US1709523A - Anode - Google Patents

Anode Download PDF

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Publication number
US1709523A
US1709523A US236562A US23656227A US1709523A US 1709523 A US1709523 A US 1709523A US 236562 A US236562 A US 236562A US 23656227 A US23656227 A US 23656227A US 1709523 A US1709523 A US 1709523A
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US
United States
Prior art keywords
eyelet
hook
anode
core
cadmium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US236562A
Inventor
Frank J Delavie
Howard H Blouch
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Grasselli Chemical Co
Original Assignee
Grasselli Chemical Co
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Filing date
Publication date
Application filed by Grasselli Chemical Co filed Critical Grasselli Chemical Co
Priority to US236562A priority Critical patent/US1709523A/en
Application granted granted Critical
Publication of US1709523A publication Critical patent/US1709523A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode
    • C25D17/12Shape or form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S29/00Metal working
    • Y10S29/012Method or apparatus with electroplating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12222Shaped configuration for melting [e.g., package, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12361All metal or with adjacent metals having aperture or cut
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12785Group IIB metal-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12785Group IIB metal-base component
    • Y10T428/12792Zn-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12951Fe-base component
    • Y10T428/12972Containing 0.01-1.7% carbon [i.e., steel]

Definitions

  • This invention relates to anodes which are particularly suited for usein electroplating objects of varying-lengths such as, for instance, lamp posts, pipe, etc, 5
  • the anodes each consist of a rod-of inert conductive material carrying a body; of the anodic metal.
  • the rod is provided with a hook at one end and an eyelet at the other end, both of which project beyondthe main .10 body of anodic metal.
  • Any desired number of the anodes may be hooked together to correspond to the length of the object to be plated by inserting the hook of one anode into the eyelet of another.
  • the anodes may be made in varying lengths.
  • the bod of anodic metal comprises longitudinal ro ections extending partly around'the eyeet'. These projections are placed in sucha way as not to interfere with the hooking of one anode with another.
  • Fig. 1 is a front elevation of the anode
  • Fig. 2 is a top plan view
  • Fig. 3 is a bottom plan view
  • Fig. 4 is a side elevation of the anode shown in Fig. 1.
  • the invention is particularly designed and adapted for use in connection with cadmium or Z1110 plating anodes comprising a steel rod as the inert conductive material and cadium or zinc as the anodic metal and will be de- :7
  • A. is a steel core of square cross-section, the upper end of which is formed into the eyelet G and the lower'end into thehook E.
  • the body B of anodic metal, specifically cadmium.
  • the projections D from the main in connection with body B extend'partly around the eyelet.
  • the 1 projections D preferably are formed as illus-j trated leaving? only a groove in the anodic t5 metal transverse to the plane of the eyelet so that two anodes may be hooked together.
  • the steel core A is shown of square crosssection. but 'ob'viousl itmay be round or of any other form.' A so, the outer. surface of the cast anodic metal may be round'orof any oltlher desired form instead of hexagonal as S 0WD.
  • Anodes of the typevdescribed and illustrated have been made of cadmium cast onto a steel core both with and without an'inte'rmediate coating of electroplated cadmium and have been found'to be of particular value for electroplating objects of varying lengths.
  • the invention is not limited to cadmium anodes comprising a steel core excepting as may be required. by the terms of the appendei i claims. Many shapes and sizes of the core of inert metal, the hook, eyelet, lugs and cast metal may be designed without departure from the invention. 1 4 I We claim I 1.
  • An anode for use inelectroplating comprising a coreof inert conductivematerial which is formed into a hook at one end and-an I eyelet at the other end,,said. core having a bod of anodic metal cast around it between v i 2.
  • An anode' for use in electroplating comprising a core of inert conductive'material which is form'edinto, a hook at one end and an eyelet at .the other.
  • said core having a body of anodicmetal cast around it between the hook and eyelet and extending partly aroundthe eyelet in the form of tv'vo'projec tions but leaving the eyelet exposed suflici'ently to allow the hook of another similar anode to be engaged therewith.
  • An anode for use in electroplating comprising a core of inerticonductive material which is formed into a hook at one end and an eyelet at the other end, said corebeing elec troplated with an anodic metal and having a body of the anodic metal cast around the electroplated core between the hook and eyelet.
  • An anode for use in electroplating comprising a core of inert conductive material which 1s formed into a hook at one end and an eyelet at the other end, said core being electroplated with an anodic metal and having a body of the anodic metal cast around the electroplated core between the hook and eyelet and extending partly around the eyelet in the form of two projections but leaving the eyelet exposed suflicientl to allow the hook of another similar ano e to be engaged therewith.
  • An anode for use 1n electroplat ng comprising a steelcore-which is formed into a hook at one end and an eyelet at the other end, said steel core having a. body of cadmium cast around it between the hook and eyelet.
  • said steel core being electroplated with cadmium and having a body of cadmium cast around the cadmium plated core between the hook and eyelet.
  • An anode for use in electroplating comprising a steel corewhich is formed into a hook at one end and an eyelet at the other end, said steel core being electroplated with cadmium and having a body of cadmium cast around the cadmium plated core between the hook and eyelet and extending partly around the eyelet-in the form of two projections but the hook of another similar anode to be engaged therewith.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Description

April 1-6, 1929.
F. J. DELAYIE ET AL ANODE Filed Nov. 29, 1927.
II -Llllllll .Patented Apr. 16, 1929.
UNITED um .PATENTo FI E- rm]: .1. DELAVIE Ann Howum H. BLOUCH, or CLEVELAND, onto, ASSIGNOBS, 3v
lnsnn ASSIGNMENTS, ro THE GBASSELLI cnnmrcal. COMPANY, OF CLEVELAND, j
01110, A oonronarxox orn'nmwnan'.
AN ODE.
Applicatibnflledlovember 29,1927. Serial No. 236,562.
This invention relates to anodes which are particularly suited for usein electroplating objects of varying-lengths such as, for instance, lamp posts, pipe, etc, 5 The anodes each consist of a rod-of inert conductive material carrying a body; of the anodic metal. The rod is provided with a hook at one end and an eyelet at the other end, both of which project beyondthe main .10 body of anodic metal. Any desired number of the anodes may be hooked together to correspond to the length of the object to be plated by inserting the hook of one anode into the eyelet of another. The anodes may be made in varying lengths. Preferably the bod of anodic metal comprises longitudinal ro ections extending partly around'the eyeet'. These projections are placed in sucha way as not to interfere with the hooking of one anode with another. v
The accompanying drawings illustrate one type of construction of the anodes inaccord= ance with our invention.
Fig. 1 is a front elevation of the anode; Fig. 2 is a top plan view; Fig. 3 is a bottom plan view and Fig. 4 is a side elevation of the anode shown in Fig. 1. v
. The invention is particularly designed and adapted for use in connection with cadmium or Z1110 plating anodes comprising a steel rod as the inert conductive material and cadium or zinc as the anodic metal and will be de- :7
scribed and illustrated such an anode.
In the drawings, A. is a steel core of square cross-section, the upper end of which is formed into the eyelet G and the lower'end into thehook E. Around this core is cast the body B of anodic metal, specifically cadmium. The projections D from the main in connection with body B extend'partly around the eyelet. The 1 projections D preferably are formed as illus-j trated leaving? only a groove in the anodic t5 metal transverse to the plane of the eyelet so that two anodes may be hooked together. I y
The steel core A is shown of square crosssection. but 'ob'viousl itmay be round or of any other form.' A so, the outer. surface of the cast anodic metal may be round'orof any oltlher desired form instead of hexagonal as S 0WD.
gradually eaten away and the anode will .--sooner or.later break, whereas anodes made .the 00k and eyelet. Y
The advantage of these anodes is that they may be very easily hooked together toproduce an anode of any desired length. The weight of the anodic metal is carried entirely bythe inert and relatively strong core... In anodes made entirely of anodic metal without a core of inert metal, the anodic metal is 1n accordance with this invention will not. It has been found that if the steelcore is first electroplated "with'cadmium, the cad-. mium body may becast onto the core much more intimately than if the core is'not electroplated. The breaking oif of the anodic V metal from the core during electrolysis is thus prevented. i
Anodes of the typevdescribed and illustrated have been made of cadmium cast onto a steel core both with and without an'inte'rmediate coating of electroplated cadmium and have been found'to be of particular value for electroplating objects of varying lengths. However, the invention is not limited to cadmium anodes comprising a steel core excepting as may be required. by the terms of the appendei i claims. Many shapes and sizes of the core of inert metal, the hook, eyelet, lugs and cast metal may be designed without departure from the invention. 1 4 I We claim I 1. An anode for use inelectroplating, comprising a coreof inert conductivematerial which is formed into a hook at one end and-an I eyelet at the other end,,said. core having a bod of anodic metal cast around it between v i 2. An anode' for use in electroplating, comprising a core of inert conductive'material which is form'edinto, a hook at one end and an eyelet at .the other. end, said core having a body of anodicmetal cast around it between the hook and eyelet and extending partly aroundthe eyelet in the form of tv'vo'projec tions but leaving the eyelet exposed suflici'ently to allow the hook of another similar anode to be engaged therewith.
3. An anode for use in electroplating, comprising a core of inerticonductive material which is formed into a hook at one end and an eyelet at the other end, said corebeing elec troplated with an anodic metal and having a body of the anodic metal cast around the electroplated core between the hook and eyelet.
4. An anode for use in electroplating, comprising a core of inert conductive material which 1s formed into a hook at one end and an eyelet at the other end, said core being electroplated with an anodic metal and having a body of the anodic metal cast around the electroplated core between the hook and eyelet and extending partly around the eyelet in the form of two projections but leaving the eyelet exposed suflicientl to allow the hook of another similar ano e to be engaged therewith.
5. An anode for use 1n electroplat ng, comprisinga steelcore-which is formed into a hook at one end and an eyelet at the other end, said steel core having a. body of cadmium cast around it between the hook and eyelet.
.6. An anode for use in electroplating, com- 'prisinga steel core which is formed into a hook at one end and an eyelet at the other end,
and extending partly around the eyelet in the form of two projections but leaving the eye-'- said steel core having a body of cadmium cast around it between the hook and eyelet leaving the eyelet exposed sufficiently to allow let exposed 'sufiiciently to allow the hook of another similar anode to be engaged therewith.
7. An anode for use in electroplating,compr1s1ng a steel corewhlch 1s formed lnto a hook at one end and an eyelet at the other end,
said steel core being electroplated with cadmium and having a body of cadmium cast around the cadmium plated core between the hook and eyelet.
8. An anode for use in electroplating, comprising a steel corewhich is formed into a hook at one end and an eyelet at the other end, said steel core being electroplated with cadmium and having a body of cadmium cast around the cadmium plated core between the hook and eyelet and extending partly around the eyelet-in the form of two projections but the hook of another similar anode to be engaged therewith. In testimony whereof, we aflix our signa- .tures.
US236562A 1927-11-29 1927-11-29 Anode Expired - Lifetime US1709523A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2445675A (en) * 1941-11-22 1948-07-20 William C Lang Apparatus for producing coated wire by continuous process
US2481827A (en) * 1941-08-14 1949-09-13 Cox George Chandler Electrode terminal connections for the electrolysis of seaport and related waters
US2529348A (en) * 1948-10-27 1950-11-07 E L Mustee And Sons Inc Method of making sacrifice rods for water tanks
US2870079A (en) * 1954-11-16 1959-01-20 Texas Co Cathodic protection of metal structures
US2947680A (en) * 1957-12-02 1960-08-02 Herman S Preiser Multiple disc anode
US3409465A (en) * 1962-03-30 1968-11-05 Ziegler Process for improving the wettability of solid metallic surfaces by molten alkali metals
US4294670A (en) * 1979-10-29 1981-10-13 Raymond Louis W Precision electroplating of metal objects

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2481827A (en) * 1941-08-14 1949-09-13 Cox George Chandler Electrode terminal connections for the electrolysis of seaport and related waters
US2445675A (en) * 1941-11-22 1948-07-20 William C Lang Apparatus for producing coated wire by continuous process
US2529348A (en) * 1948-10-27 1950-11-07 E L Mustee And Sons Inc Method of making sacrifice rods for water tanks
US2870079A (en) * 1954-11-16 1959-01-20 Texas Co Cathodic protection of metal structures
US2947680A (en) * 1957-12-02 1960-08-02 Herman S Preiser Multiple disc anode
US3409465A (en) * 1962-03-30 1968-11-05 Ziegler Process for improving the wettability of solid metallic surfaces by molten alkali metals
US4294670A (en) * 1979-10-29 1981-10-13 Raymond Louis W Precision electroplating of metal objects

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