US193158A - Improvement in dyeing yarns and fabrics in aniline-black - Google Patents
Improvement in dyeing yarns and fabrics in aniline-black Download PDFInfo
- Publication number
- US193158A US193158A US193158DA US193158A US 193158 A US193158 A US 193158A US 193158D A US193158D A US 193158DA US 193158 A US193158 A US 193158A
- Authority
- US
- United States
- Prior art keywords
- aniline
- bath
- black
- acid
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004043 dyeing Methods 0.000 title description 24
- 229920000767 polyaniline Polymers 0.000 title description 4
- 239000004744 fabric Substances 0.000 title 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 40
- 150000003839 salts Chemical class 0.000 description 28
- 239000011780 sodium chloride Substances 0.000 description 28
- 239000002253 acid Substances 0.000 description 22
- 239000004753 textile Substances 0.000 description 22
- KRVSOGSZCMJSLX-UHFFFAOYSA-L Chromic acid Chemical compound O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 16
- 229920000742 Cotton Polymers 0.000 description 14
- 239000002585 base Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- 230000004048 modification Effects 0.000 description 10
- 238000006011 modification reaction Methods 0.000 description 10
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 6
- 239000003086 colorant Substances 0.000 description 6
- 235000011167 hydrochloric acid Nutrition 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- KMUONIBRACKNSN-UHFFFAOYSA-N Potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 4
- 150000001448 anilines Chemical class 0.000 description 4
- 239000004755 animal textile Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 4
- MMCPOSDMTGQNKG-UHFFFAOYSA-N Anilinium chloride Chemical compound Cl.NC1=CC=CC=C1 MMCPOSDMTGQNKG-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 241001070941 Castanea Species 0.000 description 2
- 235000014036 Castanea Nutrition 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N Chromium(III) oxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 210000003746 Feathers Anatomy 0.000 description 2
- 240000006240 Linum usitatissimum Species 0.000 description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 2
- 235000005811 Viola adunca Nutrition 0.000 description 2
- 240000009038 Viola odorata Species 0.000 description 2
- 235000013487 Viola odorata Nutrition 0.000 description 2
- 235000002254 Viola papilionacea Nutrition 0.000 description 2
- 210000002268 Wool Anatomy 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 229940005991 chloric acid Drugs 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910052803 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 230000001419 dependent Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 230000001590 oxidative Effects 0.000 description 2
- 238000005502 peroxidation Methods 0.000 description 2
- 230000001376 precipitating Effects 0.000 description 2
- 230000000750 progressive Effects 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
Definitions
- This invention relates to certain chemical reactions, having for object the production from aniline of a series of black colors, or shades bordering on black, and also to the processes employed in applying the same for dyeing textile materials.
- novel chemical reactions of my inven tion consist in the concurrent action on aniline-oil or on its salts, of certain metallic salts and soluble chromates or bichromates or chlorates, without the necessity of exposure to air.
- the action of the metallic salts may either precede or i follow that of the chromates or bichromates, and both may be performed with or without the aid of heat.
- the first modification consists in the formation of a complex base, containing both aniline and a metal, this base being obtained by precipitating certain metallic salts by means of aniline-oil. These complex bases redissolve in acids.
- Thesecond modification consists in forming a bath containing the elements of a double salt of aniline and of metal. For example, I place together in the bath equal equivalents of perchloride of iron and hydrochlorate of aniline.
- the third modification consists in forming a bath containing the elements of an aniline salt combined with the metal-that isto say, salts of aniline with a metallic acid.
- This latter modification includes the formation, by double decomposition in the baths, of ferro and ferri cyanides of aniline, of chromates and bichromates, manganates and permanganates, tungstates, vanadates, and bivanadates of aniline.
- the application to dyeing textile materials of the above series of reactions and of processes may be efl'ectedin one, two, or three baths.
- the following is the method of dyeing with three baths.
- the complex bases above referred to are precipitated on the materials to be dyed, by first impregnating with aniline then with the metallic salt, the textile matters being carefully drained between each bath.
- the black is then developed by introducing the textiles into a bath of soluble chromates, bichromates, or chlorates.
- the textiles are placed in baths containing either the elements of a double salt of aniline and of metal, or the elements of a salt of aniline with a metallic acid.
- the textiles become dyed in this bath of a gradually deepening green color, whether the bath be cold or heated,"and they may be thoroughly rinsed without removing the dye.
- the aniline is then peroxidized and the black developed by placing the matters to be dyed in a bath of soluble chromate, bichromate, or chlorate.
- the aniline salts with a metallic acid which give the best results are those in which the metallic acid is chromicacid.
- the textiles With a bath containing (by reason of a double decomposition) the elements of chromate of aniline without an excess of chromic acid, the textiles will only be dyed of a deep green, which is changed to blue-violet by means of an alkali,
- the quantity of acid in the bath should be sufficient to saturate the base combined with the chloric acid.
- the metals whose salts are suited to one or the other of the above reactions are those which are susceptible of two degrees of oxidation, and readily converted from the one to the other by oxidation or reduction, and the following more particularly have a very energetic action, viz: iron, copper, manganese, cerium, chromium, nickel, cobalt, tungsten, uranium, and vanadium.
- the quality of the color is dependent on the nature of these acids, their proportion in the bath on the metals employed, and also on the temperature of the bath.
- I form ,a bath, A, containing, for one liter of water, aniline, thirty cubic centimeters; hydrochloric acid, ninety cubic centimeters, at 22 Baum; nitrate of sesquioxide of iron, forty cubic centimeters, at 40 Baum.
- I form a second bath, B, containing from ten to twenty grams of bichromate of potash per liter.
- the cotton in small portions at a time, is dipped in the bath A, (which may be either cold or tepid,) and after being slightly wrung, but not rinsed, is placed in the bath B, where it digests for about three hours.
- the cotton on leaving bath A retains sufficient acid to decompose the proper quantity of bichromate.
- the dyeing is complete when a sample, on being dipped in a weak warm solution of carbonate of soda, remains of a chestnut color without changing to a violet.
- the cotton is introduced into a cold bath, worked for three quarters of an hour, after which the temperature is gradually raised to 100 centigrade, and kept thereat for at least one quarter of an hour.
- the blacks obtained by these three methods are insoluble in cold sulphuric acid of 66 Baum, and will not turn green under the action' of sulphurous acid. They are, in fact,
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
UNITE WILLIAM J. s. GRAWITZ, or PARIS, FRANCE.
IMPROVEMENT IN DYEINGVARNS AND FABRICS IN ANiLlNE-BLACK.
Specification forming part of Letters Patent No. it; 3,1158, dated July 17, 1877 application filed March 13, 1877; patented in England, October 21, 1874, for fourteen years.
To all whom it may concern:
Be it known that 1, WILLIAM J ULES SAM- U'EL GRAWITZ, of Paris, France, chemist, have invented Improvements in the Production of.
Aniline Blacks and Grays, and in the application of the same for dyeing textile materials; and I do hereby declare that the following is a full, clear, and exact description of the same.
This invention relates to certain chemical reactions, having for object the production from aniline of a series of black colors, or shades bordering on black, and also to the processes employed in applying the same for dyeing textile materials.
The novel chemical reactions of my inven tion consist in the concurrent action on aniline-oil or on its salts, of certain metallic salts and soluble chromates or bichromates or chlorates, without the necessity of exposure to air.
The action of the metallic salts may either precede or i follow that of the chromates or bichromates, and both may be performed with or without the aid of heat.
I will proceed to describe the three principal modifications of my invention in the dyeing of textile materials.
The first modification consists in the formation of a complex base, containing both aniline and a metal, this base being obtained by precipitating certain metallic salts by means of aniline-oil. These complex bases redissolve in acids.
Thesecond modification consists in forming a bath containing the elements of a double salt of aniline and of metal. For example, I place together in the bath equal equivalents of perchloride of iron and hydrochlorate of aniline.
The third modification consists in forming a bath containing the elements of an aniline salt combined with the metal-that isto say, salts of aniline with a metallic acid. This latter modification includes the formation, by double decomposition in the baths, of ferro and ferri cyanides of aniline, of chromates and bichromates, manganates and permanganates, tungstates, vanadates, and bivanadates of aniline.
These complex bases, these double salts of aniline and of metal, these salts of aniline with a metallic acid, have all the property of enabling the aniline to gradually oxidize with the greatest facility, produce black, or shades bordering on black, according to the degree of oxidation.
The application to dyeing textile materials of the above series of reactions and of processes may be efl'ectedin one, two, or three baths.
The following is the method of dyeing with three baths. The complex bases above referred to are precipitated on the materials to be dyed, by first impregnating with aniline then with the metallic salt, the textile matters being carefully drained between each bath. The black is then developed by introducing the textiles into a bath of soluble chromates, bichromates, or chlorates.
In operating with two baths in two distinct ways, the textiles are placed in baths containing either the elements of a double salt of aniline and of metal, or the elements of a salt of aniline with a metallic acid. The textiles become dyed in this bath of a gradually deepening green color, whether the bath be cold or heated,"and they may be thoroughly rinsed without removing the dye. The aniline is then peroxidized and the black developed by placing the matters to be dyed in a bath of soluble chromate, bichromate, or chlorate.
In dyeing with a single bath 1 place therein either altogether or successively the whole of the constitutive elements of the black, the bath being cold when the textile materials are introduced. The reaction is allowed to com- 'mence at the ordinary temperature and the bath is then gradually raised to about 100 centigrade. When chromates are used the reaction should be allowed to continue for about half an hour before heating; otherwise a gray shade would be produced, and the color would be precipitated in the bath.
The latter method of operating in a single bath greatly facilitates dyeing piecagoods.
The aniline salts with a metallic acid which give the best results are those in which the metallic acid is chromicacid. With a bath containing (by reason of a double decomposition) the elements of chromate of aniline without an excess of chromic acid, the textiles will only be dyed of a deep green, which is changed to blue-violet by means of an alkali,
in exactly the same manner as with perchloride or nitrate of sesquioxide of iron. By peroxidizing with a bath of soluble bichromate or chromate, the green is changed to a black. Black may be at once produced if a suflicient quantity of the chromate or bichromate is.
placed in the bath.
When chlorate is used, the quantity of acid in the bath should be sufficient to saturate the base combined with the chloric acid.
When employing chromates and bic hromates it is necessary not only to saturate the base combined with the chromic acid, but also to saturate the oxide of chromium resulting from the reduction of the chromic acid.
The metals whose salts are suited to one or the other of the above reactions are those which are susceptible of two degrees of oxidation, and readily converted from the one to the other by oxidation or reduction, and the following more particularly have a very energetic action, viz: iron, copper, manganese, cerium, chromium, nickel, cobalt, tungsten, uranium, and vanadium.
I'reserve the application of all mineral or organic acids in combination either with aniline or with metals, or in a free state in the dye-bath.
The quality of the color is dependent on the nature of these acids, their proportion in the bath on the metals employed, and also on the temperature of the bath.
I will here give three examples of the method of dyeing cotton in hanks.
First example: I form ,a bath, A, containing, for one liter of water, aniline, thirty cubic centimeters; hydrochloric acid, ninety cubic centimeters, at 22 Baum; nitrate of sesquioxide of iron, forty cubic centimeters, at 40 Baum.
I form a second bath, B, containing from ten to twenty grams of bichromate of potash per liter.
The cotton, in small portions at a time, is dipped in the bath A, (which may be either cold or tepid,) and after being slightly wrung, but not rinsed, is placed in the bath B, where it digests for about three hours. The cotton on leaving bath A retains sufficient acid to decompose the proper quantity of bichromate.
I then recommenoe the same series of operations, mordanting in bath A, and peroxidizing in bath B until the obtained shade is sufficiently laid on. Three such double passages through the baths will generally suflice.
The dyeing is complete when a sample, on being dipped in a weak warm solution of carbonate of soda, remains of a chestnut color without changing to a violet.
Second example For every ten kilograms I take of water one hundred and fifty liters; hydrochloric acid, four liters; aniline, one liter; bichromate of potash, one kilogram, five hundred grams.
Idip the cotton, after well boiling, in this bath, work it for about three quarters of an hour, after which I rinse, and immerse it in a boiling bath containing one gram of persnlphate of iron, for example, per liter, slightly acidulated, for about a quarter of an hour.
Third example: I take, for one hundred kilograms of cotton, water one hundred and fifty liters; muriatic acid,"at' 22 Baum, four liters; aniline, one liter; bichromate, two kilograms, two hundred and fifty grams.
The cotton is introduced intoa cold bath, worked for three quarters of an hour, after which the temperature is gradually raised to 100 centigrade, and kept thereat for at least one quarter of an hour.
The blacks obtained by these three methods are insoluble in cold sulphuric acid of 66 Baum, and will not turn green under the action' of sulphurous acid. They are, in fact,
true blacks. By dilution, they give greys,
having the same properties. With a single cold bath I obtain what I term shades bor-.
dering on black or greys, these colors changing to a green under the action of sulphurous acid.
In this manner may be dyed cotton, flax, wool, silk, feathers, and all vegetable or animal textile matters generally. For dyeing piece goodsit is preferable to use a'single bath, or at least to revive the first bath with a salt of aniline with a metallic acid, as in the second example, before given.
The proportions of the elements indicated are those which have been found to give the best results, although I do not intend to limit myself thereto.
I claim The herein-described process of dyeing vegetable or animal textile materials of black and grey colors, or shades bordering thereon, by slow concurrent progressive reaction on the textile fibers themselves, of aniline salts and metallic oxidizing salts or acids, without exposure to the air, and with or without heat, with a subsequent peroxidation by means of chloric or chromic acid, substantially as set forth.
WILLIAM JULES SAMUEL GRAWITZ.
Witnesses:
'RoB'r. M. HOOPER,
JEAN BAPTISTE HOLLAND.
Publications (1)
Publication Number | Publication Date |
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US193158A true US193158A (en) | 1877-07-17 |
Family
ID=2262564
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US193158D Expired - Lifetime US193158A (en) | Improvement in dyeing yarns and fabrics in aniline-black |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050250571A1 (en) * | 2004-05-07 | 2005-11-10 | Kane Steven N | Method and apparatus for conducting a game of chance |
-
0
- US US193158D patent/US193158A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050250571A1 (en) * | 2004-05-07 | 2005-11-10 | Kane Steven N | Method and apparatus for conducting a game of chance |
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