US20030053932A1

US20030053932A1 - Ozone generator

Info

Publication number: US20030053932A1
Application number: US09/317,362
Authority: US
Inventors: Robert G. Khatchatrain; Ashot P. Khatchatrain; Asmik Aruntyunyan; Morev Sergey Nikolaevich
Original assignee: Hartz International Inc
Current assignee: Hartz International Inc
Priority date: 1997-10-23
Filing date: 1999-05-24
Publication date: 2003-03-20
Also published as: AU751897B2; US5911957A; WO1999020388A2; CN1193795C; HK1033745A1; JP2001520161A; CN1277557A; EP1042062A2; AU1113699A; KR20010015789A; WO1999020388A3

Abstract

The present invention relates to methods and forms of apparatus for sterilizing various objects with ozone. The contents of a container may be sterilized by attaching a lid with an ozone generator to the container and generating ozone. Clothing may be treated by attaching the clothing to an ozone generator with a housing in the shape of a clothes hanger and generating ozone. Alternatively, the ozone generator in the shape of a clothes hanger may be placed in a closet with clothing to be treated. The power supply for the ozone generator may be a portable power supply, or power may be supplied from an adapter from an electrical outlet. Shoes may be deodorized by placing an ozone generator with an oblong shape in the shoes and generating ozone. A medical device may be sterilized by attaching the medical device to a sterilizing tip attached to a tubular screen, where the tubular screen is attached to the tip at one end and to an ozone generator at the other end, energizing the ozone generator and passing an oxygen-containing gas through the ozone generator to generate ozone.

Description

BACKGROUND OF THE INVENTION

Ozone is a powerful oxidizing agent that has many industrial and household uses. Ozone effectively kills bacteria, inhibits fungal growth, and inactivates many viruses, cysts, and spores. In addition, soaps, oils, and chloramines can be rendered environmentally safe by ozone treatment. The antiseptic properties of ozone are useful for water purification, room sanitation, equipment sterilization, and food preservation.

There are several known methods for producing ozone from air or other oxygen-containing gases. A number of these processes generate ozone by passing an oxygen-containing gas between two electrodes, separated by a dielectric material—the oxygen is converted to ozone as it travels through the electrical corona. Ozone has a half-life of only about 22 minutes at ambient temperatures, and at higher temperatures the rate of ozone decay is accelerated. An efficient ozone generator should, therefore, produce a high concentration of ozone without generating appreciable heat.

To this aim, several modifications on the basic corona discharge ozone generator have been developed. U.S. Pat. No. 5,409,673 relates to an ozone generator characterized by an outer electrode overlying a portion of a dielectric tube filled with a mass of helical windings which serves as an inner electrode. Similarly, U.S. Pat. No. 5,554,344 teaches the enhancement of ozone production by employing electrodes with a jagged surface while U.S. Pat. No. 4,981,656 teaches that an electrode of polygonal shape provides uniform gas discharge at low electrical voltages. Furthermore, with regard to heat dissipation, U.S. Pat. No. 4,770,858 teaches the benefits of coating the surface of a dielectric tube with non-conductive particles of inorganic material.

Despite the numerous beneficial applications for ozone and repeated attempts in the prior art to invent an efficient ozone generator, such a discovery has not yet occurred. The failure of the prior art to provide an efficient ozone generator can be attributed to three persistent problems: improperly aligned electrodes, accumulation of heat generated by the electrical discharge, and the lack of a means to direct freshly made ozone away from the apparatus to a site intended for treatment. The need for a simple and compact apparatus which efficiently produces and rapidly disperses ozone without accumulating an appreciable amount of heat is manifest.

SUMMARY OF THE INVENTION

The present invention discloses a new apparatus and method for producing ozone by electrical silent discharge. As disclosed herein, an ozone generator, is comprised of a silent discharge means joined to a reflecting shield. The discharge means comprises a rough-surfaced dielectric element of rectangular shape, a first electrode, and a second electrode. The dielectric element is sandwiched between the first electrode and the second electrode and both electrodes are connected to a high frequency (HF) converter.

The first electrode is comprised of a plurality of helical windings that contact a plurality of flanges on the dielectric element and the second electrode is comprised of an electrically conductive coating which overlies the rough surface of the dielectric element. The rectangular shape of the dielectric element facilitates the alignment of the electrodes, and the flanges maintain this aligned position. The fusion of the second electrode with the surface of the dielectric element significantly improves ozone recovery by rapidly dispersing heat as it is generated, and the reflecting screen directs accumulated ozone away from the ozone generator and toward an intended site for treatment.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a sectional side view of a first embodiment of a silent discharge means attached to a HF converter, taken at arrow [0007] 1 of FIG. 2.
FIG. 2 is a cross-sectional view of the first embodiment of the silent discharge means. [0008]
FIG. 3 is a cross-sectional view of a second embodiment of the discharge means. [0009]
FIG. 4 is a perspective view of a first embodiment of an ozone generator according to the present invention (without reflecting screen). [0010]
FIG. 5 is a sectional view of a second embodiment of the ozone generator according to the present invention. [0011]
FIG. 6 is a sectional view of a third embodiment of the ozone generator according to the present invention. [0012]
FIG. 7 is a sectional view of a fourth embodiment of the ozone generator according to the present invention. [0013]
FIG. 8 is a sectional view of a fifth embodiment of the ozone generator according to the present invention.[0014]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The present invention will be described more fully hereinafter with reference to the accompanying drawings, in which preferred embodiments of the invention are shown. This invention may be embodied in many different forms, however, and should not be construed as limited to the embodiments set forth within. Applicants provide these embodiments so that this disclosure will be thorough and complete, and willfully convey the scope of the invention to those skilled in the art. [0015]
As shown in FIGS. [0016] 1-8, an ozone generator is comprised of a discharge means 24 optionally connected to a reflecting screen 22. The discharge means 24 is connected to a high frequency converter (HF converter) 58 which is in turn connected to a power supply 20. The power supply 20 is either a storage battery (FIG. 6, 8) or normal line current from an electrical network (110 or 220 volts) (FIG. 4, 5, 7). Optional electrical leads 28 may be used to connect the high frequency converter 58 to the discharge means 24 and the power supply 20. FIGS. 1-3 reveal that the discharge means 24 is comprised of a rough-surfaced dielectric element 34 of rectangular shape, a central aperture 44, a first electrode 32, a second electrode 36, and a plurality of flanges 30. The electrodes 32 and 36 are attached to the high frequency (HF) converter 58, which is in turn attached to the power supply 20. The power supply is either a battery or line current from an electrical network.
In a first embodiment of the discharge means [0017] 24, illustrated in FIGS. 1 and 2, the first electrode 32 is comprised of a plurality of helical windings that are mounted inside the central aperture 44 in an aligned position. Alignment of the first electrode 32 with respect to the central aperture 44, dielectric element 34, and the second electrode 36 is necessary to ensure uniform discharge at low voltages and to reduce the accumulation of heat at the dielectric element 34 and the electrodes 32 and 36. As used in this disclosure, the intended meaning of the word alignment and derivatives thereof encompasses the position of the first electrode 32 with respect to the central aperture 44, the dielectric element 34, and the placement of the first electrode 32 in a manner that maintains a constant distance of separation between the electrodes 32 and 36 along the entire length of the discharge means 24. The rectangular shape of the dielectric element 34 facilitates the determination of the position of the alignment of the first electrode 32, and flanges 30 hold the first electrode 32 in the properly aligned position. The helical windings of the first electrode 32 comprise a spiral shape. The first electrode is held in position inside the dielectric element 34 through the elastic nature or spring-like behavior of the spiral. The first electrode 32 is generally the same length as the dielectric element 34, although a first electrode 32 of any size can be constructed and mounted within a larger-sized dielectric element 34. The first electrode 32 of the first embodiment of the discharge means 24 may have 1 winding per cm to 100 windings per cm, or more desirably 2 windings per cm to 50 windings per cm, or preferably 2 windings per cm to 20 windings per cm. Similarly, the diameter of the filament used to construct the helical windings for this embodiment may include 0.001 mm to 1 mm, or more desirably 0.01 mm to 0.5 mm, or preferably 0.1 mm to 0.14 mm. The helical windings of the first electrode 32 can be made from tungsten, nickel-chromium alloy, molybdenum, or other suitable metals.
The [0018] flanges 30 which hold the first electrode 32 in an aligned position may be part of a single-piece dielectric element 34 or, alternatively, may be comprised of a material different than the dielectric element 34 and attached to the dielectric element 34 by conventional methods. The dimensions of the flanges 30 and their spacing within the central aperture 44 may depend on the type of ozone generator and its intended application. The dielectric element 34 may contain from 4 to 20 flanges 30, or desirably 4 to 10 flanges 30, or preferably 4 to 6 flanges 30.
The [0019] second electrode 36 of the first embodiment of the discharge means 24 comprises an electrically conductive coating that overlies the rough outer surface of the dielectric element 34. Suitable electrically conductive coatings include copper, silver, and aluminum, although one of skill in the art would be able to develop and/or use many equivalent coatings to fulfill the intended purpose of this element of the present invention. The electrically conductive coating can be applied by being sprayed or chemically deposited to a thickness of 0.1 microns to 100 microns or more desirably from 0.5 microns to 50 microns or preferably from 2 to 10 microns. The second electrode 36 preferably spans the entire length of the dielectric element 34, or alternatively, may overlay only a portion of the dielectric element 34.
The [0020] dielectric element 34 can be made from ceramic, but it is within the skill of anyone in the art to manufacture a dielectric element from many other suitable materials such as glass or PYREX. Alternatively, the surface of the dielectric element 34 facing the first electrode 32 can be a composite structure constructed of materials having different dielectric permeability and porosity such as ceramic and glass fiber. The thickness of the dielectric element 34 and the dimensions of the central aperture 44 may vary according to the apparatus and intended application, but, in general, the electrodes 32 and 36 are separated by a dielectric element 34 having a thickness of 0.01 mm to 10 mm or, more desirably, 0.05 mm to 2 mm or preferably 0.1 mm to 0.7 mm, and the central aperture 44 can have a diameter of 0.1 mm to 20 mm, more preferably 1 mm to 10 mm, and most preferably from 2 mm to 6 mm.
The [0021] dielectric element 34 has a rough surface which serves as the foundation for the second electrode 36, once the dielectric element 34 is overlaid with the electrically conductive coating serving as the second electrode 36. The rough surface on the dielectric element 34 can be made by sanding, chemical treatment, or by embedding the surface with electrically non-conductive particles. Particles suitable for embedding the surface of the dielectric element are glass or ceramic, but many equivalent particles would be known by one of skill in the art. Furthermore, there are many ways to create a dielectric element 34 with a rough surface, and any person of skill in the art could develop alternative means to fulfill this purpose of the invention. Discharge at low voltages is improved by the rough surface of the second electrode 36, and the intimate association of the second electrode 36 with the dielectric element 34 enables the rapid dispersion of heat generated by the discharge means 24.
The construction of the first embodiment of the discharge means [0022] 24 can be used to guide one of skill in the art to make and use the second embodiment of the discharge means 24, illustrated in FIG. 3. In the second embodiment, the first electrode 32 spirals around the outside of the dielectric element 34, and the dielectric element 34 has a central aperture 44 with a rough interior surface. Furthermore, the electrically conductive coating of the second electrode 36 overlies the rough surface inside the central aperture 44. The first electrode 32 is aligned with respect to the central aperture 44 and the second electrode 36, and flanges secure the first electrode 32 to the dielectric element 34 in the aligned position. The first electrode 32 of the second embodiment of the discharge means 24 may have 1 winding per cm to 100 windings per cm, or more desirably 2 windings per cm to 50 windings per cm, or preferably 2 windings per cm to 20 windings per cm. Similarly, the filament used to construct the helical windings for this embodiment has a diameter of 0.001 mm to 1 mm, or more desirably 0.01 mm to 0.5 mm, or preferably 0.1 mm to 0.14 mm. The helical windings of the first electrode 32 may be made from tungsten, nickel-chromium alloy, molybdenum, or other suitable metals.
The fabrication of reflecting [0023] screens 22 to accompany the embodiments illustrated in FIGS. 5-8 can be accomplished through routine experimentation by one of skill in the art given the disclosure that follows. Reflecting screens 22 are generally made from plastic or metal, but they can also be constructed from many other materials known to those of skill in the art. In FIG. 5, the reflecting screen 22 is a parabolic shape, and the dielectric element 34 of the discharge means 24 is joined to the reflecting screen 22 by a plurality of mounting brackets 26. Mounting brackets 26 can include many types of connectors whose compositions are frequently made of plastic but can be comprised of any other insulating material. By placing the discharge means 24 within the focus of the parabola of the reflecting screen 22, the flow of ozone can be directed to a site intended for sterilization.
FIG. 4 shows a first embodiment of the ozone generator in which the discharge means [0024] 24 is enclosed within a discharge housing 54. A switch 48 is connected to a high frequency converter 58 that joins to the power supply 20 and the discharge means 24. In the embodiment shown in FIG. 4, the power supply 20 is line current from an electrical network. A light emitting diode 50 is also connected to the high frequency converter 58 and indicates the operation of the ozone generator. A source of oxygen can be attached to an inlet 62 so that ozone can be generated as the oxygen passes through the discharge means 24. Alternatively, the inlet 62 can be attached directly to the dielectric element 34 when using an embodiment of the invention with a hollow dielectric element, such as one with an internal electrode 32. The ozone exits the ozone generator through a sterilizing tip 64 which is constructed so that a variety of objects can be attached and sterilized. Objects which can be attached to the sterilizing tip of this embodiment include catheters, tubing, needles, bottles, and syringes. The sterilization of many other items can be achieved by this embodiment, and the sterilization tip 64 can be modified by one of skill in the art to accommodate a multitude of medical devices.
Alternatively, as shown in FIG. 5 (embodiment 2), mounting [0025] brackets 26 and a protective shield 38 secure the discharge means 24 to a reflecting screen 22 shaped like a lid to a container. By placing this embodiment of the ozone generator over a matching container, items placed inside the container can be sterilized. According to this aspect of the present invention, an upper compartment 56 of the ozone generator houses a switch 48 joined to the timer 46, a light emitting diode 50, and a high frequency converter 58 (shown in phantom lines) joining the power source 20 and the discharge means 24. In this case, the power source is line current from an electrical network. The discharge means 24 is mounted in a lower compartment 60 of the ozone generator, and the reflecting screen 22 forms a barrier between the two compartments. By opening the switch 48, the timer 46 is set, and current from the power supply 20 is transferred through the high frequency converter 58 to the electrodes 32 and 36 and the light emitting diode 50. The light emitting diode indicates that the ozone generator is in operation. When the set time expires, the current to the high frequency converter 58, the electrodes 32 and 36, and the light emitting diode 50 is removed.
The ozone generator illustrated in FIG. 6 is constructed similarly to the embodiment shown in FIG. 5 but takes the shape of a clothes hanger and provides a means to sterilize articles of clothing. As described above, the power supply [0026] 20 (shown in phantom lines), switch 48 (not shown), timer 46 (shown in phantom lines), high frequency converter 58, and light emitting diode 50 are isolated from the discharge means 24 by a barrier created by the reflecting screen 22. In this case, the power supply 20 is a battery.
Although the embodiment set forth in FIG. 7 is fabricated in much the same manner as the ozone generators described above, an [0027] adapter 52 attached to the high frequency converter 58 enables a user to draw current directly from an electrical outlet. A photo-cell 51 allows for automatic on/off switching depending on the light level. For example, the ozone generator can be set to operate automatically at night. The ozone generator pictured in FIG. 7 provides an efficient and economical means to deodorize or sanitize a room.
The apparatus shown in FIG. 8 can be used to deodorize shoes. This ozone generator is constructed in the same manner as the embodiments shown in FIGS. [0028] 5-7, but it is shaped so that the apparatus can be placed in a shoe.
Many modifications and other embodiments of the invention will come to the mind of one skilled in the art having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the invention is not to be limited to the specific embodiments disclosed, and that modifications and embodiments are intended to be included within the scope of the appended claims. [0029]

Claims

What is claimed is:

1. A method for sterilizing the contents of a container comprising:

providing an ozone generator mounted in a housing having the shape of a lid to the container;

depositing materials intended for sterilization in the container;

joining the housing and ozone generator to the container;

energizing the ozone generator with electric power to generate an electric corona; and

passing an oxygen containing gas through the electric corona so as to generate ozone, thereby sterilizing the contents of the container.

2. The method according to claim 1, wherein the ozone generator comprises two electrodes.

3. The method according to claim 2, wherein the ozone generator further comprises a portable power supply, a timer joined to the portable power supply, a switch to the timer, and a high frequency converter joined to the power supply and the electrodes.

4. The method according to claim 3, wherein the ozone generator further comprises an adapter for an electrical outlet.

5. A method for treating clothing with ozone comprising:

providing an ozone generator mounted in a device having the shape of a clothes hanger:

attaching clothing intended for treating to the device having the shape of a clothes hanger.

passing an oxygen containing gas through the electric corona so as to generate ozone, thereby treating the clothing with ozone.

6. The method according to claim 5, wherein the ozone generator comprises two electrodes.

7. The method according to claim 6, wherein the ozone generator further comprises a portable power supply, a timer joined to the portable power supply, a switch joined to the timer, and a high frequency converter joined to the power supply and the electrodes.

8. The method according to claim 7, wherein the ozone generator further comprises an adapter for an electrical outlet.

9. A method for treating clothing in a closet with ozone comprising:

placing the device having the shape of a clothes hanger in the closet with said clothing;

passing an oxygen containing gas through the electric corona so as to generate ozone, thereby treating the clothing in the closet with ozone.

10. The method according to claim 9, wherein the ozone generator comprises two electrodes.

11. The method according to claim 10, wherein the ozone generator further comprises a portable power supply, a timer joined to the portable power supply, a switch joined to the timer, and a high frequency converter joined to the power supply and the electrodes.

12. The method according to claim 11, wherein the ozone generator further comprises an adapter for an electrical outlet

13. A method for deodorizing shoes comprising:

providing an ozone generator with a case of oblong shape;

placing the ozone generator in the case in a shoe;

passing an oxygen containing gas through the electric corona so as to generate ozone, thereby deodorizing the shoe.

14. The method according to claim 9, wherein the ozone generator comprises two electrodes.

15. The method according to claim 14, wherein the ozone generator further comprises a portable power supply, a timer joined to the portable power supply, a switch joined to the timer, and a high frequency converter joined to the power supply and the electrodes.

16. A method for sterilizing a medical device comprising:

providing an ozone generator with a tubular shaped reflecting screen, wherein the screen is connected at a first end to an inlet that can be joined to a source of an oxygen containing gas and at a second end to a sterilizing tip;

joining a source of oxygen containing gas to the inlet;

attaching a medical device to be sterilized to the sterilizing tip;

passing an oxygen containing gas through the electric corona so as to generate ozone, thereby sterilizing the medical device.

17. The method according to claim 16, wherein the ozone generator comprises two electrodes.

18. An apparatus for sterilizing the contents of a container comprising;

an ozone generator;

a housing for the ozone generator having the shape of a lid to the container; and

a power source for the ozone generator.

19. An apparatus for treating clothing with ozone comprising:

an ozone generator;

a housing for the ozone generator having the shape of a clothes hanger; and

a power source for the ozone generator.

20. An apparatus for sterilizing a medical device comprising;

an ozone generator; and

a tubular shaped reflecting screen, said screen having two ends, wherein the screen is connected at a first end to a source of oxygen containing gas and at a second end to a sterilizing tip, wherein the medical device to be sterilized is connected to the sterilizing tip.