US20050238528A1 - Heat treatable Al-Zn-Mg-Cu alloy for aerospace and automotive castings - Google Patents
Heat treatable Al-Zn-Mg-Cu alloy for aerospace and automotive castings Download PDFInfo
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- US20050238528A1 US20050238528A1 US11/111,212 US11121205A US2005238528A1 US 20050238528 A1 US20050238528 A1 US 20050238528A1 US 11121205 A US11121205 A US 11121205A US 2005238528 A1 US2005238528 A1 US 2005238528A1
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- This invention is an aluminum alloy for aerospace and automotive shaped castings, castings comprised of the alloy, and methods of making cast components of the alloy.
- Cast aluminum parts are used in structural applications in automobile suspensions to reduce weight.
- the most commonly used group of alloys, Al—Si 7 —Mg has well established strength limits. In order to obtain lighter weight parts, higher strength material is needed with established material properties for design.
- cast materials made of A356.0, the most commonly used Al—Si 7 —Mg alloy can reliably guarantee ultimate tensile strength of 290 MPa (42,060 psi), and tensile yield strength of 220 MPa (31,908 psi) with elongations of 8% or greater.
- forged products are often used. These are usually more expensive than cast products. There exists the potential for considerable cost savings if cast products can be used to replace forged products with no loss of strength, elongation, corrosion resistance, fatigue strength, etc. This is true in both automotive and aerospace applications.
- Casting alloys exhibiting higher tensile strength and fatigue resistance than the Al—Si 7 —Mg material are desirable. Such improvements could be used to reduce weight in new parts or in existing parts which can be redesigned to use the improved material properties to great advantage.
- the alloy of the present invention is an Al—Zn—Mg base alloy for low pressure permanent or semi-permanent mold, squeeze, high pressure die, pressure or gravity casting, lost foam, investment casting, V-mold, or sand mold casting with the following composition ranges (all in weight percent):
- Silicon up to about 1.0% may be employed to improve castability. Lower levels of silicon may be employed to increase strength. For some applications, manganese up to about 0.3% may be employed to improve castability. In other alloys, manganese is to be avoided.
- the alloy may also contain grain refiners such as titanium diboride, TiB 2 or titanium carbide, TiC and/or anti-recrystallization agents such as zirconium or scandium. If titanium diboride is employed as a grain refiner, the concentration of boron in the alloy may be in a range from 0.0025% to 0.05%. Likewise, if titanium carbide is employed as a grain refiner, the concentration of carbon in the alloy may be in the range from 0.0025% to 0.05%.
- Typical grain refiners are aluminum alloys containing TiC or TiB 2 .
- Zirconium if used to prevent grain growth during solution heat treatment, is generally employed in a range below 0.2%. Scandium may also be used in a range below 0.3%.
- the alloy demonstrated 50% higher tensile yield strength than is obtainable from A356.0-T6, while maintaining similar elongations. This will allow part designs requiring higher strength than alloys which are readily available today in Al—Si—Mg alloys such as A356.0-T6 or A357.0-T6. Fatigue performance in the T6 temper is increased over the A356.0-T6 material by 30%.
- the present invention is an aluminum alloy including from about 3.5-5.5% Zn, from about 1-3% Mg, about 0.05-0.5% Cu and it contains less than about 1% Si.
- the present invention is a heat treatable shaped casting of an aluminum alloy including from about 3.5-5.5% Zn, from about 1-3% Mg, from about 0.05-0.5% Cu, and less than about 1% Si.
- the present invention is a method of preparing a heat treatable aluminum alloy shaped casting.
- the method includes preparing a molten mass of an aluminum alloy including from about 3.5-5.5% Zn, from about 1-3% Mg, from about 0.05-0.5% Cu, and less than about 1% Si.
- the method further includes casting at least a portion of the molten mass in a mold configured to produce the shaped casting, permitting the molten mass to solidify, and removing the shaped casting from the mold.
- FIG. 1 is a photograph of a cut surface of a cut sample of prior art A356.0 alloy cast in a shrinkage mold showing the shrinkage cracking tendency of the prior art A356.0 alloy;
- FIG. 2 is a photograph, similar to FIG. 1 , of a cut surface of a second sample of prior art A356.0 cast in a shrinkage mold showing the shrinkage cracking tendency of the prior art A356.0 alloy;
- FIG. 3 is a photograph of a cut surface of a sample of the alloy of the present invention cast in a shrinkage mold showing a lack of shrinkage cracking
- FIG. 4 is a photograph, similar to FIG. 3 , of a cut surface of a second sample of the alloy of the present invention cast in a shrinkage mold showing a lack of shrinkage cracking.
- FIG. 5 presents strength and elongation data for directionally solidified samples of the present invention in T6 condition
- FIG. 6 is a photograph of a front knuckle casting of an alloy according to the present invention, showing locations from which tensile test samples were obtained;
- FIG. 7 is a plot of strength and elongation data for tensile test samples cut from the casting shown in FIG. 6 after T5 and also after T6 heat treatments;
- FIG. 9 is a graph showing staircase fatigue testing of the present alloy in T6 condition compared to the response of prior art A356.0-T6 with the mean fatigue strength for A356.0-T6.
- FIG. 10 is a graph showing depth of attack after an intergranular corrosion test of the alloy of the present invention compared to the prior art alloy A356.
- FIG. 11 is a photomicrograph of an alloy according to the present invention after an intergranular corrosion test, on the as cast side of the sample.
- FIG. 12 is a photomicrograph of an alloy according to the present invention after an intergranular corrosion test, on a machined side of the sample.
- FIG. 13 is a photomicrograph of the prior art alloy A356 after an intergranular corrosion test.
- FIG. 14 is a graph presenting results of a stress corrosion test on alloys of the present invention, with varied levels of copper.
- FIG. 15 is a graph showing the effect of copper and magnesium levels on stress corrosion cracking for alloys of the present invention.
- any numerical range of values herein are understood to include each and every number and/or fraction between the stated range minimum and maximum.
- a range of about 3.5 to 5.5 wt % zinc, for example, would expressly include all intermediate values of about 3.6, 3.7, 3.8 and 3.9%, all the way up to and including 5.3, 5.35, 5.4, 5.475 and 5.499% Zn.
- Table I presents composition data for the alloys which were tested.
- the first and third lines showing compositions is for directionally solidified castings.
- the second line is for the composition used in a shaped casting.
- the shaped casting was the front knuckle shown in FIG. 6 .
- TABLE I Alloy Composition Composition of test samples (Weight %) Zn Mg Si Cu Mn Fe Ti B DS Casting 4.28 1.99 0.04 0.01 0.00 0.04 0.00 0.0005 Cast 4.2 2 ⁇ 0.1 0.2 0.05 ⁇ 0.1 0.06 0.02 Knuckle DS Casting 4.57 2.03 0.04 0.31 0.04 0.05 0.06 0.02
- Table II presents room temperature mechanical properties of the directionally solidified alloys having the compositions shown in the first and third data lines of Table I.
- the first data line in Table II is for a directionally solidified casting comprised of the alloy of the first data line in Table I after five weeks of natural ageing.
- the second data line in Table 2 is for the same alloy after T5 heat treatment, and the third data line is for that alloy after T6 heat treatment.
- the fourth and fifth data lines in Table II are for the alloy in the bottom line of Table 1, which is a high copper alloy. This alloy, also, was subjected to a T6 heat treatment.
- FIG. 5 The development of mechanical properties of directionally solidified samples of the present invention during heat treatment is presented in FIG. 5 .
- the composition of these samples was presented in the first data row in Table 1.
- the solution heat treatment was at 1030° F. (554° C.) for 8 hours, which was followed by the cold water quench, and then artificial ageing. Samples were taken out of the oven and subjected to mechanical testing after various amounts of artificial ageing. The properties measured were TYS, UTS and percent elongation. The duration of the artificial ageing was 15 hours. During the first 6 hours, the temperature was 250° F. (121° C.). For the subsequent 9 hours, the temperature was 320° F. (160° C.). Values for the TYS and UTS are referenced to the scale on the left, values of percent elongation are referenced to the scale on the right.
- Table III presents data for front knuckle castings as shown in FIG. 6 .
- This is an alloy according to the present invention, and has the composition presented in the second data row in Table 1.
- the locations of tensile test samples 1, 2 and 3 are indicated in FIG. 6 .
- Tests were performed on one casting subjected to a T5 heat treatment consisting of 160° C. for 6 hours, and one casting subjected to a T6 heat treatment of solution heat treatment at 554° C. for 8 hours followed by a cold water hen by artificial ageing at 121° C. for 6 hours and 160° C. for 6 hours.
- FIG. 8 shows the S-N fatigue response of the alloy of the present invention in comparison to the response of the prior art alloy A356.0-T6.
- FIG. 9 is a graph showing staircase fatigue testing of the alloy of the present invention in T6 condition compared to the response of the prior art alloy, A356.0-T6 with a calculated mean value for A356.0-T6.
- the composition of the alloy of the present invention was as presented in the second data row of Table 1.
- the samples were solution heat treated at 526° C. or 554 ° C., quenched and artificially aged at 160° C. for 6 hours. As seen earlier, the fatigue response of these samples is appreciably improved when compared to A356.0-T6 material.
- the mean fatigue strength of the alloy of the present invention was 109.33 MPa with a standard deviation of 9.02 MPa.
- the standard deviation of the mean fatigue strength was 3.01 MPa.
- the calculated mean fatigue strength at 10 7 cycles of A356.0 T6 is 70 MPa.
- Corrosion resistance of the alloy of the present invention was tested using the ASTM G110 corrosion test, which is the “Standard Practice for Evaluating Intergranular Corrosion Resistance of Heat Treatable Aluminum Alloys by Immersion in Sodium Chloride+Hydrogen Peroxide Solution”.
- specimens are immersed in a solution that contains 57 g/L NaCl and 10 mL/L H 2 O 2 (30%) for 6-24 hours.
- the specimens are then cross-sectioned and examined under optical microscope for type (intergranular corrosion or pitting) and depth of corrosion attack.
- FIG. 10 is a graph presenting the depth of attack following the ASTM G110 corrosion test after 6 hours and 24 hours for an alloy according to the present invention and for the alloy A356.0.
- FIGS. 11 and 12 are photomicrographs of an alloy according to the present invention after 24 hours exposure to the ASTM G110 corrosion test. Very little intergranular corrosion can be seen in these photomicrographs.
- FIG. 13 is a photomicrograph of the A356.0 alloy after 24 hours of exposure to the ASTM G110 corrosion test. Considerable intergranular corrosion can be seen in this photomicrograph.
- Corrosion tests were also performed employing the ASTM G44 test, which is the “Standard Practice for Exposure of Metals and Alloys by Alternate Immersion in Neutral 3.5% Sodium Chloride Solution”.
- ASTM G44 test is the “Standard Practice for Exposure of Metals and Alloys by Alternate Immersion in Neutral 3.5% Sodium Chloride Solution”.
- stressed specimens are subject to a 1-hour cycle which includes immersion in 3.5% NaCl solution for 10 minutes and then in lab air for 50 minutes. This 1-hour cycle is continuously repeated. During the test, the specimens are regularly inspected for cracks and failures.
- Table IV presents the compositions of various alloys according to the present invention, which were employed in ASTM G44 tests.
- Alloy Composition Sample Number Zn Mg Cu Ti B Zr 59 4.23 1.5 0.29 0.029 0.0055 ⁇ 0.001 86 4.41 1.49 0.23 0.036 0.0038 n/a 110 4.39 1.74 0.28 0.057 0.0129 ⁇ 0.001 117 4.39 1.74 0.28 0.057 0.0129 ⁇ 0.001 138 4.19 1.99 0.26 0.073 0.015 ⁇ 0.001 159 4.31 1.93 0.24 0.105 0.0252 0.1127 A 4.43 2.05 0.06 0.0208 B 4.5 2 0.2 0.06 0.02 n/a C 4.5 1.2 D 4.5 1.2
- Table V presents the test results for the alloy compositions presented in Table IV.
- TABLE V ASTM G44 Test of Alloys with Various Mg and Cu Contents Run or S Stress Percentage Days to Number Temper Level(MPa) of TYS F/N Failure 59 (Knuckle) T5 152.37 75% 0/5 86 (Knuckle) T6 239.25 75% 4/5 17, 17, 22, 28 110 (Knuckle) T5 154.44 75% 0/5 117 (Knuckle) T6 196.50 75% 0/5 138 (Knuckle) T6 247.52 75% 2/5 45, 61 159 (Knuckle) T6 270.27 75% 3/5 11, 11, 11 A T5 186.16 75% 5/5 4, 4, 4, 7, 64 B T6 182.02 50% 4/4 7, 11, 13, 19 C T5 135.83 75% 0/5 D T6 194.43 75% 0/5
- FIG. 14 is a graph presenting the results of these tests. It is seen that, for alloys of the present invention, and at these high magnesium levels, increasing copper provides increased resistance to stress corrosion cracking.
- FIG. 15 is a graph showing the effect of copper and magnesium levels on stress corrosion cracking for alloys of the present invention. This shows that for alloys according to the present invention which have magnesium in the range from 1.5-2%, it is desirable to include copper in the range from0.25-0.3%.
- Table VI and VII present the results of plant trials in which repeated shots were made from a single liquid metal reservoir. One trial was performed on April 4, one was performed on June 4 and one on September 4. On each day, the composition for all the castings made varied very little.
- Table VI presents the ranges of the compositions of samples taken on each of the test days.
- the compositions contained high levels of magnesium and copper, which were expected to provide exceptionally high strength levels.
- TABLE VI MCC plant trial alloy composition ranges Date Si Fe Mn Cu Mg Zn Ti B Zr Apr- 0.05-0.09 0.03-0.04 0.03-0.04 0.22-0.27 1.9-2.2 4.1-4.7 0.03-0.06 0.001-0.0007 0.00-0.15 04 Jun- 0.03-0.09 0.04-0.08 0.04-0.05 0.24-0.29 1.5-2.0 4.6-4.9 0.03-0.11 0.008-0.025 0.00-0.12 04 Sep- 0.04-0.05 0.14-0.20 0.03-0.04 0.27-0.32 2.1-2.3 4.4-4.9 0.04-0.07 0.0006-0.0037 0.13-0.14 04
- Table VII presents the stress data, ultimate tensile strength, tensile yield strength, and elongation for four different locations in each casting.
- the column for sample numbers labels the individual castings.
- the column for location defines individual mechanical test samples cut from the casings.
Abstract
Description
- This application claims the benefit of U.S. Provisional Application Ser. No. 60/564,813 filed on Apr. 22, 2004, which is fully incorporated herein by reference thereto. It is also closely related to the patent application “A Heat Treatable Al—Zn—Mg Alloy for Shaped Castings” filed concurrently with this application, and which is also incorporated herein by reference thereto.
- This invention is an aluminum alloy for aerospace and automotive shaped castings, castings comprised of the alloy, and methods of making cast components of the alloy.
- Cast aluminum parts are used in structural applications in automobile suspensions to reduce weight. The most commonly used group of alloys, Al—Si7—Mg, has well established strength limits. In order to obtain lighter weight parts, higher strength material is needed with established material properties for design. At present, cast materials made of A356.0, the most commonly used Al—Si7—Mg alloy, can reliably guarantee ultimate tensile strength of 290 MPa (42,060 psi), and tensile yield strength of 220 MPa (31,908 psi) with elongations of 8% or greater.
- A variety of alternate alloys exist and are registered that exhibit higher strength than the Al—Si7—Mg alloys. However these exhibit problems in castability, corrosion potential or fluidity that are not readily overcome. The alternate alloys are therefore less suitable for use.
- Where high strength is required, forged products are often used. These are usually more expensive than cast products. There exists the potential for considerable cost savings if cast products can be used to replace forged products with no loss of strength, elongation, corrosion resistance, fatigue strength, etc. This is true in both automotive and aerospace applications.
- Casting alloys exhibiting higher tensile strength and fatigue resistance than the Al—Si7—Mg material are desirable. Such improvements could be used to reduce weight in new parts or in existing parts which can be redesigned to use the improved material properties to great advantage.
- The alloy of the present invention is an Al—Zn—Mg base alloy for low pressure permanent or semi-permanent mold, squeeze, high pressure die, pressure or gravity casting, lost foam, investment casting, V-mold, or sand mold casting with the following composition ranges (all in weight percent):
- Zn: about 3.5-5.5%,
- Mg: about 1-3%,
- Cu: about 0.05-0.5%,
- Si: less than about 1.0%,
- Fe and other incidental impurities: less than about 0.30%,
- Mn: less than about 0.30%.
- Silicon up to about 1.0% may be employed to improve castability. Lower levels of silicon may be employed to increase strength. For some applications, manganese up to about 0.3% may be employed to improve castability. In other alloys, manganese is to be avoided.
- The alloy may also contain grain refiners such as titanium diboride, TiB2 or titanium carbide, TiC and/or anti-recrystallization agents such as zirconium or scandium. If titanium diboride is employed as a grain refiner, the concentration of boron in the alloy may be in a range from 0.0025% to 0.05%. Likewise, if titanium carbide is employed as a grain refiner, the concentration of carbon in the alloy may be in the range from 0.0025% to 0.05%. Typical grain refiners are aluminum alloys containing TiC or TiB2.
- Zirconium, if used to prevent grain growth during solution heat treatment, is generally employed in a range below 0.2%. Scandium may also be used in a range below 0.3%.
- In the T6 temper, the alloy demonstrated 50% higher tensile yield strength than is obtainable from A356.0-T6, while maintaining similar elongations. This will allow part designs requiring higher strength than alloys which are readily available today in Al—Si—Mg alloys such as A356.0-T6 or A357.0-T6. Fatigue performance in the T6 temper is increased over the A356.0-T6 material by 30%.
- In one aspect, the present invention is an aluminum alloy including from about 3.5-5.5% Zn, from about 1-3% Mg, about 0.05-0.5% Cu and it contains less than about 1% Si.
- In another aspect, the present invention is a heat treatable shaped casting of an aluminum alloy including from about 3.5-5.5% Zn, from about 1-3% Mg, from about 0.05-0.5% Cu, and less than about 1% Si.
- In another aspect, the present invention is a method of preparing a heat treatable aluminum alloy shaped casting. The method includes preparing a molten mass of an aluminum alloy including from about 3.5-5.5% Zn, from about 1-3% Mg, from about 0.05-0.5% Cu, and less than about 1% Si. The method further includes casting at least a portion of the molten mass in a mold configured to produce the shaped casting, permitting the molten mass to solidify, and removing the shaped casting from the mold.
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FIG. 1 is a photograph of a cut surface of a cut sample of prior art A356.0 alloy cast in a shrinkage mold showing the shrinkage cracking tendency of the prior art A356.0 alloy; -
FIG. 2 is a photograph, similar toFIG. 1 , of a cut surface of a second sample of prior art A356.0 cast in a shrinkage mold showing the shrinkage cracking tendency of the prior art A356.0 alloy; -
FIG. 3 is a photograph of a cut surface of a sample of the alloy of the present invention cast in a shrinkage mold showing a lack of shrinkage cracking; and -
FIG. 4 is a photograph, similar toFIG. 3 , of a cut surface of a second sample of the alloy of the present invention cast in a shrinkage mold showing a lack of shrinkage cracking. -
FIG. 5 presents strength and elongation data for directionally solidified samples of the present invention in T6 condition; -
FIG. 6 is a photograph of a front knuckle casting of an alloy according to the present invention, showing locations from which tensile test samples were obtained; -
FIG. 7 is a plot of strength and elongation data for tensile test samples cut from the casting shown inFIG. 6 after T5 and also after T6 heat treatments; -
FIG. 8 is a graph showing the S-N fatigue response (ASTM E 466 testing, R=−1) of the present alloy in T6 condition compared to the response of prior art A356.0-T6. -
FIG. 9 is a graph showing staircase fatigue testing of the present alloy in T6 condition compared to the response of prior art A356.0-T6 with the mean fatigue strength for A356.0-T6. -
FIG. 10 is a graph showing depth of attack after an intergranular corrosion test of the alloy of the present invention compared to the prior art alloy A356. -
FIG. 11 is a photomicrograph of an alloy according to the present invention after an intergranular corrosion test, on the as cast side of the sample. -
FIG. 12 is a photomicrograph of an alloy according to the present invention after an intergranular corrosion test, on a machined side of the sample. -
FIG. 13 is a photomicrograph of the prior art alloy A356 after an intergranular corrosion test. -
FIG. 14 is a graph presenting results of a stress corrosion test on alloys of the present invention, with varied levels of copper. -
FIG. 15 is a graph showing the effect of copper and magnesium levels on stress corrosion cracking for alloys of the present invention. - When referring to any numerical range of values herein, such ranges are understood to include each and every number and/or fraction between the stated range minimum and maximum. A range of about 3.5 to 5.5 wt % zinc, for example, would expressly include all intermediate values of about 3.6, 3.7, 3.8 and 3.9%, all the way up to and including 5.3, 5.35, 5.4, 5.475 and 5.499% Zn. The same applies to each other numerical property and/or elemental range set forth herein.
- Table I presents composition data for the alloys which were tested. The first and third lines showing compositions is for directionally solidified castings. The second line is for the composition used in a shaped casting. The shaped casting was the front knuckle shown in
FIG. 6 .TABLE I Alloy Composition Composition of test samples (Weight %) Zn Mg Si Cu Mn Fe Ti B DS Casting 4.28 1.99 0.04 0.01 0.00 0.04 0.00 0.0005 Cast 4.2 2 <0.1 0.2 0.05 <0.1 0.06 0.02 Knuckle DS Casting 4.57 2.03 0.04 0.31 0.04 0.05 0.06 0.02 - Table II presents room temperature mechanical properties of the directionally solidified alloys having the compositions shown in the first and third data lines of Table I. The first data line in Table II is for a directionally solidified casting comprised of the alloy of the first data line in Table I after five weeks of natural ageing. The second data line in Table 2 is for the same alloy after T5 heat treatment, and the third data line is for that alloy after T6 heat treatment. The fourth and fifth data lines in Table II are for the alloy in the bottom line of Table 1, which is a high copper alloy. This alloy, also, was subjected to a T6 heat treatment.
TABLE II DS casting room temperature mechanical properties Temper TYS (MPa) UTS (MPa) El (%) F 5 (5 weeks natural ageing) 185 322 18 T5 245 323 14 T6 338 359 7 T6 (High Cu) 382 424 12 Cooling rate: 1° C./sec T6 (High Cu) 372 412 9 Cooling rate: 0.2° C./sec - The development of mechanical properties of directionally solidified samples of the present invention during heat treatment is presented in
FIG. 5 . The composition of these samples was presented in the first data row in Table 1. The solution heat treatment was at 1030° F. (554° C.) for 8 hours, which was followed by the cold water quench, and then artificial ageing. Samples were taken out of the oven and subjected to mechanical testing after various amounts of artificial ageing. The properties measured were TYS, UTS and percent elongation. The duration of the artificial ageing was 15 hours. During the first 6 hours, the temperature was 250° F. (121° C.). For the subsequent 9 hours, the temperature was 320° F. (160° C.). Values for the TYS and UTS are referenced to the scale on the left, values of percent elongation are referenced to the scale on the right. - Table III presents data for front knuckle castings as shown in
FIG. 6 . This is an alloy according to the present invention, and has the composition presented in the second data row in Table 1. The locations oftensile test samples FIG. 6 . Tests were performed on one casting subjected to a T5 heat treatment consisting of 160° C. for 6 hours, and one casting subjected to a T6 heat treatment of solution heat treatment at 554° C. for 8 hours followed by a cold water hen by artificial ageing at 121° C. for 6 hours and 160° C. for 6 hours.TABLE III CS front knuckle room temperature mechanical properties Sample Elongation Location Temper TYS MPa US MPa (%) 1 T5 163.4 237.9 6 2 189.6 259.2 5 3 170.3 253.0 10 1 T6 357.8 388.9 6 2 375.8 419.9 11 3 356.5 400.6 13 - It is noted that in Table III, extremely high tensile strength values and good elongation are obtained for the alloy in both T5 and T6 tempers. It is noted, again, that the composition was as presented in the second data line in Table I. The data presented in Table III are plotted in
FIG. 7 . - The graph in
FIG. 8 shows the S-N fatigue response of the alloy of the present invention in comparison to the response of the prior art alloy A356.0-T6. This test was ASTM E466, R=−1. It can be seen that after 100,000 cycles, the alloy of the present invention is markedly superior to the prior art alloy.FIG. 9 is a graph showing staircase fatigue testing of the alloy of the present invention in T6 condition compared to the response of the prior art alloy, A356.0-T6 with a calculated mean value for A356.0-T6. The composition of the alloy of the present invention was as presented in the second data row of Table 1. - The samples were solution heat treated at 526° C. or 554 ° C., quenched and artificially aged at 160° C. for 6 hours. As seen earlier, the fatigue response of these samples is appreciably improved when compared to A356.0-T6 material.
- The mean fatigue strength of the alloy of the present invention was 109.33 MPa with a standard deviation of 9.02 MPa. The standard deviation of the mean fatigue strength was 3.01 MPa. The calculated mean fatigue strength at 107 cycles of A356.0 T6 is 70 MPa.
- Corrosion resistance of the alloy of the present invention was tested using the ASTM G110 corrosion test, which is the “Standard Practice for Evaluating Intergranular Corrosion Resistance of Heat Treatable Aluminum Alloys by Immersion in Sodium Chloride+Hydrogen Peroxide Solution”.
- In this test, specimens are immersed in a solution that contains 57 g/L NaCl and 10 mL/L H2O2 (30%) for 6-24 hours. The specimens are then cross-sectioned and examined under optical microscope for type (intergranular corrosion or pitting) and depth of corrosion attack.
-
FIG. 10 is a graph presenting the depth of attack following the ASTM G110 corrosion test after 6 hours and 24 hours for an alloy according to the present invention and for the alloy A356.0. -
FIGS. 11 and 12 are photomicrographs of an alloy according to the present invention after 24 hours exposure to the ASTM G110 corrosion test. Very little intergranular corrosion can be seen in these photomicrographs. -
FIG. 13 is a photomicrograph of the A356.0 alloy after 24 hours of exposure to the ASTM G110 corrosion test. Considerable intergranular corrosion can be seen in this photomicrograph. - Corrosion tests were also performed employing the ASTM G44 test, which is the “Standard Practice for Exposure of Metals and Alloys by Alternate Immersion in Neutral 3.5% Sodium Chloride Solution”. In this test, stressed specimens are subject to a 1-hour cycle which includes immersion in 3.5% NaCl solution for 10 minutes and then in lab air for 50 minutes. This 1-hour cycle is continuously repeated. During the test, the specimens are regularly inspected for cracks and failures.
- Table IV presents the compositions of various alloys according to the present invention, which were employed in ASTM G44 tests.
TABLE IV Alloy Composition Sample Number Zn Mg Cu Ti B Zr 59 4.23 1.5 0.29 0.029 0.0055 <0.001 86 4.41 1.49 0.23 0.036 0.0038 n/a 110 4.39 1.74 0.28 0.057 0.0129 <0.001 117 4.39 1.74 0.28 0.057 0.0129 <0.001 138 4.19 1.99 0.26 0.073 0.015 <0.001 159 4.31 1.93 0.24 0.105 0.0252 0.1127 A 4.43 2.05 0.06 0.0208 B 4.5 2 0.2 0.06 0.02 n/a C 4.5 1.2 D 4.5 1.2 - Table V presents the test results for the alloy compositions presented in Table IV.
TABLE V ASTM G44 Test of Alloys with Various Mg and Cu Contents Run or S Stress Percentage Days to Number Temper Level(MPa) of TYS F/N Failure 59 (Knuckle) T5 152.37 75% 0/5 86 (Knuckle) T6 239.25 75% 4/5 17, 17, 22, 28 110 (Knuckle) T5 154.44 75% 0/5 117 (Knuckle) T6 196.50 75% 0/5 138 (Knuckle) T6 247.52 75% 2/5 45, 61 159 (Knuckle) T6 270.27 75% 3/5 11, 11, 11 A T5 186.16 75% 5/5 4, 4, 4, 7, 64 B T6 182.02 50% 4/4 7, 11, 13, 19 C T5 135.83 75% 0/5 D T6 194.43 75% 0/5 -
FIG. 14 is a graph presenting the results of these tests. It is seen that, for alloys of the present invention, and at these high magnesium levels, increasing copper provides increased resistance to stress corrosion cracking. -
FIG. 15 is a graph showing the effect of copper and magnesium levels on stress corrosion cracking for alloys of the present invention. This shows that for alloys according to the present invention which have magnesium in the range from 1.5-2%, it is desirable to include copper in the range from0.25-0.3%. - Table VI and VII present the results of plant trials in which repeated shots were made from a single liquid metal reservoir. One trial was performed on April 4, one was performed on June 4 and one on September 4. On each day, the composition for all the castings made varied very little.
- Table VI presents the ranges of the compositions of samples taken on each of the test days. The compositions contained high levels of magnesium and copper, which were expected to provide exceptionally high strength levels.
TABLE VI MCC plant trial alloy composition ranges Date Si Fe Mn Cu Mg Zn Ti B Zr Apr- 0.05-0.09 0.03-0.04 0.03-0.04 0.22-0.27 1.9-2.2 4.1-4.7 0.03-0.06 0.001-0.0007 0.00-0.15 04 Jun- 0.03-0.09 0.04-0.08 0.04-0.05 0.24-0.29 1.5-2.0 4.6-4.9 0.03-0.11 0.008-0.025 0.00-0.12 04 Sep- 0.04-0.05 0.14-0.20 0.03-0.04 0.27-0.32 2.1-2.3 4.4-4.9 0.04-0.07 0.0006-0.0037 0.13-0.14 04 - Table VII presents the stress data, ultimate tensile strength, tensile yield strength, and elongation for four different locations in each casting. The column for sample numbers labels the individual castings. The column for location defines individual mechanical test samples cut from the casings.
TABLE VII Plant trial mechanical properties UTS YTS Elong. UTS YTS Elong. Sample Location (MPa) (MPa) (%) Sample Location (MPa) (MPa) (%) April 2004 tests June 2004 tests 1-019 1 337 269 9.9 86 1 268 216 9.3 1-019 2 386 349 9.5 86 2 359 321 9.2 1-019 3 375 357 3.1 86 3 319 294 6.7 1-019 4 405 365 10.6 86 4 366 339 6.7 1-024 1 345 301 8.1 117 1 238 193 12.3 1-024 2 384 355 8.2 117 2 305 254 14.6 1-024 3 388 359 6.3 117 3 291 244 8.5 1-024 4 406 370 9.7 117 4 331 286 8.4 2-007 1 371 330 4.7 138 1 264 198 8.9 2-007 2 382 340 8.2 138 2 367 320 8.8 2-007 3 381 352 5.5 138 3 343 308 7.5 2-007 4 419 378 9.25 138 4 375 341 8.9 2-024 1 349 301 8.5 138 1L 373 334 6.6 2-024 2 381 340 9.25 138 1U 356 333 6.4 2-024 3 369 342 3.7 159 1 326 265 9.7 2-024 4 408 370 11.7 159 2 392 352 11.7 3-165 1 331 268 10.1 159 3 368 339 7.2 3-165 4 436 382 8.85 159 4 404 369 9.3 1-014 1 371 335 6.1 159 1L 407 359 9.2 1-014 2 392 352 8.4 159 1U 413 375 7.9 1-014 3 348 318 5.1 166 4 393 354 7.2 1-014 4 392 357 7.5 Sep 2004 Tests 79 1 326 267 12.4 129 1 330.5 270.5 11 79 2 385 338 9 129 2 351.5 296.5 5 79 3 401 356 9.8 129 3 369 316 11 79 4 387 357 5.6 129 4 387.5 352.5 6 53 1 355 303 12.9 151 1 284 269 4 53 2 396 343 10.8 151 2 349 302 10 53 3 396 349 9.5 151 3 380.5 334.5 10 53 4 404 371 5.7 151 4 378 365.5 4 48 1 361 305 11.6 152 1 364.5 311.5 10 48 2 393 342 11.1 152 2 386 349 6 48 3 395 350 8.85 152 3 351 320 3 - It is noted that at these high levels of magnesium and copper, excellent strength levels are obtained, with good elongation.
- Having described the presently preferred embodiments of the present invention, it is to be understood that the invention may be otherwise embodied within the scope of the appended claims.
Claims (27)
Priority Applications (9)
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US11/111,212 US20050238528A1 (en) | 2004-04-22 | 2005-04-21 | Heat treatable Al-Zn-Mg-Cu alloy for aerospace and automotive castings |
AU2005238479A AU2005238479A1 (en) | 2004-04-22 | 2005-04-22 | Heat treatable Al-Zn-Mg-Cu alloy for aerospace and automotive castings |
EP05738780A EP1759027A4 (en) | 2004-04-22 | 2005-04-22 | Heat treatable al-zn-mg-cu alloy for aerospace and automotive castings |
JP2007509667A JP2007534840A (en) | 2004-04-22 | 2005-04-22 | Heat-treatable Al-Zn-Mg-Cu alloys for aerospace and automotive castings |
PCT/US2005/013769 WO2005106058A2 (en) | 2004-04-22 | 2005-04-22 | Heat treatable al-zn-mg-cu alloy for aerospace and automotive castings |
MXPA06012243A MXPA06012243A (en) | 2004-04-22 | 2005-04-22 | Heat treatable al-zn-mg-cu alloy for aerospace and automotive castings. |
CA002564080A CA2564080A1 (en) | 2004-04-22 | 2005-04-22 | Heat treatable al-zn-mg-cu alloy for aerospace and automotive castings |
KR1020067024490A KR20070004987A (en) | 2004-04-22 | 2005-04-22 | Heat treatable al-zn-mg-cu alloy for aerospace and automotive castings |
NO20065387A NO20065387L (en) | 2004-04-22 | 2006-11-22 | Heat-treated Al-Zn-Mg alloy for stuffing for the aviation and automotive industry |
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US56481304P | 2004-04-22 | 2004-04-22 | |
US11/111,212 US20050238528A1 (en) | 2004-04-22 | 2005-04-21 | Heat treatable Al-Zn-Mg-Cu alloy for aerospace and automotive castings |
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US11/111,212 Abandoned US20050238528A1 (en) | 2004-04-22 | 2005-04-21 | Heat treatable Al-Zn-Mg-Cu alloy for aerospace and automotive castings |
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US (1) | US20050238528A1 (en) |
EP (1) | EP1759027A4 (en) |
JP (1) | JP2007534840A (en) |
KR (1) | KR20070004987A (en) |
AU (1) | AU2005238479A1 (en) |
CA (1) | CA2564080A1 (en) |
MX (1) | MXPA06012243A (en) |
NO (1) | NO20065387L (en) |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4873054A (en) * | 1986-09-08 | 1989-10-10 | Kb Alloys, Inc. | Third element additions to aluminum-titanium master alloys |
US20010028861A1 (en) * | 1997-12-17 | 2001-10-11 | Que-Tsang Fang | High strength Al-Zn-Mg alloy for making shaped castings including vehicle wheels and structural components |
US20040115087A1 (en) * | 2000-12-12 | 2004-06-17 | Axenov Andrei Anatolyevich | Aluminum-based material and a method for manufacturing products from aluminum-based material |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2240940A (en) * | 1940-09-28 | 1941-05-06 | Aluminum Co Of America | Aluminum alloy |
DE900499C (en) * | 1941-01-12 | 1953-12-28 | Ver Deutsche Metallwerke Ag | Payable corrosion-resistant wrought aluminum-zinc-magnesium alloys |
FR1343246A (en) * | 1962-12-26 | 1963-11-15 | Ver Leichtmetallwerke Gmbh | Use of a malleable aluminum alloy with little or no copper content |
GB1186161A (en) * | 1966-04-07 | 1970-04-02 | High Duty Alloys Ltd | Improvements in or relating to the Heat Treatment of Aluminium Alloys |
GB1218516A (en) * | 1968-12-27 | 1971-01-06 | Aluminum Co Of America | Clad aluminum base alloy |
US3694272A (en) * | 1970-12-24 | 1972-09-26 | Kaiser Aluminium Chem Corp | Method for forming aluminum sheet |
US3945861A (en) * | 1975-04-21 | 1976-03-23 | Aluminum Company Of America | High strength automobile bumper alloy |
JPS5383913A (en) * | 1976-12-29 | 1978-07-24 | Kobe Steel Ltd | Al-zn-mg cast alloy for welded structure |
JPS62250149A (en) * | 1986-04-24 | 1987-10-31 | Kobe Steel Ltd | Aluminum alloy for bicycle |
CA2091355A1 (en) * | 1990-08-22 | 1992-02-23 | James Christopher Mohr | Aluminium alloy suitable for can making |
EP1229141A1 (en) * | 2001-02-05 | 2002-08-07 | ALUMINIUM RHEINFELDEN GmbH | Cast aluminium alloy |
FR2846669B1 (en) * | 2002-11-06 | 2005-07-22 | Pechiney Rhenalu | PROCESS FOR THE SIMPLIFIED MANUFACTURE OF LAMINATED PRODUCTS OF A1-Zn-Mg ALLOYS AND PRODUCTS OBTAINED THEREBY |
-
2005
- 2005-04-21 US US11/111,212 patent/US20050238528A1/en not_active Abandoned
- 2005-04-22 JP JP2007509667A patent/JP2007534840A/en active Pending
- 2005-04-22 EP EP05738780A patent/EP1759027A4/en not_active Withdrawn
- 2005-04-22 AU AU2005238479A patent/AU2005238479A1/en not_active Abandoned
- 2005-04-22 KR KR1020067024490A patent/KR20070004987A/en not_active Application Discontinuation
- 2005-04-22 WO PCT/US2005/013769 patent/WO2005106058A2/en active Search and Examination
- 2005-04-22 MX MXPA06012243A patent/MXPA06012243A/en unknown
- 2005-04-22 CA CA002564080A patent/CA2564080A1/en not_active Abandoned
-
2006
- 2006-11-22 NO NO20065387A patent/NO20065387L/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4873054A (en) * | 1986-09-08 | 1989-10-10 | Kb Alloys, Inc. | Third element additions to aluminum-titanium master alloys |
US20010028861A1 (en) * | 1997-12-17 | 2001-10-11 | Que-Tsang Fang | High strength Al-Zn-Mg alloy for making shaped castings including vehicle wheels and structural components |
US20040115087A1 (en) * | 2000-12-12 | 2004-06-17 | Axenov Andrei Anatolyevich | Aluminum-based material and a method for manufacturing products from aluminum-based material |
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Also Published As
Publication number | Publication date |
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JP2007534840A (en) | 2007-11-29 |
CA2564080A1 (en) | 2005-11-10 |
KR20070004987A (en) | 2007-01-09 |
MXPA06012243A (en) | 2007-01-31 |
AU2005238479A1 (en) | 2005-11-10 |
EP1759027A4 (en) | 2007-10-03 |
WO2005106058A3 (en) | 2006-09-14 |
WO2005106058A2 (en) | 2005-11-10 |
NO20065387L (en) | 2007-01-17 |
EP1759027A2 (en) | 2007-03-07 |
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