US20030005957A1 - Solar energy converter using optical concentration through a liquid - Google Patents
Solar energy converter using optical concentration through a liquid Download PDFInfo
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- US20030005957A1 US20030005957A1 US09/887,416 US88741601A US2003005957A1 US 20030005957 A1 US20030005957 A1 US 20030005957A1 US 88741601 A US88741601 A US 88741601A US 2003005957 A1 US2003005957 A1 US 2003005957A1
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/054—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/054—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
- H01L31/0543—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the refractive type, e.g. lenses
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
Definitions
- Solar energy systems have been used to provide electricity and heat for decades. Designers of all types of energy generation systems continually strive to improve output power efficiency.
- One current problem in a solar cell energy conversion system is the efficient extraction of low-cost electricity.
- the conversion efficiency of a photovoltaic cell is the proportion of sunlight energy that the cell converts to electrical energy. Improving efficiency is vital to producing solar energy systems that are competitive with traditional energy source such as fossil fuels and nuclear power.
- Efficiency of solar energy systems has increases substantially from about 1-2% efficiency in converting sunlight into electrical energy for the earliest photovoltaic devices.
- Current conventional photovoltaic systems convert 7% to 17% of light energy into electrical energy.
- An organic dielectric liquid immersing one or more junction photovoltaic cells increases the efficiency of the photovoltaic cells.
- the organic dielectric liquid also is a highly suitable medium for usage as an optical concentrator.
- the organic dielectric liquid in combination with the junction photovoltaic cells operate as a highly efficient and low-cost optical concentrator.
- the output power of a solar cell or photovoltaic cell is increased by wetting of the surfaces of the cell with a dielectric liquid.
- a solar panel configured as an encapsulation system containing photovoltaic cells and organic dielectric liquid increases the output power of a solar cell or photovoltaic cell.
- the solar panel has a suitable geometry for refracting illumination through the organic dielectric liquid to further enhance the output power efficiency.
- panel walls have suitable transparency for operation as a light beam collector. Illumination collected through the light beam collector refracts through the organic dielectric liquid and enhances the photoelectric effect of the photovoltaic cells.
- wetting of the solar cells with the organic dielectric liquid in combination with configuration of the solar panels as encapsulation system with walls operating as light beam collectors greatly improves output power efficiency and reduces cost per watt.
- the solar panel has a form of a low height dome or cylindrical structure with a substantially flat panel tray covering a first end of the cylinder and a panel cover or lid covering a second end of the cylinder. All or a portion of the panel walls and the panel lid are transparent for functionality as a light collector.
- the horizontal cross-section of the cylinder can have any suitable shape such as a circle, an ellipse, an oval, an egg-shape, a rectangle, a triangle, a square.
- the horizontal cross-section of the cylinder can be symmetric or asymmetric.
- Any organic dielectric liquid is suitable for usage in a solar panel. Greater energy conversion efficiency is attained for a polar organic dielectric liquid with increasing efficiency for liquids with a relatively higher index of refraction.
- the organic dielectric liquid can be further selected based on the melting point and the boiling point of various liquids for solar energy systems according to seasonal weather and climate of practical usage. For example, the liquid can be selected based on values of the lowest and highest temperature of the geographical area in which the solar energy system is used.
- FIG. 1 is a schematic block diagram showing an example of a solar panel in a configuration for improving energy conversion efficiency.
- FIG. 2 is a schematic pictorial diagram that illustrates an example of a photovoltaic cell that is suitable for usage in the solar panel.
- FIG. 3 is a graph showing two photovoltaic response plots with current-voltage (I-V) characteristics for two different commercial silicon (Si) solar cells operated under natural illumination under cloudy or rainy conditions.
- FIG. 4 is a graph that illustrates a photovoltaic response plot including current-voltage (I-V) characteristics for a commercial silicon (Si) solar cell operated under natural illumination under an air mass value AM 1.5 on natural solar radiation of a clear sky.
- I-V current-voltage
- FIG. 5 is a graph of a photovoltaic response plot showing current-voltage (I-V) characteristics for a commercial silicon (Si) solar cell immersed in various depths of organic dielectric liquid.
- FIG. 6 is a graph that depicts the relationship of output power to the angle of light incident on the photovoltaic cell.
- FIG. 7 is a graph that illustrates the ratio of maximum output power received from a photovoltaic cell immersed in organic dielectric liquid as a function of incident light angle.
- FIG. 1 a schematic block diagram depicts an example of a solar panel 100 in a suitable configuration for improving energy conversion efficiency.
- the solar panel 100 comprises a panel base or tray 102 that forms a lower surface wall of the solar panel 100 , and panel walls 104 on all sides of the solar panel 100 .
- the solar panel 100 can have any shape.
- the solar panel 100 has the form of a low height cylindrical structure with the panel tray 102 covering one end of the cylinder and a panel lid 112 covering a second end of the cylinder. All or a portion of the panel walls 104 and the panel lid 112 are transparent to promote functionality as a light collector.
- the horizontal cross-section of the cylinder can have any suitable shape such as a circle, an ellipse, an oval, an egg-shape, a rectangle, a triangle, a square.
- the cross-section of the cylinder can be symmetric or asymmetric. Generally a solar panel 100 with a simple shape is generally most cost-effective.
- the panel walls 104 improve output power efficiency of the solar panel 100 in two ways. First, and most obviously, the panel walls 104 hold the organic dielectric liquid 110 in the panel tray 102 and the liquid increases the output power efficiency of photovoltaic cells 106 . Second, the panel walls 104 can be transparent to function as a light collector that can add additional large increases to the efficiency of the solar cell.
- the panel walls 104 can be geometrically configured to operate as a lens containing the refractive liquid, forming an optical system that amplifies the efficiency-enhancing effect of the liquid. In one example, the panel walls 104 can have the form of a curved lens for focusing the solar energy on the photovoltaic cell 106 .
- the solar panel 100 has a rectangular shape and accordingly has four panel walls 104 .
- Many other examples can have different geometric forms including various numbers of straight sides, curved forms, or combinations of sides and curves.
- the panel walls 104 and panel tray 102 intersect in liquid-tight connections so that the solar panel 100 holds liquid essentially without leakage.
- the solar panel 100 is configured as an encapsulation system or container that contains the photovoltaic cells 106 and the organic dielectric liquid 110 in a suitable geometry for refracting illumination through the organic dielectric liquid 110 , further enhancing the output power efficiency.
- the panel walls 104 have suitable transparency for operation as a light beam collector. Illumination collected through the light beam collector refracts through the organic dielectric liquid 110 and enhances the photoelectric effect of the photovoltaic cells 106 .
- junction photovoltaic cells 106 are arranged in the panel tray 102 .
- a solar panel 100 typically has many photovoltaic cells 106 .
- Power leads 108 are connected to the photovoltaic cells 106 for connection to an external load (not shown).
- the photovoltaic cells 106 can be arranged in any suitable configuration in the panel tray 102 , either removed from or in connection with any of the panel walls 104 .
- the encapsulation system has a base or panel tray 102 and cover or panel lid 112 area that is substantially larger than total surface area covered by the one or more photovoltaic cells 106 so that more illumination through the panel walls 104 is collected to convert to electricity.
- the photovoltaic cells 106 can be silicon junction solar cells. Other types of photovoltaic cells 106 can be used such as gallium-arsenide cells and the like.
- the panel tray 102 contains an organic dielectric liquid 110 that partially or fully immerses the one or more photovoltaic cells 106 .
- the organic dielectric liquid 110 increases the efficiency of junction photovoltaic cells 106 .
- the organic dielectric liquid 110 also has the property of a highly suitable medium for usage as an optical concentrator.
- the organic dielectric liquid 110 in combination with the junction photovoltaic cells 106 operate as a highly efficient and low-cost optical concentrator.
- the particular organic dielectric liquid 110 can be selected based on various conditions of usage.
- the output power of photovoltaic cells 106 increases simply by wetting the surfaces of the photovoltaic cells 106 with an electrically nonconductive liquid, for example even water.
- the amount of increase in output power of the photovoltaic cells 106 due to wetting depends on properties of the particular liquid such as polar or non-polar character, index of refraction, and other properties. The increase in output power occurs even when only a single surface of the photovoltaic cell 106 becomes wet.
- FIG. 2 a schematic pictorial diagram illustrates an example of an n/p junction photovoltaic cell 106 that is suitable for usage in the solar panel 100 .
- the photovoltaic cell 106 includes a plurality of semiconductor layers including an n-type semiconductor 210 and a p-type semiconductor 212 .
- the semiconductor layers including n/p junction generate an electric current in response to application of solar energy impinging on the photovoltaic cell 106 .
- the photovoltaic cell 106 comprises a top metallic grid 214 or other electrical contact for collecting electrons from the semiconductor and transferring the electrons to an external load.
- a back contact layer 216 is included to complete the electrical circuit.
- a transparent encapsulant 218 constructed from a material such as glass or plastic seals the cell.
- An antireflective coating 220 on a top surface 222 of the photovoltaic cell 106 is included to prevent light from reflecting away from the photovoltaic cell 106 .
- a transparent adhesive layer 224 affixes the transparent encapsulant 218 to the photovoltaic cell 106 .
- two photovoltaic response plots show current-voltage (I-V) characteristics for two different commercial silicon (Si) solar cells operated under natural illumination under cloudy or rainy conditions with an illumination intensity of 4400 Lx.
- An I-V response curve 312 and an I-V response curve 322 illustrate photovoltaic responses of conventional operation of solar cell A 310 and solar cell B 320 , respectively, set in a shallow, wide panel tray 102 .
- solar cell A 310 has a rectangular form with an effective front area of 5 ⁇ 5 mm 2 .
- Solar cell B 320 has a rectangular form with an effective front area of approximately 10 ⁇ 20 mm 2 .
- An I-V response curve 314 and an I-V response curve 324 illustrate photovoltaic responses for the solar cell A 310 and solar cell B 320 , respectively, for operation of the photovoltaic cells 106 immersed in organic dielectric liquid 110 .
- solar cell A 310 and solar cell B 320 are immersed in glycerin which fills the panel tray 102 to a level slightly above the front face of the respective solar cell.
- the improvement in output power of the photovoltaic cells 106 is depicted by an increment in short circuit current I SC .
- the short circuit current I SC increment 316 for solar cell A 310 is approximately 40% and the short circuit current I SC increment 326 for solar cell B 320 is approximately 36%.
- Output power for the solar cell depends on the load applied to the cell. For example, the incremental output power of solar cell B 320 for a 200 ⁇ load is approximately 47% when the solar cell is immersed in the glycerine fluid.
- a photovoltaic response plot shows current-voltage (I-V) characteristics for a commercial silicon (Si) solar cell A 310 operated under natural illumination under an air mass value AM 1.5 on natural solar radiation of a clear sky.
- Curve 401 shows the I-V characteristic for operation of a solar cell in air.
- Curve 402 shows the I-V characteristic with the solar cell immersed in ethyl alcohol.
- the improvement of short circuit current I SC and open current voltage V OC for the solar cell in liquid is about 38% and about 10%, respectively.
- the improvement in output power is approximately 64% when the solar cell is connected to a 250 ⁇ load, and approximately 23% when the solar cell is connected to a 1000 ⁇ load.
- a photovoltaic response plot shows current-voltage (I-V) characteristics for a commercial silicon (Si) solar cell immersed in various depths of organic dielectric liquid 110 under vertical illumination with 10000 Lx from a 500W/5500° K. color temperature reflection lamp.
- the photovoltaic cell 106 is the solar cell B 320 and the organic dielectric liquid 110 is tricholorethylene.
- a curve 500 shows an I-V characteristic for a conventional condition with no liquid.
- the tricholorethylene fluid has a shallow depth to produce a curve 501 in which the fluid only coats the surface of solar cell B 320 nearest the panel tray 102 .
- Output power efficiency improves simply by wetting the back surface of the photovoltaic cell 106 .
- Efficiency is further improved by increasing the fluid depth to cover the entire photovoltaic cell 106 .
- Curve 502 results when the fluid depth covers the photovoltaic cell 106 so that the fluid level is 1 mm above the top surface of the photovoltaic cell 106 .
- the optimum fluid depth of tricholorethylene for solar cell B 320 covers the top surface of the cell by 7 mm, as shown by curve 503 . Additional fluid reduces the efficiency of solar cell B 320 as shown by curve 504 and 505 .
- Curve 504 results when the solar cell B 320 is covered by 10 mm over the top surface of the cell.
- Curve 505 results when the solar cell B 320 is covered by 15 mm over the top surface of the cell.
- the most suitable depth of the organic dielectric liquid 110 appears to relate to light focusing over the location of the photovoltaic cell 106 in the panel tray 102 .
- Table I Maximum output power measurements acquired under illumination from a 500W/5500° K. color temperature lamp using organic dielectric liquids 110 of glycerin, isopropyl alcohol, toluene, and tricholorethylene are shown in Table I.
- Table I illustrates the maximum increment of short circuit current I SC , ( ⁇ I SC /I SC ) max , in solar cell B 320 in a liquid depth D.
- the specific weight ⁇ and refractive index N are given for the organic dielectric liquids 110 .
- glycerin is a non-polar dielectric.
- Isopropyl alcohol, toluene, and tricholorethylene are polar dielectric.
- any polar dielectric liquid with a high index of refraction N is suitable to enhance greater output power of junction solar cells due to wetting effect.
- Output power efficiency increases when a solar cell is operated in a highly electrically resistive and optically transparent liquid.
- any liquid that is electrically resistive and optically transparent in the wavelength region from 3000 ⁇ to 20000 ⁇ is suitable.
- Any organic dielectric liquid, whether polar or nonpolar, is suitable for usage in a solar panel. Greater energy conversion efficiency is attained for a polar organic dielectric liquid with increasing efficiency for liquids with a relatively higher index of refraction such as toluene or tricholorethylene.
- the organic dielectric liquid can also be selected according to the climate and likely seasonal weather conditions of the solar energy panel installation based on the melting point and the boiling point of various liquids.
- Suitable liquids include, but are not limited to, ethylene glycol, ethylene mercaptan, o-ethylaniline, and 3-phenylpropene.
- an organic dielectric liquid 110 with a lower freezing temperature and a higher boiling temperature is advantageous to prevent damage from freezing in cold conditions and to more efficiently utilize solar energy in hot conditions.
- the liquid need not be an organic dielectric liquid 110 but rather can be an electrically nonconductive and optically transparent dielectric such as pure water to observe an increase of output power of junction solar cells.
- a graph depicts the relationship of output power to the angle of light incident on the photovoltaic cell 106 .
- the maximum output power is measured from a solar cell as a function of the angle of incidence at which sunlight strikes the front face of the solar cell 101 and/or a side wall of the solar panel system 104 . Measurements are taken with the photovoltaic cell 106 in air or in organic dielectric liquid 110 . Data are collected in conditions of natural sunlight with a clear sky. At a plurality of angles of the sun, a point on a control curve 601 is acquired in air.
- ethanol is poured into a 10 cm diameter petri dish holding the photovoltaic cell 106 to a depth level 7 mm higher than the top surface of the photovoltaic cell 106 , and a point on an illuminated test curve 602 is acquired.
- an inserted shutter 114 blocks the sunlight to the side wall of the petri dish that is refracted through the side wall to the photovoltaic cell 106 , and a point on a blocked-illumination test curve 603 is acquired.
- the difference between the blocked-illumination test curve 603 and the control curve 601 is caused by wetting the photovoltaic cell with organic dielectric liquid 110 .
- the difference between the illuminated test curve 602 and the blocked-illumination test curve 603 results from differences in illumination by sunlight refracted through the side wall of the petri dish.
- the presence of ethanol around the photovoltaic cell 106 results in an increase of approximately 33% in the output power during daylight, as is shown by blocked-illumination test curve 603 . More than 35% of the increase in output power results from sunlight refracted through the side wall of the dish to the photovoltaic cell 106 . In total, approximately a 68% increase in output power is obtained during a sunny day.
- a graph 701 illustrates the ratio of maximum output power curve 602 from a photovoltaic cell 106 immersed in ethanol 110 to that of control curve 601 in air in FIG. 6. Similar experimental test points 702 show the same power ratios obtained comparing cell efficiency in liquid to cell efficiency in air for benzene fluid baths.
- the geometry of the solar panel 100 including aspects of the transparent panel lid 112 , the transparent panel walls 104 , the geometry of the panel walls 104 to focus solar energy in the organic dielectric liquid 110 , operates to increase solar cell efficiency.
- a solar panel 100 that utilizes the disclosed geometry and organic dielectric liquid extracts an enhanced output power from the solar cells at incident illumination angles from 10° to 75°, the full range of effective sunlight angles, without tracking sun position.
- the illustrative example 701 shows an increase of approximately 70% in the output power for a day using a solar cell immersed in ethanol.
- the example 702 shows an increase of approximately 120% in the output power for a day using a solar cell immersed in benzene.
- the structure of the illustrative solar panel including solar cells immersed in liquid and encapsulated within the panel, can have various other benefits for extraction of additional power.
- the solar panel can include pumps or other devices for circulating the liquid, so solar cells can be cooled to depress the decrease in output power that results from a rise in liquid temperature. Circulating the liquid also permits simultaneous collection of solar thermal energy from the liquid.
Abstract
Solar cells operating in liquid have an increased operating efficiency resulting from two independent physical phenomena, an increase in output current from the solar cells from simply wetting the solar cells, and enhanced collection of light through refraction and inner reflection of light in the liquid. Dielectric liquids are found to increase output power efficiency of n/p junction solar cells and also function as a medium for optical concentration. The properties of dielectic liquid permit the construction of a solar cell with a suitable geometry for functioning as an optical concentrator.
Description
- Solar energy systems have been used to provide electricity and heat for decades. Designers of all types of energy generation systems continually strive to improve output power efficiency. One current problem in a solar cell energy conversion system is the efficient extraction of low-cost electricity. The conversion efficiency of a photovoltaic cell is the proportion of sunlight energy that the cell converts to electrical energy. Improving efficiency is vital to producing solar energy systems that are competitive with traditional energy source such as fossil fuels and nuclear power. Efficiency of solar energy systems has increases substantially from about 1-2% efficiency in converting sunlight into electrical energy for the earliest photovoltaic devices. Current conventional photovoltaic systems convert 7% to 17% of light energy into electrical energy.
- What is first needed is a system and method for converting energy in a solar cell with extremely high efficiency. What are also needed are solar cell materials and structures, and solar cell fabrication procedures that are inexpensive while attaining high levels of efficiency in energy generation. A further need is a solar cell configuration that permits collection of concentrated sunlight energy for conversion to electricity to increase output power generation.
- Solar cells operating in liquid have an increased operating efficiency resulting from two independent physical phenomena, an increase in output current from the solar cells from simply wetting the solar cells, and enhanced collection of light through refraction and inner reflection of light in the liquid. Dielectric liquids are found to increase output power efficiency of n/p junction solar cells and also function as a medium for optical concentration. The properties of dielectic liquid permit the construction of a solar cell panel with a suitable geometry for functioning as an optical concentrator.
- An organic dielectric liquid immersing one or more junction photovoltaic cells increases the efficiency of the photovoltaic cells. The organic dielectric liquid also is a highly suitable medium for usage as an optical concentrator. The organic dielectric liquid in combination with the junction photovoltaic cells operate as a highly efficient and low-cost optical concentrator.
- According to one aspect of the present invention, the output power of a solar cell or photovoltaic cell is increased by wetting of the surfaces of the cell with a dielectric liquid.
- According to another aspect of the present invention, a solar panel configured as an encapsulation system containing photovoltaic cells and organic dielectric liquid increases the output power of a solar cell or photovoltaic cell. The solar panel has a suitable geometry for refracting illumination through the organic dielectric liquid to further enhance the output power efficiency. For example, panel walls have suitable transparency for operation as a light beam collector. Illumination collected through the light beam collector refracts through the organic dielectric liquid and enhances the photoelectric effect of the photovoltaic cells.
- According to another aspect of the present invention, wetting of the solar cells with the organic dielectric liquid in combination with configuration of the solar panels as encapsulation system with walls operating as light beam collectors greatly improves output power efficiency and reduces cost per watt.
- According to a further aspect of some embodiments of the present invention, the solar panel has a form of a low height dome or cylindrical structure with a substantially flat panel tray covering a first end of the cylinder and a panel cover or lid covering a second end of the cylinder. All or a portion of the panel walls and the panel lid are transparent for functionality as a light collector. The horizontal cross-section of the cylinder can have any suitable shape such as a circle, an ellipse, an oval, an egg-shape, a rectangle, a triangle, a square. The horizontal cross-section of the cylinder can be symmetric or asymmetric.
- Any organic dielectric liquid, whether polar or nonpolar, is suitable for usage in a solar panel. Greater energy conversion efficiency is attained for a polar organic dielectric liquid with increasing efficiency for liquids with a relatively higher index of refraction. The organic dielectric liquid can be further selected based on the melting point and the boiling point of various liquids for solar energy systems according to seasonal weather and climate of practical usage. For example, the liquid can be selected based on values of the lowest and highest temperature of the geographical area in which the solar energy system is used.
- The features of the described embodiments believed to be novel are specifically set forth in the appended claims. However, embodiments of the invention relating to both structure and method of operation, may best be understood by referring to the following description and accompanying drawings.
- FIG. 1 is a schematic block diagram showing an example of a solar panel in a configuration for improving energy conversion efficiency.
- FIG. 2 is a schematic pictorial diagram that illustrates an example of a photovoltaic cell that is suitable for usage in the solar panel.
- FIG. 3 is a graph showing two photovoltaic response plots with current-voltage (I-V) characteristics for two different commercial silicon (Si) solar cells operated under natural illumination under cloudy or rainy conditions.
- FIG. 4 is a graph that illustrates a photovoltaic response plot including current-voltage (I-V) characteristics for a commercial silicon (Si) solar cell operated under natural illumination under an air mass value AM 1.5 on natural solar radiation of a clear sky.
- FIG. 5 is a graph of a photovoltaic response plot showing current-voltage (I-V) characteristics for a commercial silicon (Si) solar cell immersed in various depths of organic dielectric liquid.
- FIG. 6 is a graph that depicts the relationship of output power to the angle of light incident on the photovoltaic cell.
- FIG. 7 is a graph that illustrates the ratio of maximum output power received from a photovoltaic cell immersed in organic dielectric liquid as a function of incident light angle.
- Referring to FIG. 1, a schematic block diagram depicts an example of a
solar panel 100 in a suitable configuration for improving energy conversion efficiency. Thesolar panel 100 comprises a panel base ortray 102 that forms a lower surface wall of thesolar panel 100, andpanel walls 104 on all sides of thesolar panel 100. Thesolar panel 100 can have any shape. In one set of highly suitable examples, thesolar panel 100 has the form of a low height cylindrical structure with thepanel tray 102 covering one end of the cylinder and apanel lid 112 covering a second end of the cylinder. All or a portion of thepanel walls 104 and thepanel lid 112 are transparent to promote functionality as a light collector. The horizontal cross-section of the cylinder can have any suitable shape such as a circle, an ellipse, an oval, an egg-shape, a rectangle, a triangle, a square. The cross-section of the cylinder can be symmetric or asymmetric. Generally asolar panel 100 with a simple shape is generally most cost-effective. - The
panel walls 104 improve output power efficiency of thesolar panel 100 in two ways. First, and most obviously, thepanel walls 104 hold the organicdielectric liquid 110 in thepanel tray 102 and the liquid increases the output power efficiency ofphotovoltaic cells 106. Second, thepanel walls 104 can be transparent to function as a light collector that can add additional large increases to the efficiency of the solar cell. Thepanel walls 104 can be geometrically configured to operate as a lens containing the refractive liquid, forming an optical system that amplifies the efficiency-enhancing effect of the liquid. In one example, thepanel walls 104 can have the form of a curved lens for focusing the solar energy on thephotovoltaic cell 106. - In one example, the
solar panel 100 has a rectangular shape and accordingly has fourpanel walls 104. Many other examples can have different geometric forms including various numbers of straight sides, curved forms, or combinations of sides and curves. Thepanel walls 104 and panel tray 102 intersect in liquid-tight connections so that thesolar panel 100 holds liquid essentially without leakage. - The
solar panel 100 is configured as an encapsulation system or container that contains thephotovoltaic cells 106 and the organicdielectric liquid 110 in a suitable geometry for refracting illumination through the organicdielectric liquid 110, further enhancing the output power efficiency. Thepanel walls 104 have suitable transparency for operation as a light beam collector. Illumination collected through the light beam collector refracts through the organicdielectric liquid 110 and enhances the photoelectric effect of thephotovoltaic cells 106. - One or more junction
photovoltaic cells 106 are arranged in thepanel tray 102. Asolar panel 100 typically has manyphotovoltaic cells 106.Power leads 108 are connected to thephotovoltaic cells 106 for connection to an external load (not shown). Thephotovoltaic cells 106 can be arranged in any suitable configuration in thepanel tray 102, either removed from or in connection with any of thepanel walls 104. - In some embodiments, the encapsulation system has a base or
panel tray 102 and cover orpanel lid 112 area that is substantially larger than total surface area covered by the one or morephotovoltaic cells 106 so that more illumination through thepanel walls 104 is collected to convert to electricity. - In one example the
photovoltaic cells 106 can be silicon junction solar cells. Other types ofphotovoltaic cells 106 can be used such as gallium-arsenide cells and the like. - The
panel tray 102 contains anorganic dielectric liquid 110 that partially or fully immerses the one or morephotovoltaic cells 106. Theorganic dielectric liquid 110 increases the efficiency of junctionphotovoltaic cells 106. Theorganic dielectric liquid 110 also has the property of a highly suitable medium for usage as an optical concentrator. Theorganic dielectric liquid 110 in combination with the junctionphotovoltaic cells 106 operate as a highly efficient and low-cost optical concentrator. - The particular organic
dielectric liquid 110 can be selected based on various conditions of usage. The output power ofphotovoltaic cells 106 increases simply by wetting the surfaces of thephotovoltaic cells 106 with an electrically nonconductive liquid, for example even water. The amount of increase in output power of thephotovoltaic cells 106 due to wetting depends on properties of the particular liquid such as polar or non-polar character, index of refraction, and other properties. The increase in output power occurs even when only a single surface of thephotovoltaic cell 106 becomes wet. - Referring to FIG. 2, a schematic pictorial diagram illustrates an example of an n/p junction
photovoltaic cell 106 that is suitable for usage in thesolar panel 100. Thephotovoltaic cell 106 includes a plurality of semiconductor layers including an n-type semiconductor 210 and a p-type semiconductor 212. The semiconductor layers including n/p junction generate an electric current in response to application of solar energy impinging on thephotovoltaic cell 106. Various materials are suitable for usage in the semiconductor layers including single crystal silicon, multicrystalline silicon, amorphous silicon, multicrystalline silicon thin films, single crystal silicon thin films, III-V compounds including gallium-arsenide (GaAs), Gallium-Indium-Phosphorus (GaInP), Gallium-Indium-Arsenide (GaInAs), and others. In addition to the semiconductor n/p layers, thephotovoltaic cell 106 comprises a topmetallic grid 214 or other electrical contact for collecting electrons from the semiconductor and transferring the electrons to an external load. Aback contact layer 216 is included to complete the electrical circuit. On the top surface of the complete cell, a transparent encapsulant 218 constructed from a material such as glass or plastic seals the cell. Anantireflective coating 220 on atop surface 222 of thephotovoltaic cell 106 is included to prevent light from reflecting away from thephotovoltaic cell 106. A transparent adhesive layer 224 affixes the transparent encapsulant 218 to thephotovoltaic cell 106. - Referring to FIG. 3, two photovoltaic response plots show current-voltage (I-V) characteristics for two different commercial silicon (Si) solar cells operated under natural illumination under cloudy or rainy conditions with an illumination intensity of 4400 Lx. An
I-V response curve 312 and anI-V response curve 322 illustrate photovoltaic responses of conventional operation of solar cell A 310 and solar cell B 320, respectively, set in a shallow,wide panel tray 102. In the example, solar cell A 310 has a rectangular form with an effective front area of 5×5 mm2. Solar cell B 320 has a rectangular form with an effective front area of approximately 10×20 mm2. - In conventional operation, liquid is not added to the tray. An
I-V response curve 314 and anI-V response curve 324 illustrate photovoltaic responses for the solar cell A 310 and solar cell B 320, respectively, for operation of thephotovoltaic cells 106 immersed inorganic dielectric liquid 110. In the illustrative example, solar cell A 310 and solar cell B 320 are immersed in glycerin which fills thepanel tray 102 to a level slightly above the front face of the respective solar cell. The improvement in output power of thephotovoltaic cells 106 is depicted by an increment in short circuit current ISC. The short circuit current ISCincrement 316 for solar cell A 310 is approximately 40% and the short circuit current ISCincrement 326 for solar cell B 320 is approximately 36%. Output power for the solar cell depends on the load applied to the cell. For example, the incremental output power of solar cell B 320 for a 200 Ω load is approximately 47% when the solar cell is immersed in the glycerine fluid. - Under the same illumination condition, performance of the solar cells is substantially improved by operating the
photovoltaic cells 106 partly or fully immersed inorganic dielectric liquid 110. Improvements in output power performance of a solar cell vary according to numerous factors including composition of the liquid and depth of the liquid in relation to solar cell size. - Referring to FIG. 4, a photovoltaic response plot shows current-voltage (I-V) characteristics for a commercial silicon (Si) solar cell A310 operated under natural illumination under an air mass value AM 1.5 on natural solar radiation of a clear sky.
Curve 401 shows the I-V characteristic for operation of a solar cell in air.Curve 402 shows the I-V characteristic with the solar cell immersed in ethyl alcohol. The improvement of short circuit current ISC and open current voltage VOC for the solar cell in liquid is about 38% and about 10%, respectively. The improvement in output power is approximately 64% when the solar cell is connected to a 250 Ω load, and approximately 23% when the solar cell is connected to a 1000 Ω load. - Referring to FIG. 5, a photovoltaic response plot shows current-voltage (I-V) characteristics for a commercial silicon (Si) solar cell immersed in various depths of organic
dielectric liquid 110 under vertical illumination with 10000 Lx from a 500W/5500° K. color temperature reflection lamp. In one example, thephotovoltaic cell 106 is the solar cell B 320 and theorganic dielectric liquid 110 is tricholorethylene. Acurve 500 shows an I-V characteristic for a conventional condition with no liquid. The tricholorethylene fluid has a shallow depth to produce acurve 501 in which the fluid only coats the surface of solar cell B 320 nearest thepanel tray 102. Output power efficiency improves simply by wetting the back surface of thephotovoltaic cell 106. Efficiency is further improved by increasing the fluid depth to cover the entirephotovoltaic cell 106. Curve 502 results when the fluid depth covers thephotovoltaic cell 106 so that the fluid level is 1 mm above the top surface of thephotovoltaic cell 106. In the illustrative example, the optimum fluid depth of tricholorethylene for solar cell B 320 covers the top surface of the cell by 7 mm, as shown bycurve 503. Additional fluid reduces the efficiency of solar cell B 320 as shown by curve 504 and 505. Curve 504 results when the solar cell B 320 is covered by 10 mm over the top surface of the cell. Curve 505 results when the solar cell B 320 is covered by 15 mm over the top surface of the cell. - Similar measurements result when
photovoltaic cells 106 are immersed in various organicdielectric liquids 110 such as toluene, isopropyl alcohol, and glycerin. The maximum output power from the solar cell occurs at the depth of 7±1 mm above the upper surface of the cells for the listed organicdielectric liquids 110. In other examples, the optimum fluid depth may vary according to the particular organicdielectric liquid 110 that is selected and configuration of the tray such as tray diameter. - The most suitable depth of the
organic dielectric liquid 110 appears to relate to light focusing over the location of thephotovoltaic cell 106 in thepanel tray 102. - Maximum output power measurements acquired under illumination from a 500W/5500° K. color temperature lamp using
organic dielectric liquids 110 of glycerin, isopropyl alcohol, toluene, and tricholorethylene are shown in Table I. Table I illustrates the maximum increment of short circuit current ISC, (ΔISC/ISC)max, in solar cell B 320 in a liquid depth D. The specific weight ρ and refractive index N are given for the organicdielectric liquids 110. Among the organic dielectric liquids, glycerin is a non-polar dielectric. Isopropyl alcohol, toluene, and tricholorethylene are polar dielectric.TABLE I Liquid ρ N (ΔISC/ISC)max D (mm) Tricholorethylene 1.477 1.477 0.44 7 ± 1 Toluene 0.8669 1.496 0.42 7 ± 1 Isopropylalcohol 0.7855 1.3776 0.31 7 ± 1 Glycerin 1.2613 1.4746 0.27 7 ± 1 - As shown in Table I, any polar dielectric liquid with a high index of refraction N is suitable to enhance greater output power of junction solar cells due to wetting effect.
- Output power efficiency increases when a solar cell is operated in a highly electrically resistive and optically transparent liquid. Generally, any liquid that is electrically resistive and optically transparent in the wavelength region from 3000 Å to 20000 Å is suitable. Any organic dielectric liquid, whether polar or nonpolar, is suitable for usage in a solar panel. Greater energy conversion efficiency is attained for a polar organic dielectric liquid with increasing efficiency for liquids with a relatively higher index of refraction such as toluene or tricholorethylene. In a practical application, the organic dielectric liquid can also be selected according to the climate and likely seasonal weather conditions of the solar energy panel installation based on the melting point and the boiling point of various liquids. Suitable liquids include, but are not limited to, ethylene glycol, ethylene mercaptan, o-ethylaniline, and 3-phenylpropene. Generally, an
organic dielectric liquid 110 with a lower freezing temperature and a higher boiling temperature is advantageous to prevent damage from freezing in cold conditions and to more efficiently utilize solar energy in hot conditions. - In some embodiments, the liquid need not be an
organic dielectric liquid 110 but rather can be an electrically nonconductive and optically transparent dielectric such as pure water to observe an increase of output power of junction solar cells. - Referring to FIG. 6, a graph depicts the relationship of output power to the angle of light incident on the
photovoltaic cell 106. In the illustrative example, the maximum output power is measured from a solar cell as a function of the angle of incidence at which sunlight strikes the front face of the solar cell 101 and/or a side wall of thesolar panel system 104. Measurements are taken with thephotovoltaic cell 106 in air or inorganic dielectric liquid 110. Data are collected in conditions of natural sunlight with a clear sky. At a plurality of angles of the sun, a point on acontrol curve 601 is acquired in air. For the multiple angles, ethanol is poured into a 10 cm diameter petri dish holding thephotovoltaic cell 106 to a depth level 7 mm higher than the top surface of thephotovoltaic cell 106, and a point on an illuminatedtest curve 602 is acquired. Also for each angle, an insertedshutter 114 blocks the sunlight to the side wall of the petri dish that is refracted through the side wall to thephotovoltaic cell 106, and a point on a blocked-illumination test curve 603 is acquired. At all angles of the incident light, the difference between the blocked-illumination test curve 603 and thecontrol curve 601 is caused by wetting the photovoltaic cell with organicdielectric liquid 110. For all angles of the incident light, the difference between the illuminatedtest curve 602 and the blocked-illumination test curve 603 results from differences in illumination by sunlight refracted through the side wall of the petri dish. - In the illustrative test, the presence of ethanol around the
photovoltaic cell 106 results in an increase of approximately 33% in the output power during daylight, as is shown by blocked-illumination test curve 603. More than 35% of the increase in output power results from sunlight refracted through the side wall of the dish to thephotovoltaic cell 106. In total, approximately a 68% increase in output power is obtained during a sunny day. - Referring to FIG. 7, a
graph 701 illustrates the ratio of maximumoutput power curve 602 from aphotovoltaic cell 106 immersed inethanol 110 to that ofcontrol curve 601 in air in FIG. 6. Similarexperimental test points 702 show the same power ratios obtained comparing cell efficiency in liquid to cell efficiency in air for benzene fluid baths. The geometry of thesolar panel 100 including aspects of thetransparent panel lid 112, thetransparent panel walls 104, the geometry of thepanel walls 104 to focus solar energy in theorganic dielectric liquid 110, operates to increase solar cell efficiency. - A
solar panel 100 that utilizes the disclosed geometry and organic dielectric liquid extracts an enhanced output power from the solar cells at incident illumination angles from 10° to 75°, the full range of effective sunlight angles, without tracking sun position. The illustrative example 701 shows an increase of approximately 70% in the output power for a day using a solar cell immersed in ethanol. The example 702 shows an increase of approximately 120% in the output power for a day using a solar cell immersed in benzene. - During a year, as the season changes, an angle of elevation of the sun at noon varies between Φ+23.5° and Φ−23.5° at a point with the latitude Φ on the earth. A result derived from FIGS. 6 and 7 suggests that the direction of the solar panel plane needs to be selected to effectively utilize the fallen light on the side wall of the system according to the latitude of the location on the earth.
- The increased efficiency at low angles of incidence result from the collection of incident light through the side wall of the panel. Large amounts of light collection are attained not only in bright sunlight, but also during hazy or cloudy conditions. For example, a nearly 50% increase in output power is observed in the operation of solar cells immersed in ethanol under a cloudy sky with an illumination intensity of about 4800 Lx.
- The structure of the illustrative solar panel, including solar cells immersed in liquid and encapsulated within the panel, can have various other benefits for extraction of additional power. For example, the solar panel can include pumps or other devices for circulating the liquid, so solar cells can be cooled to depress the decrease in output power that results from a rise in liquid temperature. Circulating the liquid also permits simultaneous collection of solar thermal energy from the liquid.
- While the invention has been described with reference to various embodiments, it will be understood that these embodiments are illustrative and that the scope of the invention is not limited to them. Many variations, modifications, additions and improvements of the embodiments described are possible. For example, those of ordinary skill in the art will readily implement the steps necessary to provide the structures and methods disclosed herein, and will understand that the process parameters, materials, and dimensions are given by way of example only and can be varied to achieve the desired structure as well as modifications which are within the scope of the invention. Variations and modifications of the embodiments disclosed herein may be made based on the description set forth herein, without departing from the scope and spirit of the invention as set forth in the following claims.
- In the claims, unless otherwise indicated the article “a” is to refer to “one or more ”.
Claims (20)
1. A solar energy converter comprising:
an organic dielectric liquid;
one or more solar cells distributed in contact with the organic dielectric liquid; and
an encapsulating system enclosing the organic dielectric liquid and the one or more solar cells, the encapsulating system having a substantially flat base that supports the one or more solar cells, the encapsulating system having transparent walls connected to the base, the walls enhancing collection of light through the walls and through the organic dielectric liquid and optically concentrating solar energy to the one or more solar cells.
2. A solar energy converter according to claim 1 further comprising:
one or more n/p junction solar cells; and
an organic dielectric liquid that increases output current from the n/p junction solar cells by wetting the solar cells and has a refractive index that enhances collection of the light through refraction and inner reflection of the light in the organic dielectric liquid.
3. A solar energy converter according to claim 1 further comprising:
an encapsulation system having a transparent cover that collects solar illumination through the organic dielectric liquid.
4. A solar energy converter according to claim 1 further comprising:
an encapsulation system having transparent lateral panel walls forming a lens that focuses solar illumination through the organic dielectric liquid to the one or more solar cells.
5. A solar energy converter according to claim 1 further comprising:
an encapsulation system in the configuration of a low height cylindrical structure with a substantially flat panel tray covering a first end of the cylinder and a panel cover or lid covering a second end of the cylinder.
6. A solar energy converter according to claim 1 further comprising:
an encapsulation system comprising walls and cover at least partially constructed from glass or plastic.
7. A solar energy converter according to claim 1 wherein:
the encapsulation system has a base and cover area that is substantially larger than total surface area covered by the one or more solar cells.
8. A solar energy converter according to claim 1 further comprising:
an encapsulation system in the configuration of a low height cylindrical structure with a substantially flat panel tray covering a first end of the cylinder and a panel cover or lid covering a second end of the cylinder, cylinder having a cross-sectional geometry selected from among a circle, an ellipse, an oval, an egg-shape, a rectangle, a triangle, a square and being selected from among a symmetric shape and an asymmetric shape.
9. A solar energy converter according to claim 1 further comprising:
an organic dielectric liquid that is selected from among polar dielectric liquids and nonpolar dielectric liquids.
10. A solar energy converter according to claim 1 further comprising:
an organic dielectric liquid that is a polar dielectric liquids with a relatively high index of refraction.
11. A solar energy converter according to claim 1 further comprising:
an organic dielectric liquid selected from among non-flammable liquids such as ethylene glycol, ethylene mercaptan, o-ethylaniline, and 3-phenylpropene.
12. A solar energy converter according to claim 1 further comprising:
an organic dielectric liquid selected based on the melting point and the boiling point of various liquids for solar energy systems according to seasonal weather and climate of usage.
13. A solar energy converter comprising:
a liquid;
one or more solar cells distributed in contact with the liquid; and
an encapsulating system enclosing the liquid and the one or more solar cells, the encapsulating system having a substantially flat base that supports the one or more solar cells, an encapsulation system having transparent lateral panel walls connected to the base forming a lens that focuses solar illumination through the liquid to the one or more solar cells, the walls enhancing collection of light through the walls and through the liquid and optically concentrating solar energy to the one or more solar cells.
14. A solar energy converter according to claim 13 further comprising:
an encapsulation system having a transparent cover that collects solar illumination through the liquid.
15. A solar energy converter according to claim 13 further comprising:
an encapsulation system in the configuration of a low height cylindrical structure with a substantially flat panel tray covering a first end of the cylinder and a panel cover or lid covering a second end of the cylinder.
16. A solar energy converter according to claim 13 further comprising:
an encapsulation system comprising walls and cover at least partially constructed from transparent glass or plastic.
17. A solar energy converter according to claim 13 wherein:
the encapsulation system has a base and cover area that is substantially larger than total surface area covered by the one or more solar cells.
18. A solar energy converter according to claim 13 further comprising:
an encapsulation system in the configuration of a low height cylindrical structure with a substantially flat panel tray covering a first end of the cylinder and a panel cover or lid covering a second end of the cylinder, cylinder having a cross-sectional geometry selected from among a circle, an ellipse, an oval, an egg-shape, a rectangle, a triangle, a square and being selected from among a symmetric shape and an asymmetric shape.
19. A solar energy converter comprising:
a liquid;
one or more means distributed in contact with the liquid for converting solar energy to electric energy; and
means for enclosing the liquid and the one or more converting means, the enclosing means comprising:
substantially flat means for supporting the one or more converting means solar cells and the liquid;
means for focusing solar illumination and optically concentrating solar energy through the liquid to the one or more converting means.
20. A method for converting solar energy to electrical energy comprising:
providing an organic dielectric liquid;
converting solar energy to electric energy;
enclosing the liquid in a transparent vessel having a substantially flat base and walls raised from the base; and
focusing solar illumination through the vessel walls and optically concentrating solar energy through the liquid to the one or more converting means.
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US10/154,668 US6583349B2 (en) | 2001-06-22 | 2002-05-22 | Solar energy converter using a solar cell in a shallow liquid layer |
BR0205669-0A BR0205669A (en) | 2001-06-22 | 2002-05-31 | Solar energy converter utilizing a solar cell in a liquid surface layer |
AU2002259326A AU2002259326B2 (en) | 2001-06-22 | 2002-05-31 | Solar energy converter using optical concentration through a liquid |
KR1020037002549A KR100885769B1 (en) | 2001-06-22 | 2002-05-31 | Solar energy converter using optical concentration through a liquid |
CNB028156676A CN100568540C (en) | 2001-06-22 | 2002-05-31 | In shallow liquid level, use the solar converter of solar cell |
CA002451387A CA2451387A1 (en) | 2001-06-22 | 2002-05-31 | Solar energy converter using a solar cell in a shallow liquid layer |
JP2003507901A JP2004531902A (en) | 2001-06-22 | 2002-05-31 | Solar energy converter using solar cells in a shallow liquid layer |
RU2004101610/28A RU2004101610A (en) | 2001-06-22 | 2002-05-31 | SOLAR ENERGY CONVERTER USING A SOLAR ELEMENT IN A THIN LIQUID LIQUID |
PCT/US2002/017256 WO2003001610A1 (en) | 2001-06-22 | 2002-05-31 | Solar energy converter using optical concentration through a liquid |
EP02729329A EP1407494A4 (en) | 2001-06-22 | 2002-05-31 | Solar energy converter using optical concentration through a liquid |
IL15948002A IL159480A0 (en) | 2001-06-22 | 2002-05-31 | Solar energy converter using a solar cell in a shallow liquid layer |
TW091111913A TW544945B (en) | 2001-06-22 | 2002-06-03 | Solar energy converter using optical concentration through a liquid |
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US10/411,719 US7244888B1 (en) | 2001-06-22 | 2003-04-11 | Solar energy converter using a solar cell in a shallow liquid-gel layer |
IL159480A IL159480A (en) | 2001-06-22 | 2003-12-21 | Solar energy converter using a solar cell in a shallow liquid layer |
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CN105356851B (en) * | 2015-12-16 | 2018-04-06 | 天合光能股份有限公司 | A kind of photovoltaic module incident angle effect factor method of testing |
US10090420B2 (en) | 2016-01-22 | 2018-10-02 | Solar Junction Corporation | Via etch method for back contact multijunction solar cells |
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TWI669473B (en) * | 2016-11-07 | 2019-08-21 | 張忠誠 | Method and structure for increasing solar cell power generation per unit erection area |
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US4045246A (en) | 1975-08-11 | 1977-08-30 | Mobil Tyco Solar Energy Corporation | Solar cells with concentrators |
US4169738A (en) | 1976-11-24 | 1979-10-02 | Antonio Luque | Double-sided solar cell with self-refrigerating concentrator |
US4143233A (en) | 1977-06-06 | 1979-03-06 | Monsanto Research Corporation | Solar energy collector |
USRE30584E (en) | 1979-10-01 | 1981-04-21 | Owens-Illinois | Optical concentrator and cooling system for photovoltaic cells |
JP3185654B2 (en) * | 1996-03-11 | 2001-07-11 | トヨタ自動車株式会社 | Tracking solar cell device |
AU741432B2 (en) * | 1997-04-21 | 2001-11-29 | Canon Kabushiki Kaisha | Solar cell module and method for manufacturing same |
-
2001
- 2001-06-22 US US09/887,416 patent/US20030005957A1/en not_active Abandoned
-
2002
- 2002-05-22 US US10/154,668 patent/US6583349B2/en not_active Expired - Fee Related
- 2002-05-31 KR KR1020037002549A patent/KR100885769B1/en not_active IP Right Cessation
-
2003
- 2003-02-21 ZA ZA200301417A patent/ZA200301417B/en unknown
- 2003-12-21 IL IL159480A patent/IL159480A/en not_active IP Right Cessation
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101083851B1 (en) * | 2003-05-29 | 2011-11-15 | 선엔지 피티와이 리미티드 | Collector for solar radiation |
US20160056320A1 (en) * | 2014-08-25 | 2016-02-25 | Chung-Cheng Chang | Method and device for improving power generation efficiency of a solar cell |
US10840401B2 (en) * | 2014-08-25 | 2020-11-17 | Chung-Cheng Chang | Method and device for improving power generation efficiency of a solar cell |
Also Published As
Publication number | Publication date |
---|---|
IL159480A (en) | 2010-12-30 |
US6583349B2 (en) | 2003-06-24 |
ZA200301417B (en) | 2004-07-05 |
US20030029497A1 (en) | 2003-02-13 |
KR20030034151A (en) | 2003-05-01 |
KR100885769B1 (en) | 2009-02-26 |
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