US1659158A - Apparatus for dispersing irritants - Google Patents
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- US1659158A US1659158A US710172A US71017224A US1659158A US 1659158 A US1659158 A US 1659158A US 710172 A US710172 A US 710172A US 71017224 A US71017224 A US 71017224A US 1659158 A US1659158 A US 1659158A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
- F42B12/46—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information for dispensing gases, vapours, powders or chemically-reactive substances
- F42B12/50—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information for dispensing gases, vapours, powders or chemically-reactive substances by dispersion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B27/00—Hand grenades
Definitions
- NICHOLAS E. OGLES BY AND DAY EHRENFELD, OF ED'GEWOOD, MARYLAND, ASSIGNORS, BY MESNE ASSIGNMENTS, TO FEDERAL LABORATORIES, INC., OF PITTSBURGH, PENNSYLVANIA, Av CORPORATION 01 DELAWARE.
- This invention relates to an apparatus for dispersing irritants including those which are lachrymating as-well as those which are toxic.
- irritants particularly those not readily volatile atordinary temperatures may be dispersed into the atmosphere in substantially non-persistent form without undergoing decomposition.
- a further object of this invention is to provide a device whereby the irritant may be evolved in effective concentrations without undergoing substantial chemical decomposition and without danger of explosions which render the apparatus inefiective in so far asdispersion of the irritant is concerned. These explosions also cause dangerous fragments to fiy'from the device which are to be avoided in a device for mob dispersionand similar uses where deaths or serious injuries should be avoided.
- an oo ect of this invention to provide an apparatus containing a cooling and expansion chamber for receiving the evolved irritant and having suitable openings for permitting the escape of the evolved irritant from said chamber.
- This invention is applicable to irritants such as capsaicin and diphenyl'chlorarsine, and also irritants which have pronounced lachrymating properties such as chloraceto phen'one, bromacetophenone, p-bromchloracetophenone or iodoacetophenone.
- Fig. 1 is a vertical section of a Stokes shell with an impact fuse at one end.
- Fig. 2 is a vertical section of a hand grenade provided with a standard form of bouchon.
- the Stokes shell com prises the main metal body (1) of suitable material, such as thin steel, connected with the base (2) and head (3). Near the head end the body (1) contains a plurality of perforations (4). Ordinarily, the interior of these shells is irregular at. the'base and the cavity is filled with a suitable material (5), such as parafiin, and upon this is placed a metal disc (6).
- suitable material (5) such as parafiin
- the shell is oaded by stackmg upon the metal disc (6) for the depth desired cakes or irritant mixture.
- blocks of powder (7 such as nitrocellulose, of suitable size, for example 12-inch rifle powder, and the shell and powder are then brought to a temperature. of about C.
- a small amount of nitrocellulose powder of smaller calibre (for example .30 calibre rifle powder) previously heated to about the same temperature is then poured so as to sift its way into the spaces between the large blocks of powder.
- an irritant such as chloracetophenone
- the irritant is heated to a temperature of -90? C'. and about 6% MgO 1s stlrred into the molten irritant to form a.
- the MgO is used as a stabilizer in the mix. Molten or liquefied chloracetophenone i s then added as the shell cools until when cold the chloracctophenone and nitrocellulose powder are at about the same level. 'The M20 is added to the mixture for the purpose of stabilization, it being an antiacid and tends to overcome or counteract the tendency for slow decomposition to develop in the mixture after preparation.
- a suitable starter paste may be made by thoroughly mixing 2 parts of a dry starter to 1 part of a binding solution.
- the dry starter consisting of:
- the binding solution may consist-of asolution of celluloid in acetone of about 4%.
- the openings (4) are covered by a thin strip of zinc 9) soldered tothe metal body of the shell.
- the head (3) carrying the impact fuse (10) is then screwed on to the body (1) of the shell.
- the zinc strip (9) blows off and the starter (8) burns and in turn ignites'the powder
- the powder burns and generates hot gases which carryolf the irritant volatilized thereby as an entrained component, the exit gases passing through the openings (4) into the air.
- the shell is'fill-ed so as to provlde a substantial space between the top of the irritantfuel mixture and the head
- the evolved combustion gases and irritant expand in this space and become cooled to an appreciable extent and issue from the openings (4) at a temperature below that at which flashing or substantial decomposition of the irritant would occur on coming in contact with the oxygen of the air, thus rendering the dispersion of the irritant highly eflicient and minimizing to a large extent. if not entirely, the waste of irritant which would otherwise occur by chemical reaction or decomposition.
- the grenade comprises the body (11) which is made of suitable metal, such as thin steel, and is provided with a plurality of openings (12). These holes are preferably covered with adhesive tape (13) which is subsequently coated with shellac.
- the materials may be intimately mixed and the required amount-placed in the container.
- the container is then heated by placing the grenade in boiling water (not allowing the water to enter the grenade) until the mixture becomes more or less plastic.
- the grenade is then removed from the water and the mixture pressed or tamped until compact.
- the heating should be sufficient to melt the chloraeetophenone in order that the mixture (14) will tamp or press compactly, but overheating should be avoided as this will result in a solution of smokeless powder in chloracetophenone, which will not remain fluid at or below C. and the mixture will not compress or pack well.
- a suitable mixture may be made of:
- the firing mechanism is then screwed on to the grenade at (16).
- This firing mechanism is of standard construction and comprises the bouchon having the fuse (17) which has the end tip (18) consisting of a paste similar to the starter (15).
- the pin (19) In operating the grenade the pin (19) is withdrawn by pulling the ring (20). The strap (21) is then released and flies off which permits the firing mechanism to function, t ereby igniting the fuse (17).
- the fuse which is preferably a time fuse, after the pre-determined delay, fires the tip (18) which in turn fires the starter (15). As this starter burns the mixture (14) is ignited, the tape is blown from the exit holes and the irritant is evolved through the openings (12) in the manner heretofore described in the Stokes shell.
- this invention may be readily adapted to a' rifle grenade, a bomb to be dropped fromaeroplanes and similar devices.
- a container having a cake of an intimately distributed mixture of an irritant and a fuel which burns at -a temperature sufficient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, an expansion and cooling chamber adjacent to and communicating with said mixture and means for igniting said mixture.
- a container having in a portion thereof a compact, intimately distributed mixture of 116 a lachrymatjing compound and a fuel which burns at a temperature sufiicient to volatilize the lachrymator but below that at which the lachrymator will decompose within the time required for said volatilization, an adjacent, 120 communicating portion of suflicient size to admit expansion and cooling of the gases evolved from said mixture nad means for igniting said mixture.
- a container having a compact cake of an intimately distributed mixture of an irritant and a fuel which burns at a temperature sufficient to volatilizethe irritant but below that at which the irritant will decompose within the time required for said volatiliza-' tion, means comprising an openingin said container for permitting the escape of the gases evolved from said mixture and means for igniting said mixture.
- a container having in a portion thereof a stabilized, compact, intimately distributed mixture of,an irritant and a'fuel which burns at a temperature suflicient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, an adjacent, communicating portion of said container of sufiicient size to admit expansion and cooling of the gases evolved from said mixture and ,providtilization, an adjacent, communicating portion of sufficient size to admit expansion and cooling of the gases evolved from said mixture and provided with an opening for permitting escape of said evolved gases, a starter composition cemented to the surface of said cake and having a'portion thereof assimilat ed'with said mixture, and means for igniting said starter composition.
- a device for dispersing an irritant comprising a vaporizable irritant, means for converting it into avapor'having a temperature. at which it would decompose in air, and means whereby the vaporized irritant is cooled before it leaves the device.
- a container having a cake of an intimately distributed mixture of an irritant and a fuel which burns at a temperature sufficient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, an expansion municating with said mixture, a starter composition upon the surface of said cake for igniting said mixture and means for igniting said starter composition.
- a container having a stabilized, compact, in-
- a container having in a portion thereof a cake of an intimately distributed mixture of an irritant and a fuel which burns at a temperature suflicient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, an adjacent, communicating .portion of suflicient size to admit expansion 'and'cooling of the gases evolved from said mixture, a starter composition cemented to the surface of said cake for igniting said mixture and means for igniting said starter composition.
- a container having in a portion thereof a cake of an intimately distributed mixture of an irritant and a fuel which burns at a temperature sufficient to volatilize the irritant but below that at which the irritant will decompose wlthin the tune required for said volacomprising'a vaporizable irritant, means for converting it into a vapor having a-temperature at which it would decompose in air, and a cooling and expansion chamber through which the vaporized irritant passes on its way out of the device.
- a device for dispersing an irritant comprising a vaporizable irritant, a fuel adapted to give off hot gases effective for converting the irritant into a'vapor having a temperature at which it would decompose in air, and means wherebv the vaporized irritant is cooled before it leaves the device.
- the method of dispersing an irritant which includes subjecting a vaporizable irritant in an enclosure to heat so as to convert it into a vapor having a temperature at which it would decompose in air, and cooling the vaporized irritant before it leaves the enclosure.
- the method of dispersing an irritant which is a halogen, derivative of acetophenone which includes subjecting the irritant within an enclosure to heat so as to convert the halogen derivative of acetophenone into a vapor, and cooling the vapor before it leaves the enclosure.
- a device for dispersing an irritant comprising a vaporizable irritant, a fuel which is effective for converting the irritant into a vapor having a temperature at which it would decompose in air, the fuel and the irritant being relatively so disposed that the irritant is exposed to the hot products of combustion of the fuel, and means whereby the vaporized irritant and the products of combustion are cooled on their way out of the device.
- a device for dispersing an irritant comprising a container having therein a vaporizable irritant and a fuel capable of self-sustaining combustion, the irritant being within the combustion zone of the fuel so as to be directly exposed to the flame thereof, and means whereby the vaporized irritant is cooled on its way out of the device.
- a device for dispersing an irritant comprising a container having therein a vaporizable irritant and a fuel capable of self-sustaining combustion, the irritant being within the combustion zone of the fuel so as to be directly exposed to the fiame thereof, and a cooling and expansion chamber through which the vaporized irritant passes on its way out of the device.
- a device for dispersing an irritant comprising a container having therein amixture of chloracetophenone and a fuel capable of self-sustaining combustion, effective for vaporizing the chloracetophenone, and means whereby the vaporized chloracetophenoneis cooled on its way out of the device.
- a device for dispersing an irritant comprising a container having therein a vaporizable irritant and a chemical capable of producing a heat generating reaction, the
- irritant being within the reaction zone of the chemical so as to be exposed to the heat thereof, and means whereby thevaporized irritant is cooled on its way out of the device.
- a device for dispersing an irritant comprising a container having therein a vaporizable irritant and a chemical capable of producing a heat generating reaction the irritant being within the reaction zone of the NICHOLAS E. OGLESBY. DAY EHRENFELD.
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Description
Feb. 14, 1928. 1,659,158
N. E. OGLESBY ET AL APPARATUS FOR DISPERSING IRRITANTS Original Filed April 30, 1924 NichomazE. Oglewbg and Day. Ehrenfc ld Patented Feb.14, 1928.
UNlTED STATES 1,659,158 PATENT OFFICE.
NICHOLAS E. OGLES BY AND DAY EHRENFELD, OF ED'GEWOOD, MARYLAND, ASSIGNORS, BY MESNE ASSIGNMENTS, TO FEDERAL LABORATORIES, INC., OF PITTSBURGH, PENNSYLVANIA, Av CORPORATION 01 DELAWARE.
APPARATUS FOR DI SPERSING IRRITANTS Application filed April 30, 1924, Serial No. 710,172. Renewed July 17, 1926.
This invention relates to an apparatus for dispersing irritants including those which are lachrymating as-well as those which are toxic.
Among the objects of this invention is to provide an apparatus whereby irritants particularly those not readily volatile atordinary temperatures may be dispersed into the atmosphere in substantially non-persistent form without undergoing decomposition.
A further object of this invention is to provide a device whereby the irritant may be evolved in effective concentrations without undergoing substantial chemical decomposition and without danger of explosions which render the apparatus inefiective in so far asdispersion of the irritant is concerned. These explosions also cause dangerous fragments to fiy'from the device which are to be avoided in a device for mob dispersionand similar uses where deaths or serious injuries should be avoided.
More specifically it is an oo ect of this invention to provide an apparatus containing a cooling and expansion chamber for receiving the evolved irritant and having suitable openings for permitting the escape of the evolved irritant from said chamber.
This invention is applicable to irritants such as capsaicin and diphenyl'chlorarsine, and also irritants which have pronounced lachrymating properties such as chloraceto phen'one, bromacetophenone, p-bromchloracetophenone or iodoacetophenone.
Reference is to be had to the accompanying drawings wherein specific devices embodying this invention are shown.
Fig. 1 is a vertical section of a Stokes shell with an impact fuse at one end.
Fig. 2 is a vertical section of a hand grenade provided with a standard form of bouchon.
Referring to Fig. 1, the Stokes shell com prises the main metal body (1) of suitable material, such as thin steel, connected with the base (2) and head (3). Near the head end the body (1) contains a plurality of perforations (4). Ordinarily, the interior of these shells is irregular at. the'base and the cavity is filled with a suitable material (5), such as parafiin, and upon this is placed a metal disc (6).
The shell is oaded by stackmg upon the metal disc (6) for the depth desired cakes or irritant mixture.
blocks of powder (7 such as nitrocellulose, of suitable size, for example 12-inch rifle powder, and the shell and powder are then brought to a temperature. of about C. A small amount of nitrocellulose powder of smaller calibre (for example .30 calibre rifle powder) previously heated to about the same temperature is then poured so as to sift its way into the spaces between the large blocks of powder. In using an irritant such as chloracetophenone, the irritant is heated to a temperature of -90? C'. and about 6% MgO 1s stlrred into the molten irritant to form a.
substantially uniform suspension. which is then poured into the shell so as to fill the interstices between the pieces of powder. The MgO is used as a stabilizer in the mix. Molten or liquefied chloracetophenone i s then added as the shell cools until when cold the chloracctophenone and nitrocellulose powder are at about the same level. 'The M20 is added to the mixture for the purpose of stabilization, it being an antiacid and tends to overcome or counteract the tendency for slow decomposition to develop in the mixture after preparation.
-When the mass has cooled it is thoroughly covered with a starterpastc (8) so that none of the surface rema ns exposed. A suitable starter paste may be made by thoroughly mixing 2 parts of a dry starter to 1 part of a binding solution. The dry starter consisting of:
Meal powder The binding solution may consist-of asolution of celluloid in acetone of about 4%.
The openings (4) are covered by a thin strip of zinc 9) soldered tothe metal body of the shell. The head (3) carrying the impact fuse (10) is then screwed on to the body (1) of the shell.
In operation, as the impact fuse functions the zinc strip (9) blows off and the starter (8) burns and in turn ignites'the powder The powder burns and generates hot gases which carryolf the irritant volatilized thereby as an entrained component, the exit gases passing through the openings (4) into the air.
The shellis'fill-ed so as to provlde a substantial space between the top of the irritantfuel mixture and the head The evolved combustion gases and irritant expand in this space and become cooled to an appreciable extent and issue from the openings (4) at a temperature below that at which flashing or substantial decomposition of the irritant would occur on coming in contact with the oxygen of the air, thus rendering the dispersion of the irritant highly eflicient and minimizing to a large extent. if not entirely, the waste of irritant which would otherwise occur by chemical reaction or decomposition.
into compounds or compositions lacking the desired properties of the irritant.
Referring to Fig. 2, the grenade comprises the body (11) which is made of suitable metal, such as thin steel, and is provided with a plurality of openings (12). These holes are preferably covered with adhesive tape (13) which is subsequently coated with shellac.
In loading this grenade with a mixture (14) of chloracetophenonc, nitrocellulose and a suitable stabilizer, such as MgO, the materials may be intimately mixed and the required amount-placed in the container. The container is then heated by placing the grenade in boiling water (not allowing the water to enter the grenade) until the mixture becomes more or less plastic. The grenade is then removed from the water and the mixture pressed or tamped until compact. The heating should be sufficient to melt the chloraeetophenone in order that the mixture (14) will tamp or press compactly, but overheating should be avoided as this will result in a solution of smokeless powder in chloracetophenone, which will not remain fluid at or below C. and the mixture will not compress or pack well. A suitable mixture may be made of:
Parts. Nitrocellulose (.30 calibre) 24 Ghloracetophenone 9' MgO 1 After the mass has cooled, -the starter paste (15) is applied. This starter paste may consist of substantially equal parts of meal powder and 3 solution of celluloid dissolved in acetone. The grenade is then allowed to stand open for about 12 hours until the starter paste has hardened.
The firing mechanism is then screwed on to the grenade at (16). This firing mechanism is of standard construction and comprises the bouchon having the fuse (17) which has the end tip (18) consisting of a paste similar to the starter (15).
In operating the grenade the pin (19) is withdrawn by pulling the ring (20). The strap (21) is then released and flies off which permits the firing mechanism to function, t ereby igniting the fuse (17). The fuse, which is preferably a time fuse, after the pre-determined delay, fires the tip (18) which in turn fires the starter (15). As this starter burns the mixture (14) is ignited, the tape is blown from the exit holes and the irritant is evolved through the openings (12) in the manner heretofore described in the Stokes shell.
Although the construction and operation of a hand grenade are illustrated,this invention may be readily adapted to a' rifle grenade, a bomb to be dropped fromaeroplanes and similar devices.
These devices admit of the dispersion of the irritating gas without bursting the container and without flashing (i. e. ignition of the irritant on coming in contact with air) since the gasesare cooled appreciably in the expansion space and the gases are released fairly rapidly into the air through openings in the cooling chamber which result in sudden cooling of the gas. If released sufliciently rapidly this sudden cooling will virtually blow out any flame that may start, butdanger of exploding the device arises and it is therefore advisable to do some cooling Within the expansion space.
' The present invention is not limited to the specific details set forth in the foregoing examples which should be construed as illustrative and not by way of limitation, and in View of the numerous modifications which may be eflected therein without departing from the spirit and scope of this invention, it is desired that only such limitations be imposed as are' indicated in the appended 100 claims. I
We claim as our invention:
1. In a'deviee for dispersing an irritant,
a container having a cake of an intimately distributed mixture of an irritant and a fuel which burns at -a temperature sufficient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, an expansion and cooling chamber adjacent to and communicating with said mixture and means for igniting said mixture.
2. In a. device for dispersing an irritant,
a container having in a portion thereof a compact, intimately distributed mixture of 116 a lachrymatjing compound and a fuel which burns at a temperature sufiicient to volatilize the lachrymator but below that at which the lachrymator will decompose within the time required for said volatilization, an adjacent, 120 communicating portion of suflicient size to admit expansion and cooling of the gases evolved from said mixture nad means for igniting said mixture.
.3. In a device for dispersing an irritant, a container having a compact cake of an intimately distributed mixture of an irritant and a fuel which burns at a temperature sufficient to volatilizethe irritant but below that at which the irritant will decompose within the time required for said volatiliza-' tion, means comprising an openingin said container for permitting the escape of the gases evolved from said mixture and means for igniting said mixture.
4:. In a device for dispersing an irritant, a container having in a portion thereof a stabilized, compact, intimately distributed mixture of,an irritant and a'fuel which burns at a temperature suflicient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, an adjacent, communicating portion of said container of sufiicient size to admit expansion and cooling of the gases evolved from said mixture and ,providtilization, an adjacent, communicating portion of sufficient size to admit expansion and cooling of the gases evolved from said mixture and provided with an opening for permitting escape of said evolved gases, a starter composition cemented to the surface of said cake and having a'portion thereof assimilat ed'with said mixture, and means for igniting said starter composition.
9. A device for dispersing an irritant, comprising a vaporizable irritant, means for converting it into avapor'having a temperature. at which it would decompose in air, and means whereby the vaporized irritant is cooled before it leaves the device.
10. A- device for dispersing an irritant,
. and cooling chamber adjacent to and com-- ed with an opening for permitting escape of said evolved gases and means for igniting said mixture.
5. In a device for dispersing an irritant, a container having a cake of an intimately distributed mixture of an irritant and a fuel which burns at a temperature sufficient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, an expansion municating with said mixture, a starter composition upon the surface of said cake for igniting said mixture and means for igniting said starter composition. 1
6. In a device for dispersing an. irritant, a container having a stabilized, compact, in-
timately distributed" mixture of an irritant and a fuel which burns at a temperature sufficient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, means comprising an opening in said container fonpermitting the escape of the gases evolved from said mixture, a starter composition integrally secured to the surface of said cake for igniting said mixture and means for igniting said starter composition. 1 7. Ina device for dispersing an irritant, a container having in a portion thereof a cake of an intimately distributed mixture of an irritant and a fuel which burns at a temperature suflicient to volatilize the irritant but below that at which the irritant will decompose within the time required for said volatilization, an adjacent, communicating .portion of suflicient size to admit expansion 'and'cooling of the gases evolved from said mixture, a starter composition cemented to the surface of said cake for igniting said mixture and means for igniting said starter composition.
8. Ina device for dispersing an irritant, a container having in a portion thereof a cake of an intimately distributed mixture of an irritant and a fuel which burns at a temperature sufficient to volatilize the irritant but below that at which the irritant will decompose wlthin the tune required for said volacomprising'a vaporizable irritant, means for converting it into a vapor having a-temperature at which it would decompose in air, and a cooling and expansion chamber through which the vaporized irritant passes on its way out of the device.
11. A device for dispersing an irritant, comprising a vaporizable irritant, a fuel adapted to give off hot gases effective for converting the irritant into a'vapor having a temperature at which it would decompose in air, and means wherebv the vaporized irritant is cooled before it leaves the device.
12. The method of dispersing an irritant which includes subjecting a vaporizable irritant in an enclosure to heat so as to convert it into a vapor having a temperature at which it would decompose in air, and cooling the vaporized irritant before it leaves the enclosure.
13. The method of dispersing an irritant which is a halogen, derivative of acetophenone, which includes subjecting the irritant within an enclosure to heat so as to convert the halogen derivative of acetophenone into a vapor, and cooling the vapor before it leaves the enclosure. 1
'14. A device for dispersing an irritant, comprising a vaporizable irritant, a fuel which is effective for converting the irritant into a vapor having a temperature at which it would decompose in air, the fuel and the irritant being relatively so disposed that the irritant is exposed to the hot products of combustion of the fuel, and means whereby the vaporized irritant and the products of combustion are cooled on their way out of the device. I
15. A device for dispersing an irritant, comprising a container having therein a vaporizable irritant and a fuel capable of self-sustaining combustion, the irritant being within the combustion zone of the fuel so as to be directly exposed to the flame thereof, and means whereby the vaporized irritant is cooled on its way out of the device.
16. A device for dispersing an irritant, comprising a container having therein a vaporizable irritant and a fuel capable of self-sustaining combustion, the irritant being within the combustion zone of the fuel so as to be directly exposed to the fiame thereof, and a cooling and expansion chamber through which the vaporized irritant passes on its way out of the device.
17. A device for dispersing an irritant, comprising a container having therein amixture of chloracetophenone and a fuel capable of self-sustaining combustion, effective for vaporizing the chloracetophenone, and means whereby the vaporized chloracetophenoneis cooled on its way out of the device.
18. A device for dispersing an irritant comprising a container having therein a vaporizable irritant and a chemical capable of producing a heat generating reaction, the
irritant being within the reaction zone of the chemical so as to be exposed to the heat thereof, and means whereby thevaporized irritant is cooled on its way out of the device.
19. A device for dispersing an irritant comprising a container having therein a vaporizable irritant and a chemical capable of producing a heat generating reaction the irritant being within the reaction zone of the NICHOLAS E. OGLESBY. DAY EHRENFELD.
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US710172A US1659158A (en) | 1924-04-30 | 1924-04-30 | Apparatus for dispersing irritants |
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US710172A US1659158A (en) | 1924-04-30 | 1924-04-30 | Apparatus for dispersing irritants |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2423859A (en) * | 1943-12-10 | 1947-07-15 | Joseph W Van Karner | Smoke producing device |
US2959127A (en) * | 1956-02-16 | 1960-11-08 | Fed Lab Inc | Gas grenade |
DE1166050B (en) * | 1960-06-09 | 1964-03-19 | Israel State | Warfare grenade, in particular tear gas grenade |
US3269313A (en) * | 1965-01-18 | 1966-08-30 | William G Willmann | Self-propelled sub-munition |
US4777032A (en) * | 1985-08-27 | 1988-10-11 | Societe Nationale Des Poudres Et Explosifs | Paper distributing an active compound on burning, and a pyrotechnic distributor using such paper |
US5069134A (en) * | 1990-06-08 | 1991-12-03 | Def-Tec Corporation | Flameless expulsion grenade |
US20040200374A1 (en) * | 2003-02-24 | 2004-10-14 | Arie Sansolo | Explosion simulator |
-
1924
- 1924-04-30 US US710172A patent/US1659158A/en not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2423859A (en) * | 1943-12-10 | 1947-07-15 | Joseph W Van Karner | Smoke producing device |
US2959127A (en) * | 1956-02-16 | 1960-11-08 | Fed Lab Inc | Gas grenade |
DE1166050B (en) * | 1960-06-09 | 1964-03-19 | Israel State | Warfare grenade, in particular tear gas grenade |
US3269313A (en) * | 1965-01-18 | 1966-08-30 | William G Willmann | Self-propelled sub-munition |
US4777032A (en) * | 1985-08-27 | 1988-10-11 | Societe Nationale Des Poudres Et Explosifs | Paper distributing an active compound on burning, and a pyrotechnic distributor using such paper |
US5069134A (en) * | 1990-06-08 | 1991-12-03 | Def-Tec Corporation | Flameless expulsion grenade |
US20040200374A1 (en) * | 2003-02-24 | 2004-10-14 | Arie Sansolo | Explosion simulator |
US6845715B2 (en) * | 2003-02-24 | 2005-01-25 | Arie Sansolo | Explosion simulator |
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