US1917196A - Process of carbonizing solid bituminous fuel - Google Patents
Process of carbonizing solid bituminous fuel Download PDFInfo
- Publication number
- US1917196A US1917196A US343091A US34309129A US1917196A US 1917196 A US1917196 A US 1917196A US 343091 A US343091 A US 343091A US 34309129 A US34309129 A US 34309129A US 1917196 A US1917196 A US 1917196A
- Authority
- US
- United States
- Prior art keywords
- fuel
- combustion
- products
- column
- coke
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B1/00—Retorts
- C10B1/02—Stationary retorts
- C10B1/04—Vertical retorts
Definitions
- the present invention relates to thecarbonization of solid bituminous fuel by direct contact with hot gases.
- More particularly it relates to the carbonization of such fuel by the contact of the hot products of combustion produced by the'combustion of fuel with an oxygen-containing medium that contains a greater proportionof free oxygen than does atmospheric air, with the production of coke and a, mixed gas consisting of coal gas and products of combustion relatively low in inert nitrogen.
- the object of the invention is to provide an improved method for such carbonization.
- the process includes establishing a continuous or intermittent flow of the bituminous material, one portion of which is comprised of uncarbonized and partially carbonized fuel in process of heating and another portion of which is comprised of coke resulting from the carbonization in process of cooling, establishing a hot zone intermediate of the ends of the flow of fuel by heating an intermediate portion, indirectly, by the combustion of other fuel with an oxygen containing gas that contains a greater proportion of free oxygen than atmospheric air, and directly, mentioned fuel the resultant hot products of combustion, passing them from the hot zone through the fuel in process of carbonizing to heat it and eifect carbonization, leading off the resultant mixed coal gas and products of combustion from the fuel, passing a. cooling agent through the coke resulting from the carbonization to cool it and from thence through the hot zone and through the fueI undergoing carbonization to assist in the carbonization.
- the drawing shows a partial ⁇ vertical cross section and elevation of apparatus chosen for illustration in which my process may be performed.
- 1 generally indicates the carbonizing chamber, containing a fuel bed the upper by leading into the first portion of which, indicated as 2, is comprised ofsolid bituminous fuel undergoing carbonization and the lower part of which, indicated as 3, is composed of coke resulting from the carbonization.
- the combustion chamber 4 is a combustion chamber-provided with the fuel supply means and oxygen supply means 5 and arranged to heat the intermediate section of the fuel bed through the wall 6.
- the combustion chamber 4 is in communication with the fuel bed at a zone intermediate of the ends of the fuel bed.
- the carbonizing chamber is provided with the gas off-take 7 leading from above the lfresh fuel through the valve 8 to the wash- 10 is the as off-take from the wash-box to a place o storage, not shown.
- the off-take 7 may also be connected through the valvel 11 to the input side of the circulating means 12 (a fan, as shown for illustration).
- the output side of the fan is connected by connection 13 to the base of the fuel bed.
- eans for the continuous discharge of coke may be provided as for instance the travelling grate 14 which discharges to the hopper 15.
- eans for continuous fuel may be provided charger indicated at 16.
- fresh fuel such as bituminous coal, lignite, etc.
- the charger 16 In operation fresh fuel such as bituminous coal, lignite, etc., is fed to the top of the fuel bed by .the charger 16 and cooled coke removed from its base by the grate 14.
- Fuel and an oxygen-containing medium containing a greater proportion of free oxygen than does atmospheric air are admitted to the combustion chamber 4 and partially burned therein, heating the mid-section of the fuel bed indirectly through the wall 6.
- the products of combustion pass from the combustion chamber into the mid-section of the fuel bed heating it directly and pass upward through the fuel in the upper portion of the fuel bed effecting its carbonization and distilling olf its volatile material.
- the mixed coal gas and products of combustion give up their heat in contact with the fresh fuel in the upper portion'of the fuel .bed and charging of fresh if desired as the issue from the top of the fuel bed relatively cool.
- connection 7 and valve 8 A portion of the mixed gas passes through connection 7 and valve 8 to the wash-box, the remainder is drawn through valve ll by the fan 12, passed by connection 13 to the base of the fuel bed and forced upward through the coke, cooling the coke in the passage.
- the mixed gas then passes through the highly heated zone and is heated therein and passes upward through the uncarbonized fuel above to assist in its carbonization.
- the mixed gas may be led directly to the wash-box and a small amount of steam, sufficient to cool the coke, may be admitted at 17 and passed upward through the fuel bed or steam may be mixed and recirculated with the gas produced
- the fuel introduced with oxygen, to the combustion chamber may be pulverized coal, oil, tar or gas.
- suhcient oxygen is introduced for its partial combustion only, thereby maintaining a low proportion of incombustible constituents in the resultant combustion gases.
- composition of the final mixed gas will depend, among other things, on the fuel introduced to the combustion chamber.
- partial combustion with oxygen can be regulated to furnish combustionv products containing considerable amounts of hydrocarbons as well as carbon monoxide and hydrogen and the combustion products may have a rela- -tively high calorific value.
- the supply of this fuel and the oxygen supply may be regulated to effect the partial or total carbonization of the pulverized fuel by combustion of a part of it.
- the fuel bed will retain the partially carbonized pulverized fuel and its carbonization will be completed therein. If the carbonization is completed in the combustion chamber, the fuel bed will retain the resultant coke which will be cooled and discharged with the coke produced in the fuel bed.
- the operations of carbonizing by the hot products of oxygen combustion and the cooling of the coke may be simultaneous and continuous, or they may be alternated if desired.
- the fuel bed may be in continuous descent as illustrated or the descent may be intermittent, due to periodic charging of fresh fuel and removal of coke.
- a descending flow of pulverized fuel may be established in the retort by feeding pulverized fuel at the top and removing coke at the bottom.
- the mid-section of this stream of fuel may be heated indirectly by the combustion of other fuel with oxygen in the combustion chamber and directly by passing the resultant hot products of combustion into the fuel stream and upward against the downward fall of the fuel, heating and carbonizing the fuel in the upper portion of the retort.
- a cooling agent as mixed products of oxygen combustion and coal gas or steam, may be introduced at the base of the retort to cool the coke and to be heated in the mid-section of the retort and assist in the carbonization above.
- all of the combustion need not all take place in the combustion chamber, a portion may take place in the carbonizing chamber, all of the combustion is not necessarily confined to the fuel supplied to the combustion chamber, a portion of the fuel fed to the carbonizing chamber may also be burned.
- a continuous process of carbonizing solid bituminous material with the production of coke and combustible gas which comprises providing a substantially Vertical column of solid bituminous material and feeding it downwardly longitudinally thereof into a closed space, carbonizing the material in said column by burning secondary fuel other than the material in said column in said space with an oxygen-containing gas having a greater proportion of free oxygen than atmospheric air, transferring heat to an intermediate portion of said column externally thereof from the products of the combustion but out of contact therewith, passing all the products of the combustion upwardly through said column in contact with the material therein, discharging the coke from said space, withdrawing the relatively cool mixture of coal gas and products of cumbustion from the column, and recirculating a portion of said relatively cool mixture of coal gas and products of combustion through the column to cool the coke and to become heated in the column and to transfer heat to carbonize the on-coming bituminous material.
- a continuous process of carbonizing solid bituminous fuel which comprises establishing a substantially vertical descending column of solid bituminous fuel, burning secondary fuel other than the material in said column with an oxygen-containing gas having a greater proportion of free oxygen than atmospheric air adjacent the middle portion of said column, admitting all the products of the combustion of the secondary fuel to said column, carbonizing the material in the intermediate portion of said fuel column by said burning of secondary fuel and by said products of combustion, causing products of combustion to ascend through the descending fuel column, taking off a portion of the gas so formed, and recirculating the remainder of the gas so formed from the bottom through the entire fuel column.
- a continuous process of carbonizin bituminous fuel according to claim 2 in wxich steam is passed to ether with the recirculated gas up throug the entire fuel column.
- a continuous process of carbonizing solid bituminous material with the production of coke and combustible gas comprises feeding asubstantially vertical column of solid bituminous material downward longitudinally thereof into a closed space, carbonizing the material in said co1- umn by continously burning pulverized coal in said space with an oxygen-containing gas that contains a greater proportion of free oxygen than atmospheric air in such a manner that the solid products of said combustion fall into the lower part of said column, transferring heat to an intermediate portion of said column externally thereof from the products of the combustion but out of contact therewith, passing the Huid products of combustion upwardly through said column in contact with the material therein, discharging the coke from said space, and leading olf mixed coal gas and products of combustion from the upper part of the column.
- a contlnuous process of carbonizing solid bituminous material with the production of coke and combustible gas which comprises feeding a substantially vertical column of solid bituminous material downwardly longitudinally thereof into a closed space, carbonizing the material in said column by continously burning secondary fuel other than the coke produced by said process in said space with an oxygen-containing gas that contains a greater proportion of free oxygen than atmospheric air, transferring heat to an intermediate portion of said column externally thereof from the products of the combustion but out of contact therewith, passing all the products of the combustion upwardly through said column in contact with the material therein, dischargin the coke from said space, leading of mixe coal gas and products of combustion from the upper part of the column, and recirculating a portlon of said mixture of coal gas and products of combustion through the entire column of fuel together with steam.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Description
July 4, 1933.
J. A. PERRY 1,917,196 PROCESS OF CARBONIZING SOLID BITUMINOUS FUEL Filed Feb. 27, 1929 T /9 2\ ul CLL-@um GIS Patented July 4, 1933` UNITED STATES PATENT OFFICE JOSEPH A. PERRY, OF SWARTHMORE, PENNSYLVANIA, ASSIGNOR T0 THE UNITED GAS IMPROVEMENT COMPANY, OF PHILADELPHIA, PENNSYLVANIA, A CORPORA- TION 0F PENNSYLVANIA PROCESS' OF CARBONIZING SOLID BITUMDIOUS FUEL Application filed February 27, 1929. Serial No. 343,091.
The present invention relates to thecarbonization of solid bituminous fuel by direct contact with hot gases.
More particularly it relates to the carbonization of such fuel by the contact of the hot products of combustion produced by the'combustion of fuel with an oxygen-containing medium that contains a greater proportionof free oxygen than does atmospheric air, with the production of coke and a, mixed gas consisting of coal gas and products of combustion relatively low in inert nitrogen.
The object of the invention is to provide an improved method for such carbonization.
In general the process includes establishing a continuous or intermittent flow of the bituminous material, one portion of which is comprised of uncarbonized and partially carbonized fuel in process of heating and another portion of which is comprised of coke resulting from the carbonization in process of cooling, establishing a hot zone intermediate of the ends of the flow of fuel by heating an intermediate portion, indirectly, by the combustion of other fuel with an oxygen containing gas that contains a greater proportion of free oxygen than atmospheric air, and directly, mentioned fuel the resultant hot products of combustion, passing them from the hot zone through the fuel in process of carbonizing to heat it and eifect carbonization, leading off the resultant mixed coal gas and products of combustion from the fuel, passing a. cooling agent through the coke resulting from the carbonization to cool it and from thence through the hot zone and through the fueI undergoing carbonization to assist in the carbonization.
The process will be particularly described in its application to a descendin fuel bed and in connection with the attac ed drawing which forms a part of this specification.
The drawing shows a partial\vertical cross section and elevation of apparatus chosen for illustration in which my process may be performed.
Referring to the drawing,
1 generally indicates the carbonizing chamber, containing a fuel bed the upper by leading into the first portion of which, indicated as 2, is comprised ofsolid bituminous fuel undergoing carbonization and the lower part of which, indicated as 3, is composed of coke resulting from the carbonization.
4 is a combustion chamber-provided with the fuel supply means and oxygen supply means 5 and arranged to heat the intermediate section of the fuel bed through the wall 6. The combustion chamber 4 is in communication with the fuel bed at a zone intermediate of the ends of the fuel bed.
The carbonizing chamber is provided with the gas off-take 7 leading from above the lfresh fuel through the valve 8 to the wash- 10 is the as off-take from the wash-box to a place o storage, not shown.
The off-take 7 may also be connected through the valvel 11 to the input side of the circulating means 12 (a fan, as shown for illustration). The output side of the fan is connected by connection 13 to the base of the fuel bed. eans for the continuous discharge of coke may be provided as for instance the travelling grate 14 which discharges to the hopper 15.
eans for continuous fuel may be provided charger indicated at 16.
17 is a steam supply means.
In operation fresh fuel such as bituminous coal, lignite, etc., is fed to the top of the fuel bed by .the charger 16 and cooled coke removed from its base by the grate 14.
Fuel and an oxygen-containing medium containing a greater proportion of free oxygen than does atmospheric air are admitted to the combustion chamber 4 and partially burned therein, heating the mid-section of the fuel bed indirectly through the wall 6. The products of combustion pass from the combustion chamber into the mid-section of the fuel bed heating it directly and pass upward through the fuel in the upper portion of the fuel bed effecting its carbonization and distilling olf its volatile material. The mixed coal gas and products of combustion give up their heat in contact with the fresh fuel in the upper portion'of the fuel .bed and charging of fresh if desired as the issue from the top of the fuel bed relatively cool. A portion of the mixed gas passes through connection 7 and valve 8 to the wash-box, the remainder is drawn through valve ll by the fan 12, passed by connection 13 to the base of the fuel bed and forced upward through the coke, cooling the coke in the passage. The mixed gas then passes through the highly heated zone and is heated therein and passes upward through the uncarbonized fuel above to assist in its carbonization.
Instead of recirculating the mixed gas to cool the coke, all of the mixed gas may be led directly to the wash-box and a small amount of steam, sufficient to cool the coke, may be admitted at 17 and passed upward through the fuel bed or steam may be mixed and recirculated with the gas produced The fuel introduced with oxygen, to the combustion chamber may be pulverized coal, oil, tar or gas. Preferably suhcient oxygen is introduced for its partial combustion only, thereby maintaining a low proportion of incombustible constituents in the resultant combustion gases.
The exact composition of the final mixed gas will depend, among other things, on the fuel introduced to the combustion chamber. In the case of oil or refinery oil gas, partial combustion with oxygen can be regulated to furnish combustionv products containing considerable amounts of hydrocarbons as well as carbon monoxide and hydrogen and the combustion products may have a rela- -tively high calorific value.
If the fuel supplied to the combustion chamber is pulverized coal, the supply of this fuel and the oxygen supply may be regulated to effect the partial or total carbonization of the pulverized fuel by combustion of a part of it.
As the combustion products are passed through the fuel bed, the fuel bed will retain the partially carbonized pulverized fuel and its carbonization will be completed therein. If the carbonization is completed in the combustion chamber, the fuel bed will retain the resultant coke which will be cooled and discharged with the coke produced in the fuel bed.
The operations of carbonizing by the hot products of oxygen combustion and the cooling of the coke may be simultaneous and continuous, or they may be alternated if desired.
The fuel bed may be in continuous descent as illustrated or the descent may be intermittent, due to periodic charging of fresh fuel and removal of coke.
While I may prefer to employ a fuel bed in the practice of my invention, it is also applicable to the carbonization of a stream of pulverized fuel. A descending flow of pulverized fuel may be established in the retort by feeding pulverized fuel at the top and removing coke at the bottom. The mid-section of this stream of fuel may be heated indirectly by the combustion of other fuel with oxygen in the combustion chamber and directly by passing the resultant hot products of combustion into the fuel stream and upward against the downward fall of the fuel, heating and carbonizing the fuel in the upper portion of the retort. A cooling agent, as mixed products of oxygen combustion and coal gas or steam, may be introduced at the base of the retort to cool the coke and to be heated in the mid-section of the retort and assist in the carbonization above.
In any of the above methods all of the combustion need not all take place in the combustion chamber, a portion may take place in the carbonizing chamber, all of the combustion is not necessarily confined to the fuel supplied to the combustion chamber, a portion of the fuel fed to the carbonizing chamber may also be burned.
I claim:
1. A continuous process of carbonizing solid bituminous material with the production of coke and combustible gas, which comprises providing a substantially Vertical column of solid bituminous material and feeding it downwardly longitudinally thereof into a closed space, carbonizing the material in said column by burning secondary fuel other than the material in said column in said space with an oxygen-containing gas having a greater proportion of free oxygen than atmospheric air, transferring heat to an intermediate portion of said column externally thereof from the products of the combustion but out of contact therewith, passing all the products of the combustion upwardly through said column in contact with the material therein, discharging the coke from said space, withdrawing the relatively cool mixture of coal gas and products of cumbustion from the column, and recirculating a portion of said relatively cool mixture of coal gas and products of combustion through the column to cool the coke and to become heated in the column and to transfer heat to carbonize the on-coming bituminous material.
2. A continuous process of carbonizing solid bituminous fuel, which comprises establishing a substantially vertical descending column of solid bituminous fuel, burning secondary fuel other than the material in said column with an oxygen-containing gas having a greater proportion of free oxygen than atmospheric air adjacent the middle portion of said column, admitting all the products of the combustion of the secondary fuel to said column, carbonizing the material in the intermediate portion of said fuel column by said burning of secondary fuel and by said products of combustion, causing products of combustion to ascend through the descending fuel column, taking off a portion of the gas so formed, and recirculating the remainder of the gas so formed from the bottom through the entire fuel column.
3. A continuous process of carbonizin bituminous fuel according to claim 2 in wxich steam is passed to ether with the recirculated gas up throug the entire fuel column.
4. A continuous process of carbonizing solid bituminous material with the production of coke and combustible gas, which process comprises feeding asubstantially vertical column of solid bituminous material downward longitudinally thereof into a closed space, carbonizing the material in said co1- umn by continously burning pulverized coal in said space with an oxygen-containing gas that contains a greater proportion of free oxygen than atmospheric air in such a manner that the solid products of said combustion fall into the lower part of said column, transferring heat to an intermediate portion of said column externally thereof from the products of the combustion but out of contact therewith, passing the Huid products of combustion upwardly through said column in contact with the material therein, discharging the coke from said space, and leading olf mixed coal gas and products of combustion from the upper part of the column.
5. A contlnuous process of carbonizing solid bituminous material with the production of coke and combustible gas, which comprises feeding a substantially vertical column of solid bituminous material downwardly longitudinally thereof into a closed space, carbonizing the material in said column by continously burning secondary fuel other than the coke produced by said process in said space with an oxygen-containing gas that contains a greater proportion of free oxygen than atmospheric air, transferring heat to an intermediate portion of said column externally thereof from the products of the combustion but out of contact therewith, passing all the products of the combustion upwardly through said column in contact with the material therein, dischargin the coke from said space, leading of mixe coal gas and products of combustion from the upper part of the column, and recirculating a portlon of said mixture of coal gas and products of combustion through the entire column of fuel together with steam.
JOSEPH A. PERRY.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US343091A US1917196A (en) | 1929-02-27 | 1929-02-27 | Process of carbonizing solid bituminous fuel |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US343091A US1917196A (en) | 1929-02-27 | 1929-02-27 | Process of carbonizing solid bituminous fuel |
Publications (1)
Publication Number | Publication Date |
---|---|
US1917196A true US1917196A (en) | 1933-07-04 |
Family
ID=23344675
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US343091A Expired - Lifetime US1917196A (en) | 1929-02-27 | 1929-02-27 | Process of carbonizing solid bituminous fuel |
Country Status (1)
Country | Link |
---|---|
US (1) | US1917196A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2589109A (en) * | 1945-12-29 | 1952-03-11 | Standard Oil Dev Co | Fluidized distillation of shale |
US2757129A (en) * | 1951-10-03 | 1956-07-31 | Adam A Reeves | Method for the destructive distillation of hydrocarbonaceous materials |
US4164397A (en) * | 1976-10-18 | 1979-08-14 | Hunt Herbert H | Fuel gas production |
-
1929
- 1929-02-27 US US343091A patent/US1917196A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2589109A (en) * | 1945-12-29 | 1952-03-11 | Standard Oil Dev Co | Fluidized distillation of shale |
US2757129A (en) * | 1951-10-03 | 1956-07-31 | Adam A Reeves | Method for the destructive distillation of hydrocarbonaceous materials |
US4164397A (en) * | 1976-10-18 | 1979-08-14 | Hunt Herbert H | Fuel gas production |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB301975A (en) | Improvements in the low-temperature carbonisation of fuels and in apparatus therefor | |
DD227594A3 (en) | FAST PYROLYSIS OF BROWN COALS AND ARRANGEMENT FOR IMPLEMENTING THE PROCESS | |
US2302156A (en) | Process and apparatus for the production of useful fuel gas | |
US3107985A (en) | Method for the continuous distillation of coal and other hydrocarbonaceous materials and for the autogenous hydrogenation of the condensable volatiles | |
US1866399A (en) | Continuous process for producing high heating value gas | |
US1917196A (en) | Process of carbonizing solid bituminous fuel | |
US2127542A (en) | Electrical carbonization of coal | |
US4305788A (en) | Process for the production of molded metallurgical coke from coal briquettes | |
US2094027A (en) | Apparatus for electrical carbonization of coal | |
US2773018A (en) | Continuous process for drying, preheating, and devolatilization of carbonaceous materials | |
US1718830A (en) | Apparatus for manufacturing water gas | |
US2190293A (en) | Process for the production of com | |
US3434931A (en) | Coke,tar,and clean coal gas producing method and apparatus | |
US1932296A (en) | Process for carbonizing solid carbonizable fuel | |
US1941462A (en) | Method of producing coked fuel agglomerates | |
US1785645A (en) | Apparatus for carbonizing and distilling carbonaceous materials | |
US1975396A (en) | Coal carbonizing apparatus | |
US1806146A (en) | Apparatus and process for coking liquefiable carbonaceous materials | |
US1913646A (en) | Complete gasification apparatus | |
US1009064A (en) | Gas-producer. | |
US1510442A (en) | Process of manufacturing hydrogen or gases rich in hydrogen | |
DE972423C (en) | Method for heating a vertical chamber furnace | |
US1247671A (en) | Distillation of heavy oils, oil residues, and bitumens. | |
US840461A (en) | Process of manufacturing producer-gas. | |
US2700596A (en) | Process and apparatus for the low-temperature carbonization and gasification of combustibles |