US1997398A - Flexible sound record - Google Patents
Flexible sound record Download PDFInfo
- Publication number
- US1997398A US1997398A US389328A US38932829A US1997398A US 1997398 A US1997398 A US 1997398A US 389328 A US389328 A US 389328A US 38932829 A US38932829 A US 38932829A US 1997398 A US1997398 A US 1997398A
- Authority
- US
- United States
- Prior art keywords
- core
- cellulose
- record
- solution
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 description 22
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 239000000020 Nitrocellulose Substances 0.000 description 10
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 10
- 229920001220 nitrocellulos Polymers 0.000 description 10
- 229940079938 nitrocellulose Drugs 0.000 description 10
- 229920002678 cellulose Polymers 0.000 description 9
- 239000001913 cellulose Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 235000010980 cellulose Nutrition 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 229920002301 cellulose acetate Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 241000518994 Conta Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- ZNNYSTVISUQHIF-UHFFFAOYSA-N formaldehyde;thiourea Chemical compound O=C.NC(N)=S ZNNYSTVISUQHIF-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- -1 lithopone Chemical compound 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920003124 powdered cellulose Polymers 0.000 description 1
- 235000019814 powdered cellulose Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
Definitions
- the object of the present invention is to effect improvements in a record of this type whereby the surface noise is considerably reduced without the wearing qualities being adversely afiected.
- the improved record according to the present invention comprises a paper or fabric core to each side ofwhich is attached firstly a layer of non-inflammable cellulose material and then a layer of nitrocellulose material or vice verse...
- the core is preferably treated with a waterproofing or binding composition and the layers of non-inflammable cellulose material and nitrocellulose material may both be applied in the form of a solution or of thin sheets or films, or one of the layers may be applied as a solution and the other as a sheet. It is also preerable that the various layers should have substantially the same coefiicients of expansion.
- Fig. 1 showing one form of record blank having separate layers of nitro-cellulose material and non-inflammable cellulose material
- Fig. 2 showing another form of record blank having a layer which is a mixture of these materials.
- a paper core approximately .01 inches thick is impregnated with paraiiin wax, metal stearates, rosin, bituminous compounds or other material which will leave the paper waterproof after the applicat on of heat and pressure. and which should give to the core a similar coeflicient of expansion to that of the surface material; otherwise the surace of the record, will develop unevenness and sufier in appearance and quality of surface noise.
- a solution of nitro-cellulose conta ning rosin is applied to the core.
- a sheet of cellulose acetate material approximately .003 to .005 inches thick is applied to each side of the core. The whole is then -hot pressed between the matrices carrying the required records.
- a paper core is first impregnated with either an aqueous or an alcoholic solution of urea or thiourea formaldehyde resins or phenol formaldehyde, or other synthetic resin mixed with or without colouring matter or filler the paper being squeezed thereafter between rollers to assistimpregnation and to remove excess of solution.
- the impregnated paper is then dried at a suitably low temperature and spread with nitro-cellulose solution.
- the coating of nitrocellulose solution is dried, and covered with the cellulose acetate material intended to form the playing surface of the record as in the first described method.
- the cellulose acetate material is applied in the form of a solution.
- the cellulose acetate may be dissolved in acetone or other ketones or mixtures of acetone with any of the known solvents ,for celiulose esters, together with a suitable proportion of dissolved plasticizer such as p-toluene sulphonamide, diethyl phthalate or the like and with or without pigment, dyes or filling materials such as zinc oxide, lithopone, barytes, carbon black, nigrosine or the like.
- Various resins may also be incorporated if desired.
- a suitable solution is prepared by dissolving 1220 gms. of powdered cellulose acetate together with 260 gms. of para-toluene sulphonamide in 7 litres of a mixture of acetone (75%), alcohol (10%) and benzol (15%) to form a dope of suitable con-.
- the nitro-cellulose solution used in the above examples preferably consists of the lower nitrates of cellulose dissolved in acetone or other ketones or esters such as ethyl acetate or butyl acetate, together with a plasticizer such as triphenyl phosphate.
- This solution may also contain various fillers or pigments such as zinc oxide, barytes or the like and various resins may be incorporated.
- a nitrocellulose solution suitable either for the surface of the record or as an undercoating to the surface is prepared by dissolving 1300 gms. of nitrated cotton together with 200 gms. of triphenyl phosphate in 7 litres of a mixture of acetone (75%) alcohol (10%) and benzol 15%) to form a dope of suitable consistency for spreading and 500 gms. of zinc oxide are incorporated therein.
- the layer next to the paper core is applied in the form of a solution, then it may not be necessary to impregnate the core with any waterproofing composition, although, especially in the case plied in the form of solid layers or sheets, apaper core smaller in diameter than the finished discs may be used.
- the core may be 9.75? in diameter for a 10" record.
- a secondary operation is necessary. to press together the overhanging portions of the outer films of cellulose material. This pressing together of the overhanging edges forms a seal which prevents atmospheric or other moisture from reaching the core, and if paper with a suitable finis and sizing is used for the core, impregnating with a wax or resin is unnecessary.
- fibrous material as employed in the claims includes paper or fabric and the like.
- a sound record blank comprising a core of fibrous material impregnated with a urea formaldehyde resin and having attached thereto a plurality of layers of material at least one. of which constitutes the record surface and includes a noninfiammable cellulose ester, the coeflicients of expansion of each of said layers being substantially 10 equal.
- a sound record blank comprising a core of fibrous material impregnated with a urea formaldehyde resin and having attached thereto. a plurality of layers of material at leastone of which 15 constitutes the record surface and includes a non-inflammable cellulose ester.
Landscapes
- Laminated Bodies (AREA)
Description
FLEXIBLE SOUND RECORD Filed Aug. 29, 1929 WON-INFL HMMABLE CELLULDSE MATE/EVIL NIMOCELL ULDSE MATERIAL IMPRES/VATEU PAPER 0R AR c mg; NUN-INFLAMMABLE C ELLIIL'USE MATERIAL.
MIXTURE 0F NITROP C ELLULOSE MATERIAL [AND )VfllV-lA/FL/IMMABLE ClLULO$ MATERIAL.
IMPREGNATED PAPER 0R FABRIC CORE.
' gwumtoz duoawwm Patented Apr. 9, 1935 I UNITED STATES FLEXIBLE ,SOUND RECORD Samuel Whyte, Redhill, England, assignor, by mesne assignments, to Radio Corporation of America, New York, N. Y., a corporation of Delaware Application August 29, 1929, Serial No. 389,328 In Great Britain September 11, 1928 2 Claims. (01. 154-43) The present invention relates to laminated disc 5 lose acetate or the like.
The object of the present invention is to effect improvements in a record of this type whereby the surface noise is considerably reduced without the wearing qualities being adversely afiected.
It has been found that this object is attained if both nitro-cellulose and cellulose acetate or other non-inflammable cellulose material are employed-for the outer films of the sound record. Thus the improved record according to the present invention comprises a paper or fabric core to each side ofwhich is attached firstly a layer of non-inflammable cellulose material and then a layer of nitrocellulose material or vice verse...
Alternatively only one layer consisting of a mixture of non-inflammable cellulose, material and nitro-cellulose is attached to each s de of the core.
The core is preferably treated with a waterproofing or binding composition and the layers of non-inflammable cellulose material and nitrocellulose material may both be applied in the form of a solution or of thin sheets or films, or one of the layers may be applied as a solution and the other as a sheet. It is also preerable that the various layers should have substantially the same coefiicients of expansion.
The invention is illustrated diagrammatically in the accompanying drawing, Fig. 1 showing one form of record blank having separate layers of nitro-cellulose material and non-inflammable cellulose material, and Fig. 2 showing another form of record blank having a layer which is a mixture of these materials.
In one method of carrying out the invention, a paper core approximately .01 inches thick is impregnated with paraiiin wax, metal stearates, rosin, bituminous compounds or other material which will leave the paper waterproof after the applicat on of heat and pressure. and which should give to the core a similar coeflicient of expansion to that of the surface material; otherwise the surace of the record, will develop unevenness and sufier in appearance and quality of surface noise. Then a solution of nitro-cellulose conta ning rosin is applied to the core. When the core is dry, a sheet of cellulose acetate material approximately .003 to .005 inches thick is applied to each side of the core. The whole is then -hot pressed between the matrices carrying the required records.
In another method, a paper core is first impregnated with either an aqueous or an alcoholic solution of urea or thiourea formaldehyde resins or phenol formaldehyde, or other synthetic resin mixed with or without colouring matter or filler the paper being squeezed thereafter between rollers to assistimpregnation and to remove excess of solution. The impregnated paper is then dried at a suitably low temperature and spread with nitro-cellulose solution. The coating of nitrocellulose solution is dried, and covered with the cellulose acetate material intended to form the playing surface of the record as in the first described method.
In a modification of the last method, the cellulose acetate material is applied in the form of a solution. The cellulose acetate may be dissolved in acetone or other ketones or mixtures of acetone with any of the known solvents ,for celiulose esters, together with a suitable proportion of dissolved plasticizer such as p-toluene sulphonamide, diethyl phthalate or the like and with or without pigment, dyes or filling materials such as zinc oxide, lithopone, barytes, carbon black, nigrosine or the like. Various resins may also be incorporated if desired. For example, a suitable solution is prepared by dissolving 1220 gms. of powdered cellulose acetate together with 260 gms. of para-toluene sulphonamide in 7 litres of a mixture of acetone (75%), alcohol (10%) and benzol (15%) to form a dope of suitable con-.
sistency for spreading and 480 gms. of lithopone incorporated therewith. After drying and seasoning the coated core, the whole is hot pressed between the matrices carrying the required records.
The nitro-cellulose solution used in the above examples preferably consists of the lower nitrates of cellulose dissolved in acetone or other ketones or esters such as ethyl acetate or butyl acetate, together with a plasticizer such as triphenyl phosphate. This solution may also contain various fillers or pigments such as zinc oxide, barytes or the like and various resins may be incorporated. For example, a nitrocellulose solution suitable either for the surface of the record or as an undercoating to the surface is prepared by dissolving 1300 gms. of nitrated cotton together with 200 gms. of triphenyl phosphate in 7 litres of a mixture of acetone (75%) alcohol (10%) and benzol 15%) to form a dope of suitable consistency for spreading and 500 gms. of zinc oxide are incorporated therein.
If the layer next to the paper core is applied in the form of a solution, then it may not be necessary to impregnate the core with any waterproofing composition, although, especially in the case plied in the form of solid layers or sheets, apaper core smaller in diameter than the finished discs may be used. For example, the core may be 9.75? in diameter for a 10" record. In this case, a secondary operation is necessary. to press together the overhanging portions of the outer films of cellulose material. This pressing together of the overhanging edges forms a seal which prevents atmospheric or other moisture from reaching the core, and if paper with a suitable finis and sizing is used for the core, impregnating with a wax or resin is unnecessary.
The term fibrous material as employed in the claims includes paper or fabric and the like.
I claim:
1. A sound record blank comprising a core of fibrous material impregnated with a urea formaldehyde resin and having attached thereto a plurality of layers of material at least one. of which constitutes the record surface and includes a noninfiammable cellulose ester, the coeflicients of expansion of each of said layers being substantially 10 equal.
2. A sound record blank comprising a core of fibrous material impregnated with a urea formaldehyde resin and having attached thereto. a plurality of layers of material at leastone of which 15 constitutes the record surface and includes a non-inflammable cellulose ester.
SAMUEL WHYTE.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1997398X | 1928-09-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
US1997398A true US1997398A (en) | 1935-04-09 |
Family
ID=10895642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US389328A Expired - Lifetime US1997398A (en) | 1928-09-11 | 1929-08-29 | Flexible sound record |
Country Status (1)
Country | Link |
---|---|
US (1) | US1997398A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2457154A (en) * | 1941-07-26 | 1948-12-28 | Columbia Records Inc | Phonograph record |
US2691180A (en) * | 1949-02-10 | 1954-10-12 | United Shoe Machinery Corp | Shoe cover severing machine |
US3052586A (en) * | 1954-10-11 | 1962-09-04 | Jack G Brown | Method and apparatus for the manufacture of phonograph records |
US3140095A (en) * | 1961-11-10 | 1964-07-07 | Eastman Kodak Co | Record and package therefor |
-
1929
- 1929-08-29 US US389328A patent/US1997398A/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2457154A (en) * | 1941-07-26 | 1948-12-28 | Columbia Records Inc | Phonograph record |
US2691180A (en) * | 1949-02-10 | 1954-10-12 | United Shoe Machinery Corp | Shoe cover severing machine |
US3052586A (en) * | 1954-10-11 | 1962-09-04 | Jack G Brown | Method and apparatus for the manufacture of phonograph records |
US3140095A (en) * | 1961-11-10 | 1964-07-07 | Eastman Kodak Co | Record and package therefor |
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