US20070283554A1 - Cutting tool insert - Google Patents

Cutting tool insert Download PDF

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Publication number
US20070283554A1
US20070283554A1 US11/797,569 US79756907A US2007283554A1 US 20070283554 A1 US20070283554 A1 US 20070283554A1 US 79756907 A US79756907 A US 79756907A US 2007283554 A1 US2007283554 A1 US 2007283554A1
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Prior art keywords
layer
thickness
tic
cutting tool
cemented carbide
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US11/797,569
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Ingemar Hessman
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Sandvik Intellectual Property AB
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Sandvik Intellectual Property AB
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23BTURNING; BORING
    • B23B27/00Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
    • B23B27/14Cutting tools of which the bits or tips or cutting inserts are of special material
    • B23B27/148Composition of the cutting inserts
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/32Carbides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/34Nitrides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/36Carbonitrides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40Oxides
    • C23C16/403Oxides of aluminium, magnesium or beryllium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982Coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495Thickness [relative or absolute]
    • Y10T428/24967Absolute thicknesses specified
    • Y10T428/24975No layer or component greater than 5 mils thick
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264Up to 3 mils
    • Y10T428/2651 mil or less

Definitions

  • the present invention relates to a chamfering cutting tool insert particularly useful for the milling of plates intended for manufacturing of tubes for pipelines for crude oil, natural gas or the like.
  • Pipelines are frequently used to transport fluid products for substantial distances, with oil and gas transmission pipelines being but two well-known examples.
  • Such pipelines are generally constructed of individual pipe sections that are joined together by welding.
  • Individual pipe sections are formed from huge plates on the order of 4 m ⁇ 12 m with a thickness of 25 mm, of low alloyed steel and welded longitudinally.
  • the plates are machined to obtain a chamfer suitable for the subsequent welding of the individual sections as well as the welding together of separate pipe sections.
  • the machining of the plates to obtain the desired character is made in large milling machines with cutters having a diameter of from about 600 to 1200 mm, provided with 40-80 inserts of rectangular shape tangentially mounted with dimensions of 32 ⁇ 20 ⁇ 8 mm. Normally inserts of coated cemented carbide grade tools are used.
  • the criteria for the operation are sufficient surface finish and little or no structure deformation. It is important to create a surface finish that does not disturb the welding process.
  • a cutting tool insert comprising a cemented carbide body and a coating said cemented carbide body comprising WC, from about 7.3 to about 7.9 wt-% Co and from about 1.0 to about 1.8 wt-% cubic carbides of Ta and Nb, a highly W-alloyed binder phase with a CW-ratio of from about 0.86 to about 0.94, and an edge radius of from about 20 to about 45 ⁇ m, said coating comprising
  • a first (innermost) layer of TiC x N y O z with a thickness of from about 0.1 to about 2 ⁇ m, and with equiaxed grains with size less than about 0.5 ⁇ m
  • a layer of TiC x N y O z with a thickness of from about 0.1 to about 2 ⁇ m and with equiaxed or needlelike grains with size less than about 0.5 ⁇ m
  • a method of making a cutting tool insert comprising a cemented carbide body and coating the cemented carbide body having a composition of from about 7.3 to about 7.9 wt % Co, from about 1.0 to about 1.8 wt % cubic carbides and balance WC with a content of Ti on a level corresponding to a technical impurity, the average grain size of the WC being in the range of from about 1.5 to about 2.5 ⁇ m, and hardness from about 1500 to about 1600 HV and a CW-ratio of from about 0.84 to about 0.94, and with an edge radius of from about 20 to about 45 ⁇ m comprising coating said body with
  • a first (innermost) layer of TiC x N y O z with x+y+z 1 with a thickness of from about 0.1 to about 2 ⁇ m, and with equiaxed grains with size less than about 0.5 ⁇ m using known CVD-methods
  • a layer of TiC x N y O z with x+y+z 1 with a thickness of from about 2 to about 10 ⁇ m with columnar grains and with a diameter of about ⁇ 5 ⁇ m, deposited either by MTCVD-technique (using acetonitrile as the carbon and nitrogen source for forming the layer in the temperature range of 700-900° C.) or by high temperature CVD-technique (1000-1100° C.), the process conditions being selected to grow layers with columnar grains.
  • MTCVD-technique using acetonitrile as the carbon and nitrogen source for forming the layer in the temperature range of 700-900° C.
  • high temperature CVD-technique 1000-1100° C.
  • a layer of TiC x N y O z with x+y+z 1 with z ⁇ 0.5, with a thickness of from about 0.1 to about 2 ⁇ m and with equiaxed or needlelike grains with size less than about 0.5 ⁇ m, using known CVD-methods, this layer being the same as or different from the innermost layer.
  • coated cutting tool inserts particularly useful for chamfer milling of steel plates intended for oil pipes comprising a cemented carbide body with a composition of from about 7.3 to about 7.9 wt % Co, preferably about 7.6 wt % Co, from about 1.0 to about 1.8 wt % cubic carbides, preferably from about 1.4 to about 1.7 wt % cubic carbides of the metals Ta and Nb and balance WC.
  • the content of Ti is preferably on a level corresponding to a technical impurity.
  • the average grain size of the WC is in the range of from about 1.5 to 2.5 ⁇ m, preferably about 1.8 ⁇ m and hardness from about 1500 to about 1600 HV.
  • the cobalt binder phase is rather highly alloyed with W.
  • the CW-value is a function of the W content in the Co binder phase. A high CW-value corresponds to a low W-content in the binder phase.
  • an improved cutting performance is achieved if the cemented carbide body has a CW-ratio of from about 0.84 to about 0.94 preferably from about 0.86 to about 0.91.
  • a layer of TiC x N y O z with x+y+z 1 with z ⁇ 0.5, preferably z>0.1, with a thickness of from about 0.1 to about 2 ⁇ m and with equiaxed or needlelike grains with size less than or equal to about 0.5 ⁇ m, this layer being the same as or different from the innermost layer;
  • This outermost layer of TiN has a surface roughness Rmax less than about 0.4 ⁇ m over a length of 10 ⁇ m.
  • the inserts have before coating an edge radius of from about 20 to about 45 ⁇ m, preferably about 35 ⁇ m.
  • the TiN-layer is reduced in thickness over the edge line to 50-90% of its thickness on the rake face.
  • the ⁇ -Al 2 O 3 layer has a preferred crystal growth orientation in either the (012)-, (104)- or (110)-direction, preferably in the (012)-direction, as determined by X-ray Diffraction (XRD) measurements.
  • XRD X-ray Diffraction
  • I(hkl) measured intensity of the (hkl) reflection
  • I(hkl) standard intensity of the ASTM standard powder pattern diffraction data
  • n number of reflections used in the calculation, (hkl) reflections used are: (012), (104), (110), (113), (024), (116)
  • the TC for the set of (012), (104) or (110) crystal planes is larger than about 1.3, preferably larger than about 1.5.
  • the invention also relates to a method whereby a cemented carbide body with a composition of from about 7.3 to about 7.9 wt % Co, preferably about 7.6 wt % Co, from about 1.0 to about 1.8 wt % cubic carbides, preferably from about 1.4 to about 1.7 wt % cubic carbides of the metals Ta and Nb and WC as the remainder with a content of Ti on a level corresponding to a technical impurity with an average grain size of the WC in the range of from about 1.5 to about 2.5 ⁇ m, preferably about 1.8 ⁇ m, a hardness of from about 1500 to about 1600 HV, a CW-ratio of from about 0.84 to about 0.94, preferably from about 0.86 to about 0.91, and before coating an edge radius of from about 20 to about 45 ⁇ m, preferably about 35 ⁇ m is coated with
  • a first (innermost) layer of TiC x N y O z with x+y+z 1, preferably z ⁇ 0.5, with a thickness of from about 0.1 to about 2 ⁇ m, and with equiaxed grains with size less than about 0.5 ⁇ m using known CVD-methods.
  • a layer of TiC x N y O z with x+y+z 1 with z ⁇ 0.5, preferably z>0.1, with a thickness of from about 0.1 to about 2 ⁇ m and with equiaxed or needlelike grains with size less than about 0.5 ⁇ m, using known CVD-methods, this layer being the same as or different from the innermost layer.
  • This outermost layer of TiN has a surface roughness Rmax ⁇ 0.4 ⁇ m over a length of 10 ⁇ m.
  • the smooth coating surface is obtained by a gentle wet-blasting of the coating surface with fine grained (400-150 mesh) alumina powder or by brushing the edges with brushes based on e.g. SiC as disclosed e.g. in U.S. Pat. No. 5,861,210 if present, a TiN-layer reduced in thickness over the edge line to 50-90% of the thickness on the rake face.
  • the invention also relates to the use of a cutting tool insert according to above for side and face milling of rolled low alloyed steel at low and moderate cutting speeds i.e. less than about 500 m/min.
  • Milling cutter Böhlerite special cutter of diameter 800 mm.
  • Feed rate/tooth 2.5-3.0 mm
  • Tool life criterion Surface finish.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Chemical Vapour Deposition (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

The present invention relates to a cutting tool insert for side and face milling of rolled low alloyed steel at low and at moderate cutting speeds comprising a cemented carbide body and a coating and a method for making same. The cemented carbide body comprises WC, from about 7.3 to about 7.9 wt-% Co and from about 1.0 to about 1.8 wt-% cubic carbides of Ta and Nb and a highly W-alloyed binder phase with a CW-ratio of from about 0.86 to about 0.94. The coating comprises:
    • a first (innermost) layer of TiCxNyOz with a thickness of from about 0.1 to about 2 μm, and with equiaxed grains with size less than about 0.5 μm
    • a layer of TiCxNyOz with a thickness of from about 2 to about 10 μm with columnar grains with a diameter of about less than about 5 μm
    • a layer of TiCxNyOz with a thickness of 0.1-2 μm and with equiaxed or needlelike grains with size less than about 0.5 μm
    • an outer layer of a smooth, textured, finegrained α-Al2O3 layer with a thickness of from about 2 to about 10 μm. The invention also relates to the use of such a cutting tool insert for side and face milling of rolled low alloyed steel at low and moderate cutting speeds.

Description

    BACKGROUND OF THE INVENTION
  • The present invention relates to a chamfering cutting tool insert particularly useful for the milling of plates intended for manufacturing of tubes for pipelines for crude oil, natural gas or the like.
  • Pipelines are frequently used to transport fluid products for substantial distances, with oil and gas transmission pipelines being but two well-known examples. Such pipelines are generally constructed of individual pipe sections that are joined together by welding.
  • Individual pipe sections are formed from huge plates on the order of 4 m×12 m with a thickness of 25 mm, of low alloyed steel and welded longitudinally.
  • Separate lengths of pipe are typically interconnected by electric-arc welding and many types of welding techniques are used or proposed in the art for that purpose.
  • The plates are machined to obtain a chamfer suitable for the subsequent welding of the individual sections as well as the welding together of separate pipe sections.
  • The machining of the plates to obtain the desired character is made in large milling machines with cutters having a diameter of from about 600 to 1200 mm, provided with 40-80 inserts of rectangular shape tangentially mounted with dimensions of 32×20×8 mm. Normally inserts of coated cemented carbide grade tools are used.
  • It is important to obtain long tool life and minimise the tool change frequency in order to reduce the cost. The criteria for the operation are sufficient surface finish and little or no structure deformation. It is important to create a surface finish that does not disturb the welding process.
  • OBJECT AND SUMMARY OF THE INVENTION
  • It is an object of the present invention to provide a cutting tool insert particularly useful for the chamfer milling of steel plates for oil pipelines and similar.
  • In one aspect of the invention, there is provided a cutting tool insert comprising a cemented carbide body and a coating said cemented carbide body comprising WC, from about 7.3 to about 7.9 wt-% Co and from about 1.0 to about 1.8 wt-% cubic carbides of Ta and Nb, a highly W-alloyed binder phase with a CW-ratio of from about 0.86 to about 0.94, and an edge radius of from about 20 to about 45 μm, said coating comprising
  • a first (innermost) layer of TiCxNyOz with a thickness of from about 0.1 to about 2 μm, and with equiaxed grains with size less than about 0.5 μm
  • a layer of TiCxNyOz with a thickness of from about 2 to about 10 μm with columnar grains with a diameter of less than about 5 μm
  • a layer of TiCxNyOz with a thickness of from about 0.1 to about 2 μm and with equiaxed or needlelike grains with size less than about 0.5 μm
  • an outer layer of a smooth, textured, finegrained α-Al2O3 layer with a thickness of from about 2 to about 10 μm.
  • In another aspect of the invention, there is provided a method of making a cutting tool insert comprising a cemented carbide body and coating the cemented carbide body having a composition of from about 7.3 to about 7.9 wt % Co, from about 1.0 to about 1.8 wt % cubic carbides and balance WC with a content of Ti on a level corresponding to a technical impurity, the average grain size of the WC being in the range of from about 1.5 to about 2.5 μm, and hardness from about 1500 to about 1600 HV and a CW-ratio of from about 0.84 to about 0.94, and with an edge radius of from about 20 to about 45 μm comprising coating said body with
  • a first (innermost) layer of TiCxNyOz with x+y+z=1 with a thickness of from about 0.1 to about 2 μm, and with equiaxed grains with size less than about 0.5 μm using known CVD-methods
  • a layer of TiCxNyOz with x+y+z=1 with a thickness of from about 2 to about 10 μm with columnar grains and with a diameter of about <5 μm, deposited either by MTCVD-technique (using acetonitrile as the carbon and nitrogen source for forming the layer in the temperature range of 700-900° C.) or by high temperature CVD-technique (1000-1100° C.), the process conditions being selected to grow layers with columnar grains.
  • a layer of TiCxNyOz with x+y+z=1 with z<0.5, with a thickness of from about 0.1 to about 2 μm and with equiaxed or needlelike grains with size less than about 0.5 μm, using known CVD-methods, this layer being the same as or different from the innermost layer.
  • a layer of a smooth textured α-Al2O3 layer with a thickness of from about 2 to about 10 μm, and a surface roughness (Ra) of less than about 0.3 mm over a measured length of 0.25 mm.
  • In still another aspect of the invention, there is provided a use of a cutting tool insert as described above for side and face milling of rolled low alloyed steel at low or moderate cutting speeds.
  • DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT OF THE INVENTION
  • It has now surprisingly been found that with the present invention an increased tool life can be obtained.
  • According to the present invention, coated cutting tool inserts particularly useful for chamfer milling of steel plates intended for oil pipes are provided comprising a cemented carbide body with a composition of from about 7.3 to about 7.9 wt % Co, preferably about 7.6 wt % Co, from about 1.0 to about 1.8 wt % cubic carbides, preferably from about 1.4 to about 1.7 wt % cubic carbides of the metals Ta and Nb and balance WC. The content of Ti is preferably on a level corresponding to a technical impurity. The average grain size of the WC is in the range of from about 1.5 to 2.5 μm, preferably about 1.8 μm and hardness from about 1500 to about 1600 HV.
  • The cobalt binder phase is rather highly alloyed with W. The content of W in the binder phase can be expressed as the CW-ratio=Ms/(wt % Co×0.0161), where Ms is the saturation magnetization of the cemented carbide body in kA/m and wt % Co is the weight percentage of Co in the cemented carbide. The CW-value is a function of the W content in the Co binder phase. A high CW-value corresponds to a low W-content in the binder phase.
  • According to the present invention, an improved cutting performance is achieved if the cemented carbide body has a CW-ratio of from about 0.84 to about 0.94 preferably from about 0.86 to about 0.91.
  • The coating comprises a first (innermost) layer of TiCxNyOz with x+y+z=1, preferably z<0.5, with a thickness of 0.1-2 μm, and with equiaxed grains with size less than about 0.5 μm;
  • a layer of TiCxNyOz with x+y+z=1, preferably with z=0 and x>0.3 and y>0.3, with a thickness of from about 2 to about 10 μm, preferably from about 4 to about 7 μm, with columnar grains and with a diameter of about 5 μm, preferably less than about 2 μm;
  • a layer of TiCxNyOz with x+y+z=1 with z<0.5, preferably z>0.1, with a thickness of from about 0.1 to about 2 μm and with equiaxed or needlelike grains with size less than or equal to about 0.5 μm, this layer being the same as or different from the innermost layer;
      • an outer layer of a smooth, textured, finegrained (grain size about 1 μm) α-Al2O3 layer with a thickness of from about 2 to about 10 μm, preferably from about 3 to about 6 μm, and a surface roughness (Ra) of less than about 0.3 mm over a measured length of 0.25 mm; and preferably
  • a further layer of from about 0.5 to about 1.0 μm thick TiN. This outermost layer of TiN has a surface roughness Rmax less than about 0.4 μm over a length of 10 μm.
  • The inserts have before coating an edge radius of from about 20 to about 45 μm, preferably about 35 μm. The TiN-layer is reduced in thickness over the edge line to 50-90% of its thickness on the rake face.
  • In addition, the α-Al2O3 layer has a preferred crystal growth orientation in either the (012)-, (104)- or (110)-direction, preferably in the (012)-direction, as determined by X-ray Diffraction (XRD) measurements. A Texture Coefficient, TC, is defined as: TC ( hkl ) = I ( hkl ) I o ( hkl ) { 1 n ( hkl ) I o ( hkl ) } - 1
    where
    I(hkl)=measured intensity of the (hkl) reflection
    I(hkl)=standard intensity of the ASTM standard powder pattern diffraction data
    n=number of reflections used in the calculation, (hkl)
    reflections used are: (012), (104), (110), (113), (024), (116)
  • According to the invention, the TC for the set of (012), (104) or (110) crystal planes is larger than about 1.3, preferably larger than about 1.5.
  • The invention also relates to a method whereby a cemented carbide body with a composition of from about 7.3 to about 7.9 wt % Co, preferably about 7.6 wt % Co, from about 1.0 to about 1.8 wt % cubic carbides, preferably from about 1.4 to about 1.7 wt % cubic carbides of the metals Ta and Nb and WC as the remainder with a content of Ti on a level corresponding to a technical impurity with an average grain size of the WC in the range of from about 1.5 to about 2.5 μm, preferably about 1.8 μm, a hardness of from about 1500 to about 1600 HV, a CW-ratio of from about 0.84 to about 0.94, preferably from about 0.86 to about 0.91, and before coating an edge radius of from about 20 to about 45 μm, preferably about 35 μm is coated with
  • a first (innermost) layer of TiCxNyOz with x+y+z=1, preferably z<0.5, with a thickness of from about 0.1 to about 2 μm, and with equiaxed grains with size less than about 0.5 μm using known CVD-methods.
  • a layer of TiCxNyOz with x+y+z=1, preferably with z=0 and x>0.3 and y>0.3, with a thickness of from about 2 to about 10 μm, preferably about 4-7 μm, with columnar grains and with a diameter of about less than about 5 μm, preferably less than about 2 μm, deposited either by MTCVD-technique (using acetonitrile as the carbon and nitrogen source for forming the layer in the temperature range of 700-900° C.) or by high temperature CVD-technique (1000-1100° C.), the process conditions being selected to grow layers with columnar grains, that is generally high process pressure (0.3-1 bar). However, the exact conditions depend to a certain extent on the design of the equipment used and are within the purview of the skilled artisan.
  • a layer of TiCxNyOz with x+y+z=1 with z<0.5, preferably z>0.1, with a thickness of from about 0.1 to about 2 μm and with equiaxed or needlelike grains with size less than about 0.5 μm, using known CVD-methods, this layer being the same as or different from the innermost layer.
  • a layer of a smooth textured α-Al2O3 layer with a thickness of from about 2 to about 10 μm, preferably from about 3 to about 6 μm, and a surface roughness (Ra) of less than about 0.3 mm over a measured length of 0.25 mm deposited according to U.S. Pat. No. 5,487,625, U.S. Pat. No. 5,851,687 or U.S. Pat. No. 5,766,782 and preferably
  • a further layer from about 0.5 to about 1.0 μm thick layer of CVD- or PVD-TiN. This outermost layer of TiN has a surface roughness Rmax<0.4 μm over a length of 10 μm.
  • The smooth coating surface is obtained by a gentle wet-blasting of the coating surface with fine grained (400-150 mesh) alumina powder or by brushing the edges with brushes based on e.g. SiC as disclosed e.g. in U.S. Pat. No. 5,861,210 if present, a TiN-layer reduced in thickness over the edge line to 50-90% of the thickness on the rake face.
  • When a TiCxNyOz layer with z>0 is desired, CO2 and/or CO is added to the reaction gas mixture.
  • The invention also relates to the use of a cutting tool insert according to above for side and face milling of rolled low alloyed steel at low and moderate cutting speeds i.e. less than about 500 m/min.
  • The invention is additionally illustrated in connection with the following Examples which are to be considered as illustrative of the present invention. It should be understood, however, that the invention is not limited to the specific details of the Examples.
  • EXAMPLE 1
  • Cemented carbide milling inserts of special shape 32×20×8 mm in accordance with the invention with the composition 7.6 wt-% Co, 1.25 wt-% TaC, 0.30 wt-% NbC and WC as balance with average grain size of 1.8 μm, with a binder phase alloyed with W corresponding to a CW-ratio of 0.87, and an edge radius of 35 μm were coated with a 0.5 μm equiaxed TiCN-layer followed by a 5 μm thick Ti(C,N)-layer with columnar grains by using MTCVD-technique (process temperature 850° C.). In subsequent process steps during the same coating cycle, a 1 μm thick layer with equiaxed grains of TiCxNyOz (approx. x=0.6, y=0.2 and z=0.2) was deposited followed by a 4 μm thick layer of (012)-textured α-Al2O3 deposited according to conditions given in U.S. Pat. No. 5,487,625. XRD-measurement showed a texture coefficient TC(012) of 1.5. After coating, the inserts were smoothed using a nylon straw brush containing SiC grains. Examination of the brushed inserts in a light optical microscope revealed that the outermost TiN-layer had been somewhat reduced in thickness.
  • EXAMPLE 2
  • Chamfer milling of low alloyed rolled steel plates in low carbon steel X70 was performed under the following conditions:
  • Machine: MFL Austria
  • Operation: Chamfer milling under dry conditions.
  • Work piece: Steel plates 4×12 m in 25 mm thickness.
  • Milling cutter: Böhlerite special cutter of diameter 800 mm.
  • RPM: 120 r/min
  • Cutting speed: 300 m/min
  • Feed rate/tooth: 2.5-3.0 mm
  • Radial depth of cut: 25 mm
  • Insert style: 48 pcs of special type 32×20×8
  • Grade 1: Inserts according to example 1.
  • Grade 2: Inserts from competitor A
  • Grade 3: Inserts from competitor B
  • Tool life criterion: Surface finish.
  • Result: Tool life number of plates
    Grade 1 Grade 2 Grade 3
    Invention Prior art Prior art
    125 plates 78 Plates 74 Plates
  • It is apparent that 60% better tool life in number of plates compared to prior art is obtained.
  • Although the present invention has been described in connection with a preferred embodiment thereof, it will be appreciated by those skilled in the art that additions, deletions, modifications, and substitutions not specifically described may be made without departing from the spirit and scope of the invention as defined in the appended claims.

Claims (27)

1-8. (canceled)
9. A method of manufacturing a metal workpiece with a cutting tool insert including a cemented carbide body and a coating,
said cemented carbide body comprising WC, from about 7.3 to about 7.9 wt-% Co and from about 1.0 to about 1.8 wt-% cubic carbides of Ta and Nb, a highly W-alloyed binder phase with a CW-ratio of from about 0.86 to about 0.94, and an edge radius of from about 20 to about 45 μm,
said coating comprising
a first (innermost) layer of TiCxNyOz with a thickness of from about 0.1 to about 2 μm, and with equiaxed grains with size less than about 0.5 μm,
a layer of TiCxNyOz with a thickness of from about 2 to about 10 μm with columnar grains with a diameter of less than about 5 μm,
a layer of TiCxNyOz with a thickness of from about 0.1 to about 2 μm and with equiaxed or needlelike grains with size less than about 0.5 μm, and
an outer layer of a smooth, textured, finegrained α-Al2O3 layer with a thickness of from about 2 to about 10 μm,
the method comprising:
side and face milling the metal workpiece at low or moderate cutting speeds.
10. The method of claim 9, wherein the metal workpiece is formed of rolled low alloyed steel.
11. The method of claim 9, wherein the metal workpiece is a plate.
12. The method of claim 11, comprising manufacturing a tube from the milled plate.
13. The method of claim 1, wherein the α-Al2O3 layer has a texture in the (104)-direction with a texture coefficient TC(104) larger than 1.3.
14. The method of claim 1, wherein the α-Al2O3 layer has a texture in the (110)-direction with a texture coefficient TC(110) larger than 1.3.
15. The method of claim 1, wherein the cutting tool insert includes from about 0.5 to about 1.0 μm thick layer of TiN having a surface roughness Rmax<0.4 μm over a length of 10 μm and reduced in thickness over the edge line to from about 50 to about 90% of the thickness on the rake face.
16. The method of claim 1, wherein the cemented carbide includes from about 1.4 to about 1.7 wt-% carbides of Ta and Nb.
17. A method of manufacturing a metal workpiece with a cutting tool insert, the cutting tool insert including a cemented carbide body and a coating,
wherein said cemented carbide body includes WC, from about 7.3 to about 7.9 wt-% Co and from about 1.0 to about 1.8 wt-% cubic carbides of Ta and Nb, a highly W-alloyed binder phase with a CW-ratio of from about 0.86 to about 0.94, and
wherein said coating includes
a first (innermost) layer of TiCxNyOz with a thickness of from about 0.1 to about 2 μm, and with equiaxed grains with size less than about 0.5 μm,
a second layer of TiCxNyOz with a thickness of from about 2 to about 10 μm with columnar grains with a diameter of less than about 5 μm,
a third layer of TiCxNyOz with a thickness of from about 0.1 to about 2 μm and with equiaxed or needlelike grains with size less than about 0.5 μm,
an outer layer of a smooth, textured, finegrained α-Al2O3 layer with a thickness of from about 2 to about 10 μm, and
a further layer of TiN having a surface roughness Rmax<0.4 μm over a length of 10 μm, having a thickness on a rake face of from about 0.5 to about 1.0 μm and having a reduced thickness over an edge line of from about 50 to about 90% of the thickness on the rake face,
the method comprising:
side and face milling the metal workpiece with the cutting tool insert.
18. The method of claim 17, wherein side and face milling is at a cutting speed of less than about 500 m/min.
19. The method of claim 17, wherein side and face milling is at a cutting speed of 1 about 300 m/min to about 500 m/min.
20. The method of claim 17, wherein the cutting tool insert is a chamfering cutting tool insert.
21. The method of claim 17, wherein the metal workpiece is formed of rolled low alloyed steel.
22. The method of claim 17, wherein the metal workpiece is a plate and the method comprises manufacturing a tube from the milled plate.
23. The method of claim 17, wherein the α-Al2O3 layer has a texture in the (012)-direction with a texture coefficient TC(012) larger than 1.3.
24. The method of claim 17, wherein the α-Al2O3 layer has a texture in the (104)-direction with a texture coefficient TC(104) larger than 1.3.
25. The method of claim 17, wherein the α-Al2O3 layer has a texture in the (110)-direction with a texture coefficient TC(110) larger than 1.3.
26. The method of claim 17, wherein the cemented carbide contains from about 1.4 to about 1.7 wt-% carbides of Ta and Nb.
27. The method of claim 17, wherein the insert has an edge radius of from about 20 to about 45 μm before coating.
28. The method of claim 17, wherein said edge radius is about 35 μm.
29. The method of claim 17, wherein said cemented carbide body comprises about 7.6 wt-% Co.
30. The method of claim 17, wherein an average grain size of the WC is in a range of from about 1.5 to 2.5 μm.
31. The method of claim 17, wherein said CW-ratio is from about 0.86 to about 0.91.
32. The method of claim 17, wherein the thickness of the second layer of TiCxNyOz is from about 4 to about 7 μm.
33. The method of claim 17, wherein the thickness of the outer layer of α-Al2O3 is from about 3 to about 6 μm.
34. The method of claim 17, wherein a texture coefficient of the α-Al2O3 layer for the set of (012), (104) or (110) crystal planes is larger than 1.5.
US11/797,569 2004-07-12 2007-05-04 Cutting tool insert Abandoned US20070283554A1 (en)

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EP1616977A3 (en) 2006-12-20
US7232603B2 (en) 2007-06-19
EA200500889A1 (en) 2006-04-28
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SE528109C2 (en) 2006-09-05
EA010934B1 (en) 2008-12-30

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