material being a fibrous web that is permeable to gas and impermeable to water.
28. The method of claim 22 , wherein the individual receptacles are each defined by a body having an opening and an internal cavity, the method further comprising:
supplying material into the internal cavity of each receptacle; and
sealing the opening of each receptacle to close the internal cavity;
wherein supplying the material forces air within the internal cavity to exit the receptacle through the sheet of material and plastic layer.
29. The method of claim 28 , wherein supplying the material further comprises delivering cement into the internal cavity of each receptacle.
30. An apparatus for manufacturing a receptacle for packaging bulk material, wherein the receptacle is formed from a sheet of material being permeable to gas and impermeable to water, the apparatus comprising:
one or more rollers adapted to transport the sheet of material in a machine direction;
a supply of hot melt adhesive proximate said one or more rollers;
a coating tool communicating with said supply and adapted to apply hot melt adhesive to the sheet of material so as to form a plastic layer thereon, said plastic layer having openings that are permeable to gas and impermeable to water;
a cutting tool adapted to cut the sheet of material to form a separate portion; and
a shaping tool adapted to reshape said separate portion to form the receptacle.
31. The apparatus of claim 30 , wherein said coating tool further comprises a slot nozzle adapted to receive hot melt adhesive from said supply.
32. The apparatus of claim 31 , wherein said slot nozzle is divided into separate portions such that said coating tool is adapted to apply strips of hot melt adhesive to the sheet of material.
33. The apparatus of claim 30 , wherein said coating tool further comprises a dispersing nozzle adapted to spray plastic powder onto the sheet of material.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0309413 | 2003-07-30 | ||
FR0309413A FR2858302B1 (en) | 2003-07-30 | 2003-07-30 | WATERPROOF AND AIR-PERMEABLE CONTAINER AND METHOD FOR MANUFACTURING THE SAME |
PCT/EP2004/008519 WO2005012121A1 (en) | 2003-07-30 | 2004-07-29 | Moisture-repellent receptacle, and method for the production thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
US20080063323A1 true US20080063323A1 (en) | 2008-03-13 |
Family
ID=34043691
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/566,020 Abandoned US20080063323A1 (en) | 2003-07-30 | 2004-07-29 | Moisture-Repellent Receptacle and Method for the Production Thereof |
Country Status (6)
Country | Link |
---|---|
US (1) | US20080063323A1 (en) |
EP (1) | EP1658227B1 (en) |
JP (1) | JP2007500111A (en) |
DE (1) | DE502004005663D1 (en) |
FR (1) | FR2858302B1 (en) |
WO (1) | WO2005012121A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120067497A1 (en) * | 2010-09-18 | 2012-03-22 | Mathias Hansel | Bonding tool for attaching prepared adhesive to bonding part |
US20210381168A1 (en) * | 2020-06-05 | 2021-12-09 | Fiorini Packaging Spa | Bag or bundle-type packaging with no plastic elements and high protection from moisture and water |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007063784B3 (en) * | 2007-04-18 | 2013-06-27 | Abts- Advanced Bag Technology & Service Gmbh | Flexible building material bag e.g. cement bag, has laminate comprising layers connected with each other, and inner and outer layers permeable to air, where laminate is permeable to air, and is perforated |
DE102007063783B3 (en) * | 2007-04-18 | 2013-06-27 | Abts- Advanced Bag Technology & Service Gmbh | Flexible building material bag e.g. cement bag, has laminate comprising layers connected with each other, and inner and outer layers permeable to air, where laminate is permeable to air, and is perforated |
DE102007018579B4 (en) | 2007-04-18 | 2012-03-15 | Abts- Advanced Bag Technology & Service Gmbh | Cement bag and manufacturing process |
DE102014105018A1 (en) | 2014-04-08 | 2015-10-08 | Windmöller & Hölscher Kg | Sack with fleece material |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US2593328A (en) * | 1948-07-13 | 1952-04-15 | John W Meaker | Perforated multiple ply bag |
US4672684A (en) * | 1983-10-06 | 1987-06-09 | C I L, Inc. | Thermoplastic bag |
US5988881A (en) * | 1997-06-18 | 1999-11-23 | Bpb Plc | Paper sack |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
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GB1462941A (en) * | 1974-01-02 | 1977-01-26 | Leer Koninklijke Emballage | Sack |
US5294258A (en) | 1992-04-08 | 1994-03-15 | Nordson Corporation | Apparatus for producing an integral adhesive matrix |
WO2002042060A1 (en) * | 2000-11-21 | 2002-05-30 | Frantschach Industrial Packaging Austria Gmbh | Method for producing a paper sack and a paper sack |
-
2003
- 2003-07-30 FR FR0309413A patent/FR2858302B1/en not_active Expired - Fee Related
-
2004
- 2004-07-29 US US10/566,020 patent/US20080063323A1/en not_active Abandoned
- 2004-07-29 WO PCT/EP2004/008519 patent/WO2005012121A1/en active IP Right Grant
- 2004-07-29 JP JP2006521534A patent/JP2007500111A/en not_active Withdrawn
- 2004-07-29 DE DE502004005663T patent/DE502004005663D1/en not_active Expired - Fee Related
- 2004-07-29 EP EP04763615A patent/EP1658227B1/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2593328A (en) * | 1948-07-13 | 1952-04-15 | John W Meaker | Perforated multiple ply bag |
US4672684A (en) * | 1983-10-06 | 1987-06-09 | C I L, Inc. | Thermoplastic bag |
US5988881A (en) * | 1997-06-18 | 1999-11-23 | Bpb Plc | Paper sack |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120067497A1 (en) * | 2010-09-18 | 2012-03-22 | Mathias Hansel | Bonding tool for attaching prepared adhesive to bonding part |
US8443859B2 (en) * | 2010-09-18 | 2013-05-21 | A. Raybond Et Cie | Bonding tool for attaching prepared adhesive to bonding part |
US20130233487A1 (en) * | 2010-09-18 | 2013-09-12 | Mathias Hansel | Bonding tool for attaching prepared adhesive to bonding part |
US20210381168A1 (en) * | 2020-06-05 | 2021-12-09 | Fiorini Packaging Spa | Bag or bundle-type packaging with no plastic elements and high protection from moisture and water |
Also Published As
Publication number | Publication date |
---|---|
WO2005012121A1 (en) | 2005-02-10 |
EP1658227A1 (en) | 2006-05-24 |
FR2858302A1 (en) | 2005-02-04 |
JP2007500111A (en) | 2007-01-11 |
FR2858302B1 (en) | 2006-05-26 |
DE502004005663D1 (en) | 2008-01-17 |
EP1658227B1 (en) | 2007-12-05 |
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Owner name: NORDSON CORPORATION, OHIO Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:CHEVILLIARD, PHILIPPE;REEL/FRAME:021642/0435 Effective date: 20060202 |
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STCB | Information on status: application discontinuation |
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