US1935217A - Washing and cleansing textile fibers - Google Patents
Washing and cleansing textile fibers Download PDFInfo
- Publication number
- US1935217A US1935217A US360617A US36061729A US1935217A US 1935217 A US1935217 A US 1935217A US 360617 A US360617 A US 360617A US 36061729 A US36061729 A US 36061729A US 1935217 A US1935217 A US 1935217A
- Authority
- US
- United States
- Prior art keywords
- washing
- cleansing
- textile fibers
- bath
- aliphatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
Definitions
- the present invention relates to a process of washing and cleansing textile fibers. 5
- the subject-matter of the present application is a continuation-in-part of one copending application for an improvement in Treatment of vegetable, animal and other industrial materials Ser. No. 243,466, filed December 29, 1927.
- R hydroxy alkyl groups
- the aforesaid aliphatic or mixed hydroaromatic-aliphatic ammonia derivatives are hereinafter referred to collectively as aliphatic ammonia derivatives containing at least one hydroxy alkyl group. Both these bases and their salts are very readily soluble in water, and assist the thorough wetting or complete penetration of the said material by the aqueous washing and cleansing baths.
- the washing andcleansing properties of the said bases, or their salts, for instance with higher fatty acids, are due to their dissolving and dispersing action on fats, oils, waxes, resins and the like. They may be used either alone or in a conjunction with organic saponaceous substances,
- the bases to be used despite their. powerful basic properties do not attack the animal fiber, even when in high concentration, they are excellently adapted for the washing and cleansingof, such fibers in all cases where the use of substances with an alkaline action is essential, and where the use of other alkaline substances would involve the risk of damaging the quality of crude, semi-finished and finished materials made from animal fibers.
- the usual working methods can be carried out in a substantially more energetic manner, woolen goods, for example, being treated with the said organic bases at bofling heat, which is impossible when other alkaline agents are employed.
- Example 1 A bowking liquor is mixed with 500 grams of tripropanolamine per 100 kilograms of cotton material.
- the high solvent capacity for cotton wax, and the high penetrative power of the triso propanolamine assists the bowking process in a very high degree, and enables the usual period of boiling to be shortened by a third to a half.
- Example 3 A scouring bath (at 40 centigrade) for 100 kilograms of oily and greasy wool is mixed with 5 grams of soap and 5 cc. of diethanolamine per litre of bath liquor, and the goods are worked for half an hour, squeezed and rinsed. An ex- 90 cellent cleansing effect is obtained.
- Example 4 50 kilograms of unfinished worsted fabric are subjected to the usual treatment in the carbonizing apparatus, with an addition of 1 to 2 grams of triethanolamine per litre. This treatment completely removes all the softening oil present in the goods.
- a washing and cleansing bath comprising a soap and an aliphatic ammonia derivative containing at least one hydroxy alkyl group.
- a washing and cleansing bath comprising an organic saponaceous substance and an aliphatic ammonia derivative containing at least one hydroxy alkyl 7.
- a washing and cleansing bath comprising an organic saponaceous substance and an ethanol amine.
- a washing and cleansing bath comprising an organic saponaceous substance and triethanol amine.
- composition of matter a washing and HEINRICH ULRICH. cUR'r SCHUSTER.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Description
Patented Nov. 14, 1933 JNITED STATES PATENT OFFICE WASHING AND CLEANSING TEXTILE FIBERS ware No Drawing. Application May 4, 1929, Serial No. 360,617, and in Germany November 8, 1926 Claims.
An application was filed in Germany Nov. 8,
1926, bearing Serial No. I. 29,470.
The present invention relates to a process of washing and cleansing textile fibers. 5 The subject-matter of the present application is a continuation-in-part of one copending application for an improvement in Treatment of vegetable, animal and other industrial materials Ser. No. 243,466, filed December 29, 1927.
We have found that aliphatic or mixed hydroaromatic-aliphatic ammonia derivatives, which contain one or more hydroxy alkyl groups (ROH; R=alkyl or cycloalkyl) can be employed with advantage as auxiliaries for washing and cleansing textiles, for instance animal textile fibers. For the sake of brevity the aforesaid aliphatic or mixed hydroaromatic-aliphatic ammonia derivatives are hereinafter referred to collectively as aliphatic ammonia derivatives containing at least one hydroxy alkyl group. Both these bases and their salts are very readily soluble in water, and assist the thorough wetting or complete penetration of the said material by the aqueous washing and cleansing baths. The washing andcleansing properties of the said bases, or their salts, for instance with higher fatty acids, are due to their dissolving and dispersing action on fats, oils, waxes, resins and the like. They may be used either alone or in a conjunction with organic saponaceous substances,
that is soaps, Turkey-red oils, sulphonic acids, especially alkylated aromatic sulphonic acids, or their salts, or with organic solvents, or a plurality of these substances. Cyclohexylmonoethanolamine, cyclohexyldiethanolamine, butylethanolamines, triethanolamine, diethanolamine and the like may be mentioned as typical bases of the kind in question. I
By reason of the fact that the bases to be used despite their. powerful basic properties do not attack the animal fiber, even when in high concentration, they are excellently adapted for the washing and cleansingof, such fibers in all cases where the use of substances with an alkaline action is essential, and where the use of other alkaline substances would involve the risk of damaging the quality of crude, semi-finished and finished materials made from animal fibers. Owing to the favorable properties of the bases to be used, the usual working methods can be carried out in a substantially more energetic manner, woolen goods, for example, being treated with the said organic bases at bofling heat, which is impossible when other alkaline agents are employed.
The following examples will further illustrate the nature of the said invention which however is not limited thereto.
Example 1 Example 2 A bowking liquor is mixed with 500 grams of tripropanolamine per 100 kilograms of cotton material. The high solvent capacity for cotton wax, and the high penetrative power of the triso propanolamine, assists the bowking process in a very high degree, and enables the usual period of boiling to be shortened by a third to a half.
Example 3 A scouring bath (at 40 centigrade) for 100 kilograms of oily and greasy wool is mixed with 5 grams of soap and 5 cc. of diethanolamine per litre of bath liquor, and the goods are worked for half an hour, squeezed and rinsed. An ex- 90 cellent cleansing effect is obtained.
- Example 4 50 kilograms of unfinished worsted fabric are subjected to the usual treatment in the carbonizing apparatus, with an addition of 1 to 2 grams of triethanolamine per litre. This treatment completely removes all the softening oil present in the goods.
What we claim is:
1. The process of washing and cleansing textile fibers with the aid of an aqueous bath, with which an aliphatic ammonia derivative containing atleast one hydroxy alkyl group is incorporated.
2. The process of washing and cleansing animal textile fibers with the aid of an aqueous alkaline bath, with which an aliphatic ammonia derivative containing at least one hydroxy alkyl group is incorporated.
' 3. The process of washing and cleansing animal textile fibers with the aid of an aqueous alkaline bath, in which an ethanolamine is incorporated with the said bath.
4. The process of washing and cleansing animal textile fibers with the aid of an aqueous alkaline bath in which a triethanolamine is incorporated with the said bath.
5. As a composition of matter, a washing and cleansing bath comprising a soap and an aliphatic ammonia derivative containing at least one hydroxy alkyl group.
6. As a composition of matter, a washing and cleansing bath comprising an organic saponaceous substance and an aliphatic ammonia derivative containing at least one hydroxy alkyl 7. As a composition of matter, a washing and cleansing bath comprising an organic saponaceous substance and an ethanol amine.
8'. As a composition of matter, a washing and cleansing bath comprising an organic saponaceous substance and triethanol amine.
9. As a composition of matter, a washing and HEINRICH ULRICH. cUR'r SCHUSTER.
DI S O 1. Al M E R 1,935,217.Heinrich Ulrich and Curt Sehuster, Ludwigshafen-on-Rhine, Germany;
-WASHING AND CLEANSING TEXTILE FIBERS.
Patent dated November 14,
1933. Disclaimer filed July 7, 1934, by the assignee, General Aniline Works,
Inc.
Enters this disclaimer to certain of the dams of the above identified patent,
and
Hereby disclaims from the scope of claims 1 and 2 any process in which the aliphatic ammonia derivative is employed in the form of a salt of such aliphatic ammonia derivative with an acid.
Hereby disclaims from the scope of claims 3 and 4 any process in which the ethanol amine is employed in the form-of a salt of such ethanol amine with an acid. Hereby disclaims from the scope of claims 6-10, inclusive, any composition in which the organic saponaceous substance is in chemical combination with the aliphatic ammonia derivative.
[Oficial Gazette August 7,.1984.]
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI29470D DE529859C (en) | 1926-11-09 | 1926-11-09 | Process for the treatment of vegetable, animal or other substances |
GB2419427A GB307948A (en) | 1927-09-14 | 1927-09-14 | Improved means for the treatment of textile materials |
Publications (1)
Publication Number | Publication Date |
---|---|
US1935217A true US1935217A (en) | 1933-11-14 |
Family
ID=25981376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US360617A Expired - Lifetime US1935217A (en) | 1926-11-09 | 1929-05-04 | Washing and cleansing textile fibers |
Country Status (2)
Country | Link |
---|---|
US (1) | US1935217A (en) |
DE (1) | DE529859C (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2441063A (en) * | 1943-06-04 | 1948-05-04 | Quaker Chemical Products Corp | Salts of alkylolamine boric esters |
US2471645A (en) * | 1946-08-30 | 1949-05-31 | Clorox Chemical Co | Detergent composition |
US2685496A (en) * | 1951-05-22 | 1954-08-03 | Harris Res Lab Inc | Method for stripping color from keratinous material |
US2790771A (en) * | 1954-10-12 | 1957-04-30 | Republic Steel Corp | Lubricating composition |
US2820768A (en) * | 1952-05-13 | 1958-01-21 | Fromont Louis Edmond Ge Hubert | Soaps and their methods of preparation |
US3074774A (en) * | 1959-10-16 | 1963-01-22 | Arkansas Company Inc | Discharge printing pastes and methods of application involving same |
US4509989A (en) * | 1983-03-25 | 1985-04-09 | United States Steel Corporation | Cleaning method for removing sulfur containing deposits from coke oven gas lines |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE749335C (en) * | 1937-01-24 | 1944-11-21 | Self-emulsifying mixtures | |
DE742573C (en) * | 1940-11-20 | 1953-03-16 | Sandoz A G Freiburg Schweiz | Process for printing cellulose fibers with leuco ester salts of Kuepen dyes |
-
1926
- 1926-11-09 DE DEI29470D patent/DE529859C/en not_active Expired
-
1929
- 1929-05-04 US US360617A patent/US1935217A/en not_active Expired - Lifetime
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2441063A (en) * | 1943-06-04 | 1948-05-04 | Quaker Chemical Products Corp | Salts of alkylolamine boric esters |
US2471645A (en) * | 1946-08-30 | 1949-05-31 | Clorox Chemical Co | Detergent composition |
US2685496A (en) * | 1951-05-22 | 1954-08-03 | Harris Res Lab Inc | Method for stripping color from keratinous material |
US2820768A (en) * | 1952-05-13 | 1958-01-21 | Fromont Louis Edmond Ge Hubert | Soaps and their methods of preparation |
US2790771A (en) * | 1954-10-12 | 1957-04-30 | Republic Steel Corp | Lubricating composition |
US3074774A (en) * | 1959-10-16 | 1963-01-22 | Arkansas Company Inc | Discharge printing pastes and methods of application involving same |
US4509989A (en) * | 1983-03-25 | 1985-04-09 | United States Steel Corporation | Cleaning method for removing sulfur containing deposits from coke oven gas lines |
Also Published As
Publication number | Publication date |
---|---|
DE529859C (en) | 1934-02-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US1935217A (en) | Washing and cleansing textile fibers | |
US2134346A (en) | Washing and cleansing compositions | |
EP0280976A2 (en) | Liquid textile-treating agent | |
US2806804A (en) | Method of treating wool | |
DE1617116C3 (en) | Low foaming detergents and cleaning agents | |
US1914331A (en) | Treatment of textile materials with aqueous liquids | |
US2159967A (en) | Oxides of amino acids | |
DE1098904B (en) | Process for the optical brightening of polyester fibers | |
US3057674A (en) | Dyeing carriers and their use | |
EP0056151B1 (en) | Process for the microbicidal finishing of textiles | |
US1923179A (en) | Treatment of textiles and agents therefor | |
DE738675C (en) | Process for the finishing of textile goods | |
DE2932869A1 (en) | METHOD FOR SOFT-GRIPING TEXTILE MATERIALS WITH UNSATURATED, ALIPHATIC ACID AMIDES | |
DE612686C (en) | Process for the preparation of ester and acid amide-like condensation products | |
DE2243806C3 (en) | Aqueous agent for softening textiles | |
DE2004721A1 (en) | Softener, rinsing agent | |
GB372325A (en) | Improvements in the treatment of fibrous materials | |
DE702229C (en) | Process for cleaning textile goods | |
DE575831C (en) | Process for the production of cleaning, emulsifying and wetting agents | |
AT138257B (en) | Process for cleaning fibrous materials, in particular laundry. | |
DE664818C (en) | Wetting, cleaning, dispersing and dyeing aids | |
US2346454A (en) | Surface active agent | |
DE19631596A1 (en) | Washing process | |
US1750430A (en) | Process of treating crude fibers and textile fabrics | |
US1962299A (en) | Detergent compound and method for preparing the same |