US1841036A - Manufacture of coke and combustible gas and apparatus therefor - Google Patents
Manufacture of coke and combustible gas and apparatus therefor Download PDFInfo
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- US1841036A US1841036A US5246A US524625A US1841036A US 1841036 A US1841036 A US 1841036A US 5246 A US5246 A US 5246A US 524625 A US524625 A US 524625A US 1841036 A US1841036 A US 1841036A
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- fuel
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- carbonizing
- water gas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J1/00—Production of fuel gases by carburetting air or other gases without pyrolysis
- C10J1/213—Carburetting by pyrolysis of solid carbonaceous material in a carburettor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Definitions
- This invention relates to the manufacture of coke and combustible gas, and more particularly to an improved method of and apparatus for making enriched water gas and high grade coke from caking bituminous' coal.
- the preheat of the gas is supplied by at-intervals alternating the gas superheating and fuel carbonizing operation with a heat regenerating operation during which the temperature of the carbonization prehcater is elevated by burning exhaust blast 'gases' or other low B( t. u. gases t-herein.
- water gas is employed as a heating and carbonizing medium, by which bituminous fuel is carbonized and its volatile components are driven off, the primary blast gases produced in the Water gas generator duringperiods of air blasting are burned in the preheater, and between periods of air blasting the make gas is passed through the highly ⁇ heated preheater and thence through the bed of bituminous fuel in the carbonizing shell.
- the primary object 'of the present invention is to provide an improved method and apparatus of the type above referred to by which large yields of high quality fuel gas and high grade coke can be simply, economically and effectively manufactured from caking bituminous coal.
- vAnother object of the invention is to reduce the number of pieces of apparatus from that normally employed and the loss of heat normally7 resulting from radiation to the at mosphere when water gas is employed as the 28, 1925.
- one feature 4of the invention contemplates discontinuing the use of a carbonization preheater as employed in the above described processes, and passing the gas"carbonizing me dium directly from the gas generator into a bed of'fuel to be carbonized.
- Another'object of the present invention is to provide a method and apparatus by means of which water gas can be effectively and economically manufactured and enriched with the volattile products of carbonization of bituminous raking coal.
- another feature of the invention contemplates using the sensible heat carried by water gas and the potential heat carried by primary blastgases at the time they leave the bed of fuel in the water gas generator to impart sufficient superheat to the Water gas to make it effective as the sole heating medium for carbonizing bi tuminous fuel and driving ofi' volatile hydrocarbons therefrom for its enrichment.
- Another object of the invention is to provvide a' method and apparatus by meansl of Awhich the enrichment of Water gas with the volatile products of fuel carbonization can be carried out with a more efficient utilization of heat.
- another feature of the invention contemplates burning blast gases with secondary air as they leave the top of the fuel bed in the water gas generator, storing the heat liberated by the secondary combustion as radiant energy Within the generator and fuel bed ⁇ and utilizing the heat thus stored to impart superheat to the Watergas within the generator and immediately before it enters the bed of raw bituminous fuel in the carbonizing shell.
- a water gas generator of the Doherty shaft type equipped with a refractory lining 12 and a superimposed radiation arch or dome 14.
- the arch 14 is raised above the normal fuel charging level of the generator to forma combustion chamber 16 beneath the roof of the generator and above the normal top layers 18 of the charge.
- Fuel is charged into the generator from a hopper 20 through a charging gate 22 and a charging neck 24.
- A. movably ⁇ mounted discharge mechanism 26 in the lower portion of the shaft serves to support the charge in a column andto discharge unconsumed fuel and ash from the base'of the column.
- Conduits 28 and 30 connect the interior of the generator the preferred form of the present invention 'is carried out in the apparatus illustrated in the drawing substantially as follows: Primary air is admitted periodically through a valved inlet 48 into the top of an auxiliary 40 chamber 49 of the regenerator unit 36, the relgenerator unit having been first preheated y the combustion of blow gases therein.
- the primary air passes downwardly through the hot checker brick lining of the auxiliary chamber and upwardly through the lining of a primary chamber 50, it absorbs preheat from the hot lining of the regenerator chambers, and is then passed by hot valve 51 through conduit 30 Into -a circumferential in.-
- the circumferential inlet 52 is' formed ybeneath rackback 32 and between the lining of the generator and the expanding surface of the column of fuel advancing therethrough. After entering the 55 fuel bed through the inlet 52 the preheated air rises upwardly through the column and as it reacts with the carbon of the fuel to produce low B. t. u.
- blast air entering through inlet 48 is cut olf and the air blow is followedv by a gas making run during which water or steam is admitted through a valved inlet 62 into ythe auxiliary chamber 63 of the regenerator unit 34, which has just been previously heated by the exhaust blast gases.
- Any Water admitted through the inlet 62 is rapidly vaporized by absorption of heat from the hot checker brick lining and as the steam thus produced passes downwardly through chamber 63 and upwardly through a primary chamber 64 of the regenerator unit 34 it absorbs superheatfrom the hot checker brick lining of the two chambers.
- the superheated steam is then passed into the generator and 'fuel bed either by a hot valve 65 in the conduit 28, or by hot valve 58 in the conduit 38.
- hot valve 58 is opened and hot valve 65 is closed, steam enters the generator at the top of the combustion chamber 16 and the manufacture of water gas is conducted on a down run.
- valve 58 is closed and valve 65. is opened the steam enters the fuel bed at the base of the incandescent zone,
- the gas making run maybe varied by at intervals changing the direction of flow ofthe steam through the'upper portion of the fuel bed.
- the water gas thereby made rises through the hot upper layers of the fuel bed into combustion chamber 16 and consequentlyv placed nozzlesv'56, the volume of secondary takes 0n ahigh degree of superheat by absorptioniof heat stored as radiant energy in the hot walls ofthe chamber and in the top layers of thefuel bed.
- This up-run water' gas leaves the top of the generator through conduit 42, and is passed by a hotvalve 43 directly into the circumferential passage .44 in the carbonizing shell 46.
- a hotvalve 43 directly into the circumferential passage .44 in the carbonizing shell 46.
- this uprun hot valve 58 in conduit 38' is closed.
- hot valve 65 in. conduit 28 is closed,
- Sufiicient secondary air is admitted through a valved inlet 71 in regenerator 36 to complete combustion of any unburned gases, and during the passage of the products of combustion through the linings of chamber 50 and chamber 49 substantially all the sensibleheat of thesewaste gases is taken up by the checkerbrick and they exit through stack valve 72 at the top of the auxiliary chamber 49 at a relatively low temperature.
- Regenerators 34 and 36 are equipped with air and steam inlets and auxiliary gas conduits as shown by means of which they can be used alternately for.preheating blast air,
- each of the air and steam inlets and the various gas con. nections to the regenerators is equipped with valves by means of which the direction of flow of air, steam and other gases through the entire apparatus can be periodically reversed.
- valved ofltak-es by means of which the direction of flow of make steam through the fuel bed can be periodically reversed to produce valves 51 in conduit 30, 70 in conduit 40, 58 in conduit 38 and 65 in conduit 28 afford the means of controlling the admission of steam from the two sets of regenerator units into lthe upper or lower portions of the generator, and these valves also afford the means of admitting blast air from the regenerator units into the generator and for removing waste blast gases from the generator into the regenerator units.
- fuel is advanced through generator l() continuously at about the rate at which -it is consumed by the air and steam admitted during the periods of air blowing and gas making.
- The. fuel maybe admitted at regular intervals, but it is preferably charged only during the gas making runs, in order that any volatile components which are rapidly liberated at the time the raw fuel strikes the hot upper layers of the fuel bed, may be carried off by the make gases as enriching agents and their valuable qualities thereby utilized rather than lost, as would would be the case if they are liberated and removed by the vprimary blast gases during periods of air blasting.
- The. mixture of ash, clinker and any unconsumed fuel which passes the.
- high temperature gasification zone of the generator is expanded into an enlarged chamber below the rack-back 32, wherein it is cooled and quenched bv a current of steam or other heat transferring gas charge by discharge mechanism 26.
- Steam .before being removed from the base of the for cooling the charge is admitted through an inlet and distributing coil 75 below the dischar e mechanism, and waste material such as asi and clinker which has been discharged from the base of the fuel bed is removed at intervals from the bottom of the generator through a sealed discharge door 76.
- This charge of ⁇ fuel ' may be either held in a stationary position during its carbonization or may be continuously advanced through the shaft at about the rate at which its carbon'ization is completed.
- the superheatcd water gas produced in the generator enters the column of fuel at about its mid portion, and where the fuel is advanced continuously through the carbonizing shaft, the superheated gas entering through inlet 44 is allowed to rise and distribute itself through each cross section of the downwardly advancing column.
- the temperature of the gas gradually drops as it rises, by direct heat transfer with the cooler portion of the freshly charged fuel adjacent the top ⁇ of shaft, and at the time the current of water gas leaves the top of the carbonizing ture as Well as the temperature of the volatile constituents distilled from the fuel and carried along in the gas current, has been reduced to a relatively low point (rarely eX- ceeding 500 F).
- the mixture of water gas and volatilecomponents distilled from the fuel/is preferably passed from offtake 82 directly to condensing and scrubbing apparatus (not shown).
- the carbonized fuel (coke) which has-'advanced beyond the rackback 78 is gradually expanded into an enlarged chamber below thnlet 44, and the coke in this chamber is gradually cooled by heat transfer with a counter-current circuit of steam or other cooling gas introduced at the base of the shaft through an inlet and distributing coil 84.
- Coke is continually discharged from the y base of the column by the operation of the discharge mechanism 80, and. at the same time fresh fuel is admitted in small portions to the top of the shell by a charging gate 86.
- the present process is not necessarily limited to the use of a gas generator, carbonizing shell, and auxiliary preheaters and regenerators of the type illustrated and described, although the arrangement described and illustrated embodies the preferred form of apparatus.
- the standard type of water gas generator can be adapted with slight alteration to serve the purpose of the invention admirably, both as a gas generator and as a fuel carbonizing shell.
- the altered generator would function in much the same way as the more charging level as particularly described in specialized type of Doherty shaft generator/ 123 illustrated and described as the preferred form.
- the standard type of generator will serve without any substantial alteration as a fuel carbonizing-shell.
- the bed of fuel serves much more efficiently as a screen for removing dust from the current of water gas and the water gas drives ahead of it heavy tar oils which have a tendency to condense out of the heating gas current as the gas cools and which in normal up-run .operations sometimes obstruct the flow f heating gas through the' fuel body.
- Theprincipal advantage in holding the fuel in a stationary position during carbonization is of course that the coke produced is not broken up and disintegrated to the extent that itis in cases Where it is advanced con- -tinuouslythrough the carbonizing shell, so
- ne of the chief ladvantages of the present invention is that the primary blast gases produced inthe generator are burned and a large lproportion of their potential heat is liberated and stored within the generator and fuel bed at a point where-it is immediately available for superheating the make gases and supporting complete decomposition of make steam.
- the make water gas is superheated before it leaves the generator and there is substantially no loss of sensible heat from the make gases and from the blow gases by radiation to the surrounding atmosphere.
- Ipassing-the waste blast gases through the pre eaters or regenerators 34 and 36 substantially all of the potential heat of the prima-ry blast ⁇ gases is recovered, and can be subsequently returned to the generator in the form of preheated blast air and superheated make steam.
- these several operations may be regulated by controlling the rate at which the superheated Water gas is passed through the 'bed of fuel in the carbonizing shell and by controlling the rate alt 'hich the fuel is advanced through the s 1e
- the process and apparatus may' be adapted with minor alterations to the treatment of anthracite coal, lignite, peat and oil shales.
- the 'method ofmaking high quality fuel gas and coke which comprises passino' air and steam alternately through a bed of ighly heated, solid carbonaceous fuel in a Water gas generator to produce blow gases and Water gas in'turn, introducing secondary air into the generator immediately above the fuel bed and thereby burning the blow gases therein, superheating the said Water gas within the generatorby absor tion of heat liberated as radiant energy rom the combustion of the blow gases and passing the superheated Water gas from the generator in direct heat transferring relationship through a body of bituminous fuel in a carbonizing shell thereby carbonizing'the bituminous fuel and carrying off its volatile components.
- the method of producinghigh quality uel gas and coke which comprises blasting a bed ,of highly' heated, solid carbonaceous fuel alternately with primary air and superheated'steam thereby generating blow gases and water gas in turn, introducing secondary air into the generator above the fuel bed and thereby burning the'blow gases, projecting heat thus liberated asradiant energy into the uppe'krJlayers of the fuel bed, passing water gas through the upper layersof the fuel bed to'absorb superheat therefrom, and conducting the superheated Water gas into and through a body of coking bituminous the water gas'with volatile hydrocarbons distilled therefrom.
- The'method of producing high quality fuel gas and coke which comprises passing air and steam alternately through a bed of highly heated, solid carbonaceousfel in -a water gas generator thereby producing water gas and blow gases in turn, introducing secy ondary air into the generator and thereby burning the blowV gases, projecting heat liberated by their combustion as radiant energy into the topof the generator and the upper vlayers of the fuel bed, passing water gas through the upper layers ofthe-fuel bed to absorb superheat therefrom, and passing the superheated water gas in direct heat transferring relationship with a body of solid bituminous fuel in a carbonizing shell thereby carbonizing the bituminous fuel 'and enriching the Water. gas with volatile hydrocarbons distilled therefrom.
- the method of producing high quality fuel gas and coke which comprises periodic ally introducing primary air peripherally into the mid-portion of a bed of highly heat'- ed, solid carbonaceous' fuel in a waterrgas generator, introducin secondary air into the generator above t e fuel bed and thereby burning the primary blast gases, regeny/erating heat liberated by combustion of blow v .gases in the upper layers of the fuel bed and in preheaters ring passage therethrough, passing steam in a reverse direction through the preheaters to absorb superheat and thence longitudinally through the fuel bed to generate water gas, passing the water gas through the upper layers of the fuel bed to absorb superheat, and passing a current of the superheated water gas into and through a bed ofcokingbituminous coal in a carbonizing shell thus carbonizing the coal andv heat liberated by the combustion of the blow gases into the upper layers of the fuel bed as radiant'energy,regenerating the sensible heat of the products of combustion ,in preheaters and -subsequently passing blast air
- the method of producing combustible gas and coke which comprises periodically basting primary air into the midportion of a bed vof highly heated, solid carbonaceous fuel in a water gas generator therebypro ducing blast gases, introducing secondary air into the generator above the fuel bed and thereby burning the primary blast gases, regenerating heat liberated by combustion of the blast gases in the vupper portion of the generatorand fuel bed and in preheaters during passage therethrough, passing'steam in a reverse direction through the preheaters and thence through the u per portion of the generator and intov the nel bed to absorb superheat and decompose the steam, passing the resultant superheated gaseous mixture through the said mid-portion of the fuel bed to generate water gas, and passing a current of the superheated water gas directly into and through a bed of bituminous fuel in a carbonizing shell, thus carbonizing the bituminous fuel and enriching the gas with volatile components distilled therefrom.v
- An apparatus for making enriched Water gas and coke comprising a gas generator and a carbonizing shell connected in series for functional co-operation, aradiation arch combustion chamber -in thev upper part of said generator, fuel char ng devices at the top of the generator an carbonizing shell and fuel discharging devices mounted in the base of each, a pair of preheaters, means connecting the preheaters and a circumferential blast inlet in the mid-portion of, the generator, similar means connecting the preheaters and gas oitakes at the top of the generator, valves in these connections for controlling the introduction of preheated blast air and superheated ymake steam from the preheaters respectively into the mid-portion ofthe gen'- erator and into the top thereof 'and forregulating the removal of primary blast gases and products of combustion from the generator through the preheaters, secondary air inlets in the upperportion of the generatolgyalves for controlling the admission of secondary air into 'the' generator through these inlets to,v burn a regulated'a
- An apparatus for making combustible gas-and coke comprising a water gas-generator having a circumferential blast inlet in its mid-portion, means for introducing preheated blast air and superheated steam al-A ternately into the generator through said inf let, an inlet for secondary air in the upper portion of the generator, means for controlling the combustion of primary blast gases with secondary air admitted through said inlets, a radiation arch at the top of the generator arranged to project heat liberated by the combustion of the blow gas as radiant energy downwardly in said generator, preheaters and means connecting the latter with a circumferential blast.
- the said preheaters being adapted for regenerating sensible heat from the products of secondary combustion, and means for conducting water gas through K the generator' to absorb superheat and thence into and through a carbonizing shell to carbonize the fuel and drive off its volatile components.
- An apparatus for making high quality fuel gas and coke comprising a gas generator having a radiation ,arch combustion chamber at its top, afuel carbonizing shellblast air and make steam inlets in the lower portion of/ the generator and a secondary air inlet in the 'upper part of the generator but substantially below the radiation arch therein, regeneerators connected to the blast air and make steam inlets and to exhaust gas oftakes in the top of the generator, valves in the blast inlets and gas ofl'takes for reversing the direction of iiow ofblast air, steam, and waste blast gases through the regenerators and generator, and means for conducting superheated Water gas from the gas generator directly into and through a bed of fuel in the carbonizing shell.
- An apparatus for making combustible gas comprising a water gas generator and a fuel carbonizing shell, a radiation arch combustion chamber atthe top of the gas generator,.means in the lower portion of the combustion chamber for introducing secondary air therein to burn'blow gases produced in the generator during periods of air blowing, means for introducing steam into the top oif the combustion chamber to absorb radiant vheat liberated by combustion of the blow gases, means for conducting the thus superheatcd steam downwardly throughvthe gas generator to generate water gas, means for passmg the superheated water gas d1rectly from the generator into and through the carbonizing shell, and means for controlling the degree to which steam is superheated and decomposed an ⁇ d ⁇ .the degree of superheat iinparted to water gas in the gas generator.
- the method of producing high quality fuel gas and coke' which comprisesthe steps of passing air through a column of highly heated, solid carbonaceous fuel in a water gas generator thereby producing blow gases, introducing secondary air into the generator immediately adjacent the surface ofthe fuely bed and thereby burning the blow gases and radiating heat to the generator and the fuel bed, thereafter passin said bed of fuel to pro uce water gas, superheating the water gas by absorption of the said radiated heat from the generator and fuel bed, at intervals changing the direction of How of the steam passing through a portion of the said fuel bed, and passing the superheated water gas from the generator in direct heat exchange relationship with a body of bituminous fuel in a carbonizing shell thus carbonizing the bituminous fuel and carrying a fuel gas and coke from solid carbonizable material, which comprises superheating water gas, and continuously passing the superst-eam through the,
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Description
Jn. 12, 1932. JOHNSON Y 1,841,036
MANUFACTURE OF COKE AND COMBUSTIBL GAS AND APPARATUS THEREFOR Filed Jan. 2,8, 1925 WW/m Patented Jan. 12, 1932 UNITED STATES PATEN T OFFICE ALFRED JOHNSON, OF WESTERLEIGH, NEW YORK, .ASSIGNOR TO COMBUSTION UTILITIES CORPORATION, F NEW YORK, N. Y., A CORPORATION OF MAINE C MANUFACTUREOF COKE AND COMBUSTIBLE GAS AND APPARATUS TVHEREI'OR` Application led January This invention relates to the manufacture of coke and combustible gas, and more particularly to an improved method of and apparatus for making enriched water gas and high grade coke from caking bituminous' coal.
.Several processes for making high quality fuel gas have been developed in which the calorilic value ofa low B. t. u.gas,v such as l producer' gas, blast furnace gas or water gas` is raised by passing the gas from its genera- -tor through a previously heated carbonization prehcater to be super-heated and thence in direct heat transferring relationship with i a bed of bituminous fuel to carbonize the fuel and carry olf thevolatile components distilled from the fuel for its enrichment. Itis necessary to impart a high degree of superheat to the current of low B. t. u. gas in order l to effect the carbonization of the raw fuel. According to the above processes the preheat of the gas is supplied by at-intervals alternating the gas superheating and fuel carbonizing operation with a heat regenerating operation during which the temperature of the carbonization prehcater is elevated by burning exhaust blast 'gases' or other low B( t. u. gases t-herein. When water gas is employed as a heating and carbonizing medium, by which bituminous fuel is carbonized and its volatile components are driven off, the primary blast gases produced in the Water gas generator duringperiods of air blasting are burned in the preheater, and between periods of air blasting the make gas is passed through the highly` heated preheater and thence through the bed of bituminous fuel in the carbonizing shell.
The primary object 'of the present invention is to provide an improved method and apparatus of the type above referred to by which large yields of high quality fuel gas and high grade coke can be simply, economically and effectively manufactured from caking bituminous coal.
vAnother object of the invention is to reduce the number of pieces of apparatus from that normally employed and the loss of heat normally7 resulting from radiation to the at mosphere when water gas is employed as the 28, 1925. Serial No. 5,246.
sole heat transferring medium for carbonizing bituminous fuel.
In accordance with these objects one feature 4of the invention contemplates discontinuing the use of a carbonization preheater as employed in the above described processes, and passing the gas"carbonizing me dium directly from the gas generator into a bed of'fuel to be carbonized.
Another'object of the present invention is to provide a method and apparatus by means of which water gas can be effectively and economically manufactured and enriched with the volattile products of carbonization of bituminous raking coal.
In accordance with this object another feature of the invention contemplates using the sensible heat carried by water gas and the potential heat carried by primary blastgases at the time they leave the bed of fuel in the water gas generator to impart sufficient superheat to the Water gas to make it effective as the sole heating medium for carbonizing bi tuminous fuel and driving ofi' volatile hydrocarbons therefrom for its enrichment.`
Another object of the invention is to provvide a' method and apparatus by meansl of Awhich the enrichment of Water gas with the volatile products of fuel carbonization can be carried out with a more efficient utilization of heat.
Accordingly, another feature of the invention contemplates burning blast gases with secondary air as they leave the top of the fuel bed in the water gas generator, storing the heat liberated by the secondary combustion as radiant energy Within the generator and fuel bed` and utilizing the heat thus stored to impart superheat to the Watergas within the generator and immediately before it enters the bed of raw bituminous fuel in the carbonizing shell.
lVith these and other objects and features in View the invention consists essentially in the improved method of and apparatus for making enriched water gas and high quality coke hereinafter described and particularly defined inthe claims.
The vvarious features of the invention are illustrated in the accompanying drawing,
which shows in vertical section the arrangement of apparatus embodying the preferred form of the invention.
In the apparatus illustrated in the drawing represents a water gas generator of the Doherty shaft type equipped with a refractory lining 12 and a superimposed radiation arch or dome 14. The arch 14 is raised above the normal fuel charging level of the generator to forma combustion chamber 16 beneath the roof of the generator and above the normal top layers 18 of the charge. Fuel is charged into the generator from a hopper 20 through a charging gate 22 and a charging neck 24. A. movably` mounted discharge mechanism 26 in the lower portion of the shaft serves to support the charge in a column andto discharge unconsumed fuel and ash from the base'of the column. Conduits 28 and 30 connect the interior of the generator the preferred form of the present invention 'is carried out in the apparatus illustrated in the drawing substantially as follows: Primary air is admitted periodically through a valved inlet 48 into the top of an auxiliary 40 chamber 49 of the regenerator unit 36, the relgenerator unit having been first preheated y the combustion of blow gases therein. As
the primary air passes downwardly through the hot checker brick lining of the auxiliary chamber and upwardly through the lining of a primary chamber 50, it absorbs preheat from the hot lining of the regenerator chambers, and is then passed by hot valve 51 through conduit 30 Into -a circumferential in.-
let 52 in the generator 10. The circumferential inlet 52 is' formed ybeneath rackback 32 and between the lining of the generator and the expanding surface of the column of fuel advancing therethrough. After entering the 55 fuel bed through the inlet 52 the preheated air rises upwardly through the column and as it reacts with the carbon of the fuel to produce low B. t. u. o`r primary blast gases, the temperature of the fuel bed adjacent the cir cumferential blast inlet 52 is rapidly raised to .incandescence Secondary air, with or.with v out preheat, is simultaneously admitted to the generator from a distributor 54, through valves 55 and a number of circumferentially raw bituminous fuel inl combustion chamber through conduit 38 and Ik] are passed by hot valve 58 into and through the checker brick linings of the two sections `of regenerator unit 34. Any of the primary blast gases which are unconsumed at the'time they leave the combustion chamber 16 are burned by admitting a regulated volume of secondary air into the top of the regeneraytor 34 through a valved inlet 59. The checker brick lining of the regenerator unit absorbs the sensible heat of these products of secondary combustion, and accordingly they are exhausted through stack valve 60A at a relatively low temperature.
After the temperature of the fuel bed has been raised sufficiently to support water gas reactions, blast air entering through inlet 48 is cut olf and the air blow is followedv by a gas making run during which water or steam is admitted through a valved inlet 62 into ythe auxiliary chamber 63 of the regenerator unit 34, which has just been previously heated by the exhaust blast gases. Any Water admitted through the inlet 62 is rapidly vaporized by absorption of heat from the hot checker brick lining and as the steam thus produced passes downwardly through chamber 63 and upwardly through a primary chamber 64 of the regenerator unit 34 it absorbs superheatfrom the hot checker brick lining of the two chambers. The superheated steam is then passed into the generator and 'fuel bed either by a hot valve 65 in the conduit 28, or by hot valve 58 in the conduit 38. When hot valve 58 is opened and hot valve 65 is closed, steam enters the generator at the top of the combustion chamber 16 and the manufacture of water gas is conducted on a down run. When valve 58 is closed and valve 65. is opened the steam enters the fuel bed at the base of the incandescent zone,
and the gas making run resembles the up run of `normal practice.- The gas making run maybe varied by at intervals changing the direction of flow ofthe steam through the'upper portion of the fuel bed. During the period in which steam is admitted into the generator through conduit 28 andthe circumferential passage 52, i. e. the up-run period, the water gas thereby made rises through the hot upper layers of the fuel bed into combustion chamber 16 and consequentlyv placed nozzlesv'56, the volume of secondary takes 0n ahigh degree of superheat by absorptioniof heat stored as radiant energy in the hot walls ofthe chamber and in the top layers of thefuel bed. This up-run water' gas leaves the top of the generator through conduit 42, and is passed by a hotvalve 43 directly into the circumferential passage .44 in the carbonizing shell 46. During this uprun hot valve 58 in conduit 38' is closed. During the down-run hot valve 58 is opened, hot valve 65 in. conduit 28 is closed,
.and the make gases are withdrawn through Zone. Accordingly, larger volumes of water gas can be produced during the down run and this down run gas vleaves the fuel bed in a substantially dry condition and generally carries sufficient superheatto carbonize a proportionate. amount of fuel in the carbonizing shell.
After the temperature of the fuel bed has been lowered below that at which the water gas reaction proceeds effectively the steam is cut off at inlet 62 and the gas making run is followed by another air blow during which air is admitted through a valved inlet 68 at the top of the auxiliary chamber 63 of the regenerator 34, such regenerator having served during the make cycle for imparting superheat to the make steam. During this blow the blast air and primarv blast gases pass through the apparatus in the reverse direction to that taken by the air and blast gases during the preceding blow, and accordingly the waste blast gas products of the secondary combustion in combustion chamber 16 during this cycle exit from the 'generator through conduit 40 and are passed by a hot valve 70 into and through the checker brick linings of the regenerator unit 36. Sufiicient secondary air is admitted through a valved inlet 71 in regenerator 36 to complete combustion of any unburned gases, and during the passage of the products of combustion through the linings of chamber 50 and chamber 49 substantially all the sensibleheat of thesewaste gases is taken up by the checkerbrick and they exit through stack valve 72 at the top of the auxiliary chamber 49 at a relatively low temperature.
After the temperature of the fuel bed has again been raised to incandescence by the blow cycle just described the air is cut oil' at inlet 68 and during the next gas making run water or steam is admitted through a valved inlet 74 into the top of the auxiliary chamber 49 of regenerator unit 36. The superheated steam enters the generator during the down run through conduit 40 and during the up runs through the conduit 30. During the up runs valve 5l will be opened and valve 70 will be closed. Likewise during the down run valve 70iwill be opened and valve 51 Will be closed. The supcrheated water gas produced during thc down runs is passed by hot valve 67 ythrough conduit 66 into the carbonizing shell', and the gas produced during the up runs is passed by valve 43 through conduit 42 into inlet 44 in the carbonizing shell.
Regenerators 34 and 36 are equipped with air and steam inlets and auxiliary gas conduits as shown by means of which they can be used alternately for.preheating blast air,
.for regenerating the sensible heat of the waste blast gases and for generating and supcrheating the make steam. Each of the air and steam inlets and the various gas con. nections to the regenerators is equipped with valves by means of which the direction of flow of air, steam and other gases through the entire apparatus can be periodically reversed. Likewise the generator 10 is equipped with valved ofltak-es by means of which the direction of flow of make steam through the fuel bed can be periodically reversed to produce valves 51 in conduit 30, 70 in conduit 40, 58 in conduit 38 and 65 in conduit 28 afford the means of controlling the admission of steam from the two sets of regenerator units into lthe upper or lower portions of the generator, and these valves also afford the means of admitting blast air from the regenerator units into the generator and for removing waste blast gases from the generator into the regenerator units.
According to the preferred method of operation above described fuel is advanced through generator l() continuously at about the rate at which -it is consumed by the air and steam admitted during the periods of air blowing and gas making. The. fuel maybe admitted at regular intervals, but it is preferably charged only during the gas making runs, in order that any volatile components which are rapidly liberated at the time the raw fuel strikes the hot upper layers of the fuel bed, may be carried off by the make gases as enriching agents and their valuable qualities thereby utilized rather than lost, as would would be the case if they are liberated and removed by the vprimary blast gases during periods of air blasting. The. mixture of ash, clinker and any unconsumed fuel which passes the. high temperature gasification zone of the generator is expanded into an enlarged chamber below the rack-back 32, wherein it is cooled and quenched bv a current of steam or other heat transferring gas charge by discharge mechanism 26. Steam .before being removed from the base of the for cooling the charge is admitted through an inlet and distributing coil 75 below the dischar e mechanism, and waste material such as asi and clinker which has been discharged from the base of the fuel bed is removed at intervals from the bottom of the generator through a sealed discharge door 76.
Although the Water gas produced in the ref generator during down-runs does' not receive a subsequent superheating treatment such as that imparted to thev up-run gas, it
. shell through an offtake pipe 82, its temperait nevertheless carries a relatively high degree of-superheat by reason of the fact that the make steam admitted at the top'of the combustion chamber 16 during the downrun absorbs a much higher degree of superheat and enters the fuel much more completely decomposed than does the make steam admitted through circumferentialinlet 52 during the up-run. The water gas which enters the carbonizing shell 46 during both the `up-and down-runs carries a sufficient degree of superheat to make it very effective as the sole agent for carbonizing charges of coking bitumlnous coal.
.passage 44 and beneath a rackback 7 8 which resembles in its construction the rackback 32 in the gas generator. A charge ofl bituminous fuel such as coal and the like which is to be carbonized and the volatile components of Which are to serve as enriching agents for increasing the calorific value of water gas produced in the generator, is supported in the carbonizing shell in a column by means of a discharge mechanism 80, mounted in the base Yof shaft 46. This charge of` fuel 'may be either held in a stationary position during its carbonization or may be continuously advanced through the shaft at about the rate at which its carbon'ization is completed. In either case the superheatcd water gas produced in the generator enters the column of fuel at about its mid portion, and where the fuel is advanced continuously through the carbonizing shaft, the superheated gas entering through inlet 44 is allowed to rise and distribute itself through each cross section of the downwardly advancing column. The temperature of the gas gradually drops as it rises, by direct heat transfer with the cooler portion of the freshly charged fuel adjacent the top `of shaft, and at the time the current of water gas leaves the top of the carbonizing ture as Well as the temperature of the volatile constituents distilled from the fuel and carried along in the gas current, has been reduced to a relatively low point (rarely eX- ceeding 500 F). The mixture of water gas and volatilecomponents distilled from the fuel/is preferably passed from offtake 82 directly to condensing and scrubbing apparatus (not shown).
No air is admitted yinto the carbonizing shell during the carbonization of the fuel, and accordingly the .temperatures which are maintained in that portion of the bed of fuel adjacent the circumferential inlet 44, while higher than those in any other portion of the shell, are nevertheless much lower than the temperatures which are normally maintained in the air blast zone 0f the gas generator. As a` result of these relatively low temperatures the volatile components distilled from the bituminous fuel and carried out of the 'shaft by the water gas carbonizing medium are never subjected to temperatures much in cir-V cess of those at which they are liberated from the fuel. Consequently they undergo little decomposition and the. portions precipitated in condensing and scrubbing the gas are the ,very finest grade of primary tar oils. When the fuel is advanced through the carbonizing shell at about the rate at which its carbonization is completed, the carbonized fuel (coke) which has-'advanced beyond the rackback 78 is gradually expanded into an enlarged chamber below thnlet 44, and the coke in this chamber is gradually cooled by heat transfer with a counter-current circuit of steam or other cooling gas introduced at the base of the shaft through an inlet and distributing coil 84. Coke is continually discharged from the y base of the column by the operation of the discharge mechanism 80, and. at the same time fresh fuel is admitted in small portions to the top of the shell by a charging gate 86.
The present process is not necessarily limited to the use of a gas generator, carbonizing shell, and auxiliary preheaters and regenerators of the type illustrated and described, although the arrangement described and illustrated embodies the preferred form of apparatus. The standard type of water gas generator can be adapted with slight alteration to serve the purpose of the invention admirably, both as a gas generator and as a fuel carbonizing shell. Thus by raising the top of the standard generatorand 'installing secondary air inlets above the normal fuel my co-pending application, on the manufacture of water gas, Serial No. 5,245 filed January 28, 1925, the altered generator would function in much the same way as the more charging level as particularly described in specialized type of Doherty shaft generator/ 123 illustrated and described as the preferred form. The standard type of generator will serve without any substantial alteration as a fuel carbonizing-shell.
As previously indicated, it is not essentialgoing distillationby heat transfer with the current of superheated water gas.
`In operations where the fuel undergoing carbonization is maintained stationary, it is yoften advantageous to pass all or a portion of the superheated gas carbonizing medium downwardlyv through the column of fuel and to remove the gas and volatile products of i fuel carbonization from the lower portion of. the shell through an auxiliary gas ofl'take 88'.'
y By conducting the fuel carbonization in this manner the bed of fuel serves much more efficiently as a screen for removing dust from the current of water gas and the water gas drives ahead of it heavy tar oils which have a tendency to condense out of the heating gas current as the gas cools and which in normal up-run .operations sometimes obstruct the flow f heating gas through the' fuel body. Theprincipal advantage in holding the fuel in a stationary position during carbonization is of course that the coke produced is not broken up and disintegrated to the extent that itis in cases Where it is advanced con- -tinuouslythrough the carbonizing shell, so
that the yield of high grade coke is large and the volume of fines or breeze produced is corres o ndingly small.
ne of the chief ladvantages of the present invention is that the primary blast gases produced inthe generator are burned and a large lproportion of their potential heat is liberated and stored within the generator and fuel bed at a point where-it is immediately available for superheating the make gases and supporting complete decomposition of make steam. As a result the make water gas is superheated before it leaves the generator and there is substantially no loss of sensible heat from the make gases and from the blow gases by radiation to the surrounding atmosphere. By Ipassing-the waste blast gases through the pre eaters or regenerators 34 and 36 substantially all of the potential heat of the prima-ry blast `gases is recovered, and can be subsequently returned to the generator in the form of preheated blast air and superheated make steam. Thus the combination of radiation arch generator and carbonizing shell, with auxiliary preheaters or regenerators such as those described, gives an apparatus by means of which the manufacture of high quality fuel gas, i. e., enriched Watergas, high grade coke and prima-ry tar oils, can be carried on yvery economically, with an extremely high thermal efli'ciency, and on a substantially balanced thermal'cycle. p
It is apparent that the degree of superheat imparted'to the water gas carbonizing me- Y dium, the degree to which fuel in the carbonizing shell is coked, the degree to which the make steam is'decomposed,and the degree to which the water gasl is enriched with'volatile the top of the gas generator through valves and'nost'rils 5G. Likewise, these several operations may be regulated by controlling the rate at which the superheated Water gas is passed through the 'bed of fuel in the carbonizing shell and by controlling the rate alt 'hich the fuel is advanced through the s 1e While the invention is directed primarily to the production of high quality fuel gas and high grade coke, together with primary byproducts, and consequently bituminous coal is the preferred fuel, the process and apparatus may' be adapted with minor alterations to the treatment of anthracite coal, lignite, peat and oil shales.
By usingtwo or more gas generators such as those described, equipped with radiation arch combustion chambers and auxiliary preheaters, in combination with one or more fuel carbonizing units, it is possible to carry on a continuous fuel carbonizing and gas enriching operation. Thus where two generators are employed they can be operated alternately on gas making runs and on air blast cycles to maintain a continuous fiow of superheated water gas through the bed of fuel in the carbonizing shell.
Having thus described my invention, what I claim as new is:
1. The 'method ofmaking high quality fuel gas and coke which comprises passino' air and steam alternately through a bed of ighly heated, solid carbonaceous fuel in a Water gas generator to produce blow gases and Water gas in'turn, introducing secondary air into the generator immediately above the fuel bed and thereby burning the blow gases therein, superheating the said Water gas within the generatorby absor tion of heat liberated as radiant energy rom the combustion of the blow gases and passing the superheated Water gas from the generator in direct heat transferring relationship through a body of bituminous fuel in a carbonizing shell thereby carbonizing'the bituminous fuel and carrying off its volatile components.
2. The method of producinghigh quality uel gas and coke which comprises blasting a bed ,of highly' heated, solid carbonaceous fuel alternately with primary air and superheated'steam thereby generating blow gases and water gas in turn, introducing secondary air into the generator above the fuel bed and thereby burning the'blow gases, projecting heat thus liberated asradiant energy into the uppe'krJlayers of the fuel bed, passing water gas through the upper layersof the fuel bed to'absorb superheat therefrom, and conducting the superheated Water gas into and through a body of coking bituminous the water gas'with volatile hydrocarbons distilled therefrom.
' 3. The'method of producing high quality fuel gas and coke which comprises passing air and steam alternately through a bed of highly heated, solid carbonaceousfel in -a water gas generator thereby producing water gas and blow gases in turn, introducing secy ondary air into the generator and thereby burning the blowV gases, projecting heat liberated by their combustion as radiant energy into the topof the generator and the upper vlayers of the fuel bed, passing water gas through the upper layers ofthe-fuel bed to absorb superheat therefrom, and passing the superheated water gas in direct heat transferring relationship with a body of solid bituminous fuel in a carbonizing shell thereby carbonizing the bituminous fuel 'and enriching the Water. gas with volatile hydrocarbons distilled therefrom.
4. The method of producing high quality fuel gas and coke which comprises periodic ally introducing primary air peripherally into the mid-portion of a bed of highly heat'- ed, solid carbonaceous' fuel in a waterrgas generator, introducin secondary air into the generator above t e fuel bed and thereby burning the primary blast gases, regeny/erating heat liberated by combustion of blow v .gases in the upper layers of the fuel bed and in preheaters ring passage therethrough, passing steam in a reverse direction through the preheaters to absorb superheat and thence longitudinally through the fuel bed to generate water gas, passing the water gas through the upper layers of the fuel bed to absorb superheat, and passing a current of the superheated water gas into and through a bed ofcokingbituminous coal in a carbonizing shell thus carbonizing the coal andv heat liberated by the combustion of the blow gases into the upper layers of the fuel bed as radiant'energy,regenerating the sensible heat of the products of combustion ,in preheaters and -subsequently passing blast air and make steam through the preheaters to absorb superheat, .passing the make steam through the upper layers of the fuel bed to absorb further superheat and to .produce superheated water gas, and passing the superheated water gas through a body of solid carbonizable fuel in a carbonizing shell thereby carbonizing the carbonizablefuel and enriching the gas with volatile hydrocarbons distilled therefrom.
6. The method of producing high quality fuel gas and coke whchcomprises blasting a bed of highly heated, solid carbonaceous fuel in a water gas generatorprovided with a radiation arch' alternately with primary air and superheated steam thereby forming blow gases and water gas in turn, introducing secondary air into the upper portion of the generator thereby burning the blow gases, passing the make. gases from the'- steam blastI through the upper portion of the 'generator and fuel bed to superheat the gases by absorp 7. The method of producing combustible gas and coke which comprises periodically basting primary air into the midportion of a bed vof highly heated, solid carbonaceous fuel in a water gas generator therebypro ducing blast gases, introducing secondary air into the generator above the fuel bed and thereby burning the primary blast gases, regenerating heat liberated by combustion of the blast gases in the vupper portion of the generatorand fuel bed and in preheaters during passage therethrough, passing'steam in a reverse direction through the preheaters and thence through the u per portion of the generator and intov the nel bed to absorb superheat and decompose the steam, passing the resultant superheated gaseous mixture through the said mid-portion of the fuel bed to generate water gas, and passing a current of the superheated water gas directly into and through a bed of bituminous fuel in a carbonizing shell, thus carbonizing the bituminous fuel and enriching the gas with volatile components distilled therefrom.v
8. An apparatus for making enriched Water gas and coke comprising a gas generator and a carbonizing shell connected in series for functional co-operation, aradiation arch combustion chamber -in thev upper part of said generator, fuel char ng devices at the top of the generator an carbonizing shell and fuel discharging devices mounted in the base of each, a pair of preheaters, means connecting the preheaters and a circumferential blast inlet in the mid-portion of, the generator, similar means connecting the preheaters and gas oitakes at the top of the generator, valves in these connections for controlling the introduction of preheated blast air and superheated ymake steam from the preheaters respectively into the mid-portion ofthe gen'- erator and into the top thereof 'and forregulating the removal of primary blast gases and products of combustion from the generator through the preheaters, secondary air inlets in the upperportion of the generatolgyalves for controlling the admission of secondary air into 'the' generator through these inlets to,v burn a regulated'amount of blow. gases in.
the radiation arch con'ibu'stion chamber,and means for conducting'water gas prodgced in the generator and superheated in lthe upper portion of the generator into and through thefcarbonizing shell.
9. An apparatus for making combustible gas-and coke comprising a water gas-generator having a circumferential blast inlet in its mid-portion, means for introducing preheated blast air and superheated steam al-A ternately into the generator through said inf let, an inlet for secondary air in the upper portion of the generator, means for controlling the combustion of primary blast gases with secondary air admitted through said inlets, a radiation arch at the top of the generator arranged to project heat liberated by the combustion of the blow gas as radiant energy downwardly in said generator, preheaters and means connecting the latter with a circumferential blast. inlet in the mid-portion of the generator, the said preheaters being adapted for regenerating sensible heat from the products of secondary combustion, and means for conducting water gas through K the generator' to absorb superheat and thence into and through a carbonizing shell to carbonize the fuel and drive off its volatile components.
10. 'An apparatus for making high quality fuel gas and coke which comprises a water gas generator and a fuel carbonizing shell, a radiation arch combustion chamber at the top of the -gas generator, means for introducing secondary air into the combustion chamber to burn blow gases produced during periods of air blowing, and means for passing water gas upwardly in' said generator and combustion chamber to absorb radiant heat liberated by combustion of the blow gases and thence into and through the carbonizing shell,means for removing enriched water gas from the top of the/pcarbonizing shell, and
means for` discharging coke from the base of the shell.
l1. An apparatus for making high quality fuel gas and coke comprising a gas generator having a radiation ,arch combustion chamber at its top, afuel carbonizing shellblast air and make steam inlets in the lower portion of/ the generator and a secondary air inlet in the 'upper part of the generator but substantially below the radiation arch therein, regeneerators connected to the blast air and make steam inlets and to exhaust gas oftakes in the top of the generator, valves in the blast inlets and gas ofl'takes for reversing the direction of iiow ofblast air, steam, and waste blast gases through the regenerators and generator, and means for conducting superheated Water gas from the gas generator directly into and through a bed of fuel in the carbonizing shell.
12. An apparatus for making combustible gas comprising a water gas generator and a fuel carbonizing shell, a radiation arch combustion chamber atthe top of the gas generator,.means in the lower portion of the combustion chamber for introducing secondary air therein to burn'blow gases produced in the generator during periods of air blowing, means for introducing steam into the top oif the combustion chamber to absorb radiant vheat liberated by combustion of the blow gases, means for conducting the thus superheatcd steam downwardly throughvthe gas generator to generate water gas, means for passmg the superheated water gas d1rectly from the generator into and through the carbonizing shell, and means for controlling the degree to which steam is superheated and decomposed an\d\.the degree of superheat iinparted to water gas in the gas generator.
13. The method of producing high quality fuel gas and coke' which comprisesthe steps of passing air through a column of highly heated, solid carbonaceous fuel in a water gas generator thereby producing blow gases, introducing secondary air into the generator immediately adjacent the surface ofthe fuely bed and thereby burning the blow gases and radiating heat to the generator and the fuel bed, thereafter passin said bed of fuel to pro uce water gas, superheating the water gas by absorption of the said radiated heat from the generator and fuel bed, at intervals changing the direction of How of the steam passing through a portion of the said fuel bed, and passing the superheated water gas from the generator in direct heat exchange relationship with a body of bituminous fuel in a carbonizing shell thus carbonizing the bituminous fuel and carrying a fuel gas and coke from solid carbonizable material, which comprises superheating water gas, and continuously passing the superst-eam through the,
15. The method of producing high quality heated water gas through a moving mass of the said material in a carbonizing shell, thereby carbonizing the mass,kand controlling the direction of ow of the superheated water gasthrough the said mass .during such carbonization.
` In testimony whereof I aHix my signature.
ALFRED JOHNSON.
Priority Applications (1)
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US5246A US1841036A (en) | 1925-01-28 | 1925-01-28 | Manufacture of coke and combustible gas and apparatus therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US5246A US1841036A (en) | 1925-01-28 | 1925-01-28 | Manufacture of coke and combustible gas and apparatus therefor |
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US1841036A true US1841036A (en) | 1932-01-12 |
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US5246A Expired - Lifetime US1841036A (en) | 1925-01-28 | 1925-01-28 | Manufacture of coke and combustible gas and apparatus therefor |
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- 1925-01-28 US US5246A patent/US1841036A/en not_active Expired - Lifetime
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